CN1157511C - Softener composition - Google Patents
Softener composition Download PDFInfo
- Publication number
- CN1157511C CN1157511C CNB008026335A CN00802633A CN1157511C CN 1157511 C CN1157511 C CN 1157511C CN B008026335 A CNB008026335 A CN B008026335A CN 00802633 A CN00802633 A CN 00802633A CN 1157511 C CN1157511 C CN 1157511C
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- Prior art keywords
- alkyl
- group
- weight
- formula
- hydroxyalkyl
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Abstract
The purpose of the present invention is to provide a softener composition which suppresses for a long time body smell derived from sweat etc. and is excellent in the softening effect. That is, the present invention relates to a softener composition comprising:(a) a quaternary ammonium compound represented by the formula (1):wherein R<1 >and R<2 >independently represent a C12-22 alkyl or alkenyl group, X and Y are independently -COO-, -CONR<7>-, -OCO- or -NR<7>CO-, provided that at least one of X and Y is -COO- or -OCO-, R<7 >represents a hydrogen atom or a C1-3 alkyl or hydroxyalkyl group, R<3 >and R<4 >independently represent a C1-5 alkylene group, R<5 >and R<6 >represent a C1-3 alkyl or hydroxyalkyl group or R<1>-X-R<3>- and Z<-> is an anionic group,(b) a quaternary ammonium compound represented by the formula (2):wherein R<8 >represents a C12-22 alkyl or alkenyl group, W is a group selected from -COO-, -CONR<7>-, -OCO- and -NR<7>CO-, R<7 >represents a hydrogen atom or a C1-3 alkyl or hydroxyalkyl group, preferably a hydrogen atom, R<9 >represents a C1-5 alkylene group, R<10 >and R<11 >represent a C1-3 alkyl or hydroxyalkyl group, R<12 >represents a C1-3 alkyl group or -R<26>-OH, R<26 >is a C1-5 alkylene group and Z<-> is an anionic group, anda compound selected from the following component (c) or (d):(c) 0.1 to 15% by weight of a compound represented by the formula (3) and/or formula (4):wherein R<13>and R<18 >independently represent a C5-19 alkyl or alkenyl group, R<14 >and R<15 >independently represent a C1-3 alkyl or hydroxyalkyl group and T is -COO-, -OCO-, -CONH-, -NHCO-,or a linkage, R<16 >represents a C1-3 alkylene group, R<17 >represents a C<1-6 >alkylene group or -(O-R<19>)n-, R<19 >is ethylene group or propylene group and n is a number of 1 to 10 and W<-> is an anionic group, and(d) 0.01 to 15% by weight of a compound represented by the formula (5).
Description
Technical field
The present invention introduces a kind of softener composition.
Technical background
Before this, contain the quaternary ammonium salt of chain alkyl, the acid salt of tertiary amine etc. and be used to prepare softener always.And also tested antiseptic was added in the softener composition, to reach the purpose that makes fibre health, deodorizing.JP-A-10-512015 discloses a kind of softener composition, and said composition comprises a kind of water-insoluble quaternary ammonium salt as softener, and a kind of water miscible quaternary ammonium salt as antiseptic.In addition, JP-A7-3649 discloses a kind of softener composition of fibre, and said composition comprises two-chain alkyl (C
6-24Alkyl or alkenyl, wherein can have ehter bond, ester bond or amido link to separate) amine and mono-long chain alkyl (C
6-24Alkyl or alkenyl, wherein can have ehter bond, ester bond or amido link to separate) quaternary ammonium salt, both weight ratios are 9: 1～5: 5, the pH of composition is 2-5.WO98/56886 discloses a kind of antibiotic softening agent for fibres composition, said composition is applicable to gives the fiber anti-microbial property, it comprises softening agent for fibres composition commonly used and the cationic antibacterial agent more than a kind, and its consumption is more than making fiber have the necessary amount of anti-microbial property.But antibiotic soluble quaternary ammonium can reduce soft effect, therefore will obtain satisfied antibacterial effect, and its soft effect will inevitably be lost.The composition that particularly will obtain to have concurrently anti-microbial property and good soft effect is very difficult.Said anti-microbial property be meant can long term inhibition the peculiar smell that causes because of microorganism when drying clothes of room temperature and the body odor that produces because of sweat when wearing.
Summary of the invention
Thereby, the purpose of this invention is to provide a kind of softener composition, the body odor that its energy long term inhibition is caused by perspiration, and have good soft effect.
