CN115135150A - Pesticide granule composition for rice seedling raising box with reduced phytotoxicity - Google Patents

Pesticide granule composition for rice seedling raising box with reduced phytotoxicity Download PDF

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Publication number
CN115135150A
CN115135150A CN202180014101.2A CN202180014101A CN115135150A CN 115135150 A CN115135150 A CN 115135150A CN 202180014101 A CN202180014101 A CN 202180014101A CN 115135150 A CN115135150 A CN 115135150A
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Prior art keywords
methyl
phenyl
carboxamide
granule composition
chloro
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Chinese (zh)
Inventor
向井启一郎
山口芳宽
吉浦弘
佐藤善孝
藤原敏美
南谷理沙
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Japanese Bayer Crop Science Co ltd
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Japanese Bayer Crop Science Co ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P3/00—Fungicides

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  • Life Sciences & Earth Sciences (AREA)
  • Plant Pathology (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical & Material Sciences (AREA)
  • Mycology (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides a pesticide granule composition applied to a rice seedling raising box, which reduces the pesticide damage. A pesticide granule composition for rice seedling raising boxes is characterized by containing a pesticide active ingredient, an alkyl naphthalene sulfonic acid derivative, alpha starch and smectite minerals.

Description

Pesticide granule composition for rice seedling raising box with reduced phytotoxicity
Technical Field
The invention relates to a pesticide granule composition applied to a rice seedling raising box and capable of reducing pesticide damage and a manufacturing method thereof.
Technical Field
When using an agricultural chemical, it is preferable to reduce the amount of the agricultural chemical used or the number of times of use, from the viewpoint of saving labor and reducing environmental load. In response to such a demand, a nursery box treatment is performed in transplanting rice cultivation, pesticides used in a rice field are applied to the nursery box, and effects are exerted in the rice field after transplantation. However, when seedlings are treated with a common granular pesticide, the pesticide active ingredient or other ingredients eluted or released may cause a chemical injury such as slow growth or growth failure of the seedlings. Therefore, it is desired to develop a treatment agent for a seedling box which does not cause or reduce phytotoxicity to weak seedlings during seedling raising.
A pesticide preparation has been reported so far, which aims to suppress elution of a pesticide active ingredient and reduce phytotoxicity caused by contact between a seedling in a seedling raising box and the pesticide active ingredient (patent documents 1,2, and 3). There has also been reported a pesticide preparation for reducing the phytotoxicity of seedlings by adding a specific substance in a method other than the elution control (patent document 4).
Documents of the prior art
Patent document
Patent document 1: japanese patent laid-open publication No. 2012-111752
Patent document 2: japanese Kokai publication Hei-2012 and 508713
Patent document 3: japanese patent laid-open publication No. 2012-17271
Patent document 4: japanese laid-open patent publication No. 2009-221108
Disclosure of Invention
Problems to be solved by the invention
The purpose of the present invention is to provide a pesticidal preparation composition having an excellent phytotoxicity-reducing effect on a pesticidal active ingredient having a high risk of poor growth of rice seedlings.
Means for solving the problems
The present inventors have found that a granular agrochemical composition for use in a rice nursery box containing an agrochemical active ingredient, an alkylnaphthalenesulfonic acid derivative, an alphatized starch, and a smectite mineral has an excellent phytotoxicity-reducing effect, and have completed the present invention.
The present invention provides the following solutions.
[1] A pesticidal granule composition for use in a rice seedling raising box, characterized by containing a pesticidal active ingredient, an alkylnaphthalenesulfonic acid derivative, an alphalated starch, and a smectite mineral.
[2] The pesticidal granule composition according to [1], wherein the content of the pesticidal active ingredient is 1 to 30% by weight.
[3] The pesticidal granule composition according to [1] or [2], wherein the content ratio of the alkylnaphthalenesulfonic acid derivative is 0.1 to 2.0% by weight.
[4] The pesticidal granule composition according to any one of [1] to [3], wherein the content of the gelatinized starch is 0.1 to 10% by weight.
[5] The pesticidal granule composition according to any one of [1] to [4], wherein the smectite mineral is bentonite.
[6] The pesticidal granule composition according to any one of [1] to [5], wherein the content of the smectite mineral is 1 to 50% by weight.
ADVANTAGEOUS EFFECTS OF INVENTION
The granular agricultural chemical composition of the present invention can reduce the chemical damage caused by the components containing the agricultural chemical active ingredient when applied to a seedling raising box for rice.
Detailed Description
The invention provides a pesticide granule composition applied to a rice seedling raising box, which is characterized by containing a pesticide active ingredient, an alkyl naphthalene sulfonic acid derivative, a smectite mineral and alpha starch.
The pesticide active ingredient of the present invention means an insecticide, a miticide, a nematicide, a bactericide, a molluscicide, a microbial agent, a beneficial organism, a pomacea, a herbicide, a bird repellent, a plant enhancer, a sterilant, a semiochemical, and/or a plant growth regulator.
Insecticide/acaricide/nematicide
In The present specification, The active ingredient designated by The "common name" is known and is described, for example, in "The Pesticide Manual", 16th ed., British Crop Protection Council 2012 ", or can be retrieved over The Internet (for example," http:// www.alanwood.net/pesticides "). Regarding its Classification, it is based on "IRAC Mode of Action Classification Scheme" applicable at the time of filing of the present patent application.
(1) Acetyl cholinesterase (AChE) inhibitors, for example:
carbamates, such as, for example, gossypol, aldicarb, bendiocarb, benfuracarb, butoxycarb, carb, carboxim, furacarb, ethiofencarb, fenobucarb, carboxim, furacarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, methomyl, monocarb, triazamate, oxamyl, dicarb, XMC, and methomyl; or
Organophosphates such as acephate, azamethiphos, ethoprophos, methyl glufosinate, cadusafos, phosphorus oxychloride, chlorfenvinphos, chlormephos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton-methyl, dichlorvos/DDVP, chlormephos, dimethoate, chlorfenvinphos, ethoprophos, EPN, ethion, fenamiphos, disulfoton, fenamiphos, fenitrothion, fenthion, fosthiazate, heptenophos, neonicotinophos, isopropylamidothion, isopropyl O- (methoxyaminothiophosphoryl) salicylate, triazophos, malathion, triazophos, methamidophos, methidathion, fenamiphos, monocrotophos, dibromophos, omethoate, fenpropaphos, pyrazothion, pirophos, pyrazofos, fosmidothion, pyrazofos, fosmidothion, pyrazofos, pyrazothion, fosmidothion, pyrazothion, phos, fosmidothion, phos, fenphos, fenpyrothion, fenphos, fenpyrothion, fenphos, Quinalphos, fenitrothion, butylpyrimidine phosph, disulfoton, terbufos, chlorfenvinphos, fosetyl methyl, triazophos, trichlorophosphate and aphis-fenamate.
(2) GABA-gated chloride channel antagonists are, for example:
cyclodiene-organochlorine systems, such as chlordane and endosulfan; or
Phenylpyrazole systems (Fiproles), such as ethiprole and fipronil.
(3) Sodium channel modulators, for example:
pyrethroids such as bifenthrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin-S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [ (1R) -trans isomer ], deltamethrin, sumicidin [ (EZ) - (1R) isomer ], fenvalerate, etofenprox, fenvalerate, flucythrinate, flumethrin, tau-cyhalothrin, etc, Profenofluthrin, imiprothrin, kadethrin, metofluthrin, permethrin, phenothrin [ (1R) -trans isomer ], propargyl, pyrethroids (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethrin [ (1R) isomer ], tetrabromthrin, and transfluthrin; or
DDT; or methoxy chloride.
(4) Nicotinic acetylcholine receptor (nAChR) competitive modulators are, for example:
neonicotinoids, such as acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam; or
Nicotine; or
Sulfoxaflor or fluoropyrafuranone.
(5) Nicotinic acetylcholine receptor (nAChR) allosteric modulators, for example:
spinosyns (Spinosyn) are systems such as spinetoram and spinosad.
(6) Glutamate-gated chloride channel (GluCl) allosteric modulators, for example:
avermectin/milbemycin lines, such as abamectin, emamectin-benzoate, lepimectin and milbemectin.
(7) Juvenile hormone mimics, for example:
juvenile hormone analogs such as hydridoprotenone, propuletin, and bestatin; or
Fenoxycarb; or pyriproxyfen.
(8) Various non-specific (multi-site) inhibitors are, for example:
haloalkyl systems such as methyl bromide and other alkyl halides; or
Trichloronitromethane; or sulfuryl fluoride; or borax; or tutaro; or
Methyl isocyanate products, such as dazomet (dazomet) and metam.
(9) Chordal organ modulators, for example:
pymetrozine; or flonicamid.
(10) Mite growth inhibitors are, for example:
clofentezine, hexythiazox, and flutenzine; or alternatively
Etoxazole.
(11) Microbial disruptors of the intestinal lining of insects, for example:
bacillus thuringiensis subspecies israelensis, Bacillus sphaericus (Bacillus sphaericus), Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenesmus (Bacillus thuringiensis subspecies tenestris), and Bt plant proteins: cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry3Bb, Cry34Ab1/35Ab 1.
