CN110128099A - A kind of preparation method of compounded antistatic Ceramic Tiles - Google Patents
A kind of preparation method of compounded antistatic Ceramic Tiles Download PDFInfo
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- CN110128099A CN110128099A CN201910416461.XA CN201910416461A CN110128099A CN 110128099 A CN110128099 A CN 110128099A CN 201910416461 A CN201910416461 A CN 201910416461A CN 110128099 A CN110128099 A CN 110128099A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/36—Reinforced clay-wares
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention discloses a kind of preparation methods of compounded antistatic Ceramic Tiles, belong to building material technical field.The present invention first by kaolin, bentonite, perlite, silicon ash and dispersion liquid mixing and ball milling, is subsequently added into thickener, and calcium sulfate and calcium stearate continue ball milling, and compression molding obtains adobe；By calcium carbonate, zinc carbonate, sodium bicarbonate, aluminium oxide, cordierite, boron oxide, potassium oxide, sodium oxide molybdena, tin oxide, antimony oxide, vanadic anhydride, zinc oxide, modified additive, plants essential oil, surfactant, modified fibre, water, conch meal, isocyanates mixing and ball milling obtain glaze slurry；Glaze slurries are sprayed on adobe surface, dry, heat up step by step, are sintered, and calcining cools down to get compounded antistatic Ceramic Tiles.The compounded antistatic Ceramic Tiles of technical solution of the present invention preparation have the characteristics that excellent antistatic performance, have broad prospects in the development of building material technology industry.
Description
Technical field
The invention discloses a kind of preparation methods of compounded antistatic Ceramic Tiles, belong to building material technical field.
Background technique
With the development of modern science and technology, electrostatic phenomenon is general in the industries such as information industry, textile industry, space flight and aviation
Store-through exists, and is mainly used in hospital operating room, the energy, national defence, space flight, aviation, electronics, petrochemical industry information etc. and domestic life
Field is the current optimal antistatic material compatible with decoration.Electrostatic may be led in some sensitive instrumentations and place
Fatal harm, thus the prevention of electrostatic for have it is inflammable, using potential explosive material be for the building of internal structure
It is essential.When the sheet resistance of material reaches 105-109 Ω, the electrostatic of accumulation can be discharged as soon as possible, to reach
The effect of antistatic.However in the various places for needing antistatic, many materials such as ceramics, timber, glass, cement, coating,
Plastics, clothes, shoes etc. are insulating material, so that it is arrived the requirement of antistatic, it is necessary to reduce resistance.Compounded antistatic ceramics
Brick is a kind of novel anti-static product.Previous anti-static product, as: epoxy and melamine, PVC anti-static coatings,
The high molecular materials such as plate, anti-static rubber slab, with easy to aging, not wear-resisting, easy to pollute, durability and not good enough etc. lack of preventing fires
Point.And compounded antistatic Ceramic Tiles just overcome above-mentioned disadvantage.Meanwhile and having both that ceramic wall and floor bricks are wear-resisting, anti-pollution energy
The advantage that power is strong, decorative effect is preferable is the excellent substitute of the materials such as anti-static PVC, terrazzo, granite.It is existing anti-
Electrostatic ceramic mainly passes through prepared by blending method, that is, passes through and mix a certain amount of conductive filler in the base, then pass through calcining
And form composite conducting material.A kind of novel electrostatic prevention new product with exploitation future is the primary innovation of Wall or floor tile industry,
And antistatic industry will be pushed, along energy saving, circular economy is walked, the development of environmental protection production product has important realistic meaning
And far reaching significance.
Compounded antistatic Ceramic Tiles research and develop successfully thoroughly solves the problems, such as in puzzlement the world, with its stable static electricity resistance
Energy and excellent quality will the entire antistatic markets of specification.It is provided safeguard for production, the life of the mankind.
Compounded antistatic Ceramic Tiles have the advantage that not affected by environment, and entire body all has permanent, stable antistatic
Performance.Fine heat-resisting performance, high temperature resistant are constant up to 1200 DEG C of electric conductivity.Wear-resisting, corrosion-resistant, acid and alkali-resistance, resistance to greasy dirt, anti-flammability,
Impermeable is that other materials are incomparable.Ceramic quality, never aging.It is nontoxic, tasteless, radiationless, be green product.
Designs and varieties can be selected arbitrarily.Powder amount is small, and the clean quiet environmental requirement that can meet higher level is used cooperatively with caulking agent.It applies
Work is convenient, is suitble to use in various new and old buildings objects.
And conventional composite anti-static ceramic tile the problem of can not being further increased there is also antistatic performance.Therefore, how
The shortcomings that improving conventional composite anti-static ceramic tile is that it is promoted and is applied to wider to obtain the promotion of more high combination property
Wealthy field meets industrial production demand urgent problem to be solved.