Softener composition of the present invention comprises:
(a) general formula is the quaternary ammonium compound of following (1) formula, and (b) general formula is the quaternary ammonium compound of following (2) formula, and the compound that is selected from following component (c) or component (d).
[R in the formula
1, R
2Represent C separately
12-22Alkyl or alkenyl; X, Y respectively do for oneself-COO-,-CONR
7-,-OCO-,-NR
7CO-, preferably at least X, Y one of them be-COO-,-OCO-, wherein R
7Expression hydrogen atom, C
1-3Alkyl or hydroxyalkyl; R
3And R
4C respectively does for oneself
1-5Alkylidene; R
5And R
6Be C
1-3Alkyl or hydroxyalkyl, or R
1-X-R
3-group; And Z
-Be anionic group],
[R in the formula
8Expression C
12-22Alkyl or alkenyl; W for be selected from-COO-,-CONR
7-,-OCO-and-NR
7The group of CO-, wherein R
7Be hydrogen atom, C
1-3Alkyl or hydroxyalkyl, be preferably hydrogen atom; In addition, R
9Be C
1-5Alkylidene; R
10And R
11Be C
1-3Alkyl or hydroxyalkyl; R
12Be C
1-3Alkyl or-R
26-OH group, wherein R
26Be C
1-5Alkylidene; Z
-Be anionic group],
(c) be the compound of following general formula (3) and/or general formula (4), its content is 0.1～15 weight %,
[R in the formula
13And R
18C respectively does for oneself
5-19Alkyl or alkenyl; R
14And R
15C respectively does for oneself
1-3Alkyl or hydroxyalkyl; T is-COO-,-OCO-,-CONH-,-NHCO-,
Or key; R
16Be C
1-3Alkylidene; R
17Be C
1-6Alkylidene or-(O-R
19)
n-group, wherein R
19Be ethylidene or propylidene, n is 1～10 integer; W
-Be anionic group],
(d) be the compound of following general formula (5), its content is 0.01-15 weight %, preferred 0.1～15 weight %
[R in the formula
20, R
21, R
22, R
23In 2 or 3 groups be C
8-12Alkyl, all the other groups are C
1-3Alkyl, C
1-3Hydroxyalkyl or total carbon atom number be the aralkyl of 7-15; Z
-Be anionic group].
Herein, said " key " is meant direct connection R
13And R
17Covalent bond.
Best mode for carrying out the invention
(a) of the present invention component is the compound of following general formula (1):
[R in the formula
1, R
2Represent C separately
12-22, preferred C
14-22, C more preferably
14-18Alkyl or alkenyl; X and Y respectively do for oneself and be selected from-COO-,-CONR
7-,-OCO-,-NR
7The group of CO-, preferably at least X and Y one of them be-COO-or-the OCO-group, preferred X and Y be-COO-or-CONR
7-, R wherein
7Expression hydrogen atom, C
1-3Alkyl or hydroxyalkyl; R
3And R
4C respectively does for oneself
1-5Alkylidene; R
5And R
6Be C
1-3Alkyl or hydroxyalkyl, or R
1-X-R
3-group; Z
-Be anionic group, Z
-Be preferably halide ion, sulfate ion, phosphate anion, C
1-3Alkyl sulfate ion, C
1-12The aliphatic acid ion].
Preferred especially following compounds is as (a) component.
[R ' and R " can be same to each other or different to each other and represent C
12-18Alkyl or alkenyl; R is C
1-3Alkyl or hydroxyalkyl; R " " is C
1-3Alkyl].
(b) of the present invention component is the compound of following general formula (2):
[R in the formula
8Expression C
12-22, preferred C
14-22, more preferably C
14-18Alkyl or alkenyl; W is-COO-,-CONR
7-,-OCO-,-NR
7CO-, preferred-COO-or-CONR
7-group, wherein R
7Be hydrogen atom, C
1-3Alkyl or hydroxyalkyl, be preferably hydrogen atom; In addition, R
9Be C
1-5Alkylidene; R
10, R
11Represent C separately
1-3Alkyl or hydroxyalkyl; R
12Be C
1-3Alkyl or-R
26-OH group, wherein R
26Be C
1-5Alkylidene; Z
-Be anionic group, preferred halide ion, aliphatic acid ion, C
1-3Alkyl sulfate ion].
(c) of the present invention component is the compound of above-mentioned general formula (3) or (4), and most preferred component (c) is an example with following compound, Z in the formula
-Meaning as previously mentioned.
