CN115413680A - Biological composite odor-removing bactericide and preparation method thereof - Google Patents

Biological composite odor-removing bactericide and preparation method thereof Download PDF

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Publication number
CN115413680A
CN115413680A CN202211141990.1A CN202211141990A CN115413680A CN 115413680 A CN115413680 A CN 115413680A CN 202211141990 A CN202211141990 A CN 202211141990A CN 115413680 A CN115413680 A CN 115413680A
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odor
bactericide
biological composite
modified
composite odor
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焦海军
徐骏骅
朱志鹏
杨彬
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Zhuocong Shanghai Environmental Protection Technology Development Co ltd
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Zhuocong Shanghai Environmental Protection Technology Development Co ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02Acyclic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/12Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P1/00Disinfectants; Antimicrobial compounds or mixtures thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P3/00Fungicides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/013Deodorant compositions containing animal or plant extracts, or vegetable material
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2101/00Chemical composition of materials used in disinfecting, sterilising or deodorising
    • A61L2101/32Organic compounds
    • A61L2101/44Heterocyclic compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • Wood Science & Technology (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
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Abstract

The invention discloses a biological composite odor-removing bactericide and a preparation method thereof, wherein the odor-removing bactericide comprises the following components in percentage by mass: 1.0-3.0% of polyhydroxy alcohol natural plant extract, 0.05-0.15% of modified isothiazolinone derivative, 0.01-0.03% of fluorine-containing surfactant and the balance of deionized water, wherein the polyhydroxy alcohol natural plant extract, the modified isothiazolinone derivative and the fluorine-containing surfactant are slowly added into the deionized water under ventilation conditions, stirred and subjected to homogenization reaction to obtain the modified isothiazolinone derivative. The biological compound odor-removing bactericide is sprayed on the surface of an object or in the air, can quickly adsorb and eliminate odor gas in the environment, quickly kill various harmful germs with a killing rate of over 99.5 percent, is safe and harmless to the body surface of a human body, and is suitable for odor-removing and killing operation in most human living environments under the condition of not sucking food in a large amount.

