CN115023138B - Quantitative spray aerosol product for controlling specific harmful substances and method for controlling specific harmful substances using the same - Google Patents
Quantitative spray aerosol product for controlling specific harmful substances and method for controlling specific harmful substances using the same Download PDFInfo
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- CN115023138B CN115023138B CN202180010408.5A CN202180010408A CN115023138B CN 115023138 B CN115023138 B CN 115023138B CN 202180010408 A CN202180010408 A CN 202180010408A CN 115023138 B CN115023138 B CN 115023138B
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- Prior art keywords
- specific
- aerosol
- harmful
- controlling
- quantitative
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- 239000000443 aerosol Substances 0.000 title claims abstract description 162
- 239000007921 spray Substances 0.000 title claims abstract description 103
- 239000000126 substance Substances 0.000 title claims abstract description 92
- 238000000034 method Methods 0.000 title claims description 21
- 244000005700 microbiome Species 0.000 claims abstract description 50
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 230000005484 gravity Effects 0.000 claims abstract description 14
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 241000607479 Yersinia pestis Species 0.000 claims description 138
- -1 fatty acid ester Chemical class 0.000 claims description 46
- 238000002347 injection Methods 0.000 claims description 46
- 239000007924 injection Substances 0.000 claims description 46
- 238000005507 spraying Methods 0.000 claims description 20
- 239000011550 stock solution Substances 0.000 claims description 18
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
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- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 16
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- 238000004140 cleaning Methods 0.000 description 5
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- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical class CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 5
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 description 5
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- JGFDZZLUDWMUQH-UHFFFAOYSA-N Didecyldimethylammonium Chemical class CCCCCCCCCC[N+](C)(C)CCCCCCCCCC JGFDZZLUDWMUQH-UHFFFAOYSA-N 0.000 description 4
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
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- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 4
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- FPDLLPXYRWELCU-UHFFFAOYSA-M dimethyl(dioctadecyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC FPDLLPXYRWELCU-UHFFFAOYSA-M 0.000 description 4
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- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- YHHSONZFOIEMCP-UHFFFAOYSA-O phosphocholine Chemical compound C[N+](C)(C)CCOP(O)(O)=O YHHSONZFOIEMCP-UHFFFAOYSA-O 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920001281 polyalkylene Chemical class 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- SMKRKQBMYOFFMU-UHFFFAOYSA-N prallethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OC1C(C)=C(CC#C)C(=O)C1 SMKRKQBMYOFFMU-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- HPYNBECUCCGGPA-UHFFFAOYSA-N silafluofen Chemical compound C1=CC(OCC)=CC=C1[Si](C)(C)CCCC1=CC=C(F)C(OC=2C=CC=CC=2)=C1 HPYNBECUCCGGPA-UHFFFAOYSA-N 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mycology (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Cosmetics (AREA)
Abstract
The present invention provides a quantitative spray aerosol product for controlling specific harmful substances, which can exert excellent control effects on specific harmful substances containing harmful microorganisms and/or harmful fine substances. The quantitative spray aerosol product for preventing and killing specific harmful substances including harmful microorganisms and/or harmful fine substances in space is formed by filling aerosol container with aerosol liquid containing specific harmful substance preventing and killing component and organic solvent and spray agent, wherein the specific gravity of the aerosol liquid is 0.76-0.95 at 20deg.C, and the internal pressure is set to below 0.60MPa at 25deg.C in the aerosol container.
Description
Technical Field
The present invention relates to: a quantitative spray aerosol product for controlling specific harmful substances (particularly mold, bacteria, and viruses) including harmful microorganisms and/or harmful fine substances in a space (particularly a narrow space); a specific pest control method using the product.
Background
A quantitative spray aerosol product capable of spraying a predetermined amount of a chemical by 1 spray is widely used as an insecticidal aerosol product (for example, see patent document 1) or a deodorizing aerosol product (for example, see patent document 2) because of its convenience.
The aerosol product of patent document 1 is a quantitative spray aerosol product capable of improving pest control efficiency in a spray state of the content of the aerosol product having a function capable of strongly spraying a predetermined amount.
The aerosol product of patent document 2 is a quantitative injection aerosol product that exhibits excellent deodorizing effect not only on space but also on floor malodor substances by quantitatively injecting an aerosol composition containing a specific amount of deodorizing component so as to have a specific injection particle diameter.
Prior art literature
Patent literature
Patent document 1: japanese patent laid-open No. 2006-325489
Patent document 2: japanese patent laid-open publication No. 2019-208915
Disclosure of Invention
Problems to be solved by the invention
The quantitative spray aerosol product of patent document 1 is a product that improves pest control efficiency by increasing the spray force, but such a quantitative spray aerosol product having a strong spray force is not necessarily a formulation design suitable for use in a narrow space such as a bathroom or a toilet.