(R is C
12-16Alkyl)
(R is C
6-10Alkyl, also can be the C of side chain
6-10Alkyl, m are the integer of 1-5)
(R is C
8-18Alkyl)
(d) of the present invention component is the compound of above-mentioned general formula (5), and in the general formula (5), the anionic group of representing with W-is preferably sulfate ion, halide ion, C
1-12Aliphatic acid ion or C
1-3Alkyl sulfate ion.
(softener composition)
In the softener composition of the present invention, (a) components contents is preferably 3-50 weight %, and more preferably 3-40 weight % is preferably 5-35 weight % especially.(b) components contents is 0.5-10 weight %, is preferably 0.5-5 weight %.In addition, consider that from soft effect and deodorizing effect (a) component/(b) weight ratio of component is preferably 80/20～99/1, is preferably 85/15～95/1 especially.
Component (c) is used for when of the present invention, and (c) components contents is 0.1-15 weight %, preferred 1-15 weight %, preferred especially 3-10 weight %.In addition, consider that (c)/(a) weight 1/30～1/1, preferred 1/10～1/1 from the feel and the deodorizing effect of cloth.Equally, component (d) is used for when of the present invention, considers from the feel and the deodorizing effect of cloth, (d) components contents is preferably 0.1-15 weight %, 0.2-10 weight % more preferably, and weight ratio (a)/(d) is 50/1～2/1, be preferably 30/1～2/1, more preferably 20/1～2/1.
Preferred softener composition of the present invention is the form of the aqueous solution, and this aqueous solution comprises (a) component of dilute with water and (b) component and (c) component or (d) component at least.Preferred used water is distilled water or deionized water.In addition, consider that from storage-stable the incorporation of water is 40-90 weight % in the composition, more preferably 50-85 weight % particularly preferably is 60-85 weight %.
Consider from deodorizing effect and storage-stable, preferably under 20 ℃ with the pH regulator of the present composition to 1-6, be more preferably and transfer to 2-5, especially preferably transfer to 2.5-4.
Consider that from storage-stable the present composition removes and adds above-mentioned (a) and (b), (c) and reach (d) the component, preferably mixes non-ionic surface active agent (e).Preferred nonionic is for containing 1 above C
8-20The polyoxyethylene alkyl ether of alkyl or alkenyl, special preferred formula is the non-ionic surface active agent of (6):
R
24-U-[(R
25O)p-H]q (6)
[R in the formula
24Be C
10-18, preferred C
12-18Alkyl or alkenyl; R
25Be C
2Or C
3Alkylidene, be preferably vinyl; P is the integer of 2-100, preferred 5-80, and 10-80 more preferably is preferably the integer of 20-60 especially; U is-O-,-CON-or-the N-group, U is-during O-, q is 1, U is-CON-or-during N-, q is 2].
General formula can be exemplified below for the object lesson of the compound of (6):
R
24-O-(C
2H
4O)r-H
[R in the formula
24Meaning as previously mentioned; When containing (c) component in the composition, r is the integer of 8-100, and when containing (d) component, r is 5-100, is preferably 10-80, more preferably the integer of 20-80].
R
24-O-(C
2H
4O)s(C
3H
6O)t-H
[R in the formula
24Meaning as previously mentioned.Respectively the do for oneself integer of 2-40 of s and t is preferably the integer of 5-40, and preferred s+t summation is the integer of 10-80, and ethylene oxide and propylene oxide chain link can be random addition products in the polymer, also can be the blocked addition products].
[R in the formula
24Meaning as previously mentioned, when containing (c) component in the composition, the summation of u and v is 5-100, when containing (d) component, is 10-80, is preferably the integer of 5-80].Consider that from stability the incorporation of above-mentioned non-ionic surface active agent is 0.5-10 weight %, is preferably 1-8 weight %.
In order to improve the feel of fiber product, the present invention preferably adds (f) C
8-22Aliphatic acid or its salt, addition is 0.1-5 weight %, especially preferably adds 0.5-3 weight %.That this aliphatic acid or its salt comprise is sad, capric acid, laurate, myristic acid, palmitic acid, stearic acid, oleic acid or its mixture.Preferred more than one are selected from the aliphatic acid of laurate, stearic acid, oleic acid especially.In addition, also preferred by coconut oil, palm oil, palmit seed oil or tallow fatty acid cpds that derive, that contain alkyl component.
Consider from storage-stable, in the composition of the present invention, preferably mix C
8-22The ester compounds of saturated or unrighted acid and polyalcohol, incorporation is 0.1-10 weight %, preferred especially incorporation is 0.5-5 weight %.Preferred ester type compound is single, two or three ester and the Isosorbide Dinitrates of triglycerides, diglyceride, monoglyceride, pentaerythrite.
