CN1155297A - Granulation in a fluidised bed - Google Patents

Granulation in a fluidised bed Download PDF

Info

Publication number
CN1155297A
CN1155297A CN95194514A CN95194514A CN1155297A CN 1155297 A CN1155297 A CN 1155297A CN 95194514 A CN95194514 A CN 95194514A CN 95194514 A CN95194514 A CN 95194514A CN 1155297 A CN1155297 A CN 1155297A
Authority
CN
China
Prior art keywords
acid
parent
neutralizing agent
aforementioned
bulk density
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN95194514A
Other languages
Chinese (zh)
Other versions
CN1115403C (en
Inventor
S·V·达利维狄卡
V·R·达纽卡
N·D·密斯切
F·E·帕夏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever NV
Original Assignee
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever NV filed Critical Unilever NV
Publication of CN1155297A publication Critical patent/CN1155297A/en
Application granted granted Critical
Publication of CN1115403C publication Critical patent/CN1115403C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00Special methods for preparing compositions containing mixtures of detergents
    • C11D11/04Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

A process for the manufacture of detergent powders involving fluidizing a particulate material comprising a neutralizing agent, preferably in a fluid bed, contacting LAS acid with the fluidized material to effect neutralization and optionally adding a flow aid to the material either prior, during or subsequent to the addition of LAS acid is disclosed.

