CN115215545A - Energy-saving LOW-E glass and preparation method thereof - Google Patents
Energy-saving LOW-E glass and preparation method thereof Download PDFInfo
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- CN115215545A CN115215545A CN202210557025.6A CN202210557025A CN115215545A CN 115215545 A CN115215545 A CN 115215545A CN 202210557025 A CN202210557025 A CN 202210557025A CN 115215545 A CN115215545 A CN 115215545A
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- 239000011521 glass Substances 0.000 title claims abstract description 92
- 238000002360 preparation method Methods 0.000 title claims description 8
- 239000010410 layer Substances 0.000 claims abstract description 108
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 32
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000002994 raw material Substances 0.000 claims abstract description 28
- 229910052709 silver Inorganic materials 0.000 claims abstract description 28
- 239000004332 silver Substances 0.000 claims abstract description 28
- 229910018487 Ni—Cr Inorganic materials 0.000 claims abstract description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000011241 protective layer Substances 0.000 claims abstract description 19
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 17
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 17
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011787 zinc oxide Substances 0.000 claims abstract description 16
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910000906 Bronze Inorganic materials 0.000 claims abstract description 9
- 239000010974 bronze Substances 0.000 claims abstract description 9
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002346 layers by function Substances 0.000 claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 8
- 239000010439 graphite Substances 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- OHUPZDRTZNMIJI-UHFFFAOYSA-N [Cs].[W] Chemical compound [Cs].[W] OHUPZDRTZNMIJI-UHFFFAOYSA-N 0.000 claims abstract description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 4
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims abstract description 4
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 claims abstract description 4
- 238000000137 annealing Methods 0.000 claims description 12
- 238000011282 treatment Methods 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 229910001120 nichrome Inorganic materials 0.000 claims description 7
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229910007717 ZnSnO Inorganic materials 0.000 claims description 3
- 239000003258 bubble free glass Substances 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- KYKLWYKWCAYAJY-UHFFFAOYSA-N oxotin;zinc Chemical compound [Zn].[Sn]=O KYKLWYKWCAYAJY-UHFFFAOYSA-N 0.000 claims description 3
- 238000007747 plating Methods 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 10
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052721 tungsten Inorganic materials 0.000 abstract description 5
- 239000010937 tungsten Substances 0.000 abstract description 5
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 abstract description 4
- 229910001930 tungsten oxide Inorganic materials 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 description 6
- 230000000903 blocking effect Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002457 bidirectional effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007688 edging Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 239000006066 glass batch Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 239000005344 low-emissivity glass Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000026676 system process Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B18/00—Shaping glass in contact with the surface of a liquid
- C03B18/02—Forming sheets
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3618—Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3634—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing carbon, a carbide or oxycarbide
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3639—Multilayers containing at least two functional metal layers
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/212—TiO2
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/216—ZnO
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/23—Mixtures
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/73—Anti-reflective coatings with specific characteristics
- C03C2217/734—Anti-reflective coatings with specific characteristics comprising an alternation of high and low refractive indexes
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Abstract
The invention discloses energy-saving LOW-E glass, and aims to solve the problem that the LOW-E glass cannot meet the use requirements of more markets. The key points of the technical scheme are as follows: the glass sheet comprises a glass sheet, a first bottoming dielectric layer silicon nitride layer, a second titanium oxide layer, a third protective layer nickel-chromium layer, a fourth functional layer silver layer, a fifth metal protective layer nickel-chromium layer, a sixth zinc oxide layer, a seventh silicon nitride layer and an eighth graphite protective layer, wherein the first bottoming dielectric layer, the second titanium oxide layer, the third protective layer nickel-chromium layer, the fourth functional layer silver layer, the fifth metal protective layer nickel-chromium layer, the sixth zinc oxide layer, the seventh silicon nitride layer and the eighth graphite protective layer are sequentially plated on the glass sheet, and the glass sheet is prepared from the following raw materials in percentage by weight: cesium tungsten bronze (cs0.3wo3): 7.77 percent; tungstic acid (H2 WO 4): 9.85 percent; boric acid (H3 BO 3): 49.10 percent; silica (SiO 2): 20.79 percent; sodium fluoride (NaF): 11.81 percent; antimony trioxide (Sb 2O 3): 0.67 percent. According to the invention, tungsten bronze or low-valence tungsten oxide is used as a raw material, so that the cost is greatly reduced compared with the cost of the current commercial energy-saving coated glass or ITO and the like, and the low-valence tungsten bronze or ITO has a strong near-infrared shielding effect after 950nm and a good energy-saving effect.