Summary of the invention
The present invention solves the technical problem of: it can not be into one for conventional composite anti-static ceramic tile antistatic performance
The problem of step improves, provides a kind of preparation method of compounded antistatic Ceramic Tiles.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
A kind of preparation method of compounded antistatic Ceramic Tiles, specific preparation process is as follows:
(1) according to parts by weight, 40~60 parts of kaolin are successively taken, 20~30 parts of bentonites, 20~30 parts of perlites, 10~20
Part silicon ash, 60~80 parts of dispersion liquids, 10~20 parts of thickeners, 5~8 parts of calcium sulfate, 5~8 parts of calcium stearates, first by kaolin,
Bentonite, perlite, silicon ash and dispersion liquid mixing and ball milling, are subsequently added into thickener, and calcium sulfate and calcium stearate continue ball milling, mould
It is molded, obtain adobe；
(2) according to parts by weight, by 20~30 parts of calcium carbonate, 10~20 parts of zinc carbonates, 10~20 parts of sodium bicarbonates, 30~40 parts
Aluminium oxide, 5~8 parts of cordierites, 5~8 parts of boron oxides, 5~8 parts of potassium oxides, 5~8 parts of sodium oxide molybdenas, 5~8 parts of tin oxide, 5~8
Part antimony oxide, 5~8 parts of vanadic anhydrides, 5~8 parts of zinc oxide, 5~8 parts of modified additives, 5~8 parts of plants essential oils, 5
~8 parts of surfactants, 3~5 parts of modified fibres, 200~300 parts of water, 5~8 parts of conch meals, 5~8 parts of isocyanates, mixing
Ball milling obtains glaze slurry；
(3) glaze slurries are sprayed on adobe surface, dry, heat up step by step, are sintered, calcining, and cooling is to get compounded antistatic ceramics
Brick.
Step (1) is described to mix ultrasound with water 1:10~1:20 in mass ratio for graphene oxide, is subsequently added into ammonium hydroxide tune
PH to 8.6~8.9 is saved, is stirred, obtains dispersion liquid.
Step (1) thickener is TYLOSE 30000, any one in polyvinyl alcohol or carragheen.
Step (2) described modified additive the preparation method comprises the following steps: by (N- amidino groups) dodecylacrylamide and methoxyl group
Polyethylene glycol 1:1~2:1 in mass ratio mixing, and 0.1~0.2 times of methoxy poly (ethylene glycol) quality of paracide and first is added
The ferrocene of 0.07~0.10 times of oxygroup polyethylene glycol quality, is stirred to get modified additive.
Step (2) plants essential oil is Rosemary Oil, Lavender, rose ethereal oil, jasmine essential oil, camellia
Any one in essential oil or saussurea involucrata essential oil.
Step (2) surfactant is Tween-20, is appointed in octyl phenol polyoxyethylene ether or nonylphenol polyoxyethylene ether
It anticipates one kind.
Step (2) described modified fibre the preparation method comprises the following steps: according to parts by weight, by 20~30 parts of rice hull celluloses, 2~3
Part secondary settling tank sludge, 1~2 portion of sucrose, 30~50 parts of water mixed fermentations, filtering, a Freezing smashing, sieving obtain crushed material, connect
Crushed material and sodium hydroxide solution 1:10~1:20 constant temperature in mass ratio are impregnated, filter, washing, secondary Freezing smashing, mistake
Sieve, obtains modified fibre.
Step (2) conch meal is clam shell powder, any one in husky clam meal or shell powder.
Step (2) isocyanates is toluene di-isocyanate(TDI), methyl diphenylene diisocyanate or trimethyl cyclohexane
Any one in diisocyanate.
Step (3) the glaze slurries quantity for spray is 0.1~0.5g/cm2。
The beneficial effects of the present invention are:
(1) present invention passes through addition sodium bicarbonate, modified additive, modified fibre and zinc carbonate, firstly, in use,
Molecular structure is the block copolymer with parents' performance in additive effective component, which can be self-assembly of capsule
Bubble structure, in the drying process, sodium bicarbonate are thermally decomposed, and release carbon dioxide, the generation of carbon dioxide can be total with the block
Amidine group reaction in polymers, and amidine group is made to become positively charged lotus, due to mutually exclusive between like charges, so that vesica expands,
Simultaneously as vesicle surface is electrically charged, can modified fibre in attraction system so that modified fibre is able to good be dispersed in
In system, then in nitrogen charging sintering process, as system temperature is gradually increasing, the carbon dioxide in vesica, which is heated, to be discharged, and is made
Surrounding modified fibre must be adsorbed on further to be dispersed, as system temperature is gradually increasing, zinc carbonate in system by
Thermal decomposition generates zinc oxide and carbon dioxide, under the impetus of carbon dioxide, zinc oxide is conveyed and is adsorbed on modified fibre
Dimension table face, so that the electric conductivity of modified fibre gets a promotion, as temperature continues to increase, the modified fibre in system carbonizes shape
At carbonaceous skeleton, zinc oxide is fixed so that form conductive network in system so that the antistatic performance of system obtain into
The promotion of one step；
(2) present invention is by addition isocyanates, modified additive and zinc carbonate, firstly, molecule knot in additive effective component
Structure is the block copolymer with parents' performance, which can be self-assembly of imitated vesicle structure, in mixing process, body
Isocyanates in system is reacted with water, generates carbon dioxide, the generation of carbon dioxide can be with the amidine group in the block copolymer
Reaction, and make charge on amidine group band, due to mutually exclusive between like charges, so that vesica expands, simultaneously as vesicle surface
It is electrically charged, can modified fibre in attraction system so that zinc carbonate be able to it is good be dispersed in system, then hot conditions
Under, as system temperature is gradually increasing, the carbon dioxide in vesica, which is heated, to be discharged, and is obtained so that being adsorbed on surrounding zinc carbonate
Further dispersion, as system temperature is gradually increasing, the zinc carbonate in system is thermally decomposed, and generates zinc oxide and carbon dioxide,
Under the impetus of carbon dioxide so that generate zinc oxide further dispersed, the electric conductivity of system obtain into
The promotion of one step.
