CN115283254B - Rapid screening and activating system and method for air flow of oxygen-making adsorbent particles - Google Patents

Rapid screening and activating system and method for air flow of oxygen-making adsorbent particles Download PDF

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CN115283254B
CN115283254B CN202210910987.5A CN202210910987A CN115283254B CN 115283254 B CN115283254 B CN 115283254B CN 202210910987 A CN202210910987 A CN 202210910987A CN 115283254 B CN115283254 B CN 115283254B
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tank
adsorbent particles
feeding
electromagnetic valve
discharge
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CN115283254A (en
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李延鑫
李小龙
王志光
李梦璐
王贤彬
王炳春
李进
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China Catalyst Holding Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B4/00Separating solids from solids by subjecting their mixture to gas currents
    • B07B4/08Separating solids from solids by subjecting their mixture to gas currents while the mixtures are supported by sieves, screens, or like mechanical elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3483Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B11/00Arrangement of accessories in apparatus for separating solids from solids using gas currents
    • B07B11/02Arrangement of air or material conditioning accessories
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B11/00Arrangement of accessories in apparatus for separating solids from solids using gas currents
    • B07B11/04Control arrangements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B11/00Arrangement of accessories in apparatus for separating solids from solids using gas currents
    • B07B11/06Feeding or discharging arrangements

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

The invention discloses a rapid screening and activating system and method for an oxygen-making adsorbent particle airflow, and belongs to the field of adsorbent synthesis and preparation. Mainly solves the problems that the oxygen production adsorbent has poor quality and affects the oxygen production performance due to powder falling, moisture absorption and the like. The continuous and easy-to-operate airflow screening and online activation integrated mode is provided, so that excessive mixed fine powder in the adsorbent is effectively reduced, meanwhile, fresh hot airflow is continuously introduced to replace moisture in the adsorbent particles, the smooth microstructure pore channels of the adsorbent particles are ensured, more activation sites are provided, and the oxygen production concentration is improved. Therefore, the method is not only suitable for the synthesis process of fresh oxygen-making adsorbent, but also suitable for the screening and activation of the deactivated oxygen-making adsorbent particles due to moisture absorption caused by powder falling, channel blockage, air machine jump, improper storage and the like, so as to meet the due performance index requirements, and has wide novelty, applicability and practicability.

Description

Rapid screening and activating system and method for air flow of oxygen-making adsorbent particles
Technical Field
The invention belongs to the field of adsorbent synthesis and preparation, and particularly relates to a rapid screening and activating system and method for an oxygen-making adsorbent particle airflow.
Background
The adsorbent generally has higher adsorption capacity and activity, and has good application in the fields of wastewater treatment, tail gas purification, catalytic carriers and the like. As such, their performance is degraded during their forming, packaging, and use for various reasons. The most important oxygen-making adsorbent is generally a lithium low-silicon molecular sieve, is extremely easy to absorb moisture and fall powder, and even if medical oxygen-making equipment with better tightness is used, the oxygen concentration is reduced due to inactivation of water vapor, dust accumulation and the like in the adsorption environment after 8000 hours of operation.
When the adsorbent particles are formed, the drying and roasting processes are carried out, powder is dropped on the surface to different degrees due to water loss after the process, meanwhile, due to the rotation of the drying and roasting equipment, the inner wall shoveling plate runs, a similar ball mill effect exists, friction is generated among the adsorbent particles with different sizes, different amounts of fine powder can be generated, the almost absolute dry adsorbent particles have electrostatic adsorption effect, the fine powder can be mixed with the particles, and the conventional mechanical screening is difficult to separate thoroughly. At the same time, after the adsorbent particles are discharged, different amounts of moisture are absorbed due to different environmental humidity during packaging, which seriously affects the performance of the final product.
In summary, screening and activating of oxygen-generating adsorbent particles are an important link in the synthesis and preparation processes, and related methods and devices are reported in recent literature, patent CN106268723a proposes a convenient, safe and environment-friendly oxygen-generating molecular sieve on-site activating method, which mainly aims at reactivating the adsorbent in the vacuum pressure swing adsorption process, mainly loads hot gas flow into a fixed bed column, has low efficiency, accumulates a large amount of adsorbents, diffuses relatively poorly, and generates steam which is very easy to destroy similar adsorbent particles, and at the same time, cannot process fine powder mixed on the surfaces of the adsorbent particles, so that the adsorbent particles are mixed with steam, adhered together, and very easy to block adsorbent pore channels and pipeline channels.
Therefore, it is desirable to develop a rapid screening activation method and apparatus for oxygen generating sorbent particles.
Disclosure of Invention
Aiming at the problems of the prior art, equipment and the like, the invention discloses a rapid screening and activating system and a rapid screening and activating method for an oxygen-making adsorbent particle airflow.
The technical scheme adopted by the invention for realizing the purpose is as follows:
a rapid screening and activating system for an oxygen-generating adsorbent particle airflow comprises a feeding system, a screening and activating system and a discharging system, and is characterized in that,
screening activation system, including the barrel with set up at the inside vibrations sieve of barrel to and set up at the inside gas circuit of vibration sieve top of barrel, be equipped with in proper order from feed end and discharge end on the gas circuit and spray on the vibrations sieve: a nozzle I for blowing off the fine powder air flow, a nozzle II for activating the sample particle hot air flow, and a nozzle III for cooling the sample particle air flow;
an exhaust passage is arranged at the bottom of the cylinder body.
The bottom of the cylinder body is provided with an openable ash discharge collecting tank.