Description

Biological composite odor-removing bactericide and preparation method thereof
Technical Field
The invention belongs to the field of environmental cleaning and disinfection, and particularly relates to a biological composite odor-removing bactericide and a preparation method thereof.
Background
Under the current situation of industrialization and globalization, the requirements of people on the quality of life are continuously increased; but industrial pollution and environmental pollution are also reality that people have to face as one of the by-products of industrialization and globalization. And environmental odor and the diffusion of various germs caused by comprehensive pollution are the sanitary and clean problems often encountered in daily life of people.
With the improvement of the quality of life, when an unclean environment is met, the environment odor can be quickly and simply eliminated, common germs can be killed, and the effect is expected by people; meanwhile, in most cases, environmental odor and common harmful germs are often associated or even mutually promoted. Aiming at the phenomenon of bad symbiosis and according to the harmful working mechanism, a multifunctional composite odor-removing bactericide is urgently needed to rapidly eliminate the environmental odor and kill harmful germs at the same time, so as to realize lasting clean and comfortable environment.
Disclosure of Invention
The invention mainly aims to provide a biological compound odor-removing bactericide which integrates biological safety, harmlessness, simple and easy operation and high-efficiency synergistic odor-removing, sterilizing and killing functions, and realizes double effects of quickly removing environmental odor and common odor and efficiently killing germs.
Another object of the present invention is to provide a preparation method of the biological composite odor-removing bactericide, which is simple and easy for mass production.
In order to achieve the purpose, the invention adopts the technical scheme that:
the invention provides a biological composite odor-removing bactericide which comprises the following components in percentage by mass:
1.0-3.0% of polyhydroxy alcohol natural plant extract;
0.05 to 0.15 percent of modified isothiazolinone derivative;
0.01 to 0.03 percent of fluorine-containing surfactant;
the balance being deionized water.
Preferably, the formulation of the biological composite odor-removing bactericide is a homogeneous aqueous agent or a spray.
Preferably, the polyhydroxy alcohol natural plant extract is a natural polyol substance separated and purified from honeysuckle or bitter chrysanthemum, can quickly adsorb common odor gas molecules or odor aerosol in the environment, is convenient for high-efficiency odor removal, and preferably has a mass percentage of 2%.
Preferably, the modified isothiazolinone derivative is a modified isothiazolinone compound containing a peroxide bond, and the chemical formula is C 10 H 9 ClN 2 O 4 S 2 Structural formula is
Figure BDA0003853993520000021
The odor removing and sterilizing agent is a high-activity compound containing peroxide groups and a high-efficiency germ-killing substance, can rapidly oxidize odor gas molecules into tasteless substances through an autocatalytic oxidation effect, and can also powerfully destroy body surface proteins of germs and base skeletons on DNA chains of the body surface proteins, thereby rapidly and efficiently removing odor and killing germs, and the mass percentage content of the odor removing and sterilizing agent is preferably 0.1%.
Preferably, the fluorine-containing surfactant is a perfluorohexyl polyoxyethylene ether compound with the structural formula of CF 3 -(CF 2 ) 5 -O-(CH 2 CH 2 O) 8 -CH 2 -OH, molecular formula C 23 H 35 F 13 O 10 In percentage by mass thereofThe amount was 0.02%. The surface tension of objects/organisms can be obviously reduced by adding a trace amount of the deodorant bactericide product, the surface tension of the body surface of pathogenic bacteria can be greatly reduced besides the product of the deodorant bactericide product is kept stable and homogeneous, the sterilizing component can be rapidly dissolved in the pathogenic bacteria, the efficient sterilization of the pathogenic bacteria is promoted, and the mass percentage of the sterilizing component is preferably 0.02%.
Preferably, the deionized water is high-purity deionized water and is a safe and environment-friendly carrier of active ingredients.
The invention also provides a preparation method of the biological composite odor-removing bactericide, which comprises the following steps:
step 1, adding the metered deionized water under ventilation condition by adopting a stainless steel stirring kettle with an emptying device and a stainless steel homogenizing kettle;
step 2, sequentially and slowly adding the polyhydroxy alcohol natural plant extract, the modified isothiazolinone derivative and the fluorine-containing surfactant into the stainless steel stirring kettle, and stirring for 10-20 minutes at the rotating speed of 100-300 rpm;
and 3, transferring the mixture obtained in the step 2 into the stainless steel homogenizing kettle, and homogenizing and reacting for 10-30 minutes at the rotating speed of 400-800rpm to obtain the product.
Preferably, in step 2, stirring is carried out at 200rpm for 15 minutes.
Preferably, in step 3, the reaction is homogenized for 20 minutes at a rotation speed of 600 rpm.
Compared with the prior art, the invention has the beneficial effects that:
(1) After the biological composite odor removing bactericide is sprayed into the air in large quantity, the plant extract, namely the polyalcohol substances can quickly and efficiently adsorb common odor gas molecules or odor aerosol in the environment, the modified isothiazolinone molecular structure contains active oxygen groups, oxygen in the air can be further combined in the polyalcohol molecular structure to generate high-activity free oxygen, and the odor gas molecules can be quickly oxidized into odorless molecules, so that the environmental odor can be quickly and efficiently removed.
