CN115023214A - 毛发护理组合物 - Google Patents
毛发护理组合物 Download PDFInfo
- Publication number
- CN115023214A CN115023214A CN202180009308.0A CN202180009308A CN115023214A CN 115023214 A CN115023214 A CN 115023214A CN 202180009308 A CN202180009308 A CN 202180009308A CN 115023214 A CN115023214 A CN 115023214A
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- CN
- China
- Prior art keywords
- hair care
- care composition
- dimethiconol
- composition
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- -1 cyclomethicone compound Chemical class 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 18
- 208000001840 Dandruff Diseases 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 15
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical class C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
- 229940086555 cyclomethicone Drugs 0.000 claims abstract description 9
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003429 antifungal agent Substances 0.000 claims abstract description 5
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- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229940081510 piroctone olamine Drugs 0.000 claims abstract description 5
- VIDTVPHHDGRGAF-UHFFFAOYSA-N selenium sulfide Chemical compound [Se]=S VIDTVPHHDGRGAF-UHFFFAOYSA-N 0.000 claims abstract description 5
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- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 claims description 2
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 claims description 2
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- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
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- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 claims description 2
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Abstract
公开了一种毛发护理组合物,其包含阳离子表面活性剂、硅氧烷化合物、具有8至22个碳原子的直链或支链烷烃和抗头屑剂,所述抗头屑剂选自吡罗克酮乙醇胺、硫化硒、基于唑的抗真菌剂及其混合物;其中该组合物基本上不含环聚二甲基硅氧烷化合物;其中所述环聚二甲基硅氧烷化合物以基于所述毛发护理组合物的总重量小于1.5%的量存在。
Description
技术领域
本发明涉及毛发护理组合物,更具体地涉及包含特定烷烃、抗头屑剂和硅氧烷化合物的毛发护理组合物。
背景技术
毛发护理组合物通常提供清洁或护理益处或两者的组合。洗发剂通常包含一种或多种清洁表面活性剂,其通常有助于清洁毛发和头皮,使其不含不期望的污垢、颗粒和脂肪物质。护发素是另一类毛发护理组合物,其通常用于毛发已用洗发剂洗涤后的湿状态的毛发上。提供洗发和调理双重益处的组合物也是已知的。
护发素通常包含阳离子表面活性剂。通过在毛发护理组合物中包含一种或多种调理剂来实现调理益处。通常,用于毛发护理组合物中的最常用的调理剂是水不溶性油性材料,如矿物油、天然存在的油如甘油三酯和硅氧烷化合物。调理益处通过将油性材料沉积到毛发上导致形成膜来实现,这使得毛发在潮湿时更容易梳理并且在干燥时更易于管理。最常用的毛发调理剂是硅氧烷化合物。
然而,优选的毛发护理组合物将提供比简单的清洁和调理更多的益处。例如,期望在毛发护理组合物中掺入各种有益剂以提供除清洁和护理之外的益处。例如,已通过毛发护理组合物提供了抗头皮屑益处。头皮屑是影响全球许多人的问题。其状况呈现为死皮细胞团块从头皮的脱落。这些是白色的并导致美学上令人不快的外观。引起头皮屑的因素是马拉色菌属酵母的某些成员。为了对抗这些,抗头屑产品已经包含某些具有抗真菌活性的抗头屑剂,例如,吡罗克酮乙醇胺吡啶硫酮锌、基于唑类的抗真菌剂(例如,氯咪巴唑、酮康唑)、硫化硒或其组合。
本发明涉及包含阳离子表面活性剂和硅氧烷化合物的组合的毛发调理组合物。当抗头屑剂包含在这种类型的毛发调理组合物中时,存在所谓的硅氧烷结垢问题,其中组合物的稳定性受到软磨粒(soft grit)形成的损害,所述软磨粒可污染加工机器并产生稳定性较低的产品。本发明人现已意外地发现可使用特定烷烃来最小化这种硅氧烷结垢问题并增强此类毛发组合物的稳定性。
发明内容
在第一个方面中,本发明涉及毛发护理组合物,其包含:
(a)阳离子表面活性剂;
(b)硅氧烷化合物;
(c)具有8至22个碳原子的直链或支链烷烃;和
(d)抗头屑剂,其选自吡罗克酮乙醇胺、硫化硒、基于唑的抗真菌剂及其混合物;
其中组合物基本上不含环聚二甲基硅氧烷化合物;
其中所述环聚二甲基硅氧烷化合物以基于所述毛发护理组合物的总重量小于1.5%的量存在。
考虑到下面的详细描述和实施例,本发明的所有其他方面将更容易变得清楚。
具体实施方式
除了在实施例中或另有明确说明外,本说明书中表示材料的量或反应条件、材料的物理性质和/或用途的所有数字可任选地被理解为由词语“约”修饰。
除非另有说明,否则所有量均按最终毛发护理组合物的重量计。应当注意,在指定任何值范围时,任何特定的上限值可以与任何特定的下限值相关联。
为避免疑义,词语“包含”旨在表示“包括”,但不一定是“由……组成”或“由……构成”。换句话说,所列出的步骤或选项不需要是穷举的。
