CN115109382B - 一种稀土增强酚醛防火泡沫板 - Google Patents
一种稀土增强酚醛防火泡沫板 Download PDFInfo
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- CN115109382B CN115109382B CN202210947742.XA CN202210947742A CN115109382B CN 115109382 B CN115109382 B CN 115109382B CN 202210947742 A CN202210947742 A CN 202210947742A CN 115109382 B CN115109382 B CN 115109382B
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- rare earth
- phenolic aldehyde
- foam board
- parts
- reinforced phenolic
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- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 48
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 47
- 239000006260 foam Substances 0.000 title claims abstract description 28
- -1 phenolic aldehyde Chemical class 0.000 title claims abstract description 22
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 24
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 21
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 21
- 239000010452 phosphate Substances 0.000 claims abstract description 21
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000005011 phenolic resin Substances 0.000 claims abstract description 18
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 18
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 14
- 239000004568 cement Substances 0.000 claims abstract description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000012792 core layer Substances 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 4
- 230000009471 action Effects 0.000 claims abstract description 3
- 239000002344 surface layer Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 239000004088 foaming agent Substances 0.000 claims description 15
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 229920002545 silicone oil Polymers 0.000 claims description 8
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 150000007522 mineralic acids Chemical class 0.000 claims description 6
- 150000007524 organic acids Chemical class 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 230000000977 initiatory effect Effects 0.000 claims description 3
- 238000010030 laminating Methods 0.000 claims description 3
- 238000005086 pumping Methods 0.000 claims description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 3
- WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 claims description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 238000004821 distillation Methods 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims description 2
- ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 229940044654 phenolsulfonic acid Drugs 0.000 claims description 2
- 238000010992 reflux Methods 0.000 claims description 2
- 229920001187 thermosetting polymer Polymers 0.000 claims description 2
- 230000009970 fire resistant effect Effects 0.000 claims 6
- 230000002265 prevention Effects 0.000 claims 1
- 230000003014 reinforcing effect Effects 0.000 claims 1
- 230000008021 deposition Effects 0.000 abstract description 5
- 239000002131 composite material Substances 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 9
- 239000003063 flame retardant Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 239000012774 insulation material Substances 0.000 description 4
- 229920005830 Polyurethane Foam Polymers 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000011496 polyurethane foam Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 239000012796 inorganic flame retardant Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229940098779 methanesulfonic acid Drugs 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 239000011489 building insulation material Substances 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
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Abstract
本发明涉及防火材料技术领域,特别涉及一种稀土增强酚醛防火泡沫板。一种稀土增强酚醛防火泡沫板,包括稀土增强酚醛芯层及水泥基面层;所述稀土增强酚醛芯层由稀土改性醇溶性磷酸盐、氧化铝、酚醛树脂及聚乙二醇在助剂作用下固化而得。本发明提供的稀土增强酚醛防火泡沫板,采用稀土改性醇溶性磷酸盐提高防火性能,分散均匀,不会出现沉积的问题。同时采用复合的乳化剂,进一步防止分层现象的出现。最终制得的稀土增强酚醛防火泡沫板防火性能好,韧性及抗压强度高,具有良好的应用价值。
Description
技术领域
本发明涉及防火材料技术领域,特别涉及一种稀土增强酚醛防火泡沫板。
背景技术
大量的无机或有机建筑保温材料广泛应用于建筑物的外墙结构。对人们所居住的建筑物而言,防火安全问题始终应该列于首位。
现有技术中,传统的保温材料,如聚苯乙烯(PS)和聚氨酯(PU)泡沫等,聚苯乙烯泡沫因其具有的价格较低、保温隔热性优良、吸水性小、水蒸气渗透性低、吸收冲击性好等优点而被大量用于建筑保温材料领域,但其自身的阻燃性较差,因此,近年来各行各业使用渐少;聚氨酯泡沫是隔热性能最好的保温材料之一,同时还具有不吸水的优点,但其价格较为昂贵、自身的阻燃性也较差,且燃烧时会释放出大量的有毒气体,这些因素很大程度上限制了其在建筑物外墙保温材料领域的应用。
鉴于此,公开号为CN111732814A,公告日为2020年10月02日,公开了《一种高性能防火阻燃酚醛泡沫及其制备方法》,所述高性能防火阻燃酚醛泡沫包括无机阻燃材料,与酚醛树脂、聚乙二醇、乳化剂以及发泡剂混合后加入固化剂,制备而得;其中,所述无机阻燃材料采用采用氢氧化铝、二氧化铈和二氧化硅按照10~25:5~10:8~25混合而得,通过特定比例的有机酸和无机酸进行混合(有机酸:无机酸的比例为1:3)作为固化剂,使得制备得到的酚醛泡沫测得火蔓延指数为0,烟指数降低到35,同时,测得导热系数≤0.023W/m·k,所述高性能防火阻燃酚醛泡沫在具有良好保温性能的同时,达到更高要求的防火阻燃效果。