Description

Fluidized bed prilling
The present invention relates to the low detergent composition of a kind of bulk density (BD) and utilize dry neutralization to produce this method for compositions, also showed the application of fluidized-bed in producing this class detergent composition.
Be known in the art and adopt the spray drying method for preparation detergent powder.Yet this spray-drying process has the high shortcoming of the big energy consumption of investment, and is therefore more expensive with the product of this method gained.The special benefits of this method is that the pile of grounds density of production is low, is 350-600 g/l simultaneously.
4304062 of Henkel has been narrated a kind of detergent surfactant particulate production method, this method be in the granulating and drying case under high atmospheric pressure, with in the aqueous solution of alkali and the anion surfactant of acid type.In the method, the liquid parts with the hot-air dry nonsurfactant is a basic step.
Is known with dry neutralisation preparing washing agent powder in this area, but often obtains the high powder of bulk density in this way.Indian patent 166307 (Hindustan Lever Ltd) is mentioned a kind of special purpose of interior recirculation fluidisation bed, and obtains adopting conventional fluidized-bed that product is lumpd and thickness during the course.
Deutsches Wirtschafts Patent 140987 (VEB Waschmittelwerk) discloses a kind of method of continuous production granular detergent compositions, wherein be with liquid component for example the acid parent of nonionogenic tenside or anion surfactant be sprayed onto on pulverous washing assistant material, particularly second mutually on the tripoly phosphate sodium STPP (STPP) of content height (high phase II Content), be the product of 530-580g/l to produce bulk density.Yet, according to described Deutsches Wirtschafts Patent, this method be only limited to second mutually in the high STPP of content use.
English Patent 1404317 discloses utilizes dry neutralisation to prepare the low or medium detergent powder of bulk density.In the presence of the water of q.s, sulfonic acid is mixed with excessive SODA ASH LIGHT 99.2, so that the beginning neutralization reaction, but the used water yield is not enough to soak the product that gained is the free flowing powder last current state again.This method is at mixing device spiral blade stirrer for example, and planetary-type mixer or air are carried and carried out in the mixing tank.In mixing device, the fine-grannular detergent materials is stressed to be compressed, and this can make bulk density increase.
We have now found that, produce the low powder of bulk density with the acid parent of tensio-active agent in fluidized-bed, can avoid the shortcoming of prior art.
According to a first aspect of the invention, provide a kind of method of producing the low detergent composition of bulk density, this method comprises contacts the acid parent of anion surfactant with neutralizing agent in fluidized-bed, so that its neutralization, thereby preparing washing agent composition.
In second aspect, the invention provides a kind of method of producing the low fine-grannular detergent composition of bulk density, this method comprises that the fine particle materials of the detergent builder compound that will contain neutralizing agent and choose wantonly adds fluidization zone, make its fluidization, the liquid parent of anion surfactant is contacted with the fluidizing material, so that at least a neutralization part and preferably basically in and all acid sexupara body, contain the detergent particles of neutral parent acid to some extent thereby generate.
Preferred fluidization zone is provided by fluidized-bed.
According to a further aspect in the invention, provide a kind of method of producing the low fine-grannular detergent composition of bulk density, this method comprises:
I will contain washing assistant and neutralizing agent and fine particle materials and add fluidized-bed;
Ii is in time enough, and (LAS) adds this bed with linear alkylbenzene sulfonate, so that the part that neutralizes at least should acid, thereby obtains desired powder property.
The present invention also provides the detergent composition of the method preparation of defined in a kind of available claim.
As required, this method can be carried out with intermittence or successive operating method.Term used herein " detergent composition " comprises can for example SYNTHETIC OPTICAL WHITNER and enzyme mix the detergent of the product of producing full preparation with other common used material, and the another kind of detergent ingredients of so-called additive, they can be through further handling, produce a kind of subsequently can be as required and the detergent materials of other material mixing.
According to the present invention, this method has been showed the fluidization effect by neutralizing agent, makes the acid parent of its dry neutralize anionic surfactant, and preferably this method is carried out in fluidized-bed.Dry neutralisation be meant a neutralization part at least and preferably basically in and all acid sexupara body, mixture still keeps the particulate state simultaneously.The suitably adding of the acid parent of control is not accumulated in the detergent composition it with neutral condition not.
