CN109293300A - Resistant slide type glue for tile and preparation method thereof - Google Patents
Resistant slide type glue for tile and preparation method thereof Download PDFInfo
- Publication number
- CN109293300A CN109293300A CN201811115207.8A CN201811115207A CN109293300A CN 109293300 A CN109293300 A CN 109293300A CN 201811115207 A CN201811115207 A CN 201811115207A CN 109293300 A CN109293300 A CN 109293300A
- Authority
- CN
- China
- Prior art keywords
- tile
- slide type
- resistant slide
- type glue
- glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/26—Carbonates
- C04B14/28—Carbonates of calcium
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/06—Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
- C04B18/08—Flue dust, i.e. fly ash
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/10—Mortars, concrete or artificial stone characterised by specific physical values for the viscosity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The invention discloses a kind of resistant slide type glues for tile and preparation method thereof, with the total weight of the resistant slide type glue for tile, the glue for tile includes: portland cement 20-25wt%, flyash 5-10wt%, precipitated calcium carbonate 2-5wt%, aggregate 55-70wt%, cellulose ether 0.3-0.6wt%, adhesive 1.5-3wt%, early strength agent 0.3-0.6wt% and water-absorbing resin 0.03-0.06wt%, the sum of each component are 100wt%.Resistant slide type glue for tile of the invention, which overcomes traditional ceramic tile adhesive 14d age or so adhesive strength, reduces defect, keeps adhesive strength to show a increasing trend, to bond stronger.
Description
Technical field
The invention belongs to glue for tile technical fields, more particularly, to a kind of resistant slide type glue for tile and preparation method thereof.
Background technique
Ceramic tile is as one of finishing material the most frequently used in building decoration area, because of various constructions lack of standardization in use process
And understanding, lead to ceramic tile hollowing obscission often occur.As people's level of understanding improves, pastes ceramic tile material requested and also send out
It is raw to change, by conventional on-site blended cement mortar polymer modification ceramic tile adhesive till now.Polymer modification glue for tile
Stick is to paste engineering method based on thin layer and design, 2~5mm of thickness.And it is domestic since building flatness is poor, Practical Project is because each
The direct thick-layer of kind reason pastes glue for tile, and thickness reaches 10mm or more.Therefore, during actual use often because of glue for tile thickness
There is brick phenomenon greatly very much.Meanwhile tracing detection discovery: the gluing of different larval instar is carried out for traditional glue for tile adhesive strength
Intensity, under the conditions of low polymer volume, relative to 7d age adhesive strength, ceramic tile adhesive 14d age adhesive strength occurs
It reduces, and then causes ceramic tile easy to fall off.
Summary of the invention
The purpose of the present invention is overcoming the deficiencies of existing technologies, a kind of resistant slide type glue for tile is provided, is guaranteeing initial stage glue
While glutinous intensity, so that the adhesive strength of its 28d age is in increase trend, does not occur reduction situation, prevent brick phenomenon.
To achieve the goals above, an aspect of of the present present invention provides a kind of resistant slide type glue for tile, with the resistant slide type
The total weight of glue for tile, the glue for tile include: portland cement 20-25wt%, flyash 5-10wt%, precipitated calcium carbonate 2-
5wt%, aggregate 55-70wt%, cellulose ether 0.3-0.6wt%, adhesive 1.5-3wt%, early strength agent 0.3-0.6wt% and suction
Water-resin 0.03-0.06wt%, the sum of each component are 100wt%.
Another aspect of the present invention provides a kind of preparation method of above-mentioned resistant slide type glue for tile, which includes:
By the portland cement, flyash, precipitated calcium carbonate, aggregate, cellulose ether, adhesive, early strength agent and water-absorbing resin mixing
Uniformly, the resistant slide type glue for tile is obtained.
Technical solution of the present invention has the advantages that
(1) resistant slide type glue for tile of the invention overcomes the reduction of traditional ceramic tile adhesive 14d age or so adhesive strength
Defect keeps adhesive strength to show a increasing trend, to bond stronger.
(2) present invention not only acts as filler effect by addition precipitated calcium carbonate, and it is water-fast strong to increase glue for tile
Degree, meanwhile, also improve the anti-slipping property energy of glue for tile;The addition of water-absorbing resin in the present invention not only guarantees fine powder material additive amount
In the case where more, make glue for tile that there is better open assembly time, and further promote the anti-slipping property energy of glue for tile, reduces porcelain
Brick glue is to water consumption sensibility.
(3) resistant slide type glue for tile of the invention designs low cement mixing content and adds flyash, not only guarantees initial stage glue
Viscous intensity, and guarantee that the adhesive strength of adhesive 28d age is in increase trend, do not occur reduction situation.
