CN103952747A - Electro-deposition device for composite lead-carbon material - Google Patents
Electro-deposition device for composite lead-carbon material Download PDFInfo
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- CN103952747A CN103952747A CN201410147584.5A CN201410147584A CN103952747A CN 103952747 A CN103952747 A CN 103952747A CN 201410147584 A CN201410147584 A CN 201410147584A CN 103952747 A CN103952747 A CN 103952747A
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Abstract
The invention relates to an electro-deposition device for a composite lead-carbon material. The device comprises an electroplating tank, an anode part, a movable cathode part and a stirrer, wherein the electroplating tank is divided into an anode region and a cathode region by a baffle or a membrane which can be passed by an electrolyte solution only and cannot be passed by a plated material; the cathode region of the electroplating tank is provided with a discharging hole and a feeding hole. According to the device, the problem of industrialized production of doping metal or alloy during powder electro-deposition is solved, the produced composite lead-carbon material is uniform in lead deposition quantity and stable in performance, and the device also can be used for continuous production of other kinds of metal or alloy during other particle electro-deposition.
Description
Technical field
The present invention relates to a kind of preparation facilities of plumbous carbon composite, relate in particular to a kind of electric deposition device of plumbous carbon composite.
Background technology
Using the carbon material of doping metals or alloy as electrode materials, have its excellent performance.Preparation method has ball milled, evaporation-coacervation, spray heating decomposition, epitaxial cathode sedimentation etc.By electrodip process, can obtain the coated C composite powder of metal or alloy, the standby powder size of this legal system evenly, stable performance, product cost performance be high.A kind of plumbous carbon composite (number of patent application: CN201010608794.1), the method by galvanic deposit to what prepare between activated carbon granule inside and activated carbon granule, has realized lead deposit the plumbous interface good with charcoal and has been combined.This lead carbon composite has larger proportion, more easily evenly mix with the negative electrode active material realization of the lead acid cell such as lead powder, the direct negative material as superbattery, or as superbattery negative electrode active material additive, be applied to the manufacture of superbattery, be conducive to suppress lead and charcoal coming off in circulating battery process, can effectively extend the life-span of superbattery.
But the technical scheme that this method provides adopts cladding process to prepare carbon plate negative electrode, scrapes the method for matrix material after galvanic deposit, is difficult for realizing commercial scale production.For this reason, need a kind of suitability for industrialized production problem that solves powder doping metal or alloy of installing of design.
Summary of the invention
The object of this invention is to provide a kind of can quantity-produced plumbous carbon composite electric deposition device, can realize the industrialization that the plumbous carbon composite of doping is produced.
The technical scheme that technical solution problem of the present invention adopts is: a kind of plumbous carbon composite electric deposition device, comprise plating tank, anode component, cathode assembly and agitator, described plating tank is by not only being divided into positive column by the dividing plate of plated material by electrolytic solution, Liang Ge region, cathodic area, described cathode assembly is by forming with the wire that is connected power supply at the negative electrode conducting plates of cathodic area activity, described anode component is by forming with the wire that is connected power supply at the anode conducting plate of positive column activity, the top, cathodic area of described plating tank is provided with a charging opening, the below, cathodic area of described plating tank is provided with a discharge port.
Further, described anode conducting plate is parallel to negative electrode conducting plates, and it is static relatively.
Further, the described charging opening mixing bunker in parallel with at least two is connected.
Further, the upper end of described discharge port is provided with a matrix material settling bin.
Further, the described discharge port solid-liquid separator in parallel with at least two is connected.
Further, below, the positive column of described plating tank arranges at least one electrolytic solution relief outlet.
Further, described solid-liquid separator liquid outlet, positive column electrolytic solution relief outlet are connected with below electrolytic solution container for storing liquid through pipeline, and electrolytic solution container for storing liquid is connected with mixing bunker with pump through pipeline.
The invention has the beneficial effects as follows: the present invention can realize the industrialization that the plumbous carbon composite of doping is produced, simple to operate, turnout is relatively large, the plumbous carbon composite lead deposit amount of producing evenly, stable performance, the present invention also can be used for the continuous production of other other kind metal or alloy of particle galvanic deposit.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Fig. 2 is the operation material distribution schematic diagram of electrolyzer in the present invention, and in figure, arrow represents material movement direction.
Fig. 3 is the vertical view of electrolyzer in the present invention, and in figure, arrow represents electrode turning direction.