(12) Mitochondrial ATP synthase inhibitors, such as ATP disruptors, are, for example:
diafenthiuron; or alternatively
Organotin compounds such as azocyclotin, tricyclotin and fenbutatin oxide; or alternatively
Propargite; or a tetrachlorvinphossulfone.
(13) Oxidative phosphorylation decoupling agents based on disrupting proton gradients are, for example:
chlorfenapyr, DNOC and sulfluramid.
(14) Nicotinic acetylcholine receptor channel blockers such as:
monosultap, cartap hydrochloride, thiocyclam and monosultap sodium salt.
(15) Chitin biosynthesis inhibitors (type 0), for example:
bistrifluron, chlorfluazuron, diflubenzuron, epoxiconazole, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.
(16) Chitin biosynthesis inhibitors (type 1), for example:
pediculicide.
(17) Molt disruptors (especially in the case of diptera), for example:
cyromazine.
(18) Ecdysone receptor agonists, for example, are:
chromafenozide, chlorfenozide, methoxyfenozide, and tebufenozide.
(19) Octopamine receptor agonists, for example, are:
amitraz.
(20) Mitochondrial complex III electron transport inhibitors are, for example:
hydramethylnon; or acequinocyl; or fluacrypyrim.
(21) Mitochondrial complex I electron transport inhibitors are, for example:
METI acaricides such as fenazaquin, fenpyroximate, pyriminostrobin, pyridaben, tebufenpyrad, and tolfenpyrad; or alternatively
Rotenone (Derris).
(22) Potential-dependent sodium channel blockers, for example, are:
indoxacarb; or metaflumizone.
(23) Acetyl CoA carboxylase inhibitors, for example:
tetronic and tetramic acid derivatives, such as spiroketonate, spiromesifen and spirotetramates.
(24) Mitochondrial complex IV electron transport inhibitors are, for example:
phosphines such as aluminum phosphide, calcium phosphide, phosphine, and zinc phosphide; or
Cyanide, calcium cyanide, potassium cyanide and sodium cyanide.
(25) Mitochondrial complex II electron transport inhibitors are, for example:
β -ketonitrile derivatives, such as cyenopyrafen and cyflumetofen; and carboxyanilides such as pyfluumide.
(28) A ranodine receptor modulator, for example:
diamides, such as chlorantraniliprole, cyantraniliprole, flubendiamide, tetrazolium amide (tetramirioprole), and tetrachlorantraniliprole (tetrachloro).
Other active ingredients, such as propiconazole, alfurazide, azadirachtin, Inpyrfluxam, isothiazole, fenbutate, bufenpyrad, brofenamide, bromopropylate, mefenamic-mefenamic, esfenpropathrin, chlortrimethoprim (chloroprallethrin), cryolite (cryolite), cyromanilide, cycloxaprid (cycloxaprid), cyhalodiamide (cyhalodiamide), dichloropyrad (diclomethaz), dicofol, etofenchlorantrazone, epsilon-methoxybifenthrin (epsilon-metofluthrin), epsilon-mofetil (epsilon-momfluthrin), Flometoquin, triflumimide (fluazaindzine), diflufenpyrad, furamectin (flufenamide), flufenacet, flufenacetrin (flufenacetrin), flufenapyr, flufenamate, flufenapyr, flufenamate, flufenapyr, flufenamate, flufenapyr, flufenamate, flufenapyr, flufenamate, flufenapyr, flufenamide, flufenapyr, flufenoxan, flufenapyr, flu, Mefluthrin, paichongding, pyridalyl, neoquinazoline (Pyrifluquinazon), pyriminostrobin, spirodiclofen (spirobiclofen), transfluthrin, oxathiafen (tiozafen), sulfoxonium (thiofluximate), trifluoropyrimidine, and methyl iodide; and a Bacillus firmus (Bacillus firmus) based preparation (I-1582, BioNeem, Votivo); and the following compounds: 1- { 2-fluoro-4-methyl-5- [ (2,2, 2-trifluoroethyl) sulfinyl ] phenyl } -3- (trifluoromethyl) -1H-1,2, 4-triazol-5-amine (known from WO 2006/043635) (CAS 885026-50-6), {1 '- [ (2E) -3- (4-chlorophenyl) prop-2-en-1-yl ] -5-fluorospiro [ indole-3, 4' -piperidine ] -1(2H) -yl } (2-chloropyridin-4-yl) methanone (known from WO 2003/106457) (CAS 637360-23-7), 2-chloro-N- [2- {1- [ (2E) -3- (4-chlorophenyl) prop-2-yl } methanone (known from WO 2003/106457) (CAS 637360-23-7) -en-1-yl ] piperidin-4-yl } -4- (trifluoromethyl) phenyl ] isonicotinamide (known from WO 2006/003494) (CAS 872999-66-1), 3- (4-chloro-2, 6-dimethylphenyl) -4-hydroxy-8-methoxy-1, 8-diazaspiro [4.5] dec-3-en-2-one (known from WO 0052161) (CAS 1225292-17-0), 3- (4-chloro-2, 6-dimethylphenyl) -8-methoxy-2-oxo-1, 8-diazaspiro [4.5] dec-3-en-4-yl carbonate ethyl ester (known from EP 2647626) (CAS-1440516-42-6), 4- (but-2-en-1-yloxy) -6- (3, 5-dimethylpiperidin-1-yl) -5-fluoropyrimidine (known from WO 2004/099160) (CAS 792914-58-0), PF1364 (known from JP 2010/018586) (CAS Reg.No.1204776-60-2), N- [ (2E) -1- [ (6-chloropyridin-3-yl) methyl ] pyridin-2 (1H) -ylidene ] -2,2, 2-trifluoroacetamide (known from WO 2012/029672) (CAS 1363400-41-2), (3E) -3- [1- [ (6-chloro-3-pyridinyl) methyl ] -2-pyridylidene ] -1,1, 1-trifluoropropan-2-one (known from WO 2013/144213) (CAS 1461743-15-6), N- [3- (benzylcarbamoyl) -4-chlorophenyl ] -1-methyl-3- (pentafluoroethyl) -4- (trifluoromethyl) -1H-pyrazole-5-carboxamide (known from WO 2010/051926) (CAS 1226889-14-0), 5-bromo-4-chloro-N- [ 4-chloro-2-methyl-6- (methylcarbamoyl) phenyl ] -2- (3-chloro-2-pyridyl) pyrazole-3-carboxamide (known from CN 103232431) (CAS 1449220-44-3), 4- [5- (3, 5-dichlorophenyl) -4, 5-dihydro-5- (trifluoromethyl) -3-isoxazole ] -2-methyl-N- (cis-1-oxo-3-thiacyclobutyl) benzamide, 4- [5- (3, 5-dichlorophenyl) -4, 5-dihydro-5- (trifluoromethyl) -3-isoxazole ] -2-methyl-N- (trans-1-oxo-3-thiacyclobutyl) benzamide and 4- [ (5S) -5- (3, 5-dichlorophenyl) -4, 5-dihydro-5- (trifluoromethyl) -3-isoxazole ] -2-methyl-N- (cis-1-dichloro-phenyl) -4, 5-dihydro-5- (trifluoromethyl) -3-isoxazole Oxy-3-thietanyl) benzamide (known from WO2013/050317A 1) (CAS 1332628-83-7), N- [ 3-chloro-1- (3-pyridyl) -1H-pyrazol-4-yl ] -N-ethyl-3- [ (3,3, 3-trifluoropropyl) sulfinyl ] propionamide, (+) -N- [ 3-chloro-1- (3-pyridyl) -1H-pyrazol-4-yl ] -N-ethyl-3- [ (3,3, 3-trifluoropropyl) sulfinyl ] propionamide and (-) -N- [ 3-chloro-1- (3-pyridyl) -1H-pyrazol-4-yl ] -N-ethyl- 3- [ (3,3, 3-trifluoropropyl) sulfinyl ] propanamide (known from WO2013/162715A2, WO2013/162716A2, US2014/0213448A 1) (CAS 1477923-37-7), 5- [ [ (2E) -3-chloro-2-propen-1-yl ] amino ] -1- [2, 6-dichloro-4- (trifluoromethyl) phenyl ] -4- [ (trifluoromethyl) sulfinyl ] -1H-pyrazole-3-carbonitrile (known from CN 101337937A) (CAS 1105672-77-2), 3-bromo-N- [ 4-chloro-2-methyl-6- [ (methylamino) thionylmethyl ] phenyl ] -1- (3-chloro-2-pyridinyl) -1H-pyrazole-5-methan-ol Amides, (thiobenzamides (Liudiebenjiaxuanan), known from CN 103109816A) (CAS 1232543-85-9); n- [ 4-chloro-2- [ [ (1, 1-dimethylethyl) amino ] carbonyl ] -6-methylphenyl ] -1- (3-chloro-2-pyridinyl) -3- (fluoromethoxy) -1H-pyrazole-5-carboxamide (known from WO2012/034403A 1) (CAS 1268277-22-0), N- [2- (5-amino-1, 3, 4-thiadiazol-2-yl) -4-chloro-6-methylphenyl ] -3-bromo-1- (3-chloro-2-pyridinyl) -1H-pyrazole-5-carboxamide (known from WO2011/085575A 1) (CAS 1233882-22-8), 4- [3- [2, 6-dichloro-4- [ (3, 3-dichloro-2-propen-1-yl) oxy ] phenoxy ] propoxy ] -2-methoxy-6- (trifluoromethyl) pyrimidine (known from CN 101337940A) (CAS 1108184-52-6); (2E) -and 2(Z) -2- [2- (4-cyanophenyl) -1- [3- (trifluoromethyl) phenyl ] ethylene ] -N- [4- (difluoromethoxy) phenyl ] hydrazinecarboxamide (known from CN 101715774A) (CAS 1232543-85-9); 3- (2, 2-dichlorovinyl) -2, 2-dimethyl-4- (1H-benzimidazol-2-yl) phenyl cyclopropanecarboxylate (known from CN 103524422A) (CAS 1542271-46-4); (4aS) -7-chloro-2, 5-dihydro-2- [ [ (methoxycarbonyl) [4- [ (trifluoromethyl) thio ] phenyl ] amino ] carbonyl ] indeno [1,2-e ] [1,3,4] oxapyridazine-4 a (3H) -carboxylic acid methyl ester (known from CN 102391261A) (CAS 1370358-69-2); 6-deoxy-3-O-ethyl-2, 4-di-O-methyl-1- [ N- [4- [1- [4- (1,1,2,2, 2-pentafluoroethoxy) phenyl ] -1H-1,2, 4-triazol-3-yl ] phenyl ] carbamate ] -a-L-mannopyranose (known from US2014/0275503A 1) (CAS 1181213-14-8); 8- (2-Cyclopropylmethoxy-4-trifluoromethylphenoxy) -3- (6-trifluoromethylpyridazin-3-yl) -3-azabicyclo [3.2.1] octane (CAS 1253850-56-4), (8-trans) -8- (2-cyclopropylmethoxy-4-trifluoromethylphenoxy) -3- (6-trifluoromethylpyridazin-3-yl) -3-azabicyclo [3.2.1] octane (CAS 933798-27-7), (8-cis) -8- (2-cyclopropylmethoxy-4-trifluoromethylphenoxy) -3- (6-trifluoromethylpyridazin-3-yl) -3-azabicyclo [3.2.1] octane (according to WO2007040280A1, N.B.C.), WO2007040282A1 is known) (CAS 934001-66-8), and N- [ 3-chloro-1- (3-pyridyl) -1H-pyrazol-4-yl ] -N-ethyl-3- [ (3,3, 3-trifluoropropyl) thio ] propanamide (known from WO2015/058021A1, WO2015/058028A 1) (CAS 1477919-27-9).
