CN115043644B - Ceramic hand mold with anti-static function and preparation process thereof - Google Patents

Ceramic hand mold with anti-static function and preparation process thereof Download PDF

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CN115043644B
CN115043644B CN202210387573.9A CN202210387573A CN115043644B CN 115043644 B CN115043644 B CN 115043644B CN 202210387573 A CN202210387573 A CN 202210387573A CN 115043644 B CN115043644 B CN 115043644B
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powder
mixture
parts
ceramic hand
hand mold
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CN115043644A (en
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乔栓虎
谭洪波
袁国梁
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Shandong Electric Shield Polytron Technologies Inc
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Shandong Electric Shield Polytron Technologies Inc
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    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
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Abstract

The invention relates to a ceramic hand mould with an antistatic function and a preparation process thereof, wherein the ceramic hand mould comprises the following steps: glass powder, turpentine, butyl carbitol acetate, thickening agent, fluidity control agent, cdO and In 2 O 3 、Ti 2 O 3 、SnO 2 、MoO 3 . The preparation process comprises the following steps: (1) Mixing CdO and In 2 O 3 、Ti 2 O 3 、SnO 2 、MoO 3 And uniformly stirring after mixing to obtain a mixture A. (2) Mixing the glass powder, turpentine, butyl carbitol acetate, the thickening agent and the fluidity control agent, and then uniformly stirring to obtain a mixture B. (3) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, and pressing and forming the obtained wet mixture and then firing to obtain the ceramic hand mold. According to the ceramic hand mold disclosed by the invention, by redesigning the formula, the prepared ceramic hand mold has good antistatic performance, is not easy to leave dirt on the surface, is convenient to clean, and effectively improves the quality of the ceramic hand mold.

Description

Ceramic hand mold with anti-static function and preparation process thereof
Technical Field
The invention relates to the field of glove production, in particular to a ceramic hand mold with an anti-static function and a preparation process thereof.
Background
The hand mold is a forming mold for producing gloves such as PVC, latex, butyronitrile and the like. In the production process, the hand die is continuously operated for a long time, dirt is prevented from being adhered to the hand die, and simultaneously, corn starch is adsorbed by static electricity, when the edge rolling roller is improperly adjusted, materials are adhered to the die while being hung on the edge rolling roller, the materials are brought into a material groove if the materials are not cleaned in time, the gloves have the defects of material adhesion, pinholes, two points and the like, and the yield is seriously influenced.
In order to overcome the problem that static electricity is easily generated in the use process of the hand model, a method of doping a conductive material into the hand model is generally adopted, and the generated static electricity is conducted out in time, so that the accumulation of static charges on the surface of the hand model is avoided. The conventional conductive materials include powders of metals, metal oxides, metal salts, metal alloys, and the like. However, the hand mold prepared by the conventional method still has unsatisfactory antistatic performance, has a problem that dirt is easily adhered to the surface, is not easily cleaned, affects the production efficiency of gloves, and reduces the yield of gloves.
Disclosure of Invention
Aiming at the problems, the invention provides the ceramic hand mould with the anti-static function and the preparation process thereof. In order to achieve the purpose, the invention discloses the following technical scheme:
in a first aspect of the invention, a ceramic hand model with an antistatic function is disclosed, which comprises the following raw materials in parts by weight: 25 to 35 portions of glass powder, 10 to 15 portions of turpentine, 3 to 6 portions of butyl carbitol acetate, 0.5 to 1.2 portions of thickening agent, 1 to 2 portions of fluidity control agent, 1.7 to 2.1 portions of CdO powder, in 2 O 3 1.5 to 2.8 portions of powder and Ti 2 O 3 2-2.5 parts of powder and SnO 2 2.4 to 3.6 portions of powder and MoO 3 0.6 to 1.3 portions of powder.
Furthermore, the glass powder comprises any one of boron-silicon-lead glass powder, high-boron-silicon glass powder and the like, and the ceramic hand mold with high strength and good thermal stability can be obtained after the glass powder is used as a main material and is fired.
Further, the thickener includes any one of ethyl cellulose, nitrocellulose, and the like.
Further, the fluidity controlling agent is an acrylic copolymer such as polyacrylamide, etc. In the present invention, the fluidity acts to promote the surface smoothness of the hand mold and to reduce the adhesion of dirt.
Further, the CdO powder and In 2 O 3 Powder, ti 2 O 3 Powder, snO 2 Powder, moO 3 The powder is nano powder, so thatThe anti-static function and the surface smoothness of the hand model are increased, and the adhesion of dirt is reduced.
