CN115279878A - 清洁组合物 - Google Patents
清洁组合物 Download PDFInfo
- Publication number
- CN115279878A CN115279878A CN202180020652.XA CN202180020652A CN115279878A CN 115279878 A CN115279878 A CN 115279878A CN 202180020652 A CN202180020652 A CN 202180020652A CN 115279878 A CN115279878 A CN 115279878A
- Authority
- CN
- China
- Prior art keywords
- acid
- mixtures
- composition
- cleaning
- thymol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 97
- 238000004140 cleaning Methods 0.000 title claims abstract description 32
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 claims abstract description 44
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims abstract description 41
- 235000007586 terpenes Nutrition 0.000 claims abstract description 28
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000005844 Thymol Substances 0.000 claims abstract description 22
- 229960000790 thymol Drugs 0.000 claims abstract description 22
- YHQGMYUVUMAZJR-UHFFFAOYSA-N α-terpinene Chemical compound CC(C)C1=CC=C(C)CC1 YHQGMYUVUMAZJR-UHFFFAOYSA-N 0.000 claims abstract description 22
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims abstract description 21
- 235000001510 limonene Nutrition 0.000 claims abstract description 21
- 229940087305 limonene Drugs 0.000 claims abstract description 21
- -1 aliphatic terpene alcohols Chemical class 0.000 claims abstract description 20
- 150000003505 terpenes Chemical class 0.000 claims abstract description 18
- 150000002989 phenols Chemical class 0.000 claims abstract description 13
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000005770 Eugenol Substances 0.000 claims abstract description 11
- WSTYNZDAOAEEKG-UHFFFAOYSA-N Mayol Natural products CC1=C(O)C(=O)C=C2C(CCC3(C4CC(C(CC4(CCC33C)C)=O)C)C)(C)C3=CC=C21 WSTYNZDAOAEEKG-UHFFFAOYSA-N 0.000 claims abstract description 11
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 11
- 229960002217 eugenol Drugs 0.000 claims abstract description 11
- HHTWOMMSBMNRKP-UHFFFAOYSA-N carvacrol Natural products CC(=C)C1=CC=C(C)C(O)=C1 HHTWOMMSBMNRKP-UHFFFAOYSA-N 0.000 claims abstract description 9
- RECUKUPTGUEGMW-UHFFFAOYSA-N carvacrol Chemical compound CC(C)C1=CC=C(C)C(O)=C1 RECUKUPTGUEGMW-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000007746 carvacrol Nutrition 0.000 claims abstract description 9
