CN116138266A - Anti-mite agent composition for mattress cloth and application thereof - Google Patents
Anti-mite agent composition for mattress cloth and application thereof Download PDFInfo
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- CN116138266A CN116138266A CN202310060322.4A CN202310060322A CN116138266A CN 116138266 A CN116138266 A CN 116138266A CN 202310060322 A CN202310060322 A CN 202310060322A CN 116138266 A CN116138266 A CN 116138266A
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- 239000000203 mixture Substances 0.000 title claims abstract description 109
- 239000004744 fabric Substances 0.000 title abstract description 149
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims abstract description 62
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 50
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 37
- -1 ethyl butyl Chemical group 0.000 claims abstract description 35
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- 229940005460 butyl levulinate Drugs 0.000 claims abstract description 26
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229960000490 permethrin Drugs 0.000 claims abstract description 21
- 239000003495 polar organic solvent Substances 0.000 claims abstract description 9
- 239000004202 carbamide Substances 0.000 claims abstract description 3
- 238000004519 manufacturing process Methods 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 74
- 239000000839 emulsion Substances 0.000 claims description 24
- 238000002360 preparation method Methods 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 13
- 229920000053 polysorbate 80 Polymers 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000136 polysorbate Polymers 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 150000002334 glycols Chemical class 0.000 claims description 3
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 2
- 229940035437 1,3-propanediol Drugs 0.000 claims description 2
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 2
- 230000001476 alcoholic effect Effects 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 150000002009 diols Chemical class 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 2
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 2
- 229960004063 propylene glycol Drugs 0.000 claims description 2
- 235000013772 propylene glycol Nutrition 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 13
- 238000003756 stirring Methods 0.000 description 49
- 239000012224 working solution Substances 0.000 description 48
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 22
- 238000007493 shaping process Methods 0.000 description 20
- 238000000034 method Methods 0.000 description 18
- 239000007788 liquid Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 16
- 238000001035 drying Methods 0.000 description 15
- 238000005470 impregnation Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 241000238876 Acari Species 0.000 description 10
- 230000002940 repellent Effects 0.000 description 10
- 239000005871 repellent Substances 0.000 description 10
- 239000000428 dust Substances 0.000 description 8
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 238000009998 heat setting Methods 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 238000009472 formulation Methods 0.000 description 4
- 239000000523 sample Substances 0.000 description 3
- 208000000059 Dyspnea Diseases 0.000 description 2
- 206010013975 Dyspnoeas Diseases 0.000 description 2
- 239000013566 allergen Substances 0.000 description 2
- 208000006673 asthma Diseases 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 239000013074 reference sample Substances 0.000 description 2
- 230000028327 secretion Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- 206010002660 Anoxia Diseases 0.000 description 1
- 241000976983 Anoxia Species 0.000 description 1
- 206010008479 Chest Pain Diseases 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010011703 Cyanosis Diseases 0.000 description 1
- 102100024452 DNA-directed RNA polymerase III subunit RPC1 Human genes 0.000 description 1
- 206010012434 Dermatitis allergic Diseases 0.000 description 1
- 101000689002 Homo sapiens DNA-directed RNA polymerase III subunit RPC1 Proteins 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 1
- 229920002556 Polyethylene Glycol 300 Polymers 0.000 description 1
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 206010039085 Rhinitis allergic Diseases 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 201000010105 allergic rhinitis Diseases 0.000 description 1
- 230000007953 anoxia Effects 0.000 description 1
- 201000008937 atopic dermatitis Diseases 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical compound CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 208000013220 shortness of breath Diseases 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P17/00—Pest repellants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/02—Acaricides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/236—Esters of carboxylic acids; Esters of carbonic acid containing halogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Insects & Arthropods (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an anti-mite agent composition for mattress cloth and application thereof, which solves the problem that the anti-mite effect of single permethrin is to be improved in the prior art, and comprises the following components in parts by weight: 2-10 parts of permethrin; 0 to 10 parts of ethyl butyl levulinate; (c) 2-20 parts of emulsifying agent; (d) 10-30 parts of polar organic solvent; (e) 0-10 parts of urea or thiourea; (f) The technical proposal of water for the anti-mite agent composition to 100 parts solves the technical problem well, and can be used in the production of the anti-mite agent composition for mattress cloth.
Description
Technical Field
The invention relates to an anti-mite agent composition for mattress cloth and application thereof.
Background
Mites are a serious hazard to human health, where dust mites present in the home environment are largely distributed in carpets, sofas, tapestry, curtains, cushions, back pads, throw pillows, quilts, bedsheets, coverlets, pillows, simmons (mattresses). The dust mites eat secretions of human bodies, fallen dander, fallen food residues and the like, so that the breeding speed is extremely high; secretions, excretions, hulls, cadavers, and the like of dust mites are allergens. These allergens enter the human lung and can cause dust mite asthma, manifested by chest distress, shortness of breath, dyspnea due to exhalation, cyanosis due to anoxia of lips and nails, and allergic rhinitis and allergic dermatitis.
The Simmons mattress has a large internal space, a multi-layer structure and a higher temperature and humidity in a family living environment, and is suitable for mass propagation of mites, in particular dust mites. Dust mites are most distributed on the mattress cloth of the outermost layer of the mattress. In addition, the mattress is large in size, and the mattress cannot be taken out for airing generally, so that if the anti-mite processing treatment is carried out on the mattress cloth, the number of dust mites in the whole living environment can be greatly reduced, and the possibility of dust mite asthma is reduced.