Description
Technical Field
The invention relates to the technical field of glass, in particular to energy-saving LOW-E glass and a preparation method thereof.
Background
Most of building energy consumption is lost through doors and windows, and the novel LOW-radiation LOW-E glass has higher visible light transmittance, ensures good natural lighting, can effectively control the transmission of solar thermal radiation, can reflect near and far infrared thermal radiation back, can be used in any climatic environment, and can achieve the purposes of controlling sunlight, saving energy and controlling and adjusting heat.
As long as the low-radiation glass is installed, the air conditioner cost of little indoor flower can always maintain the situation of being warm in winter and cool in summer, namely, the heat-proof energy enters the room in summer and leaks in winter, thereby having excellent bidirectional energy-saving effect, and being capable of blocking ultraviolet irradiation and enabling the color of the furniture not to change. Because the LOW-radiation coated glass has excellent energy-saving effect, the LOW-radiation LOW-E glass can be used as one of the main building materials of large buildings instead of cement wall bricks, so that an energy-saving transparent glass coat is covered for removing thick wall bricks of the large buildings, and a new green choice is provided for architectural designers. With the accelerating urbanization in China, the large-scale emergence of residences and commercial buildings all over the country, the energy-saving glass has become a new favorite in the building market.
Through the requirements of national laws and regulations in recent years and the popularization of some manufacturers, the capacity and the actual yield of the coated glass are continuously increased and are close to 1 hundred million m 2 More and more energy-saving glass enters common civil buildings and is used as a common building of a high-grade building, the external glass of the high-grade building is changed from common Low-emissivity glass to high-performance Low-E glass with better energy conservation, the using amount of the high-performance Low-E glass is continuously increased, and more high-performance Low-E glass is applied to the buildings.
The single-silver Low-E glass commonly used in China at present cannot completely meet the market demand, high-performance double-silver Low-E glass gradually enters the market only recently, double-silver Low-E glass is used as a high-end product of energy-saving glass, the technical difficulties in the aspects of heavy angle color deviation, coating uniformity, ex-situ toughening property and the like exist due to high product production technical difficulty, the yield and the production efficiency of double-silver Low-E are Low, the production cost is high all the time, and the application of the high-performance Low-E glass is limited to a certain degree. In view of the above, an improved single-silver Low-E glass appears in the market, and the energy-saving performance of the product is higher than that of the common single-silver Low-E glass in the market and lower than that of the common double-silver Low-E glass.
The production of the glass can avoid the problems encountered by double-silver Low-E glass, the energy-saving performance is close to that of the double-silver Low-E glass, the lower production cost and the higher production efficiency become new hot spots in the energy-saving glass market, however, the common improved single-silver Low-E glass has a simple film system result, the visible light transmittance of the product is sacrificed for achieving the higher energy-saving performance, the lighting effect of the glass is reduced by the lower visible light transmittance, the glass has a small-range application market only in southern areas with sufficient sunlight, the application of the improved single-silver Low-E is limited to a certain extent, and the improved Low-E glass has the advantages of Low cost and high energy-saving performance, and the improved single-silver Low-E glass still has better development potential in the field of the improved single-silver Low-E glass products.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide the energy-saving LOW-E glass and the preparation method thereof, wherein tungsten bronze or LOW-valence tungsten oxide is used as a raw material, so that the cost is greatly reduced compared with the cost of the current commercial energy-saving coated glass or ITO (indium tin oxide), the near infrared shielding effect after 950nm is very strong, and the energy-saving effect is better.