Further, in the above technical scheme, the feeding system is composed of a parallel feeding tank, an electromagnetic valve and a material collecting tank, wherein the parallel feeding tank is a feeding tank A and a feeding tank B.
Each feeding tank A or B controls the feeding rate of the adsorbent particles by an upper electromagnetic valve and a lower electromagnetic valve; simultaneously, the microcomputer program controls the feeding tank A, and the feeding tank B is alternately opened and closed, so that the continuity of the adsorbent particles is realized.
The parallel feeding tanks alternately feed, the fine powder is screened under the blowing action of the double-channel inlet air flow, and after activation, the double-row discharging tanks alternately feed, so that the continuity of work is realized.
Further, in the above technical scheme, the air channel in the screening and activating system is a double-air channel, the air channel close to the feeding end is a left air channel, the air channel close to the discharging end is a right air channel, and the air channel is respectively provided with a ball valve and a pressure gauge, and is connected with the inside of the cylinder body by adopting a flange;
the left air channel is half the length of the right air channel in the cylinder. The left gas path is of a blind end design, two groups of nozzles I are distributed near the top end, one side of the left gas path near a feed port of the feeding system is provided with a tip-connecting type disperser at the upper part;
the right air channel is divided into two parts, and a nozzle II is sequentially arranged on the right air channel according to the sequence from a feeding end to a discharging end; a nozzle III; the number of the nozzles II is two, heating ropes are wound on the gas path provided with the nozzles II, and the inner diameter of the gas path provided with the nozzles II is smaller than that of the gas path provided with the nozzles III; an arc-shaped reflecting plate is arranged on the inner wall of the cylinder above the air path provided with the nozzle II; a group of nozzles I of the left air passage are distributed near the right air inlet, a blind end air passage with the inner diameter smaller than the inner diameter is arranged near the right air inlet, two groups of nozzles II are distributed on the air passage, and the length of the air passage provided with a heating rope is consistent with that of the radiation area of the arc-shaped reflecting plate at the top end of the cylinder; a temperature sensor I is arranged between the heating rope and the arc-shaped reflecting plate.
The aperture of the nozzle I is larger than that of the nozzle II, all the nozzles are distributed in the air inlet pipeline in an arc mode, the maximum divergence angle alpha of the nozzles is consistent with the width of the vibrating screen plate in the cylinder body, and the range alpha is 15-45 degrees, and the preferred angle is 32 degrees.
The vibrating screen plate is operated by a motor eccentric wheel according to a certain process, so that the uniform forward pushing of the adsorbent particles is realized.
Further, in the above technical scheme, the outer wall of the bottom of the cylinder is designed with an openable ash discharge collecting tank, and the outer wall of the cylinder between the openable ash discharge collecting tank and the cylinder is hollowed or provided with a hole penetrating through the outer wall of the cylinder; one end of the openable ash discharge collecting tank is rotatably connected with the cylinder body, and the other end of the openable ash discharge collecting tank is provided with an automatic lock catch; the other end is provided with a cylinder driven downwards.
The exhaust passage is positioned between the collecting tank and the discharging system, a filter is arranged in the exhaust passage, the exhaust passage is connected with the ball valve II by using a flange piece, and a temperature sensor II is arranged in the cylinder body at the upper part of the exhaust passage.
Further, in the above technical solution, the discharging system is of a parallel double-tank structure, and includes a discharging tank C and a discharging tank D;
the discharge tank C and the discharge tank D are respectively provided with an upper electromagnetic valve and a lower electromagnetic valve for controlling the discharge rate of the adsorbent particles; the microcomputer program is arranged to control the discharge tank C, and the discharge tank D is alternately opened and closed, so that the continuity of the adsorbent particles is realized.
Further, in the above technical scheme, the temperature range of the temperature sensor I is 110-220 ℃, preferably 205 ℃; the temperature sensor II has a temperature in the range of 75-125℃and preferably 115 ℃.
Further, in the above technical scheme, the air inlet flow of the left air channel is 1/3-1/2 of the air inlet flow of the right air channel.
Further, in the above technical scheme, the air inlet of the air path is inert gas or air with the dew point below-45 ℃;
the invention provides a method for the rapid screening and activating system of oxygen-generating adsorbent particle airflow, which comprises the following steps:
step one, an upper electromagnetic valve for controlling feeding of a feeding tank A is opened, after adsorbent particles in a collecting tank enter the feeding tank A, the upper electromagnetic valve for controlling feeding of the feeding tank A is closed, a lower electromagnetic valve for controlling discharging of the feeding tank A is opened, adsorbent particles enter a cylinder body, at the moment, the upper electromagnetic valve for controlling feeding of the feeding tank B is opened, after the adsorbent particles in the collecting tank enter the feeding tank B, the upper electromagnetic valve for controlling feeding of the feeding tank B is closed, a lower electromagnetic valve for controlling discharging of the feeding tank B is opened, the adsorbent particles enter the cylinder body, the whole set of switching process is carried out, and system pressure stability is ensured;
step two, adjusting the air inlet flow of the left air channel and the right air channel by ball valves, detecting the pressure of the system by a pressure gauge, starting a heating rope, and judging the start and stop of activation by the temperatures of the temperature sensor I and the temperature sensor II; the spreading rate of the adsorbent particles on the vibrating screen deck, and the residence time in each zone, are adjusted by a motor.
And thirdly, after the adsorbent particles enter the cylinder body from the feeding tank A or the feeding tank B, guiding the adsorbent particles by the tip-shaped disperser, spreading the adsorbent particles on the vibration sieve plate, screening the adsorbent particles by a large-flow airflow from a double-group nozzle I in a left air inlet path, screening fine powder lower than a certain size, and storing the fine powder in the collecting tank.
