CN116075289A - 水包油型乳化组合物 - Google Patents
水包油型乳化组合物 Download PDFInfo
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- CN116075289A CN116075289A CN202180055896.1A CN202180055896A CN116075289A CN 116075289 A CN116075289 A CN 116075289A CN 202180055896 A CN202180055896 A CN 202180055896A CN 116075289 A CN116075289 A CN 116075289A
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- Prior art keywords
- oil
- polydimethylsiloxane
- water emulsion
- emulsion composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 76
- 239000007764 o/w emulsion Substances 0.000 title claims abstract description 28
- -1 polysiloxane Polymers 0.000 claims abstract description 99
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 72
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 72
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 49
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 27
- ISDGWTZFJKFKMO-UHFFFAOYSA-N 2-phenyl-1,3-dioxane-4,6-dione Chemical compound O1C(=O)CC(=O)OC1C1=CC=CC=C1 ISDGWTZFJKFKMO-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract 3
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 9
- KXTAOXNYQGASTA-UHFFFAOYSA-N 2-benzylidenepropanedioic acid Chemical compound OC(=O)C(C(O)=O)=CC1=CC=CC=C1 KXTAOXNYQGASTA-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 238000002835 absorbance Methods 0.000 abstract description 23
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 68
- 229920006037 cross link polymer Polymers 0.000 description 37
- 239000011243 crosslinked material Substances 0.000 description 20
- 239000003921 oil Substances 0.000 description 20
- 235000019198 oils Nutrition 0.000 description 20
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 19
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- 239000007788 liquid Substances 0.000 description 15
- 125000000217 alkyl group Chemical group 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
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- 238000002156 mixing Methods 0.000 description 9
