CN115287503A - Aluminum-beryllium intermediate alloy and preparation method thereof - Google Patents
Aluminum-beryllium intermediate alloy and preparation method thereof Download PDFInfo
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- 239000000956 alloy Substances 0.000 title claims abstract description 92
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 91
- SOWHJXWFLFBSIK-UHFFFAOYSA-N aluminum beryllium Chemical compound [Be].[Al] SOWHJXWFLFBSIK-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 55
- 229910052790 beryllium Inorganic materials 0.000 claims abstract description 55
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims abstract description 55
- 238000001816 cooling Methods 0.000 claims abstract description 51
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 28
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000002844 melting Methods 0.000 claims abstract description 22
- 230000008018 melting Effects 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 20
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 18
- 239000011701 zinc Substances 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- 229910052718 tin Inorganic materials 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 14
- 238000005266 casting Methods 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 238000003723 Smelting Methods 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 238000007670 refining Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000007769 metal material Substances 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 239000002826 coolant Substances 0.000 claims description 2
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical group ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 claims description 2
- 238000005204 segregation Methods 0.000 abstract description 11
- 230000035882 stress Effects 0.000 description 10
- 229910018167 Al—Be Inorganic materials 0.000 description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 239000011777 magnesium Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 229910000838 Al alloy Inorganic materials 0.000 description 8
- 229910052749 magnesium Inorganic materials 0.000 description 8
- 229910000952 Be alloy Inorganic materials 0.000 description 7
- 230000007547 defect Effects 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
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- 238000007254 oxidation reaction Methods 0.000 description 4
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- 210000001787 dendrite Anatomy 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910000861 Mg alloy Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000048 melt cooling Methods 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
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- 238000012545 processing Methods 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/04—Influencing the temperature of the metal, e.g. by heating or cooling the mould
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/026—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/06—Making non-ferrous alloys with the use of special agents for refining or deoxidising
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
The invention relates to an aluminum-beryllium intermediate alloy and a preparation method thereof, wherein the raw materials of the aluminum-beryllium intermediate alloy comprise 0.05-0.4 part by weight of tin, 0.05-0.3 part by weight of zinc, 1-5 parts by weight of beryllium and 93-98 parts by weight of aluminum. The aluminum-beryllium intermediate alloy is obtained by firstly uniformly mixing a beryllium-tin-zinc mixed melt with an aluminum melt, naturally cooling the mixture, and rapidly cooling the mixture to room temperature when the temperature of the mixture is reduced to 850-900 ℃. According to the invention, a small amount of tin and zinc are doped into the beryllium melt, the uniformly mixed beryllium-tin-zinc mixed melt is obtained under the combined action, and the addition of the tin and the zinc reduces the melting temperature of the mixed melt, so that the tin and the zinc can be better and more uniformly mixed with the aluminum melt. The invention also adopts a two-stage cooling process of natural cooling-rapid cooling, thereby reducing the segregation of beryllium and leading the aluminum-beryllium intermediate alloy to show excellent mechanical property and stress relaxation resistance.
Description
Technical Field
The invention belongs to the field of alloys, and particularly relates to an aluminum-beryllium intermediate alloy and a preparation method thereof.
Background
The intermediate alloy is an additive functional material, which is prepared by adding one or more simple substances into a metal serving as a matrix to solve the problems of easy burning loss, difficult melting of high melting point, high density, easy segregation and the like of the simple substances of the metal or improve the performance of the alloy.
The Al-base intermediate alloy is an additive product for regulating the components of molten Al, and is prepared through smelting some metal elements with relatively high smelting temperature to produce intermediate with Al, and the intermediate has obviously lowered smelting temperature, so that some metal elements with relatively high smelting temperature may be added into molten Al at relatively low temperature to regulate the element content in molten Al. The aluminum beryllium can obviously improve the organizational structure of the alloy, refine crystal grains, increase the strength and improve the cleanness, the fluidity and the corrosion resistance of aluminum or magnesium.