- WYXXLXHHWYNKJF-UHFFFAOYSA-N isocarvacrol Natural products CC(C)C1=CC=C(O)C(C)=C1 WYXXLXHHWYNKJF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000001169 1-methyl-4-propan-2-ylcyclohexa-1,4-diene Substances 0.000 claims abstract description 8
- LCHYEKKJCUJAKN-UHFFFAOYSA-N 2-propylphenol Chemical compound CCCC1=CC=CC=C1O LCHYEKKJCUJAKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- NGFPWHGISWUQOI-UHFFFAOYSA-N 2-sec-butylphenol Chemical compound CCC(C)C1=CC=CC=C1O NGFPWHGISWUQOI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229930007927 cymene Natural products 0.000 claims abstract description 8
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000007875 phellandrene derivatives Chemical class 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 30
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 229940041616 menthol Drugs 0.000 claims description 18
- 230000002378 acidificating effect Effects 0.000 claims description 12
- 239000003826 tablet Substances 0.000 claims description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 150000007524 organic acids Chemical group 0.000 claims description 7
- NOOLISFMXDJSKH-OPRDCNLKSA-N Isomenthol Chemical compound CC(C)[C@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-OPRDCNLKSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- 235000015165 citric acid Nutrition 0.000 claims description 6
- NOOLISFMXDJSKH-LPEHRKFASA-N Isomenthol Natural products CC(C)[C@@H]1CC[C@H](C)C[C@H]1O NOOLISFMXDJSKH-LPEHRKFASA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 239000002775 capsule Substances 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 4
- 239000007937 lozenge Substances 0.000 claims description 4
- 229930007461 neoisomenthol Natural products 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- 150000008064 anhydrides Chemical class 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 235000019820 disodium diphosphate Nutrition 0.000 claims description 2
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 claims description 2
- RRPFCKLVOUENJB-UHFFFAOYSA-L disodium;2-aminoacetic acid;carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O.NCC(O)=O RRPFCKLVOUENJB-UHFFFAOYSA-L 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 235000011087 fumaric acid Nutrition 0.000 claims description 2
- 239000000174 gluconic acid Substances 0.000 claims description 2