Fig. 4 is the front view of settling bin in the present invention.
Fig. 5 is the vertical view of settling bin in the present invention.
In accompanying drawing: 1: anode conducting plate; 2: negative electrode conducting plates; 3: dividing plate; 4: discharge port; 5: settling bin; 6: plating tank; 7: agitator; 8: charging opening; 9: electrolytic solution relief outlet; 10: solid-liquid separator; 11: mixing bunker; 12: pump; 13: container for storing liquid.
Embodiment
As shown in Figure 1, Figure 2, Figure 3 shows, a kind of plumbous carbon composite electric deposition device of the present invention, is comprised of plating tank 6, anode component, movable cathode assembly and agitator 7.Plating tank 6 is by not only being divided into anode, two regions of negative electrode by dividing plate 3 or the barrier film of plated material by electrolytic solution, anode component is comprised of with the wire that is connected power supply anode conducting plate 1, anode conducting plate 1 can be stereotype, cathode assembly is by forming with the wire that is connected power supply at the negative electrode conducting plates 2 of cathode zone activity, negative electrode conducting plates 2 can be titanium plate, and anode 1 plate is parallel to negative electrode and relatively it is static.Apparatus of the present invention do not comprise electroplating power supply, and DC voltage-stabilizing external power need be provided, and positive and negative electrode is connected with respective anode plate 1, negative electrode conducting plates 2 by this device wire respectively.
Cathode zone arranges a discharge port 4 and a charging opening 8.At discharge port 4 front ends, a matrix material settling bin 5 is set, this settling bin is doline (as shown in Figure 4, Figure 5), and big opening end is connected with plating tank cathodic area.Below, positive column arranges at least one electrolytic solution relief outlet 9, for regulating cathode zone liquid-solid ratio.Discharge port 4 solid-liquid separator 10 in parallel with at least two is connected, to be used alternatingly, guarantees that discharging is continuous, and solid-liquid separator can adopt centrifugal filter.Charging opening 8 mixing bunker 11 in parallel with at least two is connected, to be used alternatingly, guarantees that charging is continuous.Solid-liquid separator 10 liquid outlets, positive column electrolytic solution relief outlet 9 are connected with below electrolytic solution container for storing liquid 13 through pipeline, and electrolytic solution container for storing liquid 13 is connected with mixing bunker 11 with pump 12 through pipeline.
The working process of a kind of plumbous carbon composite electric deposition device of the present invention is as follows:
In mixing bunker 11, add in proportion activity charcoal powder and electroplate liquid, agitator 7 is uniformly mixed and makes gac fully to be soaked, open baiting valve, mixed solution enters plating tank 6 cathodic areas by charging opening 8, two mixing bunkers 11 adopt the mode of operation of the blowing of alternately preparing burden, and guarantee uninterrupted charging.The gac that enters plating tank 6 is dispersed in the electrolytic solution in cathodic area, negative electrode conducting plates 2 does not stop rotation, gac phase anticathode conducting plates 2 motion, a part of gac contacts and becomes negative electrode with negative electrode conducting plates 2, the lead ion reduce deposition that discharges on gac in this section.Along with this part gac of rotation of negative electrode conducting plates 2 has left again negative electrode conducting plates 2, but constantly having new gac contacts with negative electrode conducting plates 2 and is deposited upper lead, agitator 7 makes activated carbon at cathodic area sufficient movement, the heavier gac that is deposited lead sinks to settling bin 5 bottoms, other activity continue in cathodic area motion until on being deposited enough lead arrive certain weight proportion and sink to settling bin 5 bottoms.The plumbous gac that has been deposited of settling bin 5 bottoms is put into one of them solid-liquid separator 10 through mixture discharge port 4; through separation; plumbous carbon composite is collected; washing and drying obtains finished product; when a separator is shut down collection material therein, open another one separator and carry out mask work, be used alternatingly assurance continuous discharge; the electrolytic solution that separation obtains enters container for storing liquid 13 through pipeline, and the electrolytic solution in container for storing liquid 13 is sent into mixing bunker 11 by pump 12 and recycled.When the liquid-solid ratio of cathodic area electrolytic solution and plated body is large, open electrolytic solution relief outlet 9, get rid of electrolytic solution to regulate the liquid-solid ratio of plating tank.
