CN115477980A - Composition with blood stain removing effect and preparation method thereof - Google Patents
Composition with blood stain removing effect and preparation method thereof Download PDFInfo
- Publication number
- CN115477980A CN115477980A CN202211269146.7A CN202211269146A CN115477980A CN 115477980 A CN115477980 A CN 115477980A CN 202211269146 A CN202211269146 A CN 202211269146A CN 115477980 A CN115477980 A CN 115477980A
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- surfactant
- sodium
- blood stains
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- 239000008280 blood Substances 0.000 title claims abstract description 52
- 210000004369 blood Anatomy 0.000 title claims abstract description 52
- 230000000694 effects Effects 0.000 title claims abstract description 51
- 239000000203 mixture Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 28
- 108091005804 Peptidases Proteins 0.000 claims abstract description 26
- 239000004365 Protease Substances 0.000 claims abstract description 26
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims abstract description 26
- 239000002738 chelating agent Substances 0.000 claims abstract description 22
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 20
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 20
- 239000002888 zwitterionic surfactant Substances 0.000 claims abstract description 18
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 6
- -1 sodium fatty alcohol Chemical class 0.000 claims description 35
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 16
- 229910052708 sodium Inorganic materials 0.000 claims description 16
- 239000011734 sodium Substances 0.000 claims description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 15
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
- 229930182478 glucoside Natural products 0.000 claims description 12
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 11
- 229910052742 iron Inorganic materials 0.000 claims description 11
- 229920000570 polyether Polymers 0.000 claims description 11
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 9
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims description 9
- 108700004121 sarkosyl Proteins 0.000 claims description 9
- 229940079781 sodium cocoyl glutamate Drugs 0.000 claims description 9
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims description 9
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 7
- MLDWGLQSBBCMMO-UHFFFAOYSA-N [Na].[Na].[Na].CNCC(=O)O Chemical compound [Na].[Na].[Na].CNCC(=O)O MLDWGLQSBBCMMO-UHFFFAOYSA-N 0.000 claims description 6
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 6
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229940061605 tetrasodium glutamate diacetate Drugs 0.000 claims description 6
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 claims description 6
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 claims description 5
- 229940075468 lauramidopropyl betaine Drugs 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- 102000004190 Enzymes Human genes 0.000 abstract description 11
- 108090000790 Enzymes Proteins 0.000 abstract description 11
- 238000004140 cleaning Methods 0.000 abstract description 6
- 230000000052 comparative effect Effects 0.000 description 18
- 239000003599 detergent Substances 0.000 description 15
- 238000005406 washing Methods 0.000 description 12
- 239000004744 fabric Substances 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 238000003889 chemical engineering Methods 0.000 description 2
- 230000002860 competitive effect Effects 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical group CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 229940057950 sodium laureth sulfate Drugs 0.000 description 2
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical group [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical group [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 240000000513 Santalum album Species 0.000 description 1
- 235000008632 Santalum album Nutrition 0.000 description 1
- 244000000231 Sesamum indicum Species 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004204 blood vessel Anatomy 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000009144 enzymatic modification Effects 0.000 description 1
- 210000004392 genitalia Anatomy 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 230000003100 immobilizing effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000005906 menstruation Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to the field of A61K8/18, in particular to a composition with a blood stain removing effect and a preparation method thereof, wherein the preparation raw materials at least comprise the following components in parts by weight: 1-60 parts of anionic surfactant, 0.1-40 parts of zwitterionic surfactant, 0.1-70 parts of nonionic surfactant, 0.1-6 parts of polymer emulsion, 0.1-5 parts of protease, 0.1-5 parts of chelating agent and the balance of deionized water to 100 parts. The problems that the existing blood stain removing product has poor blood stain removing effect for long-time residual blood stain, and part of the product contains enzyme with low stability in a system, so that high enzyme activity and stain removing effect are difficult to maintain for a long time are solved, and the cleaning requirement of the clothes in the physiological period of women is met.
Description
Technical Field
The invention relates to the field of A61K8/18, in particular to a composition with a blood stain removing effect and a preparation method thereof.
