CN115960489A - Flexible plastic ink applied to extrusion compounding process - Google Patents

Flexible plastic ink applied to extrusion compounding process Download PDF

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Publication number
CN115960489A
CN115960489A CN202211676384.XA CN202211676384A CN115960489A CN 115960489 A CN115960489 A CN 115960489A CN 202211676384 A CN202211676384 A CN 202211676384A CN 115960489 A CN115960489 A CN 115960489A
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China
Prior art keywords
parts
water
ink
soluble acrylic
resin
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CN202211676384.XA
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Chinese (zh)
Inventor
王鑫
潘吉红
吴君
汪慧
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HUANGSHAN SHINING INK TECHNOLOGY CO LTD
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HUANGSHAN SHINING INK TECHNOLOGY CO LTD
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Priority to CN202211676384.XA priority Critical patent/CN115960489A/en
Publication of CN115960489A publication Critical patent/CN115960489A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Abstract

The invention belongs to the technical field of ink preparation, and particularly relates to a flexible plastic ink applied to an extrusion compounding process, which is composed of the following raw materials in parts by weight: 10-12 parts of 36% water-soluble acrylic resin, 35-45 parts of 40% water-soluble acrylic grafted polyurethane resin, 14-35 parts of pigment, 0.3-0.8 part of polyethylene wax, 0.4-0.8 part of silicon dioxide, 10-57 parts of deionized water and 3-4 parts of silane coupling agent; 1 part of aqueous chlorinated polypropylene; 3-6 parts of ethanol; 1-2 parts of 50% polyether siloxane wetting agent and 0.2-0.5 part of water-based defoaming agent, and the flexographic plastic ink applied to the extrusion compounding process selects proper water-based resin and water-based auxiliary agent, optimizes the formula, ensures that the newly developed water-based flexographic extrusion compounding ink has good printing adaptability, has the extrusion compounding strength of more than 1N/15mm, and meets the existing market requirements.

