CN115835854A - 改善清洁剂组合物的起泡性和泡质的方法、以及皮肤或毛发的清洁方法 - Google Patents
改善清洁剂组合物的起泡性和泡质的方法、以及皮肤或毛发的清洁方法 Download PDFInfo
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- CN115835854A CN115835854A CN202180048769.9A CN202180048769A CN115835854A CN 115835854 A CN115835854 A CN 115835854A CN 202180048769 A CN202180048769 A CN 202180048769A CN 115835854 A CN115835854 A CN 115835854A
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- detergent composition
- ether
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- monocyclohexylglyceryl
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Abstract
本发明提供一种改善清洁剂组合物的起泡性和泡质的方法,包括配合单环己基甘油基醚、阴离子性表面活性剂和水;另外,本发明提供一种皮肤或毛发的清洁方法,包括:通过泡沫吐出容器吐出包含单环己基甘油基醚、阴离子性表面活性剂和水的清洁液以得到起泡的清洁液;以及将该起泡的清洁液涂布于皮肤或毛发。
Description
技术领域
本发明涉及改善清洁剂组合物的起泡性和泡质的方法、以及皮肤或毛发的清洁方法。
背景技术
在清洁剂组合物中,由于起泡时产生的泡沫的量和泡沫质量(泡质)对洗涤性和使用感有很大影响,因此,改善起泡性和泡质的清洁剂组合物的开发正在活跃地进行。例如,专利文献1中记载了一种泡沫的数量、泡沫的弹性、喷出时泡沫的清洁性、低温保存后的喷出性以及毛巾干燥后的皮肤湿润感均优异的液体清洁剂组合物。专利文献2中记载了一种皮肤清洁剂,其是以泡沫状喷出而使用的皮肤清洁剂,其即使残留适当的脱脂感,也能够抑制吱吱声和紧绷感,而且泡质也优异。专利文献3中记载了一种填充于泡沫吐出容器中使用的毛发清洁剂组合物,其能够喷出良好的泡沫,即使在低温下保存稳定性也高,洗发时的泡量和泡质良好,进而毛发冲洗时的光滑性优异。
现有技术文献
专利文献
专利文献1:日本特开2019-94287号公报
专利文献2:日本特开2019-172624号公报
专利文献3:日本特开2018-177652号公报
发明内容
发明要解决的课题
专利文献1~3中记载的清洁剂组合物分别通过将所配合成分的种类和含量设为特定构成,可期待一定程度的起泡性和泡质的提高等,但在市场上,为了进一步改良清洁剂组合物的清洁性和使用感,要求进一步改善起池性和泡质。因此,本发明的目的在于提供一种改善清洁剂组合物的起泡性和泡质的方法。
解决课题的手段