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 9
- 229920002554 vinyl polymer Polymers 0.000 description 9
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 7
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- 239000000843 powder Substances 0.000 description 6
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- 206010042674 Swelling Diseases 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
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- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 4
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 4
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 4
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- JGUMTYWKIBJSTN-UHFFFAOYSA-N 2-ethylhexyl 4-[[4,6-bis[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 JGUMTYWKIBJSTN-UHFFFAOYSA-N 0.000 description 3
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical class NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
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- 239000002480 mineral oil Substances 0.000 description 3
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- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
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- 230000000475 sunscreen effect Effects 0.000 description 3
- 239000000516 sunscreening agent Substances 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical class C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- MEZZCSHVIGVWFI-UHFFFAOYSA-N 2,2'-Dihydroxy-4-methoxybenzophenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MEZZCSHVIGVWFI-UHFFFAOYSA-N 0.000 description 2
- RKJGFHYCZPZJPE-UHFFFAOYSA-N 2,2-bis(16-methylheptadecanoyloxymethyl)butyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C RKJGFHYCZPZJPE-UHFFFAOYSA-N 0.000 description 2
- FUTGDWNFCMWSJT-UHFFFAOYSA-N 2,3-bis(14-methylpentadecanoyloxy)propyl 14-methylpentadecanoate Chemical compound CC(C)CCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCC(C)C FUTGDWNFCMWSJT-UHFFFAOYSA-N 0.000 description 2