The aluminum-beryllium alloy is divided into beryllium-based aluminum alloy and aluminum-based beryllium alloy according to the beryllium content, wherein the aluminum-beryllium alloy with low beryllium content becomes aluminum-based beryllium alloy, also called aluminum-beryllium alloy, and the aluminum-beryllium intermediate alloy with the beryllium content of less than 5% is called aluminum-beryllium intermediate alloy and is generally used as an additive material of other alloy materials. The Al-Be-1, al-Be-3 and Al-Be-5 are generally commercialized, wherein the beryllium content is respectively 0.9-1.2%,2-4% and 4-6%, and aluminum-beryllium intermediate alloys with different beryllium contents can Be selected according to different requirements. The aluminum-beryllium intermediate alloy is mainly suitable for smelting aluminum alloy and magnesium alloy, can improve the cleanness, the flowability and the corrosion resistance of magnesium and aluminum, protect the oxidation and the combustion of the magnesium and the aluminum, reduce the oxidation loss of elements, improve the organizational structure of the alloy, refine crystal grains and increase the strength.
In the prior art, the preparation process of the aluminum-beryllium intermediate alloy is mainly obtained by melting and mixing a beryllium melt and an aluminum melt in a furnace under the action of a protective agent or a protective atmosphere. However, the difference between the melting points of beryllium and aluminum is large, with beryllium melting at 1280 ℃ and aluminum melting at 660 ℃. Furthermore, as can be seen from the phase diagram of beryllium aluminum, the alloy is actually eutectic at about 650 ℃, and is not a pure phase material. The length of the smelting time and the solidification time has influence on the performance of the aluminum-beryllium intermediate alloy. After the melting point of aluminum is exceeded, the longer the smelting time is, the higher the content of aluminum oxide is, the formation of metal oxide slag inclusion can influence the performance of the aluminum-beryllium intermediate alloy as an additive, and the compactness, the ductility and the hardness of the alloy are reduced. However, if the smelting time is too short, beryllium particles in the aluminum-beryllium intermediate alloy are not uniform in size, and the defects of micro pores can be accompanied, so that the performance of the alloy is affected. When the solidification time is too short, anisotropic coarse particles or flaky structures can appear, and the defects of micro pores can also be generated; if the solidification time is too long, two phases of beryllium and aluminum can be separated, and phenomena of dendrite and segregation can be generated, so that the performance is deteriorated, and even the product cannot be used.
Therefore, it is urgently needed to develop a new preparation method of aluminum-beryllium intermediate alloy, which reduces the phenomena of dendrite and segregation in the preparation process, reduces the slag inclusion of oxides in the intermediate alloy, and improves the dispersion condition of beryllium in an aluminum matrix so as to improve the performance of the aluminum-beryllium intermediate alloy as an additive in the preparation of other aluminum alloys.
CN202010477768.3 discloses a method for preparing aluminum beryllium alloy powder, in which an aluminum source is melted to form a liquid film by an arc method in a vacuum environment, and the liquid film is broken by centrifugal force.
CN201610754243.3 discloses a low beryllium-aluminum alloy and its preparation method, which comprises beryllium 1-5wt%, aluminum intermediate alloy 93-98wt%, and other trace elements 0.1-2wt%. The low beryllium aluminum alloy is obtained by adjusting the types and the proportions of trace elements and quenching by cooling water. The direct quenching with cooling water may result in coarse grains or micro pores, which may result in poor alloy performance, and thus the toughness of the intermediate alloy obtained by the patented method is insufficient.
CN202110965607.3 discloses a low-density high-modulus aluminum alloy, wherein beryllium accounts for 0.2-1.5%, li accounts for 2.5-3.5%, mn accounts for 1-3%, mg accounts for 0.05-2%, zr accounts for 0.05-0.15%, sc accounts for 0.05-0.15%, and the balance is aluminum. After casting and forming to obtain a cast ingot, annealing treatment, hot extrusion deformation, solid solution treatment and aging treatment are carried out to obtain the low-density high-modulus aluminum alloy. The casting and melting process is complex, and needs to be processed by different devices for many times, so that the operation cost and the operation difficulty of production enterprises are increased.
