CN115304337A - Heat-preservation and heat-insulation dry powder with health-care and health-preserving functions and preparation method and application thereof - Google Patents

Heat-preservation and heat-insulation dry powder with health-care and health-preserving functions and preparation method and application thereof Download PDF

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Publication number
CN115304337A
CN115304337A CN202211133211.3A CN202211133211A CN115304337A CN 115304337 A CN115304337 A CN 115304337A CN 202211133211 A CN202211133211 A CN 202211133211A CN 115304337 A CN115304337 A CN 115304337A
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heat
powder
dry powder
health
preservation
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关其焕
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00025Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Finishing Walls (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention belongs to the technical field of building materials, and particularly relates to heat-preservation and heat-insulation dry powder with health-care and health-preserving functions, and a preparation method and application thereof. The invention provides a heat-insulating dry powder with health care and health preserving functions, which comprises, by mass, 10-50% of ordinary silicate white cement, 10-50% of gray calcium, 2-50% of illite powder, 0.5-35% of tourmaline powder, 0.5-30% of talcum powder, 1-40% of calcite powder, 0.5-6% of redispersible latex powder, 0.1-1% of cellulose ether, 0.1-0.5% of hydrophobic agent and 0.1-5% of vitrified micro-beads. The heat preservation and insulation dry powder with the health care and health preserving functions has good effects of heat preservation, radiation protection and harmful substance absorption, permanently releases negative ions and infrared rays beneficial to human bodies, and has excellent health care and health preserving effects.