虽然上述方案制备得到的高性能防火阻燃酚醛泡沫的导热系数高,防火阻燃效果好,但是其采用的无机填料固化过程中存在沉积、分布不均的问题,导致固化后的泡沫存在局部阻燃效果差的问题。
发明内容
为解决上述现有技术中防火无机填料固化过程中存在沉积、分布不均的问题,本发明提供一种稀土增强酚醛防火泡沫板,包括稀土增强酚醛芯层及水泥基面层。
所述稀土增强酚醛芯层由稀土改性醇溶性磷酸盐、氧化铝、酚醛树脂及聚乙二醇在助剂作用下固化而得。
在一些实施例中,所述酚醛树脂为热固性酚醛树脂。
在一些实施例中,所述水泥基面层由玻璃纤维丝或玻璃纤维网格,复合水泥、细砂、高分子乳液制得。
在一些实施例中,所述稀土改性醇溶性磷酸盐的制备过程为:在反应容器中加入85%磷酸溶液,升温至70℃后,恒温搅拌并缓慢加入氢氧化铝,然后将温度升高至90℃,逐滴加入氯化镧的乙醇溶液,恒温下冷凝回流5h,转移至旋转蒸发仪减压蒸馏2h,制得预聚物晶体,烘干后研磨,加入乙醇溶解,制得稀土改性醇溶性磷酸盐预聚物。
在一些实施例中,所述助剂包括乳化剂、发泡剂及固化剂。
在一些实施例中,所述固化剂为有机酸和无机酸的混合酸按照1:3的混合。
在一些实施例中,所述有机酸为甲基磺酸、苯酚磺酸、对甲苯磺酸的一种或组合。所述无机酸为磷酸。
在一些实施例中,所述乳化剂为EL-30与EL50中至少1种与硅油的组合。所述硅油占所述乳化剂总质量的40%~70%。
在一些实施例中,所述发泡剂为正戊烷,正己烷,环戊烷,环己烷中的一种或组合。
在一些实施例中,所述酚醛树脂100份。聚乙二醇5-18份。固化剂10-20份。氧化铝10-25份。稀土改性醇溶性磷酸盐10-15份。乳化剂10-15份。发泡剂8-16份。
本发明还提供一种制备如上任意所述的稀土增强酚醛防火泡沫板的制备方法,步骤如下:
S100、在搅拌罐(A料罐)中加入酚醛树脂、聚乙二醇、发泡剂、乳化剂、稀土改性醇溶性磷酸盐及氧化铝搅拌均匀。
S200、将配置好的固化剂倒入固化剂罐(B料罐)中。
S300、在流水线前端在流水线前端部分先将下层水泥基卷材放置在下层放卷架上,上层水泥基卷材放置在上层放卷架上。
S400、烘房温度提前升至60~75℃。
S500、将A\B料罐的料液抽至浇筑头快速搅拌后,将料液浇注在两块板之间,进入层压机起发、固化成型。
基于上述,与现有技术相比,本发明提供的稀土增强酚醛防火泡沫板,采用稀土改性醇溶性磷酸盐提高防火性能,分散均匀,不会出现沉积的问题。同时采用复合的乳化剂,进一步防止分层现象的出现。最终制得的稀土增强酚醛防火泡沫板防火性能好,韧性及抗压强度高,具有良好的应用价值。
本发明的其它特征和有益效果将在随后的说明书中阐述,并且,部分地从说明书中变得显而易见,或者通过实施本发明而了解。本发明的目的和其他有益效果可通过在说明书、权利要求书中所指出的结构和/或组分来实现和获得。
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例;下面所描述的本发明不同实施方式中所设计的技术特征只要彼此之间未构成冲突就可以相互结合;基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
在本发明的描述中,需要说明的是,本发明所使用的所有术语(包括技术术语和科学术语)具有与本发明所属领域的普通技术人员通常所理解的含义相同的含义,不能理解为对本发明的限制;应进一步理解,本发明所使用的术语应被理解为具有与这些术语在本说明书的上下文和相关领域中的含义一致的含义,并且不应以理想化或过于正式的意义来理解,除本发明中明确如此定义之外。
实施例1
S100、在搅拌罐(A料罐)中加入酚醛树脂、聚乙二醇、发泡剂、乳化剂、稀土改性醇溶性磷酸盐及氧化铝搅拌均匀。
S200、将配置好的固化剂倒入固化剂罐(B料罐)中。
S300、在流水线前端在流水线前端部分先将下层水泥基卷材放置在下层放卷架上,上层水泥基卷材放置在上层放卷架上。
S400、烘房温度提前升至70℃。
S500、将A\B料罐的料液抽至浇筑头快速搅拌后,将料液浇注在两块板之间,进入层压机起发、固化成型。
以质量份数计,各组配比为:酚醛树脂100份,聚乙二醇5份,固化剂10份,氧化铝10份,稀土改性醇溶性磷酸盐10份,乳化剂10份,发泡剂8份。
发泡剂为正戊烷,乳化剂为40%的硅油与60%EL-30的组合,固化剂为甲基磺酸与磷酸的组合,甲基磺酸与磷酸的质量比为1:3。
实施例2
与实施例1相比,区别点在于酚醛树脂100份,聚乙二醇18份,固化剂20份,氧化铝25份,稀土改性醇溶性磷酸盐15份,乳化剂15份,发泡剂16份。
其余组分、配比及制备步骤与实施例1相同。
实施例3
与实施例1相比,区别点在于酚醛树脂100份,聚乙二醇12份,固化剂15份,氧化铝18份,稀土改性醇溶性磷酸盐12份,乳化剂12份,发泡剂12份。
其余组分、配比及制备步骤与实施例1相同。
对比例1
与实施例1相比,区别点在于酚醛树脂100份,聚乙二醇20份,固化剂25份,氧化铝30份,稀土改性醇溶性磷酸盐20份,乳化剂20份,发泡剂20份。
其余组分、配比及制备步骤与实施例1相同。
对比例2
与实施例1相比,区别点在于酚醛树脂100份,聚乙二醇3份,固化剂8份,氧化铝8份,稀土改性醇溶性磷酸盐5份,乳化剂8份,发泡剂5份。
其余组分、配比及制备步骤与实施例1相同。
对比例3
与实施例1相比,区别点在于乳化剂仅为硅油。