Background
In daily life, clothes of women, injured patients or medical care personnel and other people in special environments during menstruation are easily stained and stained by blood stains, and the underwear, bed sheets and the like are inevitably stained by the blood stains. The female physiological blood stain is influenced by factors such as genital secretion flora, pH and the like, and has a larger difference with blood stain components in animal blood vessels, a common blood stain cleaning method is not suitable, the blood stain is divided into fresh blood stain and old blood stain, iron in the fresh blood stain exists in a ferrous form and can be dissolved in water, the iron in the old blood stain is oxidized into ferric iron and is subjected to complexing coagulation with protein, the blood stain is formed on a fabric by being stained with the protein and is very difficult to remove by a chemical detergent, and trace residues are left even after cleaning, so that the attractiveness and subsequent use of the fabric are greatly influenced. Therefore, the cleaning of the blood stain in the physiological period of the female is always a problem that the female feels headache and feels shy in tooth opening.
The washing machine cannot achieve the washing effect because the washing machine cannot be specially used for washing a certain place, and therefore the washing machine generally needs to be washed by hands. Women's underclothes are generally made of cotton components, and when one piece of underclothes with physiological blood stains is cleaned, the underclothes are continuously rubbed with hands for ten minutes in a few days, and are soaked and discontinuously rubbed with hands for half an hour or even 1 to 2 hours in a more days, so that time and labor are wasted, and the cleaning effect is poor. Moreover, despite the fact that various detergents on the market today are full of commercial products such as washing powder, laundry detergent, soap powder and the like, and the eight-flower-shaped detergent is also specially used for the laundry detergent for women underwear, the effect is not ideal. For example, chinese patent application CN202011406968.6 discloses a detergent with strong blood stain removal effect and a preparation method thereof, in the disclosed patent, the detergent for removing blood stains is prepared by protease, sodium citrate, isomeric alcohol polyoxyethylene ether, C12-15 alkanol polyether-9, secondary alkyl sodium sulfonate, cocamidopropyl betaine and the like, but the detergent is mainly prepared by the protease, the activity of the protease is relatively high due to the influence of external environmental factors, the activity is volatile and ineffective, the stability in a system is relatively low, and the relatively high enzyme activity and the decontamination effect are difficult to maintain for a long time. In order to improve the stability of enzyme in the system, the prior art generally adopts the following methods: transforming the gene of the strain for producing the protease, immobilizing the protease and adding a stabilizer. Compared with the complexity and higher cost of enzyme modification and enzyme coating technology, the method of adding the stabilizer to keep the enzyme activity is simpler and more convenient and has wide application, but the stabilizer (such as boric acid) has certain irritation to the skin.
Disclosure of Invention
In order to solve the problems that the existing bloodstain removing product has poor bloodstain removing effect on the bloodstains remained for a long time, and part of the products contain enzymes with low stability in a system and are difficult to maintain high enzyme activity and decontamination effect for a long time, the composition with the bloodstain removing effect is provided, overcomes the defects that the enzyme stability of the existing enzyme-containing product is low and boric acid stabilizers have certain potential safety hazards, and has the effect of effectively removing fresh and old bloodstains.
The invention provides a composition with a blood stain removing effect, which at least comprises the following raw materials in parts by weight: 1-60 parts of anionic surfactant, 0.1-40 parts of zwitterionic surfactant, 0.1-70 parts of nonionic surfactant, 0-6 parts of polymer emulsion, 0.1-5 parts of protease, 0.1-5 parts of chelating agent and the balance of deionized water to 100 parts.
As a preferable technical scheme, the anionic surfactant is at least one of fatty alcohol polyether sulfate sodium, alkyl sodium sulfonate, sodium lauroyl sarcosinate and sodium cocoyl glutamate; preferably, the anionic surfactant is a combination of sodium fatty alcohol polyether sulfate, sodium alkyl sulfonate, sodium lauroyl sarcosinate and sodium cocoyl glutamate; preferably, the mass ratio of the fatty alcohol polyether sulfate sodium to the alkyl sodium sulfonate to the sodium lauroyl sarcosinate to the sodium cocoyl glutamate is 1: (3-8): (0.1-3): (0.5-2). Preferably, the sodium fatty alcohol polyether sulfate is sodium laureth sulfate, and the sodium alkyl sulfonate is sodium dodecyl sulfate; based on the system of the invention, by introducing the components with the mass ratio of 1: (3-8): (0.1-3): (0.5-2) the sodium fatty alcohol polyether sulfate, the sodium alkyl sulfonate, the sodium lauroyl sarcosinate and the sodium cocoyl glutamate which are used as anionic surfactants generate synergistic action with a zwitterionic surfactant, a nonionic surfactant and protease in a system, so that the activity of the protease in the system is not influenced, and the clear removing effect on fresh and old blood stains is improved.