Description

Flexible plastic ink applied to extrusion compounding process
Technical Field
The invention relates to a flexible plastic ink applied to an extrusion compounding process. Belongs to the technical field of preparation of flexographic extrusion composite plastic printing ink.
Background
At present, the flexographic inner printing composite ink used in the market is the inner printing composite ink mainly using alcohol-soluble resin, (PVB resin, NC resin, PU resin and PA resin) as main resin, and ester (n-propyl ester) solvent with the content not less than 5 percent must be added in the formula of the ink to improve the solubility and the transfer performance of a flexographic plate. The printing ink contains organic solvents such as alcohol, ester and ether, a large amount of volatile organic gases (VOCs) can be generated in the production and use processes, the organic solvents can swell and corrode the plastic printing plate, the plate pasting glue is dissolved, printing faults such as poor leveling and edge warping are caused, and the condition that the solvent residue is high and the safety standard cannot be reached in partial products can occur. The alcohol-soluble flexographic composite ink has high solvent volatilization speed, is easy to generate the conditions of dry plate, dirty plate, blocked mesh roller and the like, and the hard dispersion resin in the alcohol-soluble flexographic composite ink can cause low subsequent extrusion composite strength, wherein the extrusion PE composite strength is almost zero, so that the alcohol-soluble flexographic composite ink cannot meet the market demand.
Disclosure of Invention
The invention provides a flexographic plastic ink applied to an extrusion compounding process, which solves the problems of low extrusion PE compounding strength, high VOCs (volatile organic compounds) emission, poor printing adaptability of dry plates, dirty plates, screen blocking rollers and the like of alcohol-soluble flexographic inner printing ink in the prior art, thoroughly solves related problems through new product development and meets market requirements.
In order to solve the technical problems, the technical scheme of the invention is as follows:
a flexographic plastic ink applied to an extrusion compounding process is composed of the following raw materials in parts by weight: 10-12 parts of 36% water-soluble acrylic resin, 35-45 parts of 40% water-soluble acrylic grafted polyurethane resin, 14-35 parts of pigment, 0.3-0.8 part of polyethylene wax, 0.4-0.8 part of silicon dioxide, 10-57 parts of deionized water and 3-4 parts of silane coupling agent; 1 part of aqueous chlorinated polypropylene; 3-6 parts of ethanol; 1-2 parts of 50% polyether siloxane wetting agent and 0.2-0.5 part of water-based defoaming agent.
The water-soluble acrylic resin is a main dispersion resin of the flexographic extrusion composite ink, has good shearing resistance, and can wrap and disperse pigment molecules well through grinding, so that the water-soluble acrylic resin has excellent stability. Available commercially.
The water-based acrylic acid grafted polyurethane resin is a main body connecting resin of a flexible plate extrusion composite ink, has the color development of the ink acrylic acid and the toughness of polyurethane, has high hardness of acrylic acid components, can improve the resistance (heat resistance, weather resistance and corrosion resistance) of an ink film, and provides the adhesive force of a polyurethane group on a plastic substrate PET. Available commercially. Pigments are colorants, which impart various colors to the ink and are commercially available. The polyethylene wax improves the printing adaptability of the ink and can be purchased in the market. Silica, which improves the printability and anti-blocking properties of the ink, is commercially available. The aqueous solvent, which is used for dissolving the resin, wetting the pigment, improving the solvent evaporation rate, adjusting the viscosity, and the like, is commercially available. Ethanol solvent: the small amount of the additive can effectively eliminate bubbles in the production and use of the ink, reduce the surface tension of the ink and ensure better leveling on the film.
The waterborne chlorinated polypropylene resin is used as auxiliary resin for flexographic extrusion composite ink, mainly improves the adhesive force on a BOPP plastic base material, and can effectively improve the strength of extrusion compounding because the PE material of the extrusion compounding can generate chemical bonds with chlorinated polypropylene. The silane coupling agent plays a role in bridging and crosslinking in an ink system, can quickly generate bridging reaction when the temperature exceeds 60 ℃, improves the adhesive force of resin and a plastic base material, ensures that the ink has more stable film formation after crosslinking, and also improves the extrusion composite strength in the subsequent extrusion composite process.