And fourthly, continuously propelling the sieved adsorbent particles under the action of the vibration sieve plate, activating the air flow from the double-group fine-pore-diameter nozzles II of the right air passage in a heated area, heating the air flow to a certain temperature by the heating rope, radiating heat by the arc-shaped reflecting plate to heat the adsorbent particles, wherein the fine nozzles II are small in pore diameter, generate high pressure and high-flow-rate fresh hot air flow, expel water in the adsorbent particles, and adjust the opening of the ball valve II in the exhaust passage.
Step five, after the temperature of the adsorbent particles is raised and activated, rapidly cooling by the right air passage single-group large-aperture nozzle III, opening an upper electromagnetic valve at the top of the discharge tank C in a discharging system, and collecting the adsorbent particles; when the discharging tank C is full, opening a lower electromagnetic valve at the bottom of the discharging tank C, simultaneously closing an upper electromagnetic valve at the top of the discharging tank C, opening an upper electromagnetic valve at the top of the discharging tank D in a discharging system, and collecting adsorbent particles; and after the discharge tank D is full, opening a lower electromagnetic valve at the bottom of the discharge tank D, and alternately repeating the operation of the discharge tank C and the discharge tank D.
Further, in the above technical scheme, the motor controls the constant time periods of the adsorbent particles in each process interval, specifically, in the nozzle I for blowing off the fine powder airflow, the nozzle II for activating the sample particle airflow, and the nozzle III for cooling the sample particle airflow to be 0.5-1.5h, 1.5-2.5 and 0.5-1h, respectively.
Advantageous effects
The invention discloses a rapid airflow screening and activating method for oxygen-making adsorbent particles, which effectively solves the problems that the oxygen-making performance of the current oxygen-making adsorbent particles is affected due to poor quality of products caused by powder falling, moisture absorption and the like in the processes of preparation, packaging and use.
The continuous and easy-to-operate airflow screening and online activation integrated mode is provided, so that excessive adsorption fine powder in the oxygen-making adsorbent particles is effectively reduced, meanwhile, fresh hot air flow is continuously introduced to replace moisture in the adsorbent particles, the microstructure pore channels of the adsorbent particles are ensured to be smooth, the activation sites are increased, and the oxygen production concentration is improved.
More importantly, the rapid screening and activating method for the air flow of the oxygen-making adsorbent particles is not only suitable for the synthesis process of fresh oxygen-making adsorbents, but also suitable for screening and activating the deactivated oxygen-making adsorbent particles due to moisture absorption caused by powder dropping, channel blockage, air machine jump, improper storage and the like so as to meet the requirement of due oxygen production performance indexes.
Therefore, the rapid screening and activating method for the air flow of the oxygen-generating adsorbent particles has wide novelty, applicability and practicability.
Drawings
FIG. 1 is a schematic diagram of an apparatus for a rapid screening activation process for oxygen generating sorbent particulate gas streams in accordance with the present invention.
FIG. 2 is a view of left gas path A-A in a rapid screening activation method for oxygen generating sorbent particle gas flow in accordance with the present invention.
FIG. 3 is a schematic diagram of the motor operation of a vibrating screen plate for a rapid screening activation method of oxygen-generating sorbent particle gas flow in accordance with the present invention.
In the figure, 1 is a cylinder; 2-an arc-shaped reflecting plate; 3-a motor; 4-1, a temperature sensor I; 4-2, a temperature sensor II; 5-left air path; 6-right air path; 7-ball valve I; 8-a flange I; 9, vibrating the screen plate; 10-1-nozzle I; 10-2-nozzle II; 11-heating rope; 12-tip disperser; 13-eccentric wheel; 14-an air cylinder; 15-a collecting tank; 16-automatic locking; 17-an exhaust passage; 18-ball valve II; 19-a collecting tank; 20-an electromagnetic valve I; 21-a feed tank A; 22-an electromagnetic valve II; 23-an electromagnetic valve III; 24-discharge tank C; 25-an electromagnetic valve IV; 26-pressure gauge I;
Detailed Description
The following description of the preferred embodiments is provided in connection with the accompanying drawings so that the advantages and features of the present invention will be more readily understood by those skilled in the art, and thus the scope of the present invention will be more clearly and clearly defined.
Example 1
A rapid screening and activating system for air flow of oxygen-generating adsorbent particles comprises a feeding system, a screening and activating system and a discharging system,
screening activation system, including barrel 1 and the vibrations sieve 9 of setting in barrel 1 inside to and set up at the inside gas circuit of vibrations sieve 9 top of barrel 1, be equipped with in proper order from feed end and discharge end on the gas circuit and spray on the vibrations sieve 9: a nozzle I for blowing off the fine powder air flow, a nozzle II for activating the sample particle hot air flow, and a nozzle III for cooling the sample particle air flow;
the bottom of the cylinder body 1 is provided with an exhaust passage 17.
The bottom of the cylinder body 1 is provided with an openable ash discharge collecting tank 15.
Further, in the above technical solution, the feeding system is composed of a parallel feeding tank, an electromagnetic valve and a material collecting tank 19, and the parallel feeding tank is a feeding tank a21 and a feeding tank B.
Each feed tank A21 or B controls the feeding rate of the adsorbent particles by an upper electromagnetic valve and a lower electromagnetic valve; simultaneously, the microcomputer program controls the feeding tank A21 and the feeding tank B to be alternately opened and closed, so that the continuity of the adsorbent particles is realized.