(4) in the present invention, the addition of level-one flyash and precipitated calcium carbonate increases the volume content of fine powder in glue for tile,
Air-sweeping type packs production efficiency under the conditions of improving low cement mixing content, and reduces its abrasion to production equipment.
Other features and advantages of the present invention will then part of the detailed description can be specified.
Specific embodiment
The preferred embodiment of the present invention is described in more detail below.Although the following describe preferred implementations of the invention
Mode, however, it is to be appreciated that may be realized in various forms the present invention without that should be limited by the embodiments set forth herein.Phase
Instead, these embodiments are provided so that the present invention is more thorough and complete, and can be by the scope of the present invention completely
It is communicated to those skilled in the art.
An aspect of of the present present invention provides a kind of resistant slide type glue for tile, with the total weight of the resistant slide type glue for tile,
The glue for tile includes: portland cement 20-25wt%, flyash 5-10wt%, precipitated calcium carbonate 2-5wt%, aggregate 55-
70wt%, cellulose ether 0.3-0.6wt%, adhesive 1.5-3wt%, early strength agent 0.3-0.6wt% and water-absorbing resin 0.03-
0.06wt%, the sum of each component are 100wt%.
Inventor studies discovery: the adhesive strength of the different larval instar of traditional glue for tile, under the conditions of low polymer volume, phase
For 7d age adhesive strength, ceramic tile adhesive 14d age adhesive strength is reduced, this illustrates glue for tile contraction distortion to glue
Viscous intensity generates destruction, and due to the increase of glue for tile area and thickness, so that this destruction becomes apparent from, here it is
The main reason for causing current ceramic tile to fall off.By using low cement mixing content and level-one flyash is used in combination in the present invention thus,
Precipitated calcium carbonate and water-absorbing resin are added in glue for tile simultaneously, so that the glue for tile of preparation can not only guarantee 28d age glue
Viscous intensity, and 3d adhesive strength reaches 0.5MPa, and keeps adhesive strength in 28d age to show a increasing trend, and rubber powder is mixed
Amount is significantly less than 8% volume.
In the present invention, by adding precipitated calcium carbonate, adhesive anti-slipping property energy is promoted;Meanwhile precipitated calcium carbonate plus
Enter, is able to ascend glue for tile construction smoothness and product plumpness;It is able to ascend glue for tile compactness, and then increases glue for tile
Water-fast intensity;The addition of water-absorbing resin can reduce glue for tile to water consumption sensibility;Meanwhile being also able to solve fine powder content
In the case where more, the shorter defect of glue for tile open assembly time promotes hydrated cementitious, promotes the adhesive strength of glue for tile;Pass through suction
The effect of the coordinated of water-resin and precipitated calcium carbonate, promotes the glue for tile cohesive force that precipitated calcium carbonate is used alone, and promotes porcelain
Brick glue ability of anti-deformation, so that the anti-slipping property of glue for tile can be promoted further.
In accordance with the present invention it is preferred that the portland cement is No. 42.5 ordinary portland cements, 42.5R ordinary silicon
At least one of acid salt cement and No. 52.5 ordinary portland cements.
In accordance with the present invention it is preferred that the flyash is level-one flyash.
In accordance with the present invention it is preferred that the precipitated calcium carbonate is technical grade, average grain diameter is 1000-1500 mesh;Preferably
1250 mesh.
In accordance with the present invention it is preferred that the aggregate is the washing river sand of 40-80 mesh and the washing river sand of 80-120 mesh, institute
The mass ratio for stating the washing river sand of 40-80 mesh and the washing river sand of 80-120 mesh is 0.5-2:1.
In accordance with the present invention it is preferred that the cellulose ether is ethoxyl methyl cellulose ether and/or hydroxypropyl methyl fiber
Plain ether, the viscosity of the cellulose ether are 10000-35000mPa.s.
In accordance with the present invention it is preferred that the adhesive be vinylacetate and ethylene copolymer rubber powder, ethylene, vinyl chloride with
Vinyl laurate ternary polymerization rubber powder, vinylacetate, ethylene and higher aliphatic vinyl acetate ternary polymerization rubber powder, acetic acid second
Enester and higher aliphatic vinyl acetate are copolymerized rubber powder, vinylacetate, acrylate and higher aliphatic vinyl acetate ternary polymerization
Rubber powder, acrylate and at least one of styrene copolymerized rubber powder and acrylic acid homopolymerization rubber powder.
In accordance with the present invention it is preferred that the early strength agent is calcium salt series early strength agent;Such as calcium formate.
In accordance with the present invention it is preferred that the water-absorbing resin is polyacrylate water-absorbing resin and/or polyoxygenated alkanes
Water-absorbing resin, the average grain diameter of the water-absorbing resin are 200-300 mesh.