The polyether siloxane wetting agent is used for solving the problems that the ink is easy to sag and shrink due to large surface tension (72 dyn) and surface tension (38-52 dyn) of a film, and the polyether siloxane can reduce the surface tension of the ink.
The aqueous defoaming agent reduces the introduction of a large amount of gas in the process of dispersion and grinding of the ink, improves wetting and operability, eliminates bubbles generated in the process of using the ink and reduces spray during printing.
In other embodiments, the flexographic plastic ink applied to the extrusion compounding process is composed of the following raw materials in parts by weight: 10 parts of 36% water-soluble acrylic resin, 35 parts of 40% water-soluble acrylic grafted polyurethane resin, 20 parts of pigment, 0.3 part of polyethylene wax, 0.4 part of silicon dioxide, 10 parts of deionized water and 3 parts of silane coupling agent; 1 part of aqueous chlorinated polypropylene; 3 parts of ethanol; 1 part of 50 percent polyether siloxane wetting agent and 0.3 part of water-based defoaming agent.
In other embodiments, the flexographic plastic ink applied to the extrusion compounding process is composed of the following raw materials in parts by weight: 12 parts of 36% water-soluble acrylic resin, 45 parts of 40% water-soluble acrylic grafted polyurethane resin, 35 parts of pigment, 0.8 part of polyethylene wax, 0.8 part of silicon dioxide, 57 parts of deionized water and 3 parts of silane coupling agent; 1 part of aqueous chlorinated polypropylene; 6 parts of ethanol; 2 parts of 50% polyether siloxane wetting agent and 0.5 part of water-based defoaming agent.
In other embodiments, the flexographic plastic ink applied to the extrusion compounding process is composed of the following raw materials in parts by weight: 11 parts of 36% water-soluble acrylic resin, 40 parts of 40% water-soluble acrylic grafted polyurethane resin, 14 parts of pigment, 0.5 part of polyethylene wax, 0.5 part of silicon dioxide, 36 parts of deionized water and 4 parts of silane coupling agent; 1 part of aqueous chlorinated polypropylene; 5 parts of ethanol; 1.5 parts of 50 percent polyether siloxane wetting agent and 0.2 part of water-based defoaming agent.
The invention has the following advantages and beneficial effects:
the invention relates to a flexographic plastic ink applied to an extrusion compounding process, which is prepared by grinding organic pigment or inorganic pigment, water-soluble acrylic resin, water-soluble acrylic acid grafted polyurethane resin, water-based chlorinated polypropylene resin, polyether siloxane wetting agent, silane coupling agent, wax powder, silicon powder and the like by using water instead of normal propyl alcohol, propylene glycol methyl ether, propylene glycol ethyl ether and alcohol as main solvents, and selecting proper water-based resin and water-based auxiliary agent through new product research and development, and optimizing a formula, so that the newly developed water-based flexographic extrusion compounding ink has good printing adaptability, the extrusion compounding strength is greater than 1N/15mm, and the existing market demands are met. With the promotion of environmental protection requirements and the concern of people on health, the flexible printing ink for extruding and compounding is developed, the discharge problem of VOCs is effectively solved, the solvent residue of finished products is reduced, the constructability of flexible printing is improved, and the market trend is met.
Detailed Description
The following further describes the embodiments of the present invention. It should be noted that the description of the embodiments is provided to help understanding of the present invention, and is not intended to limit the present invention. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
A flexographic plastic ink applied to an extrusion compounding process is composed of the following raw materials in parts by weight: 10-12 parts of 36% water-soluble acrylic resin, 35-45 parts of 40% water-soluble acrylic grafted polyurethane resin, 14-35 parts of pigment, 0.3-0.8 part of polyethylene wax, 0.4-0.8 part of silicon dioxide, 10-57 parts of deionized water and 3-4 parts of silane coupling agent; 1 part of aqueous chlorinated polypropylene; 3-6 parts of ethanol; 1-2 parts of 50% polyether siloxane wetting agent and 0.2-0.5 part of water-based defoaming agent.
