CN115531228A - Cosmetic composition for improving hair containing no siloxane - Google Patents
Cosmetic composition for improving hair containing no siloxane Download PDFInfo
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- CN115531228A CN115531228A CN202210740099.3A CN202210740099A CN115531228A CN 115531228 A CN115531228 A CN 115531228A CN 202210740099 A CN202210740099 A CN 202210740099A CN 115531228 A CN115531228 A CN 115531228A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
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Abstract
The present invention relates to a cosmetic composition for improving hair without using a silicon component, and more particularly, to a cosmetic composition for improving hair, which contains straight-chain or branched-chain type hydrocarbon, polyol derivative lubricant and carboxylic acid derivative lubricant as effective ingredients, thereby providing an excellent hair care effect of conventional silicone oils and is environmentally friendly.
Description
Technical Field
The present invention relates to a cosmetic composition for improving hair without using silicone oil.
Background
With the popularization of modern life patterns, external stimuli such as excessive combing, blow drying, frequent washing, or the penetration of chemicals are aggravating damage to the hair surface. Therefore, care products (for example, shampoo, conditioner, hair cream, hair treatment gel, etc.) which can prevent damage to hair and are excellent in hair quality, glossiness, and combability tend to increase.
Silicone oils are high molecular weight, have little viscosity change due to temperature change, are light and smooth, and can continuously impart gloss and luster when applied to hair or the like, and therefore, have been used as a raw material for cleansing agents and cosmetics.
However, as the results of continuous research indicate that silicone oil is an environmental pollutant harmful to biodiversity, europe prohibits the use of silicone oil for cleaning products, and the world shows a tendency to restrict the use of silicone oil. Further, when the silicon component is used in a hair cosmetic, the silicon component blocks pores, and when the silicon oil is used for a long time, the pores with active sebum secretion are blocked, so that sebum cannot be normally discharged, which causes the onset of head dermatitis, such as folliculitis.
[ Prior Art documents ]
[ patent literature ] A
Disclosure of Invention
Problems to be solved by the invention
In order to solve the above problems of the conventional art, the present invention provides a cosmetic composition for improving hair, which has excellent hair care effects of conventional silicone oils and is environmentally friendly.
Means for solving the problems
The cosmetic composition for improving hair of the present invention comprises: straight-chain or branched hydrocarbon having 6 to 30 carbon atoms; and a lubricant including one or more of a polyol derivative lubricant represented by the following chemical formulas 1 to 3 and a carboxylic acid derivative lubricant represented by the following chemical formulas 4 to 6.
[ chemical formula 1]
[ chemical formula 2]
[ chemical formula 3]
[ chemical formula 4]
[ chemical formula 5]
[ chemical formula 6]
In the above chemical formulas 1 to 6, the R a Each independently is H, alkyl with 1 to 20 carbon atoms, alkenyl with 3 to 20 carbon atoms or alkynyl with 3 to 20 carbon atoms, and R is b Each independently is H, hydroxyl, alkoxy with 1 to 20 carbon atoms, alkyl with 1 to 20 carbon atoms, alkenyl with 3 to 20 carbon atoms or alkynyl with 3 to 20 carbon atoms, and R is 1 And R 2 Each independently is H, alkyl with 1 to 20 carbon atoms or alkenyl or alkynyl with 3 to 20 carbon atoms, n is an integer from 1 to 4, m is an integer from 4 to 10, R 3 Each independently an organic substrate having a carbon number of 3 to 103.
Effects of the invention
The cosmetic composition for improving hair according to the present invention is completely free of silicone oil, is environmentally friendly, and does not cause a problem of residual silicon components on the scalp. When the shampoo is applied to hair and washed, the hair feels fresh and comfortable, and the hair is soft and smooth and is not frizzy. Can be used in hair growth perfume, hair care nutrient solution, hair conditioner essence, scalp conditioner, hair treatment cream, hair conditioner, shampoo, hair lotion, etc.