本发明人等为了解决上述课题而进行了深入研究,结果发现,通过在特定的清洁剂组合物中配合单环己基甘油基醚,能够改善清洁剂组合物的起泡性和泡质。即,本发明是一种改善清洁剂组合物的起泡性和泡质的方法,其包括配合单环己基甘油基醚、阴离子性表面活性剂和水。另外,本发明是一种皮肤或毛发的清洁方法,包括:通过泡沫吐出容器吐出包含单环己基甘油基醚、阴离子性表面活性剂和水的清洁液以得到起泡的清洁液;以及将该起泡的清洁液涂布于皮肤或毛发。
发明效果
本发明的效果在于,提供一种改善清洁剂组合物的起泡性和泡质的方法。
具体实施方式
本发明的改善清洁剂组合物的起泡性和泡质的方法的特征在于,包括配合单环己基甘油基醚、阴离子性表面活性剂和水。即,本发明所用的清洁剂组合物中包含单环己基甘油基醚、阴离子性表面活性剂和水。根据本方法,在使用清洁剂组合物时,能够改善起泡性和泡质。在此,本发明中的泡质是指清洁时起泡的状态的泡质。
本方法中的清洁剂组合物中的单环己基甘油基醚的含量没有特别限定,从本发明效果的观点考虑,相对于清洁剂组合物的总量,优选为0.01~10.0质量%,更优选为0.05~7.0质量%,进一步优选为0.10~5.0质量%。作为与单环己基甘油基醚类似的化合物,例如有:烃基结构不同的甘油基醚类、烷烃二醇类等,但在配合单环己基甘油基醚以外的化合物的情况下,如后述的实施例等所示,虽然在清洁剂组合物中观察到一定程度的起泡性和泡质的改善等,但无法得到本发明这样显著的起泡性和泡质改善效果。
作为本发明使用的清洁剂组合物中的阴离子性表面活性剂,没有特别限定,可以使用清洁剂组合物中通常使用的阴离子性表面活性剂,例如可举出:高级脂肪酸盐、高级醇硫酸酯盐、硫化烯烃盐、高级烷基磺酸盐、α-烯烃磺酸盐、硫酸化脂肪酸盐、磺化脂肪酸盐、磷酸酯盐、脂肪酸酯的硫酸酯盐、甘油酯硫酸酯盐、脂肪酸酯的磺酸盐、α-磺基脂肪酸甲酯盐、聚氧化烯烷基醚硫酸盐、聚氧化烯烷基苯基醚硫酸盐、聚氧化烯烷基醚羧酸盐、聚氧化烯烷基醚磷酸盐、酰化肽、脂肪酸烷醇酰胺或其环氧烷加成物的硫酸酯盐、磺基琥珀酸酯、烷基苯磺酸盐、烷基萘磺酸盐、烷基苯并咪唑磺酸盐、聚氧化烯磺基琥珀酸盐、N-酰基-N-甲基牛磺酸盐、N-酰基谷氨酸或其盐、酰氧基乙磺酸盐、烷氧基乙磺酸盐、N-酰基-β-丙氨酸或其盐、N-酰基-N-羧乙基牛磺酸或其盐、N-酰基-N-羧甲基甘氨酸或其盐、酰基乳酸盐、N-酰基肌氨酸盐、以及烷基或烯基氨基羧甲基硫酸盐等中的1种或2种以上的混合物。本发明中,从改善起泡性和泡质的效果的观点考虑,作为阴离子性表面活性剂,优选包含选自聚氧化烯烷基醚硫酸盐、聚氧化烯烷基苯基醚硫酸盐、聚氧化烯烷基醚羧酸盐和聚氧化烯烷基醚磷酸盐中的至少1种阴离子性表面活性剂,更优选包含至少1种聚氧化烯烷基醚硫酸盐。此时,聚氧化烯烷基醚硫酸盐的结构没有特别限定,例如可以使用具有碳数8~20的直链或支链状烷基、且加成有1~20摩尔的碳数2~4的环氧烷的聚氧化烯烷基醚的硫酸酯盐。从本发明效果的观点考虑,作为阴离子性表面活性剂,特别优选包含具有碳数10~16的直链或支链状烷基、且加成有碳数2~3的环氧烷的聚氧化烯烷基醚的硫酸酯盐(例如,聚氧乙烯(1~4)月桂基醚硫酸钠)。
