CN115246723A - Special ceramic tile adhesive for alkali-efflorescence-resistant super-soft rock plate and preparation method thereof - Google Patents
Special ceramic tile adhesive for alkali-efflorescence-resistant super-soft rock plate and preparation method thereof Download PDFInfo
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- CN115246723A CN115246723A CN202210301930.5A CN202210301930A CN115246723A CN 115246723 A CN115246723 A CN 115246723A CN 202210301930 A CN202210301930 A CN 202210301930A CN 115246723 A CN115246723 A CN 115246723A
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- China
- Prior art keywords
- efflorescence
- alkali
- rock plate
- soft rock
- cellulose ether
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2623—Polyvinylalcohols; Polyvinylacetates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/38—Polysaccharides or derivatives thereof
- C04B24/383—Cellulose or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0045—Polymers chosen for their physico-chemical characteristics
- C04B2103/0057—Polymers chosen for their physico-chemical characteristics added as redispersable powders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0085—Thixotropic agents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2023—Resistance against alkali-aggregate reaction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Finishing Walls (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The tile glue adhesive special for the alkali-efflorescence-resistant super-soft rock plate comprises, by weight, 35-50 parts of cement, 10-30 parts of filler, 1-10 parts of redispersible latex powder, 0.3-1.5 parts of cellulose ether and 0.1-0.8 part of early strength agent. The invention adopts ethylene-vinyl acetate copolymer with 35-40% of vinyl acetate mass fraction as emulsion powder, can form a film on the surfaces of cement and filler, inhibits the precipitation of metal ions therein, and has the effect of alkali efflorescence resistance, and adopts the ethylene-vinyl acetate copolymer and the cement (5-8): (35-50), the bonding effect between the tile adhesive and the rock plate can be increased, and the tile adhesive has good flexibility, tensile strength and skid resistance, and can reach the standard of C2TES 1.
Description
Technical Field
The invention relates to a tile glue adhesive special for a whiskering-resistant ultra-soft rock board, relates to C04B, and particularly relates to the field of compositions of inorganic materials such as cement and lime.
Background
The rock plate is a novel material which is formed by pressing and sintering natural stone powder through a special process, has the performances of scratch resistance, corrosion resistance, easy cleaning and oil stain resistance, and has extremely low water permeability, so that the penetration of stains is avoided, the bacterial breeding is reduced, but the rock plate is lower in water permeability, compact in surface structure, difficult in the penetration of cement-based slurry and poor in adhesive property with a base body during construction, and therefore, the development of the tile adhesive special for bonding the rock plate is very important.
The invention patent CN201410631027.0 in China discloses a high-strength ceramic tile adhesive without efflorescence, which adopts high-alumina cement as a cementing material, and is matched with fly ash, blast furnace slag and double-fly ash fillers to effectively inhibit efflorescence, but the high-alumina cement has different hydration products and poor stability due to different construction environmental conditions. The Chinese patent CN201810558857.3 discloses a cement-based tile adhesive and a composition for preparing the same, wherein the content of sand is increased to more than 65%, and the shrinkage rate of a system is reduced, but the adopted Portland cement has low compressive strength and is easy to crack after being subjected to strong gravity.
Disclosure of Invention
In order to improve the bonding strength of the tile adhesive and a rock plate and have certain flexibility and transverse deformation rate, the first aspect of the invention provides a tile adhesive special for a saltpetering-resistant super-soft rock plate, which comprises, by weight, 35-50 parts of cement, 10-30 parts of filler, 1-10 parts of redispersible latex powder, 0.3-1.5 parts of cellulose ether and 0.1-0.8 part of an auxiliary agent.
As a preferable embodiment, the preparation raw materials comprise, by weight, 40-50 parts of cement, 15-25 parts of filler, 5-8 parts of redispersible latex powder, 0.5-1.2 parts of cellulose ether and 0.3-0.6 part of early strength agent.
As a preferred embodiment, the preparation raw materials comprise, by weight, 45 parts of cement, 20 parts of filler, 6 parts of redispersible latex powder, 0.8 part of cellulose ether and 0.5 part of early strength agent.
As a preferred embodiment, the cement is portland cement, and preferably, the strength grade of the portland cement is one or a combination of several selected from 42.5, 42.5R, 52.5R,62.5 and 62.5R.
In a preferred embodiment, the portland cement has a strength rating of 52.5 and is white cement.
As a preferred embodiment, the filler is selected from one or a combination of several of sand, silica fume, mineral powder, coal ash and quartz sand, and preferably, the particle size of the filler is 50-250 meshes.