- 235000012208 gluconic acid Nutrition 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 2
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 2
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 239000011736 potassium bicarbonate Substances 0.000 claims description 2
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 2
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 2
- 235000011181 potassium carbonates Nutrition 0.000 claims description 2
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 125000005587 carbonate group Chemical group 0.000 claims 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 229960000686 benzalkonium chloride Drugs 0.000 description 4
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 4
- 239000004579 marble Substances 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 2
- NOOLISFMXDJSKH-BBBLOLIVSA-N (1s,2r,5r)-5-methyl-2-propan-2-ylcyclohexan-1-ol Chemical compound CC(C)[C@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-BBBLOLIVSA-N 0.000 description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 2
- 229920003171 Poly (ethylene oxide) Chemical class 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical group C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 229960001927 cetylpyridinium chloride Drugs 0.000 description 2
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 2
- 229960004670 didecyldimethylammonium chloride Drugs 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 229940075966 (+)- menthol Drugs 0.000 description 1
- NOOLISFMXDJSKH-AEJSXWLSSA-N (+)-menthol Chemical compound CC(C)[C@H]1CC[C@H](C)C[C@@H]1O NOOLISFMXDJSKH-AEJSXWLSSA-N 0.000 description 1
- NOOLISFMXDJSKH-GUBZILKMSA-N (-)-neoisomenthol Chemical compound CC(C)[C@@H]1CC[C@H](C)C[C@@H]1O NOOLISFMXDJSKH-GUBZILKMSA-N 0.000 description 1
- ZUTYZAFDFLLILI-UHFFFAOYSA-N 4-sec-Butylphenol Chemical compound CCC(C)C1=CC=C(O)C=C1 ZUTYZAFDFLLILI-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229960004830 cetylpyridinium Drugs 0.000 description 1
- NEUSVAOJNUQRTM-UHFFFAOYSA-N cetylpyridinium Chemical compound CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 NEUSVAOJNUQRTM-UHFFFAOYSA-N 0.000 description 1
- RLGQACBPNDBWTB-UHFFFAOYSA-N cetyltrimethylammonium ion Chemical class CCCCCCCCCCCCCCCC[N+](C)(C)C RLGQACBPNDBWTB-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 229960004873 levomenthol Drugs 0.000 description 1