本发明使用的清洁剂组合物中的阴离子性表面活性剂的含量没有特别限定,从本发明效果的观点考虑,清洁剂组合物中的阴离子性表面活性剂的含量相对于清洁剂组合物的总量,优选为0.1~20.0质量%,更优选为1.0~15.0质量%,进一步优选为2.0~12.0质量%,特别优选为3.0~10.0质量%。
清洁剂组合物中的阴离子性表面活性剂的含量与单环己基甘油基醚的含量的比率没有特别限定,从起泡性和泡质的改善效果的观点考虑,单环己基甘油基醚的含量相对于阴离子性表面活性剂的含量100质量份,优选为1~1000质量份,更优选为1~500质量份,进一步优选为2~300质量份,特别优选为5~100质量份。
本发明使用的清洁剂组合物中所含的水没有特别限定,可以使用自来水、纯水、RO水、去离子水、蒸馏水等。另外,本发明使用的清洁剂组合物中的水的含量没有特别限定,从本发明效果的观点考虑,清洁剂组合物中的水的含量相对于清洁剂组合物的总量,优选为20%~99质量%,更优选为40~95质量%,进一步优选为60~90质量%。
本发明使用的清洁剂组合物除了上述的单环己基甘油基醚、阴离子性表面活性剂和水以外,还可以含有在清洁剂组合物中通常使用的其他成分。作为这样的其他成分,例如可举出:阳离子性表面活性剂、非离子性表面活性剂、两性表面活性剂、溶剂(不包括水)、油性成分、增稠剂、抗菌剂、香料、保湿剂、螯合剂、生理活性成分、抗氧化剂、树脂粉体、颜料、色素等。
本发明使用的清洁剂组合物中可含有的阳离子性表面活性剂只要是在清洁剂组合物中通常使用的阳离子性表面活性剂,就没有特别限定,例如可举出:烷基(烯基)三甲基铵盐、二烷基(烯基)二甲基铵盐、烷基(烯基)季铵盐、含有醚基或酯基或酰胺基的单或二烷基(烯基)季铵盐、烷基(烯基)吡啶盐、烷基(烯基)二甲基苄基铵盐、烷基(烯基)异喹啉盐、二烷基(烯基)吗啉盐、聚氧乙烯烷基(烯基)胺、烷基(烯基)胺盐、多胺脂肪酸衍生物、戊醇脂肪酸衍生物、苯扎氯铵、苄索氯铵、阳离子化聚合物(阳离子化纤维素、阳离子化瓜尔胶、阳离子化塔拉胶、阳离子化刺槐豆胶、阳离子化黄原胶等)等,可以含有这些中的1种或2种以上。从本发明效果的观点考虑,作为阳离子性表面活性剂,优选使用包含选自瓜尔胶羟丙基三甲基氯化铵、刺槐豆胶羟丙基三甲基氯化铵、聚季铵盐-6和聚季铵盐-10中的至少1种的清洁剂组合物。本发明使用的清洁剂组合物含有阳离子性表面活性剂时的阳离子性表面活性剂的含量没有特别限定,例如,相对于清洁剂组合物的总量,清洁剂组合物中的阳离子性表面活性剂的含量优选为0.01~10质量%,更优选为0.05~5质量%,进一步优选为0.1~3质量%。
清洁剂组合物含有阳离子性表面活性剂时的清洁剂组合物中的阳离子性表面活性剂的含量与单环己基甘油基醚的含量的比率没有特别限定,从泡质和起泡力的改善效果的观点考虑,单环己基甘油基醚的含量相对于阳离子性表面活性剂的含量100质量份,优选为1~1000质量份,更优选为10~500质量份,进一步优选为20~300质量份。