Suitable neutralizing agent is granuliform, and contains alkaline inorganic material, preferably contains basic salt.Suitable material comprises alkaline carbonate and supercarbonate, for example their sodium salt.
The suitable consumption of neutralizing agent with enough fully neutralizing acid sexupara body be as the criterion.If desired, can use neutralizing agent, to guarantee to neutralize fully or provide another kind of effect, for example in the clean effect of using under the yellow soda ash situation that increases above stoichiometric quantity.
Except anion surfactant by the neutralisation preparation, can add other anion surfactants in due course, or nonionic, positively charged ion, zwitter-ion, both sexes or semi-polarity tensio-active agent and composition thereof.Suitable tensio-active agent comprises those tensio-active agents of Schwarz and Perry general introduction in " tensio-active agent and washing composition " the 1st volume.Therefore, if desired, with containing C 12-C 15The soap saturated or that unsaturated fatty acids is produced of carbon atom also can be used as anion surfactant to be used.
The suitable consumption of detergent surfactant is the 5-40% (weight) of detergent composition, is preferably 12-30%.
Detergent composition is fit to contain detergent builder compound.Washing assistant can add simultaneously with neutralizing agent as required and/or add after adding neutralizing agent.Preferably washing assistant and neutralizing agent are added simultaneously.
Can use arbitrary washing assistant commonly used, suitable washing assistant comprises the calcite of yellow soda ash, zeolite, tripoly phosphate sodium STPP (STPP), Trisodium Citrate and/or high surface area.Washing assistant also can mix by individually a kind of in the above-mentioned washing assistant or with other washing assistant and form.
Washing assistant and neutralizing agent can be commaterials, yellow soda ash for example, and in this case, the quantity of material of use should enough play this two kinds of effects.
The suitable consumption of washing assistant is the 15-65% (weight) of detergent composition, and is preferably 15-50%.
Detergent powder prepared in accordance with the present invention has suitably low bulk density, is 350-650g/l or 450-650g/l, and is for example, about 500g/l, therefore equally matched with the bulk density that utilizes spray-drying process to obtain.
With a kind of optional adding in the composition with preferred flow promotor.Can before or after adding part or all acid parent, flow promotor be mixed with neutralizing agent and washing assistant (if the work that has).Before or after adding a part of acid parent, add flow promotor, thereby the bulk density of product powder is obviously descended.
The suitable consumption of flow promotor is the 0.1-15% (weight) of detergent composition, and preferred consumption is 0.5-5%.
Suitable flow promotor comprises crystalline form or amorphous alkali metal silicate, calcite, diatomite, silicon-dioxide, for example sedimentary silicon-dioxide, sal epsom and lime carbonate, for example sedimentary lime carbonate.Can adopt these mixtures of material as required.In preferred embodiments, flow promotor is Dicamol.
Said composition also can contain granuliform weighting agent, and weighting agent is fit to comprise inorganic salt, for example sodium sulfate and sodium-chlor.The consumption of weighting agent is the 5-50% (weight) of composition.
Detergent composition produced according to the invention is fit to contain detergent surfactant and washing assistant, and one or more optional flow promotors, weighting agent and other composition, for example dyestuff, spices, fluorescent bleaches, SYNTHETIC OPTICAL WHITNER and enzyme on a small quantity.
We find that also the raw material of selecting to have the certain particle size characteristic can make bulk density obviously descend.
The suitable size-grade distribution of granulate material is that granularity is no more than 5% (weight) greater than the particle of 250 μ.Also preferred size is at least 30% (weight) less than the particle of 75 μ.The mean particle size that fine particle materials suits is less than 200 μ, so that provide the bulk density of special needs low detergent powder.
If desired, can add a certain amount of water, be beneficial to neutralization.The water yield that adds can be the 0.5-2% (weight) of finished product detergent composition.These water added before adding acid parent, or added simultaneously with acid parent, or alternately added with acid parent and all to suit.
Granulate material is added fluidized-bed by rights, add the LAS acid of aequum then, preferably it is sprayed onto on the described material, and preferably adds from the top.If flow promotor is arranged, can add with raw material.But, preferably after adding a part of LAS acid, add flow promotor, so that obtain lower bulk density.
Fluidized-bed is adapted at room temperature to 60 ℃ operation down.It is enough big that air velocity is wanted, so that cause fluidization, and is preferably 0.6-1ms -1Because the fluidization of solid material helps neutralization and granulation, particle is discharged, so the fluidization of solid material is an essential characteristic of the present invention.This is opposite with mixing process, in mixing process, has a mind to make particle to contact with each other and push, and this can cause the bulk density of powder to increase and degradation.