As a preferred technical solution, the zwitterionic surfactant is a combination of cocamidopropyl betaine and lauramidopropyl betaine; preferably, the mass ratio of the cocamidopropyl betaine to the lauramidopropyl betaine is (0.01-1): (0.01-3).
As a preferred technical scheme, the nonionic surfactant is selected from one or a combination of several of fatty acid methyl ester ethoxylate, fatty alcohol-polyoxyethylene ether and alkyl glucoside; preferably, the nonionic surfactant is a combination of fatty acid methyl ester ethoxylate, fatty alcohol-polyoxyethylene ether and alkyl glucoside; preferably, the mass ratio of the fatty acid methyl ester ethoxylate to the fatty alcohol-polyoxyethylene ether to the alkyl glucoside is (0.01-1): (0.01-3): (0.01-3); preferably, the alkyl glucoside is dodecyl glucoside, the fatty alcohol-polyoxyethylene ether is isomeric tridecanol polyoxyethylene ether, and the inventors find that the mass ratio of the alkyl glucoside to the fatty alcohol-polyoxyethylene ether is (0.01-1): (0.01-3): and (0.01-3) fatty acid methyl ester ethoxylate, fatty alcohol-polyoxyethylene ether and alkyl glucoside, wherein the bloodstain removing effect of the composition is synergistically improved, the dispersion effect of the surfactant in a system is improved, and the stability of the system is ensured.
As a preferable technical scheme, the mass ratio of the anionic surfactant to the zwitterionic surfactant to the nonionic surfactant is (1-12): (1-4): (1-7). Based on the system, the composition with the blood stain removing effect is prepared by adopting the combination of an anionic surfactant, a zwitterionic surfactant and a nonionic surfactant to cooperate with protease, and particularly, the mass ratio of the anionic surfactant to the zwitterionic surfactant to the nonionic surfactant in the system is controlled to be (1-12): (1-4): (1-7), the activity and stability of protease in the system are not influenced, and the provided composition has a strong effect of removing fresh and old bloodstains.
As a preferred technical scheme, the polymer emulsion comprises 0.1-5 parts of acrylate copolymer emulsion and 0.1-1 part of styrene/acrylic emulsion by weight; the acrylic ester copolymer emulsion is from the following types; the styrene/acrylic emulsion is from the type of styrene/acrylic emulsion. Based on the system, the polymer emulsion is introduced into the acrylate copolymer emulsion and the styrene/acrylic emulsion, so that the stability of the protease in the system is improved, the influence of the introduction of part of the surfactant on the structure and the activity of the protease is avoided, the protease can keep the activity in the system for a long time, and the removal effect on old blood stains is improved.
As a preferable technical scheme, the chelating agent is at least one of tetrasodium glutamate diacetate, trisodium methylglycine diacetate and an iron ion chelating agent; preferably, the chelating agent is a combination of tetrasodium glutamate diacetate, trisodium methylglycine diacetate, an iron ion chelating agent; the mass ratio of the tetrasodium glutamate diacetate to the trisodium methylglycine diacetate to the iron ion chelating agent is 1: (0.1-0.5): (0.01-0.1). The type of the iron ion chelating agent is YL-702, and the iron ion chelating agent is from remote chemical engineering.
The invention also provides a preparation method of the composition with the function of removing blood stains, which at least comprises the following steps:
(1) Adding an anionic surfactant into deionized water according to parts by weight, and stirring for 25-35 min at 70-90 ℃ to obtain a solution A;
(2) Sequentially adding a zwitterionic surfactant and a nonionic surfactant into the solution A to obtain a solution B;
(3) Cooling to 40-50 deg.C, adding polymer emulsion, chelating agent, and protease into solution B, stirring and mixing for 10-30min, and cooling to 20-30 deg.C.