The permethrin is a common anti-mite agent for mattress cloth fabric, and how to improve the anti-mite effect of the agent is a subject of continuous attention in the field.
Disclosure of Invention
One of the technical problems to be solved by the invention is to solve the problem that the single-dose anti-mite effect of permethrin in the prior art is to be improved, and provide a novel anti-mite agent composition for mattress cloth, which has a better anti-mite effect.
In order to solve one of the technical problems, the technical scheme of the invention is as follows:
an anti-mite composition for mattress cloths, comprising, by weight:
(a) 2-10 parts of permethrin;
(b) 0-10 parts of ethyl butyl levulinate;
(c) 2-20 parts of emulsifying agent;
(d) 10-30 parts of polar organic solvent;
(e) Urea or thiourea, 0-10 parts;
(f) Water, such that the anti-mite composition is up to 100 parts.
By way of non-limiting example, permethrin is 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts, and the like.
Preferably, the ethyl butyllevulinate is more than 0 part and 10 parts or less, and the ethyl butyllevulinate and the permethrin have a mutual synergistic effect in terms of improving the anti-mite effect, namely, the ethyl butyllevulinate is a synergistic agent of the permethrin in terms of improving the anti-mite effect.
By way of non-limiting example, ethyl butyllevulinate is 0.5 part, 1 part, 1.5 part, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts, and the like. More preferably 1 to 9 parts.
By way of non-limiting example, the emulsifier is 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, and the like. More preferably 5 to 20 parts, most preferably 5 to 15 parts.
As non-limiting examples, the polar organic solvents are 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, and the like. More preferably 10 to 25 parts.
Preferably, the component (e) is more than 0 parts and 10 parts or less, and the component (e) has an enhancing effect on the fenpropathrin in terms of improving the anti-mite effect.
By way of non-limiting example, component (e) is 0.5 part, 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4.0 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts, and the like. More preferably 0.5 to 9 parts, most preferably 1 to 8 parts.
In the above technical solution, preferably, the emulsifier includes a nonionic surfactant.
In the above-described embodiments, the nonionic surfactant includes, for example, at least one selected from the group consisting of fatty alcohol polyoxyethylene ether, fatty acid polyoxyethylene ether, tween (i.e., polyoxyethylene sorbitan fatty acid ester), and hydrogenated castor oil ethylene oxide adduct.
In the above technical solution, the tween is, for example, at least one selected from the group consisting of tween-20, tween-40, tween-60 and tween-80.
Tween-80 was used for the emulsifier in examples and comparative examples only in the same manner.
In the above technical solution, preferably, the polar organic solvent is an alcoholic hydroxyl group-containing compound, abbreviated as solvent alcohol. The solvent alcohol is at least one selected from the group consisting of C1-C4 alcohols, glycol monoalkyl ethers, and glycols containing ether linkages.
In the above technical scheme, preferably, the C1-C4 alcohol is monohydric alcohol or dihydric alcohol. Such as, but not limited to, methanol, ethanol, ethylene glycol, n-propanol, isopropanol, 1, 2-propanediol, 1, 3-propanediol, n-butanol.
In the above technical scheme, preferably, the glycol monoalkyl ether corresponds to the following formula 1:
R 1 O(CH 2 CH 2 o) nH, formula 1;
wherein R is 1 Is C1-C4 alkyl, n is 1-3.
In the above technical scheme, preferably, the dihydric alcohol containing ether bond accords with the following formula 2:
m is the average degree of polymerization, number average molecular weight = ethylene oxide molecular weight m + molecular weight of water; wherein the number average molecular weight is 100 to 700. Such as, but not limited to, number average molecular weights of 100, 150, 200, 250, 300, 350, 400, 450, 500, 550, 600, 650, and the like.
By way of non-limiting example only of a specific ether linkage-containing glycol, the glycol series being the name of a commercially available variety, includes at least one selected from the group consisting of: diethylene glycol (or diethylene glycol), m is 2, and the number average molecular weight is 106; triethylene glycol (or triethylene glycol), m is 3, and the number average molecular weight is 150; and tetraethylene glycol (or tetraethylene glycol), m is 4, and the number average molecular weight is 194; etc.
Only as a non-limiting example of a commercial variety of PEG with "PEG (also called polyethylene glycol) +number average molecular weight" as a series name, a specific ether bond-containing diol includes at least one selected from the group consisting of: PEG-200, PEG-300, PEG-400, PEG-500, and PEG-600, and the like.
The polar organic solvents used in the examples and comparative examples of the present invention were PEG-400, by way of comparison only.
The technical key of the invention is the selection of the components of the composition, and when the composition formula is disclosed by the specification of the invention, the person skilled in the art can select and use the method commonly used in the art to obtain the anti-mite composition for mattress cloth according to the understanding of the person skilled in the art, and the obtained composition has comparable technical effects without the need of creative labor.
By way of example only, a second object of the present invention is to provide a method for preparing an anti-mite composition for mattress cloths, which is one of the above-mentioned objects.
In order to solve the second technical problem, the technical scheme of the invention is as follows:
the process for producing an anti-mite composition according to any one of the above technical problems, comprising:
(1) Dissolving the emulsifier into the polar organic solvent to obtain an emulsifier solution;
(2) Dispersing ethyl butyllevulinate in an emulsifier solution when the anti-mite composition contains ethyl butyllevulinate to obtain a solution A;
(3) Dispersing the solution A into water or dispersing the solution A into an aqueous solution of the component (e) when the anti-mite composition contains the component (e) to obtain emulsion B, wherein the emulsion B is less than or equal to 100 parts;
(4) When emulsion B is less than 100 parts, the required amount of water to the anti-mite composition is made up.