By following non-limiting examples explanation the present invention.Embodiment 1-19
Pulverous washing assistant/inorganic alkaline material (in embodiment 1-4, yellow soda ash plays two kinds of effects) and weighting agent are added fluidized-bed, and make its fluidization by operation under greater than the apparent air velocity of minimum fluidization velocity.The temperature of fluidized-bed is a room temperature to 60 ℃.Linear alkyl benzene sulphonic acid (LAS acid) is sprayed onto on the powder mixture in the fluidized-bed.
The relative quantity of each composition changes in the composition, and lists in the table 1 below.
Embodiment 1-3 explanation in the method, adds the influence of flow promotor (using Dicamol here) in composition in the different time.In embodiment 1, do not add flow promotor in the material.In embodiment 2, before adding LAS acid, in raw material, add flow promotor.In embodiment 3, after the LAS acid of adding 50%, add flow promotor.It is favourable that fine-graded granulated material is adopted in embodiment 4 explanations.These the results are shown in the following table 1.
Table 1
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
LAS ?????17 ?????17 ?????17 ??????1
SODA ASH LIGHT 99.2 ?????30 ?????30 ?????30 ?????30
Dicamol ?????- ?????2 * ?????2 ** ?????2 **
Salt ?????45 ?????43 ?????43 ??????-
Fine salt ?????- ?????- ?????- ?????43
BD(g,/L) ????687 ????625 ????603 ????546
DFR(ml/sec) ????85.72 ???96.77 ????88.23 ????93.8
aROD(%) ????81.6 ???80.6 ????82.3 ????82.5
The a dissolution rate
*When beginning, add Dicamol
*After the LAS of adding 50%, add Dicamol
The measuring method of powder dissolution rate is: by concentration is 1.4%, and powder is joined in the 1L water, stirs and measures the electricity of solution and lead under 100rpm, up to stable reading.Listed numeral means the dissolution rate of powder behind about 90sec.
Embodiment 2 and 3 explanations added flow promotor before or after adding a part of LAS acid can make bulk density obviously descend.
Embodiment 5-19 is according to the method for the described embodiment of being used for 1-4 and adopts the various feedstock production with different grain size distribution that other powder, its details are listed among the following table 3-5.Table 2 has been summarized the size-grade distribution of various materials.
Table 2
Various raw material properties
Size-grade distribution SODA ASH LIGHT 99.2 ???Na 2SO 4 Salt Fine salt ?????STPP
(μ) ?????????????????????????????????%wt
>500 ????1.8 ????0.12 ????1.78 ????1.00 ?????0.94
500-250 ????2.06 ????0.60 ????80.40 ????1.26 ?????1.40
250-150 ????6.52 ????21.90 ????14.80 ????10.02 ?????6.86
150-100 ????26.20 ????55.14 ????2.88 ????21.80 ?????24.88
100-75 ????16.20 ????8.56 ????0.14 ????24.07 ?????7.92
<75 ????47.14 ????13.68 ?????- ????36.83 ?????58.00
Mean particle size (μ) ????92.7 ????138.2 ????360.30 ????112.5 ?????85.7
BD,g/l ????508 ????1,347 ????1,070 ?????997 ?????649
DFR,ml/sec Do not flow ????83.33 ????142.85 Do not flow Do not flow
Table 3
Embodiment ??????5 ?????6 ?????7 ?????8 ?????9 ?????10
LAS,% ?????17.0 ????20.0 ????23.0 ????23.7 ????25.0 ????27.1
Moisture, % ?????6.8 ????6.0 ????4.8 ????6.0 ????4.5 ????5.1
STPP,% ?????35.0 ????22.0 ????35.0 ????35.0 ????25.0 ????25.0
SODA ASH LIGHT 99.2, % ?????22.0 ????20.0 ????22.0 ????22.0 ????20.0 ????20.0
Fine salt, % ??????- ????30.0 ?????- ?????- ????16.0 ????15.0
Alkaline silicate, % ??????- ?????- ?????- ?????- ?????- ????1.0
Bulk density, g/L ?????500 ????510 ????500 ????490 ????500 ????495
?DFR,ml/sec ?????100 ????120 ????120 ????120 ????100 ?????88
Table 4
Embodiment ????11 ????12 ?????13 ????14 ????15
LAS acid, % ???28.5 ???28.7 ????29.13 ????29.6 ???31.1
Moisture, % ???4.5 ???6.7 ?????6.2 ????7.4 ????6.8
STPP,% ???25.0 ???35.0 ?????25.0 ????35.0 ???35.0
SODA ASH LIGHT 99.2, % ???20.0 ???22.0 ?????20.0 ????22.0 ???22.0
Fine salt, % ???16.0 ????- ??????- ?????- ?????-
Na 2SO 4,% ????- ????- ?????16.0 ?????- ?????-
Bulk density, g/L ???514 ????470 ?????510 ????500 ????520
DFR,ml/sec ???120 ????100 ?????88 ????102 ????115
Table 5
Embodiment ?????16 ?????17 ?????18 ?????19
LAS,% ????17.0 ????17.0 ????17.0 ????13.0
Soap, % ??????- ??????- ??????- ?????4.0
SODA ASH LIGHT 99.2, % ????22.0 ????30.0 ????35.0 ????20.0
STPP,% ????35.0 ??????- ??????- ????35.0
The calcite on high surface, % ??????- ??????- ????16.0 ??????-
Moisture, % ?????6.8 ?????3.5 ?????3.0 ?????4.0
BD,g/L ?????500 ?????530 ?????480 ?????500
DFR,ml/sec ?????100 ?????100 ?????120 ?????150
Table 3 and table 4 illustrate the result of the STPP washing assistant powder of the tensio-active agent that contains 17-31%.As shown in table 2, SODA ASH LIGHT 99.2 and STPP have similar size-grade distribution and make the product of bulk density near 500g/l based on some prescriptions of these builder systems.Table 5 illustrates based on various builder systems, i.e. the powder of STPP, SODA ASH LIGHT 99.2 and high surface area calcite.Make the powder that bulk density is about 500g/l with SODA ASH LIGHT 99.2 and these two washing assistant prescriptions of STPP, and make the powder that bulk density is lower than 500g/l based on the prescription of high surface area calcite.Embodiment 19 relates to a mixed surfactant system that contains 13%LAS acid and 4% soap, and makes the powder that bulk density is 500g/l.