本发明使用的清洁剂组合物中可含有的非离子性表面活性剂只要是在清洁剂组合物中通常使用的非离子性表面活性剂,就没有特别限定,例如可举出:山梨糖醇酐脂肪酸酯、甘油聚甘油脂肪酸酯、丙二醇脂肪酸酯、氢化蓖麻油衍生物、甘油烷基醚、POE-山梨糖醇酐脂肪酸酯、POE-山梨糖醇脂肪酸酯、POE-甘油脂肪酸酯类、POE-脂肪酸酯、POE-烷基醚、POE·POP-烷基醚、四POE·四POP-乙二胺缩合物、POE-蓖麻油氢化蓖麻油衍生物、POE-蜂蜡·羊毛脂衍生物、烷醇酰胺、POE-丙二醇脂肪酸酯、POE-烷基胺、POE-脂肪酰胺、脂肪酸二甘醇、蔗糖脂肪酸酯、烷基乙氧基二甲基氧化胺等,可以含有这些中的1种或2种以上。从本发明效果的观点考虑,作为非离子性表面活性剂,优选使用含有选自椰油脂肪酸二乙醇酰胺、月桂酸单乙醇酰胺、脂肪酸异丙醇酰胺和椰油酰胺甲基单乙醇酰胺(椰油酰胺甲基MEA)中的至少1种的清洁剂组合物。本发明使用的清洁剂组合物含有非离子性表面活性剂时的非离子性表面活性剂的含量没有特别限定,例如,相对于清洁剂组合物的总量,清洁剂组合物中的非离子性表面活性剂的含量优选为0.01~10质量%,更优选为0.05~5质量%,进一步优选为0.1~3质量%。
清洁剂组合物含有非离子性表面活性剂时的清洁剂组合物中的非离子性表面活性剂的含量与单环己基甘油基醚的含量的比率没有特别限定,从起泡性和泡质的改善效果的观点考虑,单环己基甘油基醚的含量相对于非离子性表面活性剂的含量100质量份,优选为1~1000质量份,更优选为10~500质量份,进一步优选为20~300质量份。
本发明使用的清洁剂组合物中可含有的两性表面活性剂只要是在清洁剂组合物中通常使用的两性表面活性剂,就没有特别限定,例如可举出:咪唑啉系甜菜碱、烷基二甲氨基乙酸甜菜碱、脂肪酰胺丙基甜菜碱、磺基甜菜碱、烷基二甲基氧化胺等,可以含有这些中的1种或2种以上。从本发明效果的观点考虑,作为两性表面活性剂,优选使用包含选自月桂酰胺丙基甜菜碱、月桂基二甲氨基乙酸甜菜碱和月桂基羟基磺基甜菜碱中的至少1种的清洁剂组合物。本发明使用的清洁剂组合物含有两性表面活性剂时的两性表面活性剂的含量没有特别限定,例如,清洁剂组合物中的两性表面活性剂的含量相对于清洁剂组合物的总量,优选为0.01~15质量%,更优选为0.05~12质量%,进一步优选为0.1~10质量%。
清洁剂组合物含有两性表面活性剂时的清洁剂组合物中的两性表面活性剂的含量与单环己基甘油基醚的含量的比率没有特别限定,从泡质和起泡力的改善效果的观点考虑,单环己基甘油基醚的含量相对于两性表面活性剂的含量100质量份,优选为1~500质量份,更优选为2~300质量份,进一步优选为5~100质量份。
本发明使用的清洁剂组合物中可含有的溶剂只要是在清洁剂中通常使用的溶剂,就没有特别限定,但不包括水,例如可举出:乙醇、丙醇、异丙醇等,可以含有这些中的1种或2种以上。本发明使用的清洁剂组合物含有溶剂时的溶剂的含量没有特别限定,例如,相对于清洁剂组合物的总量,清洁剂组合物中的溶剂的含量优选为0.01~30质量%,更优选为0.1~20质量%。