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 description 2
- CNXZMGRWEYQCOQ-UHFFFAOYSA-N 2-methoxy-3-phenylprop-2-enoic acid Chemical class COC(C(O)=O)=CC1=CC=CC=C1 CNXZMGRWEYQCOQ-UHFFFAOYSA-N 0.000 description 2
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 2
- WYWZRNAHINYAEF-UHFFFAOYSA-N Padimate O Chemical compound CCCCC(CC)COC(=O)C1=CC=C(N(C)C)C=C1 WYWZRNAHINYAEF-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 2
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- XVAMCHGMPYWHNL-UHFFFAOYSA-N bemotrizinol Chemical compound OC1=CC(OCC(CC)CCCC)=CC=C1C1=NC(C=2C=CC(OC)=CC=2)=NC(C=2C(=CC(OCC(CC)CCCC)=CC=2)O)=N1 XVAMCHGMPYWHNL-UHFFFAOYSA-N 0.000 description 2
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- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
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- BIHCCQRFXYRMHE-UHFFFAOYSA-N heptan-2-yl undecanoate Chemical compound CCCCCCCCCCC(=O)OC(C)CCCCC BIHCCQRFXYRMHE-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- Animal Behavior & Ethology (AREA)
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- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
[课题]一种水包油型乳化组合物，其即使配合有机硅弹性体，也能够提高吸光度。[解决手段]一种水包油型乳化组合物，其包含：(A)亚苄基丙二酸盐聚硅氧烷、(B)有机硅弹性体、和(C)聚二甲基硅氧烷主链具有碳数4以上的烃基的HLB8以下的表面活性剂。
Description
技术领域
本发明涉及水包油型乳化组合物。
背景技术
由于水包油型乳化组合物在涂布于肌肤时能够得到清爽且湿润的触感，因此作为直接适用于肌肤的皮肤化妆品等皮肤外用剂的基剂被广泛使用。特别是，水包油型乳化组合物中，由于具有涂布后的肌肤的粘腻感、干涩感的减轻、使皮肤柔软化的效果，因此，配合有有机硅弹性体(例如专利文献1、2)。
另外，亚苄基丙二酸盐聚硅氧烷是UV-B区域(ultraviolet-B：280～320nm)的紫外线吸收剂的一种，但与其他紫外线吸收剂相比，紫外线防御能力力低，在使其配合量增多而以高SPF(防晒系数(sun protection factor))制品为目标的情况下，具有高配合引起的干涩感、油腻感之类的问题。鉴于这样的问题，专利文献3中记载了在组合亚苄基丙二酸盐聚硅氧烷与2,2’-亚甲基双[6-(2H-苯并三唑-2-基)-4-(1,1,3,3-四甲基丁基)苯酚]并配合而成的防晒化妆品中，通过配合特定结构的两末端有机硅改性甘油，即使在制造具有高SPF的制品的情况下，也能够得到优异的使用感。
现有技术文献
专利文献
专利文献1：国际公开第2013/047196号
专利文献2：日本专利第5588164号
专利文献3：日本专利第5469319号
发明内容
发明要解决的问题
一般而言，已知配合有机硅弹性体时吸光度会降低。目前，在有机硅弹性体的分散中使用特定的表面活性剂时，吸光度飞跃性地提高，进而试着在该分散体中配合亚苄基丙二酸盐聚硅氧烷时，发现吸光度协同地提高，至此完成了本发明。
即，本发明是基于上述见解而完成的，其目的在于，提供即使配合有机硅弹性体，也能够提高吸光度的水包油型乳化组合物。
用于解决问题的方案
本发明的水包油型乳化组合物包含：
(A)亚苄基丙二酸盐聚硅氧烷、
(B)有机硅弹性体、和