In a preferred embodiment, the filler is sand having a particle size of a combination of 80-120 mesh and 200 mesh.
As a preferred embodiment, the weight ratio of the sand with the particle size of 80-120 meshes to the sand with the particle size of 200 meshes is 1: (0.8-1.5).
As a preferred embodiment, the weight ratio of the sand with the particle size of 80-120 meshes to the sand with the particle size of 200 meshes is 1:1.2.
the applicant found in the course of the experiment that the weight ratio of sand with a particle size of 80-120 mesh to 200 mesh was 1:1.2, the dispersion of the filler in the tile adhesive is improved and the compressive strength of the tile adhesive is also improved, presumably because: the sand with small particle size can be inserted into the sand with large particle size, the sand with large particle size plays a good reinforcing effect as the synergistic effect of the skeleton structure and the small particle size, and the sand with different particle sizes can slide to form a stable structure, so that the stress defect is prevented from being generated when the sand is impacted by external force.
In a preferred embodiment, the redispersible latex powder is selected from one or more of ethylene-vinyl acetate copolymer, vinyl acetate-ethylene versatate copolymer, acrylic acid copolymer, ethylene-vinyl chloride-vinyl laurate copolymer, vinyl acetate-ethylene-vinyl fatty acid copolymer, acrylate-styrene copolymer and vinyl acetate homopolymer.
In a preferred embodiment, the redispersible latex powder is an ethylene-vinyl acetate copolymer.
In a preferred embodiment, the mass fraction of the vinyl acetate in the ethylene-vinyl acetate copolymer is 20 to 40%.
In a preferred embodiment, the mass fraction of the vinyl acetate in the ethylene-vinyl acetate copolymer is 35 to 40%.
In a preferred embodiment, the mass fraction of the vinyl acetate in the ethylene-vinyl acetate copolymer is 38%.
In a preferred embodiment, the ethylene-vinyl acetate copolymer has a glass transition temperature of 0 to 5 ℃.
In a preferred embodiment, the ethylene-vinyl acetate copolymer has a glass transition temperature of 0 ℃.
In the experimental process, the applicant finds that the rock plate ceramic tile has extremely low water absorption rate, compact surface structure and difficult infiltration of cement-based slurry, and the pasting difficulty of the ceramic tile is increased due to the large size of the rock plate ceramic tile, and the applicant increases the bonding strength of the ceramic tile adhesive by introducing ethylene-vinyl acetate copolymer rubber powder into the ceramic tile adhesive, and the tensile property is improved to some extent, and the possible reason is guessed as follows: the Van der Waals force between the tile glue adhesive and the rock plate tile can be destroyed after the tile glue adhesive is soaked in water, the tile glue adhesive and the rock plate tile are only bonded through anchoring force, and after the ethylene-vinyl acetate copolymer adhesive powder is introduced, the compactness of the tile glue adhesive is increased by the polymer, the condition that the Van der Waals force is destroyed when moisture enters the interior of the tile glue adhesive is reduced, so that the bonding strength of the tile glue adhesive is improved. And the ethylene-vinyl acetate copolymer rubber powder can enter gaps between cement and fillers, so that the compressive strength and flexibility are improved, and the deformability influence caused by shrinkage after bonding and curing of the rock plate ceramic tile is reduced. The applicant further found that when the weight ratio of latex powder to cement is (5-8): (35-50), the adhesive has good bonding effect and flexibility, and good transverse deformability, and the performance of the tile adhesive is not obviously improved beyond the preferable range, and the production cost is greatly increased.
As a preferred embodiment, the cellulose ether is selected from one or a combination of several of hydroxypropyl methyl cellulose ether, hydroxyethyl ethyl cellulose ether, hydroxyethyl methyl cellulose ether, hydroxyethyl carboxymethyl cellulose ether, hydroxypropyl carboxymethyl cellulose ether.
As a preferred embodiment, the cellulose ether is hydroxypropyl methyl cellulose ether.
In a preferred embodiment, the mass fraction of the methoxyl groups in the hydroxypropyl methyl cellulose ether is 26-30%, and the mass fraction of the hydroxypropyl groups is 8-11%.
As a preferred embodiment, the viscosity of the 2% by mass aqueous solution of the hydroxypropyl methylcellulose ether at 20 ℃ is 75000 to 100000cps.