CN202110777069.5 discloses a method for preparing an aluminum beryllium intermediate alloy, wherein a vacuum furnace is not used in the method, an electric furnace is used for melting in a crucible, preheated metal beryllium is added into the deep part of aluminum liquid in batches, and the aluminum liquid is melted in a rotating manner. But the melting point of beryllium is as high as 1280 ℃, and the preheated metal beryllium at 600 ℃ is added into the aluminum liquid, so that the beryllium cannot be melted, and the patent method has the doubtful possibility of not obtaining the aluminum-beryllium intermediate alloy.
CN20201143840.5 discloses a preparation method of magnesium-aluminum-beryllium intermediate alloy for casting addition, which comprises preheating pure aluminum, pure magnesium and metal beryllium, then adding 3/4 of the preheated pure aluminum, heating and melting to obtain aluminum liquid, overheating to high temperature, adding the preheated metal beryllium in batches and stirring, adding the rest pure aluminum after the metal beryllium is completely melted, and adding the preheated pure magnesium after the pure aluminum is completely melted. And refining and casting to obtain the magnesium-aluminum-beryllium intermediate alloy. But it does not explore the properties of the obtained master alloy.
CN201910196180.8 discloses a preparation method of an aluminum beryllium intermediate alloy wire rod, which comprises the steps of heating aluminum water to 730-750 ℃ under the condition of argon, adding aluminum beryllium 10 alloy, heating to 710-830 ℃, refining, and carrying out hot rolling to obtain the aluminum beryllium intermediate alloy with the beryllium content of 0.1-5%. The patent uses aluminum beryllium 10 alloy (Be content is about 10%) to replace beryllium, and avoids the defect caused by too large difference between melting points of aluminum and beryllium. However, the performance of the master alloy obtained in the patent still needs to be improved.
Aluminum beryllium intermediate alloys are commonly added to magnesium and aluminum alloys to reduce oxidation slag inclusions and to densify the magnesium or aluminum oxide film layer, but aluminum beryllium alloys have a much higher melting point than magnesium and aluminum, making processing difficult, and are themselves susceptible to oxidation during addition to the magnesium and aluminum melt, affecting the ductility and hardness of the product.
Disclosure of Invention
The invention aims to provide an aluminum-beryllium intermediate alloy and a preparation method thereof. Because the difference between the melting points of beryllium and aluminum is large, the conventional smelting method has phase separation in the solidification process, so that the metallic beryllium is not uniformly dispersed in the aluminum melt, and the phenomena of dendritic crystals and segregation are generated, thereby affecting the performance of the alloy. The invention can reduce the dendritic crystal and segregation phenomena caused by the difference of melting points by controlling the cooling speed; however, the cooling speed is too fast, and casting defects such as shrinkage cavities and the like appear in the alloy, so that the mechanical properties such as the tensile strength, the yield strength and the like of the alloy are obviously reduced. The method comprises the steps of firstly carrying out a natural cooling process to fully eliminate casting defects among melts, and then carrying out a liquid nitrogen rapid cooling process to accelerate cooling, reduce dendrite and segregation phenomena, and finally obtain the aluminum-beryllium intermediate alloy with excellent performance.
In order to achieve the purpose, the invention provides an aluminum-beryllium intermediate alloy, which comprises 0.05-0.4 weight part of tin, 0.05-0.3 weight part of zinc, 1-5 weight parts of beryllium and 93-98 weight parts of aluminum.
Tin is a metal with a relatively low melting point, and an alloy with a relatively low melting point can be obtained by utilizing the characteristic of tin, but only a mixed phase of beryllium and tin can be obtained according to a binary phase diagram of beryllium and tin. In order to avoid the large difference between the melting points of beryllium and aluminum, the inventor adds a certain amount of zinc into the beryllium-tin melt, so that the beryllium-tin-zinc mixed melt can be fully and uniformly dispersed to obtain a relatively uniform single phase.