- 125000000396 limonene group Chemical group 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical class CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0056—Lavatory cleansing blocks
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0052—Gas evolving or heat producing compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2034—Monohydric alcohols aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
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Abstract
本发明涉及用于清洁表面，特别是用于清洁如抽水马桶的浸没表面的单位剂量清洁组合物。该组合物包含表面活性剂体系，其包含阳离子表面活性剂，选自百里酚、仲丁基苯酚、香芹酚、丁香酚、丙基苯酚或其混合物的一种或多种取代的酚，一种或多种脂肪族萜烯醇；和选自柠檬烯、α‑萜品烯、萜品油烯、伞花烃、水芹烯或其混合物的一种或多种不饱和萜烯。
Description
技术领域
本发明涉及用于清洁表面，特别是用于清洁如抽水马桶的浸没表面的清洁组合物。
背景技术
需要向消费者提供能够去除家居表面(例如厨房和浴室表面)上的污渍的清洁组合物。特别地，需要能有效除去浸没于水中例如抽水马桶中的污渍的清洁组合物。
本领域已知的用于清洁抽水马桶的清洁组合物在保持卫生表面(抗微生物)方面是有效的，但是通常这种清洁组合物往往在浸没表面上的具有低的清洁功效。
仍然需要即使在浸没在水中的表面上也具有去污功效并确保保持卫生环境的清洁组合物。
本发明的一个目的是提供一种在浸没表面上提供清洁益处的组合物。
在第一方面，提供了单位剂量，优选固体，清洁组合物，其包含：
a)包含阳离子表面活性剂的表面活性剂体系，
b)选自百里酚、仲丁基苯酚、香芹酚、丁香酚、丙基苯酚或其混合物的一种或多种取代酚，优选百里酚，
c)一种或多种脂肪族萜烯醇，优选薄荷醇；以及
d)选自柠檬烯、α-萜品烯、萜品油烯、伞花烃、水芹烯或其混合物的一种或多种不饱和萜烯，优选柠檬烯，
其中所述组合物包含具有碱性组分和酸性组分的泡腾系统(effervescentsystem)。
令人惊奇地发现，根据本发明的清洁组合物能够在浸没表面上(例如：抽水马桶)提供清洁益处。
为了避免疑义，本发明的一个方面的任何特征可用于本发明的任何其它方面。词语“包含(comprising)”旨在表示“包括(including)”，但并不必然是“由……组成(consisting of)”或“由……构成(composed of)”。因此，术语“包含”并不意味着限制于任何随后陈述的元素，而是任选地还涵盖具有主要或次要功能意义的未指定元素。换句话说，所列出的步骤或选项不需要是穷举的。无论何时使用词语“包括”或“具有”，这些术语意味着等同于如上定义的“包含”。应注意，以下描述中给出的实施例旨在阐明本发明，而非旨在将本发明限制于这些实施例本身。除了在实施例中，或另外明确指出，本说明书中表示材料的量或反应条件、材料的物理性质和/或用途的所有数字应理解为由词语“约”修饰。除非另有说明，否则以“x至y”形式表示的数值范围应理解为包括x和y。当针对特定特征以“x至y”的格式描述多个优选范围时，应理解也考虑组合不同端点的所有范围。除非另有说明，本文所用的量以基于组合物总重量的重量百分比表示并缩写为“wt％”。
单位剂量可以是固体或液体。优选地，单位剂量是浓缩物、胶囊、片剂、锭剂或块型剂(block)。优选地，单位剂量是固体。优选地，单位剂量是片剂、锭剂或块型剂。单位剂量优选是液体，且液体单位剂量是浓缩物或胶囊。
该组合物包含阳离子表面活性剂。优选地，阳离子表面活性剂是季铵表面活性剂，优选地，季铵表面活性剂选自十六烷基三甲基氯化铵(CTAC)、二癸基二甲基氯化铵(DDAC)、烷基二甲基苄基氯化铵(ADBAC)、氯化十六烷吡啶及其混合物。其他盐(例如：十六烷基三甲基铵、十二烷基二甲基铵、烷基二甲基苄基铵和十六烷基吡啶的溴盐和碘盐)也可以使用。更优选地，季铵表面活性剂是烷基二甲基苄基氯化铵，例如苯扎氯铵(BKC)。
优选地，组合物包含0.1至20wt％，更优选0.5至15wt％，甚至更优选1至10wt％，优选1至8wt％，还更优选1.5至5wt％的阳离子表面活性剂。
优选地，a)、b)、c)和d)的总和在0.1-10wt％，更优选1-9wt％，甚至更优选2-8wt％，最优选3-7wt％的范围内。
所述组合物优选包含：
b)0.01至5wt％的一种或多种取代酚，其选自百里酚、仲丁基苯酚、香芹酚、丁香酚、丙基苯酚或其混合物，优选百里酚，
c)0.01至5wt％的一种或多种脂肪族萜烯醇，优选薄荷醇；以及
d)0.01至5wt％的一种或多种不饱和萜烯，其选自柠檬烯、α-萜品烯、萜品油烯、伞花烃、水芹烯或其混合物，优选柠檬烯，
选自百里酚、仲丁基苯酚、香芹酚、丁香酚、丙基苯酚或其混合物的一种或多种取代酚的量优选在0.01至5wt％，优选0.02至2.5wt％，更优选0.05至2wt％，甚至更优选0.075至1.5wt％，还更优选0.1至1.0wt％，最优选0.5至1.0wt％的范围内。