Claims (7)
1. a plumbous carbon composite electric deposition device, it is characterized in that: comprise plating tank (6), anode component, cathode assembly and agitator (7), described plating tank (6) is by not only being divided into positive column by the dividing plate (3) of plated material by electrolytic solution, Liang Ge region, cathodic area, described cathode assembly is by forming with the wire that is connected power supply at the negative electrode conducting plates (2) of cathodic area activity, described anode component is by forming with the wire that is connected power supply at the anode conducting plate (1) of positive column activity, the top, cathodic area of described plating tank (6) is provided with a charging opening (8), the below, cathodic area of described plating tank (6) is provided with a discharge port (4).
2. a kind of plumbous carbon composite electric deposition device according to claim 1, is characterized in that: described anode conducting plate (1) is parallel to negative electrode conducting plates (2), and it is static relatively.
3. a kind of plumbous carbon composite electric deposition device according to claim 2, is characterized in that: described charging opening (8) mixing bunker (11) in parallel with at least two is connected.
4. according to a kind of plumbous carbon composite electric deposition device described in claim 1~3 any one, it is characterized in that: the upper end of described discharge port (4) is provided with a matrix material settling bin (5).
5. according to a kind of plumbous carbon composite electric deposition device described in claim 1~3 any one, it is characterized in that: described discharge port (4) solid-liquid separator (10) in parallel with at least two is connected.
6. a kind of plumbous carbon composite electric deposition device according to claim 5, is characterized in that: the below, positive column of described plating tank arranges at least one electrolytic solution relief outlet (9).
7. a kind of plumbous carbon composite electric deposition device according to claim 6, it is characterized in that: described solid-liquid separator (10) liquid outlet, positive column electrolytic solution relief outlet (9) are connected with below electrolytic solution container for storing liquid (13) through pipeline, electrolytic solution container for storing liquid (13) is connected with mixing bunker (11) with pump (12) through pipeline.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115283254A (en) * | 2022-07-29 | 2022-11-04 | 中触媒新材料股份有限公司 | System and method for quickly screening and activating oxygen production adsorbent particle airflow |
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CN1556253A (en) * | 2004-01-06 | 2004-12-22 | 上海维安热电材料股份有限公司 | Preparation method of composite cladding material and equipment |
US20110079515A1 (en) * | 2009-07-15 | 2011-04-07 | Gilliam Ryan J | Alkaline production using a gas diffusion anode with a hydrostatic pressure |
CN102899679A (en) * | 2012-10-24 | 2013-01-30 | 四川大学 | Method for coproducing sulfuric acid by utilizing gypsum mineralized CO2 |
CN103219162A (en) * | 2013-03-27 | 2013-07-24 | 江苏华富储能新技术股份有限公司 | Nanometer carbon-lead super capacitor battery |
CN203807580U (en) * | 2014-04-15 | 2014-09-03 | 株洲冶炼集团股份有限公司 | Electro-deposition device for lead carbon composite material |
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2014
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Patent Citations (6)
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US5672181A (en) * | 1994-02-16 | 1997-09-30 | Hans Warlimont | Method for manufacturing a hardened lead storage battery electrode |
CN1556253A (en) * | 2004-01-06 | 2004-12-22 | 上海维安热电材料股份有限公司 | Preparation method of composite cladding material and equipment |
US20110079515A1 (en) * | 2009-07-15 | 2011-04-07 | Gilliam Ryan J | Alkaline production using a gas diffusion anode with a hydrostatic pressure |
CN102899679A (en) * | 2012-10-24 | 2013-01-30 | 四川大学 | Method for coproducing sulfuric acid by utilizing gypsum mineralized CO2 |
CN103219162A (en) * | 2013-03-27 | 2013-07-24 | 江苏华富储能新技术股份有限公司 | Nanometer carbon-lead super capacitor battery |
CN203807580U (en) * | 2014-04-15 | 2014-09-03 | 株洲冶炼集团股份有限公司 | Electro-deposition device for lead carbon composite material |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN115283254A (en) * | 2022-07-29 | 2022-11-04 | 中触媒新材料股份有限公司 | System and method for quickly screening and activating oxygen production adsorbent particle airflow |
CN115283254B (en) * | 2022-07-29 | 2023-08-25 | 中触媒新材料股份有限公司 | Rapid screening and activating system and method for air flow of oxygen-making adsorbent particles |
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Application publication date: 20140730 |