Bactericide
The active ingredients designated by the "common name" in this specification are known and are described, for example, in "Pesticide Manual (16th Ed., British Crop Protection Council)" or may be retrieved over the Internet (e.g., "http:// www.alanwood.net/pesticides").
In all the components described in the classes (1) to (15), if these functional groups can be used, a salt may be formed with an appropriate base or acid as the case may be. All of the fungicide blend components described in the classes (1) to (15) may include tautomeric forms in some cases.
(1) Inhibitors of ergosterol biosynthesis, for example, (1.001) cyproconazole, (1.002) difenoconazole, (1.003) epoxiconazole, (1.004) fenhexamid, (1.005) fenpropidin, (1.006) fenpropimorph, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1.009) flutriafol, (1.010) imazazole, (1.011) imazalil, (1.012) ipconazole, (1.013) metconazole, (1.014) myclobutanil, (1.015) paclobutrazol, (1.016) prochloraz, (1.017) propiconazole, (1.018) prothioconazole, (1.019) pyrisoxazole, (1.020) sporozosin, (1.021) tebuconazole, (1.022) tetraconazole, (1.023) triadimenol, (1.024) tridemorph, (1.025) tridemorph, (1.026) triticonazole, (1.5) (R1, S-2- (1, 5-methyl) -1- (1H-2-benzyl) -1- (1-2, 2, 4-triazol-1-ylmethyl) cyclopentanol, (1.027) (1S,2R,5R) -5- (4-chlorobenzyl) -2- (chloromethyl) -2-methyl-1- (1H-1,2, 4-triazol-1-ylmethyl) cyclopentanol, (1.028) (2R) -2- (1-chlorocyclopropyl) -4- [ (1R) -2, 2-dichlorocyclopropyl ] -1- (1H-1,2, 4-triazol-1-yl) butan-2-ol (1.029) (2R) -2- (1-chlorocyclopropyl) -4- [ (1S) -2, 2-dichlorocyclopropyl ] -1- (1H-1,2, 4-triazol-1-yl) butan-2-ol, (1.030) (2R) -2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl ] -1- (1H-1,2, 4-triazol-1-yl) propan-2-ol, (1.031) (2S) -2- (1-chlorocyclopropyl) -4- [ (1R) -2, 2-dichlorocyclopropyl ] -1- (1H-1,2, 4-triazol-1-yl) butan-2-ol, (1.032) (2S) -2- (1-chlorocyclopropyl) -4- [ (1S) -2, 2-dichlorocyclopropyl ] -1- (1H-1,2, 4-triazol-1-yl) butan-2-ol, (1.033) (2S) -2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl ] -1- (1H-1,2, 4-triazol-1-yl) propan-2-ol, (1.034) (R) - [3- (4-chloro-2-fluorophenyl) -5- (2, 4-difluorophenyl) -1, 2-oxazol-4-yl ] (pyridin-3-yl) methanol, (1.035) (S) - [3- (4-chloro-2-fluorophenyl) -5- (2, 4-difluorophenyl) -1, 2-oxazol-4-yl ] (pyridin-3-yl) methanol, (1.036) [3- (4-chloro-2-fluorophenyl) -5- (2, 4-difluorophenyl) -1, 2-oxazol-4-yl ] (pyridin-3-yl) methanol, (1.037)1- ({ (2R,4S) -2- [ 2-chloro-4- (4-chlorophenoxy) phenyl ] -4-methyl-1, 3-dioxolan-2-yl } methyl) -1H-1,2, 4-triazole, (1.038)1- ({ (2S,4S) -2- [ 2-chloro-4- (4-chlorophenoxy) phenyl ] -4-methyl-1, 3-dioxolan-2-yl } methyl) -1H-1,2, 4-triazole, (1.039)1- { [3- (2-chlorophenyl) -2- (2, 4-difluorophenyl) oxiran-2-yl ] methyl } -1H-1,2, 4-triazol-5-yl thiocyanate, (1.040)1- { [ rel (2R,3R) -3- (2-chlorophenyl) -2- (2, 4-difluorophenyl) oxiran-2-yl ] methyl } -1H-1,2, 4-triazol-5-yl thiocyanate, (1.041)1- { [ rel (2R,3S) -3- (2-chlorophenyl) -2- (2, 4-difluorophenyl) oxiran-2-yl ] methyl } -1H-1,2, 4-triazol-5-yl thiocyanate, (1.042)2- [ (2R,4R,5R) -1- (2, 4-dichlorophenyl) -5-hydroxy-2, 6, 6-trimethylheptan-4-yl ] -2, 4-dihydro-3H-1, 2, 4-triazol-3-thione, (1.043)2- [ (2R,4R,5S) -1- (2, 4-dichlorophenyl) -5-hydroxy-2, 6, 6-trimethylheptan-4-yl ] -2, 4-dihydro-3H-1, 2, 4-triazol-3-thione, (1.044)2- [ (2R,4S,5R) -1- (2, 4-dichlorophenyl) -5-hydroxy-2, 6, 6-trimethylheptan-4-yl ] -2, 4-dihydro-3H-1, 2, 4-triazole-3-thione, (1.045)2- [ (2R,4S,5S) -1- (2, 4-dichlorophenyl) -5-hydroxy-2, 6, 6-trimethylheptan-4-yl ] -2, 4-dihydro-3H-1, 2, 4-triazole-3-thione, (1.046)2- [ (2S,4R,5R) -1- (2, 4-dichlorophenyl) -5-hydroxy-2, 6, 6-trimethylheptan-4-yl ] -2, 4-dihydro-3H-1, 2, 4-triazole-3-thione, (1.047)2- [ (2S,4R,5S) -1- (2, 4-dichlorophenyl) -5-hydroxy-2, 6, 6-trimethylheptan-4-yl ] -2, 4-dihydro-3H-1, 2, 4-triazole-3-thione, (1.048)2- [ (2S,4S,5R) -1- (2, 4-dichlorophenyl) -5-hydroxy-2, 6, 6-trimethylheptan-4-yl ] -2, 4-dihydro-3H-1, 2, 4-triazole-3-thione, (1.049)2- [ (2S,4S,5S) -1- (2, 4-dichlorophenyl) -5-hydroxy-2, 6, 6-trimethylheptan-4-yl ] -2, 4-dihydro-3H-1, 2, 4-triazole-3-thione, (1.050)2- [1- (2, 4-dichlorophenyl) -5-hydroxy-2, 6, 6-trimethylheptan-4-yl ] -2, 4-dihydro-3H-1, 2, 4-triazole-3-thione, (1.051)2- [ 2-chloro-4- (2, 4-dichlorophenoxy) phenyl ] -1- (1H-1,2, 4-triazole-1-yl) propan-2-ol, (1.052)2- [ 2-chloro-4- (4-chlorophenoxy) phenyl ] -1- (1H-1,2, 4-triazol-1-yl) butan-2-ol, (1.053)2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl ] -1- (1H-1,2, 4-triazol-1-yl) butan-2-ol, (1.054)2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl ] -1- (1H-1,2, 4-triazol-1-yl) pentan-2-ol, (1.055)2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl ] -1- (1H-1,2, 4-triazol-1-yl) propan-2-ol, (1.056)2- { [3- (2-chlorophenyl) -2- (2, 4-difluorophenyl) oxiran-2-yl ] methyl } -2, 4-dihydro-3H-1, 2, 4-triazol-3-thione, (1.057)2- { [ rel (2R,3R) -3- (2-chlorophenyl) -2- (2, 4-difluorophenyl) oxiran-2-yl ] methyl } -2, 4-dihydro-3H-1, 2, 4-triazol-3-thione, (1.058)2- { [ rel (2R,3S) -3- (2-chlorophenyl) -2- (2, 4-difluorophenyl) oxiran-2-yl ] methyl } -2, 4-dihydro-3H-1, 2, 4-triazole-3-thione, (1.059)5- (4-chlorobenzyl) -2- (chloromethyl) -2-methyl-1- (1H-1,2, 4-triazol-1-ylmethyl) cyclopentanol, (1.060)5- (allylsulfanyl) -1- { [3- (2-chlorophenyl) -2- (2, 4-difluorophenyl) oxiran-2-yl ] methyl } -1H-1,2, 4-triazole, (1.061)5- (allylsulfanyl) -1- { [ rel (2R,3R) -3- (2-chlorophenyl) -2- (2, 4-difluorophenyl) oxiran-2-yl ] methyl } -1H-1,2, 4-triazole, (1.062)5- (allylsulfanyl) -1- { [ rel (2R,3S) -3- (2-chlorophenyl) -2- (2, 4-difluorophenyl) oxiran-2-yl ] methyl } -1H-1,2, 4-triazole, (1.063) N' - (2, 5-dimethyl-4- { [3- (1,1,2, 2-tetrafluoroethoxy) phenyl ] sulfanyl } phenyl) -N-ethyl-N-methyliminocarboxamide, and pharmaceutically acceptable salts thereof, (1.064) N '- (2, 5-dimethyl-4- { [3- (2,2, 2-trifluoroethoxy) phenyl ] sulfanyl } phenyl) -N-ethyl-N-methylimidamide carboxamide, (1.065) N' - (2, 5-dimethyl-4- { [3- (2,2,3, 3-tetrafluoropropoxy) phenyl ] sulfanyl } phenyl) -N-ethyl-N-methylimidamide carboxamide, (1.066) N '- (2, 5-dimethyl-4- { [3- (pentafluoroethoxy) phenyl ] sulfanyl } phenyl) -N-ethyl-N-methylimidamide carboxamide, (1.067) N' - (2, 5-dimethyl-4- {3- [ (1,1,2, 2-tetrafluoroethyl) sulfanyl ] phenoxy } phenyl) -N-ethyl-N-methyliminocarboxamide, (1.068) N ' - (2, 5-dimethyl-4- {3- [ (2,2, 2-trifluoroethyl) sulfanyl ] phenoxy } phenyl) -N-ethyl-N-methyliminocarboxamide, (1.069) N ' - (2, 5-dimethyl-4- {3- [ (2,2,3, 3-tetrafluoropropyl) sulfanyl ] phenoxy } phenyl) -N-ethyl-N-methyliminocarboxamide, (1.070) N ' - (2, 5-dimethyl-4- {3- [ (pentafluoroethyl) sulfanyl ] phenoxy } phenyl) -N-ethyl-N-methyliminocarboxamide, (1.071) N '- (2, 5-dimethyl-4-phenoxyphenyl) -N-ethyl-N-methylimide carboxamide, (1.072) N' - (4- { [3- (difluoromethoxy) phenyl ] sulfanyl } -2, 5-dimethylphenyl) -N-ethyl-N-methylimide carboxamide, (1.073) N '- (4- {3- [ (difluoromethyl) sulfanyl ] phenoxy } -2, 5-dimethylphenyl) -N-ethyl-N-methylimide carboxamide, (1.074) N' - [ 5-bromo-6- (2, 3-dihydro-1H-inden-2-yloxy) -2-methylpyridin-3-yl ] -N-ethyl-N-methylimide Benzimide carboxamide, (1.075) N ' - {4- [ (4, 5-dichloro-1, 3-thiazol-2-yl) oxy ] -2, 5-dimethylphenyl } -N-ethyl-N-methylimide carboxamide, (1.076) N ' - { 5-bromo-6- [ (1R) -1- (3, 5-difluorophenyl) ethoxy ] -2-methylpyridin-3-yl } -N-ethyl-N-methylimide carboxamide, (1.077) N ' - { 5-bromo-6- [ (1S) -1- (3, 5-difluorophenyl) ethoxy ] -2-methylpyridin-3-yl } -N-ethyl-N-methylimide carboxamide, and, (1.078) N '- { 5-bromo-6- [ (cis-4-isopropylcyclohexyl) oxy ] -2-methylpyridin-3-yl } -N-ethyl-N-methylimide-carboxamide, (1.079) N' - { 5-bromo-6- [ (trans-4-isopropylcyclohexyl) oxy ] -2-methylpyridin-3-yl } -N-ethyl-N-methylimide-carboxamide, (1.080) N' - { 5-bromo-6- [1- (3, 5-difluorophenyl) ethoxy ] -2-methylpyridin-3-yl } -N-ethyl-N-methylimidecarboxamide.
(2) Inhibitors of the respiratory chain in complex I or complex II, such as (2.001) benzovindiflupyr, (2.002) bixafen, (2.003) boscalid, (2.004) carboxin, (2.005) fluopyram, (2.006) flutolanilide, (2.007) fluxapyroxad, (2.008) furametpyr, (2.009) isotianil, (2.010) pyrazolonaphthylamide (trans-epimer 1R,4S,9S), (2.011) pyrazolonaphthylamide (trans-epimer 1S,4R,9R), (2.012) pyrazolonaphthylamide (trans-epimer racemic compound 1RS,4SR,9SR), (2.013) pyrazolonaphthylamide (cis-epimer compound (1RS,4SR,9RS) and trans-epimer compound (1RS,4SR,9SR), (2.014) cis-epimer compound (cis-1R, 4SR,9SR), 4S,9R), (2.015) isopyrazam (cis-epimer 1S,4R,9S), (2.016) isopyrazam (cis-epimer racemic compound 1RS,4SR,9RS), (2.017) penflufen, (2.018) penthiopyrad, (2.019) penflufenacet hydroxylamine (pydiflumetofen), (2.020) Biphenyl pyrazinamide, (2.021) fluzacyclofenamide, (2.022)1, 3-dimethyl-N- (1,1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.023)1, 3-dimethyl-N- [ (3R) -1,1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl ] -1H-pyrazole-4-carboxamide, 2.023, (2.024)1, 3-dimethyl-N- [ (3S) -1,1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl ] -1H-pyrazole-4-carboxamide, (2.025) 1-methyl-3- (trifluoromethyl) -N- [ 2' - (trifluoromethyl) biphenyl-2-yl ] -1H-pyrazole-4-carboxamide, (2.026) 2-fluoro-6- (trifluoromethyl) -N- (1,1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl) benzamide, (2.027)3- (difluoromethyl) -1-methyl-N- (1,1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.028)3- (difluoromethyl) -1-methyl-N- [ (3R) -1,1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl ] -1H-pyrazole-4-carboxamide, (2.029)3- (difluoromethyl) -1-methyl-N- [ (3S) -1,1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl ] -1H-pyrazole-4-carboxamide, (2.030)3- (difluoromethyl) -N- (7-fluoro-1, 1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl) -1-methyl-1H-pyrazole-4-carboxamide, (2.031)3- (difluoromethyl) -N- [ (3R) -7-fluoro-1, 1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl ] -1-methyl-1H-pyrazole-4-carboxamide, (2.032)3- (difluoromethyl) -N- [ (3S) -7-fluoro-1, 1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl ] -1-methyl-1H-pyrazole-4-carboxamide, (2.033)5, 8-difluoro-N- [2- (2-fluoro-4- { [4- (trifluoromethyl) pyridin-2-yl ] oxy } phenyl) ethyl ] quinazolin-4-amine, (2.034) N- (2-cyclopentyl-5-fluorobenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.035) N- (2-tert-butyl-5-methylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.036) N- (2-tert-butylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.037) N- (5-chloro-2-ethylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.038) N- (5-chloro-2-isopropylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.039) N- [ (1R,4S) -9- (dichloromethylene) -1,2,3, 4-tetrahydro-1, 4-Methonaphthalen-5-yl ] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.040) N- [ (1S,4R) -9- (dichloromethylene) -1,2,3, 4-tetrahydro-1, 4-methanonaphthalen-5-yl ] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.041) N- [1- (2, 4-dichlorophenyl) -1-methoxypropan-2-yl ] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.042) N- [ 2-chloro-6- (trifluoromethyl) benzyl ] -N -cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.043) N- [ 3-chloro-2-fluoro-6- (trifluoromethyl) benzyl ] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.044) N- [ 5-chloro-2- (trifluoromethyl) benzyl ] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.045) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-N-cyclopropyl-4- (difluoromethyl) -5-fluoro-1-methyl-N - [ 5-methyl-2- (trifluoromethyl) benzyl ] -1H-pyrazole-4-carboxamide, (2.046) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-fluoro-6-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.047) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropyl-5-methylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.048) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -1-methyl-1H-pyrazole -4-thiamine carbonate, (2.049) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.050) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (5-fluoro-2-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.051) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-4, 5-dimethylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.052) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-5-fluorobenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.053) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-5-methylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.054) N-cyclopropyl-N- (2-cyclopropyl-5-fluorobenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.055) N-cyclopropyl-N- (2-cyclopropyl-5-methylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.056) N-cyclopropyl-N- (2-cyclopropylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide.
