CN1155297A - Granulation in a fluidised bed - Google Patents
Granulation in a fluidised bed Download PDFInfo
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- CN1155297A CN1155297A CN95194514A CN95194514A CN1155297A CN 1155297 A CN1155297 A CN 1155297A CN 95194514 A CN95194514 A CN 95194514A CN 95194514 A CN95194514 A CN 95194514A CN 1155297 A CN1155297 A CN 1155297A
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- Prior art keywords
- acid
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- neutralizing agent
- aforementioned
- bulk density
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- 238000005469 granulation Methods 0.000 title description 2
- 230000003179 granulation Effects 0.000 title description 2
- 238000000034 method Methods 0.000 claims abstract description 41
- 239000003599 detergent Substances 0.000 claims abstract description 37
- 239000002253 acid Substances 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 22
- 239000000843 powder Substances 0.000 claims abstract description 22
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 19
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims description 38
- 238000005406 washing Methods 0.000 claims description 21
- 238000005243 fluidization Methods 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 229910021532 Calcite Inorganic materials 0.000 claims description 6
- 238000009826 distribution Methods 0.000 claims description 6
- 239000010419 fine particle Substances 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 229960001866 silicon dioxide Drugs 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- -1 alkylbenzene sulfonate Chemical class 0.000 claims description 2
- 229910010272 inorganic material Inorganic materials 0.000 claims description 2
- 239000011147 inorganic material Substances 0.000 claims description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims 1
- 150000008041 alkali metal carbonates Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000012530 fluid Substances 0.000 abstract 1
- 239000011236 particulate material Substances 0.000 abstract 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 17
- 235000019832 sodium triphosphate Nutrition 0.000 description 15
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 13
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 13
- 239000013543 active substance Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000004482 other powder Substances 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
A process for the manufacture of detergent powders involving fluidizing a particulate material comprising a neutralizing agent, preferably in a fluid bed, contacting LAS acid with the fluidized material to effect neutralization and optionally adding a flow aid to the material either prior, during or subsequent to the addition of LAS acid is disclosed.
Description
The present invention relates to the low detergent composition of a kind of bulk density (BD) and utilize dry neutralization to produce this method for compositions, also showed the application of fluidized-bed in producing this class detergent composition.
Be known in the art and adopt the spray drying method for preparation detergent powder.Yet this spray-drying process has the high shortcoming of the big energy consumption of investment, and is therefore more expensive with the product of this method gained.The special benefits of this method is that the pile of grounds density of production is low, is 350-600 g/l simultaneously.
4304062 of Henkel has been narrated a kind of detergent surfactant particulate production method, this method be in the granulating and drying case under high atmospheric pressure, with in the aqueous solution of alkali and the anion surfactant of acid type.In the method, the liquid parts with the hot-air dry nonsurfactant is a basic step.
Is known with dry neutralisation preparing washing agent powder in this area, but often obtains the high powder of bulk density in this way.Indian patent 166307 (Hindustan Lever Ltd) is mentioned a kind of special purpose of interior recirculation fluidisation bed, and obtains adopting conventional fluidized-bed that product is lumpd and thickness during the course.
Deutsches Wirtschafts Patent 140987 (VEB Waschmittelwerk) discloses a kind of method of continuous production granular detergent compositions, wherein be with liquid component for example the acid parent of nonionogenic tenside or anion surfactant be sprayed onto on pulverous washing assistant material, particularly second mutually on the tripoly phosphate sodium STPP (STPP) of content height (high phase II Content), be the product of 530-580g/l to produce bulk density.Yet, according to described Deutsches Wirtschafts Patent, this method be only limited to second mutually in the high STPP of content use.
English Patent 1404317 discloses utilizes dry neutralisation to prepare the low or medium detergent powder of bulk density.In the presence of the water of q.s, sulfonic acid is mixed with excessive SODA ASH LIGHT 99.2, so that the beginning neutralization reaction, but the used water yield is not enough to soak the product that gained is the free flowing powder last current state again.This method is at mixing device spiral blade stirrer for example, and planetary-type mixer or air are carried and carried out in the mixing tank.In mixing device, the fine-grannular detergent materials is stressed to be compressed, and this can make bulk density increase.