In the experimental process, the applicant finds that the hydroxypropyl methyl cellulose ether with the viscosity of 75000-100000cps can enable the tile glue adhesive to have better thixotropic performance, and the sliding of a rock plate can be reduced after the rock plate is bonded with the tile glue adhesive, so that the rock plate has better skid resistance. And 75000-100000cps hydroxypropyl methyl cellulose ether is adopted, so that the construction operability is good at low temperature, and the blade coating is easy.
As a preferred embodiment, the auxiliary agent is selected from one or a combination of several of an early strength agent, a thickening agent, a water retention agent and a defoaming agent, and preferably, the auxiliary agent is the early strength agent.
As a preferred embodiment, the early strength agent is selected from one or more of calcium formate, triethanolamine, urea, carbonate, sulfate, nitrate and chloride.
As a preferred embodiment, the early strength agent is calcium formate.
The second aspect of the invention provides a preparation method of a tile glue adhesive special for a whiskering-resistant ultra-soft rock plate, which comprises the following steps:
(1) Mixing and stirring cement, filler, redispersible latex powder and cellulose ether at a stirring speed of 200-500r/min for 30-40min;
(2) Adding early strength agent, mixing, stirring and discharging.
Compared with the prior art, the invention has the following beneficial effects:
(1) The tile glue adhesive special for the alkali efflorescence resistant super-soft rock plate adopts the ethylene-vinyl acetate copolymer with the mass fraction of the vinyl acetate of 35-40% as the emulsion powder, can form a film on the surfaces of cement and a filler, inhibits the precipitation of metal ions in the cement and the filler, and has the alkali efflorescence resistant effect.
(2) The tile glue adhesive special for the alkali-efflorescence-resistant super-soft rock plate adopts an ethylene-vinyl acetate copolymer and cement (5-8): (35-50), the bonding effect between the tile glue adhesive and the rock plate can be increased, and the tile glue adhesive has good flexibility and tensile strength and good skid resistance and can reach the standard of C2TES 1.
(3) The tile glue adhesive special for the alkali-efflorescence-resistant super-soft rock plate disclosed by the invention adopts the synergistic effect of the ethylene-vinyl acetate copolymer with the glass transition temperature of 0 ℃ and the silicate white cement with the strength grade of 52.5, so that the tile glue adhesive can be constructed to form a film at a lower temperature, is less influenced by environmental conditions and has stable performance.
(4) The tile glue adhesive special for the alkali-efflorescence-resistant super-soft rock plate is prepared by combining and compounding the filler with the grain size of 80-120 meshes and the filler with the grain size of 200 meshes, so that the compressive strength of the bonded rock plate is improved, and the tile glue adhesive also has good dispersibility.
(5) The special tile glue adhesive for the alkali-efflorescence-resistant super-soft rock plate disclosed by the invention adopts the hydroxypropyl methyl cellulose ether with the viscosity of 75000-100000cps, so that the tile glue adhesive has proper thixotropy, the sliding of the bonded rock plate is reduced, and the curing and drying time is favorably shortened.
Detailed Description
The present invention will be specifically described below by way of examples. It is to be noted that the following examples are given solely for the purpose of illustration and are not to be construed as limitations on the scope of the invention, as many insubstantial modifications and variations of the invention described above will now occur to those skilled in the art.
In addition, the starting materials used are all commercially available, unless otherwise specified.
Example 1
The tile glue adhesive special for the alkali-efflorescence-resistant super-soft rock plate comprises, by weight, 45 parts of cement, 20 parts of filler, 6 parts of redispersible latex powder, 0.8 part of cellulose ether and 0.5 part of an auxiliary agent.
The cement is silicate white cement with the strength grade of 52.5, and is purchased from Jinan Pteng chemical company Limited.
The filler is sand, the particle size is a combination of 80-120 meshes and 200 meshes, and the weight ratio is 1:1.2, purchased from Guishou county Pengyu building materials factory.
The redispersible latex powder is an ethylene-vinyl acetate copolymer, the mass fraction of vinyl acetate in the ethylene-vinyl acetate copolymer is 38%, the glass transition temperature is 0 ℃, and the redispersible latex powder is purchased from German Wake and has the model number of 316N.
The cellulose ether is hydroxypropyl methyl cellulose ether, the mass fraction of methoxyl in the hydroxypropyl methyl cellulose ether is 26-30%, the mass fraction of hydroxypropyl is 8-11%, the mass fraction of 2% of the aqueous solution of the hydroxypropyl methyl cellulose ether has the viscosity of 75000-100000cps at 20 ℃, and is purchased from Beijing Wan Tommy Technical Co., ltd.
The auxiliary agent is an early strength agent and is calcium formate.