(C)聚二甲基硅氧烷主链具有碳数4以上的烃基的HLB8以下的表面活性剂。
本发明的水包油型乳化组合物优选相对于组合物总量包含除(A)亚苄基丙二酸盐聚硅氧烷以外的(D)油溶性紫外线吸收剂8质量％以上。
优选(B)有机硅弹性体相对于(C)聚二甲基硅氧烷主链具有碳数4以上的烃基的HLB8以下的表面活性剂的质量比为0.5～10。
优选(B)有机硅弹性体相对于(A)亚苄基丙二酸盐聚硅氧烷的质量比为0.1～2。
发明的效果
本发明的水包油型乳化组合物包含：
(A)亚苄基丙二酸盐聚硅氧烷、
(B)有机硅弹性体、和
(C)聚二甲基硅氧烷主链具有碳数4以上的烃基的HLB8以下的表面活性剂，因此，即使配合有机硅弹性体，也能够提高吸光度。
具体实施方式
以下，详细说明本发明。
本发明的水包油型乳化组合物包含：
(A)亚苄基丙二酸盐聚硅氧烷、
(B)有机硅弹性体、和
(C)聚二甲基硅氧烷主链具有碳数4以上的烃基的HLB8以下的表面活性剂。
以下，对各成分进行详细说明。
需要说明的是，以下的POE为聚氧乙烯、PEG为聚乙二醇、PPG为聚丙二醇的简称。
(A)亚苄基丙二酸盐聚硅氧烷
本发明的水包油型乳化组合物中包含的亚苄基丙二酸盐聚硅氧烷是常温下为液态的有机硅改性化合物，也称为聚硅氧烷-15。(A)亚苄基丙二酸盐聚硅氧烷是公知的紫外线吸收剂，可以使用市售品，例如可列举出“PARSOL SLX”(DSM Nutritional Products)。通过(A)亚苄基丙二酸盐聚硅氧烷的配合，进一步协同地提高吸光度的作用机理未必明确，但认为通过(A)亚苄基丙二酸盐聚硅氧烷进入到后述(B)有机硅弹性体所构成的分子的孔中，可以抑制(B)有机硅弹性体引起的吸光度的降低。
(A)亚苄基丙二酸盐聚硅氧烷的配合量相对于组合物总量优选0.1～10质量％，更优选0.3～8质量％，进一步优选0.5～5质量％。通过相对于组合物总量为0.1质量％以上，从而能够进一步提高吸光度，通过为10质量％以下，从而可以确保更良好的使用性。
(B)有机硅弹性体
本发明的水包油型乳化组合物中包含的有机硅弹性体(交联型有机硅)没有特别限定，但可优选使用选自由聚二甲基硅氧烷交联聚合物、聚二甲基硅氧烷/乙烯基聚二甲基硅氧烷交联聚合物(聚硅氧烷11)、聚二甲基硅氧烷/苯基乙烯基聚二甲硅氧烷交联聚合物、乙烯基聚二甲基硅氧烷/月桂基聚二甲基硅氧烷交联聚合物、月桂基聚二甲基硅氧乙基聚二甲基硅氧烷/双-乙烯基聚二甲基硅氧烷交联聚合物、C30-45烷基鲸蜡硬脂基聚二甲基硅氧烷交联聚合物、鲸蜡硬脂基聚二甲基硅氧烷交联聚合物组成的组中的1种或2种以上。
在制备本发明的水包油型乳化组合物时，优选将有机硅弹性体以在常温下用液态油分溶胀的溶胀物的形态配合。由此，交联型有机硅的分散性和稳定性进一步提高。
作为溶胀中使用的液态油分，例如可列举出液态硅油、液态烃油、液态酯油、液态高级脂肪酸等，特别优选常温(25℃)下为低粘度、例如100mPa·s以下的液态油分。优选的粘度范围为1～100mPa·s。
作为优选配合形态的有机硅弹性体的液态油溶胀物中，交联型有机硅与液态油的混合的比率以质量比计优选为5：95～40：60。通过液态油溶胀物处于该质量比的范围内，从而更适合水包油型乳化组合物的制备。
有机硅弹性体的液态油溶胀物也可以使用市售品，作为市售品的例子，可列举出以下制品。
作为聚二甲基硅氧烷交联聚合物的溶胀物，可列举出9040Silicone ElastomerBlend(聚二甲基硅氧烷交联聚合物、十甲基环五硅氧烷的混合物中交联物为12％)、9041Silicone Elastomer Blend(聚二甲基硅氧烷交联聚合物、聚二甲基硅氧烷5mPa·s的混合物中交联物为16％)、9045Silicone Elastomer Blend(聚二甲基硅氧烷交联聚合物、十甲基环五硅氧烷的混合物中交联物为12.5％)、EL-8040ID Silicone Organic Blend(聚二甲基硅氧烷交联聚合物、异十二烷的混合物中交联物为16％)(以上，Dow Corning TorayCo.,Ltd.制)等。
作为聚二甲基硅氧烷/乙烯基聚二甲基硅氧烷交联聚合物的溶胀物，可列举出KSG-15(聚二甲基硅氧烷/乙烯基聚二甲基硅氧烷交联聚合物、环五聚二甲基硅氧烷的混合物中交联物为4～10％)、KSG-16(聚二甲基硅氧烷/乙烯基聚二甲基硅氧烷交联聚合物、聚二甲基硅氧烷6mPa·s的混合物中交联物为20～30％)、KSG-1610(聚二甲基硅氧烷/乙烯基聚二甲基硅氧烷交联聚合物、甲基聚三甲基硅氧烷的混合物中交联物为15～20％)(以上，信越化学工业株式会社制)、GRANSIL GCM(聚硅氧烷-11和八甲基环四硅氧烷的混合物中交联物为约6％)、GRANSIL GCM-5(聚硅氧烷-11和十甲基环五硅氧烷的混合物中交联物为约6％)、GRANSIL