In order to improve storage-stable, add inorganic salts in the present composition, as calcium chloride etc., addition is 0-1000ppm, is preferably 1-1000ppm, more preferably 10-500ppm.But, owing to contain sodium salt, sylvite in the surfactant such as soap, so be not subjected to above-mentioned restriction because of the inorganic salts that use this class surfactant to sneak in the composition.
In addition, in order to improve storage-stable, the present invention further preferably mixes solvent composition, and this solvent is selected from ethanol, isopropyl alcohol, glycerol, ethylene glycol, propylene glycol, diethylene glycol (DEG), dipropylene glycol, polyoxyethylene phenyl ether.The addition of solvent is preferably the 0-20 weight % of composition, 0.1-20 weight % more preferably, and particularly preferred addition is 0.5-10 weight %.In addition, if select ethanol for use, use the ethanol of polyoxyethylene alkyl ether sulfate modification, or the ethanol of 8-acetyl group sucrose modification is comparatively suitable.Be generally used for mixing the batching in the fibre finish, also can mix in the softener composition of the present invention as components such as siloxanes, spices (the preferred especially composition of forming by various flavor components, this flavor component is shown in the component (c) and component (d) of JP-A8-113871) or pigments.
Embodiment
＜furnish component 〉
The component that is used for the embodiment of the invention is as follows.
R:C
18With C
16Saturated alkyl (the C that mixes
18Group/C
16Group=60/40 weight ratio)
R:C
18With C
16Saturated alkyl (the C that mixes
18Group/C
16Group=60/40 weight ratio)
R:C
17With C
15Saturated alkyl (the C that mixes
17Group/C
15Group=60/40 weight ratio)
R:C
17With C
15Saturated alkyl (the C that mixes
17Group/C
15Group=60/40 weight ratio) (a-5) dioleoyl ethyoxyl dimethyl methyl ammonium sulfate
R:C
17With C
15Saturated alkyl (the C that mixes
17Group/C
15Group=60/40 weight ratio) (a '-1) two oil base alkyl dimethyl ammonium chlorides
R:C
18With C
16Saturated alkyl (the C that mixes
18Group/C
16Group=60/40 weight ratio)
R:C
17With C
15Saturated alkyl (the C that mixes
17Group/C
15Group=60/40 weight ratio)
(d-1) DDAC
(e-1) C
12The addition compound product of saturated alcohols and average 21 ethylene oxide molecules.
(e-2) addition compound product of lauric acid diethyl amide and average 20 ethylene oxide molecules.
(f-1) Le Na Star Network S-50 (stearic acid, KAO. Corp. SA produces)
(f-2) laurate
(f-3) myristic acid
(f-4) palmitic acid
(g-1) mixture of エ キ セ Le 150[stearic acid glycerine list, two and three esters (monoesters: diester: three esters=60: 35: 5) KAO. Corp. SA produces]
(g-2) calcium chloride
(g-3) ethylene glycol
(h-1) pigment (acid blue 9)
(h-2) spices [jasminolene (18) bromelia β-Nai Jiami (4), cyclacet (4), benzyl acetate (10), muskone (5), anisylacetone (2) but, the contract mixture of dicarbaldehyde (5), phenmethylol (5), dipropylene glycol (10) of wheat Sol santal (サ Application ダ Le マ イ Application-Le コ ア) (2), peach aldehyde C14 (1), linalool (18), Dihydromyrcenol 85 (8), borneol (4), cedrol (4), laurine, the numeral in the bracket is meant its percetage by weight in spice mixt].
(h-3) siloxanes (production of シ リ コ one Application company of TSA730 Toshiba)
Embodiment 1
With the softener composition shown in the above-mentioned compound table 1 (product 1-6 of the present invention and comparative product 1-3).Two sweat shirts (100% cotton) are cleaned (double barrels type washing machine VH-360S1 with commercially available weakly alkaline washing agent (production of ア Star Network KAO. Corp. SA) in washing machine, Toshiba produces, and detergent concentration 0.0667 weight % uses the 30L running water, 20 ℃ of water temperatures, wash time 10 minutes).Discharge washings, dehydration after 1 minute, injection 30L running water also washed 5 minutes, behind the venting water, dewatered 1 minute.And then inject the 30L running water, add the softener composition shown in the 5g table 1, stirs after 5 minutes and dewaters, with clothes be 70% in humidity, room temperature is 25 ℃ thermostatic chamber inner drying 12 hours.