The water-soluble acrylic resin is a main dispersion resin of the flexographic extrusion composite ink, has good shearing resistance, and can wrap and disperse pigment molecules well through grinding so as to ensure that the water-soluble acrylic resin has excellent stability. Available commercially.
The water-based acrylic acid grafted polyurethane resin is a main body connecting resin of a flexible plate extrusion composite ink, has the color development of the ink acrylic acid and the toughness of polyurethane, has high acrylic acid component hardness, can improve the tolerance (heat resistance, weather resistance and corrosion resistance) of an ink film, and provides the adhesive force of a polyurethane group on a plastic substrate PET. Available commercially. Pigments, which are colorants, impart various colors to inks, and are commercially available. The polyethylene wax improves the printing adaptability of the ink and can be purchased in the market. Silica, which improves the printability and anti-blocking properties of the ink, is commercially available. The aqueous solvent, which is used for dissolving the resin, wetting the pigment, improving the solvent evaporation rate, adjusting the viscosity, and the like, is commercially available. Ethanol solvent: the small amount of the additive can effectively eliminate bubbles in the production and use of the ink, reduce the surface tension of the ink and ensure better leveling on the film.
The waterborne chlorinated polypropylene resin is used as auxiliary resin for flexographic extrusion composite ink, mainly improves the adhesive force on a BOPP plastic base material, and can effectively improve the strength of extrusion compounding because the PE material of the extrusion compounding can generate chemical bonds with chlorinated polypropylene. The silane coupling agent plays a role in bridging and crosslinking in an ink system, can quickly generate bridging reaction when the temperature exceeds 60 ℃, improves the adhesive force of resin and a plastic substrate, ensures that the ink is more stable in film forming after crosslinking is generated, and also improves the extrusion composite strength in the subsequent extrusion composite process.
The polyether siloxane wetting agent is used for solving the problems that the ink is easy to sag and shrink due to large surface tension (72 dyn) and surface tension (38-52 dyn) of a film, and the polyether siloxane can reduce the surface tension of the ink.
The aqueous defoaming agent reduces the introduction of a large amount of gas in the process of dispersing and grinding the ink, improves the wetting and operability, eliminates bubbles generated in the process of using the ink, and reduces the spray during printing.
Example 1:
a flexographic plastic ink applied to an extrusion compounding process is composed of the following raw materials in parts by weight: 12 parts of 36% water-soluble acrylic resin, 35 parts of 40% water-soluble acrylic grafted polyurethane resin, 33 parts of pigment, 0.4 part of polyethylene wax, 0.4 part of silicon dioxide, 12 parts of deionized water and 3 parts of silane coupling agent; 1 part of aqueous chlorinated polypropylene; 2 parts of ethanol; 1 part of 50 percent polyether siloxane wetting agent and 0.2 part of water-based defoaming agent.
Example 2:
a flexographic plastic ink applied to an extrusion compounding process is composed of the following raw materials in parts by weight: 11 parts of 36% water-soluble acrylic resin, 39 parts of 40% water-soluble acrylic grafted polyurethane resin, 15 parts of pigment, 0.6 part of polyethylene wax, 0.4 part of silicon dioxide, 23 parts of deionized water and 3.5 parts of silane coupling agent, wherein the pigment is water-soluble red pigment; 1 part of aqueous chlorinated polypropylene; 4.5 parts of ethanol; 1.5 parts of 50 percent polyether siloxane wetting agent and 0.5 part of water-based defoaming agent.
Example 3:
a flexographic plastic ink applied to an extrusion compounding process is composed of the following raw materials in parts by weight: 10 parts of 36% water-soluble acrylic resin, 40 parts of 40% water-soluble acrylic grafted polyurethane resin, 13.5 parts of pigment, 0.6 part of polyethylene wax, 0.4 part of silicon dioxide, 24 parts of deionized water and 3.5 parts of silane coupling agent; 1 part of aqueous chlorinated polypropylene; 5 parts of ethanol; 1.7 parts of 50 percent polyether siloxane wetting agent and 0.3 part of water-based defoaming agent.
The properties of the ink produced in each example were described, and the product was tested and used, and the results are shown in table 1 below.
TABLE 1
Figure BDA0004017093840000051
Figure BDA0004017093840000061
The embodiments of the present invention have been described in detail, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, and the scope of protection is still within the scope of the invention.