Drawings
Fig. 1 shows an Anti-scattering (Anti-frizz) effect achieved after the cosmetic compositions according to the examples of the present invention and the comparative examples were applied to the hair.
* Reference signs
Detailed Description
Hereinafter, examples of the present invention will be described in detail. It is to be understood, however, that this invention is not to be limited thereto, but only by the scope of the following claims.
In describing the present invention, if it is considered that detailed descriptions of related well-known configurations or functions may obscure the gist of the present invention, detailed descriptions thereof will be omitted.
The terms or words used in the specification and claims should not be construed as limited to general or dictionary meanings, but interpreted as meanings and concepts conforming to the technical idea of the present invention based on the principle that the concepts of the terms are properly defined to describe the invention in the most preferable way.
Further, the constitution shown by the embodiment and the preparation example described in the present invention is only the most preferable embodiment of the present invention, which does not represent the technical idea of the present invention, and therefore, it should be understood that various equivalents and modifications may be substituted therefor at the time of filing this application.
In the present specification, "" indicates the same or different atoms or moieties related to chemical formulas.
The cosmetic composition for improving hair of the present invention comprises a lubricant and hydrocarbon, but does not contain silicone oil.
The cosmetic composition can be applied to the hair, so that the hair becomes sticky and heavy if the solvent is not volatile after the cosmetic composition is applied. Therefore, the cosmetic composition of the present invention contains hydrocarbon as a solvent, has good volatility, and has strong solubility of a lubricant.
After the lubricant is uniformly applied to the hair, the hydrocarbon should be volatilized. Thus, the hydrocarbon is preferably a linear or branched hydrocarbon having 6 to 30 carbon atoms, more preferably a linear or branched hydrocarbon having 8 to 20 carbon atoms. When the carbon number of the hydrocarbon is less than 6, the volatility of the hydrocarbon is too high to uniformly apply the lubricant to the hair, and when the carbon number is 30 or more, the hydrocarbon solvent is not sufficiently volatilized after being applied to the hair and remains on the hair, which makes the hair greasy and sticky. In this case, when the carbon number of the hydrocarbon is 8 or more, the lubricant is more preferably dissolved, and when the carbon number of the hydrocarbon is 20 or less, the volatility is more excellent, and the feeling of use of the cosmetic composition can be further improved.
For example, the hydrocarbon may comprise one or more selected from the group consisting of: <xnotran> (Isododecane), (Undecane), (Isohexadecane), (Tridecane), (Isooctane), C10-11 (C10-11 Isoparaffin), C10-12 (C10-12 Isoparaffin), C10-13 (C10-13 Isoparaffin), C11-12 (C11-12 Isoparaffin), C11-13 (C11-13 Isoparaffin), C11-14 (C11-14 Isoparaffin), C12-14 (C12-14 Isoparaffin), C12-20 (C12-20 Isoparaffin), C13-14 (C13-14 Isoparaffin), C13-16 (C13-16 Isoparaffin), (Hydrogenated Polyisobutene), (Hydrogenated Polydecene) (C6-14 ) (Hydrogenated Poly ((C6-14 Olefin)), , : (Isododecane), (Undecane), (Tridecane) C13-16 (C13-16 Isoparaffin), , (Isododecane) , (silky) . </xnotran>
The cosmetic composition of the present invention moisturizes the scalp in order to improve damaged or frizzy hair, and comprises a lubricant in the hydrocarbon solvent. Specifically, the lubricant contains, as a lubricating ester, one or more of a polyol derivative represented by the following chemical formulae 1 to 3 and a carboxylic acid derivative represented by the following chemical formulae 4 to 6.
[ chemical formula 1]
[ chemical formula 2]
[ chemical formula 3]
[ chemical formula 4]
[ chemical formula 5]
[ chemical formula 6]
In the above chemical formulas 1 to 3, the R a Each independently is H, an alkyl group having 1 to 20 carbon atoms, an alkenyl group having 3 to 20 carbon atoms or an alkynyl group having 3 to 20 carbon atoms, preferably R a Each independently is H, an alkyl group having 1 to 10 carbon atoms, an alkenyl group having 3 to 10 carbon atoms, or an alkynyl group having 3 to 10 carbon atoms.