We have now found that, produce the low powder of bulk density with the acid parent of tensio-active agent in fluidized-bed, can avoid the shortcoming of prior art.
According to a first aspect of the invention, provide a kind of method of producing the low detergent composition of bulk density, this method comprises contacts the acid parent of anion surfactant with neutralizing agent in fluidized-bed, so that its neutralization, thereby preparing washing agent composition.
In second aspect, the invention provides a kind of method of producing the low fine-grannular detergent composition of bulk density, this method comprises that the fine particle materials of the detergent builder compound that will contain neutralizing agent and choose wantonly adds fluidization zone, make its fluidization, the liquid parent of anion surfactant is contacted with the fluidizing material, so that at least a neutralization part and preferably basically in and all acid sexupara body, contain the detergent particles of neutral parent acid to some extent thereby generate.
Preferred fluidization zone is provided by fluidized-bed.
According to a further aspect in the invention, provide a kind of method of producing the low fine-grannular detergent composition of bulk density, this method comprises:
I will contain washing assistant and neutralizing agent and fine particle materials and add fluidized-bed;
Ii is in time enough, and (LAS) adds this bed with linear alkylbenzene sulfonate, so that the part that neutralizes at least should acid, thereby obtains desired powder property.
The present invention also provides the detergent composition of the method preparation of defined in a kind of available claim.
As required, this method can be carried out with intermittence or successive operating method.Term used herein " detergent composition " comprises can for example SYNTHETIC OPTICAL WHITNER and enzyme mix the detergent of the product of producing full preparation with other common used material, and the another kind of detergent ingredients of so-called additive, they can be through further handling, produce a kind of subsequently can be as required and the detergent materials of other material mixing.
According to the present invention, this method has been showed the fluidization effect by neutralizing agent, makes the acid parent of its dry neutralize anionic surfactant, and preferably this method is carried out in fluidized-bed.Dry neutralisation be meant a neutralization part at least and preferably basically in and all acid sexupara body, mixture still keeps the particulate state simultaneously.The suitably adding of the acid parent of control is not accumulated in the detergent composition it with neutral condition not.
Suitable neutralizing agent is granuliform, and contains alkaline inorganic material, preferably contains basic salt.Suitable material comprises alkaline carbonate and supercarbonate, for example their sodium salt.
The suitable consumption of neutralizing agent with enough fully neutralizing acid sexupara body be as the criterion.If desired, can use neutralizing agent, to guarantee to neutralize fully or provide another kind of effect, for example in the clean effect of using under the yellow soda ash situation that increases above stoichiometric quantity.
Except anion surfactant by the neutralisation preparation, can add other anion surfactants in due course, or nonionic, positively charged ion, zwitter-ion, both sexes or semi-polarity tensio-active agent and composition thereof.Suitable tensio-active agent comprises those tensio-active agents of Schwarz and Perry general introduction in " tensio-active agent and washing composition " the 1st volume.Therefore, if desired, with containing C
12-C
15The soap saturated or that unsaturated fatty acids is produced of carbon atom also can be used as anion surfactant to be used.
The suitable consumption of detergent surfactant is the 5-40% (weight) of detergent composition, is preferably 12-30%.
Detergent composition is fit to contain detergent builder compound.Washing assistant can add simultaneously with neutralizing agent as required and/or add after adding neutralizing agent.Preferably washing assistant and neutralizing agent are added simultaneously.
Can use arbitrary washing assistant commonly used, suitable washing assistant comprises the calcite of yellow soda ash, zeolite, tripoly phosphate sodium STPP (STPP), Trisodium Citrate and/or high surface area.Washing assistant also can mix by individually a kind of in the above-mentioned washing assistant or with other washing assistant and form.
Washing assistant and neutralizing agent can be commaterials, yellow soda ash for example, and in this case, the quantity of material of use should enough play this two kinds of effects.
The suitable consumption of washing assistant is the 15-65% (weight) of detergent composition, and is preferably 15-50%.
Detergent powder prepared in accordance with the present invention has suitably low bulk density, is 350-650g/l or 450-650g/l, and is for example, about 500g/l, therefore equally matched with the bulk density that utilizes spray-drying process to obtain.