本文中发现的本发明的公开内容被认为涵盖了在彼此多重从属的权利要求中发现的所有实施方案,而不管权利要求可以以没有多重从属或冗余的情况存在的事实。
在特征关于本发明的特定方面(例如本发明的组合物)公开的情况下,认为这种公开加以必要的变更也适用于本发明的任何其他方面(例如本发明的方法)。
如本文所用,“毛发护理组合物”意指包括用于局部施用于哺乳动物,尤其是人的毛发和/或头皮的组合物。这种组合物通常可分类为免洗型或洗去型,并且包括施用于人体也用于改善外观、清洁、气味控制或一般美学的任何产品。本发明的组合物可以是液体、洗剂、霜剂、泡沫、磨砂膏、凝胶或条的形式。此类组合物的非限制性实例包括免洗型毛发洗剂、霜剂和洗去型洗发剂、护发素、沐浴露或皂条。本发明的组合物优选为洗去型组合物,特别优选洗发剂或护发素,最优选护发素。
毛发护理组合物包含选自阳离子表面活性剂的调理表面活性剂,其单独使用或混合使用。优选地,阳离子表面活性剂具有式N+R1R2R3R4,其中R1、R2、R3和R4独立地为(C1至C30)烷基或苄基。优选地,R1、R2、R3和R4中的一个、两个或三个独立地为(C4至C30)烷基,并且其他的一个或多个R1、R2、R3和R4基团为(C1-C6)烷基或苄基。更优选地,R1、R2、R3和R4中的一个或两个独立地为(C6至C30)烷基,并且其他R1、R2、R3和R4基团为(C1-C6)烷基或苄基。任选地,烷基可以在烷基链内包含一个或多个酯(-OCO-或-COO-)和/或醚(-O-)键。烷基可以任选地被一个或多个羟基取代。烷基可以是直链或支链的,并且对于具有3个或更多个碳原子的烷基,可以是环状的。烷基可以是饱和的或可以含有一个或多个碳-碳双键(例如油烯基)。烷基任选地在烷基链上被一个或多个乙烯氧基团乙氧基化。
适用于本发明的毛发护理组合物中的阳离子表面活性剂包括鲸蜡基三甲基氯化铵、山嵛基三甲基氯化铵、鲸蜡基吡啶鎓氯化物、四甲基氯化铵、四乙基氯化铵、辛基三甲基氯化铵、十二烷基三甲基氯化铵、十六烷基三甲基氯化铵、辛基二甲基苄基氯化铵、癸基二甲基苄基氯化铵、硬脂基二甲基苄基氯化铵、双十二烷基二甲基氯化铵、双十八烷基二甲基氯化铵、牛油基三甲基氯化铵、二氢化牛油基二甲基氯化铵(例如,来自Akzo Nobel的Arquad 2HT/75)、椰油基三甲基氯化铵、PEG-2-油基氯化铵及其相应的氢氧化物。其他合适的阳离子表面活性剂包括具有CTFA名称季铵盐-5、季铵盐-31和季铵盐-18的那些材料。任何前述材料的混合物也可以是合适的。用于根据本发明的护发素中的特别有用的阳离子表面活性剂是鲸蜡基三甲基氯化铵,可商购获得,例如作为来自Hoechst Celanese的GENAMINCTAC。用于根据本发明的护发素中的另一种特别有用的阳离子表面活性剂是山嵛基三甲基氯化铵,可商购获得,例如作为来自Clariant的GENAMIN KDMP。再另一种优选的阳离子表面活性剂是硬脂酰氨基丙基二甲胺。用于本发明组合物的最优选的阳离子表面活性剂是硬脂酰氨基丙基二甲胺、山嵛基三甲基氯化铵、十六烷基三甲基氯化铵或其混合物。
毛发护理组合物通常包含基于毛发护理组合物的总重量0.1%至5%,更优选0.5%至2.5%的量的阳离子表面活性剂,并且包括其中包含的所有范围。
本发明的毛发护理组合物包含不是环聚二甲基硅氧烷的硅氧烷化合物。优选地,硅氧烷化合物是非挥发性硅氧烷。如本文所用,“非挥发性”是指硅氧烷在25℃和一个大气压下的蒸气压小于1000Pa。
优选地,硅氧烷化合物是硅油的乳化液滴,其具有小于15μm、优选小于10μm、更优选小于5μm的平均液滴直径(D3,2)。优选地,硅油的平均液滴直径(D3,2)大于0.05μm,更优选大于0.1μm,理想地为0.1μm至5μm。硅油的平均液滴直径(D3,2)可以通过激光散射技术测量,例如使用来自Malvern Instruments的2600D粒度仪。