(3) Inhibitors of the respiratory chain in complex III, such as (3.001) ametoctradin, (3.002) amisulbrom, (3.003) azoxystrobin, (3.004) toluidinate (coumethosystrobin), (3.005) coumoxystrobin, (3.006) cyazofamid, (3.007) dimoxystrobin, (3.008) enestroburin, (3.009) famoxadone, (3.010) fenamidone, (3.011) flufenamidol (flufenoxystrobin), (3.012) fluoxastrobin, (3.013) kresoxim, (3.014) metominostrobin, (3.015) orysastrobin, (3.016) picoxystrobin, (3.017) pyrazoxynil, (3.018) pyraclostrobin, (3.019) pyraclostrobin, (3.020) pyraclostrobin, (3.021) (2E) -2- {2 [ { 1e) -1- (3- { -1- { -fluoro-E) -1-fluoro-2-phenyloxy } met ] methyl } amino } methyl phenyl ethyl methyl [ (2- (2) iminomethyl) phenyl ] methyl) methyl } amino } phenyl methyl) methyl } phenyl } amino } methyl ethyl } methyl Phenylacetamide, (3.022) (2E,3Z) -5- { [1- (4-chlorophenyl) -1H-pyrazol-3-yl ] oxy } -2- (methoxyimino) -N, 3-dimethylpent-3-enamide, (3.023) (2R) -2- {2- [ (2, 5-dimethylphenoxy) methyl ] phenyl } -2-methoxy-N-methylacetamide, (3.024) (2S) -2- {2- [ (2, 5-dimethylphenoxy) methyl ] phenyl } -2-methoxy-N-methylacetamide, (3.025) (3S,6S,7R,8R) -8-benzyl-3- [ ({3- [ (isobutyryloxy) methoxy ] -4-methoxypyridine- 2-yl } carbonyl) amino ] -6-methyl-4, 9-dioxo-1, 5-dioxolan-7-yl 2-methylpropionate, (3.026)2- {2- [ (2, 5-dimethylphenoxy) methyl ] phenyl } -2-methoxy-N-methylacetamide, (3.027) N- (3-ethyl-3, 5, 5-trimethylcyclohexyl) -3-carboxamide-2-hydroxybenzamide, (3.028) (2E,3Z) -5- { [1- (4-chloro-2-fluorophenyl) -1H-pyrazol-3-yl ] oxy } -2- (methoxyimino) -N, 3-dimethylpent-3-enamide.
(4) Inhibitors of mitosis and cell division, for example (4.001) carbendazim, (4.002) diethofencarb, (4.003) ethaboxam, (4.004) fluopicolide, (4.005) pencycuron, (4.006) thiabendazole, (4.007) thiophanate-methyl, (4.008) zoxamide, (4.009) 3-chloro-4- (2, 6-difluorophenyl) -6-methyl-5-phenylpyridazine, (4.010) 3-chloro-5- (4-chlorophenyl) -4- (2, 6-difluorophenyl) -6-methylpyridazine, (4.011) 3-chloro-5- (6-chloropyridin-3-yl) -6-methyl-4- (2,4, 6-trifluorophenyl) pyridazine, (4.012)4- (2-bromo-4-fluorophenyl) -N- (2, 6-difluorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, (4.013)4- (2-bromo-4-fluorophenyl) -N- (2-bromo-6-fluorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, (4.014)4- (2-bromo-4-fluorophenyl) -N- (2-bromophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, (4.015)4- (2-bromo-4-fluorophenyl) -N- (2-chloro-6-fluorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, and mixtures thereof, (4.016)4- (2-bromo-4-fluorophenyl) -N- (2-chlorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, (4.017)4- (2-bromo-4-fluorophenyl) -N- (2-fluorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, (4.018)4- (2-chloro-4-fluorophenyl) -N- (2, 6-difluorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, (4.019)4- (2-chloro-4-fluorophenyl) -N- (2-chloro-6-fluorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, (4.020)4- (2-chloro-4-fluorophenyl) -N- (2-chlorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, (4.021)4- (2-chloro-4-fluorophenyl) -N- (2-fluorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, (4.022)4- (4-chlorophenyl) -5- (2, 6-difluorophenyl) -3, 6-dimethylpyridazine, (4.023) N- (2-bromo-6-fluorophenyl) -4- (2-chloro-4-fluorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, (4.024) N- (2-bromophenyl) -4- (2-chloro-4-fluorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine, (4.025) N- (4-chloro-2, 6-difluorophenyl) -4- (2-chloro-4-fluorophenyl) -1, 3-dimethyl-1H-pyrazol-5-amine.
(5) Compounds which can show activity at multiple sites, for example (5.001) bordeaux, (5.002) captafol, (5.003) captan, (5.004) chlorothalonil, (5.005) copper hydroxide, (5.006) copper naphthenate, (5.007) copper oxide, (5.008) basic copper chloride, (5.009) copper sulfate (2+), (5.010) dithianon, (5.011) dodine, (5.012) folpet, (5.013) mancozeb, (5.014) maneb, (5.015) metiram, (5.016) zineb (zinmetiram), (5.017) oxine (copperone), (5.018) propineb, (5.019) sulfur and sulfur preparations such as calcium polysulfide, (5.020) thiuram, (5.021) zineb, (5.022) ziram.
(6) Compounds capable of inducing host defenses, for example, (6.001) acibenzolar-S-methyl, (6.002) isotianil, (6.003) thiabendazole, (6.004) tiadinil.
(7) Inhibitors of amino acid and/or protein biosynthesis, such as (7.001) cyprodinil, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate, (7.004) oxytetracycline, (7.005) pyrimethanil, (7.006)3- (5-fluoro-3, 3,4, 4-tetramethyl-3, 4-dihydroisoquinolin-1-yl) quinoline.
(8) Inhibitors of ATP production, such as (8.001) silthiopham.
(9) Cell wall synthesis inhibitors, for example (9.001) benthiavalicarb-isopropyl, (9.002) dimethomorph, (9.003) flumorph, (9.004) iprovalicarb, (9.005) mandipropamid, (9.006) pyrimorph (pyrimorph), (9.007) propamocarb, (9.008) (2E) -3- (4-tert-butylphenyl) -3- (2-chloropyridin-4-yl) -1- (morpholin-4-yl) prop-2-en-1-one, (9.009) (2Z) -3- (4-tert-butylphenyl) -3- (2-chloropyridin-4-yl) -1- (morpholin-4-yl) prop-2-en-1-one.
(10) Inhibitors of lipid and membrane synthesis, such as propamocarb (10.001), propamocarb hydrochloride (10.002), and tolclofos-methyl (10.003).
(11) Melanin biosynthesis inhibitors such as (11.001) tricyclazole, (11.002)2,2, 2-trifluoroethyl { 3-methyl-1- [ (4-methylbenzoyl) amino ] butan-2-yl } carbamate.
(12) Inhibitors of nucleic acid synthesis, for example (12.001) benalaxyl, (12.002) benalaxyl-M (kiralaxyl), (12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam).
(13) Signal transduction inhibitors such as (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) propoxymidine, (13.005) phenoxyquinoline, (13.006) vinclozolin.
(14) Compounds that can act as uncouplers, such as (14.001) fluazinam, (14.002) Demodex.