With a kind of optional adding in the composition with preferred flow promotor.Can before or after adding part or all acid parent, flow promotor be mixed with neutralizing agent and washing assistant (if the work that has).Before or after adding a part of acid parent, add flow promotor, thereby the bulk density of product powder is obviously descended.
The suitable consumption of flow promotor is the 0.1-15% (weight) of detergent composition, and preferred consumption is 0.5-5%.
Suitable flow promotor comprises crystalline form or amorphous alkali metal silicate, calcite, diatomite, silicon-dioxide, for example sedimentary silicon-dioxide, sal epsom and lime carbonate, for example sedimentary lime carbonate.Can adopt these mixtures of material as required.In preferred embodiments, flow promotor is Dicamol.
Said composition also can contain granuliform weighting agent, and weighting agent is fit to comprise inorganic salt, for example sodium sulfate and sodium-chlor.The consumption of weighting agent is the 5-50% (weight) of composition.
Detergent composition produced according to the invention is fit to contain detergent surfactant and washing assistant, and one or more optional flow promotors, weighting agent and other composition, for example dyestuff, spices, fluorescent bleaches, SYNTHETIC OPTICAL WHITNER and enzyme on a small quantity.
We find that also the raw material of selecting to have the certain particle size characteristic can make bulk density obviously descend.
The suitable size-grade distribution of granulate material is that granularity is no more than 5% (weight) greater than the particle of 250 μ.Also preferred size is at least 30% (weight) less than the particle of 75 μ.The mean particle size that fine particle materials suits is less than 200 μ, so that provide the bulk density of special needs low detergent powder.
If desired, can add a certain amount of water, be beneficial to neutralization.The water yield that adds can be the 0.5-2% (weight) of finished product detergent composition.These water added before adding acid parent, or added simultaneously with acid parent, or alternately added with acid parent and all to suit.
Granulate material is added fluidized-bed by rights, add the LAS acid of aequum then, preferably it is sprayed onto on the described material, and preferably adds from the top.If flow promotor is arranged, can add with raw material.But, preferably after adding a part of LAS acid, add flow promotor, so that obtain lower bulk density.
Fluidized-bed is adapted at room temperature to 60 ℃ operation down.It is enough big that air velocity is wanted, so that cause fluidization, and is preferably 0.6-1ms
-1Because the fluidization of solid material helps neutralization and granulation, particle is discharged, so the fluidization of solid material is an essential characteristic of the present invention.This is opposite with mixing process, in mixing process, has a mind to make particle to contact with each other and push, and this can cause the bulk density of powder to increase and degradation.
By following non-limiting examples explanation the present invention.Embodiment 1-19
Pulverous washing assistant/inorganic alkaline material (in embodiment 1-4, yellow soda ash plays two kinds of effects) and weighting agent are added fluidized-bed, and make its fluidization by operation under greater than the apparent air velocity of minimum fluidization velocity.The temperature of fluidized-bed is a room temperature to 60 ℃.Linear alkyl benzene sulphonic acid (LAS acid) is sprayed onto on the powder mixture in the fluidized-bed.
The relative quantity of each composition changes in the composition, and lists in the table 1 below.
Embodiment 1-3 explanation in the method, adds the influence of flow promotor (using Dicamol here) in composition in the different time.In embodiment 1, do not add flow promotor in the material.In embodiment 2, before adding LAS acid, in raw material, add flow promotor.In embodiment 3, after the LAS acid of adding 50%, add flow promotor.It is favourable that fine-graded granulated material is adopted in embodiment 4 explanations.These the results are shown in the following table 1.
Table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| LAS | ?????17 | ?????17 | ?????17 | ??????1 |
| SODA ASH LIGHT 99.2 | ?????30 | ?????30 | ?????30 | ?????30 |
| Dicamol | ?????- | ?????2 * | ?????2 ** | ?????2 ** |
| Salt | ?????45 | ?????43 | ?????43 | ??????- |
| Fine salt | ?????- | ?????- | ?????- | ?????43 |
| BD(g，/L) | ????687 | ????625 | ????603 | ????546 |
| DFR(ml/sec) | ????85.72 | ???96.77 | ????88.23 | ????93.8 |
| aROD(％) | ????81.6 | ???80.6 | ????82.3 | ????82.5 |
The a dissolution rate
*When beginning, add Dicamol
*After the LAS of adding 50%, add Dicamol
The measuring method of powder dissolution rate is: by concentration is 1.4%, and powder is joined in the 1L water, stirs and measures the electricity of solution and lead under 100rpm, up to stable reading.Listed numeral means the dissolution rate of powder behind about 90sec.