The parallel feeding tanks alternately feed, the fine powder is screened under the blowing action of the double-channel inlet air flow, and after activation, the double-row discharging tanks alternately feed, so that the continuity of work is realized.
Further, in the above technical scheme, the air channel in the screening and activating system is a double-air channel, the air channel close to the feeding end is a left air channel 5, the air channel close to the discharging end is a right air channel 6, and a ball valve and a pressure gauge are respectively arranged and are connected with the inside of the cylinder 1 by adopting a flange;
the length of the left air channel 5 is half of that of the right air channel 6 in the barrel 1. The left gas circuit 5 is designed as a blind end, two groups of nozzles I are distributed near the top end, and a sharp disperser 12 is welded with the feed inlet of the feed system;
the right air channel 6 is divided into two parts, and nozzles II are sequentially arranged on the right air channel 6 according to the sequence from a feeding end to a discharging end; a nozzle III; the number of the nozzles II is two, the heating ropes 11 are wound on the air channel provided with the nozzles II, and the inner diameter of the air channel provided with the nozzles II is smaller than that of the air channel provided with the nozzles III; an arc-shaped reflecting plate 2 is arranged on the inner wall of the cylinder body 1 above the air passage provided with the nozzle II; a group of nozzles I10-1 are distributed near the right air inlet, a blind end air passage with the inner diameter smaller than the inner diameter is arranged near the left air passage 5, two groups of nozzles II 10-2 are distributed on the air passage, and the length of the air passage provided with a heating rope 11 is consistent with the length of the radiation area of the arc-shaped reflecting plate 2 at the top end of the cylinder body 1; a temperature sensor I is arranged between the heating rope 11 and the arc-shaped reflecting plate.
The aperture of the nozzle I10-1 is larger than that of the nozzle II 10-2, all the nozzles are distributed in the air inlet pipeline in an arc mode, and the maximum divergence angle alpha of the nozzles is consistent with the width of the vibrating screen plate 9 in the cylinder body 1, wherein the range alpha is 15-45 degrees, and the preferred angle is 32 degrees.
The vibrating screen plate 9 is operated by the eccentric wheel 13 of the motor 3 according to a certain process, so that the uniform forward pushing of the adsorbent particles is realized.
Further, in the above technical solution, the bottom outer wall of the cylinder 1 is designed with an openable ash discharge collecting tank 15, and the outer wall of the cylinder between the openable ash discharge collecting tank 15 and the cylinder 1 is hollowed or provided with a hole penetrating through the outer wall of the cylinder; one end of the openable ash discharge collecting tank 15 is rotatably connected with the cylinder, and the other end is provided with an automatic lock catch 16; the other end is provided with a downwardly driven cylinder 14.
An exhaust passage 17 is provided between the collecting tank 15 and the discharge system, a filter is provided in the exhaust passage 17, a flange is connected to a ball valve II 18, and a temperature sensor II is provided in the cylinder 1 at the upper part of the exhaust passage 17.
Further, in the above technical solution, the discharging system is of a parallel double-tank structure, and includes a discharging tank C24 and a discharging tank D;
an upper electromagnetic valve and a lower electromagnetic valve which are respectively eight-profile-controlled for the discharge rate of the adsorbent particles are arranged in the discharge tank C24 and the discharge tank D; the microcomputer program is arranged to control the discharge tank C24, and the discharge tank D is alternately opened and closed, so that the continuity of the adsorbent particles is realized.
Further, in the above technical scheme, the temperature range of the temperature sensor I is controlled to be 110-220 ℃, preferably 205 ℃; the temperature sensor II has a temperature in the range of 75-125℃and preferably 115 ℃.
Further, in the above technical scheme, the air inlet flow of the left air channel is 1/3-1/2 of the air inlet flow of the right air channel.
Further, in the above technical scheme, the air inlet of the air path is inert gas or air with the dew point below-45 ℃;
the invention provides a method for the rapid screening and activating system of oxygen-generating adsorbent particle airflow, which comprises the following steps:
step one, an upper electromagnetic valve I20 for controlling feeding of a feeding tank A is opened, after adsorbent particles in a collecting tank 19 enter the feeding tank A21, the upper electromagnetic valve I20 for controlling feeding of the feeding tank A is closed, a lower electromagnetic valve II 22 for controlling discharging of the feeding tank A is opened, at the moment, the adsorbent particles enter a cylinder 1, the upper electromagnetic valve for controlling feeding of a feeding tank B is opened, after the adsorbent particles in the collecting tank 19 enter the feeding tank B, the upper electromagnetic valve for controlling feeding of the feeding tank B is closed, a lower electromagnetic valve for controlling discharging of the feeding tank B is opened, the adsorbent particles enter the cylinder 1, and the whole set of switching process ensures stable system pressure;
step two, adjusting the air inlet flow of the left air channel 5 and the right air channel 6 by ball valves, detecting the system pressure by a pressure gauge I26, starting a heating rope 11, and judging the starting and stopping of activation by the temperatures of the temperature sensor I4-1 and the temperature sensor II 4-2; the spreading rate of the adsorbent particles on the vibrating screen plate 9, and the residence time in each zone, are adjusted by the motor 3.
And thirdly, after the adsorbent particles enter the cylinder body 1 from the feeding tank A21 or the feeding tank B, the adsorbent particles are guided by the tip-shaped disperser 12 and spread on the vibrating screen plate 9, and the adsorbent particles are screened by a large-flow airflow from the double-group nozzles I10-1 in the left air inlet channel 5, are screened and stored in the collecting tank 15.