(15) Other compounds, such as (15.001) abscisic acid, (15.002) thiobenothionitrile, (15.003) besoxazine, (15.004) carbapenem (capsomycin), (15.005) carvone, (15.006) mefenamic acid, (15.007) thiabendazole, (15.008) cyflufenamid, (15.009) cymoxanil, (15.010) boscalid, (15.011) fluthiacet, (15.012) fosetyl-aluminum, (15.013) calcium fosetyl-calcium, (15.014) sodium triethylphosphonate, (15.015) methyl isothiocyanate, (15.016) metrafenone, (15.017) milomycin, (15.018) natamycin, (15.019) nickel dimethyldithiocarbamate, (2) phthalidyl, (56) oxomocarbin (oxocarbazib), (15.022) fluthiazopyrazole pyrazofen, (15.023) oxofenacin (oxofenthionin), (15.024) pentachlorophenol and salts, (36 15.025) phosphonic acid and salts thereof, (15.026) propamocarb (ethoxycarb) (pyrane-15.027) pyrofenacetophenone (15.027) (36 15.025 2) pyr-fenacetophenone (3674), (15.028) Terfquinoline, (15.029) phyllo-cumylphthalein, (15.030) sulfenamide, (15.031)1- (4- {4- [ (5R) -5- (2, 6-difluorophenyl) -4, 5-dihydro-1, 2-oxazol-3-yl ] -1, 3-thiazol-2-yl } piperidin-1-yl) -2- [ 5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl ] ethanone, (15.032)1- (4- {4- [ (5S) -5- (2, 6-difluorophenyl) -4, 5-dihydro-1, 2-oxazol-3-yl ] -1, 3-thiazol-2-yl } piperidin-1-yl) -2- [5- Methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl ] ethanone, (15.033)2- (6-benzylpyridin-2-yl) quinazoline, (15.034)2, 6-dimethyl-1H, 5H- [1,4] dithio [2,3-c:5, 6-c' ] dipyrrole-1, 3,5,7(2H,6H) -tetraone, (15.035)2- [3, 5-bis (difluoromethyl) -1H-pyrazol-1-yl ] -1- [4- (4- {5- [2- (prop-2-en-1-yloxy) phenyl ] -4, 5-dihydro-1, 2-oxazol-3-yl } -1, 3-thiazol-2-yl) piperidin-1-yl ] ethanone, (15.036)2- [3, 5-bis (difluoromethyl) -1H-pyrazol-1-yl ] -1- [4- (4- {5- [ 2-chloro-6- (prop-2-en-1-yloxy) phenyl ] -4, 5-dihydro-1, 2-oxazol-3-yl } -1, 3-thiazol-2-yl) piperidin-1-yl ] ethanone, (15.037)2- [3, 5-bis (difluoromethyl) -1H-pyrazol-1-yl ] -1- [4- (4- {5- [ 2-fluoro-6- (prop-2-en-1-yloxy) Phenyl ] -4, 5-dihydro-1, 2-oxazol-3-yl } -1, 3-thiazol-2-yl) piperidin-1-yl ] ethanone, (15.038)2- [6- (3-fluoro-4-methoxyphenyl) -5-methylpyridin-2-yl ] quinazoline, (15.039)2- { (5R) -3- [2- (1- { [3, 5-bis (difluoromethyl) -1H-pyrazol-1-yl ] acetyl } piperidin-4-yl) -1, 3-thiazol-4-yl ] -4, 5-dihydro-1, 2-oxazol-5-yl } -3-chlorophenylmethane sulfonate, pharmaceutically-acceptable salts thereof, and pharmaceutically-acceptable salts thereof, (15.040)2- { (5S) -3- [2- (1- { [3, 5-bis (difluoromethyl) -1H-pyrazol-1-yl ] acetyl } piperidin-4-yl) -1, 3-thiazol-4-yl ] -4, 5-dihydro-1, 2-oxazol-5-yl } -3-chlorophenylmethane sulfonate, (15.041)2- {2- [ (7, 8-difluoro-2-methylquinolin-3-yl) oxy ] -6-fluorophenyl } propan-2-ol, (15.042)2- { 2-fluoro-6- [ (8-fluoro-2-methylquinolin-3-yl) oxy ] phenyl } propan-2-ol, (15.043)2- {3- [2- (1- { [3, 5-bis (difluoromethyl) -1H-pyrazol-1-yl ] acetyl } piperidin-4-yl) -1, 3-thiazol-4-yl ] -4, 5-dihydro-1, 2-oxazol-5-yl } -3-chlorophenylmethane sulfonate, (15.044)2- {3- [2- (1- { [3, 5-bis (difluoromethyl) -1H-pyrazol-1-yl ] acetyl } piperidin-4-yl) -1, 3-thiazol-4-yl ] -4, 5-dihydro-1, 2-oxazol-5-yl } phenylmethane sulfonate, methyl ethyl acetate, benzyl acetate, and benzyl acetate, (15.045) 2-phenylphenol and its salts, (15.046)3- (4,4, 5-trifluoro-3, 3-dimethyl-3, 4-dihydroisoquinolin-1-yl) quinoline, (15.047)3- (4, 4-difluoro-3, 3-dimethyl-3, 4-dihydroisoquinolin-1-yl) quinoline, (15.048) 4-amino-5-fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidin-2 (1H) -one), (15.049) 4-oxo-4- [ (2-phenylethyl) amino ] butyric acid, (15.050) 5-amino-1, 3, 4-thiadiazole-2-thiol, (15.051) 5-chloro-N '-phenyl-N' - (propane-2-ol) -en-1-yl) thiophene 2-sulfonylhydrazide, (15.052) 5-fluoro-2- [ (4-fluorobenzyl) oxy ] pyrimidin-4-amine, (15.053) 5-fluoro-2- [ (4-methylbenzyl) oxy ] pyrimidin-4-amine, (15.054) 9-fluoro-2, 2-dimethyl-5- (quinolin-3-yl) -2, 3-dihydro-1, 4-benzoxazepine, (15.055) but-3-en-1-yl {6- [ ({ [ (Z) - (1-methyl-1H-tetrazol-5-yl) (phenyl) methylene ] amino } oxy) methyl ] pyridin-2-yl } carbamate, and, (15.056) Ethyl (2Z) -3-amino-2-cyano-3-phenylacrylate, (15.057) phenazine-1-carboxylic acid, (15.058) propyl 3,4, 5-trihydroxybenzoate, (15.059) quinolin-8-ol, (15.060) quinolin-8-ol sulfate (2:1), (15.061) tert-butyl {6- [ ({ [ (1-methyl-1H-tetrazol-5-yl) (phenyl) methylidene ] amino } oxy) methyl ] pyridin-2-yl } carbamate.
As the microbial agent, beneficial organisms, there are: in particular, products (e.g., proteins and secondary metabolites) derived from bacteria, fungi, yeasts, plant extracts, and microorganisms.
Examples of the bacteria include: spore-forming bacteria, bacteria that form colonies on roots, and bacteria that function as biological insecticides, bactericides, or nematicides.
Examples of the above-mentioned bacteria are the following bacteria:
bacillus amyloliquefaciens (Bacillus amyloliquefaciens) strain FZB42(DSM 231179) or Bacillus cereus (Bacillus cereus), in particular Bacillus cereus (B.cereus) strain CNCM I-1562, or Bacillus firmus (Bacillus firmus) strain I-1582 (accession number CNCM I-1582), or Bacillus pumilus (Bacillus pumilus), in particular strain GB34 (accession number ATCC 700814) and QST2808 (accession number NRRL B-30087), or Bacillus subtilis (Bacillus subtilis), in particular strain GB03 (accession number ATCC SD-1397), or Bacillus subtilis (Bacillus subtilis) strain QST713 (accession number NRRL B-21661), or Bacillus subtilis strain OST 02 (accession number NRRL B-50421), Bacillus thuringiensis (Bacillus thuringiensis), in particular Bacillus subtilis strain ATCC H-12752), or Bacillus subtilis strain OST 02 (Bacillus thuringiensis) strain OST 30014 (Bacillus thuringiensis), in particular Bacillus thuringiensis strain ATCC H-5952), Or of the species silurus thuringiensis (B.thuringiensis subsp.aizawai), in particular the strain ABTS-1857(SD-1372), or of the species Bacillus thuringiensis subsp.kurstaki (B.thuringiensis subsp.kurstaki) strain HD-1, or of the species Bacillus thuringiensis subsp.tenborinis (B.thuringiensis subsp.tenborinis) strain NB 176(SD-5428), Pasteurella puncture (Pasteurentans), Pasteurella sp (Pasteurella p.) (Rotylenchus reniformis) PR3 (ATCC accession number SD-5834), Streptomyces microflavus (Streptomyces microflavus) strain AQ6121 (QRD 31.013, NRB-50), Streptomyces flavus (Streptomyces 60606032).
Examples of fungi and yeasts are as follows:
beauveria bassiana (Beauveria bassiana), in particular the strain ATCC 74040, Chaetomium parviflora (Coniothyrium minitans), in particular the strain CON/M/91-8 (accession number DSM-9660), Lecanicillium spp (Lecanicillium spp.), in particular the strain HRO LEC 12, Verticillium lecanii (Lecanicillium lecanii) (previously known as Verticillium lecanii), in particular the strain KV01, Metarrhizium anisopliae (Metarrhizium anisopliae), in particular the strain F52(DSM3884/ATCC 90448), Pyrococcus nikowia, in particular the strain NRRL Y-30ola, Paecilomyces perennis (Paecilomyces fumosus) (new name: Paecilomyces fumosa (Isarvillea), in particular the strain ApoNRRL Y-30752), in particular the strain Paramicum flavum purpureus (ATCC 251), in P (P) in particular the strain Talavicularia purpurea sp.sp.251, in particular the strain Iridium sp.11, the strain Iridium Moniliensis (ATCC No. 20874), or Pseudomycin strain P11), in particular the strain, In particular strain V117b, Trichoderma atroviride (Trichoderma atroviride), in particular strain SC1 (accession number CBS 122089), Trichoderma harzianum (Trichoderma harzianum), in particular Trichoderma harzianum (T. harzianum rifai) T39 (accession number CNCM I-952).