Claims (10)

1. method of producing the low detergent composition of bulk density, this method comprises makes the acid parent of anion surfactant contact in fluidized-bed with neutralizing agent, so that neutralize this parent, thereby makes detergent composition.
2. method of producing the low fine-grannular detergent composition of bulk density, this method comprises that the fine particle materials of the detergent builder compound that will contain neutralizing agent and choose wantonly adds fluidization zone, make its fluidization, the liquid parent of anion surfactant is contacted with this fluidizing material, so that at least a neutralization part and preferably basically in and all acid sexupara body, contain the detergent particles of neutral parent acid to some extent thereby generate.
3. method of producing the low fine-grannular detergent composition of bulk density, this method comprises:
The fine particle materials that i. will contain washing assistant and neutralizing agent adds fluidized-bed;
Ii. in time enough, (LAS) adds this bed with linear alkylbenzene sulfonate, so that the part that neutralizes at least should acid, thereby obtains desired powder property.
4. according to each method in the aforementioned claim, wherein neutralizing agent comprises alkaline inorganic material, preferred alkali metal carbonate.
5. according to each method in the aforementioned claim, comprising the method that adds one or more mobile washing assistants, add-on is the 0.1-15% (weight) of composition.
6. according to each method in the aforementioned claim, wherein flow promotor is adding after adding a part of acid parent.
7. according to each method among the claim 1-5, wherein flow promotor is to add before adding acid parent.
8. according to each method in the aforementioned claim, wherein flow promotor is one or more dicamol, crystalline or unbodied alkaline silicate, calcite, diatomite, sedimentary silicon-dioxide, sal epsom.
9. according to each method in the aforementioned claim, wherein the size-grade distribution of neutralizing agent and other material granule is, granularity greater than the particle of 250 μ m be no more than 5% and granularity less than the particle of 75 μ m greater than 30%.
10. adopt according to each method, the detergent composition that can prepare or its composition in the aforementioned claim.
CN95194514A 1994-08-05 1995-07-24 Granulation in a fluidised bed Expired - Fee Related CN1115403C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9415904A GB9415904D0 (en) 1994-08-05 1994-08-05 Process for the production of detergent composition
GB9415904.3 1994-08-05

Publications (2)

Publication Number Publication Date
CN1155297A true CN1155297A (en) 1997-07-23
CN1115403C CN1115403C (en) 2003-07-23

Family

ID=10759488

Family Applications (1)

Application Number Title Priority Date Filing Date
CN95194514A Expired - Fee Related CN1115403C (en) 1994-08-05 1995-07-24 Granulation in a fluidised bed

Country Status (13)

Country Link
EP (1) EP0775193A1 (en)
CN (1) CN1115403C (en)
AU (1) AU702808B2 (en)
BR (1) BR9508505A (en)
CA (1) CA2195313A1 (en)
CZ (1) CZ289884B6 (en)
GB (1) GB9415904D0 (en)
HU (1) HU222907B1 (en)
PL (1) PL181161B1 (en)
SK (1) SK282576B6 (en)
TW (1) TW380161B (en)
WO (1) WO1996004359A1 (en)
ZA (1) ZA956415B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1094383C (en) * 1998-09-11 2002-11-20 自贡市化工研究设计院 Spraying-fluidized bed prilling method for precipitation of hydrated silicon dioxide