作为本发明使用的清洁剂组合物中可含有的油性成分,只要是在清洁剂组合物中通常使用的油性成分,就没有特别限定,例如可举出:油脂(杏仁油、鳄梨油、牛油果油、葵花籽油、澳洲坚果油、羊毛脂、还原羊毛脂、貂油、可可脂、椰子油、棕榈油、棕榈仁油、氢化椰子油、氢化棕榈油、氢化棕榈仁油、山茶油、芝麻油、蓖麻油、橄榄油、大豆油、牛油、三癸酸甘油酯、三辛酸甘油酯、三辛酸甘油酯、三异硬脂酸甘油酯、三山萮酸甘油酯、三羟基硬脂酸甘油酯等)、烃油(异十二烷、异十六烷、液体石蜡、凡士林、角鲨烷、角鲨烯、微晶蜡、矿物油、氢化聚异丁烯、氢化聚癸烯、聚癸烯等)、酯油(癸酸鲸蜡酯、月桂酸己酯、肉豆蔻酸肉豆蔻酯、棕榈酸异硬脂酯、异硬脂酸异丙酯、油酸癸酯、肉豆蔻酸异丙酯、辛酸鲸蜡酯、乙基己酸鲸蜡酯、异壬酸辛酯、二甲基辛酸己基癸基酯、邻苯二甲酸二乙酯、间苯二甲酸二乙酯、己二酸二异硬脂酯、癸二酸二异丙酯、二硬脂酸乙二醇酯、二乙基己酸新戊二醇酯、羟基硬脂酸辛酯等)、高级醇(辛醇、癸醇、月桂醇、肉豆蔻醇、鲸蜡醇、异鲸蜡醇、硬脂醇、异硬脂醇、油醇、十六醇、辛基十二醇、癸基十四醇、十四烷基十八醇、十二烷基十六醇、己基癸醇、山萮醇)、硅油(二甲基聚硅氧烷、苯基聚三甲基硅氧烷、二苯基二聚甲基硅氧烷、二苯基甲硅烷氧基苯基聚三甲基硅氧烷、三甲基五苯基三硅氧烷、十甲基环五硅氧烷、八甲基环四硅氧烷、十二甲基环六硅氧烷、甲基聚三甲基硅氧烷、二甲基聚硅氧烷、十甲基四硅氧烷、乙基三硅氧烷等)等,可以含有这些中的1种或2种以上。本发明使用的清洁剂组合物含有油性成分时的油性成分的含量没有特别限定,例如,相对于清洁剂组合物的总量,清洁剂组合物中的油性成分的含量优选为0.01~30质量%,更优选为0.1~20质量%。
本发明使用的清洁剂组合物中可含有的增稠剂只要是在清洁剂中通常使用的增稠剂,就没有特别限定,例如可举出:海藻酸钙、普鲁兰多糖、琼脂、明胶、罗望子多糖类、黄原胶、卡拉胶、高甲氧基果胶、低甲氧基果胶、瓜尔胶、阿拉伯胶、结晶纤维素、阿拉伯半乳聚糖、刺梧桐树胶、黄蓍胶、褐藻酸、白蛋白、酪蛋白、凝胶多糖、β-葡聚糖、结冷胶、右旋糖酐、二甲基二烯丙基氯化铵聚合物(聚季铵盐-6)、二甲基二烯丙基氯化铵-丙烯酰胺共聚物、丙烯酰胺-丙烯酸-二甲基二烯丙基氯化铵共聚物、纤维素或其衍生物、角蛋白和胶原蛋白或它们的衍生物等,可以含有这些中的1种或2种以上。本发明使用的清洁剂组合物含有增稠剂时的增稠剂的含量没有特别限定,例如,清洁剂组合物中的增稠剂的含量相对于清洁剂组合物的总量,优选为0.01~10质量%,更优选为0.05~5质量%,进一步优选为0.1~3质量%。
本发明使用的清洁剂组合物中可含有的抗菌剂只要是在清洁剂中通常使用的抗菌剂,就没有特别限定,例如可举出:对羟基苯甲酸甲酯、对羟基苯甲酸乙酯、对羟基苯甲酸丙酯、对羟基苯甲酸丁酯、1,2-戊二醇、1,2-己二醇、1,2-辛二醇、水杨酸、苯甲酸钠、甲基氯异噻唑啉酮、甲基异噻唑啉酮、咪唑啉脲、苯扎氯铵、苄索氯铵、山梨酸、光敏剂等,可以含有这些中的1种或2种以上。本发明使用的清洁剂组合物含有抗菌剂时的抗菌剂的含量没有特别限定,例如,相对于清洁剂组合物的总量,清洁剂组合物中的抗菌剂的含量优选为0.01~10质量%,更优选为0.05~5质量%,进一步优选为0.1~3质量%。