And fourthly, continuously propelling the sieved adsorbent particles under the action of the vibration sieve plate 9, activating the air flow in a heated area by the double-group fine-pore-diameter nozzles II 10-2 from the right air passage 6, heating the air flow to a certain temperature by the heating ropes 11, and simultaneously radiating heat by the arc-shaped reflecting plate 2 to heat the adsorbent particles, wherein the fine nozzles II 10-2 are small in pore diameter, generate high-pressure and high-flow-rate fresh hot air flow, drive water in the adsorbent particles out, and adjust the opening of the ball valves II 18 in the exhaust passages 17.
Step five, after the temperature of the adsorbent particles is raised and activated, rapidly cooling by a single group of large-aperture nozzles III of the right gas circuit 6, opening an upper electromagnetic valve at the top of the discharge tank C24 in a discharging system, and collecting the adsorbent particles; when the discharging tank C24 is full, opening a lower electromagnetic valve at the bottom of the discharging tank C, simultaneously closing an upper electromagnetic valve at the top of the discharging tank C24, opening an upper electromagnetic valve at the top of the discharging tank D in a discharging system, and collecting adsorbent particles; and after the discharge tank D is full, opening a lower electromagnetic valve at the bottom of the discharge tank D, and alternately repeating the operation of the discharge tank C and the discharge tank D.
Further, in the above technical scheme, the motor 3 controls the constant duration of each process interval of the adsorbent particles, specifically, the nozzle i for blowing off the fine powder airflow, the nozzle ii for activating the sample particle airflow, and the nozzle iii for cooling the sample particle airflow, to be 0.5-1.5h, 1.5-2.5 h, and 0.5-1h, respectively.
Example 2
Referring to fig. 1-2, a rapid screening activation system for an oxygen generating sorbent particulate gas stream comprises a feed system, a screening activation system, and a discharge system. The device is characterized in that parallel feeding tanks alternately feed, fine powder is screened under the action of blowing of double-channel inlet air flow, and after activation, double-row discharging tanks alternately feed, so that the continuity of work is realized.
Further, the feeding system is composed of a parallel feeding tank, an electromagnetic valve and a collecting tank 19, wherein the parallel feeding tank is divided into a feeding tank A21 and a feeding tank B.
The feeding tank A21 controls the feeding rate of the adsorbent particles by an upper electromagnetic valve I20 arranged at the upper end and a lower electromagnetic valve II 22 arranged at the lower end. The feeding tank B controls the feeding rate of the adsorbent particles by an upper electromagnetic valve arranged at the upper end and a lower electromagnetic valve arranged at the lower end. Simultaneously, the microcomputer program controls the feeding tank A21 and the feeding tank B to be alternately opened and closed, so that the continuity of the adsorbent particles is realized.
Further, the screening activation system is designed by a double-air-passage, namely a left air passage 5 near a feeding end and a right air passage 6 near a discharging end. Wherein, left gas circuit 5 has ball valve I7, manometer I26, adopts flange I8 to be connected with barrel 1 inside. Similarly, the right air channel 6 is provided with a ball valve and a pressure gauge, and is connected with the inside of the cylinder body 1 by adopting a flange.
The length of the left air passage 5 in the cylinder 1 is half of the length of the right air passage 6. The left air channel 5 is designed to be a blind end, two groups of nozzles I10-1 are distributed near the top end, and a sharp disperser 12 is welded at the feed inlet of the feed system. The right air channel 6 is divided into two parts, a group of nozzles I10-1 corresponding to the left air channel 5 are distributed near the right air inlet, and the right air inlet is an air inlet at the ball valve of the right air channel 6. Immediately, the left side of the right air channel 6 is a blind end air channel with small inner diameter, two groups of nozzles II 10-2 are distributed on the air channel, and meanwhile, a heating rope 11 is wound on the part and is consistent with the length of the radiation area of the arc-shaped reflecting plate 2 welded at the top end of the cylinder body 1. In this upper region, a temperature sensor i is provided.
The aperture of the nozzle I10-1 is larger than that of the nozzle II 10-2, all the nozzles are distributed in the air inlet pipeline in an arc mode, and the maximum divergence angle alpha of the nozzles is consistent with the width of the vibrating screen plate 9 in the cylinder body 1, wherein the range alpha is 15-45 degrees, and the preferred angle is 32 degrees.
The vibration sieve plate 9 is controlled by the motor 3 and the eccentric wheel 13 to operate according to a certain process, so that the uniform forward pushing of the adsorbent particles is realized.
Further, an openable ash discharge collecting tank 15 is designed on the outer wall of the bottom of the cylinder 1, and a hollow or hole penetrating through the outer wall of the cylinder is formed on the outer wall of the cylinder between the openable ash discharge collecting tank 15 and the cylinder 1; one end of the openable ash discharge collecting tank 15 is rotatably connected with the cylinder, and the other end is provided with an automatic lock catch 16; the other end is provided with a downwardly driven cylinder 14.
Meanwhile, an exhaust passage 17 is arranged between the right side of the collecting tank 15 and the discharging system, a filter is arranged in the collecting tank, a flange sheet is connected with a ball valve II 18, and a temperature sensor II is arranged in an outlet area in the barrel 1.
Further, the discharging system is similar to the feeding system in structure and is designed with two parallel-connection material tanks, and the parallel-connection material tanks are divided into a discharging tank C24 and a discharging tank D.