The third technical problem to be solved by the invention is the application of the anti-mite composition.
In order to solve the third technical problem, the technical scheme of the invention is as follows:
use of an anti-mite agent composition according to any one of the technical solutions of the above technical problems or an anti-mite agent composition obtained by the preparation method according to any one of the technical solutions of the second technical problems in anti-mite finishing of mattress cloths.
Moreover, the technical key of the invention is the selection of the components of the anti-mite agent composition, and the person skilled in the art can reasonably select the methods commonly used in the art to obtain comparable technical effects without the need of creative labor for how to apply the composition to the anti-mite finishing of mattress cloths.
By way of example only, the anti-mite finishing method of the mattress cloth fabric comprises the following steps:
(I) Contacting the to-be-anti-mite finishing bed mattress cloth with an anti-mite finishing working solution to obtain a fabric I with liquid;
(II) drying;
(III) heat setting;
wherein the anti-mite finishing working solution is a liquid material containing the following anti-mite agent composition:
an anti-mite composition according to any one of the above technical problems or an anti-mite composition obtained by the method according to any one of the above technical problems.
Those skilled in the art know that when the anti-mite composition is in a range with a relatively low concentration of an effective substance (the effective substance is the general term of the component (a), the component (b) and the component (e), and the whole term is the same), the anti-mite composition is convenient to use, for example, the anti-mite composition can be directly used as an anti-mite finishing working solution for anti-mite finishing of bedding cloth fabrics. When the anti-mite composition is in a range with higher effective matter concentration, the composition occupies relatively smaller space per unit effective matter content, so that the storage and transportation cost is reduced, and the person skilled in the art also knows that the anti-mite composition with high effective concentration can be used as an anti-mite finishing working solution only by simply diluting the composition with water to the required concentration.
In the above technical solution, the material of the to-be-anti-mite finishing mattress cloth fabric in the step (I) is not particularly limited, and may be cotton, acrylic, polyester, polypropylene or spandex.
In the technical scheme, the form of the bedding cloth fabric to be anti-mite finished can be textile, knitwear or non-woven fabric.
The raw material fabrics in the embodiment and the comparative example of the invention are all mattress cloth fabrics provided by the company of the division of the like furniture, which are just the same ratio, the double-sided circular knitting machine sandwich jacquard fabric is a composite fabric which is formed by combining a front side, a sandwich and a back side into a whole through joint, and has the following specific specification:
in the above technical solution, the manner of contacting in the step (I) is not particularly limited, and may be dip contact, spray contact, roll contact, or the like. Further, the impregnation may be a batch impregnation or a continuous impregnation. The specific mode of the anti-mite finishing mattress cloth to be contacted with the anti-mite finishing working solution can be reasonably selected by the person skilled in the art, comparable technical effects can be achieved, and creative labor is not required.
In the above technical scheme, the contact time is not particularly limited, as long as the contact between the fabric deodorant finishing working solution and the fabric reaches or is basically balanced, the contact time is prolonged without particularly influencing the technical effect, but the contact time is too long to cause the increase of the production time cost, and the contact time is too short to influence the load capacity of the photocatalyst, based on the principle of the contact time, the person skilled in the art can comprehensively consider the factors to reasonably select the dipping time, and can obtain the comparable technical effect without carrying out creative labor.
By way of example only, when step (I) is contacted by batch impregnation, such as, but not limited to, not less than 1 minute for a period of time of impregnation, further non-limiting examples of impregnation periods may be 2 minutes, 3 minutes, 4 minutes, 5 minutes, 6 minutes, 7 minutes, 8 minutes, 9 minutes, 10 minutes, 11 minutes, 15 minutes, 30 minutes, 40 minutes, 50 minutes, 60 minutes, and the like. The impregnation times were 10 minutes in both the examples and comparative examples, which are merely comparable.
Those skilled in the art will recognize that the impregnation process will involve the ratio of the amount of anti-mite finishing working liquid to the amount of mattress pad to be anti-mite finished, and that those skilled in the art can reasonably select this ratio to achieve comparable technical results without the need for creative effort. By way of non-limiting example only, when step (I) is performed by batch impregnation, the ratio of the amount of the anti-mite finishing working liquid to the amount of the anti-mite finishing mattress pad to be used is 10 or more by weight, for example, but not limited to, 12, 14, 16, 18, 20, 30, etc., and further, by the same ratio, the weight ratio is 15 in the examples of the present invention and the comparative examples.
The impregnation in the examples and comparative examples of the present invention was batch impregnation, by way of comparison only.
In the above technical solution, the solution carrying rate in the solution carrying fabric I in the step (I) is not particularly limited, and a person skilled in the art can reasonably control the solution carrying rate according to the concentration of the effective matters in the anti-mite finishing working solution, the ability of the fabric to adsorb the anti-mite finishing working solution, the amount of the effective matters loaded with the anti-mite agent in the anti-mite mattress cloth fabric to be obtained, whether the fabric is extruded or not after impregnation, and the extrusion degree. The specification of the invention adopts the meaning of the liquid carrying rate commonly used in the field, and the liquid carrying rate, namely the ratio of the mattress cloth fabric to the anti-mite finishing working liquid, is based on the weight and relative to the mattress cloth fabric to be anti-mite finished. By way of example only, the fluid carrying rate in the fluid carrying fabric I may be 50-100%, such as, but not limited to, 55%, 60%, 65%, 70%, 75%, 80%, 85%, 90%, 95% and the like. The liquid carrying rate was controlled to 80% in the same comparative example and comparative example.