Specific embodiment
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 1:1~2:1 in mass ratio,
And into beaker be added 0.1~0.2 times of methoxy poly (ethylene glycol) quality paracide and methoxy poly (ethylene glycol) quality 0.07
~0.10 times of ferrocene is stirred 30~50min under the conditions of revolving speed is 300~500r/min to get modified addition
Agent；According to parts by weight, by 20~30 parts of rice hull celluloses, 2~3 parts of secondary settling tank sludge, 1~2 portion of sucrose, 30~50 parts of water are placed in
It is 30~35 DEG C in temperature, under the conditions of revolving speed is 300~500r/min, mixed fermentation 3~5 days, must ferment mixing in fermentation cauldron
Liquid, then fermentation mixed liquor is filtered, No. 1 filter cake is obtained, then No. 1 filter cake is placed in No. 1 vacuum refrigeration pulverizer, it is primary to freeze
It crushes, crosses the sieve of 260 mesh, obtain crushed material, the sodium hydroxide solution that crushed material and mass fraction are 20~30% is then pressed into quality
It is placed in mixing kettle than 1:10~1:20, is 60~80 DEG C in temperature, under the conditions of revolving speed is 300~500r/min, constant temperature impregnates 3
It after~5h, then will filter, and obtain No. 2 filter cakes, it is neutral for then being washed No. 2 filter cakes to cleaning solution with glacial acetic acid with deionized water,
Then No. 2 filter cakes after washing are placed in No. 2 vacuum refrigeration pulverizers, secondary Freezing smashing, cross the sieve of 400 mesh, obtains modification
Fiber；According to parts by weight, 40~60 parts of kaolin are successively taken, 20~30 parts of bentonites, 20~30 parts of perlites, 10~20 parts
Silicon ash, 60~80 parts of dispersion liquids, 10~20 parts of thickeners, 5~8 parts of calcium sulfate, 5~8 parts of calcium stearates are swollen first by kaolin
Profit soil, perlite, silicon ash and dispersion liquid are placed in No. 1 ball mill 40~60min of mixing and ball milling, are then added into No. 1 ball mill
Thickener, calcium sulfate and calcium stearate continue 40~60min of ball milling, obtain ball milling homogenate, and ball milling homogenate is then placed in molding machine
Middle compression molding, obtains adobe；According to parts by weight, by 20~30 parts of calcium carbonate, 10~20 parts of zinc carbonates, 10~20 parts of bicarbonates
Sodium, 30~40 parts of aluminium oxide, 5~8 parts of cordierites, 5~8 parts of boron oxides, 5~8 parts of potassium oxides, 5~8 parts of sodium oxide molybdenas, 5~8 parts
Tin oxide, 5~8 parts of antimony oxides, 5~8 parts of vanadic anhydrides, 5~8 parts of zinc oxide, 5~8 parts of modified additives, 5~8 parts
Plants essential oil, 5~8 parts of surfactants, 3~5 parts of modified fibres, 200~300 parts of water, 5~8 parts of conch meals, 5~8 parts of isocyanides
Acid esters is placed in 40~60min of mixing and ball milling in No. 2 ball mills, obtains glaze slurry；Glaze slurries are sprayed on adobe surface, then will
Adobe after spraying is placed under room temperature, and dry to constant weight, dry brick is then placed in sintering furnace by dry brick, is connect
Nitrogen is filled with into furnace with 60~90mL/min rate, and be warming up to 1400~1600 with the heating rate of 10~15 DEG C/min
DEG C, it is sintered 2~3h, air is then filled with into furnace with 60~90mL/min rate, under the conditions of temperature is 1400~1600 DEG C,
After calcining 2~3h, room temperature is down to get compounded antistatic Ceramic Tiles with furnace.The thickener is TYLOSE 30000, poly- second
Any one in enol or carragheen.The plants essential oil is Rosemary Oil, Lavender, rose ethereal oil, jasmine
Any one in flower essential oil, camellia essential oil or saussurea involucrata essential oil.The surfactant is Tween-20, octylphenol polyethylene ethylene oxide
Any one in ether or nonylphenol polyoxyethylene ether.The conch meal is clam shell powder, any one in husky clam meal or shell powder
Kind.The isocyanates is toluene di-isocyanate(TDI), in methyl diphenylene diisocyanate or trimethylhexane diisocyanate
Any one.The glaze slurries quantity for spray is 0.1~0.5g/cm2.