Embodiment 2 and 3 explanations added flow promotor before or after adding a part of LAS acid can make bulk density obviously descend.
Embodiment 5-19 is according to the method for the described embodiment of being used for 1-4 and adopts the various feedstock production with different grain size distribution that other powder, its details are listed among the following table 3-5.Table 2 has been summarized the size-grade distribution of various materials.
Table 2
| Various raw material properties | |||||
| Size-grade distribution | SODA ASH LIGHT 99.2 | ???Na 2SO 4 | Salt | Fine salt | ?????STPP |
| (μ) | ?????????????????????????????????％wt | ||||
| ＞500 | ????1.8 | ????0.12 | ????1.78 | ????1.00 | ?????0.94 |
| 500-250 | ????2.06 | ????0.60 | ????80.40 | ????1.26 | ?????1.40 |
| 250-150 | ????6.52 | ????21.90 | ????14.80 | ????10.02 | ?????6.86 |
| 150-100 | ????26.20 | ????55.14 | ????2.88 | ????21.80 | ?????24.88 |
| 100-75 | ????16.20 | ????8.56 | ????0.14 | ????24.07 | ?????7.92 |
| ＜75 | ????47.14 | ????13.68 | ?????- | ????36.83 | ?????58.00 |
| Mean particle size (μ) | ????92.7 | ????138.2 | ????360.30 | ????112.5 | ?????85.7 |
| BD，g/l | ????508 | ????1,347 | ????1,070 | ?????997 | ?????649 |
| DFR，ml/sec | Do not flow | ????83.33 | ????142.85 | Do not flow | Do not flow |
Table 3
| Embodiment | ??????5 | ?????6 | ?????7 | ?????8 | ?????9 | ?????10 |
| LAS，％ | ?????17.0 | ????20.0 | ????23.0 | ????23.7 | ????25.0 | ????27.1 |
| Moisture, % | ?????6.8 | ????6.0 | ????4.8 | ????6.0 | ????4.5 | ????5.1 |
| STPP，％ | ?????35.0 | ????22.0 | ????35.0 | ????35.0 | ????25.0 | ????25.0 |
| SODA ASH LIGHT 99.2, % | ?????22.0 | ????20.0 | ????22.0 | ????22.0 | ????20.0 | ????20.0 |
| Fine salt, % | ??????- | ????30.0 | ?????- | ?????- | ????16.0 | ????15.0 |
| Alkaline silicate, % | ??????- | ?????- | ?????- | ?????- | ?????- | ????1.0 |
| Bulk density, g/L | ?????500 | ????510 | ????500 | ????490 | ????500 | ????495 |
| ?DFR，ml/sec | ?????100 | ????120 | ????120 | ????120 | ????100 | ?????88 |
Table 4
| Embodiment | ????11 | ????12 | ?????13 | ????14 | ????15 |
| LAS acid, % | ???28.5 | ???28.7 | ????29.13 | ????29.6 | ???31.1 |
| Moisture, % | ???4.5 | ???6.7 | ?????6.2 | ????7.4 | ????6.8 |
| STPP，％ | ???25.0 | ???35.0 | ?????25.0 | ????35.0 | ???35.0 |
| SODA ASH LIGHT 99.2, % | ???20.0 | ???22.0 | ?????20.0 | ????22.0 | ???22.0 |
| Fine salt, % | ???16.0 | ????- | ??????- | ?????- | ?????- |
| Na 2SO 4，％ | ????- | ????- | ?????16.0 | ?????- | ?????- |
| Bulk density, g/L | ???514 | ????470 | ?????510 | ????500 | ????520 |
| DFR，ml/sec | ???120 | ????100 | ?????88 | ????102 | ????115 |
Table 5
| Embodiment | ?????16 | ?????17 | ?????18 | ?????19 |
| LAS，％ | ????17.0 | ????17.0 | ????17.0 | ????13.0 |
| Soap, % | ??????- | ??????- | ??????- | ?????4.0 |
| SODA ASH LIGHT 99.2, % | ????22.0 | ????30.0 | ????35.0 | ????20.0 |
| STPP，％ | ????35.0 | ??????- | ??????- | ????35.0 |
| The calcite on high surface, % | ??????- | ??????- | ????16.0 | ??????- |
| Moisture, % | ?????6.8 | ?????3.5 | ?????3.0 | ?????4.0 |
| BD，g/L | ?????500 | ?????530 | ?????480 | ?????500 |