In the above-mentioned embodiments, the temperature of the drying in the step (II) is preferably 80 to 110℃such as, but not limited to, 85℃90℃95℃100℃105 ℃. The drying temperatures in the examples and comparative examples of the present invention were 100℃for the same comparison only.
In the above technical solution, the drying time of the step (II) is preferably 3 to 10 minutes, for example, but not limited to, 3.5 minutes, 4 minutes, 4.5 minutes, 5 minutes, 5.5 minutes, 6 minutes, 6.5 minutes, 7 minutes, 7.5 minutes, 8 minutes, 8.5 minutes, 9 minutes, 9.5 minutes, and the like. The drying time was 5 minutes in the examples and comparative examples of the present invention, which were merely comparable.
In the above-mentioned embodiments, the heat-setting temperature in the step (III) is preferably 120 to 180℃such as, but not limited to, 125℃130℃135℃140℃145℃150℃155℃160℃165℃170℃175℃and the like. The heat setting temperatures in the examples and comparative examples of the present invention were 150℃by comparison only.
In the above embodiment, the heat setting time of the step (III) is preferably 1 to 5 minutes, for example, but not limited to, 1.5 minutes, 2 minutes, 2.5 minutes, 3 minutes, 3.5 minutes, 4 minutes, 4.5 minutes, and the like. The heat setting time was 3 minutes in the examples and comparative examples of the present invention, which were comparable only.
The mite-proof performance evaluation of the mite-proof agent composition for the bed cloth adopts a repelling method specified in section 9.1 of the standard GB/T24253-2009 evaluation of the mite-proof performance of textiles, the mite-proof finishing bed cloth fabric to be mite-proof finished without mite-proof treatment is used as a reference sample, the mite-proof finishing bed cloth fabric subjected to mite-proof treatment, namely the mite-proof bed cloth is used as a sample, and the reference sample and the sample are not subjected to washing treatment specified in section 8.3 of the standard. The greater the repellency of the test sample, the better the anti-mite effect.
The present invention will be described in detail with reference to examples and comparative examples.
Detailed Description
[ comparative example 1 ]
1. Anti-mite agent composition for mattress cloth
1.1 formulation of an anti-mite composition for mattress cloths
An anti-mite composition for mattress cloths, comprising, by weight:
(a) 8 parts of permethrin;
(c) Tween-80,8 parts;
(d) PEG-400, 16 parts;
(f) Water, such that the anti-mite composition is up to 100 parts.
1.2 preparation of an anti-mite composition for mattress cloths
Dissolving 8 parts of Tween-80 in 16 parts of PEG-400 to obtain an emulsifier solution;
adding 8 parts of permethrin into the emulsifier solution, and uniformly stirring to obtain a solution A;
adding the solution A into 61 parts of water under stirring to obtain emulsion B;
water was added to emulsion B with stirring until the total parts of the anti-mite composition for mattress cloths was 100 parts.
2. Preparation of anti-mite finishing working solution
Under stirring, adding 40 parts of the anti-mite agent composition into 960 parts of water, and uniformly stirring to obtain the anti-mite finishing working solution for the mattress cloth.
3. Anti-mite finishing method for bedding cloth fabric
Immersing the mattress cloth fabric to be subjected to mite-proof arrangement in the mite-proof arrangement working solution for mattress cloth in the section 2 for 10 minutes, wherein the weight ratio of the fabric to the mite-proof arrangement working solution for mattress cloth (also called bath ratio in the industry) is 1:15, then extruding to enable the liquid carrying rate to be 80%, then drying at 100 ℃ for 5 minutes by a shaping dryer, and shaping at 150 ℃ for 3 minutes to obtain the mite-proof mattress cloth.
Through tests, the anti-mite mattress cloth has a mite repellent rate of 76%.
[ comparative example 2 ]
1. Anti-mite agent composition for mattress cloth
1.1 formulation of an anti-mite composition for mattress cloths
An anti-mite composition for mattress cloths, comprising, by weight:
(b) 8 parts of ethyl butyl levulinate;
(c) Tween-80,8 parts;
(d) PEG-400, 16 parts;
(f) Water, such that the anti-mite composition is up to 100 parts.
1.2 preparation of an anti-mite composition for mattress cloths
Dissolving 8 parts of Tween-80 in 16 parts of PEG-400 to obtain an emulsifier solution;
adding 8 parts of ethyl butyl levulinate into the emulsifier solution, and uniformly stirring to obtain a solution A;
adding the solution A into 61 parts of water under stirring to obtain emulsion B;
water was added to emulsion B with stirring until the total parts of the anti-mite composition for mattress cloths was 100 parts.
2. Preparation of anti-mite finishing working solution
Under stirring, adding 40 parts of the anti-mite agent composition into 960 parts of water, and uniformly stirring to obtain the anti-mite finishing working solution for the mattress cloth.