Furthermore, the raw material of the ceramic hand model also comprises 1.5 to 3 weight parts of surfactant. Optionally, the surfactant comprises: stearic acid, sodium dodecylbenzenesulfonate, glyceryl monostearate, etc.
In a second aspect of the present invention, a preparation process of the ceramic hand mold with the antistatic function is disclosed, which comprises the following steps:
(1) Mixing the CdO powder and In 2 O 3 Powder, ti 2 O 3 Powder, snO 2 Powder, moO 3 The powder is mixed and stirred evenly to obtain a mixture A for standby.
(2) And mixing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent, and then uniformly stirring to obtain a mixture B.
(3) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, and pressing and forming the obtained wet mixture and then firing to obtain the ceramic hand mold.
Further, in the step (1), the stirring time is 10-30 min, so that the materials are fully and uniformly mixed.
Further, in the step (2), the stirring time is 35-60 min, so that the materials are fully and uniformly mixed.
Further, in the step (3), the firing temperature is 1250 to 1380 ℃ and the time is 2.5 to 4 hours.
Compared with the prior art, the invention has the following beneficial effects: according to the ceramic hand mold disclosed by the invention, by redesigning the formula, the prepared ceramic hand mold has good antistatic performance, is not easy to leave dirt on the surface, is convenient to clean, and effectively improves the quality of the ceramic hand mold. In the invention, cdO and In are used 2 O 3 、Ti 2 O 3 、SnO 2 、MoO 3 The compound of the components is a composite conductive agent, and the metal oxide components are mutually cooperated, so that the excellent antistatic performance of the ceramic hand model is ensured, and the surface of the ceramic hand model is not easy to be combined with the surface of the ceramic hand model in the using processDirt is bonded, and the self-cleaning function of the ceramic hand mold is improved. In addition, the addition of butyl carbitol acetate ensures that the surface of the ceramic hand mold is smooth, reduces the surface roughness and improves the self-cleaning function of the ceramic hand mold.
Detailed Description
It is to be understood that the following detailed description is exemplary and is intended to provide further explanation of the invention as claimed. The invention will now be further illustrated by specific examples.
Example 1
A preparation process of a ceramic hand mold with an anti-static function comprises the following steps:
(1) Preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, in 2 O 3 2.2 parts of nano powder and Ti 2 O 3 2.5 parts of nano powder and SnO 2 3.0 parts of nano powder and MoO 3 And 1.1 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, ti 2 O 3 Nano powder and SnO 2 Nano powder, moO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And (3) placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer, and stirring for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring the formed wet mixed material into a heating furnace, firing the mixture at 1300 ℃ for 3 hours, and cooling the mixture to room temperature along with the furnace after the firing is finished to obtain the ceramic hand mold.
Example 2
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) Preparing raw materials: accurately weighing the following components in parts by weight by using a balanceThe components of (A): 35 parts of high borosilicate glass powder, 15 parts of turpentine, 3 parts of butyl carbitol acetate, 1.2 parts of nitrocellulose, 2.0 parts of polyacrylamide, 2.1 parts of CdO nano powder, in 2 O 3 2.8 parts of nano powder and Ti 2 O 3 2.0 parts of nano powder and SnO 2 2.4 parts of nano powder and MoO 3 And 1.3 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, ti 2 O 3 Nano powder and SnO 2 Nano powder, moO 3 And (3) placing the nano powder into a mixer, and stirring for 30min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 60min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixture into a hand mould, applying pressure of 40MPa to press and form, transferring the mixture into a heating furnace, firing at 1380 ℃ for 2.5 hours, and cooling to room temperature along with the furnace to obtain the ceramic hand mould.
Example 3
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) Preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 25 parts of high borosilicate glass powder, 10 parts of turpentine, 6 parts of butyl carbitol acetate, 0.5 part of nitrocellulose, 1.0 part of polyacrylamide, 1.7 parts of CdO nano powder, in 2 O 3 1.5 parts of nano powder and Ti 2 O 3 2.3 parts of nano powder and SnO 2 3.6 parts of nano powder and MoO 3 0.6 part of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, ti 2 O 3 Nano powder and SnO 2 Nano powder, moO 3 And (3) placing the nano powder into a mixer, and stirring for 10min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 35min to obtain a mixture B.
(4) Adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring into a heating furnace, firing at 1250 ℃ for 4 hours, and cooling to room temperature along with the furnace after finishing, thus obtaining the ceramic hand mold.