| DFR，ml/sec | ?????100 | ?????100 | ?????120 | ?????150 |
Table 3 and table 4 illustrate the result of the STPP washing assistant powder of the tensio-active agent that contains 17-31%.As shown in table 2, SODA ASH LIGHT 99.2 and STPP have similar size-grade distribution and make the product of bulk density near 500g/l based on some prescriptions of these builder systems.Table 5 illustrates based on various builder systems, i.e. the powder of STPP, SODA ASH LIGHT 99.2 and high surface area calcite.Make the powder that bulk density is about 500g/l with SODA ASH LIGHT 99.2 and these two washing assistant prescriptions of STPP, and make the powder that bulk density is lower than 500g/l based on the prescription of high surface area calcite.Embodiment 19 relates to a mixed surfactant system that contains 13%LAS acid and 4% soap, and makes the powder that bulk density is 500g/l.
Claims (10)
1. method of producing the low detergent composition of bulk density, this method comprises makes the acid parent of anion surfactant contact in fluidized-bed with neutralizing agent, so that neutralize this parent, thereby makes detergent composition.
2. method of producing the low fine-grannular detergent composition of bulk density, this method comprises that the fine particle materials of the detergent builder compound that will contain neutralizing agent and choose wantonly adds fluidization zone, make its fluidization, the liquid parent of anion surfactant is contacted with this fluidizing material, so that at least a neutralization part and preferably basically in and all acid sexupara body, contain the detergent particles of neutral parent acid to some extent thereby generate.
3. method of producing the low fine-grannular detergent composition of bulk density, this method comprises:
The fine particle materials that i. will contain washing assistant and neutralizing agent adds fluidized-bed;
Ii. in time enough, (LAS) adds this bed with linear alkylbenzene sulfonate, so that the part that neutralizes at least should acid, thereby obtains desired powder property.
4. according to each method in the aforementioned claim, wherein neutralizing agent comprises alkaline inorganic material, preferred alkali metal carbonate.
5. according to each method in the aforementioned claim, comprising the method that adds one or more mobile washing assistants, add-on is the 0.1-15% (weight) of composition.
6. according to each method in the aforementioned claim, wherein flow promotor is adding after adding a part of acid parent.
7. according to each method among the claim 1-5, wherein flow promotor is to add before adding acid parent.
8. according to each method in the aforementioned claim, wherein flow promotor is one or more dicamol, crystalline or unbodied alkaline silicate, calcite, diatomite, sedimentary silicon-dioxide, sal epsom.
9. according to each method in the aforementioned claim, wherein the size-grade distribution of neutralizing agent and other material granule is, granularity greater than the particle of 250 μ m be no more than 5% and granularity less than the particle of 75 μ m greater than 30%.