Furthermore, the aluminum-beryllium intermediate alloy comprises, by weight, 0.1-0.2 part of tin, 0.2-0.4 part of zinc, 1-5 parts of beryllium, 93-98 parts of aluminum and less than or equal to 0.3 part of other components.
Further, the aluminum-beryllium intermediate alloy is prepared by uniformly mixing a beryllium, tin and zinc mixed melt and an aluminum melt to obtain a mixed melt.
Furthermore, the mixed melt cooling is a cooling stage of natural cooling-rapid cooling.
The aluminum-beryllium intermediate alloy also contains other components with the weight percent less than or equal to 0.3 percent; the other components, such as impurity elements of iron, silicon, copper, nickel, etc., are impurities inevitably introduced into the raw material.
The second purpose of the invention is to provide a preparation method of the aluminum-beryllium intermediate alloy, which comprises the following steps:
(S1) heating beryllium in specified parts by mass in a smelting furnace until the beryllium is molten, adding tin powder and zinc powder in specified parts by mass in batches under the condition of stirring, and obtaining a beryllium-tin-zinc mixed melt after all metals are molten after the addition;
(S2) heating the aluminum with the specified mass part to be molten to obtain an aluminum melt, and heating the aluminum melt to 1100-1200 ℃;
(S3) slowly adding the beryllium-tin-zinc mixed melt obtained in the step (S1) into the aluminum melt obtained in the step (S2), stirring all the time, completely melting at 1100-1200 ℃, removing surface scum, adding a refining agent, and refining for 3-5 hours under heat preservation to obtain a mixed melt;
and (S4) adding the mixed melt into a casting mold with a cooling device, naturally cooling, starting the cooling device to enable the cooling rate to be 60-100 ℃/min when the melt is cooled to 850-900 ℃, and rapidly cooling to room temperature to obtain the aluminum-beryllium intermediate alloy.
The rapid cooling is realized by a cavity circulating cooling device of the casting mold, and the cooling medium is liquid nitrogen and can provide a cooling rate of 60-100 ℃/min. The invention adopts natural cooling firstly, fully eliminates the casting defects among the melts at a relatively slow cooling rate, and inhibits discontinuous precipitation; when the temperature is cooled to 850-900 ℃, the rapid cooling is changed, which is beneficial to reducing the segregation of beryllium. However, the cooling rate should not be too fast, which may result in destruction of the micro-crystalline phases in the alloy and thus in poor mechanical properties.
Further, in the step (S3), the refining agent is hexachloroethane and is added in an amount of 0.1 to 1wt% of the total mixed melt (the sum of the beryllium-tin-zinc mixed melt and the aluminum melt).
Further, steps (S1) to (S4) are performed under an inert atmosphere, which is one or a mixed gas of argon and nitrogen.
Furthermore, the metal materials used, i.e., metallic beryllium, metallic tin, metallic zinc, and metallic aluminum, need to be subjected to removal of impurities such as oxides on the surface before they are melted by heating.
Compared with the prior art, the invention achieves the following technical progress:
1. according to the invention, a small amount of tin and zinc are doped into the beryllium melt, the uniformly mixed beryllium-tin-zinc mixed melt is obtained under the combined action, the tin and the zinc are added, the mixed melt and the melting temperature are reduced, the aluminum-beryllium intermediate alloy can be better and more uniformly mixed with the aluminum melt, and the aluminum-beryllium intermediate alloy is prepared by cooling.
2. In the preparation process, a two-stage cooling process of natural cooling and rapid cooling is adopted, and the cooling rate of rapid cooling is screened according to the time for starting rapid cooling, so that the segregation of beryllium is reduced, and the aluminum-beryllium intermediate alloy has excellent stress relaxation resistance.
Drawings
FIG. 1 is a photograph of an aluminum beryllium master alloy ingot obtained in example 1.