The technical purpose of the invention is realized by the following technical scheme: the utility model provides an energy-conserving LOW-E glass, includes glass original sheet and the first layer of dielectric layer silicon nitride layer, the second layer titanium oxide layer of bottoming, third layer protective layer nickel-chromium layer, fourth layer functional layer silver layer, the fifth layer metal protective layer nickel-chromium layer, the sixth layer zinc oxide layer, the seventh layer silicon nitride layer and the eighth layer graphite protective layer of plating in proper order on glass original sheet, the weight percent calculation that glass original sheet constitutes according to the raw materials, the batching component proportion of each raw materials is as follows: cesium tungsten bronze (cs0.3wo3): 7.77 percent; tungstic acid (H2 WO 4): 9.85 percent; boric acid (H3 BO 3): 49.10 percent; silica (SiO 2): 20.79 percent; sodium fluoride (NaF): 11.81 percent; antimony trioxide (Sb 2O 3): 0.67 percent.
The invention is further configured to: the first underlying dielectric layer may be silicon nitride (Si) 3 N 4 Zinc oxide ZnO, zinc tin oxide ZnSnO or titanium oxide TiO 2 The thickness is 0-15nm.
The invention is further configured to: the second titanium oxide layer is titanium oxide TiO 2 A layer with a thickness of 15-40nm.
The invention is further configured to: the third protective layer nickel-chromium layer can be a nickel-chromium NiCr layer or a chromium Cr layer, and the thickness of the third protective layer nickel-chromium layer is 5-15nm.
The invention is further configured to: the silver layer of the fourth functional layer is a silver Ag layer, and the thickness of the silver layer is 5-20nm.
The technical purpose of the invention is also realized by the following technical scheme: a preparation method of energy-saving LOW-E glass comprises the following steps: (1) Taking the raw material components according to a formula, crushing the raw materials, sieving the crushed raw materials by a 200-400-mesh sieve, and fully mixing the raw materials for 20-60 minutes to obtain a mixed raw material;
(2) Performing high-temperature treatment on the mixed raw material obtained in the step (1) in a tank furnace at 1550-1650 ℃ until clear and bubble-free glass liquid is formed;
(3) Cooling the glass liquid obtained in the step (2) to 1100-1400 ℃, forming through a tin bath, then putting the formed glass into an annealing furnace for annealing at the annealing temperature of 530-570 ℃, and cutting after the annealing is finished to obtain a glass sheet;
(4) And (4) sequentially coating or pasting each layer of the glass sheet obtained in the step (3) in coating equipment and pasting equipment to obtain the energy-saving LOW-E glass.
In conclusion, the invention has the following beneficial effects:
the invention is to plate nitrogen on the glass wafer in sequenceSilicon oxide Si 3 N 4 Titanium oxide TiO2, nickel chromium NiCr, silver Ag, nickel chromium NiCr, zinc oxide ZnO, silicon nitride Si 3 N 4 Graphite C and the arrangement sequence of the film layers are completely different from the prior art. The inventor finds that the Low-E glass prepared by adopting the coating film arrangement sequence has high infrared ray blocking coefficient and higher sun-shading coefficient, and meets the high-quality Low-radiation blocking effect. Meanwhile, the Low-E glass film layer has the characteristic of extremely high stability, can withstand high-temperature toughening treatment and is not damaged in the toughening treatment process of the coated glass; the toughening treatment film has firm internal binding force, can be conveniently subjected to various mechanical cutting and edging processing treatments, does not cause film layer falling, has no surface color deviation and no difference color after toughening treatment, and has excellent overall surface texture performance.
Drawings
FIG. 1 is a schematic view of the overall structure of the present invention, showing the structural features of the energy-saving LOW-E glass.
In the figure: 1. glass base sheet; 2. bottoming the dielectric layer silicon nitride layer; 3. a titanium oxide layer; 4. a protective layer of nickel chromium; 5. a functional layer silver layer; 6. a metal protective layer nickel-chromium layer; 7. a zinc oxide layer; 8. a silicon nitride layer; 9. A graphite protective layer.
Detailed Description
In order to make those skilled in the art better understand the technical solution of the present invention, the following detailed description of the present invention is provided with reference to the accompanying drawings and specific embodiments, and it is to be noted that the embodiments and features of the embodiments of the present application can be combined with each other without conflict.