优选地，取代酚是百里酚。还可以优选使用百里酚(香芹酚)的结构异构体。
优选地，组合物包含0.01至5wt％，更优选0.02至2.5wt％，甚至更优选0.05至2wt％，进一步更优选0.075至1.5wt％，还更优选0.1至1.0wt％，最优选0.5至1.0wt％的百里酚。
组合物包含一种或多种脂肪族萜烯醇。优选地，组合物包含0.01至5wt％，更优选0.02至2.5wt％，甚至更优选0.025至1.0wt％，还更优选0.05至0.75wt％，甚至更优选0.1至0.5wt％的萜烯醇。
萜烯醇优选选自薄荷醇、异薄荷醇、新薄荷醇、新异薄荷醇及其混合物。萜烯醇可以是(+)或(-)立体异构体，例如(+)-薄荷醇、(+)-异薄荷醇、(+)-新薄荷醇、(+)-新异薄荷醇、(-)-薄荷醇、(-)-异薄荷醇、(-)-新薄荷醇、(-)-新异薄荷醇。
薄荷醇的结构如下：
在本申请的含义内，“脂肪族萜烯”优选指不含不饱和(碳-碳)键的萜烯。
本发明的组合物还包含一种或多种不饱和萜烯。优选地，组合物包含0.01至5wt％，更优选0.02至2.5wt％，甚至更优选0.025至1.0wt％，还更优选0.05至0.75wt％，甚至更优选0.1至0.5wt％的一种或多种不饱和萜烯。
优选地，一种或多种不饱和萜烯包括柠檬烯、α-萜品烯、萜品油烯、伞花烃、水芹烯或其混合物，更优选柠檬烯。
在本申请的含义内，“不饱和萜烯”优选是指萜烯确实包含不饱和(碳-碳)键并且不包含羟基。
优选地，不饱和萜烯是柠檬烯。柠檬烯的结构如下：
优选地，组合物包含百里酚、薄荷醇和柠檬烯。优选地，该组合物包含0.05-2wt％的百里酚、0.025-1wt％的薄荷醇、0.025-2wt％的柠檬烯。
组合物优选包含0.1-10wt％，优选1-9wt％，更优选2-8wt％，最优选3-7wt％的取代酚、脂肪族萜烯醇、不饱和萜烯或其混合物。
优选地，取代酚、脂肪族萜烯醇和不饱和萜烯以1：0.5：0.5的比率存在。
应当理解，如果取代酚以1份存在，则脂肪族萜烯醇以0.5份存在，且不饱和萜烯以0.5份存在。
例如，如果是取代酚(例如，百里酚或丁香酚或丁基苯酚)以1份存在，则脂肪族萜烯醇(例如，薄荷醇)以0.5份存在；且不饱和萜烯(例如，柠檬烯、α-萜品烯或萜品油烯)以0.5份存在。
组合物包含具有碱性组分和酸性组分的泡腾系统。
碱性组分优选选自碳酸盐、碳酸氢盐、倍半碳酸盐及其混合物。更优选地，碳酸盐组分优选为碱金属碳酸盐，优选碳酸钠、碳酸氢钠、碳酸钾、碳酸氢钾、甘氨酸碳酸钠及其混合物。
酸性组分优选选自有机酸，例如羧酸、有机酸盐、有机酸酐、无机酸、无机酸盐及其混合物。优选地，有机酸以及相关的盐和酸酐选自具有至多8个碳原子的羧酸。
酸性组分在泡腾系统中的存在量优选为20-80wt％，更优选20-60wt％，甚至更优选20-40wt％。
优选地，酸组分是有机酸、酸酐、磷酸二氢钠、焦磷酸二氢二钠、酸式柠檬酸盐、酸式亚硫酸钠及其混合物，优选地其中酸源是选自柠檬酸、苹果酸、酒石酸、富马酸、氨基磺酸、草酸、马来酸、葡糖酸、琥珀酸、水杨酸、己二酸及其混合物的有机酸，更优选地其中酸是柠檬酸。
酸性和碱性组分以实现单位剂量的快速、完全溶解的量包括。因此，酸性组分与碱性组分的摩尔比应在约1.0：2.0至约1.0：4.0的范围内。
优选地，酸性和碱性组分的组合应占单位剂量的50wt％。更优选地，酸性和碱性组分占单位剂量的至少75wt％，最优选占单位剂量的至少80wt％。
优选地，组合物包含0.1至20wt％，更优选0.5至20wt％，甚至更优选1至15wt％的包含阳离子表面活性剂的表面活性剂体系。
组合物优选包含小于5wt％，更优选小于2.5wt％，最优选小于1wt％的一种或多种阴离子表面活性剂。
优选地，阴离子表面活性剂选自烷基苯磺酸盐、烷基磺酸盐，烷基硫酸盐、氟化脂肪酸的盐、硅氧烷(silicones)、脂肪醇硫酸盐、聚氧乙烯脂肪醇醚硫酸盐、α-烯烃磺酸盐、聚氧乙烯脂肪醇磷酸酯醚、烷基醇及其混合物。
优选地，表面活性剂体系包含小于2％，优选小于1％的非离子表面活性剂，最优选地，组合物不含非离子表面活性剂。
优选地，非离子表面活性剂选自氨基多葡萄糖苷(APG)、脂肪醇乙氧基化物、烷基酚乙氧基化物和脂肪酸烷氧基化物和tergitol(乙氧基化醇)。
在第二方面，提供了制备单位剂量清洁组合物的方法，包括以下步骤：
i.将碱性组分、酸性组分和阳离子表面活性剂与以下组合：
a)选自百里酚、仲丁基苯酚、香芹酚、丁香酚、丙基苯酚或其混合物的一种或多种取代酚，优选百里酚，
b)一种或多种脂肪族萜烯醇，优选薄荷醇；以及
c)选自柠檬烯、α-萜品烯、萜品油烯、伞花烃、水芹烯或其混合物的一种或多种不饱和萜烯，优选柠檬烯，以提供清洁组合物，优选固体清洁组合物。
为清洁组合物描述的组分和量经必要的修改适用于制备清洁组合物的方法。
优选地，方法包括形成固体清洁组合物，更优选形成单位剂量的步骤。优选地，单位剂量是浓缩物、胶囊、片剂、锭剂或块型剂。
在第三方面，提供了一种清洁浸没表面(优选抽水马桶)的方法，所述方法包括使如本文所定义的组合物与水(优选在抽水马桶中)接触的步骤。
在第四方面，提供了如本文所定义的组合物用于清洁浸没表面(优选抽水马桶)的用途。
现在将通过以下非限制性实施例举例说明本发明。
实施例
实验中使用的材料是可商购的并且从其供应商处购买，如下所示：
百里酚(Ronak Fine Industries)，
4-仲丁基苯酚(产品目录号B7030；TCI Chemicals India private limited)，