Detailed Description
Example 1
(S1) heating 5 parts by mass of beryllium in a smelting furnace until the beryllium is molten, adding 0.2 part by mass of tin powder and 0.2 part by mass of zinc powder in three batches under the condition of stirring, and obtaining a mixed melt of the beryllium, the tin and the zinc after all metals are molten;
(S2) heating 95 parts by mass of aluminum ingot to be molten to obtain an aluminum melt, and heating the aluminum melt to 1100 ℃;
(S3) slowly adding the beryllium, tin and zinc mixed melt obtained in the step (S1) into the aluminum melt obtained in the step (S2), stirring all the time, completely melting at 1100 ℃, removing surface scum, and refining for 5 hours in a heat preservation way to obtain a mixed melt;
and (S4) adding the mixed melt into a casting mold with a cavity circulating cooling device, naturally cooling, starting a liquid nitrogen circulating cooling device to enable the cooling rate to be 60 ℃/min when the temperature of the melt is reduced to 850 ℃, and rapidly cooling to room temperature to obtain the aluminum-beryllium intermediate alloy.
The chemical components and impurities of the aluminum-beryllium intermediate alloy are tested according to the GB/T20975 rule, in order to test the segregation condition of the aluminum-beryllium intermediate alloy, the obtained alloy ingot is respectively arranged in an alloy central area, an upper layer, a lower layer, two outer sides and five areas in total, 3 samples are taken in each area, the content of Be elements is tested, the average value is calculated, the difference value between the highest value and the lowest value of the content of Be elements in the five areas is calculated, and the obtained result is shown in the following table 1:
TABLE 1 analysis of Al-Be intermediate alloy composition
Example 2
Other conditions and operations were the same as in example 1 except that 0.1 part by mass of tin powder and 0.3 part by mass of zinc powder were added. The chemical composition of the aluminum-beryllium intermediate alloy prepared in example 2 was tested, and the results are shown in table 2 below:
TABLE 2 analysis of Al-Be intermediate alloy composition
Example 3
The other conditions and operations were the same as in example 1 except that 0.15 parts by mass of tin powder and 0.25 parts by mass of zinc powder were added. The chemical composition of the aluminum-beryllium intermediate alloy prepared in example 3 was tested, and the results are shown in table 3 below:
TABLE 3 analysis of Al-Be intermediate alloy composition
Example 4
The other conditions and operations were the same as in example 1 except that in (S4), when the melt was cooled to 900 ℃, the liquid nitrogen circulation cooling device was turned on to reduce the temperature at a rate of 100 ℃/min, and the results are shown in the following table, 4:
TABLE 4 analysis of Al-Be intermediate alloy composition
Comparative example 1
The other conditions and operations were the same as in example 1 except that 0.4 parts by mass of tin powder was added and no zinc powder was added. The chemical components of the aluminum-beryllium intermediate alloy prepared in the comparative example 1 are tested, and the results are shown in the following table 5:
TABLE 5 analysis of Al-Be intermediate alloy composition
Comparative example 2
The other conditions and operations were the same as in example 1 except that 0.4 part by mass of zinc powder was added and no tin powder was added. The chemical composition of the aluminum-beryllium intermediate alloy prepared in the comparative example 2 is tested, and the results are shown in the following table 6:
TABLE 6 analysis of Al-Be intermediate alloy composition
Comparative example 3
The other conditions and operations are the same as those in example 1, except that in step (S4), the mixed melt is added to a mold, and natural cooling is performed to cool the mixed melt to room temperature, thereby obtaining an aluminum-beryllium intermediate alloy. Namely, the rapid cooling of the liquid nitrogen is not carried out. The chemical compositions of the aluminum-beryllium master alloy prepared in the comparative example 3 are tested, and the results are shown in the following table 7:
TABLE 7 analysis of Al-Be intermediate alloy composition
Comparative example 4
And the other conditions and operations are the same as those in the example 1, except that in the step (S4), the mixed melt is added into a casting mold with a cavity circulating cooling device, the liquid nitrogen circulating cooling device is started to reduce the temperature at a rate of 60 ℃/min, and the aluminum-beryllium intermediate alloy is rapidly cooled to room temperature. I.e. no air cooling is performed.