其余组分、配比及制备步骤与实施例1相同。对比例3在生产过程中出现分层现象,生产所得产品质量不合格。
对比例4
与实施例1相比,区别点在于稀土改性醇溶性磷酸盐替换为6份氧化镧及6份磷酸铝的组合。
其余组分、配比及制备步骤与实施例1相同。
需要说明的是,上述实施例中的具体参数或一些常用试剂,为本发明构思下的具体实施例或优选实施例,而非对其限制。本领域技术人员在本发明构思及保护范围内,可以进行适应性调整。
此外,若无特殊说明,所采用的原料也可以为本领域常规市售产品、或者由本领域常规方法制备得到。
对实施例及对比例进行性能测试,测试项目及方法见表1,测试结果见表2。
表1测试项目及方法
防火性能 | GB8624 |
韧性(拉拔强度) | GB20974 |
抗压强度 | GB20974 |
表2测试结果
实施例1 | 实施例2 | 实施例3 | 对比例1 | 对比例2 | 对比例3 | 对比例4 | |
防火性能 | A2 | A2 | A2 | B1 | B1 | - | B2 |
韧性(拉拔强度) | 0.15 | 0.13 | 0.20 | 0.11 | 0.12 | - | 0.15 |
抗压强度 | 0.12 | 0.14 | 0.15 | 0.10 | 0.13 | - | 0.12 |
综上所述,与现有技术相比,本发明提供的稀土增强酚醛防火泡沫板,采用稀土改性醇溶性磷酸盐提高防火性能,分散均匀,不会出现沉积的问题。同时采用复合的乳化剂,进一步防止分层现象的出现。最终制得的稀土增强酚醛防火泡沫板防火性能好,韧性及抗压强度高,具有良好的应用价值。
另外,本领域技术人员应当理解,尽管现有技术中存在许多问题,但是,本发明的每个实施例或技术方案可以仅在一个或几个方面进行改进,而不必同时解决现有技术中或者背景技术中列出的全部技术问题。本领域技术人员应当理解,对于一个权利要求中没有提到的内容不应当作为对于该权利要求的限制。
尽管本文中较多的使用了诸如稀土增强酚醛芯层、水泥基面层等术语,但并不排除使用其它术语的可能性。使用这些术语仅仅是为了更方便地描述和解释本发明的本质;把它们解释成任何一种附加的限制都是与本发明精神相违背的;本发明实施例的说明书和权利要求书中的术语“第一”、“第二”、等(如果存在)是用于区别类似的对象,而不必用于描述特定的顺序或先后次序。
最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。
Claims (8)
1.一种稀土增强酚醛防火泡沫板,其特征在于:包括稀土增强酚醛芯层及水泥基面层;
所述稀土增强酚醛芯层由稀土改性醇溶性磷酸盐、氧化铝、酚醛树脂及聚乙二醇在助剂作用下固化而得;所述助剂包括乳化剂、发泡剂及固化剂;
所述乳化剂为EL-30与EL-50中至少1种与硅油的组合;所述硅油占所述乳化剂总质量的40%~70%。
2.根据权利要求1所述的稀土增强酚醛防火泡沫板,其特征在于:所述酚醛树脂为热固性酚醛树脂。
3.根据权利要求1所述的稀土增强酚醛防火泡沫板,其特征在于:所述稀土改性醇溶性磷酸盐的制备过程为:在反应容器中加入85%磷酸溶液,升温至70℃后,恒温搅拌并缓慢加入氢氧化铝,然后将温度升高至90℃,逐滴加入氯化镧的乙醇溶液,恒温下冷凝回流5h,转移至旋转蒸发仪减压蒸馏2h,制得预聚物晶体,烘干后研磨,加入乙醇溶解,制得稀土改性醇溶性磷酸盐预聚物。
4.根据权利要求3所述的稀土增强酚醛防火泡沫板,其特征在于:所述固化剂为有机酸和无机酸的混合酸按照1:3的混合。
5.根据权利要求4所述的稀土增强酚醛防火泡沫板,其特征在于:所述有机酸为甲基磺酸、苯酚磺酸、对甲苯磺酸的一种或组合;所述无机酸为磷酸。
6.根据权利要求3所述的稀土增强酚醛防火泡沫板,其特征在于:所述发泡剂为正戊烷,正己烷,环戊烷,环己烷中的一种或组合。
7.根据权利要求3所述的稀土增强酚醛防火泡沫板,其特征在于:所述酚醛树脂100份;聚乙二醇5-18份;固化剂10-20份;氧化铝10-25份;稀土改性醇溶性磷酸盐10-15份;乳化剂10-15份;发泡剂8-16份。
8.一种稀土增强酚醛防火泡沫板的制备方法,其特征在于,步骤如下:
S100、在搅拌罐A料罐中加入酚醛树脂、聚乙二醇、发泡剂、乳化剂、稀土改性醇溶性磷酸盐及氧化铝搅拌均匀;所述乳化剂为EL-30与EL-50中至少1种与硅油的组合;所述硅油占所述乳化剂总质量的40%~70%;
S200、将配置好的固化剂倒入固化剂罐B料罐中;
S300、在流水线前端部分先将下层水泥基卷材放置在下层放卷架上,上层水泥基卷材放置在上层放卷架上;
S400、烘房温度提前升至60~75℃;
S500、将A\B料罐的料液抽至浇筑头快速搅拌后,将料液浇注在两块板之间,进入层压机起发、固化成型。
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5667341A (en) * | 1979-11-07 | 1981-06-06 | Sumitomo Bakelite Co Ltd | Phenolic resin foam |
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Publication number | Priority date | Publication date | Assignee | Title |
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