Likewise, the discharge tank C24 controls the discharge rate of the adsorbent particles by an upper solenoid valve III 23 at the upper end and a lower solenoid valve IV 25 at the lower end. The discharge tank D controls the discharge rate of the adsorbent particles by an upper electromagnetic valve at the upper end and a lower electromagnetic valve at the lower end. Simultaneously, the microcomputer program controls the discharge tank C24, and the discharge tank D is alternately opened and closed, so that the continuity of the adsorbent particles is realized.
Further, the temperature range of the heating area temperature sensor I is 110-220 ℃, and the preferable temperature is 205 ℃; the outlet zone temperature sensor ii has a temperature in the range 75-125 c, preferably 115 c.
Further, the rapid screening and activating system for the air flow of the oxygen-generating adsorbent particles is characterized in that the air inlet flow of the left air channel is 1/3-1/2 of the air inlet flow of the right air channel.
Further, the intake air is an inert gas or air having a dew point of-45 ℃ or lower, and preferably the assist gas is nitrogen.
Example 3
Referring to fig. 1-2, a rapid screening activation method for oxygen producing sorbent particle gas streams using the system of example 2, comprising the steps of:
step one, after the adsorbent particles in the collecting tank 19 enter the feeding tank A21, the electromagnetic valve I20 is closed, the electromagnetic valve II 22 is opened, the adsorbent particles enter the cylinder 1, at the moment, the feeding tank B is connected in parallel, the operation of the feeding tank A21 is completed, the whole set of switching process is completed, and the pressure stability of the system is ensured.
And step two, adjusting the air inlet flow of the left air channel 5 by the ball valve I7, and similarly, adjusting the air inlet flow of the right air channel 6 by the rightmost ball valve. The pressure gauge I26 detects the system pressure, the heating rope 11 is started, and the temperature sensor I4-1 and the temperature sensor II 4-2 judge the start and stop of activation. The spreading rate of the adsorbent particles on the vibrating screen plate 9, and the residence time in each zone, are adjusted by the motor 3.
And thirdly, after the adsorbent particles enter the cylinder body 1 from the feeding tank A21 or the feeding tank B, the right sharp-pointed disperser 12 is guided to spread on the vibrating screen plate 9, and the adsorbent particles are screened by a large-flow airflow from the double-group nozzles I10-1 in the left air inlet channel 5, screened and stored in the collecting tank 15, wherein the large-flow airflow is large-aperture.
And fourthly, continuously propelling the sieved adsorbent particles under the action of the vibration sieve plate 9, activating the air flow from the double groups of fine nozzles II 10-2 of the right air passage 6 in a heated area, heating the air flow to a certain temperature by the heating rope 11, radiating heat by the arc-shaped reflecting plate 2 to heat the adsorbent particles, wherein the fine nozzles II 10-2 are small in aperture, generate high pressure and high flow rate fresh hot air flow, expel water in the adsorbent particles, and adjust the opening of the ball valve II 18 in the exhaust passage 17.
And fifthly, after the temperature of the adsorbent particles is raised and activated, rapidly cooling by using a single group of large-aperture nozzles of the right gas circuit 6, and opening an electromagnetic valve III 23 on a discharge tank C24 in a discharging system to collect the adsorbent particles. When the discharge tank C24 is full, the lower electromagnetic valve IV 25 is opened, the electromagnetic valve III 23 is closed, and the discharge tank D repeats the above operation. The operation is to open the upper electromagnetic valve at the upper end of the discharge tank D in the discharging system, collect adsorbent particles, open the lower electromagnetic valve at the lower end of the discharge tank D after the discharge tank D is full, and simultaneously close the upper electromagnetic valve at the upper end of the discharge tank D.
Further, the motor 3 controls the working constant time periods under the process intervals of the adsorbent particles, specifically, the nozzle I for blowing off the fine powder airflow, the nozzle II for activating the sample particle airflow and the nozzle III for cooling the sample particle airflow, which are respectively 0.5-1.5h, 1.5-2.5 h and 0.5-1h, and the preferable interval time periods are respectively 1.0,2.0,0.5.
Example 4
Raw lithium sieve (LiLSX) sorbent particles with a solids content of 75.7%, crush strength of 2.32% (130N), 5.12% (250N), relative crystallinity of 90.4%, N 2 /O 2 The separation coefficient was 4.82.
Referring to fig. 3, the difference between this embodiment and embodiment 3 is that the vibration sieve plate 9 and the motor 3 are divided into a section 1 as a nozzle i for blowing off the fine powder airflow, a section 2 as a nozzle ii for activating the sample particle airflow, and a section 3 as a nozzle iii for cooling the sample particle airflow, and the specific operation process diagram is as follows:
table 1 operating conditions of the motor during one period
Example 5
The materials similar to those in example 4 are processed, and as can be seen from fig. 1-3, because the feed tank a21, the feed tank B, the discharge tank C24 and the discharge tank C24 are all designed in parallel, the drying and constant pressure environment inside the equipment can be ensured during switching and continuous feeding, the air tightness is high, the contact with the environment is reduced, and the isolation system belongs to an isolation system. The specific operation process is as follows:
firstly, the electromagnetic valve I20 is opened, after the adsorbent particles in the collecting tank 19 enter the feeding tank A21, the feeding tank A21 is full of about 15kg, the electromagnetic valve I20 is closed, the electromagnetic valve II 22 is controlled to be opened, the adsorbent particles uniformly enter the cylinder 1, are guided by the tip-shaped disperser 12, and are spread on the vibrating screen plate 9. At this time, the feeding tank B is connected in parallel, the operation of the feeding tank A21 is completed, the whole set of switching process is completed, and the pressure stability of the system is ensured.