3. Anti-mite finishing method for bedding cloth fabric
Immersing the mattress cloth fabric to be subjected to mite-proof arrangement in the mite-proof arrangement working solution for mattress cloth in the section 2 for 10 minutes, wherein the weight ratio of the fabric to the mite-proof arrangement working solution for mattress cloth (also called bath ratio in the industry) is 1:15, then extruding to enable the liquid carrying rate to be 80%, then drying at 100 ℃ for 5 minutes by a shaping dryer, and shaping at 150 ℃ for 3 minutes to obtain the mite-proof mattress cloth.
Through tests, the anti-mite mattress cloth has 65% of mite repellent rate.
[ comparative example 3 ]
1. Anti-mite agent composition for mattress cloth
1.1 formulation of an anti-mite composition for mattress cloths
An anti-mite composition for mattress cloths, comprising, by weight:
(c) Tween-80,8 parts;
(d) PEG-400, 16 parts;
(e) Thiourea, 8 parts;
(f) Water, such that the anti-mite composition is up to 100 parts.
1.2 preparation of an anti-mite composition for mattress cloths
Dissolving 8 parts of Tween-80 in 16 parts of PEG-400 to obtain an emulsifier solution;
dissolving 8 parts of thiourea in 61 parts of water to obtain a thiourea solution;
adding the emulsifier solution into the thiourea solution under stirring to obtain a mixed solution B;
water was added to the mixed solution B under stirring until the total parts of the anti-mite composition for mattress cloths was 100 parts.
2. Preparation of anti-mite finishing working solution
Under stirring, adding 40 parts of the anti-mite agent composition into 960 parts of water, and uniformly stirring to obtain the anti-mite finishing working solution for the mattress cloth.
3. Anti-mite finishing method for bedding cloth fabric
Immersing the mattress cloth fabric to be subjected to mite-proof arrangement in the mite-proof arrangement working solution for mattress cloth in the section 2 for 10 minutes, wherein the weight ratio of the fabric to the mite-proof arrangement working solution for mattress cloth (also called bath ratio in the industry) is 1:15, then extruding to enable the liquid carrying rate to be 80%, then drying at 100 ℃ for 5 minutes by a shaping dryer, and shaping at 150 ℃ for 3 minutes to obtain the mite-proof mattress cloth.
Through tests, the anti-mite mattress cloth has a mite repellent rate of 45%.
[ example 1 ]
1. An anti-mite composition for mattress cloths, comprising, by weight:
(a) 6 parts of permethrin;
(b) 2 parts of ethyl butyl levulinate;
(c) Tween-80,8 parts;
(d) PEG-400, 16 parts;
(f) Water, such that the anti-mite composition is up to 100 parts.
1.2 preparation of an anti-mite composition for mattress cloths
Dissolving 8 parts of Tween-80 in 16 parts of PEG-400 to obtain an emulsifier solution;
adding 6 parts of permethrin and 2 parts of ethyl butyl levulinate into the emulsifier solution, and uniformly stirring to obtain a solution A;
adding the solution A into 61 parts of water under stirring to obtain emulsion B;
water was added to emulsion B with stirring until the total parts of the anti-mite composition for mattress cloths was 100 parts.
2. Preparation of anti-mite finishing working solution
Under stirring, adding 40 parts of the anti-mite agent composition into 960 parts of water, and uniformly stirring to obtain the anti-mite finishing working solution for the mattress cloth.
3. Anti-mite finishing method for bedding cloth fabric
Immersing the mattress cloth fabric to be subjected to mite-proof arrangement in the mite-proof arrangement working solution for mattress cloth in the section 2 for 10 minutes, wherein the weight ratio of the fabric to the mite-proof arrangement working solution for mattress cloth (also called bath ratio in the industry) is 1:15, then extruding to enable the liquid carrying rate to be 80%, then drying at 100 ℃ for 5 minutes by a shaping dryer, and shaping at 150 ℃ for 3 minutes to obtain the mite-proof mattress cloth.
Through tests, the anti-mite mattress cloth has 91% of mite repellent rate.
[ example 2 ]
1. An anti-mite composition for mattress cloths, comprising, by weight:
(a) 6 parts of permethrin;
(c) Tween-80,8 parts;
(d) PEG-400, 16 parts;
(e) Thiourea, 2 parts of the total of the components,
(f) Water, such that the anti-mite composition is up to 100 parts.
1.2 preparation of an anti-mite composition for mattress cloths
Dissolving 8 parts of Tween-80 in 16 parts of PEG-400 to obtain an emulsifier solution;
adding 6 parts of permethrin into the emulsifier solution, and uniformly stirring to obtain a solution A;
dissolving 2 parts of thiourea in 61 parts of water to obtain a thiourea solution;
adding the solution A into thiourea solution under stirring to obtain emulsion B;
water was added to emulsion B with stirring until the total parts of the anti-mite composition for mattress cloths was 100 parts.
2. Preparation of anti-mite finishing working solution
Under stirring, adding 40 parts of the anti-mite agent composition into 960 parts of water, and uniformly stirring to obtain the anti-mite finishing working solution for the mattress cloth.
3. Anti-mite finishing method for bedding cloth fabric
Immersing the mattress cloth fabric to be subjected to mite-proof arrangement in the mite-proof arrangement working solution for mattress cloth in the section 2 for 10 minutes, wherein the weight ratio of the fabric to the mite-proof arrangement working solution for mattress cloth (also called bath ratio in the industry) is 1:15, then extruding to enable the liquid carrying rate to be 80%, then drying at 100 ℃ for 5 minutes by a shaping dryer, and shaping at 150 ℃ for 3 minutes to obtain the mite-proof mattress cloth.