Has the beneficial effects that:
1. the invention provides a composition with a bloodstain removing effect, which effectively improves the stability of biological enzyme in a system, has a strong effect of removing fresh and old bloodstains, and is suitable for cleaning clothes in a female physiological period.
2. Based on the system of the invention, by introducing the components with the mass ratio of 1: (3-8): (0.1-3): (0.5-2) the sodium fatty alcohol polyether sulfate, the sodium alkyl sulfonate, the sodium lauroyl sarcosinate and the sodium cocoyl glutamate which are used as anionic surfactants generate synergistic action with a zwitterionic surfactant, a nonionic surfactant and protease in a system, so that the activity of the protease in the system is not influenced, and the clear removing effect on fresh and old blood stains is improved.
3. Based on the system of the invention, the mass ratio of (0.01-1): (0.01-3): and (0.01-3) fatty acid methyl ester ethoxylate, fatty alcohol-polyoxyethylene ether and alkyl glucoside, wherein the bloodstain removing effect of the composition is synergistically improved, the dispersing effect of the surfactant in a system is improved, and the stability of the system is ensured.
4. Based on the system, the polymer emulsion is introduced into the acrylate copolymer emulsion and the styrene/acrylic emulsion, so that the stability of the protease in the system is improved, the influence of the introduction of part of the surfactant on the structure and the activity of the protease is avoided, the protease can keep the activity in the system for a long time, and the removal effect on old blood stains is improved.
Drawings
FIG. 1 is a graph comparing the blood stain removing effect of the compositions with blood stain removing effect prepared in examples 1 and 2 of the present invention with that of comparative example;
in the figure, a1-9 are cotton cloth before washing by using examples 1 and 2 and comparative examples 1-7 respectively; in the figure, b1-9 are cotton cloths washed by adopting examples 1 and 2 and comparative examples 1-7 respectively;
Detailed Description
Example 1
The embodiment 1 of the invention provides a composition with a blood stain removing effect, and the composition comprises the following raw materials in parts by weight: 15.5 parts of anionic surfactant, 5 parts of zwitterionic surfactant, 5.5 parts of nonionic surfactant, 1.1 parts of polymer emulsion, 1 part of protease, 0.6 part of chelating agent and the balance of deionized water to 100 parts.
The anionic surfactant is a combination of fatty alcohol polyether sodium sulfate, sodium alkyl sulfonate, sodium lauroyl sarcosinate and sodium cocoyl glutamate; the mass ratio of the fatty alcohol polyether sulfate sodium to the alkyl sodium sulfonate to the sodium lauroyl sarcosinate to the sodium cocoyl glutamate is 1:5:2:1. the sodium fatty alcohol polyether sulfate is sodium laureth sulfate, and the sodium alkyl sulfonate is sodium dodecyl sulfate.
The zwitterionic surfactant is a combination of cocamidopropyl betaine and lauramidopropyl betaine; the mass ratio of the cocamidopropyl betaine to the lauramidopropyl betaine is 1:0.5.
the nonionic surfactant is a combination of fatty acid methyl ester ethoxylate, fatty alcohol-polyoxyethylene ether and alkyl glucoside; the mass ratio of the fatty acid methyl ester ethoxylate to the fatty alcohol-polyoxyethylene ether to the alkyl glucoside is 0.8:0.5:0.1; the alkyl glucoside is dodecyl glucoside, and the fatty alcohol-polyoxyethylene ether is isomeric tridecanol polyoxyethylene ether.
The polymer emulsion comprises 0.6 part of acrylate copolymer emulsion and 0.5 part of styrene/acrylic emulsion in parts by weight; the acrylate copolymer emulsion is S-05 and is sourced from Jiang Susheng New Material science and technology Limited; the styrene/acrylic emulsion was model number Opulyn 301, and was derived from the dow chemical of the united states.
The chelating agent is a combination of tetrasodium glutamate diacetate, trisodium methylglycine diacetate and an iron ion chelating agent; the mass ratio of the tetrasodium glutamate diacetate to the trisodium methylglycine diacetate to the iron ion chelating agent is 1:0.2:0.01. the model of the iron ion chelating agent is YL-702, and is from remote chemical engineering.