In the above chemical formulas 2 to 3, the R b Each independently is H, hydroxyl, alkoxy with 1 to 20 carbon atoms, alkyl with 1 to 20 carbon atoms, alkenyl with 3 to 20 carbon atoms or alkynyl with 3 to 20 carbon atoms, preferably R b Are respectively and independentlyIs H, hydroxyl, alkoxy with 1 to 10 carbon atoms, alkyl with 1 to 10 carbon atoms, alkenyl with 3 to 10 carbon atoms or alkynyl with 3 to 10 carbon atoms.
In the above chemical formulas 1 to 4, the R 1 And R 2 Each independently is H, a linear or branched alkyl group having 1 to 20 carbon atoms, or an alkenyl or alkynyl group having 3 to 20 carbon atoms.
In the above chemical formula 2, n is an integer of 1 to 4, and in the chemical formula 6, m is an integer of 4 to 10.
In the above chemical formulae 4 to 6, R 3 Each independently an organic substrate having a carbon number of 3 to 103. Specifically, the R is 3 May be one of the substituents represented by the following chemical formulas 7 to 9, respectively.
[ chemical formula 7]
[ chemical formula 8]
[ chemical formula 9]
In the above chemical formula 2, R 4 Is an alkoxy group containing one or more H, an alkyl group having 1 to 20 carbon atoms, or a double or triple bond having 4 to 20 carbon atoms, R c Each independently is H, methyl or hydroxy.
In the above chemical formulae 8 to 9, R 5 Each independently is H, hydroxyl, alkoxy having 1 to 20 carbon atoms, alkyl having 1 to 20 carbon atoms, alkenyl having 1 to 20 carbon atoms, or alkynyl having 1 to 20 carbon atoms.
In the above chemical formula 7, o is an integer of 0 to 13, and when o is 0, the structure is as the following chemical formula 7-1.
[ chemical formula 7-1]
In the above chemical formulas 8 to 9, p is each independently an integer of 1 to 10, and in the above chemical formula 9, q is an integer of 1 to 10.
The polyol derivative lubricant may be included in the lubricant, may be represented by the above chemical formulae 1 to 3, and specifically, for example, may include one or more selected from the group consisting of: propylene Glycol diethyl hexanoate (Propylene Glycol diethyl hexanoate), propylene Glycol Dipelargonate (Propylene Glycol Dipelargonate), glycerol tripentanoate (Tripentanoin), neopentyl Glycol Diheptanoate (Propylene Glycol Diheptanoate), neopentyl Glycol Dicaprate (Neopentyl Glycol Dicaprate), propylene Glycol Dicaprate (Propylene Glycol Dicaprate), propylene Glycol Dicaprylate (Propylene Glycol Dicaprate), propylene Glycol diethyl hexanoate (Propylene Glycol dihexyl hexanoate), glycerol triisooctanoate (triethanol), glycerol caprylate (Caprylic triglyceride), glycerol Capric triglyceride (Caprylic triglyceride), glycerol Capric triglyceride (Capric triglyceride) and glycerol Capric triglyceride (7) (preferably comprising one or more of the following PEG derivatives: propylene Glycol diethyl hexanoate (Propylene Glycol diethyl hexanoate), propylene Glycol Dipelargonate (Propylene Glycol Dipelargonate) and Neopentyl Glycol Diheptanoate (Neopentyl Glycol Diheptanoate).