Through tests, the anti-mite mattress cloth has a mite repellent rate of 85%.
[ example 3 ]
1. An anti-mite composition for mattress cloths, comprising, by weight:
(b) 2 parts of ethyl butyl levulinate;
(c) Tween-80,8 parts;
(d) PEG-400, 16 parts;
(e) Thiourea, 6 parts of the total amount of the components,
(f) Water, such that the anti-mite composition is up to 100 parts.
1.2 preparation of an anti-mite composition for mattress cloths
Dissolving 8 parts of Tween-80 in 16 parts of PEG-400 to obtain an emulsifier solution;
adding 2 parts of ethyl butyl levulinate into the emulsifier solution, and uniformly stirring to obtain a solution A;
dissolving 6 parts of thiourea in 61 parts of water to obtain a thiourea solution;
adding the solution A into thiourea solution under stirring to obtain emulsion B;
water was added to emulsion B with stirring until the total parts of the anti-mite composition for mattress cloths was 100 parts.
2. Preparation of anti-mite finishing working solution
Under stirring, adding 40 parts of the anti-mite agent composition into 960 parts of water, and uniformly stirring to obtain the anti-mite finishing working solution for the mattress cloth.
3. Anti-mite finishing method for bedding cloth fabric
Immersing the mattress cloth fabric to be subjected to mite-proof arrangement in the mite-proof arrangement working solution for mattress cloth in the section 2 for 10 minutes, wherein the weight ratio of the fabric to the mite-proof arrangement working solution for mattress cloth (also called bath ratio in the industry) is 1:15, then extruding to enable the liquid carrying rate to be 80%, then drying at 100 ℃ for 5 minutes by a shaping dryer, and shaping at 150 ℃ for 3 minutes to obtain the mite-proof mattress cloth.
Through tests, the anti-mite mattress cloth has 55% of mite repellent rate.
[ example 4 ]
1. An anti-mite composition for mattress cloths, comprising, by weight:
(b) 6 parts of ethyl butyl levulinate;
(c) Tween-80,8 parts;
(d) PEG-400, 16 parts;
(e) Thiourea, 2 parts of the total of the components,
(f) Water, such that the anti-mite composition is up to 100 parts.
1.2 preparation of an anti-mite composition for mattress cloths
Dissolving 8 parts of Tween-80 in 16 parts of PEG-400 to obtain an emulsifier solution;
adding 6 parts of ethyl butyl levulinate into the emulsifier solution, and uniformly stirring to obtain a solution A;
dissolving 2 parts of thiourea in 61 parts of water to obtain a thiourea solution;
adding the solution A into thiourea solution under stirring to obtain emulsion B;
water was added to emulsion B with stirring until the total parts of the anti-mite composition for mattress cloths was 100 parts.
2. Preparation of anti-mite finishing working solution
Under stirring, adding 40 parts of the anti-mite agent composition into 960 parts of water, and uniformly stirring to obtain the anti-mite finishing working solution for the mattress cloth.
3. Anti-mite finishing method for bedding cloth fabric
Immersing the mattress cloth fabric to be subjected to mite-proof arrangement in the mite-proof arrangement working solution for mattress cloth in the section 2 for 10 minutes, wherein the weight ratio of the fabric to the mite-proof arrangement working solution for mattress cloth (also called bath ratio in the industry) is 1:15, then extruding to enable the liquid carrying rate to be 80%, then drying at 100 ℃ for 5 minutes by a shaping dryer, and shaping at 150 ℃ for 3 minutes to obtain the mite-proof mattress cloth.
Through tests, the anti-mite mattress cloth has a mite repellent rate of 70%.
[ example 5 ]
1. Anti-mite agent composition for mattress cloth
1.1 formulation of an anti-mite composition for mattress cloths
An anti-mite composition for mattress cloths, comprising, by weight:
(a) 4 parts of permethrin;
(b) 2 parts of ethyl butyl levulinate;
(c) Tween-80,8 parts;
(d) PEG-400, 16 parts;
(e) Thiourea, 2 parts of the total of the components,
(f) Water, such that the anti-mite composition is up to 100 parts.
1.2 preparation of an anti-mite composition for mattress cloths
Dissolving 8 parts of Tween-80 in 16 parts of PEG-400 to obtain an emulsifier solution;
adding 4 parts of permethrin and 2 parts of ethyl butyl levulinate into the emulsifier solution, and uniformly stirring to obtain a solution A;
dissolving 2 parts of thiourea in 61 parts of water to obtain a thiourea solution;
adding the solution A into thiourea solution under stirring to obtain emulsion B;
water was added to emulsion B with stirring until the total parts of the anti-mite composition for mattress cloths was 100 parts.
2. Preparation of anti-mite finishing working solution
Under stirring, adding 40 parts of the anti-mite agent composition into 960 parts of water, and uniformly stirring to obtain the anti-mite finishing working solution for the mattress cloth.
3. Anti-mite finishing method for bedding cloth fabric
Immersing the mattress cloth fabric to be subjected to mite-proof arrangement in the mite-proof arrangement working solution for mattress cloth in the section 2 for 10 minutes, wherein the weight ratio of the fabric to the mite-proof arrangement working solution for mattress cloth (also called bath ratio in the industry) is 1:15, then extruding to enable the liquid carrying rate to be 80%, then drying at 100 ℃ for 5 minutes by a shaping dryer, and shaping at 150 ℃ for 3 minutes to obtain the mite-proof mattress cloth.