10. adopt according to each method, the detergent composition that can prepare or its composition in the aforementioned claim.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9415904A GB9415904D0 (en) | 1994-08-05 | 1994-08-05 | Process for the production of detergent composition |
| GB9415904.3 | 1994-08-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1155297A true CN1155297A (en) | 1997-07-23 |
| CN1115403C CN1115403C (en) | 2003-07-23 |
Family
ID=10759488
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95194514A Expired - Fee Related CN1115403C (en) | 1994-08-05 | 1995-07-24 | Granulation in a fluidised bed |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0775193A1 (en) |
| CN (1) | CN1115403C (en) |
| AU (1) | AU702808B2 (en) |
| BR (1) | BR9508505A (en) |
| CA (1) | CA2195313A1 (en) |
| CZ (1) | CZ289884B6 (en) |
| GB (1) | GB9415904D0 (en) |
| HU (1) | HU222907B1 (en) |
| PL (1) | PL181161B1 (en) |
| SK (1) | SK282576B6 (en) |
| TW (1) | TW380161B (en) |
| WO (1) | WO1996004359A1 (en) |
| ZA (1) | ZA956415B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1094383C (en) * | 1998-09-11 | 2002-11-20 | 自贡市化工研究设计院 | Spraying-fluidized bed prilling method for precipitation of hydrated silicon dioxide |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9526097D0 (en) * | 1995-12-20 | 1996-02-21 | Unilever Plc | Process |
| TW397862B (en) * | 1996-09-06 | 2000-07-11 | Kao Corp | Detergent granules and method for producing the same, and high-bulk density detergent composition |
| US6172034B1 (en) | 1996-10-04 | 2001-01-09 | The Procter & Gamble | Process for making a detergent composition by non-tower process |
| US6143711A (en) * | 1996-10-04 | 2000-11-07 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
| US6150323A (en) * | 1996-10-04 | 2000-11-21 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
| US6211137B1 (en) | 1996-10-04 | 2001-04-03 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
| US6136777A (en) * | 1996-10-04 | 2000-10-24 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
| US6391844B1 (en) | 1996-10-04 | 2002-05-21 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
| US6121229A (en) * | 1996-10-04 | 2000-09-19 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
| US6211138B1 (en) | 1996-10-04 | 2001-04-03 | The Procter & Gamble Company | Process for making a detergent composition by non-tower process |
| GB9712580D0 (en) * | 1997-06-16 | 1997-08-20 | Unilever Plc | Production of detergent granulates |
| GB9712583D0 (en) | 1997-06-16 | 1997-08-20 | Unilever Plc | Production of detergent granulates |
| GB9712587D0 (en) * | 1997-06-16 | 1997-08-20 | Unilever Plc | Production of detergent granulates |
| GB9713748D0 (en) * | 1997-06-27 | 1997-09-03 | Unilever Plc | Production of detergent granulates |
| ATE371011T1 (en) * | 1997-07-14 | 2007-09-15 | Procter & Gamble | METHOD FOR PRODUCING A LOW BULK DENSITY DETERGENT BY CONTROLLED AGGLOMERATION IN A FLUID BED DRYER |
| JP2002507629A (en) * | 1997-07-14 | 2002-03-12 | ザ、プロクター、エンド、ギャンブル、カンパニー | Method for making low-density detergent composition by controlling agglomeration by particle size |
| WO1999003965A1 (en) | 1997-07-15 | 1999-01-28 | The Procter & Gamble Company | Process for making high-active detergent agglomerates by multi-stage surfactant paste injection |
| US6440342B1 (en) | 1998-07-08 | 2002-08-27 | The Procter & Gamble Company | Process for making a low density detergent composition by controlling nozzle height in a fluid bed dryer |
| ES2184523T3 (en) | 1998-10-26 | 2003-04-01 | Procter & Gamble | PROCEDURES FOR OBTAINING A DETERGENT GRANULAR COMPOSITION THAT HAS AN IMPROVED ASPECT AND SOLUBILITY. |
| GB9825563D0 (en) | 1998-11-20 | 1999-01-13 | Unilever Plc | Particulate laundry detergent compositions containing anionic surfactant granules |