合适的硅氧烷化合物包括聚硅氧烷,特别是CTFA命名为二甲基聚硅氧烷的聚二甲基硅氧烷。同样适用于本发明组合物(特别是洗发剂和护发素)的是具有羟基端基的聚二甲基硅氧烷,其CTFA命名为聚二甲基硅氧烷醇。可使用的另一类硅氧烷是官能化硅氧烷,如氨基官能硅氧烷,意指含有至少一个伯、仲或叔胺基团或季铵基团的硅氧烷。合适的氨基官能硅氧烷的实例包括CTFA命名为“氨端聚二甲基硅氧烷”的聚硅氧烷。同样适用于本发明组合物的是具有轻微交联度的硅氧烷胶,如例如WO 96/31188中所述的。优选地,硅氧烷化合物包括聚二甲基硅氧烷、聚二甲基硅氧烷醇、氨基封端的聚二甲基硅氧烷,其衍生物或混合物。
在另一个优选的实施方案中,硅氧烷化合物是聚二甲基硅氧烷醇衍生物,包括聚二甲基硅氧烷醇/倍半硅氧烷共聚物、聚二甲基硅氧烷醇精氨酸、聚二甲基硅氧烷醇蜂蜡、聚二甲基硅氧烷醇山嵛酸酯、聚二甲基硅氧烷醇半胱氨酸、聚二甲基硅氧烷醇白池花籽油酸酯(meadowfoamate)、聚二甲基硅氧烷醇甲硫氨酸、聚二甲基硅氧烷醇泛醇、聚二甲基硅氧烷醇硬脂酸酯、三甲基甲硅烷氧基硅酸酯/聚二甲基硅氧烷醇交联聚合物、丙烯酸酯/聚二甲基硅氧烷醇丙烯酸酯共聚物或其混合物。特别优选的是聚二甲基硅氧烷醇/倍半硅氧烷共聚物。
用作乳化硅油本身的优选硅氧烷化合物的粘度在25℃下通常为至少10,000cSt(厘沲=mm2·S-1),优选至少60,000cSt,最优选至少500,000cSt,理想地至少1,000,000cSt。优选粘度不超过109cSt,以方便配制。硅氧烷的粘度可以例如通过相关的国际标准如ISO 3104来测定。
用于本发明的毛发护理组合物中的合适的乳化硅氧烷可作为预形成的硅氧烷乳液购自硅氧烷供应商,如Dow Chemical Corporation和GE Silicones。为了易于加工和控制硅氧烷粒度,优选使用这种预形成的硅氧烷乳液。这种预形成的硅氧烷乳液通常另外包含合适的乳化剂,并且可以通过化学乳化方法(如乳液聚合)或通过使用高剪切混合器的机械乳化来制备。合适的预形成的硅氧烷乳液的实例包括Dowsil 1785BA、MEM 7134POE/MEM7154、Dowsil CE-7126,其均可得自Dow。这些是聚二甲基硅氧烷醇/聚二甲基硅氧烷、氨基封端的聚二甲基硅氧烷的乳液。合适的预形成的硅氧烷乳液的另一个实例包括来自Dow的商品名为CE-1607IHD乳液的聚二甲基硅氧烷醇/倍半硅氧烷共聚物。
基于毛发护理组合物的总重量,硅氧烷化合物通常以0.1至10%,更优选0.5至5%,最优选0.5至3%的量存在于本发明的毛发护理组合物中,并且包括其中所包含的所有范围。
毛发护理组合物还包含具有8至22个碳原子,优选10至20个,更优选12至18个碳原子的直链或支链烷烃。可用于本发明的烷烃的说明性实例包括例如辛烷、异辛烷、癸烷、异癸烷、十二烷、异十二烷、十四烷、异十四烷、十六烷、异十六烷、十八烷、异十八烷、二十烷、异二十烷、二十二烷、异二十二烷或其混合物。优选地,烷烃是包含异辛烷、异癸烷、异十二烷、异十四烷、异十六烷、异十八烷、异二十烷、异二十二烷或其混合物的支链烷烃。特别优选异十六烷。
基于毛发护理组合物的总重量,直链或支链烷烃优选以0.01至5%,更优选0.05至3%,最优选0.1至2%范围内的水平存在于本发明的毛发护理组合物中,并且包括其中所包含的所有范围。
存在于毛发护理组合物中的抗头屑剂为具有对抗头皮屑的活性的化合物,并且通常为抗微生物剂,优选为抗真菌剂。可用于本发明的合适的抗头屑剂选自吡罗克酮乙醇胺硫化硒及其混合物。在优选的实施方案中,抗头屑剂是吡罗克酮乙醇胺。