Claims (4)

1. A flexible plastic ink applied to an extrusion compounding process is characterized in that: the composite material is prepared from the following raw materials in parts by weight: 10-12 parts of 36% water-soluble acrylic resin, 35-45 parts of 40% water-soluble acrylic grafted polyurethane resin, 14-35 parts of pigment, 0.3-0.8 part of polyethylene wax, 0.4-0.8 part of silicon dioxide, 10-57 parts of deionized water and 3-4 parts of silane coupling agent; 1 part of aqueous chlorinated polypropylene; 3-6 parts of ethanol; 1-2 parts of 50% polyether siloxane wetting agent and 0.2-0.5 part of water-based defoaming agent.
2. The flexographic plastic ink for extrusion lamination process according to claim 1, wherein: the composite material is prepared from the following raw materials in parts by weight: 10 parts of 36% water-soluble acrylic resin, 35 parts of 40% water-soluble acrylic grafted polyurethane resin, 20 parts of pigment, 0.3 part of polyethylene wax, 0.4 part of silicon dioxide, 10 parts of deionized water and 3 parts of silane coupling agent; 1 part of aqueous chlorinated polypropylene; 3 parts of ethanol; 1 part of 50 percent polyether siloxane wetting agent and 0.3 part of water-based defoaming agent.
3. The flexographic plastic ink for extrusion lamination process according to claim 1, wherein: the composite material is prepared from the following raw materials in parts by weight: 12 parts of 36% water-soluble acrylic resin, 45 parts of 40% water-soluble acrylic grafted polyurethane resin, 35 parts of pigment, 0.8 part of polyethylene wax, 0.8 part of silicon dioxide, 57 parts of deionized water and 3 parts of a silane coupling agent; 1 part of aqueous chlorinated polypropylene; 6 parts of ethanol; 2 parts of 50% polyether siloxane wetting agent and 0.5 part of water-based defoaming agent.
4. The flexographic plastic ink for extrusion lamination process according to claim 1, wherein: the composition is characterized by comprising the following raw materials in parts by weight: 11 parts of 36% water-soluble acrylic resin, 40 parts of 40% water-soluble acrylic grafted polyurethane resin, 14 parts of pigment, 0.5 part of polyethylene wax, 0.5 part of silicon dioxide, 36 parts of deionized water and 4 parts of silane coupling agent; 1 part of aqueous chlorinated polypropylene; 5 parts of ethanol; 1.5 parts of 50 percent polyether siloxane wetting agent and 0.2 part of water-based defoaming agent.
CN202211676384.XA 2022-12-26 2022-12-26 Flexible plastic ink applied to extrusion compounding process Pending CN115960489A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08269381A (en) * 1995-03-31 1996-10-15 Toyo Ink Mfg Co Ltd Water-based printing ink
JP2008049706A (en) * 2007-08-23 2008-03-06 Toyo Ink Mfg Co Ltd Aqueous urethane resin, aqueous printing ink composition, and packaging material using the composition
CN101457053A (en) * 2008-09-25 2009-06-17 黄山市新力油墨化工厂 Extruding composition printing ink and preparation method thereof
CN101492583A (en) * 2008-01-22 2009-07-29 东莞市佳景印刷材料有限公司 Watersoluble packaging pouch printing ink and method for preparing the same
CN101717596A (en) * 2009-12-08 2010-06-02 杭华油墨化学有限公司 Water-based ink for package printing of high-adhesion film and manufacturing method thereof
CN102140272A (en) * 2010-01-28 2011-08-03 中国科学院化学研究所 Ink resin composite used for plastic gravure printing and preparation method thereof
JP2013234214A (en) * 2012-05-07 2013-11-21 Toyo Ink Sc Holdings Co Ltd Aqueous polyurethane resin and use of the same
CN114364542A (en) * 2019-09-03 2022-04-15 东丽株式会社 Method for manufacturing printed matter

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08269381A (en) * 1995-03-31 1996-10-15 Toyo Ink Mfg Co Ltd Water-based printing ink
JP2008049706A (en) * 2007-08-23 2008-03-06 Toyo Ink Mfg Co Ltd Aqueous urethane resin, aqueous printing ink composition, and packaging material using the composition
CN101492583A (en) * 2008-01-22 2009-07-29 东莞市佳景印刷材料有限公司 Watersoluble packaging pouch printing ink and method for preparing the same
CN101457053A (en) * 2008-09-25 2009-06-17 黄山市新力油墨化工厂 Extruding composition printing ink and preparation method thereof
CN101717596A (en) * 2009-12-08 2010-06-02 杭华油墨化学有限公司 Water-based ink for package printing of high-adhesion film and manufacturing method thereof
CN102140272A (en) * 2010-01-28 2011-08-03 中国科学院化学研究所 Ink resin composite used for plastic gravure printing and preparation method thereof
JP2013234214A (en) * 2012-05-07 2013-11-21 Toyo Ink Sc Holdings Co Ltd Aqueous polyurethane resin and use of the same
CN114364542A (en) * 2019-09-03 2022-04-15 东丽株式会社 Method for manufacturing printed matter

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Application publication date: 20230414