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9526097D0 (en) * 1995-12-20 1996-02-21 Unilever Plc Process
TW397862B (en) * 1996-09-06 2000-07-11 Kao Corp Detergent granules and method for producing the same, and high-bulk density detergent composition
US6211137B1 (en) 1996-10-04 2001-04-03 The Procter & Gamble Company Process for making a detergent composition by non-tower process
US6136777A (en) * 1996-10-04 2000-10-24 The Procter & Gamble Company Process for making a detergent composition by non-tower process
US6391844B1 (en) 1996-10-04 2002-05-21 The Procter & Gamble Company Process for making a detergent composition by non-tower process
US6211138B1 (en) 1996-10-04 2001-04-03 The Procter & Gamble Company Process for making a detergent composition by non-tower process
US6150323A (en) * 1996-10-04 2000-11-21 The Procter & Gamble Company Process for making a detergent composition by non-tower process
US6121229A (en) * 1996-10-04 2000-09-19 The Procter & Gamble Company Process for making a detergent composition by non-tower process
US6143711A (en) * 1996-10-04 2000-11-07 The Procter & Gamble Company Process for making a detergent composition by non-tower process
US6172034B1 (en) 1996-10-04 2001-01-09 The Procter & Gamble Process for making a detergent composition by non-tower process
GB9712580D0 (en) * 1997-06-16 1997-08-20 Unilever Plc Production of detergent granulates
GB9712587D0 (en) * 1997-06-16 1997-08-20 Unilever Plc Production of detergent granulates
GB9712583D0 (en) 1997-06-16 1997-08-20 Unilever Plc Production of detergent granulates
GB9713748D0 (en) * 1997-06-27 1997-09-03 Unilever Plc Production of detergent granulates
US6258773B1 (en) 1997-07-14 2001-07-10 The Procter & Gamble Company Process for making a low density detergent composition by controlling agglomeration via particle size
DE69838293D1 (en) * 1997-07-14 2007-10-04 Procter & Gamble METHOD FOR PRODUCING LASER BULK DUST DETERGENT BY CONTROLLING AGGLOMERATION IN A SWABILITY DRYER
ATE266084T1 (en) 1997-07-15 2004-05-15 Procter & Gamble METHOD FOR PRODUCING HIGHLY CONCENTRATED DETERGENT AGGLOMERATES BY MULTI-STEP INJECTION OF SURFACTANT PASTES
US6440342B1 (en) 1998-07-08 2002-08-27 The Procter & Gamble Company Process for making a low density detergent composition by controlling nozzle height in a fluid bed dryer
WO2000024863A1 (en) 1998-10-26 2000-05-04 The Procter & Gamble Company Processes for making granular detergent composition having improved appearance and solubility
GB9825563D0 (en) 1998-11-20 1999-01-13 Unilever Plc Particulate laundry detergent compositions containing anionic surfactant granules
DE19855380A1 (en) * 1998-12-01 2000-06-08 Henkel Kgaa Granulation process
DE19859778A1 (en) 1998-12-23 2000-06-29 Henkel Kgaa Multi-phase cleaning agent with naphthalenesulfonic acid-formaldehyde condensate
MXPA01009857A (en) 1999-03-30 2002-05-06 Unilever Nv Detergent powder composition.
GB9927653D0 (en) 1999-11-22 2000-01-19 Unilever Plc Process for preparing granular detergent compositions
GB0119708D0 (en) * 2001-08-13 2001-10-03 Unilever Plc Process for the production of detergent granules
GB0119711D0 (en) * 2001-08-13 2001-10-03 Unilever Plc Process for the production of detergent granules
DE102005005499A1 (en) * 2005-02-04 2006-08-17 Henkel Kgaa Process for the preparation of detergents or cleaners
EP2123742A1 (en) 2008-05-14 2009-11-25 The Procter and Gamble Company A solid laundry detergent composition comprising light density silicate salt