Also, a carboxylic acid derivative lubricant may be included in the lubricant, may be represented by the above chemical formulae 4 to 6, and specifically, for example, may include one or more selected from the group consisting of: isoamyl Laurate (Isoamyl Laurate), isostearyl pivalate (Isoamyl Neopentanoate), cetyl Ethylhexanoate (Cetyl ethyl hexanoate), cocoyl decanoate (Coco-caproate), cocoyl octanoate (Coco-Caprylate), ethylhexyl Stearate (ethyl Hexyl Stearate), hexyl Laurate (Hexyl Laurate), dioctyl Carbonate (Dicaprylyl Carbonate), PEG-7Glyceryl Cocoate (PEG-7 Glyceryl Cocoate), hexyl decanoate (hexyllauryl Laurate), decyl Oleate (Decyl Oleate), dibutyl Adipate (Dibutyl Adipate), cetyl Palmitate (Cetyl Palmitate), octyl dodecanol Myristate (myristyl Palmitate), palmitic Palmitate (ethyl Hexyl Palmitate), and poly (2) acrylates, preferably selected from the group consisting of one or more of the following: isoamyl Laurate (Isoamyl Laurate), cetyl Ethylhexanoate (cethyl ethylhexoate), PEG-7Glyceryl Cocoate (PEG-7 Glyceryl Cocoate), and Cetyl Palmitate (cethyl palmate).
When the cosmetic composition of the present invention further comprises C12-15Alkyl benzoate (C12-15 Alkyl benzoate) as an additive, the hair care effect of the cosmetic composition is particularly excellent, and preferably, the specific content of the C12-15Alkyl benzoate is 0.1 to 3.0% by weight based on the total weight of the cosmetic composition. When the content of the C12-15alkyl benzoate is less than 0.1% by weight, the effect of the C12-15alkyl benzoate is very slight, and when the content exceeds 3.0% by weight, the hair becomes wet, greasy and sticky when used for hair care, and the consumer feels that the use feeling is poor.
The lubricant may comprise only one, preferably both, of the polyol derivative lubricant or the carboxylic acid derivative lubricant, in particular in a weight ratio of polyol derivative lubricant to carboxylic acid derivative lubricant of 1:35 to 35:1.
in the cosmetic composition of the present invention, when the ratio of the hydrocarbon to the lubricant is a specific condition as a solvent, the care effect is more excellent, and specifically, it is preferable that the hydrocarbon is contained in an amount of 60 to 90 wt% and the lubricant is contained in an amount of 10 to 40 wt% based on the total weight of the cosmetic composition, and it is more preferable that the hydrocarbon is contained in an amount of 60 to 85 wt% and the lubricant is contained in an amount of 10 to 35 wt% based on the total weight of the cosmetic composition.
The present invention will be further described below by way of preparation examples and experimental examples. The examples are intended to describe the invention in detail, and the scope of the invention is not limited by the examples.
[ preparation example: preparation of cosmetic composition
Examples 1 to 12 were prepared by mixing the components described in table 1 below, and comparative examples 1 to 6 were prepared by mixing the components described in table 2 below for comparison.
[ Experimental example 1: evaluation of Hair-Conditioning Effect
In order to evaluate the hair care effects of comparative examples 1 to 6 and examples 1 to 12, test hairs having a weight of 1.5g and a length of 100mm were taken out, friction was measured using a coefficient of friction tester (Neo-Tribo (FCMS 170)), and after the comparative examples 1 to 6 and examples 1 to 12 were uniformly applied to the same hairs, they were dried, and friction was measured using a coefficient of friction tester (Neo-Tribo (FCMS 170)) and reported in table 3 below.
The friction coefficient was repeatedly measured and the average value was determined by measuring 10 times, and the smaller the friction coefficient, the more excellent the hair care effect was.
[ TABLE 3]
| Coefficient of frictionAverage out | Deviation of coefficient of friction | |
| Untreated group | 0.353 | 0.010 |
| Comparative example 1 | 0.361 | 0.012 |
| Comparative example 2 | 0.334 | 0.006 |
| Comparative example 3 | 0.320 | 0.007 |
| Comparative example 4 | 0.308 | 0.013 |
| Comparative example 5 | 0.282 | 0.010 |
| Comparative example 6 | 0.242 | 0.013 |
| Example 1 | 0.207 | 0.010 |
| Example 2 | 0.132 | 0.007 |
| Example 3 | 0.112 | 0.005 |
| Example 4 | 0.104 | 0.004 |
| Example 5 | 0.070 | 0.021 |
| Example 6 | 0.076 | 0.033 |
| Example 7 | 0.087 | 0.020 |
| Example 8 | 0.089 | 0.024 |
| Example 9 | 0.096 | 0.018 |
| Example 10 | 0.091 | 0.011 |
| Example 11 | 0.076 | 0.004 |
| Example 12 | 0.083 | 0.018 |
It was confirmed that hair care was more effective than when oils composed of hydrocarbon were used (comparative examples 4 to 6, examples 1 to 12) as compared with silicone oils (comparative example 1), mineral oils (comparative example 2) or ethanol mainly used for cosmetics (comparative example 3) which were generally used for softening (softening) hair. In addition, ethanol or hydrocarbon has a problem of high volatility due to its low Boiling Point (BP), and therefore, has been remedied with a lubricant. When the hydrocarbon and the lubricant are mixed at an appropriate ratio, the hair care effect is remarkably excellent.
After confirmation by comparative example 4 and example 2, it was found that the lubricant was effective when the amount was maintained at a certain amount or more. It was confirmed by examples 2 to 4 that the inclusion of alkyl benzoate was found to result in a lower coefficient of friction and more effective care effect. It was confirmed from examples 5 to 7 that the hair care effect was more excellent when the carboxylic acid group derivative lubricant was contained than when the polyol derivative lubricant was contained.
[ Experimental example 2: evaluation of Hair growth Effect
To evaluate the hair growth effect, comparative examples 1 to 6 and examples 1 to 12 were applied to test hair samples, respectively, and allowed to dry.
After a certain light is irradiated to the hair sample and a gloss band (gloss band) appearing on the surface of the hair due to scattered light is photographed, the photographed image is analyzed and evaluated.
The gloss band (gloss band) is extracted from the captured image by the analysis program, and the pixel value of the area occupied by the gloss band (gloss band) in the total area is obtained and is shown in table 4 below.
An increase in the area of the gloss band (gloss band) indicates an increase in lightness.
[ TABLE 4]
| Gloss band area value (fixed number) | |
| Untreated | 1840 |
| Comparative example 1 | 2992 |
| Comparative example 3 | 2519 |
| Comparative example 4 | 2680 |
| Comparative example 6 | 2621 |
| Example 2 | 3090 |
| Example 3 | 3409 |
| Example 4 | 3473 |
| Example 5 | 3492 |
| Example 7 | 3184 |
| Example 8 | 3772 |
| Example 9 | 3955 |
| Example 10 | 4301 |
| Example 11 | 4322 |
| Example 12 | 4987 |
It was confirmed that comparative example 1 using silicone oil was more effective than the compositions of the other comparative examples, and the effect was close to that of the composition of example 2. However, the example compositions are more excellent in lightness than the comparative examples, and this procedure shows that the examples of the present invention are more excellent in hair growth effect than silicone oil even without using silicone oil.
[ Experimental example 3: comparison and evaluation of the greasy feel of the Hair
To evaluate the greasy feel, comparative examples 1 to 6 and examples 1 to 12 were each applied to a test hair sample and allowed to dry.
After 24 hours of standing, 10 groups were observed by visual evaluation and evaluated according to the following evaluation criteria, and the results thereof are shown in table 5 below.
Evaluation criteria
-very viscous; 1. slightly viscous; 2. generally; 3is appropriate; 4. is very suitable; 5. lower scores indicate a more greasy and viscous hair.
As shown in table 5 above, the hair of comparative example 2 using only mineral oil was the most greasy, and conventionally, silicone oil was generally used, showing good results. The compositions of the examples of the present invention, although no silicone oil was used, had a feeling of use similar to that of silicone oil or felt suitable.
[ Experimental example 4: evaluation of dyeing Retention
In order to evaluate the retention of comparative examples 1 to 6 and examples 1 to 12, hair dyes were uniformly applied to the hair samples for experiments, respectively, left for 40 minutes, applied with shampoo, rinsed with clear water, and dried by opening a blower.
After uniformly applying the compositions of examples 1 to 6 and examples 1 to 12 to the dried hair, ultraviolet rays were irradiated for 24 hours, and the color was measured by a color difference meter (hromameter CM 700).
The brightness values detected by the color difference meter (Chromameter CM 700) are shown in table 6 below, and the L value is compared as an index, where L + indicates bright, L-indicates dark, and the larger the L value, the brighter it. The larger Δ L (untreated value — treated value) indicates more serious discoloration, and the smaller Δ L indicates no color difference before and after the experiment, indicating that the color retention state is good.
[ TABLE 6]
| Brightness value | △L | |
| Untreated | 44.54 | - |
| Comparative example 1 | 40.93 | 3.61 |
| Comparative example 4 | 42.31 | 2.23 |
| Comparative example 5 | 41.37 | 3.17 |
| Comparative example 6 | 41.27 | 3.27 |
| Example 1 | 42.16 | 2.38 |
| Example 2 | 42.81 | 1.73 |
| Example 5 | 43.42 | 1.12 |
| Example 7 | 42.47 | 2.07 |
| Example 10 | 43.02 | 1.52 |
| Example 11 | 42.54 | 2.00 |
| Example 12 | 43.26 | 1.28 |
(Unit: L)
Comparative examples 4 to 6, examples 1 to 12 consisting of hydrocarbon and lubricant show more superior results in terms of color retention after dyeing than the silicone oil (comparative example 1) which is generally used. Also, the compositions of examples showed better results than the comparative examples in terms of color retention.
[ Experimental example 5: evaluation of the suppleness of frizzy hair (combing test)
To evaluate the softening effect of frizzy hair, comparative examples 1 to 6 and examples 1 to 12 were each applied evenly to each test hair sample (back combing) 5 times) and then allowed to dry.
The hair samples were combed until fully combed and the number of combing was measured and reported in table 7 below.
Less combing indicates less frizziness of the hair.
[ TABLE 7]
| Carding times (times) | |
| Untreated with | 21 |
| Comparative example 1 | 14 |
| Comparative example 4 | 18 |
| Comparative example 5 | 20 |
| Example 1 | 13 |
| Example 5 | 15 |
| Example 6 | 13 |
| Example 7 | 15 |
| Example 8 | 13 |
| Example 9 | 14 |
| Example 10 | 12 |
| Example 11 | 15 |
For combing of frizzy hair, the use of the composition of the comparative example or example is more effective than without treatment. The silicone oil used in general (comparative example 1) produced an effect superior to that of the other comparative example compositions. Also, the example composition of the present invention shows an effect similar to that of a silicone oil, although it does not employ a silicone oil.
[ Experimental example: anti-scatter (Anti-Fizz) evaluation)
In order to evaluate the scattering prevention (Anti-Fizz) of comparative examples 1 to 7 and examples 1 to 11, after the hair for experiment was treated with permanent wave, the hair was naturally dried and completely straightened by using a straightening splint, and the hair for experiment was prepared.
The experimental hair samples were evenly coated with the example and comparative compositions and allowed to dry.
After being placed in an incubation tank at a temperature of 40 ℃ to 45 ℃ and a humidity of 50% to 60% for 36 hours, the state of the hair was visually evaluated. Fig. 1 shows a photograph of individual hairs.
The less curly hair, the more excellent the Anti-scatter (Anti-Fizz) effect.
As shown in FIG. 1, the Anti-scatter (Anti-Fizz) effect of the example composition is better than that of the comparative example composition.
It was visually observed that comparative example 1 or comparative example 2 (not shown) seemed to be excellent in the Anti-scattering (Anti-Fizz) effect, but it was confirmed that the hair was oily and sticky.
The foregoing is merely illustrative of the present invention, and it is to be understood that the present invention may be implemented in various forms by those skilled in the art without departing from the essential characteristics of the invention. Therefore, the disclosed examples and experimental examples should not be considered in a limiting sense, but rather in an illustrative sense. The scope of the invention should be determined not by the above description but by the appended claims, and all features that are equivalent to them should be considered as falling within the scope of the invention.
Claims (10)
1. A cosmetic composition for improving hair comprising:
straight-chain or branched hydrocarbon having 6 to 30 carbon atoms; and
a lubricant comprising one or more of a polyol derivative lubricant represented by the following chemical formulae 1 to 3 and a carboxylic acid derivative lubricant represented by the following chemical formulae 4 to 6,
[ chemical formula 1]
[ chemical formula 2]
[ chemical formula 3]
[ chemical formula 4]
[ chemical formula 5]
[ chemical formula 6]
In the above chemical formulae 1 to 6,
said R is a Each independently is H, an alkyl group having 1 to 20 carbon atoms, an alkenyl group having 3 to 20 carbon atoms or an alkynyl group having 3 to 20 carbon atoms,
said R is b Each independently of the other, H, hydroxyl, alkoxy having 1 to 20 carbon atoms, alkyl having 1 to 20 carbon atoms, alkenyl having 3 to 20 carbon atoms or alkynyl having 3 to 20 carbon atoms,
the R is 1 And R 2 Each independently H, a carbon number of 1 to 20Linear or branched alkyl or alkenyl or alkynyl having 3 to 20 carbon atoms,
the n is an integer of 1 to 4,
the m is an integer of 4 to 10,
said R is 3 Each independently an organic matrix having a carbon number of 3 to 103.
2. The cosmetic composition for improving hair according to claim 1, characterized in that: the hydrocarbon comprises 60 to 90 wt% and the lubricant comprises 10 to 40 wt% of the total weight of the cosmetic composition.
3. The cosmetic composition for improving hair according to claim 1, characterized in that: the carbon number of the hydrocarbon is 8 to 20.
4. The cosmetic composition for improving hair according to claim 1, characterized in that: the hydrocarbon may comprise one or more selected from the group consisting of: isododecane (Isododecane), undecane (Undecanoe) Isohexadecane (Isohexadecane), tridecane (Tridecanoe), isooctane (Isooctane), C10-11 Isoparaffin (C10-11 Isoparaffin), C10-12 Isoparaffin (C10-12 Isoparaffin), C10-13Isoparaffin (C10-13 Isoparaffin), C11-12 Isoparaffin (C11-12 Isoparaffin), C11-13Isoparaffin (C11-13 Isoparaffin), C11-14Isoparaffin (C11-14 Isoparaffin), C12-14 Isoparaffin (C12-14 Isoparaffin), C12-20 Isoparaffin (C12-20 Isoparaffin), C13-14 Isoparaffin (C13-14 Isoparaffin), C13-16Isoparaffin (C13-16 Isoparaffin), and Hydrogenated Polyisobutene ((Hydrogenated Polyisobutene) (Hydrogenated C6-Hydrogenated Polyisobutene) (Hydrogenated isobutene).
5. The cosmetic composition for improving hair according to claim 1, characterized in that: the hydrocarbon is Isododecane (Isododecane).
6. The cosmetic composition for improving hair according to claim 1, characterized in that: the polyol derivative lubricant may comprise one or more selected from the group consisting of: propylene Glycol diethyl hexanoate (Propylene Glycol diethyl hexanoate), propylene Glycol Dipelargonate (Propylene Glycol Dipelargonate), glycerol tripentanoate (Tripentanoin), neopentyl Glycol Diheptanoate (Neopentyl Glycol Diheptanoate), neopentyl Glycol Dicaprate (Neopentyl Glycol Dicaprate), propylene Glycol Dicaprylate (Propylene Glycol Dicaprate), propylene Glycol diethyl hexanoate (Propylene Glycol Dicaprylate), glycerol triisooctanoate (triethanol), glycerol caprylate (Caprylic triglyceride), triglyceride (Capric triglyceride), triglyceride (Capric triglyceride), and glycerol 7/7 (Capric PEG).