Example 1
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to beaker
0.2 times of methoxy poly (ethylene glycol) quality of paracide of middle addition and 0.10 times of methoxy poly (ethylene glycol) quality of ferrocene, in
Under the conditions of revolving speed is 500r/min, 50min is stirred to get modified additive；According to parts by weight, by 30 parts of rice husk fibres
Dimension, 3 parts of secondary settling tank sludge, 2 portions of sucrose, 50 parts of water are placed in fermentation cauldron, are 35 DEG C in temperature, revolving speed is 500r/min condition
Under, mixed fermentation 5 days, fermentation mixed liquor is obtained, then fermentation mixed liquor is filtered, obtain No. 1 filter cake, No. 1 filter cake is then placed in No. 1
In vacuum refrigeration pulverizer, a Freezing smashing crosses the sieve of 260 mesh, obtains crushed material, be then by crushed material and mass fraction
30% sodium hydroxide solution 1:20 in mass ratio is placed in mixing kettle, in temperature be 80 DEG C, revolving speed be 500r/min under the conditions of,
After constant temperature impregnates 5h, then will filtering, obtain No. 2 filter cakes, then No. 2 filter cakes are washed with glacial acetic acid to cleaning solution with deionized water be
No. 2 filter cakes after washing are then placed in No. 2 vacuum refrigeration pulverizers, secondary Freezing smashing by neutrality, are crossed the sieve of 400 mesh, are obtained
Modified fibre；According to parts by weight, 60 parts of kaolin, 30 parts of bentonites, 30 parts of perlites, 20 parts of silicon ashes, 80 parts of dispersions are successively taken
Kaolin, bentonite, perlite, silicon ash and dispersion liquid are first placed in by liquid, 20 parts of thickeners, 8 parts of calcium sulfate, 8 parts of calcium stearates
No. 1 ball mill mixing and ball milling 60min, is then added thickener into No. 1 ball mill, and calcium sulfate and calcium stearate continue ball milling
60min obtains ball milling homogenate, and then ball milling homogenate is placed in molding machine and is pressed and molded, adobe is obtained；According to parts by weight, by 30
Part calcium carbonate, 20 parts of zinc carbonates, 20 parts of sodium bicarbonates, 40 parts of aluminium oxide, 8 parts of cordierites, 8 parts of boron oxides, 8 parts of potassium oxides, 8 parts
Sodium oxide molybdena, 8 parts of tin oxide, 8 parts of antimony oxides, 8 parts of vanadic anhydrides, 8 parts of zinc oxide, 8 parts of modified additives, 8 portions of plants
Essential oil, 8 parts of surfactants, 5 parts of modified fibres, 300 parts of water, 8 parts of conch meals, 8 parts of isocyanates are placed in No. 2 ball mills and mix
Ball milling 60min is closed, glaze slurry is obtained；Glaze slurries are sprayed on adobe surface, and the adobe after spraying is then placed in room temperature condition
Under, dry to constant weight, dry brick is then placed in sintering furnace by dry brick, is then filled with 90mL/min rate into furnace
Enter nitrogen, and be warming up to 1600 DEG C with the heating rate of 15 DEG C/min, is sintered 3h, is then filled with 90mL/min rate into furnace
Air after calcining 3h, is down to room temperature with furnace under the conditions of temperature is 1600 DEG C to get compounded antistatic Ceramic Tiles.The thickening
Agent is TYLOSE 30000.The plants essential oil is Rosemary Oil.The surfactant is Tween-20.The shell
Powder is clam shell powder.The isocyanates is toluene di-isocyanate(TDI).The glaze slurries quantity for spray is 0.5g/cm2。
Example 2
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to beaker
0.2 times of methoxy poly (ethylene glycol) quality of paracide of middle addition and 0.10 times of methoxy poly (ethylene glycol) quality of ferrocene, in
Under the conditions of revolving speed is 500r/min, 50min is stirred to get modified additive；According to parts by weight, by 30 parts of rice husk fibres
Dimension, 3 parts of secondary settling tank sludge, 2 portions of sucrose, 50 parts of water are placed in fermentation cauldron, are 35 DEG C in temperature, revolving speed is 500r/min condition
Under, mixed fermentation 5 days, fermentation mixed liquor is obtained, then fermentation mixed liquor is filtered, obtain No. 1 filter cake, No. 1 filter cake is then placed in No. 1
In vacuum refrigeration pulverizer, a Freezing smashing crosses the sieve of 260 mesh, obtains crushed material, be then by crushed material and mass fraction
30% sodium hydroxide solution 1:20 in mass ratio is placed in mixing kettle, in temperature be 80 DEG C, revolving speed be 500r/min under the conditions of,
After constant temperature impregnates 5h, then will filtering, obtain No. 2 filter cakes, then No. 2 filter cakes are washed with glacial acetic acid to cleaning solution with deionized water be
No. 2 filter cakes after washing are then placed in No. 2 vacuum refrigeration pulverizers, secondary Freezing smashing by neutrality, are crossed the sieve of 400 mesh, are obtained
Modified fibre；According to parts by weight, 60 parts of kaolin, 30 parts of bentonites, 30 parts of perlites, 20 parts of silicon ashes, 80 parts of dispersions are successively taken