Then, the flow of the left air passage 5 is adjusted to be 12m by the ball valve I7 3 And/h, adjusting the air inlet flow of the right air passage 6 to 25m by the rightmost ball valve 3 And/h, adjusting the opening of a ball valve II 18 in the exhaust passage 17, detecting the indicating number of a system pressure gauge I26 to be 0.1-0.5Mpa, opening a heating rope 11, wherein the temperature of a temperature sensor I4-1 is 205 ℃, and after the temperature is constant for 30min, the temperature of a temperature sensor II 4-2 is 110 ℃. The motor 3 operates according to the set technological conditions, the nozzle I for blowing off the fine powder airflow in the interval 1, the nozzle II for activating the sample particle airflow in the interval 2, and the nozzle III for cooling the sample particle airflow in the interval 3 have constant time periods of 1.0h, 2.0 h and 0.5h respectively, and the adsorbent particles start to spread and advance on the vibrating screen plate 9.
Next, from the double set of nozzles i 10-1 in the left inlet channel 5, which is large-bore, the adsorbent particles are air-screened, and fines below 40 mesh are screened and stored in the collection tank 15.
Further, the sieved adsorbent particles continue to advance under the action of the vibrating screen plate 9, and in a heated area, heat is radiated by the arc-shaped reflecting plate 2 to heat the adsorbent particles, and air flows from the right air path 6 and the double groups of fine nozzles II 10-2 are activated. Because the fine nozzle II 10-2 has a small aperture, a high pressure and high flow rate fresh hot air flow is generated, so that moisture in the adsorbent particles is driven out and discharged from the exhaust passage 17.
And finally, rapidly cooling the adsorbent particles to about 45 ℃ by using a single group of large-aperture nozzles of the right gas circuit 6, opening an electromagnetic valve III 23 on the discharge tank C24 in the discharging system, and collecting the adsorbent particles. When the discharge tank C24 is full, the lower electromagnetic valve IV 25 is opened, the electromagnetic valve III 23 is closed, and the discharge tank D repeats the above operation. The operation is to open the upper electromagnetic valve at the upper end of the discharge tank D in the discharging system, collect adsorbent particles, open the lower electromagnetic valve at the lower end of the discharge tank D after the discharge tank D is full, and simultaneously close the upper electromagnetic valve at the upper end of the discharge tank D. Each discharge tank C24, or discharge tank D, collected about 12.75kg of adsorbent particles.
Example 6
For comparison, the same materials were used and a muffle furnace was used for the drying and activation process.
Example 7
For comparison, the same materials were used and a drying and activating process was performed using a forced air oven.
Example 8
When in total use (h): the total mass of the materials is 15-20kg, and the whole process takes time from the beginning of treatment to the packaging of the final product.
Solids content (%): roasting at 575 ℃ for 1-3h, and changing the mass before and after weighing;
crush strength (%): sieving under the action of 130N and 250N pressure, and weighing to obtain mass change; meanwhile, the method is also an important index for measuring the amount of the fine powder.
Relative crystallinity (%): calculation after testing with XRD instrument. The value of the method can be used for rapidly evaluating whether the structure of the adsorbent is damaged or not.
Nitrogen-oxygen separation coefficient (N) 2 /O 2 ): according to GB/T35109-2017 molecular sieve nitrogen-oxygen separation static determination method;
TABLE 2 sample conditions for different treatments
The foregoing description is only illustrative of the present invention and is not intended to limit the scope of the invention, and all equivalent structures or equivalent processes or direct or indirect application in other related technical fields are included in the scope of the present invention.

Claims (9)

1. A rapid screening and activating system for an oxygen-generating adsorbent particle airflow comprises a feeding system, a screening and activating system and a discharging system, and is characterized in that,
the screening and activating system comprises a cylinder, a vibrating screen plate arranged in the cylinder, and an air channel arranged in the cylinder and above the vibrating screen plate, wherein the air channel is sequentially provided with a nozzle I for spraying and blowing off fine powder air flow, a nozzle II for activating sample particle hot air flow and a nozzle III for cooling sample particle air flow according to the sequence from a feeding end to a discharging end;
an exhaust passage is arranged at the bottom of the cylinder;
the bottom of the cylinder body is provided with an openable ash discharge collecting tank;
the screening and activating system is characterized in that an air channel is a double-air channel, a left air channel is close to a feeding end, a right air channel is close to a discharging end, a ball valve and a pressure gauge are respectively arranged, and the ball valve and the pressure gauge are connected with the inside of the cylinder body through flanges;
the left air path is half of the right air path in the barrel; the left gas path is of a blind end design, two groups of nozzles I are distributed near the top end, one side of the left gas path near a feed inlet of the feed system is provided with a pointed disperser at the upper part;
the right air channel is divided into two parts, and a nozzle II and a nozzle III are sequentially arranged on the right air channel according to the sequence from a feeding end to a discharging end; the number of the nozzles II is two, heating ropes are wound on the gas path provided with the nozzles II, and the inner diameter of the gas path provided with the nozzles II is smaller than that of the gas path provided with the nozzles III; an arc-shaped reflecting plate is arranged on the inner wall of the cylinder above the air path provided with the nozzle II; the length of the air channel provided with the heating rope is consistent with that of the radiation area of the arc-shaped reflecting plate at the top end of the cylinder; a temperature sensor I is arranged between the heating rope and the arc-shaped reflecting plate;
the aperture of the nozzle I is larger than that of the nozzle II, all the nozzles are arc-shaped, and the maximum divergence angle alpha is consistent with the width of the vibrating screen plate in the cylinder body, wherein the range of alpha is 15-45 degrees;
the vibrating screen plate is operated by a motor eccentric wheel according to a certain process, so that the uniform forward pushing of the adsorbent particles is realized.