Example 4
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) Preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 28 parts of high borosilicate glass powder, 11 parts of turpentine, 5 parts of butyl carbitol acetate, 1.0 part of nitrocellulose, 1.3 parts of polyacrylamide, 1.5 parts of sodium dodecyl benzene sulfonate, 1.8 parts of CdO nano powder, in 2 O 3 2.1 parts of nano powder and Ti 2 O 3 2.0 parts of nano powder and SnO 2 3.3 parts of nano powder and MoO 3 And 1.0 part of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, ti 2 O 3 Nano powder and SnO 2 Nano powder, moO 3 And (3) placing the nano powder in a mixer, and stirring for 20min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 40min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand die mold, then applying pressure of 40MPa to press and mold, transferring the mixture into a heating furnace, firing the mixture at 1350 ℃ for 3.5 hours, and cooling the mixture to room temperature along with the furnace to obtain the ceramic hand die.
Example 5
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) Preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 32 parts of high borosilicate glass powder, 14 parts of turpentine and 4.5 parts of butyl carbitol acetate1.1 parts of nitrocellulose, 2.0 parts of polyacrylamide, 3.0 parts of glycerin monostearate, 1.9 parts of CdO nano powder and In 2 O 3 2.5 parts of nano powder and Ti 2 O 3 2.5 parts of nano powder and SnO 2 3.5 parts of nano powder and MoO 3 0.7 part of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, ti 2 O 3 Nano powder and SnO 2 Nano powder, moO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 45min to obtain a mixture B.
(4) Adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring into a heating furnace, firing at 1350 ℃ for 3.5 hours, and cooling to room temperature along with the furnace after firing to obtain the ceramic hand mold.
Example 6
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) Preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, ti 2 O 3 2.5 parts of nano powder and SnO 2 3.0 parts of nano powder and MoO 3 And 1.1 parts of nano powder.
(2) Putting the In 2 O 3 Nano powder, ti 2 O 3 Nano powder and SnO 2 Nano powder, moO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring the formed wet mixed material into a heating furnace, firing the mixture at 1300 ℃ for 3 hours, and cooling the mixture to room temperature along with the furnace after the firing is finished to obtain the ceramic hand mold.
Example 7
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) Preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, ti 2 O 3 2.5 parts of nano powder and SnO 2 3.0 parts of nano powder and MoO 3 And 1.1 parts of nano powder.
(2) Mixing the CdO nano powder and Ti 2 O 3 Nano powder and SnO 2 Nano powder, moO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring the formed wet mixed material into a heating furnace, firing the mixture at 1300 ℃ for 3 hours, and cooling the mixture to room temperature along with the furnace after the firing is finished to obtain the ceramic hand mold.
Example 8
A preparation process of a ceramic hand mold with an anti-static function comprises the following steps:
(1) Preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, in 2 O 3 2.2 parts of nano powder and SnO 2 3.0 parts of nano powder and MoO 3 And 1.1 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder and SnO 2 Nano powder, moO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring the formed wet mixed material into a heating furnace, firing the mixture at 1300 ℃ for 3 hours, and cooling the mixture to room temperature along with the furnace after the firing is finished to obtain the ceramic hand mold.
Example 9
A preparation process of a ceramic hand mold with an anti-static function comprises the following steps:
(1) Preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, in 2 O 3 2.2 parts of nano powder and Ti 2 O 3 2.5 parts of nano powder, moO 3 And 1.1 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, ti 2 O 3 Nano powder and SnO 2 Nano powder, moO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And (3) placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer, and stirring for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring the formed wet mixed material into a heating furnace, firing the mixture at 1300 ℃ for 3 hours, and cooling the mixture to room temperature along with the furnace after the firing is finished to obtain the ceramic hand mold.
Example 10
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) Preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, in 2 O 3 2.2 parts of nano powder and Ti 2 O 3 2.5 parts of nano powder and SnO 2 3.0 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, ti 2 O 3 Nano powder and SnO 2 Nano powder, moO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring the formed wet mixed material into a heating furnace, firing the mixture at 1300 ℃ for 3 hours, and cooling the mixture to room temperature along with the furnace after the firing is finished to obtain the ceramic hand mold.
Example 11
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) Preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder and In 2 O 3 2.2 parts of nano powder and Ti 2 O 3 2.5 parts of nano powder and SnO 2 3.0 parts of nano powder and MoO 3 And 1.1 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, ti 2 O 3 Nano powder, snO 2 Nano powder, moO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And (3) placing the glass powder, the turpentine, the thickening agent and the fluidity control agent into a mixer, and stirring for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring the formed wet mixed material into a heating furnace, firing the mixture at 1300 ℃ for 3 hours, and cooling the mixture to room temperature along with the furnace after the firing is finished to obtain the ceramic hand mold.