Kaolin, bentonite, perlite, silicon ash and dispersion liquid are first placed in by liquid, 20 parts of thickeners, 8 parts of calcium sulfate, 8 parts of calcium stearates
No. 1 ball mill mixing and ball milling 60min, is then added thickener into No. 1 ball mill, and calcium sulfate and calcium stearate continue ball milling
60min obtains ball milling homogenate, and then ball milling homogenate is placed in molding machine and is pressed and molded, adobe is obtained；According to parts by weight, by 30
Part calcium carbonate, 20 parts of sodium bicarbonates, 40 parts of aluminium oxide, 8 parts of cordierites, 8 parts of boron oxides, 8 parts of potassium oxides, 8 parts of sodium oxide molybdenas, 8 parts
Tin oxide, 8 parts of antimony oxides, 8 parts of vanadic anhydrides, 8 parts of zinc oxide, 8 parts of modified additives, 8 parts of plants essential oils, 8 parts of tables
Face activating agent, 5 parts of modified fibres, 300 parts of water, 8 parts of conch meals, 8 parts of isocyanates are placed in mixing and ball milling in No. 2 ball mills
60min obtains glaze slurry；Glaze slurries are sprayed on adobe surface, are then placed in the adobe after spraying under room temperature, dry
To constant weight, dry brick is then placed in sintering furnace by dry brick, and nitrogen is then filled with into furnace with 90mL/min rate,
And 1600 DEG C are warming up to the heating rate of 15 DEG C/min, it is sintered 3h, air is then filled with into furnace with 90mL/min rate, in
Under the conditions of temperature is 1600 DEG C, after calcining 3h, room temperature is down to get compounded antistatic Ceramic Tiles with furnace.The thickener is carboxylic
Methyl cellulose ether.The plants essential oil is Rosemary Oil.The surfactant is Tween-20.The conch meal is clam
Clam shell powder.The isocyanates is toluene di-isocyanate(TDI).The glaze slurries quantity for spray is 0.5g/cm2。
Example 3
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to beaker
0.2 times of methoxy poly (ethylene glycol) quality of paracide of middle addition and 0.10 times of methoxy poly (ethylene glycol) quality of ferrocene, in
Under the conditions of revolving speed is 500r/min, 50min is stirred to get modified additive；According to parts by weight, by 30 parts of rice husk fibres
Dimension, 3 parts of secondary settling tank sludge, 2 portions of sucrose, 50 parts of water are placed in fermentation cauldron, are 35 DEG C in temperature, revolving speed is 500r/min condition
Under, mixed fermentation 5 days, fermentation mixed liquor is obtained, then fermentation mixed liquor is filtered, obtain No. 1 filter cake, No. 1 filter cake is then placed in No. 1
In vacuum refrigeration pulverizer, a Freezing smashing crosses the sieve of 260 mesh, obtains crushed material, be then by crushed material and mass fraction
30% sodium hydroxide solution 1:20 in mass ratio is placed in mixing kettle, in temperature be 80 DEG C, revolving speed be 500r/min under the conditions of,
After constant temperature impregnates 5h, then will filtering, obtain No. 2 filter cakes, then No. 2 filter cakes are washed with glacial acetic acid to cleaning solution with deionized water be
No. 2 filter cakes after washing are then placed in No. 2 vacuum refrigeration pulverizers, secondary Freezing smashing by neutrality, are crossed the sieve of 400 mesh, are obtained
Modified fibre；According to parts by weight, 60 parts of kaolin, 30 parts of bentonites, 30 parts of perlites, 20 parts of silicon ashes, 80 parts of dispersions are successively taken
Kaolin, bentonite, perlite, silicon ash and dispersion liquid are first placed in by liquid, 20 parts of thickeners, 8 parts of calcium sulfate, 8 parts of calcium stearates
No. 1 ball mill mixing and ball milling 60min, is then added thickener into No. 1 ball mill, and calcium sulfate and calcium stearate continue ball milling
60min obtains ball milling homogenate, and then ball milling homogenate is placed in molding machine and is pressed and molded, adobe is obtained；According to parts by weight, by 30
Part calcium carbonate, 20 parts of zinc carbonates, 40 parts of aluminium oxide, 8 parts of cordierites, 8 parts of boron oxides, 8 parts of potassium oxides, 8 parts of sodium oxide molybdenas, 8 parts of oxygen
Change tin, 8 parts of antimony oxides, 8 parts of vanadic anhydrides, 8 parts of zinc oxide, 8 parts of modified additives, 8 parts of plants essential oils, 8 parts of surfaces
Activating agent, 5 parts of modified fibres, 300 parts of water, 8 parts of conch meals, 8 parts of isocyanates are placed in mixing and ball milling 60min in No. 2 ball mills,
Obtain glaze slurry；Glaze slurries are sprayed on adobe surface, are then placed in the adobe after spraying under room temperature, dry to perseverance
Weight, dry brick is then placed in sintering furnace by dry brick, is then filled with nitrogen into furnace with 90mL/min rate, and with
The heating rate of 15 DEG C/min is warming up to 1600 DEG C, is sintered 3h, is then filled with air, Yu Wendu into furnace with 90mL/min rate
Under the conditions of 1600 DEG C, after calcining 3h, room temperature is down to get compounded antistatic Ceramic Tiles with furnace.The thickener is carboxymethyl