Through tests, the anti-mite mattress cloth has a mite repellent rate of 93 percent.
[ example 6 ]
1. An anti-mite composition for mattress cloths, comprising, by weight:
(a) 8 parts of permethrin;
(b) 2 parts of ethyl butyl levulinate;
(c) Tween-80,8 parts;
(d) PEG-400, 16 parts;
(e) Thiourea, 4 parts of the total amount of the components,
(f) Water, such that the anti-mite composition is up to 100 parts.
1.2 preparation of an anti-mite composition for mattress cloths
Dissolving 8 parts of Tween-80 in 16 parts of PEG-400 to obtain an emulsifier solution;
adding 8 parts of permethrin and 2 parts of ethyl butyl levulinate into the emulsifier solution, and uniformly stirring to obtain a solution A;
dissolving 4 parts of thiourea in 61 parts of water to obtain a thiourea solution;
adding the solution A into thiourea solution under stirring to obtain emulsion B;
water was added to emulsion B with stirring until the total parts of the anti-mite composition for mattress cloths was 100 parts.
2. Preparation of anti-mite finishing working solution
Under stirring, adding 40 parts of the anti-mite agent composition into 960 parts of water, and uniformly stirring to obtain the anti-mite finishing working solution for the mattress cloth.
3. Anti-mite finishing method for bedding cloth fabric
Immersing the mattress cloth fabric to be subjected to mite-proof arrangement in the mite-proof arrangement working solution for mattress cloth in the section 2 for 10 minutes, wherein the weight ratio of the fabric to the mite-proof arrangement working solution for mattress cloth (also called bath ratio in the industry) is 1:15, then extruding to enable the liquid carrying rate to be 80%, then drying at 100 ℃ for 5 minutes by a shaping dryer, and shaping at 150 ℃ for 3 minutes to obtain the mite-proof mattress cloth.
Through tests, the anti-mite mattress cloth has the repellent rate of more than 99 percent to mites.
[ example 7 ]
1. An anti-mite composition for mattress cloths, comprising, by weight:
(a) 6 parts of permethrin;
(b) 4 parts of ethyl butyl levulinate;
(c) Tween-80,8 parts;
(d) PEG-400, 16 parts;
(e) Thiourea, 2 parts of the total of the components,
(f) Water, such that the anti-mite composition is up to 100 parts.
1.2 preparation of an anti-mite composition for mattress cloths
Dissolving 8 parts of Tween-80 in 16 parts of PEG-400 to obtain an emulsifier solution;
adding 6 parts of permethrin and 4 parts of ethyl butyl levulinate into the emulsifier solution, and uniformly stirring to obtain a solution A;
dissolving 2 parts of thiourea in 61 parts of water to obtain a thiourea solution;
adding the solution A into thiourea solution under stirring to obtain emulsion B;
water was added to emulsion B with stirring until the total parts of the anti-mite composition for mattress cloths was 100 parts.
2. Preparation of anti-mite finishing working solution
Under stirring, adding 40 parts of the anti-mite agent composition into 960 parts of water, and uniformly stirring to obtain the anti-mite finishing working solution for the mattress cloth.
3. Anti-mite finishing method for bedding cloth fabric
Immersing the mattress cloth fabric to be subjected to mite-proof arrangement in the mite-proof arrangement working solution for mattress cloth in the section 2 for 10 minutes, wherein the weight ratio of the fabric to the mite-proof arrangement working solution for mattress cloth (also called bath ratio in the industry) is 1:15, then extruding to enable the liquid carrying rate to be 80%, then drying at 100 ℃ for 5 minutes by a shaping dryer, and shaping at 150 ℃ for 3 minutes to obtain the mite-proof mattress cloth.
Through tests, the anti-mite mattress cloth has the repellent rate of more than 99 percent to mites.
It should be noted that the above-described embodiments are only for explaining the present invention and do not constitute any limitation of the present invention. The invention has been described with reference to exemplary embodiments, but it is understood that the words which have been used are words of description and illustration, rather than words of limitation. Modifications may be made to the invention as defined in the appended claims, and the invention may be modified without departing from the scope and spirit of the invention. Although the invention is described herein with reference to particular means, materials and embodiments, the invention is not intended to be limited to the particulars disclosed herein, as the invention extends to all other means and applications which perform the same function.
Claims (10)
1. An anti-mite composition for mattress cloths, comprising, by weight:
(a) 2-10 parts of permethrin;
(b) 0-10 parts of ethyl butyl levulinate;
(c) 2-20 parts of emulsifying agent;
(d) 10-30 parts of polar organic solvent;
(e) Urea or thiourea, 0-10 parts;
(f) Water, such that the anti-mite composition is up to 100 parts.
2. An anti-mite agent composition according to claim 1, wherein the parts of ethyl butyllevulinate is more than 0 parts and 10 parts or less, and/or the parts of component (e) is more than 0 parts and 10 parts or less.
3. The anti-mite composition of claim 1, wherein the emulsifier comprises a nonionic surfactant.
4. The nonionic surfactant includes, for example, at least one selected from the group consisting of fatty alcohol polyoxyethylene ether, fatty acid polyoxyethylene ether, tween, and hydrogenated castor oil ethylene oxide adduct. The tween is, for example, at least one selected from the group consisting of tween-20, tween-40, tween-60 and tween-80.