In the description of the present invention, it should be noted that the terms "upper", "lower", "inner", "outer", "top/bottom", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of description and simplification of description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus should not be construed as limiting the present invention.
In the description of the present invention, it is to be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "disposed," "sleeved/connected," "connected," and the like are to be construed broadly, e.g., "connected," which may be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
The present invention will be described in detail below with reference to the accompanying drawings.
The utility model provides an energy-conserving LOW-E glass, as shown in figure 1, including glass original sheet 1 and the first layer of dielectric layer silicon nitride layer 2 of bottoming, second layer titanium oxide layer 3, third layer of protective layer nickel chromium layer 4, fourth layer of functional layer silver layer 5, fifth layer of metal protective layer nickel chromium layer 4, sixth layer of zinc oxide layer 7, seventh layer of silicon nitride layer 8 and eighth layer of graphite protective layer 9 of plating in proper order on glass original sheet 1, glass original sheet 1 calculates according to the weight percentage that the raw materials constitute, the batching component proportion of each raw materials is as follows: cesium tungsten bronze (cs0.3wo3): 7.77 percent; tungstic acid (H2 WO 4): 9.85 percent; boric acid (H3 BO 3): 49.10 percent; silica (SiO 2): 20.79 percent; sodium fluoride (NaF): 11.81 percent; antimony trioxide (Sb 2O 3): 0.67 percent.
The first underlying dielectric layer 2, which may be silicon nitride Si 3 N 4 Zinc oxide ZnO, zinc tin oxide ZnSnO or titanium oxide TiO 2 The thickness is 0-15nm, the second titanium oxide layer 3 is titanium oxide TiO 2 The thickness of the third protective layer nickel-chromium layer 4 can be a nickel-chromium NiCr layer or a chromium Cr layer, the thickness is 5-15nm, and the thickness of the fourth functional layer silver layer 5 is a silver Ag layer, and the thickness is 5-20nm.
A preparation method of energy-saving LOW-E glass comprises the following steps: (1) Taking the raw material components according to a formula, crushing the raw materials, sieving the crushed raw materials by a 200-400-mesh sieve, and fully mixing the raw materials for 20-60 minutes to obtain a mixed raw material;
(2) Performing high-temperature treatment on the mixed raw material obtained in the step (1) in a tank furnace at 1550-1650 ℃ until clear and bubble-free glass liquid is formed;
(3) Cooling the molten glass obtained in the step (2) to 1100-1400 ℃, forming the molten glass through a tin bath, putting the formed glass into an annealing furnace for annealing at the annealing temperature of 530-570 ℃, and cutting the glass after the annealing is finished to obtain a glass original sheet 1;
(4) And (4) sequentially coating or pasting each layer of the glass original sheet 1 obtained in the step (3) in coating equipment and film pasting equipment to obtain the energy-saving LOW-E glass.
The method adopts tungsten bronze or low-valence tungsten oxide as the raw material, so that the cost is greatly reduced compared with the cost of the current commercial energy-saving coated glass or ITO and the like, and the method has strong near-infrared shielding effect after 950nm and better energy-saving effect;
the method selects a common glass melting process, directly combines the properties of the infrared shielding material powder with a glass substrate, has stronger stability than the traditional film pasting and coating process, and greatly prolongs the service life; the method of the invention takes tungsten bronze or low-valence tungsten oxide as one of the glass batch, which can fully exert the energy-saving effect; meanwhile, due to the multiple possibilities of the glass components, the glass can be optimized through adjustment of various components or system processes such as temperature atmosphere and the like, so that the possibility of performance improvement is greatly increased, and a larger development space is provided;
the invention is characterized in that silicon nitride Si is plated on the glass original sheet 1 in sequence 3 N 4 Titanium oxide TiO2, nickel chromium NiCr, silver Ag, nickel chromium NiCr, zinc oxide ZnO, silicon nitride Si 3 N 4 Graphite C, the arrangement sequence of the film layer is completely different from the prior art. The inventor finds that the Low-E glass prepared by adopting the coating film arrangement sequence has high infrared ray blocking coefficient and higher sun-shading coefficient, and meets the requirements of high-quality and Low-radiation blocking effect. Meanwhile, the Low-E glass film layer has the characteristic of extremely high stability, can withstand high-temperature toughening treatment and is not damaged in the toughening treatment process of the coated glass; has firm internal binding force, can conveniently carry out various mechanical cutting and edge grinding processing treatments without generatingThe raw film layer falls off, the surface color of the film layer after toughening treatment has no deviation and no difference color, and the overall surface texture is excellent.