IDS(聚硅氧烷-11和异癸烷的混合物中交联物为约7％)、GRANSIL DMG-3(聚硅氧烷11和聚二甲基硅氧烷3mPa·s的混合物中交联物为约12％)、GRANSIL DMG-6(聚硅氧烷-11和聚二甲基硅氧烷6mPa·s的混合物中交联物为约18％)、GRANSIL DMG-20(聚硅氧烷-11和聚二甲基硅氧烷20mPa·s的混合物中交联物为约25％)、GRANSIL DMG-50(聚硅氧烷-11和聚二甲基硅氧烷50mPa·s的混合物中交联物为约26％)、GRANSIL PM(聚硅氧烷-11和苯基聚三甲基硅氧烷的混合物中交联物为约20％)、GRANSIL ININ(聚硅氧烷-11和异壬酸异壬酯的混合物中交联物为约15％)(以上，GRANT公司制)等。
作为聚二甲基硅氧烷/苯基乙烯基聚二甲硅氧烷交联聚合物的溶胀物，可列举出KSG-18A(聚二甲基硅氧烷/苯基乙烯基聚二甲硅氧烷交联聚合物、二苯基甲硅烷氧基苯基聚三甲基硅氧烷的混合物中交联物为10～20％)(信越化学工业株式会社制)等。
作为乙烯基聚二甲基硅氧烷/月桂基聚二甲基硅氧烷交联聚合物的溶胀物，可列举出KSG-41(乙烯基聚二甲基硅氧烷/月桂基聚二甲基硅氧烷交联聚合物、矿物油的混合物中交联物为25～30％)、KSG-42(乙烯基聚二甲基硅氧烷/月桂基聚二甲基硅氧烷交联聚合物、异十二烷的混合物中交联物为20～30％)、KSG-43(乙烯基聚二甲基硅氧烷/月桂基聚二甲基硅氧烷交联聚合物、甘油三(乙基己酸)酯的混合物中交联物为25～35％)、KSG-44(乙烯基聚二甲基硅氧烷/月桂基聚二甲基硅氧烷交联聚合物、角鲨烷的混合物中交联物为25～35％)(以上，信越化学工业株式会社制)等。
作为C30-45烷基鲸蜡硬脂基聚二甲基硅氧烷交联聚合物的溶胀物，可列举出VELVESIL 125(C30-45烷基鲸蜡硬脂基聚二甲基硅氧烷交联聚合物、环五聚二甲基硅氧烷的混合物中交联物为约12.5％)、VELVESIL Plus(C30-45烷基鲸蜡硬脂基聚二甲基硅氧烷交联聚合物、环五聚二甲基硅氧烷、PEG/PPG-20/23聚二甲基硅氧烷5mPa·s的混合物中交联物为约20％)(以上，Momentive Performance Materials公司制)等。
作为鲸蜡硬脂基聚二甲基硅氧烷交联聚合物的溶胀物，可列举出VELVESIL DM(鲸蜡硬脂基聚二甲基硅氧烷交联聚合物、聚二甲基硅氧烷5mPa·s的混合物中交联物为约17％)(Momentive Performance Materials公司制)等。作为部分交联型聚醚改性有机硅和二甲基硅油的混合物，可列举出KSG-210(固体成分20～30％)，作为含氟烷基环状有机聚硅氧烷等环状含氟有机硅的混合物，可列举出KSG-51(固体成分15～25％)，作为部分交联型聚甘油改性有机硅和二甲基硅油的混合物，可列举出KSG-710(固体成分20～25％)(以上，信越化学工业株式会社制)等。
作为含烷基交联型聚醚改性有机硅，可列举出：矿物油·PEG-15/月桂基聚二甲基硅氧烷交联聚合物(“KSG-310”；信越化学工业株式会社制)、异十二烷·PEG-15/月桂基聚二甲基硅氧烷交联聚合物(“KSG-320″；信越化学工业株式会社制)、甘油三(乙基己酸)酯·PEG-15/月桂基聚二甲基硅氧烷交联聚合物(“KSG-330”；信越化学工业株式会社制)、角鲨烷·PEG-15/月桂基聚二甲基硅氧烷交联聚合物·PEG-10/月桂基聚二甲基硅氧烷交联聚合物(“KSG-340”；信越化学工业株式会社制)、聚二甲基硅氧烷·PEG-15/月桂基聚二甲基硅氧乙基聚二甲基硅氧烷(“KSG360Z”；信越化学工业株式会社制)等。
作为含烷基交联型聚甘油改性有机硅，可列举出矿物油·月桂基聚二甲基硅氧烷/聚甘油-3交联聚合物(“KSG-810”；信越化学工业株式会社制)、异十二烷·月桂基聚二甲基硅氧烷/聚甘油-3交联聚合物(“KSG-820”；信越化学工业株式会社制)、甘油三(乙基己酸)酯·月桂基聚二甲基硅氧烷/聚甘油-3交联聚合物(“KSG-830”；信越化学工业株式会社制)、角鲨烷·月桂基聚二甲基硅氧烷/聚甘油-3交联聚合物(“KSG-840”；信越化学工业株式会社制)等。
有机硅弹性体的配合量相对于组合物总量优选0.1～10质量％，更优选1～8质量％，进而优选2～7质量％。通过使配合量为0.1质量％以上，从而可以进一步得到涂布后的肌肤的粘腻感、干涩感的减轻、使皮肤柔软化的效果，通过为10质量％以下，从而可以进一步确保组合物的稳定性。
(B)有机硅弹性体相对于(A)亚苄基丙二酸盐聚硅氧烷的质量比((B)成分/(A)成分)优选0.1～2，更优选0.12～1.95，进而优选0.15～1.8。通过使质量比(B)/(A)为0.1以上，从而进一步成为无粘腻感且顺滑的使用性，通过为2以下，从而可以进一步提高吸光度。