(evaluation of softness)
With the softener composition shown in the table 1 and corresponding with it but do not add antibacterial components (c) or composition (d) carries out soft treatment as stated above, by 10 people groups composition is compared in pairs, by following standard evaluation, obtain mean value.
+ 1: wash softness of back clothes at last with containing component (c) or composition (d)
0: no matter with whether having component (c) or composition (d) to wash the soft degree indifference of back clothes at last
-1: wash softness of back clothes at last with no component (c) or composition (d).
(smell evaluation)
By following standard, to the smell of the clothes of thermostatic chamber inner drying, and the stink of this clothes after more than the 20 year old male sex 5 people are wearing 12 hours estimate, and tries to achieve mean value by 10 people groups (one's late 30s, the male sex 10 people).
0: almost can't smell stink
1: frowziness slightly, but less than irksome degree
2: frowziness
3: stink is obvious
Table 1
| Product of the present invention | Comparative product | |||||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 1 | 2 | 3 | 4 | |||
| Softener composition | Component ︵ weight % ︶ | (a-1) | 15 | 6 | 15 | |||||||
| (a-2) | 15 | |||||||||||
| (a-3) | 15 | 6 | ||||||||||
| (a-4) | 15 | |||||||||||
| (a-5) | 15 | 15 | 7.5 | |||||||||
| (c-1) | 5 | 5 | 5 | 5 | ||||||||
| (c-2) | 5 | 5 | ||||||||||
| (c-3) | 3 | 3 | ||||||||||
| (d-1) | 5 | 10 | ||||||||||
| (e-1) | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | ||||
| (e-2) | 2 | 2 | ||||||||||
| (f-1) | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | ||
| (g-1) | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | ||
| (g-2) | 100 ppm | 100 ppm | 100 ppm | 100 ppm | 100 ppm | 100 ppm | 100 ppm | 100 ppm | 100 ppm | 100 ppm | ||
| (g-3) | 3 | 3 | 3 | 3 | 3 | 3 | 3 | 3 | 3 | |||
| (b-1) | 1.5 | 1.5 | 0.5 | |||||||||
| (b-2) | 1.5 | 1.5 | 0.5 | |||||||||
| (h-1) | 10 ppm | 10 ppm | 10 ppm | 10 ppm | 10 ppm | 10 ppm | 10 ppm | 10 ppm | 10 ppm | 10 ppm | ||
| (h-2) | 50 ppm | 50 ppm | 50 ppm | 50 ppm | 50 ppm | 50 ppm | 50 ppm | 50 ppm | 50 ppm | 50 ppm | ||
| (h-3) | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |||
| Deionized water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | ||
| Add up to | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | ||
| pH(20℃) | 3.5 | 3.5 | 3.5 | 3.5 | 3.5 | 3.5 | 3.5 | 3.5 | 1 | 3.5 | ||
| Stink | Dried clothes | 0.6 | 0.4 | 0.6 | 0.6 | 0.4 | 0.6 | 1.3 | 1.4 | 1.5 | 1.2 | |
| Clothes after the dress | 1.1 | 1.0 | 1.2 | 1.1 | 1.0 | 1.2 | 1.4 | 1.7 | 1.7 | 1.5 | ||
| Softness | +0.2 | +0.1 | +0.1 | +0.2 | +0.1 | +0.1 | -0.3 | -0.4 | -0.5 | -0.2 | ||
*PH regulates with 0.1N aqueous sulfuric acid or 0.1N sodium hydrate aqueous solution.
Embodiment 2
Prepare the softener composition shown in the table 2 (product 7～11 of the present invention) with embodiment 1 same method.In addition, the spices in the table 2 be with the perfume composition in the table 3 of 100 parts of weight and 10 parts of weight-dipropylene glycol that contracts mixes the back and uses.Press the same mode of embodiment 1 to the softener composition evaluation, can be seen by its result, all products all present good smelly effect and the softness of pressing down.
Table 2
| Product of the present invention | |||||||
| 7 | 8 | 9 | 10 | 11 | |||
| Softener composition | Component ︵ weight ︶ % | (a-1) | 15 | 15 | 15 | ||
| (a-2) | 15 | 15 | |||||
| (c-1) | 3 | 3 | 3 | ||||
| (c-2) | 3 | 3 | |||||
| (e-1) | 2 | 2 | 2 | ||||
| (e-2) | 2 | 2 | |||||
| (f-1) | 1 | 1 | 1 | 1 | 1 | ||
| (g-1) | 1 | 1 | 1 | 1 | 1 | ||
| (g-2) | 100ppm | 100ppm | 100ppm | 100ppm | 100ppm | ||
| (b-1) | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | ||
| (h-1) | 10ppm | 10ppm | 10ppm | 10ppm | 10ppm | ||
| Spices (spices shown in the table 3) | Spices 1 0.37 | Spices 2 0.25 | Spices 3 0.3 | Spices 4 0.3 | Spices 5 0.3 | ||
| Deionized water | Surplus | Surplus | Surplus | Surplus | Surplus | ||
| Add up to | 100 | 100 | 100 | 100 | 100 | ||
| pH(20℃) | 3.5 | 3.5 | 3.5 | 3.5 | 3.5 | ||
*PH regulates with 0.1N aqueous sulfuric acid or 0.1N sodium hydrate aqueous solution.