本发明使用的清洁剂组合物中可含有的香料只要是在清洁剂中通常使用的香料,就没有特别限定,例如可举出:天然系香料(冬青油、橡苔树脂、乳香香树脂、橙油、合金欢油、小豆蔻油、胡萝卜籽油、樟木油、枯茗油、葡萄柚油、丁香油、芫荽油、香茅油、茉莉油、姜油、肉桂油、留兰香油、香叶油、百里香油、松油、罗勒油、欧芹籽油、薄荷油、香草精、罗汉柏叶油、扁柏油、胡椒油、胡椒薄荷油、香柠檬油、橘子油、桔子油、含羞草油、桉树油、柚子油、白柠檬油、薰衣草精油、柠檬油、玫瑰油、迷迭香油、月桂油、月桂叶油等)、合成香料(黄葵内酯、茴香醛、苯乙酮、甲基柏木酮、阿道克醛(adoxa1)、降龙涎香醚、戊基肉桂醛、水杨酸异戊酯、吲哚、紫罗兰酮、羟苯酮(oxyphenylone)、佳乐麝香、丁香烯、Santalex、肉桂醇、二甲基苄基甲醇、茉莉吡喃(jasmopyrane)、萜品醇、橙花醇乙酸酯、乙酸苯基乙酯、环十五内酯(pentalide)、乙酸邻叔丁基环己酯(verdox)、乙酸苄酯、苄醇、水杨酸苄酯、乙酸沉香醇酯(bergamyl acetate)、苯甲醛、甲酸苄酯、薄荷醇、甲基萘基酮、苯乙酸甲酯、覆盆子酮、柠檬烯、玫瑰苯酮(rose phenone)、大黄呋喃(rhubafuran)、玫瑰醚、香草醛等)等,可以含有这些中的1种或2种以上。本发明使用的清洁剂组合物含有香料时的香料的含量没有特别限定,例如,相对于清洁剂组合物的总量,清洁剂组合物中的香料的含量优选为0.01~3质量%,更优选为0.02~1质量%。
本发明使用的清洁剂组合物中可含有的保湿剂只要是在清洁剂中通常使用的保湿剂,就没有特别限定,例如可举出:二甘醇单乙基醚、脱氧核糖核酸、粘多糖类、透明质酸钠、硫酸软骨素钠、胶原蛋白、弹性蛋白、几丁质、壳聚糖、水解蛋壳膜等生物高分子,氨基酸、乳酸钠、尿素、吡咯烷酮羧酸钠、乳清等,可以含有这些中的1种或2种以上。本发明使用的清洁剂组合物含有保湿剂时的保湿剂的含量没有特别限定,例如,相对于清洁剂组合物的总量,清洁剂组合物中的保湿剂的含量优选为0.01~10质量%,更优选为0.05~5质量%,进一步优选为0.1~3质量%。
本发明使用的清洁剂组合物中可含有的螯合剂只要是在清洁剂中通常使用的螯合剂,就没有特别限定,例如可举出:EDTA、EDTA二钠、EDTA三钠、BDTA四钠、喷替酸盐、植酸盐、依替膦酸盐、草酸盐、多磷酸盐、偏磷酸盐、柠檬酸盐、丙氨酸、二羟乙基甘氨酸、葡糖酸、抗坏血酸、琥珀酸、酒石酸、乳酸、乙醇酸、琥珀酸、乙酸钠、苹果酸、酒石酸、富马酸、单乙醇胺、二乙醇胺、三乙醇胺、异丙醇胺、三异丙醇胺、2-氨基-2-甲基-1,3-丙二醇、2-氨基-2-羟甲基-1,3-丙二醇、精氨酸、氢氧化钠、氢氧化钾、氨水、碳酸胍、碳酸铵等,可以含有这些中的1种或2种以上。本发明使用的清洁剂组合物含有螯合剂时的螯合剂的含量没有特别限定,例如,相对于清洁剂组合物的总量,清洁剂组合物中的螯合剂的含量优选为0.01~5质量%,更优选为0.02~3质量%。
本发明使用的清洁剂组合物的制造方法没有特别限定,可以通过通常的清洁剂组合物的制造方法,例如将配合成分进行搅拌和混合等来制备。
本发明中,使清洁剂组合物起泡的方法没有特别限定,例如可举出如下方法:将清洁剂组合物以气溶胶状封入容器后吐出(喷出)而使用的方法;将液体或凝胶状的清洁剂组合物通过气溶胶型或非气溶胶型的泡沫吐出容器吐出成泡沫状而使用的方法;将清洁剂组合物以液体状或凝胶状从容器中吐出后,用手指等使之起泡而使用的方法等,可以根据目的和使用方式适当选定。