Another aspect of the present invention provides a kind of preparation method of above-mentioned resistant slide type glue for tile, which includes:
By the portland cement, flyash, precipitated calcium carbonate, aggregate, cellulose ether, adhesive, early strength agent and water-absorbing resin mixing
Uniformly, the resistant slide type glue for tile is obtained.
The present invention is further illustrated by the following examples:
In following embodiment, portland cement is No. 42.5 ordinary silicons that Jidong Cement Co., Ltd., Tangshan provides
Acid salt cement, 42.5R ordinary portland cement and No. 52.5 ordinary portland cements;Level-one flyash is that Beijing Orient one hundred is safe
Building materials provide;Cellulose ether is that the ethoxyl methyl cellulose ether that Long Hu Science and Technology Ltd. in Beijing provides and hydroxypropyl methyl are fine
Plain ether is tieed up, viscosity is respectively in 10000mPa.s and 25000mPa.s;Adhesive is the vinegar that Long Hu Science and Technology Ltd. in Beijing provides
Vinyl acetate and ethylene copolymer rubber powder and acrylate and styrene copolymerized rubber powder;Early strength agent is Beijing Long Hu Science and Technology Ltd.
The calcium formate of offer;Precipitated calcium carbonate provides for one mining industry processing factory of Lingshou County mine, 1250 mesh of mesh number;Washing river sand is Tangshan capital
Profit company provides;Water-absorbing resin is the polyacrylate water-absorbing resin of 200 mesh that material Science and Technology Ltd. provides of taking in the fresh again
With polyoxygenated alkanes water-absorbing resin.
Embodiment 1
The present embodiment provides a kind of resistant slide type glue for tile, which includes: No. 52.5 ordinary portland cements
200kg, level-one flyash 100kg, 1250 mesh precipitated calcium carbonate 20kg, 40-80 mesh wash river sand 423.4kg, 80~120 mesh water
River sand 216kg, 10000mPa.s ethoxyl methyl cellulose ether 6kg, vinylacetate and ethylene copolymer rubber powder 30kg are washed, it is early strong
Agent 4kg, Acrylates water-absorbing resin 0.6kg.
Specific preparation method is to be uniformly mixed above-mentioned each component, obtains the resistant slide type glue for tile.
Embodiment 2
The present embodiment provides a kind of resistant slide type glue for tile, which includes: No. 42.5 ordinary portland cements
250kg, level-one flyash 50kg, 1250 mesh precipitated calcium carbonate 50kg, 40-80 mesh wash river sand 205kg, the washing of 80~120 mesh
River sand 409kg, 25000mPa.s hydroxypropyl methyl cellulose ether 4.5kg, acrylate and styrene copolymerized rubber powder 25kg are early strong
Agent 6kg, Acrylates water-absorbing resin 0.5kg.
Specific preparation method is to be uniformly mixed above-mentioned each component, obtains the resistant slide type glue for tile.
Embodiment 3
The present embodiment provides a kind of resistant slide type glue for tile, which includes: No. 42.5 ordinary portland cements
250kg, level-one flyash 50kg, 1250 mesh precipitated calcium carbonate 30kg, 40-80 mesh wash river sand 325kg, the washing of 80~120 mesh
River sand 323.7kg, 25000mPa.s hydroxypropyl methyl cellulose ether 3kg, vinylacetate and ethylene copolymer rubber powder 15kg are early strong
Agent 3kg, polyoxygenated alkanes water-absorbing resin 0.3kg.
Specific preparation method is to be uniformly mixed above-mentioned each component, obtains the resistant slide type glue for tile.
Embodiment 4
The present embodiment provides a kind of resistant slide type glue for tile, which includes: No. 42.5 ordinary portland cements
225kg, level-one flyash 75kg, 1250 mesh precipitated calcium carbonate 40kg, 40-80 mesh wash river sand 420kg, the washing of 80~120 mesh
River sand 210kg, 10000mPa.s ethoxyl methyl cellulose ether 4.5kg, vinylacetate and ethylene copolymer rubber powder 20kg are early strong
Agent 5kg, polyoxygenated alkanes water-absorbing resin 0.5kg.
Specific preparation method is to be uniformly mixed above-mentioned each component, obtains the resistant slide type glue for tile.
Comparative example 1
This comparative example is distinguished as with embodiment 1 without containing 1250 mesh precipitated calcium carbonates, Acrylates water-absorbing resin
Content is 20.6kg;Other each components and dosage and preparation method are same as Example 1.
Comparative example 2
This comparative example is distinguished as with embodiment 1 without containing Acrylates water-absorbing resin, 1250 mesh precipitated calcium carbonates
Content is 20.6kg;Other each components and dosage and preparation method are same as Example 1.
Test case 1
According to cement base glue for tile pertinent regulations in JC/T 547-2005 " ceramic wall and floor bricks adhesive " to embodiment 1-4
The glue for tile of resistant slide type glue for tile and comparative example the 1-2 preparation of preparation is detected, and specific testing result is shown in Tables 1 and 2.