(2) The modified isothiazolinone derivative is added, high-activity free oxygen is generated by combining oxygen in air, and meanwhile, under the synergistic permeation action of the fluorine-containing surfactant (the fluorine-containing surfactant can obviously reduce the surface energy of the body surface of pathogenic bacteria, so that the odor removal bactericide is rapidly dissolved into the body surface and even the body of the pathogenic bacteria), the modified isothiazolinone derivative can be rapidly combined, protein molecules on the body surface of pathogenic bacteria and organisms are oxidized to be damaged and inactivated, and meanwhile, the base skeleton of DNA of genetic materials of the pathogenic bacteria can be attacked and destroyed, namely: can destroy the biological structure and function of the pathogenic bacteria rapidly and irreversibly from the outside and the inside, thereby achieving the purpose of rapidly and efficiently killing harmful pathogenic bacteria.
(3) The biological compound deodorizing bactericide is sprayed on the surface of an object or in the air, can quickly adsorb and eliminate odor gas in the environment, quickly kill various harmful germs with a killing rate of over 99.5 percent, is safe and harmless to the body surface of a human body through tests, is suitable for deodorizing and killing operation in most human living environments under the condition of not sucking food in a large amount, and is an efficient multifunctional synergistic cleanser.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions of the embodiments of the present invention are clearly and completely described below. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the described embodiments of the invention without any inventive step, are within the scope of protection of the invention.
In the following examples, the natural plant extract of polyhydroxylated alcohols is natural polyalcohol substances separated and purified from honeysuckle; the modified isothiazolinone derivative is a modified isothiazolinone compound containing a peroxy bond and has a chemical formula of C 10 H 9 ClN 2 O 4 S 2 Structural formula is
Figure BDA0003853993520000031
The fluorine-containing surfactant isPerfluorohexyl polyoxyethylene ether compound with the structural formula of CF 3 -(CF 2 ) 5 -O-(CH 2 CH 2 O) 8 -CH 2 -OH, molecular formula C 23 H 35 F 13 O 10
The following examples prepare biological composite odor-removing bactericide by the following steps:
step 1, adding metered deionized water under ventilation conditions by adopting a stainless steel stirring kettle with an emptying device and a stainless steel homogenizing kettle;
step 2, sequentially and slowly adding the polyhydroxy alcohol natural plant extract, the modified isothiazolinone derivative and the fluorine-containing surfactant into a stainless steel stirring kettle, and stirring for 15 minutes at the rotating speed of 200 rpm;
and 3, transferring the mixture obtained in the step 2 into a stainless steel homogenizing kettle, and homogenizing and reacting for 20 minutes at the rotating speed of 600rpm to obtain the product.
Example 1
This example provides a biological composite odor-removing bactericide, which is prepared according to the following table, 1000g:
Figure BDA0003853993520000041
the components in the proportion are prepared according to the preparation method of the biological composite odor removing bactericide and then are filled for use, and tests show that the odor removing bactericide of the embodiment can be used for quickly removing odor and killing germs.
Example 2
This example provides a biological composite odor-removing bactericide, which is prepared according to the following table, 1000g:
Figure BDA0003853993520000042
the components in the proportion are prepared according to the preparation method of the biological composite odor removing bactericide and then are filled for use, and tests show that the odor removing bactericide of the embodiment can be used for quickly removing odor and killing germs.
Example 3
This example provides a biological composite odor-removing bactericide, which is prepared according to the following table, 1000g:
Figure BDA0003853993520000043
the components in the proportion are prepared according to the preparation method of the biological composite odor removing bactericide and then are filled for use, and tests show that the odor removing bactericide of the embodiment can be used for quickly removing odor and killing germs.
Example 4
This example provides a biological composite odor-removing bactericide, which is prepared according to the following table, 1000g:
Figure BDA0003853993520000044
the components in the proportion are prepared according to the preparation method of the biological composite odor removing bactericide and then are filled for use, and tests show that the odor removing bactericide of the embodiment can be used for quickly removing odor and killing germs.
Example 5
This example provides a biological composite odor-removing bactericide, which is prepared according to the following table, 1000g:
Figure BDA0003853993520000051
the components in the proportion are prepared according to the preparation method of the biological composite odor removing bactericide and then are filled for use, and tests show that the odor removing bactericide of the embodiment can be used for quickly removing odor and killing germs.
Example 6
This example provides a biological composite odor-removing bactericide, which is prepared according to the following table, 1000g:
Figure BDA0003853993520000052
the components in the proportion are prepared according to the preparation method of the biological composite odor removing bactericide and then are filled for use, and tests show that the odor removing bactericide of the embodiment can be used for quickly removing odor and killing germs.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. It will be readily apparent to those skilled in the art that various modifications to these embodiments and the generic principles defined herein may be applied to other embodiments without the use of the inventive faculty. Therefore, the present invention is not limited to the above-described embodiments, and those skilled in the art should make improvements and modifications within the scope of the present invention according to the principle of the present invention without departing from the scope of the present invention.