Examples of viruses are as follows:
granule disease virus (GV) of codling moth (Adoxophyes orana), granule disease virus (GV) of codling moth (Cydia pomonella), Nuclear Polyhedrosis Virus (NPV) of Heliothis armigera (Helicoverpa armigera), Spodoptera exigua (Spodoptera exigua) mNPV, Spodoptera frugiperda (Spodoptera frugiperda) mNPV, African cotton leafworm (Aica cotton leaf moth) (Spodoptera littoralis) NPV.
Bacteria and fungi that are applied to plants or parts of plants or organs of plants in the form of "inoculum" and that, by their specific properties, enhance the growth and health of plants are likewise contained. Examples include the following bacteria and fungi:
agrobacterium species (Agrobacterium sp.), Rhizobium rhizogenes (Azospirillum caerulea), Rhizobium Azotobacter species (Azospirillum sp.), Rhizobium Azotobacter species (Azotobacter sp.), Rhizobium lentimorbus species (Bradyrhizobium sp.), Burkholderia species (Burkholderia sp.), especially Burkholderia cepacia (Burkholderia cepacia) (previously known as Pseudomonas cepacia (Pseudomonas cepacia)), Macrospora species (Gigaspora sp.) or Macrocystium mononthospora (Gigaspora monospora), Coccidioides species (Glomspora sp.), Ceratopsis species (Lactucola), Rhizobium pararhizobium (Rhizobium zobium), Rhizobium pararhizobium sp., Rhizobium sp., or (Rhizobium sp., Rhi, Boletus spp (Suillus spp.) and Streptomyces spp (Streptomyces spp.).
Examples of products formed from plant extracts and microorganisms, which contain proteins and secondary metabolites, include the following:
garlic (Allium sativum), Artemisia intermedia (Artemisia absinthium), azadirachtin (azadirachtin), BioKeeper WP, black cinnamon (Cassia nigricans), Celastrus angulatus (Celastrus angulus), Chenopodium ambrosioides (Chenopodium album), chitin, Armour-Zen, pteris excelsum (Dryopteris filix-mas), Equisetum arvense (Equisetum arvense), Fortune azalea, fungast, Heads (anadium quinoa) saponin extract), pyrethrum (pyrenthrum/pyrrothrin), Quassia quassima (Quassia amara), Quercus (Quercus), Quillaja (Quillaja), Regalia (reilia "Regalia" ("regalis") TM Examples of suitable ingredients include, but are not limited to, extracts of ecticides "), rotenone, ryanodine/ranine, comfrey (Symphytum officinale), Tanacetum vulgare (Tanacetum vulgare), thymol, triac 70, TriCon, tropaeolum (tropicum maju), Urtica dioica (Urtica), veratrine (Veratrin), mistletoe (Viscum album), cruciferae (Brassicaceae) extracts, in particular rapeseed powder or mustard seed powder.
The smectite group mineral of the present invention preferably includes montmorillonite, beidellite, nontronite, saponite, hectorite, sauconite, and stevensonite. Bentonite containing montmorillonite as a main component is also contained in the smectite group mineral of the present invention. The smectite mineral of the present invention is preferably bentonite.
The alkylnaphthalenesulfonic acid derivative of the present invention preferably includes a sodium salt of a naphthalenesulfonic acid-formaldehyde condensate, a sodium salt of an alkylnaphthalenesulfonic acid-formaldehyde condensate, and preferably a sodium salt of an alkylnaphthalenesulfonic acid-formaldehyde condensate.
The content of the alkylnaphthalenesulfonic acid derivative in the pesticidal granule composition of the present invention is preferably 0.1 to 2.0% by weight, more preferably 0.15 to 0.75% by weight, and even more preferably 0.2 to 0.6% by weight.
In the pesticidal granule composition of the present invention, the content ratio of the gelatinized starch is preferably 0.1 to 10% by weight, more preferably 0.2 to 5% by weight, and further preferably 0.5 to 3% by weight.
The content ratio of the smectite group mineral in the pesticidal granule composition of the present invention is preferably 1 to 50% by weight, more preferably 2 to 30% by weight, and even more preferably 3 to 20% by weight.
The pesticidal granule composition of the present invention may further contain an extender, a water-soluble binder, a surfactant, a solvent, a stabilizer, a granulation accelerator, a preservative, a coloring material, a pH adjuster, a perfume and the like as auxiliaries.
Examples of the extender include: clay, calcium carbonate, quartz sand and pulverized products thereof, diatomaceous earth, talc, Zeeklite, sericite, acid clay, activated clay, silica, pumice, zeolite, vermiculite, white carbon black, vitreous powder obtained by pulverizing hollow spheres of white sand, or other inorganic carriers, or water-insoluble organic carriers such as cellulose, pulp, rice hull, wood flour, starch, and soybean flour, or water-soluble solid carriers such as urea, lactose, sucrose, salt, mirabilite, and citric anhydride.
Examples of the water-soluble binder include: sodium carboxymethylcellulose, hydroxypropylmethylcellulose, methylcellulose, methylethylcellulose, hydroxypropylcellulose, sodium polyacrylate, tragacanth, polyvinylpyrrolidone, polyvinyl alcohol, dextrin, alginic acid, sodium alginate, and the like.
Examples of the surfactant include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants.
Examples of the nonionic surfactant include polyoxyalkylene alkyl ether, polyoxyalkylene alkylaryl ether, polyoxyalkylene allyl phenyl ether, polyoxyalkylene alkyl ester, polyoxyalkylene sorbitan alkylate, polyoxyalkylene phenyl ether polymer, polyoxyalkylene alkylene aryl phenyl ether, polyoxyalkylene alkylene glycol, and polyoxyethylene polyoxypropylene block polymer.
Examples of the anionic surfactant include lignosulfonate, alkylaryl sulfonate, dialkyl sulfosuccinate, polyoxyalkylene alkylaryl ether sulfate, alkylnaphthalene sulfonate, polyoxyalkylene allyl phenyl ether sulfate, lauryl sulfate, and the like.
Examples of the cationic surfactant include alkyltrimethylammonium salts, alkyldimethylbenzylammonium salts, and alkylpyridinium salts.
Examples of the amphoteric surfactant include dialkyl diaminoethyl betaine and alkyl dimethyl benzyl betaine. However, the surfactant usable in the present invention is not limited to these examples, and 1 or 2 or more kinds of surfactants can be used in combination without any problem.
Examples of the pH adjuster include citric acid, malic acid, phosphoric acid, sodium citrate, potassium citrate, magnesium oxide, sodium carbonate, sodium hydrogen carbonate, disodium hydrogen phosphate, dipotassium hydrogen phosphate, trisodium phosphate, potassium pyrophosphate, sodium pyrophosphate, or their aqueous solutions, anhydrous crystals, and the like. However, the pH adjusting agent usable in the present invention is not limited to these examples, and there is no problem even if 1 or 2 or more kinds are used in combination.
The pesticidal granule composition of the present invention can be produced by a production method known per se. For example, the desired pesticidal granules can be prepared by granulating the pesticidal active ingredient, the smectite mineral, the alphalated starch, the alkylnaphthalenesulfonic acid derivative, and if necessary, the extender, the water-soluble binder, the surfactant, the solvent, the stabilizer, the pH adjuster, the granulation accelerator, the preservative, the coloring agent, the perfume, and the like, together by a method such as a coating method or a kneading method.
In the case of the coated granule, the agricultural chemical active ingredient, the smectite mineral, the gelatinized starch, and the alkylnaphthalenesulfonic acid derivative may be contained in the coating layer or may be impregnated in the water-absorbent core.
In the case of producing the coated granule, for example, a mixed solution of water and a surfactant is added to and mixed with the granule core, and the obtained mixture is coated with a raw powder prepared by adding an agricultural chemical active ingredient, a smectite mineral, an alphalated starch, an alkylnaphthalenesulfonic acid derivative, and the above-mentioned adjuvants, followed by mixing and pulverization, followed by drying, if necessary, crushing, sieving, granule-sizing, and the like, to produce a desired agricultural chemical granule.
Examples of the particle core in the coated granule include calcium carbonate components such as limestone and marble, quartz sand, pumice, clay particles, and inorganic particles obtained by granulation.
On the other hand, in the case of producing the kneaded granule, the desired agricultural chemical granule can be produced by mixing the agricultural chemical active ingredient with the smectite mineral, the alphalated starch, the alkylnaphthalenesulfonic acid derivative, and the above-mentioned auxiliary agent, adding water to the mixture, sufficiently mixing or kneading the mixture, granulating the mixture, drying the obtained granulated product, and optionally crushing, sieving, granulating the dried product, or the like.
A kneader is used for the kneading. Examples of the kneading machine include universal mixer, kneader and Rhodizer
Figure BDA0003793350610000191
Mixers, vertical granulators, and the like.
The amount of water used in kneading is usually 5 to 20 parts by weight per 100 parts by weight of the mixture.