Table 3
| Perfume composition (weight %) | Spices 1 | Spices 2 | Spices 3 | Spices 4 | Spices 5 |
| Hexyl cinnamon aldehyde | 0 | 0 | 13 | 0 | 0 |
| The bromelia β-Nai Jiami | 0 | 0 | 3 | 0 | 0 |
| Cyclacet | 0 | 0 | 3 | 0 | 0 |
| Benzyl acetate | 0 | 0 | 7 | 0 | 0 |
| Muskone | 0 | 0 | 3 | 0 | 0 |
| Anisylacetone | 0 | 0 | 1 | 0 | 0 |
| But wheat Sol santal | 0 | 0 | 1 | 0 | 0 |
| Peach aldehyde C14 | 0 | 0 | 1 | 0 | 0 |
| Irone-γ | 7 | 0 | 0 | 3 | 0 |
| イソイ-ス-パ-(Iso E super) | 7 | 0 | 0 | 3 | 0 |
| テンロ-ム(Tentarome ) | 14 | 0 | 0 | 7 | 0 |
| Acetate 4-tert-butyl group cyclohexyl | 14 | 0 | 0 | 7 | 0 |
| Lilial | 20 | 0 | 0 | 10 | 0 |
| ヘソオナ-ル(Herional) | 3 | 0 | 0 | 2 | 0 |
| Cumarin | 3 | 0 | 0 | 1 | 0 |
| アンブロキサン(Abroxan) | 1 | 0 | 0 | 0 | 0 |
| α-terpinyl acetate | 0 | 12 | 0 | 0 | 20 |
| Cedryl acetate | 0 | 8 | 0 | 0 | 13 |
| Lyral | 0 | 8 | 0 | 0 | 13 |
| Pearl acid anhydride (パ-Le ラ イ De) | 0 | 4 | 0 | 0 | 7 |
| The sandalidol | 0 | 4 | 0 | 0 | 7 |
| Phenyl acetaldehyde 50%PEA | 0 | 0 | 0 | 0 | 1 |
| Aldehyde C12MNA | 0 | 0 | 0 | 0 | 1 |
| Cinnamyl cinnamate | 0 | 2 | 0 | 0 | 3 |
| Benzylisoeugenol | 0 | 2 | 0 | 0 | 3 |
| Linalool | 0 | 0 | 0 | 0 | 13 |
| The dihydroxy myrcenol | 0 | 0 | 0 | 0 | 7 |
| Borneol | 0 | 0 | 0 | 0 | 3 |
| Cedrol | 0 | 0 | 0 | 0 | 3 |
| The laurine dicarbaldehyde that contracts | 0 | 0 | 0 | 0 | 3 |
| Phenmethylol | 0 | 0 | 0 | 0 | 3 |
| Benzyl carbinol | 12 | 0 | 29 | 0 | 0 |
| Citronellol | 6 | 0 | 13 | 0 | 0 |
| Terpineol | 6 | 0 | 13 | 0 | 0 |
| The phenethyl dimethylcarbinol | 3 | 0 | 7 | 0 | 0 |
| Phenylmethylcarbinol | 2 | 0 | 3 | 0 | 0 |
| Cinnamyl alcohol | 2 | 0 | 3 | 0 | 0 |
| The 1-menthol | 0 | 24 | 0 | 27 | 0 |
| The Mang geraniol | 0 | 12 | 0 | 13 | 0 |
| Dihydromyrcenol | 0 | 12 | 0 | 13 | 0 |
| Phenyl hexanol | 0 | 6 | 0 | 7 | 0 |
| Dimethyl benzyl carbinol | 0 | 6 | 0 | 7 | 0 |
| Add up to (weight %) | 100 | 100 | 100 | 100 | 100 |
Embodiment 3
With the softener composition shown in the above-mentioned compound table 4.5 shirts (100% cotton) and 5 towels (100% cotton) (the dress material gross weight is 1.5kg) are cleaned (double barrels type washing machine VH-360S1 with commercially available weakly alkaline washing agent (production of ア Star Network KAO. Corp. SA) in washing machine, Toshiba produces, detergent concentration 0.0667 weight %, use the 30L running water, 20 ℃ of water temperatures, wash time 10 minutes).Discharge washings, dewater after 1 minute, injection 30L running water also washed 5 minutes, behind the venting water, dewatered 1 minute.And then injecting the 30L running water, the composition 7ml of interpolation table 1 also stirred 5 minutes.Subsequent dewatering, air dry.