通常,基于毛发护理组合物的总重量,本发明的毛发护理组合物包含0.01至10%,更优选0.01至5%,还更优选0.05至2%,并且最优选0.05至1.5%的量的抗头屑剂,并且包括其中所包含的所有范围。
组合物的pH优选等于或高于4.0,更优选在4.0至7.0的范围内。
本发明的毛发护理组合物基本上不含环聚二甲基硅氧烷化合物。如本文所用,“基本上不含”是指基于毛发护理组合物的总重量,环聚二甲基硅氧烷化合物以小于1.5%,优选小于1.0%,更优选小于0.75%,还更优选小于0.5%,且甚至更优选小于0.1%的量存在,并且最优选不存在于组合物中,并且包括其中所包含的所有范围。合适的环聚二甲基硅氧烷化合物的实例包括八甲基环四硅氧烷、十甲基环五硅氧烷、十二甲基环六硅氧烷或其混合物。最常用的环聚二甲基硅氧烷化合物为十甲基环五硅氧烷,其被称为D5,并且优选本发明的毛发护理组合物基本上不含D5。
本发明的毛发护理组合物可另外包含脂肪醇。据认为脂肪醇和阳离子表面活性剂的组合使用是特别有利的,因为这导致形成阳离子表面活性剂分散在其中的层状相。
代表性脂肪醇包含8至22个碳原子,更优选16至22个碳原子。脂肪醇通常是含有直链烷基的化合物。合适的脂肪醇的实例包括鲸蜡醇、硬脂醇及其混合物。这些材料的使用也是有利的,因为它们有助于本发明组合物的整体调理性质。
基于毛发护理组合物的总重量,脂肪醇优选以0.5至10%,更优选0.1至8%,还更优选0.2至7%,且最优选0.3至6%范围内的水平存在于本发明的毛发护理组合物中,并且包括其中所包含的所有范围。阳离子表面活性剂与脂肪醇的重量比通常为1:1至1:10,更优选1:1.5至1:8,最优选1:2至1:5。
防腐剂也可掺入本发明的毛发护理组合物中以防止潜在有害微生物的生长。合适的传统防腐剂包括对羟基苯甲酸的烷基酯、乙内酰脲衍生物、丙酸盐和各种季铵化合物。可用于本发明中的防腐剂类型的说明性但非限制性实例包括例如苯氧基乙醇、水杨酸钠、对羟基苯甲酸甲酯、对羟基苯甲酸丁酯、对羟基苯甲酸丙酯、重氮烷基脲、脱氢乙酸钠、1,2-己二醇、苯甲醇、苯甲酸钠、碘丙炔基丁基氨基甲酸酯、辛甘醇、EDTA二钠或其混合物。在尤为优选的实施方案中,防腐剂是1,2-己二醇、苯甲醇或其混合物。防腐剂优选以毛发护理组合物的0.01至2%重量范围内的量来使用。
本发明的毛发护理组合物可含有本领域常用的其它成分以增强物理特性和性能。合适的成分包括但不限于香料、染料和颜料、pH调节剂、珠光剂或遮光剂、粘度调节剂、增稠剂和天然毛发营养物质,如植物制剂、水果提取物、糖衍生物和氨基酸。
本发明的组合物主要旨在用于在洗去型或免洗型组合物中,优选在洗去型组合物(如护发素)中,局部施用于个体的头皮和/或至少一部分毛发。
提供以下实施例以便于理解本发明。这些实施例不是为了限制权利要求的范围而提供的。
实施例
实施例1
这个实施例证明了通过使用烷烃减少的硅氧烷结垢。根据表1中详述的配方制备组合物。所有成分以总制剂的重量百分比表示,并且表示为活性成分的水平。
表1
a.来自Dow的商品名为Dowsil 1785BA的商业聚二甲基硅氧烷醇。
b .来自Dow的商品名为CE-1607IHD乳液的商业材料,其含有42wt%的聚二甲基硅氧烷醇/倍半硅氧烷共聚物和28wt%的异十六烷。
方法
使用以下程序测量%硅氧烷结垢:将约800g调理剂组合物置于1000mL烧杯中,并用平桨以160rpm搅拌20min。然后取出700g调理剂组合物并将100g留在烧杯中。将约700g热水(80-90℃)加入烧杯中,并用平浆以160rpm搅拌20min。然后使用710μm筛网过滤稀释的物质。然后用800mL水(25℃)填充烧杯的内容物并以160rpm搅拌1min。之后,使用710μm筛网过滤烧杯的内容物。然后将烧杯、筛网和桨叶在45℃的烘箱中干燥3小时。然后测量烧杯、桨叶和筛网的重量增加,这是硅氧烷结垢的绝对量的指标。然后使用以下等式计算%硅氧烷结垢:
%硅氧烷结垢=(硅氧烷结垢的绝对量)/(所取的毛发调理剂组合物的量)*100。
结果
%硅氧烷结垢报告于表2中。
表2
高于3%的硅氧烷结垢(根据上面列出的程序)被认为是不可接受的。结果清楚地表明了与样品1和2相比,包含烷烃的样品3至8表现出较低的硅氧烷结垢。
Claims (15)
1.一种毛发护理组合物,其包含:
(a)阳离子表面活性剂;
(b)硅氧烷化合物;
(c)具有8至22个碳原子的直链或支链烷烃;和
(d)抗头屑剂,其选自吡罗克酮乙醇胺、硫化硒、基于唑的抗真菌剂及其混合物;
其中所述组合物基本上不含环聚二甲基硅氧烷化合物;
其中所述环聚二甲基硅氧烷化合物以基于所述毛发护理组合物的总重量小于1.5%的量存在。
2.根据权利要求1所述的毛发护理组合物,其中所述硅氧烷化合物是在25℃和一个大气压下具有小于1000Pa的蒸气压的非挥发性硅氧烷。
3.根据权利要求1或权利要求2所述的毛发护理组合物,其中所述硅氧烷化合物为聚硅氧烷,所述聚硅氧烷包括聚二甲基硅氧烷、聚二甲基硅氧烷醇、氨基封端的聚二甲基硅氧烷、聚二甲基硅氧烷醇衍生物或其混合物。
4.根据权利要求3所述的毛发护理组合物,其中所述硅氧烷化合物为聚二甲基硅氧烷醇衍生物,其包括聚二甲基硅氧烷醇/倍半硅氧烷共聚物、聚二甲基硅氧烷醇精氨酸、聚二甲基硅氧烷醇蜂蜡、聚二甲基硅氧烷醇山嵛酸酯、聚二甲基硅氧烷醇半胱氨酸、聚二甲基硅氧烷醇白池花籽油酸酯、聚二甲基硅氧烷醇甲硫氨酸、聚二甲基硅氧烷醇泛醇、氨基封端的聚二甲基硅氧烷、聚二甲基硅氧烷醇硬脂酸酯、三甲基甲硅烷氧基硅酸酯/聚二甲基硅氧烷醇交联聚合物、丙烯酸酯/聚二甲基硅氧烷醇丙烯酸酯共聚物或其混合物,优选聚二甲基硅氧烷醇/倍半硅氧烷共聚物。
5.根据前述任一项权利要求所述的毛发护理组合物,其中所述组合物包含为所述组合物重量的0.1至10%,优选0.5至5%的量的所述硅氧烷化合物。
6.根据前述任一项权利要求所述的毛发护理组合物,其中所述直链或支链烷烃包括辛烷、异辛烷、癸烷、异癸烷、十二烷、异十二烷、十四烷、异十四烷、十六烷、异十六烷、十八烷、异十八烷、二十烷、异二十烷、二十二烷、异二十二烷或其混合物。
7.根据权利要求6所述的毛发护理组合物,其中所述直链或支链烷烃包括异辛烷、异癸烷、异十二烷、异十四烷、异十六烷、异十八烷、异二十烷、异二十二烷或其混合物,优选异十六烷。
8.根据前述任一项权利要求所述的毛发护理组合物,其中所述组合物包含为所述组合物重量的0.01至5%,优选0.05至3%的量的所述直链或支链烷烃。
9.根据前述任一项权利要求所述的毛发护理组合物,其中所述抗头屑剂为吡罗克酮乙醇胺。
10.根据前述任一项权利要求所述的毛发护理组合物,其中所述组合物包含为所述组合物重量的0.01至10%,优选0.01至5%的量的所述抗头屑剂。
11.根据前述任一项权利要求所述的毛发护理组合物,其中所述环聚二甲基硅氧烷化合物包括八甲基环四硅氧烷、十甲基环五硅氧烷、十二甲基环六硅氧烷或其混合物,优选所述环聚二甲基硅氧烷化合物为十甲基环五硅氧烷。
12.根据权利要求1至10中任一项所述的毛发护理组合物,其中所述组合物中不存在所述环聚二甲基硅氧烷化合物。
13.根据前述任一项权利要求所述的毛发护理组合物,其中所述阳离子表面活性剂包括硬脂酰胺基丙基二甲胺、山嵛基三甲基氯化铵、鲸蜡基三甲基氯化铵或其混合物。
14.根据前述任一项权利要求所述的毛发护理组合物,其中所述组合物还包含脂肪醇。
15.根据权利要求14所述的毛发护理组合物,其中所述脂肪醇包含8至22个碳原子。
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