In another aspect, embodiment 1 of the present invention provides a method for preparing a composition with blood stain removing effect, comprising the following steps:
(1) Adding an anionic surfactant into deionized water according to parts by weight, and stirring for 30min at 80 ℃ to obtain a solution A;
(2) Sequentially adding a zwitterionic surfactant and a nonionic surfactant into the solution A to obtain a solution B;
(3) Cooling to 45 ℃, adding the polymer emulsion, the chelating agent and the protease into the solution B in sequence, stirring and mixing for 20min, and cooling to 25 to obtain the product.
Example 2
The embodiment 2 of the invention provides a composition with a blood stain removing effect and a preparation method thereof, and the specific implementation mode of the composition is the same as that of the embodiment 1, except that the preparation raw materials of the composition comprise the following components in parts by weight: 20.5 parts of anionic surfactant, 6 parts of zwitterionic surfactant, 5.5 parts of nonionic surfactant, 1.1 parts of polymer emulsion, 2 parts of protease, 0.4 part of chelating agent and the balance of deionized water to 100 parts.
Example 3
The embodiment 3 of the invention provides a composition with a blood stain removing effect and a preparation method thereof, and the specific implementation manner of the composition is the same as that of the embodiment 1, except that the composition comprises the following raw materials in parts by weight: 26 parts of anionic surfactant, 4 parts of zwitterionic surfactant, 4 parts of nonionic surfactant, 1 part of protease, 0.5 part of chelating agent and the balance of deionized water to 100 parts.
Comparative example 1
Comparative example 1 of the present invention is a feminine undergarment detergent, derived from the forest pharmaceutical.
Comparative example 2
Comparative example 2 of the present invention is an underwear laundry detergent wooden sandalwood, derived from a washing room.
Comparative example 3
Comparative example 3 of the present invention is a laundry detergent for underwear derived from the blue moon.
Comparative example 4
Comparative example 4 of the present invention is a welsh underwear detergent.
Comparative example 5
The comparative example 5 of the invention is underwear laundry detergent, which is derived from sesame seed.
Comparative example 6
Comparative example 6 of the present invention is PWU underwear laundry detergent.
Comparative example 7
Comparative example 7 of the present invention is VIVITREE underwear laundry detergent.
Performance test method
1. And (3) testing the bloodstain removing effect:
1. the purpose is as follows:
clothes to be tested are washed in a simulated and practical use mode, and the whiteness value and whiteness maintenance (see table 1 for results) of each tested clothes are measured so as to evaluate the color cross-over prevention effect of the sample and the competitive products.
2. Materials and instruments
(1) Testing white cloth, fresh blood (blood similar to human blood, such as chicken blood, pig blood, rabbit blood);
(2) The instrument comprises the following steps: a whiteness meter;
(3) Sample preparation: examples 1, 2;
(4) Competitive products: comparative examples 1 to 7.
3. The testing steps are as follows:
(1) preparing a plurality of 5cm by 5cm pure cotton white cloth, coating 0.5g of fresh pig blood on the pure cotton white cloth, airing at room temperature for 72 hours,
taking a picture and waiting for washing;
(2) wetting cotton cloth to be washed by water, then pre-coating 2g of a sample to be detected in a bloodstain area, and uniformly spreading the sample in the bloodstain;
(3) taking 1L of tap water from a 2L beaker, and rubbing the bloodstain part of the cotton cloth with hands for 60 times;
(4) washing with water for 60 times;
(5) finally, the film is rinsed with clean water, dried and photographed for recording (see fig. 1).
Note: (1) paying attention to the kneading force and times; (2) The closer the whiteness value of the clothes before and after washing is to the initial whiteness value, the more obvious the washing liquid has the function of removing blood stains on the clothes.
2. And (3) stability testing:
1. low-temperature stability: the compositions prepared in the examples were filled into transparent PET bottles and placed in a refrigerator at 5 ℃ for 48 hours, the state of the bodies was observed and recorded, and the results are recorded in Table 1.