(C)聚二甲基硅氧烷主链具有碳数4以上的烃基的HLB8以下的表面活性剂
作为本发明的水包油型乳化组合物中包含的(C)聚二甲基硅氧烷主链具有碳数4以上的烃基的HLB8以下的表面活性剂(以下，也简称为(C)成分)，可以优选列举出含烷基聚醚改性有机硅、含烷基聚甘油改性有机硅等。通过(C)成分的配合而使吸光度飞跃性地提高的作用机理未必明确，但认为与提高(B)有机硅弹性体的分散有关。
作为含烷基聚醚改性有机硅，可列举出月桂基PEG-9聚二甲基硅氧乙基聚二甲基硅氧烷：Silicone SC0928SL(信越化学工业株式会社制)、鲸蜡基PEG/PPG-10/1聚二甲基硅氧烷：ABIL EM180(GOLDSCHMITT公司制)等。
作为含烷基聚甘油改性有机硅，可列举出月桂基聚甘油-3聚二甲基硅氧乙基聚二甲基硅氧烷(“KF-6105”；信越化学工业株式会社制)、双-丁基聚二甲基硅氧烷聚甘油-3(作为市售品的Silicone KF-6109(信越化学工业株式会社制))等。
(C)成分的配合量相对于组合物总量优选0.01～1质量％，更优选0.03～0.9质量％，进而优选0.05～0.8质量％。通过使配合量为0.01质量％以上，可以进一步提高吸光度，通过为1质量％以下，可以进一步降低粘腻感。
(B)有机硅弹性体相对于(C)成分的质量比((B)成分/(C)成分)优选0.5～10，更优选0.55～9，进而优选0.6～8。通过使质量比(B)/(C)为0.5以上，可以进一步降低粘腻感，通过为10以下，可以进一步提高吸光度。
(D)油溶性紫外线吸收剂
本发明的水包油型乳化组合物优选包含除(A)亚苄基丙二酸盐聚硅氧烷以外的(D)油溶性紫外线吸收剂。
(D)油溶性紫外线吸收剂只要为一直以来化妆品中使用者即可，没有特别限定。例如，可列举出甲氧基肉桂酸衍生物、水杨酸衍生物、苯甲酰衍生物、樟脑衍生物、对氨基苯甲酸衍生物、三嗪衍生物、β,β-二苯基丙烯酸酯衍生物和二苯甲酮衍生物。油溶性紫外线吸收剂根据需要可以以1种或2种以上的组合而配合。
作为甲氧基肉桂酸衍生物，可示例出甲氧基肉桂酸辛酯或甲氧基肉桂酸乙基己酯(例如“PARSOL MCX”；Hoffmann-La Roche)、甲氧基肉桂酸异丙酯、甲氧基肉桂酸异戊酯(例如“Neo Heliopan E1000”；Harman and Raymer公司)、西诺沙酯、甲氧基肉桂酸DEA盐、二异丙基肉桂酸甲酯、甘油乙基己酸酯二甲氧基肉桂酸酯、二(2-乙基己基)-4’-甲氧基亚苄基丙二酸酯等。
作为水杨酸衍生物，可示例出胡莫柳酯(“Eusolex HMS”；Rona/EM Industries公司)、水杨酸乙基己酯(水杨酸辛酯、例如“Neo Heliopan OS”；Harman and Raymer公司)、水杨酸二丙二醇酯(例如“Dipsal”；Skell公司)、水杨酸TEA盐(例如“Neo Heliopan TS”；Harman and Raymer公司)等。
作为苯甲酰衍生物，可示例出4-叔丁基-4’-甲氧基二苯甲酰甲烷(例如“PARSOL1789”)等。
作为樟脑衍生物，可示例出对苯二亚甲基-3,3’-二樟脑-10,10’-二磺酸盐、4-甲基苄亚基樟脑等。
作为对氨基苯甲酸衍生物，可示例出对氨基苯甲酸(PABA)乙酯、二羟丙基PABA乙酯、二甲基PABA乙基己酯(例如“ESCALOL 507”；ISP公司)、甘油PABA酯、PEG-25-PABA(例如“Uvinul P25”；BASF公司)、二乙氨羟苯甲酰基苯甲酸己酯(例如“Uvinul A Plus”)等。
作为三嗪衍生物，可示例出双-乙基己氧苯酚甲氧苯基三嗪(例如“Tinosorb S”；Ciba Specialty Chemicals公司)、乙基己基三嗪酮(例如“Uvinul T150”；BASF公司)、二乙基己基丁酰胺基三嗪酮(例如“Uvasorb HEB”；3VSigma公司)、2,4,6-三(二异丁基-4’-氨基亚苄基丙二酸酯)-均三嗪、2,4,6-三[4-(2-乙基己基氧基羰基)苯胺基]-1,3,5-三嗪等。
作为β,β-二苯基丙烯酸酯衍生物，可示例出奥克立林(例如“Uvinul N539T”；BASF公司)等。
作为二苯甲酮衍生物，可示例出二苯甲酮-1(例如“Uvinul 400”；BASF公司)、二苯甲酮-2(例如“Uvinul D50”；BASF公司)、二苯甲酮-3或羟苯甲酮(例如“Uvinul M40”；BASF公司)、二苯甲酮-4(例如“Uvinul MS40”；BASF公司)、二苯甲酮-5、二苯甲酮-6(例如“Helisorb 11”；Norquay公司)、二苯甲酮-8(例如“Spectra-Sorb UV-24”；Americancyanamide公司)、二苯甲酮-9(例如“Uvinul DS-49”；BASF公司)、二苯甲酮-12等。