| DE19855380A1 (en) * | 1998-12-01 | 2000-06-08 | Henkel Kgaa | Granulation process |
| DE19859778A1 (en) | 1998-12-23 | 2000-06-29 | Henkel Kgaa | Multi-phase cleaning agent with naphthalenesulfonic acid-formaldehyde condensate |
| ES2250122T3 (en) | 1999-03-30 | 2006-04-16 | Unilever N.V. | DETERGENT COMPOSITION IN POWDER. |
| GB9927653D0 (en) | 1999-11-22 | 2000-01-19 | Unilever Plc | Process for preparing granular detergent compositions |
| GB0119708D0 (en) * | 2001-08-13 | 2001-10-03 | Unilever Plc | Process for the production of detergent granules |
| GB0119711D0 (en) * | 2001-08-13 | 2001-10-03 | Unilever Plc | Process for the production of detergent granules |
| DE102005005499A1 (en) * | 2005-02-04 | 2006-08-17 | Henkel Kgaa | Process for the preparation of detergents or cleaners |
| EP2123742A1 (en) | 2008-05-14 | 2009-11-25 | The Procter and Gamble Company | A solid laundry detergent composition comprising light density silicate salt |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3425948A (en) * | 1966-01-03 | 1969-02-04 | Wyandotte Chemicals Corp | Composition and process for light-weight surfactant products |
| ZA72295B (en) * | 1971-02-01 | 1973-09-26 | Colgate Palmolive Co | Method for neutralization of detergent acid |
| GB1404317A (en) * | 1971-10-23 | 1975-08-28 | Bell Chemicals Pty Ltd | Manufacture of detergent powders |
| DD140987B1 (en) * | 1979-01-05 | 1982-06-30 | Manfred Mittelstrass | CONTINUOUS MANUFACTURING METHOD GRANULATED WASHING AND CLEANING AGENT IN SWIVEL LAYERED APPARATUS |
| RO88903A2 (en) * | 1983-11-04 | 1986-06-30 | Intreprinderea De Detergenti"Dero",Ro | PROCESS AND INSTALLATION FOR MANUFACTURING PELLET DETERGENTS |
| US4734224A (en) * | 1986-09-15 | 1988-03-29 | The Dial Corporation | Dry neutralization process for detergent slurries |
| GB8818613D0 (en) * | 1988-08-05 | 1988-09-07 | Paterson Zochonis Uk Ltd | Detergents |
| DE4232874A1 (en) * | 1992-09-30 | 1994-03-31 | Henkel Kgaa | Process for the preparation of surfactant granules |
-
1994
- 1994-08-05 GB GB9415904A patent/GB9415904D0/en active Pending
-
1995
- 1995-07-24 WO PCT/EP1995/002935 patent/WO1996004359A1/en active IP Right Grant
- 1995-07-24 CN CN95194514A patent/CN1115403C/en not_active Expired - Fee Related
- 1995-07-24 SK SK145-97A patent/SK282576B6/en unknown
- 1995-07-24 EP EP95927721A patent/EP0775193A1/en not_active Withdrawn
- 1995-07-24 AU AU31656/95A patent/AU702808B2/en not_active Ceased
- 1995-07-24 CZ CZ1997305A patent/CZ289884B6/en not_active IP Right Cessation
- 1995-07-24 PL PL95318548A patent/PL181161B1/en not_active IP Right Cessation
- 1995-07-24 BR BR9508505A patent/BR9508505A/en not_active IP Right Cessation
- 1995-07-24 CA CA002195313A patent/CA2195313A1/en not_active Abandoned
- 1995-07-24 HU HU9700357A patent/HU222907B1/en not_active IP Right Cessation
- 1995-08-01 ZA ZA9506415A patent/ZA956415B/en unknown
- 1995-08-09 TW TW084108296A patent/TW380161B/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1094383C (en) * | 1998-09-11 | 2002-11-20 | 自贡市化工研究设计院 | Spraying-fluidized bed prilling method for precipitation of hydrated silicon dioxide |
Also Published As
| Publication number | Publication date |
|---|---|
| AU702808B2 (en) | 1999-03-04 |
| HU222907B1 (en) | 2003-12-29 |
| CN1115403C (en) | 2003-07-23 |
| BR9508505A (en) | 1998-05-26 |
| CA2195313A1 (en) | 1996-02-15 |
| PL181161B1 (en) | 2001-06-29 |
| EP0775193A1 (en) | 1997-05-28 |
| HUT77715A (en) | 1998-07-28 |
| TW380161B (en) | 2000-01-21 |
| SK282576B6 (en) | 2002-10-08 |
| ZA956415B (en) | 1997-02-03 |
| CZ289884B6 (en) | 2002-04-17 |
| PL318548A1 (en) | 1997-06-23 |
| GB9415904D0 (en) | 1994-09-28 |
| AU3165695A (en) | 1996-03-04 |
| SK14597A3 (en) | 1997-07-09 |
| WO1996004359A1 (en) | 1996-02-15 |
| MX9700863A (en) | 1997-09-30 |
| CZ30597A3 (en) | 1997-09-17 |
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