(evaluation of deodorizing effect)
Shirt after said method is handled was being worn 12 hours by more than 20 year old the male sex 5 people, after the dress, by 10 people groups (the one's late 30s male sex 10 people) bad smell of perspiration on the shirt was passed judgment on by following standard, tried to achieve mean value.Zero expression mean value is less than 0.8; represents that mean value is greater than 0.8, less than 1.2; △ represents that mean value is greater than 1.2, less than 1.7; * expression mean value is greater than 1.7, and evaluation result is shown in table 1.
0: almost can't smell stink
1: frowziness but less than irksome degree slightly
2: frowziness
3: stink is obvious
(evaluation of flexibility)
Towel of handling with said method and the composition of not using table 4, but use the towel (contrast) handled with quadrat method by 10 people groups (male sex 10 people of one's late 30s) by following standard judge, try to achieve mean value.Zero expression mean value is greater than 2; represents that mean value is greater than 1, less than 1.5; △ represents that mean value is greater than 0.5, less than 1; * expression mean value is less than 0.5, and evaluation result is shown in table 1.
+ 3: compare much soft in the same old way
+ 2: comparison is soft in the same old way
+ 1: comparison is soft slightly in the same old way
0: with to identical in the same old way
Table 4
| Furnish component (weight %) | Product of the present invention | Comparative product | |||
| 12 | 13 | 5 | 6 | ||
| Softener composition | a-3 | 12 | 12 | ||
| a-6 | 12 | ||||
| b-2 | 2 | 2 | |||
| a’-1 | 7.5 | ||||
| d-1 | 3 | 5 | 10 | 1 | |
| f-2 | 1 | ||||
| f-4 | 2 | ||||
| e-1 | 5 | 5 | 5 | ||
| e-2 | 5 | ||||
| g-2 | 100ppm | 100ppm | 100ppm | 100ppm | |
| h-1 | 10ppm | 10ppm | 10ppm | 10ppm | |
| h-3 | 0.3 | 0.3 | 0.3 | 0.3 | |
| PH regulator agent and deionized water | Surplus | Surplus | Surplus | Surplus | |
| pH * | 2.5 | 2.5 | 1 | 2.5 | |
| Add up to | 100 weight % | ||||
| (a)/(d) | 4.6/1 | 2.8/1 | 0.75/1 | 12/1 | |
| Stink is estimated | ○ | ○ | △ | □ | |
| Soft effect | ○ | ○ | × | □ | |
*PH regulates with 0.1N aqueous hydrochloric acid solution or 0.1N sodium hydrate aqueous solution.
Claims (3)
1. softener composition, it comprises:
(a) general formula is the quaternary ammonium compound of (1), and its content is 3-50 weight %;
R in the formula
1, R
2Represent C separately
12-22Alkyl or alkenyl; X, Y respectively do for oneself-COO-,-CONR
7-,-OCO-or-NR
7CO-, among X and the Y at least one be-COO-or-OCO-group, wherein R
7Expression hydrogen atom, C
1-3Alkyl or hydroxyalkyl; R
3, R
4C respectively does for oneself
1-5Alkylidene; R
5, R
6Be C
1-3Alkyl or hydroxyalkyl, or R
1-X-R
3-group; And Z
-Be anionic group,
(b) general formula is the quaternary ammonium compound of (2), and its content is 0.5-10 weight %;
R in the formula
8Expression C
12-22Alkyl or alkenyl; W for be selected from-COO-,-CONR
7-,-OCO-,-NR
7The group of CO-, wherein R
7Be hydrogen atom, C
1-3Alkyl or hydroxyalkyl, be preferably hydrogen atom; In addition, R
9Be C
1-5Alkylidene; R
10, R
11Be C
1-3Alkyl or hydroxyalkyl; R
12 areC
1-3Alkyl or-R
26-OH group, wherein R
26Be C
1-5Alkylidene; Z
-Be anionic group, (c) compound of the compound of following general formula (3) and/or general formula (4), its content is 0.1～15 weight %,
R in the formula
13, R
18C respectively does for oneself
5-19Alkyl or alkenyl; R
14, R
15C respectively does for oneself
1-3Alkyl or hydroxyalkyl; T is
Or singly-bound; R
16Be C
1-3Alkylidene; R
17Be C
1-6Alkylidene or-(O-R
19)
n-group, wherein R
19Be ethylidene or propylidene, n is 1～10; With W-be anionic group, and
(d) be the compound of following general formula (5), its content is 0.01-15 weight %,
R in the formula
20, R
21, R
22, R
23In 2 groups be C
8-12Alkyl, all the other groups are C
1-3Alkyl, C
1-3Hydroxyalkyl or total carbon atom number be the aralkyl of 7-15; And W
-Be anionic group.