Cellulose ether.The plants essential oil is Rosemary Oil.The surfactant is Tween-20.The conch meal is CONCHA MERETRICID SEU CYCLINAE
Powder.The isocyanates is toluene di-isocyanate(TDI).The glaze slurries quantity for spray is 0.5g/cm2。
Example 4
According to parts by weight, by 30 parts of rice hull celluloses, 3 parts of secondary settling tank sludge, 2 portions of sucrose, 50 parts of water are placed in fermentation cauldron, Yu Wen
Degree is 35 DEG C, under the conditions of revolving speed is 500r/min, mixed fermentation 5 days, obtains fermentation mixed liquor, then the mixed liquor filtering that will ferment, obtains 1
No. 1 filter cake, is then placed in No. 1 vacuum refrigeration pulverizer, a Freezing smashing by number filter cake, crosses the sieve of 260 mesh, must crush
The sodium hydroxide solution 1:20 in mass ratio that crushed material and mass fraction are 30% is then placed in mixing kettle, is in temperature by material
80 DEG C, under the conditions of revolving speed is 500r/min, it after constant temperature impregnates 5h, then will filter, and No. 2 filter cakes be obtained, then with deionized water by No. 2
It is neutrality that filter cake, which is washed with glacial acetic acid to cleaning solution, and then No. 2 filter cakes after washing are placed in No. 2 vacuum refrigeration pulverizers,
Secondary Freezing smashing crosses the sieve of 400 mesh, obtains modified fibre；According to parts by weight, 60 parts of kaolin, 30 parts of bentonites are successively taken,
30 parts of perlites, 20 parts of silicon ashes, 80 parts of dispersion liquids, 20 parts of thickeners, 8 parts of calcium sulfate, 8 parts of calcium stearates are swollen first by kaolin
Profit soil, perlite, silicon ash and dispersion liquid are placed in No. 1 ball mill mixing and ball milling 60min, and thickening is then added into No. 1 ball mill
Agent, calcium sulfate and calcium stearate continue ball milling 60min, obtain ball milling homogenate, and then ball milling homogenate is placed in molding machine and is molded into
Type obtains adobe；According to parts by weight, by 30 parts of calcium carbonate, 20 parts of zinc carbonates, 20 parts of sodium bicarbonates, 40 parts of aluminium oxide, 8 parts of violets
Green stone, 8 parts of boron oxides, 8 parts of potassium oxides, 8 parts of sodium oxide molybdenas, 8 parts of tin oxide, 8 parts of antimony oxides, 8 parts of vanadic anhydrides, 8 parts
Zinc oxide, 8 parts of plants essential oils, 8 parts of surfactants, 5 parts of modified fibres, 300 parts of water, 8 parts of conch meals, 8 parts of isocyanates are set
The mixing and ball milling 60min in No. 2 ball mills, obtains glaze slurry；Glaze slurries are sprayed on adobe surface, then by the brick after spraying
Base is placed under room temperature, and dry to constant weight, dry brick is then placed in sintering furnace by dry brick, then with 90mL/
Min rate is filled with nitrogen into furnace, and is warming up to 1600 DEG C with the heating rate of 15 DEG C/min, 3h is sintered, then with 90mL/
Min rate is filled with air into furnace, in temperature be 1600 DEG C under the conditions of, calcine 3h after, with furnace be down to room temperature to get it is compound prevent it is quiet
Electroceramics brick.The thickener is TYLOSE 30000.The plants essential oil is Rosemary Oil.The surfactant is
Tween-20.The conch meal is clam shell powder.The isocyanates is toluene di-isocyanate(TDI).The glaze slurries quantity for spray
For 0.5g/cm2。
Example 5
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to beaker
0.2 times of methoxy poly (ethylene glycol) quality of paracide of middle addition and 0.10 times of methoxy poly (ethylene glycol) quality of ferrocene, in
Under the conditions of revolving speed is 500r/min, 50min is stirred to get modified additive；According to parts by weight, by 30 parts of rice husk fibres
Dimension, 3 parts of secondary settling tank sludge, 2 portions of sucrose, 50 parts of water are placed in fermentation cauldron, are 35 DEG C in temperature, revolving speed is 500r/min condition
Under, mixed fermentation 5 days, fermentation mixed liquor is obtained, then fermentation mixed liquor is filtered, obtain No. 1 filter cake, No. 1 filter cake is then placed in No. 1
In vacuum refrigeration pulverizer, a Freezing smashing crosses the sieve of 260 mesh, obtains crushed material, be then by crushed material and mass fraction
30% sodium hydroxide solution 1:20 in mass ratio is placed in mixing kettle, in temperature be 80 DEG C, revolving speed be 500r/min under the conditions of,
After constant temperature impregnates 5h, then will filtering, obtain No. 2 filter cakes, then No. 2 filter cakes are washed with glacial acetic acid to cleaning solution with deionized water be
No. 2 filter cakes after washing are then placed in No. 2 vacuum refrigeration pulverizers, secondary Freezing smashing by neutrality, are crossed the sieve of 400 mesh, are obtained
Modified fibre；According to parts by weight, 60 parts of kaolin, 30 parts of bentonites, 30 parts of perlites, 20 parts of silicon ashes, 80 parts of dispersions are successively taken