A preparation method of a tile glue adhesive special for a saltpetering-resistant super-soft rock plate comprises the following steps:
(1) Mixing and stirring cement, filler, redispersible latex powder and cellulose ether at a stirring speed of 200r/min for 30min;
(2) Adding early strength agent, mixing, stirring and discharging.
Example 2
The specific steps of the tile adhesive binder special for the alkali-efflorescence-resistant super-soft rock plate and the preparation method are the same as those of the example 1, and the difference is that the preparation raw materials comprise, by weight, 70 parts of cement, 20 parts of filler, 6 parts of redispersible latex powder, 0.8 part of cellulose ether and 0.5 part of early strength agent.
Example 3
The specific steps of the tile glue adhesive special for the alkali-efflorescence-resistant ultra-soft rock plate are the same as those of the example 1, and the difference is that the redispersible latex powder is an ethylene-vinyl acetate copolymer, and the glass transition temperature is 5 ℃.
Example 4
The specific steps of the tile glue adhesive special for the alkali efflorescence resistant super-soft rock plate and the preparation method thereof are the same as example 1, and the difference is that the cellulose ether is hydroxypropyl methyl cellulose ether, the mass fraction of the aqueous solution of the hydroxypropyl methyl cellulose ether is 2%, and the viscosity of the aqueous solution at 20 ℃ is 45000cps.
Performance testing
The tile adhesive prepared in the above examples 1 to 4 was mixed with water, the amount of water added was 15% by mass of the tile adhesive, and the mixture was stirred into a paste.
1. Sliding distance: the slip distance of the dispensed paste tile glue binder to the rock plate was tested according to the JCT547-2015 standard.
2. Transverse deformability: the dispensed tile paste adhesive was tested for transverse deformability according to the JCT547-2015 standard.
3. Tensile bond strength: the tensile bonding performance of the prepared pasty tile glue adhesive and a rock plate after being soaked in water is tested according to JCT547-2015 standard.
The test was carried out according to the above criteria and the test results are shown in Table 1.
TABLE 1
| Sliding distance/mm | Transverse deformability/%) | Tensile bond strength/MPa | |
| Example 1 | |||
| Example 2 | |||
| Example 3 | |||
| Example 4 |
Claims (10)
1. The tile glue adhesive special for the alkali-efflorescence-resistant super-soft rock plate is characterized by comprising, by weight, 35-50 parts of cement, 10-30 parts of filler, 1-10 parts of redispersible latex powder, 0.3-1.5 parts of cellulose ether and 0.1-0.8 part of an auxiliary agent.
2. The tile adhesive special for the alkali-efflorescence-resistant ultra-soft rock plate as claimed in claim 1, wherein the cement is portland cement, and preferably, the strength grade of the portland cement is one or a combination of more of 42.5R, 52.5R, 62.5R and 62.5R.
3. The tile glue adhesive special for the alkali-efflorescence-resistant ultra-soft rock plate as claimed in claim 1, wherein the filler is one or a combination of sand, silica fume, mineral powder, coal ash and quartz sand, and preferably, the particle size of the filler is 50-250 meshes.
4. The tile glue adhesive special for the alkali-efflorescence-resistant ultra-soft rock plate as claimed in claim 1, wherein the re-dispersible latex powder is selected from one or more of ethylene-vinyl acetate copolymer, vinyl acetate-ethylene versatate copolymer, acrylic acid copolymer, ethylene-vinyl chloride-vinyl laurate copolymer, vinyl acetate-ethylene-vinyl fatty acid copolymer, acrylate-styrene copolymer and vinyl acetate homopolymer.
5. The tile glue adhesive special for the alkali-efflorescence-resistant ultra-soft rock plate as claimed in claim 4, wherein the mass fraction of the vinyl acetate in the ethylene-vinyl acetate copolymer is 20-40%.
6. The tile glue adhesive special for the alkali-efflorescence-resistant ultra-soft rock plate as claimed in claim 4, wherein the glass transition temperature of the ethylene-vinyl acetate copolymer is 0-10 ℃.
7. The tile glue binder for alkali-efflorescence-resistant ultra-soft rock-slab applications as claimed in claim 1 or 2, wherein the cellulose ether is selected from one or a combination of hydroxypropyl methyl cellulose ether, hydroxyethyl ethyl cellulose ether, hydroxyethyl methyl cellulose ether, hydroxyethyl carboxymethyl cellulose ether, hydroxypropyl carboxymethyl cellulose ether.