Description

Heat-preservation and heat-insulation dry powder with health-care and health-preserving functions as well as preparation method and application thereof
The application is a divisional application with application date of 2017, 11 and 08 days, application number of 201711092260.6 and invention name of 'a heat-preservation and heat-insulation dry powder wall decoration material with health care and health preserving functions'.
Technical Field
The invention belongs to the technical field of building materials, and particularly relates to heat-preservation and heat-insulation dry powder with health-care and health-preserving functions, and a preparation method and application thereof.
Background
The indoor air quality of the indoor space is an important factor influencing the body health of people, and how to improve the indoor air quality is a technical problem which must be solved by modern household environment.
Disclosure of Invention
Aiming at the problems in the prior art, the invention aims to provide the heat-preservation and heat-insulation dry powder with the health-care and health-preserving functions as well as the preparation method and the application thereof, and the powder is endowed with the capabilities of releasing negative ions, releasing infrared rays beneficial to human bodies, preventing radiation, absorbing and releasing volatile harmful substances such as formaldehyde and the like by modifying the functionality of the dry powder, so that the dry powder has the effect of building a healthy and health-preserving living environment.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
the heat-insulating dry powder wall decoration material with health care and health preserving functions is characterized by comprising, by mass, 10-50% of ordinary silicate white cement, 10-50% of gray calcium, 2-50% of illite powder, 0.5-30% of tourmaline powder, 0.5-30% of talcum powder, 1-40% of calcite powder, 0.5-6% of redispersible latex powder, 0.1-1% of cellulose ether, 0.1-0.5% of hydrophobic agent and 0.1-5% of vitrified micro-beads.
The preparation method of the heat-preservation and heat-insulation dry powder wall decorative material comprises the following specific steps: accurately weighing various materials according to the formula ratio, firstly putting other materials except the vitrified micro bubbles into a stirrer for mixing for 20 minutes, uniformly stirring, then adding the vitrified micro bubbles for mixing for 3 minutes, uniformly stirring, and finally packaging to obtain a finished product.
Further, the mass ratio of the heat-preservation and heat-insulation dry powder wall decoration material to water is 100.
The beneficial effects of the invention are: the invention has the effects of good heat insulation, heat preservation, permanent negative ion release, infrared ray release beneficial to human body, radiation protection and harmful substance absorption, and has obvious health care and health preserving effects.
Detailed Description
The present invention will be further described in detail with reference to examples, but the embodiments of the present invention are not limited thereto, and they should not be construed as limiting the scope of the present invention.
The components contained in the thermal insulation dry powder wall decoration material provided by the invention are specifically explained below.
< white cement >
The white Portland cement is made up by using raw material with proper composition, burning until it is partially molten, using calcium silicate as main component, adding proper quantity of gypsum into clinker with low iron content and grinding so as to obtain the invented white hydraulic cementing material. The white cement is characterized by higher whiteness and bright color, is generally used as various building decorative materials, typically whitewash, sculpture, ground and terrazzo products, can also be used for manufacturing white and colored concrete members, and is a decorative cement variety with the largest production scale. The content of the white cement in the dry powder wall decoration material is preferably 10-50% by mass, and by adopting the content range, a certain flexural strength and compressive strength can be provided for the dry powder wall decoration material.
< Ash calcium >
The lime-calcium is CaCO 3 The natural high-quality limestone as main component is calcined at high temp. to obtain raw lime (CaO), then carefully selected, partially digested and its main component is Ca (OH) 2 Then the mixture is crushed by a high-speed winnowing hammer type crusher, and the appearance of the mixture is pure white and fine. The content of the ash calcium in the dry powder wall decoration material is preferably 10-50% by mass, and by adopting the content range, certain strength can be provided for the dry powder wall decoration material, and the construction property is improved.
< illite powder >
Illite powder is prepared by processing illite into powder, is a common clay mineral, is usually prepared by weathering muscovite and potash feldspar, is produced in argillaceous rocks, or is formed by alteration of other minerals, and is an intermediate transitional mineral for forming other clay minerals. Pure illite clay is white but often stained yellow, green and brown due to impurities. Illite has excellent chemical and physical properties such as rich potassium, high aluminum, low iron, smoothness, brightness, fineness, heat resistance and the like. The illite can freely release negative ions and far infrared rays. The content of the illite powder in the invention is preferably 2-50% by mass, and by adopting the content range, the dry powder wall decorative material can provide functions of permanently releasing negative ions, inhibiting bacteria, purifying air and the like, and can decompose toxic substances and gases, release infrared rays beneficial to human bodies, protect radiation and ultraviolet rays and protect the living environment.
Tourmaline powder
Tourmaline powder is powder obtained by mechanically pulverizing raw tourmaline ore after removing impurities. The tourmaline powder after processing and purification has higher negative ion generation amount and far infrared emissivity. Tourmaline is also called tourmaline, and the chemical general formula of the tourmaline is NaR 3 Al 6 Si 6 O 18 BO 33 (OH,F) 4 The crystal belongs to a group of ring-structured silicate minerals of trigonal system, wherein R represents a metal cation, and when R is Fe 2+ Then the black crystal tourmaline is formed. The tourmaline crystal is in a column shape close to a triangle, the crystal forms at two ends are different, the column surface has longitudinal grains, the columnar, needle-shaped, radial and block aggregates are usually formed, the glass is glossy, the fracture is turpentine glossy, the fracture is translucent to transparent, no cleavage is generated, the Mohs hardness is 7-7.5, the specific gravity is 2.98-3.20, and the piezoelectric property and the pyroelectric property are realized. The content of the tourmaline powder in the invention is preferably 0.5-35% by mass, and by adopting the content range, the dry powder wall decorative material can provide the functions of releasing negative ions, killing germs and releasing far infrared rays, improve the air quality and improve the immunity of human bodies.
< Talc powder >
The talcum powder is white or white-like, fine and non-sandy powder, and has greasy feeling, no odor and no smell. The product is insoluble in water, dilute mineral acid or dilute hydroxide solution, and can be used for medicine. The preferred content of the talcum powder in the invention is 0.5-30% by mass, and the talcum powder can provide harmful substance adsorption and bacteriostasis functions for the dry powder wall decorative material.