Kaolin, bentonite, perlite, silicon ash and dispersion liquid are first placed in by liquid, 20 parts of thickeners, 8 parts of calcium sulfate, 8 parts of calcium stearates
No. 1 ball mill mixing and ball milling 60min, is then added thickener into No. 1 ball mill, and calcium sulfate and calcium stearate continue ball milling
60min obtains ball milling homogenate, and then ball milling homogenate is placed in molding machine and is pressed and molded, adobe is obtained；According to parts by weight, by 30
Part calcium carbonate, 20 parts of zinc carbonates, 20 parts of sodium bicarbonates, 40 parts of aluminium oxide, 8 parts of cordierites, 8 parts of boron oxides, 8 parts of potassium oxides, 8 parts
Sodium oxide molybdena, 8 parts of tin oxide, 8 parts of antimony oxides, 8 parts of vanadic anhydrides, 8 parts of zinc oxide, 8 parts of modified additives, 8 parts of surfaces
Activating agent, 5 parts of modified fibres, 300 parts of water, 8 parts of conch meals, 8 parts of isocyanates are placed in mixing and ball milling 60min in No. 2 ball mills,
Obtain glaze slurry；Glaze slurries are sprayed on adobe surface, are then placed in the adobe after spraying under room temperature, dry to perseverance
Weight, dry brick is then placed in sintering furnace by dry brick, is then filled with nitrogen into furnace with 90mL/min rate, and with
The heating rate of 15 DEG C/min is warming up to 1600 DEG C, is sintered 3h, is then filled with air, Yu Wendu into furnace with 90mL/min rate
Under the conditions of 1600 DEG C, after calcining 3h, room temperature is down to get compounded antistatic Ceramic Tiles with furnace.The thickener is carboxymethyl
Cellulose ether.The surfactant is Tween-20.The conch meal is clam shell powder.The isocyanates is that toluene two is different
Cyanate.The glaze slurries quantity for spray is 0.5g/cm2。
Example 6
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to beaker
0.2 times of methoxy poly (ethylene glycol) quality of paracide of middle addition and 0.10 times of methoxy poly (ethylene glycol) quality of ferrocene, in
Under the conditions of revolving speed is 500r/min, 50min is stirred to get modified additive；According to parts by weight, 60 parts of kaolinites are successively taken
Native 30 parts of bentonites, 30 parts of perlites, 20 parts of silicon ashes, 80 parts of dispersion liquids, 20 parts of thickeners, 8 parts of calcium sulfate, 8 parts of calcium stearates,
Kaolin, bentonite, perlite, silicon ash and dispersion liquid are first placed in No. 1 ball mill mixing and ball milling 60min, then to No. 1 ball milling
Thickener is added in machine, calcium sulfate and calcium stearate continue ball milling 60min, obtain ball milling homogenate, are then placed in into ball milling homogenate
It is pressed and molded in type machine, obtains adobe；According to parts by weight, by 30 parts of calcium carbonate, 20 parts of zinc carbonates, 20 parts of sodium bicarbonates, 40 parts
Aluminium oxide, 8 parts of cordierites, 8 parts of boron oxides, 8 parts of potassium oxides, 8 parts of sodium oxide molybdenas, 8 parts of tin oxide, 8 parts of antimony oxides, 8 part five
V 2 O, 8 parts of zinc oxide, 8 parts of modified additives, 8 parts of plants essential oils, 8 parts of surfactants, 300 parts of water, 8 parts of conch meals,
8 parts of isocyanates are placed in mixing and ball milling 60min in No. 2 ball mills, obtain glaze slurry；Glaze slurries are sprayed on adobe surface, connect
The adobe after spraying is placed under room temperature, dry to constant weight, dry brick is then placed in sintering furnace by dry brick
In, nitrogen is then filled with into furnace with 90mL/min rate, and be warming up to 1600 DEG C with the heating rate of 15 DEG C/min, sintering
3h is then filled with air into furnace with 90mL/min rate, under the conditions of temperature is 1600 DEG C, after calcining 3h, is down to room with furnace
Temperature is to get compounded antistatic Ceramic Tiles.The thickener is TYLOSE 30000.The plants essential oil is Rosemary Oil.
The surfactant is Tween-20.The conch meal is clam shell powder.The isocyanates is toluene di-isocyanate(TDI).Institute
Stating glaze slurries quantity for spray is 0.5g/cm2。
Comparative example: the compounded antistatic Ceramic Tiles of Guangdong material production Co., Ltd production.
Example 1 to the resulting compounded antistatic Ceramic Tiles of example 6 and comparative example product are subjected to performance detection, it is specific to detect
Method is as follows:
Specimen surface resistance, test condition are measured by digital insulation resistance meter (PC27 type, Yuanzhong Electronic Equipments Factory, Shanghai)
It is 25 DEG C for environment temperature, humidity 35%.
Specific testing result is as shown in table 1:
The 1 specific testing result of compounded antistatic Ceramic Tiles of table
By 1 testing result of table it is found that the compounded antistatic Ceramic Tiles of technical solution of the present invention preparation have excellent static electricity resistance
It the characteristics of energy, has broad prospects in the development of building material technology industry.