5. The anti-mite composition according to claim 1, wherein the polar organic solvent is an alcoholic hydroxyl group-containing compound, abbreviated as solvent alcohol. The solvent alcohol is at least one selected from the group consisting of C1-C4 alcohols, glycol monoalkyl ethers, and glycols containing ether linkages.
6. An anti-mite composition according to claim 5, wherein the C1-C4 alcohol is a monohydric alcohol or a dihydric alcohol. Such as, but not limited to, methanol, ethanol, ethylene glycol, n-propanol, isopropanol, 1, 2-propanediol, 1, 3-propanediol, n-butanol.
7. The anti-mite agent composition according to claim 5, wherein the glycol monoalkyl ether satisfies the following formula 1:
R 1 O(CH 2 CH 2 o) n H, formula 1;
wherein R is 1 Is C1-C4 alkyl, n is 1-3.
8. The anti-mite agent composition according to claim 5, wherein the ether bond-containing diol corresponds to the following formula 2:
m is the average degree of polymerization, number average molecular weight = ethylene oxide molecular weight m + molecular weight of water; wherein the number average molecular weight is 100 to 700.
9. A process for preparing an anti-mite composition according to any one of claims 1 to 8, comprising:
(1) Dissolving the emulsifier into the polar organic solvent to obtain an emulsifier solution;
(2) Dispersing ethyl butyllevulinate in an emulsifier solution when the anti-mite composition contains ethyl butyllevulinate to obtain a solution A;
(3) Dispersing the solution A into water or dispersing the solution A into an aqueous solution of the component (e) when the anti-mite composition contains the component (e) to obtain emulsion B, wherein the emulsion B is less than or equal to 100 parts;
(4) When emulsion B is less than 100 parts, the required amount of water to the anti-mite composition is made up.
10. Use of an anti-mite agent composition according to any one of claims 1 to 8 or obtained according to the preparation method of claim 9 in an anti-mite finishing of bedding pieces.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310060322.4A CN116138266B (en) | 2023-01-17 | 2023-01-17 | Anti-mite agent composition for mattress cloth and application thereof |
| CN202311413183.5A CN117481136A (en) | 2023-01-17 | 2023-01-17 | Anti-mite agent composition for mattress cloth and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310060322.4A CN116138266B (en) | 2023-01-17 | 2023-01-17 | Anti-mite agent composition for mattress cloth and application thereof |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202311413183.5A Division CN117481136A (en) | 2023-01-17 | 2023-01-17 | Anti-mite agent composition for mattress cloth and application thereof |
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| Publication Number | Publication Date |
|---|---|
| CN116138266A true CN116138266A (en) | 2023-05-23 |
| CN116138266B CN116138266B (en) | 2024-03-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202311413183.5A Pending CN117481136A (en) | 2023-01-17 | 2023-01-17 | Anti-mite agent composition for mattress cloth and application thereof |
| CN202310060322.4A Active CN116138266B (en) | 2023-01-17 | 2023-01-17 | Anti-mite agent composition for mattress cloth and application thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101550636A (en) * | 2009-05-05 | 2009-10-07 | 山东俊富无纺布有限公司 | Method for processing non-weaving cloth with anti-acarid function by applying spun-bonded process |
| CN106808542A (en) * | 2017-01-13 | 2017-06-09 | 李水金 | A kind of timber preservative and preparation method thereof |
| CN107140878A (en) * | 2017-07-12 | 2017-09-08 | 合肥信亚达智能科技有限公司 | Building materials prepared by a kind of utilization lake mud and preparation method thereof |
| CN107761374A (en) * | 2016-08-16 | 2018-03-06 | 牛绍英 | A kind of antibacterial, the fabric/fiber dressing liquid of insecticidal medium and its application method and textile article/fibre/paper products |
| CN107780210A (en) * | 2016-08-24 | 2018-03-09 | 张裕 | A kind of mould proof, mosquito fiber/fabric/paper dressing liquid and its application method and product |
| CN113854320A (en) * | 2021-10-18 | 2021-12-31 | 阜南县猛发工艺品有限公司 | Insect-proof mildew-proof agent for bamboo rattan woven product and preparation method thereof |
-
2023
- 2023-01-17 CN CN202311413183.5A patent/CN117481136A/en active Pending
- 2023-01-17 CN CN202310060322.4A patent/CN116138266B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101550636A (en) * | 2009-05-05 | 2009-10-07 | 山东俊富无纺布有限公司 | Method for processing non-weaving cloth with anti-acarid function by applying spun-bonded process |
| CN107761374A (en) * | 2016-08-16 | 2018-03-06 | 牛绍英 | A kind of antibacterial, the fabric/fiber dressing liquid of insecticidal medium and its application method and textile article/fibre/paper products |
| CN107780210A (en) * | 2016-08-24 | 2018-03-09 | 张裕 | A kind of mould proof, mosquito fiber/fabric/paper dressing liquid and its application method and product |
| CN106808542A (en) * | 2017-01-13 | 2017-06-09 | 李水金 | A kind of timber preservative and preparation method thereof |
| CN107140878A (en) * | 2017-07-12 | 2017-09-08 | 合肥信亚达智能科技有限公司 | Building materials prepared by a kind of utilization lake mud and preparation method thereof |
| CN113854320A (en) * | 2021-10-18 | 2021-12-31 | 阜南县猛发工艺品有限公司 | Insect-proof mildew-proof agent for bamboo rattan woven product and preparation method thereof |
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| Publication number | Publication date |
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| CN116138266B (en) | 2024-03-01 |
| CN117481136A (en) | 2024-02-02 |
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