< Calcite powder >
Calcite powder is heavy calcium, is short for heavy calcium carbonate, has the main component of heavy calcium carbonate, is also short for heavy calcium, is generally used as a filler, is widely used in daily chemical industries such as artificial floor tiles, rubber, plastics, papermaking, coatings, paints, printing ink, cables, building products, food, medicine, textile, feed, toothpaste and the like, and can be used as a filler to increase the volume of products and reduce the production cost. The content of the calcite powder is preferably 1-40% by mass, and by adopting the content range, the filler can be provided for the dry powder wall decoration material, so that the production cost is reduced.
< redispersible emulsion powder >
The redispersible emulsion powder is water-soluble redispersible powder which is divided into ethylene/vinyl acetate copolymer, vinyl acetate/vinyl versatate copolymer, acrylic acid copolymer and the like, is a powder adhesive prepared after spray drying, takes polyvinyl alcohol as protective colloid, and can be quickly redispersed into emulsion after contacting with water. Because the redispersible latex powder has high binding capacity and other unique properties, such as: water resistance, workability, heat insulation, and the like, and thus their application range is extremely wide. The redispersible latex powder has outstanding bonding strength, improves the flexibility of the mortar, has longer open time, endows the mortar with excellent alkali resistance, can improve the adhesion and the bonding property, the breaking strength, the waterproofness, the plasticity, the wear resistance and the constructability of the mortar, and has stronger flexibility in the flexible anti-crack mortar. The content of the redispersible latex powder is preferably 0.5 to 6 percent by mass, and by adopting the content range, slurry bonding and flexibility can be provided for the dry powder wall decorative material, so that the workability and the tensile strength of the material are improved.
< cellulose ethers >
Cellulose ether is a high molecular compound having an ether structure made of cellulose. The cellulose macromolecule contains three hydroxyl groups per glucosyl ring, a primary hydroxyl group on a sixth carbon atom and secondary hydroxyl groups on second and third carbon atoms, and the hydrogen in the hydroxyl group is replaced by a hydrocarbon group to form a cellulose ether derivative, which is a product of the cellulose macromolecule with the hydrogen of the hydroxyl group replaced by the hydrocarbon group. Cellulose is a polyhydroxy high molecular compound which is not dissolved or melted, and after etherification, the cellulose can be dissolved in water, dilute alkali solution and organic solvent and has thermoplasticity. The content of the cellulose ether in the invention is preferably 0.1-1% by mass, and by adopting the content range, the water content of the slurry can be provided for the dry powder wall decorative material of the invention, and the water loss and cracking can be prevented.
< Water repellent >
The hydrophobic agent is a mixed compound, is subjected to surface modification treatment by scientific technology, is dispersed in water to form a stable dispersoid, and can form a special water-resistant structure (change a contact angle) on the film-forming surface of the coating when added into the coating, so that the surface has extremely strong hydrophobic, hydrophobic and waterproof capabilities, the taste masking effect is improved, and the air permeability of a coating film is not influenced. The problem of poor recoatability of organosilicon hydrophobic materials is solved, and the problem of poor air permeability of other hydrophobing agents is also solved, so that the coating has good lotus leaf double hydrophobicity, self-cleaning property, hydrophobicity, waterproofness, stain resistance, scrub resistance and other properties. The content of the water repellent agent in the invention is preferably 0.1-0.5% by mass, and by adopting the content range, the water repellent, waterproof and air permeable performances can be provided for the dry powder wall decorative material, and the taste masking effect is improved.
< vitrified small ball >
The vitrified micro bubbles have certain particle strength due to surface vitrification, have very stable physical and chemical properties, strong aging resistance and weather resistance, excellent heat insulation, fire prevention and sound absorption properties, are suitable for various fields, and can be used as light filling aggregate and heat insulation, fire prevention, sound absorption and heat preservation materials. In the building material industry, the vitrified micro bubbles are used as lightweight aggregate, so that the fluidity and the self-resistance strength of mortar can be improved, the material shrinkage rate is reduced, the comprehensive performance of products is improved, and the comprehensive production cost is reduced. In the application of light dry-mixed mortar (heat preservation type, masonry type and plastering type), vitrified micro bubbles are used for replacing the traditional common expanded perlite and polyphenyl particles to be used as the light aggregate of the dry-mixed heat preservation mortar, so that the problems of high water absorption, easy pulverization, high volume shrinkage rate in slurry stirring, low later strength of products, hollowing and cracking and the like are solved, the defects of easy flammability, poor fire resistance, harmful gas generation at high temperature, low aging resistance and weather resistance, high rebound elasticity in construction and the like of polyphenyl particle organic materials are overcome, and the comprehensive performance and the construction performance of the heat preservation mortar are improved. The content of the vitrified micro bubbles in the invention is preferably 0.1-5% by mass, and by adopting the content range, the heat preservation, heat insulation, fire prevention and sound absorption effects can be provided for the dry powder wall decoration material.
Example 1
The heat-insulating dry powder wall decoration material with the health care and health preserving functions comprises, by mass, 30% of ordinary silicate white cement, 15% of gray calcium, 10% of illite powder, 4% of tourmaline powder, 5% of talcum powder, 30% of calcite powder, 1% of redispersible latex powder, 0.5% of cellulose ether, 0.2% of hydrophobic agent and 4.3% of vitrified micro bubbles.
The preparation method of the heat-preservation and heat-insulation dry powder wall decoration material comprises the following specific steps: accurately weighing various materials according to the formula ratio, firstly putting other materials except the vitrified micro bubbles into a stirrer for mixing for 20 minutes, uniformly stirring, then adding the vitrified micro bubbles for mixing for 3 minutes, uniformly stirring, and finally packaging to obtain a finished product.
The mass ratio of the heat-preservation and heat-insulation dry powder wall decoration material to water is 100.
Although the present invention has been described in detail with reference to the above embodiments, it is only a part of the embodiments, not all of the embodiments, and other embodiments can be obtained without inventive step according to the embodiments, and the embodiments are within the scope of the present invention.