2. The rapid screening and activating system for oxygen-generating sorbent particle gas flow of claim 1, wherein the feed system is comprised of a parallel feed tank, solenoid valve and aggregate tank, the parallel feed tank being feed tank a, feed tank B;
each feeding tank A or B controls the feeding rate of the adsorbent particles by an upper electromagnetic valve and a lower electromagnetic valve; simultaneously, the microcomputer program controls the feeding tank A, and the feeding tank B is alternately opened and closed.
3. The rapid screening and activating system for the air flow of oxygen-generating adsorbent particles according to claim 2, wherein the outer wall of the bottom of the cylinder is provided with an openable ash discharge collecting tank, and the outer wall of the cylinder between the openable ash discharge collecting tank and the cylinder is hollowed or provided with a hole penetrating through the outer wall of the cylinder; one end of the openable ash discharge collecting tank is rotatably connected with the cylinder body, and the other end of the openable ash discharge collecting tank is provided with an automatic lock catch; the other end is provided with a cylinder which can be driven downwards;
the exhaust passage is positioned between the collecting tank and the discharge system, a filter is arranged in the exhaust passage, and a temperature sensor II is arranged in the cylinder body at the upper part of the exhaust passage.
4. A rapid screening activation system for oxygen generating sorbent particulate gas streams of claim 3 wherein the discharge system is of a parallel double tank construction comprising a discharge tank C and a discharge tank D;
the discharge tank C and the discharge tank D are respectively provided with an upper electromagnetic valve and a lower electromagnetic valve for controlling the discharge rate of the adsorbent particles; a microcomputer program is arranged to control the discharge tank C, and the discharge tank D is alternately opened and closed.
5. The rapid screening activation system for an oxygen generating sorbent particulate gas stream of claim 4 wherein temperature sensor i is in the range of 110 ℃ to 220 ℃; the temperature range of the temperature sensor II is 75-125 ℃.
6. The rapid screening activation system for oxygen generating sorbent particulate air flow of claim 1, wherein the left air path inlet flow is 1/3-1/2 of the right air path inlet flow.
7. A rapid screening activation system for oxygen generating sorbent particulate gas streams as claimed in claim 1 wherein the gas path inlet is an inert gas or air at a dew point of-45 ℃ or less.
8. A method for the rapid screening activation system for oxygen producing sorbent particle gas streams of claim 5, comprising the steps of:
step one, an upper electromagnetic valve for controlling feeding of a feeding tank A is opened, after adsorbent particles in a collecting tank enter the feeding tank A, the upper electromagnetic valve for controlling feeding of the feeding tank A is closed, a lower electromagnetic valve for controlling discharging of the feeding tank A is opened, adsorbent particles enter a cylinder body, at the moment, the upper electromagnetic valve for controlling feeding of the feeding tank B is opened, after the adsorbent particles in the collecting tank enter the feeding tank B, the upper electromagnetic valve for controlling feeding of the feeding tank B is closed, a lower electromagnetic valve for controlling discharging of the feeding tank B is opened, the adsorbent particles enter the cylinder body, the whole set of switching process is carried out, and system pressure stability is ensured;
step two, adjusting the air inlet flow of the left air channel and the right air channel by ball valves, detecting the pressure of the system by a pressure gauge, starting a heating rope, and judging the start and stop of activation by the temperatures of the temperature sensor I and the temperature sensor II; adjusting the spreading rate of the adsorbent particles on the vibrating screen plate and the residence time in each zone by a motor;
step three, after the adsorbent particles enter a cylinder body from the feeding tank A or the feeding tank B, guiding the adsorbent particles by the tip-shaped disperser, spreading the adsorbent particles on the vibrating screen plate, screening the adsorbent particles by a large-flow airflow from a double-group nozzle I in a left air inlet path, screening fine powder lower than a certain size, and storing the fine powder in the collecting tank;
step four, the sieved adsorbent particles continue to advance under the action of a vibrating screen plate, and in a heated area, the air flow is activated by the air flow of the double-group fine-pore-diameter nozzles II from the right air path, and is heated to a certain temperature by the heating rope, and meanwhile, the arc-shaped reflecting plate radiates heat to heat the adsorbent particles;
step five, after the temperature of the adsorbent particles is raised and activated, rapidly cooling by the right air passage single-group large-aperture nozzle III, opening an upper electromagnetic valve at the top of the discharge tank C in a discharging system, and collecting the adsorbent particles; when the discharging tank C is full, opening a lower electromagnetic valve at the bottom of the discharging tank C, simultaneously closing an upper electromagnetic valve at the top of the discharging tank C, opening an upper electromagnetic valve at the top of the discharging tank D in a discharging system, and collecting adsorbent particles; and after the discharge tank D is full, opening a lower electromagnetic valve at the bottom of the discharge tank D, and alternately repeating the operation of the discharge tank C and the discharge tank D.
9. The method according to claim 8, wherein the motor controls the constant time periods of the adsorbent particles in each process zone, specifically, in the nozzle i for blowing off the fine powder gas stream, the nozzle ii for activating the sample particle hot gas stream, and the nozzle iii for cooling the sample particle gas stream, to be 0.5-1.5h, 1.5-2.5, and 0.5-1h, respectively.
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