The above description is only a preferred embodiment of the present invention, and the protection scope of the present invention is not limited to the above embodiments, and all technical solutions belonging to the idea of the present invention belong to the protection scope of the present invention. It should be noted that modifications and embellishments within the scope of the invention may occur to those skilled in the art without departing from the principle of the invention, and are considered to be within the scope of the invention.
Claims (6)
1. The utility model provides an energy-conserving LOW-E glass, includes glass original sheet (1) and the first layer of the system of plating down dielectric layer silicon nitride layer (2), second layer titanium oxide layer (3), third layer protection layer nickel chromium layer (4), fourth layer functional layer silver layer (5), fifth layer metal protection layer nickel chromium layer (4), sixth layer zinc oxide layer (7), seventh layer silicon nitride layer (8) and eighth layer graphite protection layer (9) in proper order on glass original sheet (1), glass original sheet (1) calculates according to the weight percentage that the raw materials constitute, and the batching component proportion of each raw materials is as follows: cesium tungsten bronze (cs0.3wo3): 7.77 percent; tungstic acid (H2 WO 4): 9.85 percent; boric acid (H3 BO 3): 49.10 percent; silica (SiO 2): 20.79 percent; sodium fluoride (NaF): 11.81 percent; antimony trioxide (Sb 2O 3): 0.67 percent.
2. The energy-saving LOW-E glass as set forth in claim 1, wherein: the first underlying dielectric layer (2) may be silicon nitride (Si) 3 N 4 Zinc oxide ZnO, zinc tin oxide ZnSnO or titanium oxide TiO 2 The thickness is 0-15nm.
3. An energy saving LOW-E glass according to claim 1, wherein: the second titanium oxide layer (3) is titanium oxide TiO 2 Layer with a thickness of 15-40nm.
4. The energy-saving LOW-E glass and the preparation method thereof according to claim 1, characterized in that: the third protective layer nickel-chromium layer (4) can be a nickel-chromium NiCr layer or a chromium Cr layer, and the thickness is 5-15nm.
5. The energy-saving LOW-E glass and the preparation method thereof according to claim 1, characterized in that: the fourth functional layer silver layer (5) is a silver Ag layer with the thickness of 5-20nm.
6. The method for preparing energy-saving LOW-E glass according to claim 1, characterized in that: the method comprises the following steps: (1) Taking the raw material components according to a formula, crushing the raw materials, sieving the crushed raw materials by a 200-400-mesh sieve, and fully mixing the raw materials for 20-60 minutes to obtain a mixed raw material;
(2) Performing high-temperature treatment on the mixed raw material obtained in the step (1) in a tank furnace at 1550-1650 ℃ until clear and bubble-free glass liquid is formed;
(3) Cooling the glass liquid obtained in the step (2) to 1100-1400 ℃, forming through a tin bath, then putting the formed glass into an annealing furnace for annealing at the annealing temperature of 530-570 ℃, and cutting after the annealing is finished to obtain a glass sheet (1);
(4) And (4) sequentially coating or pasting each layer of the glass original sheet (1) obtained in the step (3) in coating equipment and film pasting equipment to obtain the energy-saving LOW-E glass.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108101383A (en) * | 2018-02-27 | 2018-06-01 | 四川南玻节能玻璃有限公司 | One kind can tempering Low-E energy-saving glass |
| CN111268904A (en) * | 2020-03-09 | 2020-06-12 | 上海大学 | Preparation method of energy-saving glass |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108101383A (en) * | 2018-02-27 | 2018-06-01 | 四川南玻节能玻璃有限公司 | One kind can tempering Low-E energy-saving glass |
| CN111268904A (en) * | 2020-03-09 | 2020-06-12 | 上海大学 | Preparation method of energy-saving glass |
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