Table 1
As can be seen from the table, adhesive adhesive strength of the invention meets practical bonding demand, and resistant slide ability
It is prominent, meet standard requirements;Simultaneously by the data comparison of embodiment and comparative example it is found that passing through precipitated calcium carbonate and water suction tree
The compound use of rouge can reach good resistant slide effect.
Table 2
Various embodiments of the present invention are described above, above description is exemplary, and non-exclusive, and
It is not limited to disclosed each embodiment.Without departing from the scope and spirit of illustrated each embodiment, for this skill
Many modifications and changes are obvious for the those of ordinary skill in art field.
Claims (10)
1. a kind of resistant slide type glue for tile, which is characterized in that with the total weight of the resistant slide type glue for tile, the glue for tile packet
It includes: portland cement 20-25wt%, flyash 5-10wt%, precipitated calcium carbonate 2-5wt%, aggregate 55-70wt%, cellulose
Ether 0.3-0.6wt%, adhesive 1.5-3wt%, early strength agent 0.3-0.6wt% and water-absorbing resin 0.03-0.06wt%, each component
The sum of be 100wt%.
2. resistant slide type glue for tile according to claim 1, wherein the portland cement is No. 42.5 normal silicates
At least one of cement, 42.5R ordinary portland cement and No. 52.5 ordinary portland cements.
3. resistant slide type glue for tile according to claim 1, wherein the flyash is level-one flyash.
4. resistant slide type glue for tile according to claim 1, wherein the precipitated calcium carbonate is technical grade, average grain diameter
For 1000-1500 mesh.
5. resistant slide type glue for tile according to claim 1, wherein the aggregate is the washing river sand and 80- of 40-80 mesh
The washing river sand of 120 mesh, the mass ratio of the washing river sand of the washing river sand and 80-120 mesh of the 40-80 mesh are 0.5-2:1.
6. resistant slide type glue for tile according to claim 1, wherein the cellulose ether is ethoxyl methyl cellulose ether
And/or hydroxypropyl methyl cellulose ether, the viscosity of the cellulose ether are 10000-35000mPa.s.
7. resistant slide type glue for tile according to claim 1, wherein the adhesive is vinylacetate and ethylene copolymer
Rubber powder, ethylene, vinyl chloride and vinyl laurate ternary polymerization rubber powder, vinylacetate, ethylene and higher aliphatic vinyl acetate
Ternary polymerization rubber powder, vinylacetate and higher aliphatic vinyl acetate are copolymerized rubber powder, vinylacetate, acrylate and advanced rouge
At least one in fat vinyl acetate ternary polymerization rubber powder, acrylate and styrene copolymerized rubber powder and acrylic acid homopolymerization rubber powder
Kind.
8. resistant slide type glue for tile according to claim 1, wherein the early strength agent is calcium salt series early strength agent.
9. resistant slide type glue for tile according to claim 1, wherein the water-absorbing resin is polyacrylate water suction tree
Rouge and/or polyoxygenated alkanes water-absorbing resin, the average grain diameter of the water-absorbing resin are 200-300 mesh.
10. the preparation method of resistant slide type glue for tile described in any one of claim 1-9, which is characterized in that the preparation
Method includes: by the portland cement, flyash, precipitated calcium carbonate, aggregate, cellulose ether, adhesive, early strength agent and water suction
Resin is uniformly mixed, and obtains the resistant slide type glue for tile.
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CN201811115207.8A CN109293300A (en) | 2018-09-25 | 2018-09-25 | Resistant slide type glue for tile and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112500112A (en) * | 2021-02-04 | 2021-03-16 | 广东博智林机器人有限公司 | Ceramic tile adhesive and ceramic tile paving method |
CN114014615A (en) * | 2021-12-22 | 2022-02-08 | 山东铁壁虎建材有限公司 | Concrete rapid repair material with super early strength, low shrinkage and high ductility and preparation method thereof |
CN115246723A (en) * | 2022-03-24 | 2022-10-28 | 上海牛元工贸有限公司 | Special ceramic tile adhesive for alkali-efflorescence-resistant super-soft rock plate and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN112500112A (en) * | 2021-02-04 | 2021-03-16 | 广东博智林机器人有限公司 | Ceramic tile adhesive and ceramic tile paving method |
CN114014615A (en) * | 2021-12-22 | 2022-02-08 | 山东铁壁虎建材有限公司 | Concrete rapid repair material with super early strength, low shrinkage and high ductility and preparation method thereof |
CN115246723A (en) * | 2022-03-24 | 2022-10-28 | 上海牛元工贸有限公司 | Special ceramic tile adhesive for alkali-efflorescence-resistant super-soft rock plate and preparation method thereof |
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