Performance testing
The surface resistance (according to the standard: ANSI/ESD 541-2008) and surface roughness of the ceramic hand mold prepared in each of the above examples were measured to measure the antistatic ability and self-cleaning ability of the ceramic hand mold, and the results are shown in tables 1 and 2.
TABLE 1
Example number 1 2 3 4 5 6
Surface resistance 3.6×10 6 4.4×10 6 4.9×10 6 6.1×10 6 5.8×10 6 8.8×10 7
Roughness/mum 0.27 0.33 0.31 0.23 0.26 0.54
TABLE 2
Example number 7 8 9 10 11
Surface resistance 1.4×10 8 6.6×10 7 2.4×10 8 3.7×10 8 6.9×10 6
Roughness/mum 0.72 0.58 0.69 0.63 0.47
As can be seen from the test results In tables 1 and 2, the surface resistance of the ceramic hand molds obtained In examples 6 to 10 is generally higher than that of examples 1 to 5, which indicates that CdO and In are used 2 O 3 、Ti 2 O 3 、SnO 2 、MoO 3 After the compound is a composite conductive agent, the metal oxide components are matched with each other in a synergistic manner, so that the antistatic performance of the ceramic hand mold can be obviously improved, and the ceramic hand mold can be an excellent antistatic body. Meanwhile, the composite conductive agent and the butyl carbitol acetate are added, so that the roughness of the surface of the ceramic hand mold is obviously reduced, and the self-cleaning function of the ceramic hand mold is improved.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (12)

1. The ceramic hand model with the antistatic function is characterized by comprising the following raw materials in parts by weight: 25 to 35 parts of glass powder, 10 to 15 parts of turpentine, 3 to 6 parts of butyl carbitol acetate, 0.5 to 1.2 parts of thickening agent, 1 to 2 parts of fluidity control agent, 1.7 to 2.1 parts of CdO powder, in 2 O 3 1.5 to 2.8 portions of powder and Ti 2 O 3 2 to 2.5 parts of powder and SnO 2 2.4 to 3.6 parts of powder and MoO 3 0.6 to 1.3 portions of powder.
2. The ceramic hand mold with the antistatic function according to claim 1, wherein the glass powder comprises any one of boron-silicon-lead glass powder and high-boron-silicon glass powder.
3. The ceramic hand mold with the antistatic function according to claim 1, wherein the thickener comprises any one of ethyl cellulose and nitrocellulose.
4. The ceramic hand mold with antistatic function as claimed in claim 1, wherein the fluidity controlling agent is propylene copolymer.
5. The ceramic hand mold with antistatic function as claimed in claim 4, wherein the propylene-based copolymer is polyacrylamide.
6. The ceramic hand mold with antistatic function as claimed In claim 1, wherein the CdO powder and In are 2 O 3 Powder, ti 2 O 3 Powder, snO 2 Powder, moO 3 The powder is nanometer powder.
7. The ceramic hand mould with the antistatic function as claimed in any one of claims 1 to 6, wherein the raw material of the ceramic hand mould further comprises 1.5 to 3 parts by weight of a surfactant.
8. The ceramic hand mold with antistatic function as claimed in claim 7, wherein the surfactant comprises: any one of stearic acid, sodium dodecyl benzene sulfonate and glyceryl monostearate.
9. The process for preparing the ceramic hand mold with the antistatic function according to any one of claims 1 to 7, characterized by comprising the steps of:
(1) Mixing the CdO powder and In 2 O 3 Powder, ti 2 O 3 Powder, snO 2 Powder, moO 3 Mixing the powders, and stirring to obtain mixture A;
(2) Mixing the glass powder, turpentine, butyl carbitol acetate, a thickening agent and a fluidity control agent, and then uniformly stirring to obtain a mixture B;
(3) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, and pressing and forming the obtained wet mixture and then firing to obtain the ceramic hand mold.
10. The preparation process of the ceramic hand mold with the antistatic function, according to claim 9, is characterized in that in the step (1), the stirring time is 10 to 30min.
11. The preparation process of the ceramic hand mold with the antistatic function, according to claim 9, is characterized in that in the step (2), the stirring time is 35 to 60min.
12. The process for preparing the ceramic hand mold with the antistatic function according to any one of claims 9 to 11, wherein in the step (3), the firing temperature is 1250 to 1380 ℃ and the time is 2.5 to 4 hours.
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