子香酚(Nishant Aromas)，
薄荷醇(产品目录号M2772；Sigma Aldrich)，
D-柠檬烯(Cutrale)，
萜品油烯(产品目录号86485；Sigma Aldrich)；以及
α-萜品烯(产品目录号223182；Sigma Aldrich)。
制备根据表1的组合物(片剂形式)。
表1
| 成分 | 1 | 2 | A | B |
| 碳酸钠 | 28 | 28 | 28 | 28 |
| 柠檬酸(食品级) | 66 | 66 | 66 | 66 |
| 硫酸钠 | 2 | 2 | 2 | 2 |
| 氨基多葡萄糖苷(APG，非离子的) | 0 | 2 | 0 | 0 |
| SLS | 2 | 0 | 2 | 2 |
| 百里酚/薄荷醇/柠檬烯* | 0.5 | 0.5 | 0 | 1.5 |
| 烷基二甲基苄基氯化铵(BKC) | 1 | 1 | 1.5 | 0 |
| 香料 | 0.5 | 0.5 | 0.5 | 0.5 |
| 总计 | 100 | 100 | 100 | 100 |
*比率：百里酚：薄荷醇：柠檬烯＝1：0.5：0.5
水垢去除试验
在具有与马桶的典型虹吸管相似形状和尺寸的塑料装置中进行水垢去除测试。将12个片剂(根据表1的每种组合物)装载在设备的倾斜侧(60°角)上的硅板(P)上(对应于24cm2面积)。第二硅板(L)上装载了8个水垢片(对应于16cm2的面积)，其水平地放置在设备的底部。用2升自来水填充该装置，然后加入80g净产品(在表1中提及的)。接触30分钟后，移除装载的片剂，在温和流动的自来水下冲洗30秒，然后在70℃下干燥过夜，之后重新称重以计算片剂重量损失。最少3次重复用于评估每个系统。
水垢去除＝(Pi-Pf)/24+(Li-Lf)/16＝水垢去除mg/1cm2
Pi＝试验开始前12个片剂的初始重量(mg)
Pf＝干燥过夜后12个片剂的最终重量(mg)
Li＝试验开始前8个片剂的初始重量(mg)
Lf＝干燥过夜后8个片剂的最终重量(mg)
表2
此外，还使用Carrara大理石瓷砖(8cm×3cm×1cm)作为代表性表面来评估根据本发明的组合物(在下表3中)的水垢去除能力。该方法测量作为大理石和水垢的主要组分的碳酸钙的溶解水平。然后通过重量法评价由于这些测试组合物获得的碳酸钙溶解。简言之，用压缩空气干燥清洁瓷砖以除去大理石残余物，然后将它们置于烘箱中(105℃，2h)。2h后，取出瓷砖并在玻璃干燥器中在室温下冷却；并称重以记录以克计的“初始重量”。然后进一步使用这种瓷砖。将瓷砖浸泡在具有表3中所示的80g测试组合物(溶解在70mL水中的10g组合物)的塑料圆筒中持续1h(连同提供4.01±0.03％污垢去除的作为参考的2％HCl溶液)。此后，用自来水冲洗瓷砖以除去所有产物残余物。然后将瓷砖置于烘箱中(105℃持续2h)，之后在玻璃干燥器中在室温下冷却；并称重以记录以克计的“最终重量”。
使用以下等式根据去除的Carrara大理石的重量确定污垢去除：
污垢去除％＝(初始重量-最终重量)/初始重量×100
表3
| 成分 | 3 | 4 | 5 |
| 碳酸钠 | 28 | 28 | 28 |
| 柠檬酸(食品级) | 66 | 66 | 66 |
| 硫酸钠 | 2 | 2 | 2 |
| 氨基多葡萄糖苷(APG，非离子的) | 0 | 0 | 0 |
| SLS | 2 | 2 | 2 |
| 百里酚/薄荷醇/柠檬烯<sup>1</sup> | 0.5 | - | - |
| 4-仲丁基苯酚/薄荷醇/α萜品烯<sup>1</sup> | - | 0.5 | - |
| 丁香酚/薄荷醇/萜品油烯<sup>1</sup> | - | - | 0.5 |
| 烷基二甲基苄基氯化铵(BKC) | - | 1 | 1 |
| 阳离子氯化十六烷吡啶 | 1 | - | - |
| 香料 | 0.5 | 0.5 | 0.5 |
| 总计 | 100 | 100 | 100 |
1比例：1：0.5：0.5
表4
污渍去除试验
将根据本发明的组合物(1，表1)与可商购的马桶清洁剂(Harpic)进行比较。23名消费者测试组合物和对比产品3天。以10分标度评价污渍去除-从1没有污渍去除到10完全污渍去除。
表5
Claims (14)
1.一种单位剂量清洁组合物，其包含：
a)阳离子表面活性剂，
b)一种或多种取代酚，其选自百里酚、仲丁基苯酚、香芹酚、丁香酚、丙基苯酚及其混合物，
c)一种或多种脂肪族萜烯醇，其选自薄荷醇、异薄荷醇、新薄荷醇、新异薄荷醇及其混合物；以及
d)一种或多种不饱和萜烯，其选自柠檬烯、α-萜品烯、萜品油烯、伞花烃、水芹烯及其混合物，
其中所述组合物包含具有碱性组分和酸性组分的泡腾型系统。
2.根据权利要求1所述的组合物，其中a)、b)、c)和d)的总和在0.1至10wt％的范围内。
3.根据权利要求1或2所述的组合物，其包含：
b)0.01至5wt％的一种或多种取代酚，其选自百里酚、仲丁基苯酚、香芹酚、丁香酚、丙基苯酚及其混合物，
c)0.01至5wt％的一种或多种脂肪族萜烯醇，其选自薄荷醇、异薄荷醇、新薄荷醇、新异薄荷醇及其混合物；以及
d)0.01至5wt％的一种或多种不饱和萜烯，其选自柠檬烯、α-萜品烯、萜品油烯、伞花烃、水芹烯及其混合物。
4.根据前述权利要求中任一项所述的组合物，其包含百里酚、薄荷醇和柠檬烯。
5.根据前述权利要求中任一项所述的组合物，其中所述碱性组分为碳酸盐源，其选自碱金属碳酸盐，优选碳酸钠、碳酸氢钠、碳酸钾、碳酸氢钾、甘氨酸碳酸钠及其混合物。