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3425948A (en) * 1966-01-03 1969-02-04 Wyandotte Chemicals Corp Composition and process for light-weight surfactant products
ZA72295B (en) * 1971-02-01 1973-09-26 Colgate Palmolive Co Method for neutralization of detergent acid
GB1404317A (en) * 1971-10-23 1975-08-28 Bell Chemicals Pty Ltd Manufacture of detergent powders
DD140987B1 (en) * 1979-01-05 1982-06-30 Manfred Mittelstrass CONTINUOUS MANUFACTURING METHOD GRANULATED WASHING AND CLEANING AGENT IN SWIVEL LAYERED APPARATUS
RO88903A2 (en) * 1983-11-04 1986-06-30 Intreprinderea De Detergenti"Dero",Ro PROCESS AND INSTALLATION FOR MANUFACTURING PELLET DETERGENTS
US4734224A (en) * 1986-09-15 1988-03-29 The Dial Corporation Dry neutralization process for detergent slurries
GB8818613D0 (en) * 1988-08-05 1988-09-07 Paterson Zochonis Uk Ltd Detergents
DE4232874A1 (en) * 1992-09-30 1994-03-31 Henkel Kgaa Process for the preparation of surfactant granules

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1094383C (en) * 1998-09-11 2002-11-20 自贡市化工研究设计院 Spraying-fluidized bed prilling method for precipitation of hydrated silicon dioxide

Also Published As

Publication number Publication date
SK14597A3 (en) 1997-07-09
BR9508505A (en) 1998-05-26
HUT77715A (en) 1998-07-28
PL318548A1 (en) 1997-06-23
CN1115403C (en) 2003-07-23
WO1996004359A1 (en) 1996-02-15
CA2195313A1 (en) 1996-02-15
CZ289884B6 (en) 2002-04-17
PL181161B1 (en) 2001-06-29
MX9700863A (en) 1997-09-30
AU702808B2 (en) 1999-03-04
HU222907B1 (en) 2003-12-29
ZA956415B (en) 1997-02-03
EP0775193A1 (en) 1997-05-28
SK282576B6 (en) 2002-10-08
GB9415904D0 (en) 1994-09-28
AU3165695A (en) 1996-03-04
TW380161B (en) 2000-01-21
CZ30597A3 (en) 1997-09-17

Similar Documents

Publication Publication Date Title
CN1115403C (en) Granulation in a fluidised bed
CN1111595C (en) Process for making a low density detergent composition by agglomeration with an inorganic double salt
EP0402111B1 (en) Formation of detergent granules by deagglomeration of detergent dough
CN1165607C (en) Production of detergent granulates
JPH0747757B2 (en) Detergent composition
CN1122710C (en) Process for making low density detergent composition by agglomeration with inorganic double salt
PL184656B1 (en) Method of obtaining a detergent composition
KR960001021B1 (en) Detergent compositions and the preparation thereof
CN1267329A (en) Production of detergent granulates
CN1054631C (en) Detergent compositions
EP1165735B2 (en) Detergent powder composition
CN1541260A (en) Process for prodn. of detergent granules
CN1170918C (en) Process for making low density detergent composition by controlling nozzle height in fluid bed dryer
CN1343250A (en) Process for producing coated detergent particles
CN1120229C (en) Preparation of low density detergent agglomerates containing silica
CN1280398C (en) Process for the production of detergent granules
CN1433462A (en) Process for preparing granular detergent compositions
CN1568362A (en) Process for the production of detergent granules
CN1116402C (en) Preparation of low density detergent agglomerates containing silica
PL187377B1 (en) Method of making a detergent composition
CN1188145A (en) Granulated detergent with improved oil stain removing ability
MXPA97000863A (en) Granulation in a fluidized bed
CN1188144A (en) Method for preparing surface-active detergent containing anion and cleaning active surface-active agent granule
MXPA97002347A (en) Compositions highly active granular detergents and processing for elaboration

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee