CN115300405A - 一种具有护色效果的发用组合物及其制备方法和应用 - Google Patents
一种具有护色效果的发用组合物及其制备方法和应用 Download PDFInfo
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- CN115300405A CN115300405A CN202210964377.3A CN202210964377A CN115300405A CN 115300405 A CN115300405 A CN 115300405A CN 202210964377 A CN202210964377 A CN 202210964377A CN 115300405 A CN115300405 A CN 115300405A
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Abstract
本发明属于日用化学品技术领域,公开了一种具有护色效果的发用组合物及其制备方法和应用。所述发用组合物包括以下重量份数的组分:牛磺酸盐类表面活性剂5~30份、两性表面活性剂1~5份,成膜剂0.2~2份、油脂1~5份、悬浮剂0~5份、增稠剂0~2份、外观改良剂0~2份、香精0~0.5份、防腐剂0~0.5份、水53~91.8份。本发明提供的发用组合物,不含任何染料或色素,依靠牛磺酸盐表面活性剂自身的温和性和对头发蛋白的亲和力,以及它和阳离子聚合物之间的絮胶原理在头发上沉积硅油等油脂从而成膜,起到锁色固色、减缓褪色的效果。而且该发用组合物具有一定的调理性能,对烫染和未烫染的头发均适用。
Description
技术领域
本发明属于日用化学品技术领域,具体涉及一种具有护色效果的发用组合物及其制备方法和应用。
背景技术
随着生活水平的提高,越来越多的消费者追求时尚,烫发染发的群体也相应增多。然而,任何一种染发剂都不能永久地保留发色不变。日光照射、清洗、热风等因素都会造成染后头发颜色的光泽度下降。
专利CN108938472A公开了一种色素沉淀类护色洗发水制备工艺,通过用额外色素补色的方法来弥补洗发过程中染料分子的脱落造成的褪色,是目前最常用的针对染发褪色解决方案。但这种香波产品中色素含量非常高,容易沾染皮肤,且大部分色素随冲洗过程中排入下水道,会给水生物环境带来一定的影响。专利CN112933002A公开了一种具有头发护色作用的洗护发组合物及其制备方法和应用,主要利用澳洲坚果籽油、大果越桔果提取物、硅等大量油脂来成膜,减少头发颜色的褪色。但,它采用的是月桂醇聚醚硫酸酯铵体系,清洁力较强,相对而言刺激性也较强。专利CN107789223A公开了一种护色提亮香波组合物,采用了氨基酸表面活性剂,但对氨基酸表面活性剂难增稠和甲基牛磺酸钠无过多的介绍。
专利CN114224765A公开了一种氨基酸表面活性剂,包含牛磺酸盐并配合特定种类的增稠剂,提供的氨基酸洗发水具有较高的粘度和透明度,在低温下可纺性能依旧优越、流动性和蘸取性良好,具有较好的头发和头皮护理功效。专利CN114010520A公开了一种个人护理组合物,以N-烷酰基牛磺酸钠为主要阴离子表面活性剂,利用N-烷酰基牛磺酸盐与两性表面活性剂之间的协同性作用,制备出的个人护理组合物中无硫酸盐,除了必要的温和性外,还具有优异的发泡性能、粘度以及长期稳定性等。专利CN108697608A公开了一种不含硫酸盐的水性个人护理组合物,通过甲基油酰基牛磺酸盐、羟乙基磺酸盐、两性表面活性剂或两性离子表面活性剂的组合物使得有可能实现组合物的粘度、发泡特性与调理之间的可接受的折衷。上述专利技术虽然公开了牛磺酸盐类表面活性剂和两性表面活性剂的复配组合,但主要侧重于表面活性剂常规的发泡性能、粘度、稳定性、温和性等性能,而对于表面活性剂的选择与护色效果的关系,则未有相应的研究。
发明内容
针对以上现有技术存在的缺点和不足之处,本发明的首要目的在于提供一种具有护色效果的发用组合物。本发明提供的具有护色作用的发用组合物选用牛磺酸盐类做主表活体系,较温和洁净,且辅助成膜效果优于硫酸盐表面活性剂。它能够修护头发表面翘起的毛鳞片,恢复头发表面的疏水性保护膜,减少头发受到的损伤,对头发颜色起到护理和养护作用。能够为染后的头发提供从发根到发梢的护理,从而锁色固色。
本发明的另一目的在于提供上述具有护色效果的发用组合物的制备方法。
本发明的再一目的在于提供上述具有护色效果的发用组合物在洗发和护发产品中的应用。
本发明目的通过以下技术方案实现:
一种具有护色效果的发用组合物,包括以下重量份数的组分:
牛磺酸盐类表面活性剂5~30份、两性表面活性剂1~5份,成膜剂0.2~2份、油脂1~5份、悬浮剂0~5份、增稠剂0~2份、外观改良剂0~2份、香精0~0.5份、防腐剂0~0.5份、水53~91.8份。
进一步地,所述牛磺酸盐类表面活性剂为脂肪酰甲基牛磺酸盐和脂肪酰甲基牛磺酸牛磺酸盐中的至少一种。
进一步优选地,所述脂肪酰甲基牛磺酸盐为甲基椰油酰基牛磺酸钠、甲基月桂酰基牛磺酸钠、甲基肉豆蔻酰基牛磺酸钠中的至少一种;所述脂肪酰甲基牛磺酸牛磺酸盐为椰油酰甲基牛磺酸牛磺酸钠、月桂酰甲基牛磺酸牛磺酸钠、肉豆蔻酰基甲基牛磺酸牛磺酸钠中的至少一种。
更优选地,所述牛磺酸盐类表面活性剂为甲基椰油酰基牛磺酸钠或甲基椰油酰基牛磺酸牛磺酸钠。
进一步地,所述两性表面活性剂为脂肪酰两性基乙酸钠、脂肪酰两性基二乙酸钠、脂肪酰胺丙基甜菜碱、脂肪酰胺羟丙基磺基甜菜碱中的至少一种。
进一步地优选地,所述两性表面活性剂为脂肪酰胺羟丙基磺基甜菜碱。在牛磺酸盐体系,它可辅助增稠,使组合物体系更加稳定。也能有效促进絮胶的持续时间,改善组合物的调理效果。
进一步地,所述成膜剂为聚季铵盐类、阳离子瓜尔胶中的至少一种;所述聚季铵盐类为聚季铵盐-10、聚季铵盐-4、聚季铵盐-47、聚季铵盐-22中的至少一种;所述阳离子瓜尔胶为瓜尔胶羟丙基三甲基氯化铵、羟丙基瓜尔胶羟丙基三甲基氯化铵中的至少一种。
进一步优选地,所述聚季铵盐类为聚季铵盐-47,所述阳离子瓜尔胶为瓜尔胶羟丙基三甲基氯化铵。
成膜剂主要提供成膜和调理作用。如果它带电量高会更加容易在头发上成膜,但过度强的分子作用力,会导致配方的兼容性、稳定性出现问题,例如絮凝导致浑浊等。在本发明中成膜剂选择为特定的阳离子聚合物,其与牛磺酸盐类表面活性剂之间的絮胶作用在头发上沉积硅油等油脂从而成膜,起到显著改善的锁色固色效果。
进一步地,所述油脂为硅油、天然油脂中的至少一种;所述硅油为甲基硅油、挥发性硅油、水溶性硅油、苯基硅油、乳化硅油和氨基硅油中的至少一种。优选乳化硅油。
进一步地,所述悬浮剂为卡波姆、丙烯酸(酯)类/C10-30烷醇丙烯酸酯交联聚合物中的至少一种;所述增稠剂为椰油酰胺MEA;所述外观改良剂为珠光片。
上述具有护色效果的发用组合物的制备方法,包括以下步骤:
(1)将悬浮剂和水预分散加入反应器中,混合搅拌均匀,得混合物A;
(2)升温至70~75℃,将牛磺酸盐类表面活性剂、两性表面活性剂、增稠剂、外观改良剂加入A中,搅拌均匀,得到混合物B;
(3)将成膜剂加入B中,搅拌均匀,得到混合物C;
(4)降温至40℃以下,将油脂加入C中,搅拌均匀,调节pH和粘度,加入香精和防腐剂,搅拌均匀出料,得到具有护色效果的发用组合物。
上述具有护色效果的发用组合物在洗发和护发产品中的应用。
与现有技术相比,本发明的有益效果是:
(1)本发明采用牛磺酸盐表面活性剂作为主表面活性剂,它泡沫性能优良,也是氨基酸表面活性剂的一种。它对头发的亲和力好,具有明显改善头发角蛋白持水力的作用:可能因此能够抑制染色头发的褪色作用。发用组合物的整体效果的优异性还在于弱酸性pH条件下,对人体比较温和,依靠氨基酸表活体系的絮凝沉积行为成膜,达到比较好的护色锁色保护作用。
(2)本发明提供的发用组合物,不含任何染料或色素,依靠牛磺酸盐表面活性剂自身的温和性和对头发蛋白的亲和力,以及它和阳离子聚合物之间的絮胶原理在头发上沉积硅油等油脂从而成膜,起到锁色固色、减缓褪色的效果。而且该发用组合物具有一定的调理性能,对烫染和未烫染的头发均适用。
具体实施方式
下面结合实施例对本发明作进一步详细的描述,但本发明的实施方式不限于此。
实施例1
本实施例的一种具有护色效果的发用组合物,包括以下重量份数的组分:
本实施例的具有护色效果的发用组合物通过如下方法制备得到:
(1)将卡波姆和去离子水预分散加入反应器中,混合搅拌均匀,得混合物A;
(2)升温至70~75℃,将甲基椰油酰基牛磺酸钠、椰油酰胺丙基甜菜碱、椰油酰胺MEA、珠光片加入A中,搅拌均匀,得到混合物B;
(3)将聚季铵盐-47和瓜尔胶羟丙基三甲基氯化铵加入B中,搅拌均匀,得到混合物C;
(4)降温至40℃以下,将乳化硅油加入C中,搅拌均匀,加入柠檬酸和NaCl调节pH和粘度,加入香精和防腐剂,搅拌均匀出料,得到具有护色效果的发用组合物。
实施例2
本实施例的一种具有护色效果的发用组合物,包括以下重量份数的组分:
本实施例的具有护色效果的发用组合物通过如下方法制备得到:
(1)将卡波姆和去离子水预分散加入反应器中,混合搅拌均匀,得混合物A;
(2)升温至70~75℃,将甲基月桂酰基牛磺酸钠、椰油酰胺丙基甜菜碱、椰油酰胺MEA、珠光片加入A中,搅拌均匀,得到混合物B;
(3)将聚季铵盐-47和瓜尔胶羟丙基三甲基氯化铵加入B中,搅拌均匀,得到混合物C;
(4)降温至40℃以下,将乳化硅油加入C中,搅拌均匀,加入柠檬酸和NaCl调节pH和粘度,加入香精和防腐剂,搅拌均匀出料,得到具有护色效果的发用组合物。
实施例3
本实施例的一种具有护色效果的发用组合物,包括以下重量份数的组分:
本实施例的具有护色效果的发用组合物通过如下方法制备得到:
(1)将卡波姆和去离子水预分散加入反应器中,混合搅拌均匀,得混合物A;
(2)升温至70~75℃,将椰油酰基甲基牛磺酸牛磺酸钠、椰油酰胺丙基甜菜碱、椰油酰胺MEA、珠光片加入A中,搅拌均匀,得到混合物B;
(3)将聚季铵盐-47和瓜尔胶羟丙基三甲基氯化铵加入B中,搅拌均匀,得到混合物C;(4)降温至40℃以下,将乳化硅油加入C中,搅拌均匀,加入柠檬酸和NaCl调节pH和粘度,加入香精和防腐剂,搅拌均匀出料,得到具有护色效果的发用组合物。
对比例1
本对比例与实施例1相比,用月桂醇聚醚硫酸酯钠代替甲基椰油酰基牛磺酸钠做主表活,其余相同。
对比例2
本对比例为某市售产品(硫酸盐主表活),不含色素和防晒剂。
对比例3
本对比例与实施例1相比,不添加聚季铵盐-47和瓜尔胶羟丙基三甲基氯化铵,其余有效成分及含量相同。
对比例4
本对比例与实施例1相比,不添加乳化硅油,其余有效成分及含量相同。
对比例5
本对比例与实施例1相比,椰油酰胺丙基甜菜碱的添加量为1%,其余有效成分及含量相同。
护色功效评价测试
实验方法:
选取同一批次的发束,使用相同漂白剂漂白至8-9度,接着染发剂进行染色,洗涤后自然风干,测试发束基础L、a、b值,计算dE值。dE越小,表示护色效果越好。
护色效果测试方法:
用实施例提供的发用组合物和对比例去洗涤发束,自然风干后再用标准光源照射2h,用发用组合物循环洗涤8次;恒温恒湿后测试L、a、b值,计算dE值。
Lab值的测试方法:
选取同一批次相同颜色染发发束,将处理后的发束在恒温恒湿的条件下自然晾干。将发束平铺于白板上,保证发束均匀不透光,用荧光白度计,型号WSD-3U在每束发束上正反面的中段各取3个位置进行测试,求平均值分别得到L、a、b值;在发束处理前会先进行基础Lab值的测试,得L0、a0、b0值。
dE=(△L2+△a2+△b2)1/2;
相应测试结果如下表1所示。
表1dE得分