8. The tile glue adhesive special for the alkali-efflorescence-resistant super-soft rock boards as claimed in claim 4, wherein the mass fraction of the methoxyl groups in the hydroxypropyl methyl cellulose ether is 26-30%, and the mass fraction of the hydroxypropyl groups is 8-11%.
9. The tile glue adhesive special for the alkali-efflorescence-resistant super-soft rock plate as claimed in claim 1 or 2, wherein the auxiliary agent is one or a combination of several of an early strength agent, a thickening agent, a water retention agent and a defoaming agent.
10. A method for preparing the tile glue adhesive special for the alkali-efflorescence-resistant ultra-soft rock plate according to any one of claims 1 to 9, which comprises the following steps:
(1) Mixing and stirring cement, filler, redispersible latex powder and cellulose ether at the stirring speed of 200-500r/min for 30-40min;
(2) Adding early strength agent, mixing, stirring and discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210301930.5A CN115246723A (en) | 2022-03-24 | 2022-03-24 | Special ceramic tile adhesive for alkali-efflorescence-resistant super-soft rock plate and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210301930.5A CN115246723A (en) | 2022-03-24 | 2022-03-24 | Special ceramic tile adhesive for alkali-efflorescence-resistant super-soft rock plate and preparation method thereof |
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| CN115246723A true CN115246723A (en) | 2022-10-28 |
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| CN202210301930.5A Pending CN115246723A (en) | 2022-03-24 | 2022-03-24 | Special ceramic tile adhesive for alkali-efflorescence-resistant super-soft rock plate and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117510137A (en) * | 2023-10-31 | 2024-02-06 | 广东合睿智造新材料有限公司 | Adhesive for pasting large-size rock plate for alkali excitation system |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102674773A (en) * | 2012-05-21 | 2012-09-19 | 张立功 | Preparation method, products and construction method of improved adhesive for ceramic tiles |
| CN104230271A (en) * | 2014-09-11 | 2014-12-24 | 北京东方雨虹防水技术股份有限公司 | Flexible tile adhesive |
| CN107117908A (en) * | 2017-06-21 | 2017-09-01 | 江世妹 | A kind of ceramic tile adhesive of exterior wall retrofit |
| CN107337409A (en) * | 2017-08-02 | 2017-11-10 | 上海永丽节能材料有限公司 | Celular glass insulating system special-purpose adhesive and preparation method thereof and application method |
| CN108585684A (en) * | 2018-05-17 | 2018-09-28 | 北京宝辰联合科技股份有限公司 | A kind of cement base Ceramic Tiles adhesive |
| CN109293300A (en) * | 2018-09-25 | 2019-02-01 | 华砂砂浆有限责任公司 | Resistant slide type glue for tile and preparation method thereof |
| CN109678426A (en) * | 2019-01-16 | 2019-04-26 | 派丽(上海)管理有限公司 | A kind of one-component cement base glue for tile |
-
2022
- 2022-03-24 CN CN202210301930.5A patent/CN115246723A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102674773A (en) * | 2012-05-21 | 2012-09-19 | 张立功 | Preparation method, products and construction method of improved adhesive for ceramic tiles |
| CN104230271A (en) * | 2014-09-11 | 2014-12-24 | 北京东方雨虹防水技术股份有限公司 | Flexible tile adhesive |
| CN107117908A (en) * | 2017-06-21 | 2017-09-01 | 江世妹 | A kind of ceramic tile adhesive of exterior wall retrofit |
| CN107337409A (en) * | 2017-08-02 | 2017-11-10 | 上海永丽节能材料有限公司 | Celular glass insulating system special-purpose adhesive and preparation method thereof and application method |
| CN108585684A (en) * | 2018-05-17 | 2018-09-28 | 北京宝辰联合科技股份有限公司 | A kind of cement base Ceramic Tiles adhesive |
| CN109293300A (en) * | 2018-09-25 | 2019-02-01 | 华砂砂浆有限责任公司 | Resistant slide type glue for tile and preparation method thereof |
| CN109678426A (en) * | 2019-01-16 | 2019-04-26 | 派丽(上海)管理有限公司 | A kind of one-component cement base glue for tile |
Non-Patent Citations (1)
| Title |
|---|
| 张丹枫: "《烯烃聚合》", 华东理工大学出版社, pages: 133 - 134 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117510137A (en) * | 2023-10-31 | 2024-02-06 | 广东合睿智造新材料有限公司 | Adhesive for pasting large-size rock plate for alkali excitation system |
| CN117510137B (en) * | 2023-10-31 | 2024-05-07 | 广东合睿智造新材料有限公司 | Adhesive for pasting large-size rock plate for alkali excitation system |
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