Claims (9)

1. The biological composite deodorizing bactericide is characterized by comprising the following components in percentage by mass:
1.0-3.0% of polyhydroxy alcohol natural plant extract;
0.05 to 0.15 percent of modified isothiazolinone derivative;
0.01 to 0.03 percent of fluorine-containing surfactant;
the balance being deionized water.
2. The biological composite odor-removing bactericide as claimed in claim 1, wherein the dosage form of the biological composite odor-removing bactericide is homogeneous aqueous agent or spray.
3. The biological composite odor-removing bactericide as claimed in claim 1, wherein the natural plant extract of polyhydroxy alcohols is natural polyol substance separated and purified from honeysuckle or bitter chrysanthemum, and its mass percentage content is 2%.
4. An organism according to claim 1The composite odor-removing bactericide is characterized in that the modified isothiazolinone derivative is a modified isothiazolinone compound containing a peroxide bond and having a chemical formula of C 10 H 9 ClN 2 O 4 S 2 Structural formula is
Figure FDA0003853993510000011
The mass percentage content is 0.1 percent.
5. The biological composite odor-removing bactericide as claimed in claim 1, wherein said fluorine-containing surfactant is perfluorohexyl polyoxyethylene ether compound with molecular formula C 23 H 35 F 13 O 10 Structural formula is CF 3 -(CF 2 ) 5 -O-(CH 2 CH 2 O) 8 -CH 2 -OH, the mass percentage of which is 0.02%.
6. The biological composite odor-removing bactericide as claimed in claim 1, wherein the deionized water is high-purity deionized water.
7. A method for preparing a biological composite odor-removing bactericide as claimed in any one of claims 1 to 6, which comprises the following steps:
step 1, adding the metered deionized water under a ventilation condition by adopting a stainless steel stirring kettle with an emptying device and a stainless steel homogenizing kettle;
step 2, sequentially and slowly adding the polyhydroxy alcohol natural plant extract, the modified isothiazolinone derivative and the fluorine-containing surfactant into the stainless steel stirring kettle, and stirring for 10-20 minutes at the rotating speed of 100-300 rpm;
and 3, transferring the mixture obtained in the step 2 into the stainless steel homogenizing kettle, and carrying out homogenizing reaction for 10-30 minutes at the rotating speed of 400-800rpm to obtain the product.
8. The method for preparing the biological composite odor-removing bactericide as claimed in claim 7, wherein in step 2, stirring is carried out at 200rpm for 15 minutes.
9. The method for preparing the biological composite odor-removing bactericide according to claim 7, wherein in the step 3, the homogenization reaction is carried out for 20 minutes at the rotating speed of 600 rpm.
CN202211141990.1A 2022-09-20 2022-09-20 Biological composite odor-removing bactericide and preparation method thereof Pending CN115413680A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114946890A (en) * 2022-06-16 2022-08-30 卓聪(上海)环保科技发展有限公司 Biological environment-friendly disinfectant product for efficiently killing new coronavirus and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114946890A (en) * 2022-06-16 2022-08-30 卓聪(上海)环保科技发展有限公司 Biological environment-friendly disinfectant product for efficiently killing new coronavirus and preparation method thereof

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Application publication date: 20221202