本发明中，(D)油溶性紫外线吸收剂的配合量相对于组合物总量优选8质量％以上，更优选9～20质量％，进一步优选10～18质量％。(D)油溶性紫外线吸收剂的配合量相对于组合物总量为8质量％以上，从而可以进一步提高紫外线防御能力。
本发明的水包油型乳化组合物在不有损本发明的效果的范围内可以配合通常的化妆品、准药物中可配合的其他任意成分。作为其他任意成分，没有限定，例如可列举出液体油脂、固体油脂、蜡类、烃油、高级脂肪酸、合成酯油、硅油等油分、粉末成分、色料、保湿剂、水性增稠剂、分散剂、防腐剂、香料、各种药剂等。
作为液体油脂，例如可列举出鳄梨油、山茶籽油、澳洲坚果籽油、玉米油、橄榄油、菜籽油、芝麻油、桃仁油、小麦胚芽油、山茶花油、蓖麻油、亚麻籽油、红花油、棉籽油、紫苏油、大豆油、花生油、茶籽油、榧子油、米糠油、泡桐油、日本桐油、霍霍巴油、胚芽油、三甘油等。
作为固体油脂，例如可列举出可可脂、椰子油、氢化椰子油、棕榈油、棕榈仁油、木蜡仁油、氢化油、木蜡、氢化蓖麻油等。
作为蜡类，例如可列举出蜜蜡、小烛树蜡、棉蜡、巴西棕榈蜡、杨梅蜡、虫蜡、褐煤蜡、糠蜡、木棉蜡、甘蔗蜡、月桂酸己酯、霍霍巴蜡、虫胶蜡、POE胆甾醇醚等。
作为烃油，例如可列举出液体石蜡、地蜡、角鲨烷、姥鲛烷、石蜡、纯地蜡、角鲨烯、凡士林、微晶蜡、氢化聚癸烯等。
作为高级脂肪酸，例如可列举出月桂酸、肉豆蔻酸、棕榈酸、硬脂酸、山萮酸、油酸、十一碳烯酸、妥尔酸、异硬脂酸、亚油酸、亚麻酸、二十碳五烯酸(EPA)、二十二碳六烯酸(DHA)等。
作为合成酯油，可列举出肉豆蔻酸异丙酯、辛酸十六烷基酯、肉豆蔻酸辛基十二烷基酯、棕榈酸异丙酯、硬脂酸丁酯、月桂酸己酯、肉豆蔻酸肉豆蔻酯、油酸癸酯、二甲基辛酸己癸酯、十六烷基乳酸酯、十四烷基乳酸酯、乙酰化羊毛脂、异鲸蜡醇硬脂酸酯、异鲸蜡醇异硬脂酸酯、胆甾醇12-羟基硬脂酸酯、乙二醇二(2-乙基己酸)酯、二季戊四醇脂肪酸酯、单异硬脂酸-N-烷基二醇酯、新戊二醇二癸酸酯、二异硬脂醇苹果酸酯、甘油二(2-庚基十一烷酸)酯、三羟甲基丙烷三(2-乙基己酸)酯、三羟甲基丙烷三异硬脂酸酯、季戊四醇四(2-乙基己酸)酯、2-乙基己酸三甘油酯、三辛酸甘油酯、三异棕榈酸甘油酯、三羟甲基丙烷三异硬脂酸酯、十六烷基-2-乙基己酸酯、棕榈酸2-乙基己酯、甘油三肉豆蔻酸酯、甘油三(2-庚基十一烷酸)酯、蓖麻油脂肪酸甲酯、油酸油酯、乙酰甘油酯、棕榈酸2-庚基十一烷基酯、己二酸二异丁酯、N-月桂酰基-L-谷氨酸-2-辛基十二烷基酯、二(2-庚基十一烷醇)己二酸酯、月桂酸乙酯、癸二酸二(2-乙基己基)酯、肉豆蔻酸2-己基癸酯、棕榈酸2-己基癸酯、己二酸2-己基癸酯、癸二酸二异丙酯、琥珀酸2-乙基己酯、柠檬酸三乙酯等。
作为硅油，例如可列举出链状聚硅氧烷(例如二甲基硅油、甲基苯基聚硅氧烷、二苯基聚硅氧烷等)；环状聚硅氧烷(例如八甲基环四硅氧烷、十甲基环五硅氧烷、十二甲基环六硅氧烷等)、形成三维网络结构的有机硅树脂、硅橡胶、各种改性聚硅氧烷(氨基改性聚硅氧烷、聚醚改性聚硅氧烷、烷基改性聚硅氧烷、氟改性聚硅氧烷等)等。
上述的各油分可以使用1种或适宜组合2种以上而使用。
作为粉末成分，可列举出氧化锌、氧化钛等紫外线散射剂、滑石、云母、高岭土等体质颜料、聚乙烯粉末、聚甲基丙烯酸甲酯粉末、尼龙粉末等聚合物粉末等。
作为保湿剂，例如可列举出甘油、1,3-丁二醇、一缩二丙二醇、丙二醇等多元醇、海藻糖、透明质酸、硫酸软骨素等水溶性高分子等。
作为水性增稠剂，例如可列举出琥珀酰聚糖、二甲基丙烯酰胺/丙烯酰基二甲基牛磺酸钠交联聚合物、纤维素胶、羧乙烯基聚合物、黄原胶、丙烯酸羟乙酯/丙烯酰二甲基牛磺酸钠共聚物等。
本发明的水包油型乳化组合物可以通过例如分别将构成油相的成分与构成水相的成分混合、并且将油相添加到水相中进行乳化等之类的水包油型乳化组合物(化妆品)的常规方法来制造。
本发明的水包油型乳化组合物可以作为液态、乳液态、乳霜状、凝胶状、巴伐露(Bavarois)状等各种剂型的化妆品而提供。
另外，本发明的水包油型乳化组合物可以作为护肤化妆品、防晒化妆品、配合有色料的化妆品、粉底液、打底霜、BB乳霜而提供。
实施例
以下列举实施例来进一步具体地说明本发明，但本发明不限于这些。配合量只要没有特别说明，均为质量％。
(实施例1～3和比较例1～3)
以下述表1所示的配方制作水包油型乳化组合物，关于制作的组合物，以以下基准进行评价。
(峰最高值)
向测定板(S板)(5×5cm的V形槽PMMA板、SPFMASTER-PA01)以2mg/cm2的量滴加各例的组合物(样品)，用手指涂布60秒，干燥15分钟后，对于形成的涂膜的吸光度，利用株式会社日立制作所公司制U-3500型自动记录分光光度计测定吸光度。将无涂布的板作为空白，以下式算出吸光度(Abs)，将吸光度的最大值峰作为峰最高值。