2. the softener composition of claim 1, said composition also comprises non-ionic surface active agent (e).
3. claim 1 or 2 softener composition, said composition also comprises (f) C of 0.1-5 weight %
8-22Aliphatic acid or its salt.
Applications Claiming Priority (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP323180/1999 | 1999-11-12 | ||
| JP32318099 | 1999-11-12 | ||
| JP2000102428A JP3389549B2 (en) | 1999-11-12 | 2000-04-04 | Softener composition |
| JP102428/2000 | 2000-04-04 | ||
| JP102428/00 | 2000-04-04 | ||
| JP2000114097A JP3389550B2 (en) | 2000-04-14 | 2000-04-14 | Softener composition |
| JP114097/2000 | 2000-04-14 | ||
| JP114097/00 | 2000-04-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1336973A CN1336973A (en) | 2002-02-20 |
| CN1157511C true CN1157511C (en) | 2004-07-14 |
Family
ID=27339962
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB008026335A Expired - Fee Related CN1157511C (en) | 1999-11-12 | 2000-11-09 | Softener composition |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1154068B1 (en) |
| CN (1) | CN1157511C (en) |
| DE (1) | DE60027138T2 (en) |
| ES (1) | ES2260065T3 (en) |
| WO (1) | WO2001036737A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2134825A4 (en) * | 2007-03-13 | 2011-10-19 | Elementis Specialties Inc | Biodegradable cleaning compositions |
| JP5394215B2 (en) * | 2008-12-11 | 2014-01-22 | 花王株式会社 | Softener composition |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2928141A1 (en) * | 1979-07-12 | 1981-02-05 | Hoechst Ag | SOFT SOFTENER |
| JPH03287867A (en) * | 1990-03-30 | 1991-12-18 | Kao Corp | Flexibilizing finish |
| JP2970132B2 (en) * | 1991-10-04 | 1999-11-02 | ライオン株式会社 | Liquid softener composition |
| AU6271294A (en) * | 1993-03-01 | 1994-09-26 | Procter & Gamble Company, The | Concentrated biodegradable quaternary ammonium fabric softener compositions and compounds containing intermediate iodine value unsaturated fatty acid chains |
| US5399272A (en) * | 1993-12-17 | 1995-03-21 | The Procter & Gamble Company | Clear or translucent, concentrated biodgradable quaternary ammonium fabric softener compositions |
| JP3476608B2 (en) * | 1995-11-13 | 2003-12-10 | 花王株式会社 | Soft finish composition |
| IL121037A0 (en) * | 1997-06-09 | 1997-11-20 | Innoscent Ltd | Laundry fabric softener which inhibits bacterial growth and odor formation |
| JPH1161640A (en) * | 1997-08-06 | 1999-03-05 | Nof Corp | Softening agent composition |
-
2000
- 2000-11-09 CN CNB008026335A patent/CN1157511C/en not_active Expired - Fee Related
- 2000-11-09 ES ES00974874T patent/ES2260065T3/en not_active Expired - Lifetime
- 2000-11-09 DE DE60027138T patent/DE60027138T2/en not_active Expired - Lifetime
- 2000-11-09 EP EP00974874A patent/EP1154068B1/en not_active Expired - Lifetime
- 2000-11-09 WO PCT/JP2000/007897 patent/WO2001036737A1/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CN1336973A (en) | 2002-02-20 |
| ES2260065T3 (en) | 2006-11-01 |
| EP1154068A4 (en) | 2002-09-04 |
| EP1154068B1 (en) | 2006-04-05 |
| EP1154068A1 (en) | 2001-11-14 |
| DE60027138T2 (en) | 2006-12-28 |
| WO2001036737A1 (en) | 2001-05-25 |
| DE60027138D1 (en) | 2006-05-18 |
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