7. The cosmetic composition for improving hair according to claim 1, characterized in that: the carboxylic acid derivative lubricant may comprise one or more selected from the group consisting of: isoamyl Laurate (Isoamyl Laurate), isostearyl pivalate (Isoamyl Neopentanoate), cetyl Ethylhexanoate (Cetyl ethyl hexanoate), cocoyl decanoate (Coco-caproate), cocoyl octanoate (Coco-Caprylate), ethylhexyl Stearate (ethyl Hexyl Stearate), hexyl Laurate (Hexyl Laurate), dioctyl Carbonate (Dicaprylyl Carbonate), PEG-7Glyceryl Cocoate (PEG-7 Glyceryl Cocoate), hexyl decanoate Laurate (hexyllauryl Laurate), decyl Oleate (Decyl Oleate), dibutyl Adipate (Dibutyl Adipate), cetyl Palmitate (Cetyl Palmitate), octyl dodecanol Myristate (myristyl Palmitate), ethylhexyl Palmitate (ethyl Hexyl Palmitate), and polyethylene glycol 2 (capryl-2).
8. The cosmetic composition for improving hair according to claim 1, characterized in that: the cosmetic composition further comprises C12-15Alkyl benzoate (C12-15 Alkyl benzoate).
9. The cosmetic composition for improving hair according to claim 8, characterized in that: the alkyl benzoate may be included in an amount of 0.1 to 3.0 wt% based on the total weight of the cosmetic composition.
10. The cosmetic composition for improving hair according to claim 1, characterized in that: the weight ratio of the polyol derivative lubricant to the carboxylic acid derivative lubricant is 1:35 to 35:1.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2021-0085265 | 2021-06-30 | ||
| KR1020210085265A KR20230003765A (en) | 2021-06-30 | 2021-06-30 | Silicone-free cosmetic composition for hair improvement |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115531228A true CN115531228A (en) | 2022-12-30 |
Family
ID=84723889
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210740099.3A Pending CN115531228A (en) | 2021-06-30 | 2022-06-28 | Cosmetic composition for improving hair containing no siloxane |
Country Status (2)
| Country | Link |
|---|---|
| KR (1) | KR20230003765A (en) |
| CN (1) | CN115531228A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011087976A1 (en) * | 2011-12-08 | 2012-08-23 | Henkel Ag & Co. Kgaa | Composition, useful for caring keratin fibers, comprises an isoparaffin comprising isodecane, isoundecane, isododecane, isotridecane or isotetradecane, an oil body and a specified range of water, in a carrier |
| EP2623088A2 (en) * | 2011-12-08 | 2013-08-07 | Henkel AG&Co. KGAA | Hair care product |
| DE102014213136A1 (en) * | 2014-07-07 | 2016-01-07 | Henkel Ag & Co. Kgaa | Isoparaffin-containing cosmetic agent |
| US20170112738A1 (en) * | 2014-07-07 | 2017-04-27 | Henkel Ag & Co. Kgaa | Cosmetic including isoparaffin |
-
2021
- 2021-06-30 KR KR1020210085265A patent/KR20230003765A/en not_active Application Discontinuation
-
2022
- 2022-06-28 CN CN202210740099.3A patent/CN115531228A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011087976A1 (en) * | 2011-12-08 | 2012-08-23 | Henkel Ag & Co. Kgaa | Composition, useful for caring keratin fibers, comprises an isoparaffin comprising isodecane, isoundecane, isododecane, isotridecane or isotetradecane, an oil body and a specified range of water, in a carrier |
| EP2623088A2 (en) * | 2011-12-08 | 2013-08-07 | Henkel AG&Co. KGAA | Hair care product |
| DE102014213136A1 (en) * | 2014-07-07 | 2016-01-07 | Henkel Ag & Co. Kgaa | Isoparaffin-containing cosmetic agent |
| US20170112738A1 (en) * | 2014-07-07 | 2017-04-27 | Henkel Ag & Co. Kgaa | Cosmetic including isoparaffin |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20230003765A (en) | 2023-01-06 |
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