实施例1 | 实施例2 | 实施例3 | 对比例1 | 对比例2 | 对比例3 | 对比例4 | 对比例5 | |
dE | 11.3 | 12.5 | 10.9 | 20.5 | 16.7 | 19.0 | 17.6 | 13.4 |
由表1结果可见,本发明采用牛磺酸盐表面活性剂作为主表面活性剂,配合特定的两性表面活性剂、阳离子聚合物和油脂成分,所得组合物具有明显改善的护色效果。特别是牛磺酸盐表面活性剂、阳离子聚合物和油脂三者的协同作用效果明显。其原因在于依靠牛磺酸盐表面活性剂自身的温和性和对头发蛋白的亲和力,以及它和阳离子聚合物之间的絮胶原理在头发上沉积硅油等油脂从而成膜,起到锁色固色、减缓褪色的效果。
上述实施例为本发明较佳的实施方式,但本发明的实施方式并不受上述实施例的限制,其它的任何未背离本发明的精神实质与原理下所作的改变、修饰、替代、组合、简化,均应为等效的置换方式,都包含在本发明的保护范围之内。
Claims (10)
1.一种具有护色效果的发用组合物,其特征在于,包括以下重量份数的组分:
牛磺酸盐类表面活性剂5~30份、两性表面活性剂1~5份,成膜剂0.2~2份、油脂1~5份、悬浮剂0~5份、增稠剂0~2份、外观改良剂0~2份、香精0~0.5份、防腐剂0~0.5份、水53~91.8份。
2.根据权利要求1所述的一种具有护色效果的发用组合物,其特征在于,所述牛磺酸盐类表面活性剂为脂肪酰甲基牛磺酸盐和脂肪酰甲基牛磺酸牛磺酸盐中的至少一种;所述脂肪酰甲基牛磺酸盐为甲基椰油酰基牛磺酸钠、甲基月桂酰基牛磺酸钠、甲基肉豆蔻酰基牛磺酸钠中的至少一种;所述脂肪酰甲基牛磺酸牛磺酸盐为椰油酰甲基牛磺酸牛磺酸钠、月桂酰甲基牛磺酸牛磺酸钠、肉豆蔻酰基甲基牛磺酸牛磺酸钠中的至少一种。
3.根据权利要求2所述的一种具有护色效果的发用组合物,其特征在于,所述牛磺酸盐类表面活性剂为甲基椰油酰基牛磺酸钠或甲基椰油酰基牛磺酸牛磺酸钠。
4.根据权利要求1所述的一种具有护色效果的发用组合物,其特征在于,所述两性表面活性剂为脂肪酰两性基乙酸钠、脂肪酰两性基二乙酸钠、脂肪酰胺丙基甜菜碱、脂肪酰胺羟丙基磺基甜菜碱中的至少一种。
5.根据权利要求1所述的一种具有护色效果的发用组合物,其特征在于,所述成膜剂为聚季铵盐类、阳离子瓜尔胶中的至少一种;所述聚季铵盐类为聚季铵盐-10、聚季铵盐-4、聚季铵盐-47、聚季铵盐-22中的至少一种;所述阳离子瓜尔胶为瓜尔胶羟丙基三甲基氯化铵、羟丙基瓜尔胶羟丙基三甲基氯化铵中的至少一种。
6.根据权利要求5所述的一种具有护色效果的发用组合物,其特征在于,所述聚季铵盐类为聚季铵盐-47,所述阳离子瓜尔胶为瓜尔胶羟丙基三甲基氯化铵。
7.根据权利要求1所述的一种具有护色效果的发用组合物,其特征在于,所述油脂为硅油、天然油脂中的至少一种;所述硅油为甲基硅油、挥发性硅油、水溶性硅油、苯基硅油、乳化硅油和氨基硅油中的至少一种。
8.根据权利要求1所述的一种具有护色效果的发用组合物,其特征在于,所述悬浮剂为卡波姆、丙烯酸(酯)类/C10-30烷醇丙烯酸酯交联聚合物中的至少一种;所述增稠剂为椰油酰胺MEA;所述外观改良剂为珠光片。
9.权利要求1~8任一项所述的一种具有护色效果的发用组合物的制备方法,其特征在于,包括以下步骤:
(1)将悬浮剂和水预分散加入反应器中,混合搅拌均匀,得混合物A;
(2)升温至70~75℃,将牛磺酸盐类表面活性剂、两性表面活性剂、增稠剂、外观改良剂加入A中,搅拌均匀,得到混合物B;
(3)将成膜剂加入B中,搅拌均匀,得到混合物C;
(4)降温至40℃以下,将油脂加入C中,搅拌均匀,调节pH和粘度,加入香精和防腐剂,搅拌均匀出料,得到具有护色效果的发用组合物。
10.权利要求1~8任一项所述的一种具有护色效果的发用组合物在洗发和护发产品中的应用。
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