When the above-mentioned kneaded granule is produced, it is usually used
Figure BDA0003793350610000192
Preferably, it is
Figure BDA0003793350610000193
Is carried out with the screen of (1).
Examples of the pelletizer to be used include a screw-type extrusion pelletizer, a roll-type extrusion pelletizer, a disk-type extrusion pelletizer, a pellet press-type extrusion pelletizer, a basket-type extrusion pelletizer, a blade-type extrusion pelletizer, an oscillation-type extrusion pelletizer, a gear-type extrusion pelletizer, a ring-mode extrusion pelletizer and the like, and specifically, multigram MG-55-2; DALTON CORPORATION.
The obtained granules are dried at a temperature of usually 50 to 120 ℃ and preferably 60 to 80 ℃.
The pesticidal granule composition of the present invention can be applied at any time from before sowing to the time of transplanting.
In the application before sowing, for example, a method of mixing the pesticidal granule composition with bed soil, adding the mixture to a seedling box, and then sowing seeds is exemplified.
The application in sowing may be a method of spreading the solid agricultural chemical composition after sowing the seeds or before covering with soil.
In the application at the time of transplantation, for example, there is a method of spreading the pesticidal granule composition in a seedling raising box from several days before to the day of transplantation of seedlings into paddy fields or upland fields; a method of transplanting seedlings by a rice transplanter or the like and simultaneously spraying a solid agricultural chemical composition by a sprayer; and so on.
The pesticidal granule composition of the present invention may be applied to a nursery box by any method. For example, a spraying machine may be used in addition to the mixing with the bed soil as described above.
Examples of the seedling raising box that can be used in the method of the present invention include a seedling raising box for rice, a plug for horticultural crops (vegetables, fruit trees, flowers), and a plastic container.
The amount of the solid agricultural chemical composition applied to the rice seedling raising boxes by the method of the present invention is usually 10 to 200g, preferably 50 to 100g per one seedling raising box. When the culture medium is applied to a plastic container such as 448 holes (manufactured by Minoru industries, Ltd.) of a seedling box dedicated to Minoru potting system, the amount of the culture medium is usually 33 to 66g (1 to 2kg per 10 a) per container.
The pesticidal granule composition to be applied to the rice seedling raising box of the present invention can be obtained by a granulation method generally used for formulation of a pesticide. For example, the composition is prepared by adding an agricultural chemical active ingredient, an alkylnaphthalenesulfonic acid derivative, an alphalated starch, a smectite mineral, a surfactant, a water-soluble binder, a solvent, an auxiliary agent, an extender and the like as necessary, mixing and pulverizing the mixture by a vertical granulator (trade name manufactured by Powrex corporation), adding water and kneading the mixture to perform extrusion, granulating the mixture by the granulator, and drying the granulated mixture by a fluidized bed dryer to perform granulation. The powder mixture may be granulated by a rotary granulator while adding water thereto, and dried and granulated, or may be produced by a fluidized bed granulator which performs granulation by spraying a binder, an aqueous solution, an active ingredient, or the like while fluidizing the powder mixture.
The formulation which can be used for applying the granular material to the rice seedling raising box of the present invention is not limited as long as it is a solid preparation other than powder, such as granules, tablets, etc.
Examples
The present invention will be described in further detail with reference to production examples, comparative examples and test examples, but the present invention is not limited thereto.
Among the substances used in the present example, those which need to be specifically described are shown below.
Isotianil is a known compound, and can be produced, for example, by the method described in international publication No. 99/024413 pamphlet.
Penflufen is a known compound and can be produced, for example, by the method described in the pamphlet of international publication No. 2003/010149.
Tetratolanilide is a known compound, and is produced, for example, by the method described in the pamphlet of International publication No. 2011/157664.
Examples of the alkylnaphthalenesulfonic acid derivatives include Morwet D425 (manufactured by AKZO Nobel), TERSPERSE 2020 (manufactured by Huntsman), and Agrosurf WG-2300 (manufactured by Takara Shuzo Co., Ltd.).
Examples of the gelatinized Starch include Amycol HF, Amycol C, Amycol KF, Amycol HG-N, Amycol BJ-2, Amycol W, Starch MH-A, Amycol FW (manufactured by Nissan chemical Co., Ltd.), Alster (アルスター), Alster H, Waxy alpha (manufactured by Nippon food chemical Co., Ltd.), Corn Starch alpha Y, Corn Starch alpha S-1, cassava Starch alpha for industrial use, cassava Starch alpha TP-2 for industrial use, wheat Starch alpha-105 (manufactured by Sanko Starch industries, Ltd.), Amylox No.1, and Amylox No.1A (manufactured by Nippon Corn Starch Co., Ltd.).
The smectite group mineral includes montmorillonite, and examples thereof include bentonite such as fuji bentonite, scion high bentonite, red city bentonite, mianzyi bentonite, Super Clay (manufactured by Ho Jun corporation), Kunigel V1, Kunigel V2, Kunigel VA, Kunibond (manufactured by kukufeng corporation), and guanxi bentonite (manufactured by Kasanen corporation).
The solid components in the amounts shown in Table 1 were mixed by using a universal mixer (5 DM-L-03-r; DALTON CORPORATION), the liquid-soluble component was dissolved in an optimum amount of water (corresponding to 13.5% relative to the mixture), and then the mixture was added to the above mixture and further mixed/kneaded for 2 minutes, and then the mixture was extruded through a screen having a mesh opening of 1.0mm by using a pelletizer (MultiGran MG-55-2; manufactured by DALTON CORPORATION) to pelletize, and the pelletized product was dried at 80 ℃ by using a dryer (FD-LAB-1; manufactured by POWREX CORPORATION). Finally, the mixture was sieved using sieves with mesh sizes of 1.4mm and 0.5mm to obtain the pesticidal granule composition of the present invention and the pesticidal granule composition of the comparative example.
[ Table 1]
Composition (I) Example 1 Example 2 Comparative example 1
Isotianil 2.00 2.00 2.00
Pentopyram 2.00 2.00 2.00
Tetrazoxamide 1.50 1.50 1.50
Alpha starch 2.00 2.00 2.00
Alkyl naphthalene sulfonic acid formaldehyde condensate sodium salt 0.5 0.25 0
Sodium carboxymethyl cellulose 1.00 1.00 1.00
Polyoxyalkylene allyl phenyl ether sulfate sodium salt 2.00 2.00 2.00
Dialkyl sulfosuccinate salts 0.03 0.03 0.03
Smectite group mineral 15.0 15.0 15.0
Citric acid anhydride 0.30 0.30 0.30
White carbon black 1.14 1.14 1.14
Clay clay 72.53 72.78 73.03
Growth test for rice based on pre-treatment of covering soil during rice seeding
A small-sized rice seedling box (about 1/12 in the size of 30 cm. times.60 cm in the conventional seedling box) was used, and the test pellet composition was treated at a ratio of 8.3 g/seedling box before covering with soil at the time of sowing, and 12.5g of dry rice (variety: super polished rice) was sown. After germination for 66 hours in a seedling raising device (28 ℃ throughout the day), seedlings were raised on a seedling bed mattress (20 ℃) in a vinyl house. After 21 days of seedling raising, the root-cutting strength of rice (treated area) was measured. The rooting strength of the treated area and the rooting strength of the non-treated area are compared by the mathematical formula 1 to calculate the growth rate (%), and the growth state is evaluated according to the following criteria.
[ mathematical formula 1]
Figure BDA0003793350610000221
< criterion for growth Condition >)
Evaluation of Growth rate (%)
－－ More than 95 percent
－ More than 80 percent and less than 95 percent
+ More than 60 percent and less than 80 percent
[ Table 2]
Pesticide granule composition (Table 1) Growth rate (%) Growth rate determination
Example 1 103.4％ －－
Example 2 94.6％ －
Comparative example 1 77.0％ +
From the results of the above growth test on rice, it was confirmed that the pesticidal granule composition of the present invention has an excellent phytotoxicity reducing effect.

Claims (6)

1. A pesticide granule composition for rice seedling raising boxes is characterized by containing a pesticide active ingredient, an alkyl naphthalene sulfonic acid derivative, alpha starch and smectite minerals.
2. The pesticidal granule composition according to claim 1, wherein the content ratio of the pesticidal active ingredient is 1 to 30% by weight.
3. The pesticidal granule composition according to claim 1 or 2, wherein the content ratio of the alkylnaphthalenesulfonic acid derivative is from 0.1% by weight to 2.0% by weight.
4. The pesticidal granule composition according to any one of claims 1 to 3, wherein the content ratio of the gelatinized starch is 0.1 to 10% by weight.
5. A pesticidal granule composition according to any one of claims 1 to 4 wherein the smectite mineral is bentonite.
6. The pesticidal granule composition according to any one of claims 1 to 5, wherein the smectite mineral is contained in a proportion of 1 to 50% by weight.
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JP2017039650A (en) * 2015-08-18 2017-02-23 クミアイ化学工業株式会社 Agrochemical composition and usage thereof
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JP2017109963A (en) * 2015-12-17 2017-06-22 クミアイ化学工業株式会社 Manufacturing method of particulate agrochemical composition

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