2. Low-temperature stability: the compositions prepared in the examples were filled into transparent PET bottles and placed in an incubator at 50 ℃ for 48 hours, the state of the bodies was observed and recorded, and the results are reported in Table 1.
In the table, "-" indicates no measurement.
Claims (10)
1. The composition with the function of removing blood stains is characterized by comprising the following raw materials in parts by weight: 1-80 parts of anionic surfactant, 0.1-40 parts of zwitterionic surfactant, 0.1-70 parts of nonionic surfactant, 0-6 parts of polymer emulsion, 0.1-5 parts of protease, 0.1-5 parts of chelating agent and the balance of deionized water to 100 parts.
2. The composition with the effect of removing blood stains according to claim 1, wherein the mass ratio of the anionic surfactant to the zwitterionic surfactant to the nonionic surfactant is (1-12): (1-4): (1-7).
3. The composition for removing blood stains according to claim 1 or 2, wherein the anionic surfactant is at least one of sodium fatty alcohol polyether sulfate, sodium alkyl sulfonate, sodium lauroyl sarcosinate and sodium cocoyl glutamate.
4. A composition for removing blood stains according to claim 3, wherein the anionic surfactant is a combination of sodium fatty alcohol polyether sulfate, sodium alkyl sulfonate, sodium lauroyl sarcosinate and sodium cocoyl glutamate.
5. The composition for removing blood stains according to claim 4, wherein the zwitterionic surfactant is a combination of cocamidopropyl betaine and lauramidopropyl betaine.
6. The composition with blood stain removing effect according to claim 5, wherein the non-ionic surfactant is selected from one or more of fatty acid methyl ester ethoxylate, fatty alcohol-polyoxyethylene ether and alkyl glucoside.
7. The composition for removing blood stains according to claim 6, wherein the nonionic surfactant is a combination of fatty acid methyl ester ethoxylate, fatty alcohol-polyoxyethylene ether and alkyl glucoside.
8. The composition with the bloodstain removing function according to claim 7, wherein the polymer emulsion comprises 0.1-5 parts by weight of acrylate copolymer emulsion and 0.1-1 part by weight of styrene/acrylic acid emulsion.
9. The composition for removing blood stains according to claim 8, wherein the chelating agent is at least one of tetrasodium glutamate diacetate, trisodium methylglycine diacetate, and an iron ion chelating agent.
10. A method for preparing a composition for removing blood stains according to any one of claims 1 to 9, comprising at least the steps of:
(1) Adding anionic surfactant into deionized water in weight portion, at 70-90 deg.c,
stirring for 25-35 min to obtain solution A;
(2) Sequentially adding a zwitterionic surfactant and a nonionic surfactant into the solution A to obtain a solution B;
(3) Cooling to 40-50 deg.C, adding polymer emulsion, chelating agent, and protease into solution B, stirring and mixing for 10-30min, and cooling to 20-30 deg.C.
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| EP3486303A1 (en) * | 2017-11-21 | 2019-05-22 | Henkel IP & Holding GmbH | Laundry composition having broad spectrum stain removal |
| CN111808685A (en) * | 2020-06-30 | 2020-10-23 | 纳爱斯浙江科技有限公司 | Detergent composition |
| CN112442427A (en) * | 2020-12-04 | 2021-03-05 | 株洲千金药业股份有限公司 | Detergent capable of effectively removing bloodstains and preparation method thereof |
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2022
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0426906A1 (en) * | 1989-11-06 | 1991-05-15 | Colgate-Palmolive Company | Heavy duty fabric softening laundry detergent composition |
| CN104031753A (en) * | 2014-05-27 | 2014-09-10 | 广州立白企业集团有限公司 | Detergency-improved tableware detergent composition with suspended particles |
| EP3486303A1 (en) * | 2017-11-21 | 2019-05-22 | Henkel IP & Holding GmbH | Laundry composition having broad spectrum stain removal |
| CN108676629A (en) * | 2018-06-13 | 2018-10-19 | 北京日光旭升精细化工技术研究所 | Remove bloodstain cleaning agent and preparation method thereof |
| CN111808685A (en) * | 2020-06-30 | 2020-10-23 | 纳爱斯浙江科技有限公司 | Detergent composition |
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