6.根据前述权利要求中任一项所述的组合物，其中所述酸性组分是有机酸、酸酐、磷酸二氢钠、焦磷酸二氢二钠、酸式柠檬酸盐、酸式亚硫酸钠及其混合物，优选地其中所述酸源为有机酸，其选自柠檬酸、苹果酸、酒石酸、富马酸、氨基磺酸、草酸、马来酸、葡糖酸、琥珀酸、水杨酸、己二酸及其混合物，更优选地其中所述酸是柠檬酸。
7.根据前述权利要求中任一项所述的组合物，其包含0.1至20wt％的阳离子表面活性剂。
8.根据前述权利要求中任一项所述的组合物，其中所述阳离子表面活性剂是季铵表面活性剂。
9.根据前述权利要求中任一项所述的组合物，其中所述组合物包含0.1至5wt％的阴离子表面活性剂。
10.根据前述权利要求中任一项所述的组合物，其中所述组合物包含0至2wt％的非离子表面活性剂。
11.一种制备单位剂量清洁组合物的方法，包括以下步骤：
i.将碱性组分、酸性组分和阳离子表面活性剂与以下物质组合：
a.一种或多种取代酚，其选自百里酚、仲丁基苯酚、香芹酚、丁香酚、丙基苯酚或其混合物，
b.一种或多种脂肪族萜烯醇，其选自薄荷醇、异薄荷醇、新薄荷醇、新异薄荷醇及其混合物；以及
c.一种或多种不饱和萜烯，其选自柠檬烯、α-萜品烯、萜品油烯、伞花烃、水芹烯或其混合物，
以提供清洁组合物。
12.根据权利要求11所述的方法，其中单位剂量是浓缩剂、胶囊、片剂、锭剂或块型剂。
13.一种清洁浸没表面，优选抽水马桶的方法，所述方法包括使根据权利要求1至10中任一项所述的或根据权利要求11至12获得的组合物与水，优选在抽水马桶中接触的步骤。
14.根据权利要求1至10中任一项所述的或根据权利要求11至12获得的组合物用于清洁浸没表面，优选抽水马桶的用途。
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| EP20163023 | 2020-03-13 | ||
| EP20163023.3 | 2020-03-13 | ||
| PCT/EP2021/056359 WO2021180936A1 (en) | 2020-03-13 | 2021-03-12 | A cleaning composition |
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| CN115279878A true CN115279878A (zh) | 2022-11-01 |
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| EP (1) | EP4118176A1 (zh) |
| CN (1) | CN115279878A (zh) |
| BR (1) | BR112022017867A2 (zh) |
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| WO2023046691A1 (en) * | 2021-09-22 | 2023-03-30 | Unilever Ip Holdings B.V. | Fabric softening composition |
| WO2023180053A1 (en) | 2022-03-22 | 2023-09-28 | Unilever Ip Holdings B.V. | A solid hard surface cleaning composition |
| WO2024068248A1 (en) | 2022-09-29 | 2024-04-04 | Unilever Ip Holdings B.V. | A solid cleaning and disinfection composition |
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2021
- 2021-03-12 EP EP21710517.0A patent/EP4118176A1/en active Pending
- 2021-03-12 WO PCT/EP2021/056359 patent/WO2021180936A1/en active Application Filing
- 2021-03-12 CN CN202180020652.XA patent/CN115279878A/zh active Pending
- 2021-03-12 BR BR112022017867A patent/BR112022017867A2/pt unknown
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- 2022-08-29 ZA ZA2022/09625A patent/ZA202209625B/en unknown
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Also Published As
| Publication number | Publication date |
|---|---|
| EP4118176A1 (en) | 2023-01-18 |
| ZA202209625B (en) | 2023-12-20 |
| BR112022017867A2 (pt) | 2022-11-01 |
| WO2021180936A1 (en) | 2021-09-16 |
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