本发明中,清洁剂组合物的具体的使用形式没有特别限定,可举出:洗面奶、清洁剂、沐浴露、洗手液、洗发水、剃须膏、按摩霜等。从本发明效果的观点考虑,清洁剂组合物优选为皮肤用清洁剂组合物或毛发用清洁剂组合物。另外,本发明使用的清洁剂组合物的剂型只要是能够在使用时起泡使用的剂型,就没有特别限定,例如可举出:水溶液系、凝胶系、气溶胶系、水-油系乳剂(W/O型乳剂、O/W型乳剂、W/O/W型乳剂、O/W/O型乳剂)等。
上述清洁剂组合物的使用方法只要是在清洁时能够起泡使用的方法,就没有特别限定,可以根据使用目的或使用形式而适当制备。另外,清洁剂组合物在清洁时可以用水等稀释后使用,例如,可以用水稀释至2~1000倍使用。在将清洁剂组合物稀释的情况下,从清洁时的起泡力、泡质和清洁性的观点考虑,优选以如下方式稀释:使得稀释液中的单环己基甘油基醚的含量相对于所述稀释液的总量为0.001~1.0质量%。
另外,本发明的清洁方法是一种皮肤或毛发的清洁方法,其包括:将含有单环己基甘油基醚、阴离子性表面活性剂和水的清洁液在起泡的状态下应用于皮肤或毛发来清洁。此时的清洁液既可以将上述清洁剂组合物用水稀释而制备,也可以用另外的方式制备成清洁液。根据本发明,能够在使清洁液起泡时产生的泡沫的量(起泡性)和泡质提高的状态下清洁皮肤或毛发,因此能够期待清洁性和使用感的提高。此时,在使清洁液起泡的状态下清洁的具体方法没有特别限定,例如可举出如下方法:将清洁液以气溶胶状封入容器后吐出(喷出)而使用的方法;将液体或凝胶状的清洁液通过气溶胶型或非气溶胶型的泡沫吐出容器吐出成泡沫状而使用的方法;将清洁液以液体状或凝胶状从容器中吐出后,用手指等使之起泡而使用的方法等。从本发明效果的观点考虑,将液体或凝胶状的清洁液通过气溶胶型或非气溶胶型的泡沫吐出容器吐出成泡沫状而使用时的清洁液中的单环己基甘油基醚的含量优选为0.001~1.0质量%。另外,从本发明效果的观点考虑,优选将清洁液以液体状或凝胶状从容器中吐出后用手指等使之起泡而使用时的清洁液中的单环己基甘油基醚的含量相对于上述清洁液的总量为0.001~1.0质量%。
实施例
以下,通过实施例具体说明本发明。予以说明,在以下的实施例等中,只要没有特别说明,“%”为质量基准。
<清洁剂组合物的制备>
[实施例1]
以表1所示的配比(质量%)配合(混合)各成分,制备清洁剂组合物1。
[比较例1~4]
将清洁剂组合物1的单环己基甘油基醚变更为苯氧基乙醇(比较例1)、1,2-辛二醇(比较例2)、单乙基己基甘油基醚(比较例3),除此以外,以与实施例1相同的组成分别制备清洁剂组合物2、3和4。另外,作为比较例4,不配合单环己基甘油基醚,除此以外,以与实施例1相同的组成制备清洁剂组合物5。
[表1]
*聚氧乙烯(1~4)月桂基醚硫酸钠
<起泡性评价>
在制备的各清洁剂组合物6.6g中分别加入蒸馏水13.4g进行稀释,由此制备清洁液。接着,将各清洁液转移到家用MILLSER(岩谷产业株式会社制,IFM-620DG)的容器中后,以转速20,000次/分钟搅拌5秒钟使清洁液起泡。对各清洁液中产生的泡沫,目测观察从起泡起静置60秒后的泡沫的体积,基于上述MILLSER(搅拌机)的容器容量,测定起泡量。重复3次根据本方法的起泡量的测定,计算出其平均值。计算结果示于表2。