Claims (7)

1. The heat-insulating dry powder with the health-care and health-preserving functions is characterized by comprising, by mass, 10-50% of white cement, 10-50% of gray calcium, 2-50% of illite powder, 0.5-35% of tourmaline powder, 0.5-30% of talcum powder, 1-40% of calcite powder, 0.5-6% of redispersible latex powder, 0.1-1% of cellulose ether, 0.1-0.5% of hydrophobic agent and 0.1-5% of vitrified micro-beads;
the preparation method of the heat-preservation and heat-insulation dry powder comprises the following specific steps:
accurately weighing various materials according to the formula ratio, putting the materials except the vitrified micro bubbles into a stirrer for mixing for 20 minutes, uniformly stirring, then adding the vitrified micro bubbles for mixing for 3 minutes, uniformly stirring, and finally packaging to obtain the heat-insulating dry powder.
2. The heat-insulating dry powder as claimed in claim 1, wherein the dry powder comprises, by mass, 30% of white cement, 15% of gray calcium, 10% of illite powder, 4% of tourmaline powder, 5% of talcum powder, 30% of calcite powder, 1% of redispersible latex powder, 0.5% of cellulose ether, 0.2% of hydrophobic agent and 4.3% of vitrified micro bubbles.
3. The heat-insulating dry powder according to any one of claims 1 to 2, wherein the tourmaline powder is black crystal tourmaline powder.
4. A heat preservation and insulation slurry with health care and health preserving functions is characterized in that raw materials comprise heat preservation and insulation dry powder and water, the mass ratio of the heat preservation and insulation dry powder to the water is 100.
5. The preparation method of the heat preservation and insulation dry powder of any one of claims 1 to 3 comprises the following specific steps:
accurately weighing various materials according to the formula ratio, putting the materials except the vitrified micro bubbles into a stirrer for mixing for 20 minutes, uniformly stirring, then adding the vitrified micro bubbles for mixing for 3 minutes, uniformly stirring, and finally packaging to obtain the heat-insulating dry powder.
6. Use of the heat-insulating dry powder of any one of claims 1 to 3 or the heat-insulating dry powder obtained by the preparation method of claim 5 as a wall decoration material.
7. The application according to claim 6, characterized in that it comprises the following steps: adding water into the heat-preservation and heat-insulation dry powder, uniformly stirring to obtain slurry, and painting the wall working surface by adopting the slurry; the mass ratio of the heat preservation and insulation dry powder to water is 100.
CN202211133211.3A 2017-11-08 2017-11-08 Heat-preservation and heat-insulation dry powder with health-care and health-preserving functions and preparation method and application thereof Pending CN115304337A (en)

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CN107746227A (en) * 2017-11-08 2018-03-02 关其焕 A kind of heat insulating dry powder wall decorative material for having health functionses
CN111560178B (en) * 2020-07-04 2021-11-23 信息产业电子第十一设计研究院科技工程股份有限公司 zero-VOC inorganic fire-resistant functional coating suitable for electronic clean workshop and preparation method thereof
CN112456926A (en) * 2020-09-08 2021-03-09 北京盛德致远工程技术有限公司 Repair material and application thereof
CN114163178A (en) * 2021-12-15 2022-03-11 广州市昌福环保新材料股份有限公司 Multipurpose mixture capable of releasing negative ions to decompose formaldehyde and preparation method thereof

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Application publication date: 20221108