Claims (10)
1. a kind of preparation method of compounded antistatic Ceramic Tiles, it is characterised in that specific preparation process is as follows:
(1) according to parts by weight, 40~60 parts of kaolin are successively taken, 20~30 parts of bentonites, 20~30 parts of perlites, 10~20
Part silicon ash, 60~80 parts of dispersion liquids, 10~20 parts of thickeners, 5~8 parts of calcium sulfate, 5~8 parts of calcium stearates, first by kaolin,
Bentonite, perlite, silicon ash and dispersion liquid mixing and ball milling, are subsequently added into thickener, and calcium sulfate and calcium stearate continue ball milling, mould
It is molded, obtain adobe；
(2) according to parts by weight, by 20~30 parts of calcium carbonate, 10~20 parts of zinc carbonates, 10~20 parts of sodium bicarbonates, 30~40 parts
Aluminium oxide, 5~8 parts of cordierites, 5~8 parts of boron oxides, 5~8 parts of potassium oxides, 5~8 parts of sodium oxide molybdenas, 5~8 parts of tin oxide, 5~8
Part antimony oxide, 5~8 parts of vanadic anhydrides, 5~8 parts of zinc oxide, 5~8 parts of modified additives, 5~8 parts of plants essential oils, 5
~8 parts of surfactants, 3~5 parts of modified fibres, 200~300 parts of water, 5~8 parts of conch meals, 5~8 parts of isocyanates, mixing
Ball milling obtains glaze slurry；
(3) glaze slurries are sprayed on adobe surface, dry, heat up step by step, are sintered, calcining, and cooling is to get compounded antistatic ceramics
Brick.
2. a kind of preparation method of compounded antistatic Ceramic Tiles according to claim 1, it is characterised in that: step (1) is described
Graphene oxide is mixed into ultrasound with water 1:10~1:20 in mass ratio, ammonium hydroxide is subsequently added into and adjusts pH to 8.6~8.9, stirring
Mixing, obtains dispersion liquid.
3. a kind of preparation method of compounded antistatic Ceramic Tiles according to claim 1, it is characterised in that: step (1) is described
Thickener is TYLOSE 30000, any one in polyvinyl alcohol or carragheen.
4. a kind of preparation method of compounded antistatic Ceramic Tiles according to claim 1, it is characterised in that: step (2) is described
Modified additive the preparation method comprises the following steps: by (N- amidino groups) dodecylacrylamide and methoxy poly (ethylene glycol) 1:1 in mass ratio
~2:1 mixing, and 0.1~0.2 times of methoxy poly (ethylene glycol) quality of paracide and methoxy poly (ethylene glycol) quality is added
0.07~0.10 times of ferrocene, is stirred to get modified additive.
5. a kind of preparation method of compounded antistatic Ceramic Tiles according to claim 1, it is characterised in that: step (2) is described
Plants essential oil is Rosemary Oil, Lavender, rose ethereal oil, jasmine essential oil, in camellia essential oil or saussurea involucrata essential oil
Any one.
6. a kind of preparation method of compounded antistatic Ceramic Tiles according to claim 1, it is characterised in that: step (2) is described
Surfactant is Tween-20, any one in octyl phenol polyoxyethylene ether or nonylphenol polyoxyethylene ether.
7. a kind of preparation method of compounded antistatic Ceramic Tiles according to claim 1, it is characterised in that: step (2) is described
Modified fibre the preparation method comprises the following steps: according to parts by weight, by 20~30 parts of rice hull celluloses, 2~3 parts of secondary settling tank sludge, 1~2 part
Sucrose, 30~50 parts of water mixed fermentations, filtering, a Freezing smashing, sieving obtain crushed material, then by crushed material and hydroxide
Sodium solution 1:10~1:20 constant temperature in mass ratio impregnates, and filters, washing, secondary Freezing smashing, and sieving obtains modified fibre.
8. a kind of preparation method of compounded antistatic Ceramic Tiles according to claim 1, it is characterised in that: step (2) is described
Conch meal is clam shell powder, any one in husky clam meal or shell powder.
9. a kind of preparation method of compounded antistatic Ceramic Tiles according to claim 1, it is characterised in that: step (2) is described
Isocyanates is toluene di-isocyanate(TDI), any one in methyl diphenylene diisocyanate or trimethylhexane diisocyanate
Kind.
10. a kind of preparation method of compounded antistatic Ceramic Tiles according to claim 1, it is characterised in that: step (3) is described
Glaze slurries quantity for spray is 0.1~0.5g/cm2。
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| CN110804331A (en) * | 2019-11-20 | 2020-02-18 | 佛山市东鹏陶瓷有限公司 | Antistatic agent, preparation method thereof, and preparation methods of paint and ceramic tile using antistatic agent |
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| CN115043644A (en) * | 2022-04-13 | 2022-09-13 | 山东电盾科技股份有限公司 | Ceramic hand mold with anti-static function and preparation process thereof |
| CN115594488A (en) * | 2022-12-15 | 2023-01-13 | 佛山市陶莹新型材料有限公司（Cn） | Anti-static ceramic and preparation method thereof |
| CN117430405A (en) * | 2023-10-09 | 2024-01-23 | 山东亮剑陶瓷有限公司 | Antistatic ceramic tile and preparation method thereof |
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