<泡质评价>
在制备的各清洁剂组合物13.3g中分别加入蒸馏水26.7g,制备清洁液。接着,将各清洁液转移到家用MILLSER(岩谷产业株式会社制,IFM-620DG)的容器中后,以转速20,000次/分钟搅拌10分钟使清洁液起泡。将各清洁液中产生的泡沫总量立即转移到50m1烧杯中,并在泡沫顶部静静地放置一枚1元硬币,然后测定从放置在泡沫顶部到1元硬币落到烧杯底面的时间。该时间(保持时间)越长,表示越能够长时间维持牢固且具有弹性的泡沫,可以说泡质优异。重复3次根据本方法的保持时间的测定,计算出其平均值。计算结果示于表2。
[表2]
在配合有单环己基甘油基醚的实施例1中,与未配合单环己基甘油基醚的比较例4相比,确认起泡性和泡质得到改善。这样的效果也明显优于使用苯氧基乙醇、1,2-辛二醇、单乙基己基甘油基醚代替单环己基甘油基醚的比较例1~3,通过配合单环己基甘油基醚,可以显著改善清洁剂组合物的起泡性和泡质。
Claims (9)
1.改善清洁剂组合物的起泡性和泡质的方法,包括配合单环己基甘油基醚、阴离子性表面活性剂和水。
2.权利要求1所述的方法,其中,所述清洁剂组合物中的所述单环己基甘油基醚的含量相对于该清洁剂组合物的总量,为0.01~10.0质量%。
3.权利要求1或2所述的方法,其中,所述清洁剂组合物中的所述阴离子性表面活性剂的含量相对于该清洁剂组合物的总量,为0.1~20.0质量%。
4.权利要求1~3任一项所述的方法,其中,所述单环己基甘油基醚的含量相对于所述阴离子性表面活性剂的含量100质量份,为1~1000质量份。
5.权利要求1~4任一项所述的方法,其中,所述阴离子性表面活性剂包含选自聚氧化烯烷基醚硫酸盐、聚氧化烯烷基苯基醚硫酸盐、聚氧化烯烷基醚羧酸盐和聚氧化烯烷基醚磷酸盐中的至少1种阴离子性表面活性剂。
6.权利要求1~5任一项所述的方法,其中,所述清洁剂组合物为皮肤用清洁剂组合物或毛发用清洁剂组合物。
7.皮肤或毛发的清洁方法,包括:
通过泡沫吐出容器吐出包含单环己基甘油基醚、阴离子性表面活性剂和水的清洁液以得到起泡的清洁液,和
将该起泡的清洁液涂布于皮肤或毛发。
8.权利要求7所述的皮肤或毛发的清洁方法,其中,所述清洁液中的所述单环己基甘油基醚的含量相对于该清洁液的总量,为0.001~1.0质量%。
9.单环己基甘油基醚的用于改善含有阴离子性表面活性剂和水的清洁剂组合物的起泡性和泡质的用途。
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WO2020066893A1 (ja) * | 2018-09-25 | 2020-04-02 | 株式会社Adeka | グリセリルエーテル含有組成物の製造方法およびグリセリルエーテル含有組成物 |
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JPWO2022014487A1 (zh) | 2022-01-20 |
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