The chemical composition of the aluminum-beryllium master alloy prepared in the comparative example 4 is tested, and the results are shown in the following table 8:
TABLE 8 analysis of Al-Be intermediate alloy composition
Application example
The following performance tests were performed on the aluminum beryllium master alloys obtained in the above examples and comparative examples, and the results are shown in table 9 below:
tensile strength: the tests were carried out according to the standard GB/T228.1-2010.
Yield strength: the tests were carried out according to the standard GB/T228.1-2010.
Stress relaxation resistance: the method is characterized in that the method is carried out according to GB/T2039, the loading stress is 800MPa, the initial stress and the residual stress after 100 hours are tested after the stress of the test alloy is relaxed for 100 hours at 250 ℃, and the method is obtained by calculating according to the following formula:
TABLE 9 test of Al-Be intermediate alloy Properties
It can be seen that the aluminum-beryllium intermediate alloy obtained by the invention has excellent comprehensive performance, less beryllium segregation phenomenon, high mechanical strength and excellent stress relaxation resistance.
Claims (9)
1. The aluminum-beryllium intermediate alloy is characterized in that raw materials comprise 0.05-0.4 part by weight of tin, 0.05-0.3 part by weight of zinc, 1-5 parts by weight of beryllium and 93-98 parts by weight of aluminum.
2. The aluminum-beryllium intermediate alloy of claim 1, wherein the aluminum-beryllium intermediate alloy comprises 0.1-0.2 parts by weight of tin, 0.2-0.4 parts by weight of zinc, 1-5 parts by weight of beryllium, 93-98 parts by weight of aluminum, and less than or equal to 0.3 parts by weight of other components.
3. The aluminum-beryllium intermediate alloy as claimed in claim 1, which is prepared by first mixing a mixed melt of beryllium, tin and zinc with an aluminum melt, and cooling.
4. The aluminum-beryllium intermediate alloy of claim 3, wherein the cooling is a cooling stage of natural cooling and rapid cooling.
5. The method for preparing the aluminum-beryllium intermediate alloy as set forth in any one of claims 1 to 4, which comprises the following steps:
(S1) heating beryllium in specified parts by mass in a smelting furnace until the beryllium is molten, adding tin powder and zinc powder in specified parts by mass in batches under the condition of stirring, and obtaining a beryllium-tin-zinc mixed melt after all metals are molten after the addition;
(S2) heating the aluminum with the specified mass part to be molten to obtain an aluminum melt, and heating the aluminum melt to 1100-1200 ℃;
(S3) slowly adding the beryllium, tin and zinc mixed melt obtained in the step (S1) into the aluminum melt obtained in the step (S2), stirring all the time, completely melting at 1100-1200 ℃, removing surface scum, adding a refining agent, and refining for 3-5 hours under heat preservation to obtain a mixed melt;
and (S4) adding the mixed melt into a casting mold with a cooling device, naturally cooling, and rapidly cooling to room temperature when the melt is cooled to 850-900 ℃ to obtain the aluminum-beryllium intermediate alloy.
6. The preparation method according to claim 5, wherein the rapid cooling is realized by a cavity circulation cooling device of the casting mold, the cooling medium is liquid nitrogen, and the temperature reduction rate of the rapid cooling is 60-100 ℃/min.
7. The method according to claim 5, wherein in the step (S3), the refining agent is hexachloroethane and is added in an amount of 0.1 to 1wt% based on the total amount of the mixed melt (total of the beryllium-tin-zinc mixed melt and the aluminum melt).
8. The method according to claim 5, wherein the steps (S1) to (S4) are performed under an inert atmosphere, and the inert atmosphere is one or a mixture of argon and nitrogen.
9. The method according to claim 5, wherein the metal material is beryllium, tin, zinc, or aluminum, and the impurities such as oxides are removed from the surface of the metal material before the metal material is melted by heating.
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Denomination of invention: An aluminum beryllium intermediate alloy and its preparation method Effective date of registration: 20231117 Granted publication date: 20230131 Pledgee: China Construction Bank Corporation Shanghai Hongkou Branch Pledgor: Shanghai Taiyang Technology Co.,Ltd. Registration number: Y2023310000750 |