Abs＝-log(T/To)
T：样品的透射率、To：无涂布的透射率
＜吸光度(Abs)累计值的测定＞
向测定板(S板)(5×5cm的V形槽PMMA板、SPFMASTER-PA01)以2mg/cm2的量滴加各例的组合物(样品)，用手指涂布60秒，干燥15分钟后，对于形成的涂膜的吸光度，利用株式会社日立制作所公司制U-3500型自动记录分光光度计进行测定。将无涂布的板作为空白，以下式算出吸光度(Abs)，将280nm～400nm下的测定值累计，求出吸光度累计值。
Abs＝-log(T/To)
T：样品的透射率、To：无涂布的透射率
将配方和评价结果示于表1。需要说明的是，表所示成分中的主要物质的市售品名示于以下。
·丙烯酸(酯)类/C10-30烷醇丙烯酸酯交联聚合物：PEMULEN TR-2(LubrizolAdvanced Materials,Inc.制)
·丙烯酰二甲基牛磺酸铵/山萮醇聚醚-25甲基丙烯酸酯交联聚合物：ARISTOFLEXHMB(Clariant GMBH公司制)
·双-丁基聚二甲基硅氧烷聚甘油-3：Silicone KF-6109(信越化学工业株式会社制)
·月桂基PEG-9聚二甲基硅氧乙基聚二甲基硅氧烷：Silicone SC0928SL(信越化学工业株式会社制)
·鲸蜡基PEG/PPG-10/1聚二甲基硅氧烷：ABIL EM180(GOLDSCHMITT公司制)
·月桂基甜菜碱：ANON BL-SF(日油株式会社制)
·聚硅氧烷-11/聚二甲基硅氧烷(3CS)：Gransil DMG-3((GRANT INDUSTRIES公司制)
·亚苄基丙二酸盐聚硅氧烷：PARSOL SLX(DSM Nutritional Products公司制)
[表1]
如表1所示，实施例的水包油型乳化组合物即使配合有机硅弹性体，吸光度的峰最高值、累计值均高。另一方面，不含(C)成分的比较例1、不含(A)亚苄基丙二酸盐聚硅氧烷的比较例2、3中吸光度的峰最高值、累计值的优势降低。特别是，比较例3即使增加对防晒化妆品有用的最常用的奥克立林，也不及实施例的峰最高值、累计值。
Claims (4)
1.一种水包油型乳化组合物，其包含：
(A)亚苄基丙二酸盐聚硅氧烷、
(B)有机硅弹性体、和
(C)聚二甲基硅氧烷主链具有碳数4以上的烃基的HLB8以下的表面活性剂。
2.根据权利要求1所述的水包油型乳化组合物，其中，相对于组合物总量包含除所述(A)亚苄基丙二酸盐聚硅氧烷以外的(D)油溶性紫外线吸收剂8质量％以上。
3.根据权利要求1或2所述的水包油型乳化组合物，其中，(B)有机硅弹性体相对于所述(C)聚二甲基硅氧烷主链具有碳数4以上的烃基的HLB8以下的表面活性剂的质量比为0.5～10。
4.根据权利要求1、2或3所述的水包油型乳化组合物，其中，所述(B)有机硅弹性体相对于所述(A)亚苄基丙二酸盐聚硅氧烷的质量比为0.1～2。
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| JP2020-151109 | 2020-09-09 | ||
| JP2020151109A JP2022045492A (ja) | 2020-09-09 | 2020-09-09 | 水中油型乳化組成物 |
| PCT/JP2021/032951 WO2022054820A1 (ja) | 2020-09-09 | 2021-09-08 | 水中油型乳化組成物 |
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| JP5469319B2 (ja) * | 2008-08-22 | 2014-04-16 | 株式会社 資生堂 | 日焼け止め化粧料 |
| EP2827834B1 (en) * | 2012-03-19 | 2017-11-08 | The Procter and Gamble Company | Superabsorbent polymers and silicone elastomer for use in hair care compositions |
| EP3024431A1 (en) * | 2013-07-22 | 2016-06-01 | The Procter & Gamble Company | Stable, high salt containing skin care compositions |
| JP6831737B2 (ja) * | 2017-03-30 | 2021-02-17 | 株式会社コーセー | 水中油型化粧料 |
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