The quantitative aerosol spray product of patent document 2 exhibits a sufficient deodorizing effect not only on spaces but also on floors, but is not necessarily a product suitable for controlling harmful microorganisms in a narrow space such as a bathroom or a toilet because it causes problems such as generation or propagation of harmful microorganisms such as mold and bacteria in ceilings and walls where cleaning is difficult.
As described above, various kinds of quantitative spray aerosol products have been developed for the purpose of insect disinfestation, deodorization, and the like, but the development of quantitative spray aerosol products in which harmful microorganisms such as mold, bacteria, viruses, and the like, and harmful fine substances such as indoor dust, PM2.5, and the like are targeted for control has been difficult, and has not been put to practical use.
In particular, in the control of harmful microorganisms such as mold in a bathroom, it has been common to use (1) a fumigant or (2) a total amount of an aerosol. These preparations prevent the generation of harmful microorganisms such as mold at a certain period after use by one treatment, but each time, the used fumigant or the full-spray aerosol must be discarded, which takes labor and time. If the place of use is not completely sealed, there is a concern that smoke or a part of the medicine leaks into another room during use. Accordingly, it is desired to develop a quantitative spray aerosol product capable of controlling harmful microorganisms such as mold by a simpler operation than (1) fumigant or (2) total spray aerosol.
The present invention has been made in view of the above problems, and an object thereof is to provide: by uniformly adhering a sufficient amount of a control component to a ceiling or a wall, a quantitative spray aerosol product for controlling a specific pest, which exhibits an excellent control effect on a specific pest including a harmful microorganism and/or a harmful fine substance, in a space (particularly a small space); a specific pest control method using the product.
Means for solving the problems
The quantitative injection aerosol product for controlling specific harmful substances according to the present invention for solving the above problems is characterized in that,
Which is a quantitative spray aerosol product for controlling specific harmful substances including harmful microorganisms and/or harmful fine substances in a space,
The quantitative spray aerosol product for preventing and controlling specific harmful substances is formed by filling aerosol containers with a quantitative spray valve with aerosol collagen liquid containing specific harmful substance preventing and controlling components and organic solvent and a spray agent,
The specific gravity of the aerosol stock solution is 0.76-0.95 at 20 ℃,
In the aerosol container, the internal pressure is set to 0.60MPa or less at 25 ℃.
According to the quantitative spray aerosol product for controlling a specific pest of the present constitution, which is obtained by filling an aerosol container provided with a quantitative spray valve with an aerosol raw liquid containing a specific pest control component and an organic solvent and a spray agent, the specific gravity of the aerosol raw liquid at 20 ℃ and the internal pressure of the aerosol container at 25 ℃ are within the above ranges, whereby when the quantitative spray aerosol product for controlling a specific pest is sprayed toward a space, the sprayed particles do not remain excessively in the air, and a sufficient amount of the control component uniformly adheres to the ceiling and the wall surface. Harmful microorganisms such as mold and bacteria tend to be generated and propagated in large amounts on ceilings and walls where cleaning is difficult, and even in the case of harmful fine substances such as house dust, the harmful fine substances tend to adhere to ceilings and walls, and thus, by means of a sufficient amount of the control component adhering uniformly to ceilings and walls, an excellent control effect can be exerted on specific harmful substances including harmful microorganisms and/or harmful fine substances in a space.
In the quantitative spray aerosol product for controlling a specific pest according to the present invention, it is preferable that the volume ratio (a/b) of the aerosol collagen liquid (a) to the propellant (b) in the aerosol container is set to 1/99 to 70/30 in terms of a volume ratio.
According to the quantitative spray aerosol product for controlling a specific pest of the present constitution, when the quantitative spray aerosol product for controlling a specific pest is sprayed toward a space by setting the capacity ratio (a/b) to the above range, the sprayed particles do not remain excessively in the air, and a sufficient amount of the control component uniformly adheres to the ceiling and the wall surface, thereby exhibiting an excellent control effect on a specific pest including a harmful microorganism and/or a harmful fine substance.
In the quantitative injection aerosol product for controlling specific harmful substances according to the present invention,
The organic solvent is preferably at least one selected from the group consisting of a lower alcohol having 2 to 3 carbon atoms, a higher fatty acid ester having 16 to 20 carbon atoms, and a hydrocarbon solvent.
According to the quantitative spray aerosol product for controlling a specific pest of the present constitution, by using at least one selected from the group consisting of a lower alcohol having 2 to 3 carbon atoms, a higher fatty acid ester having 16 to 20 carbon atoms and a hydrocarbon-based solvent as an organic solvent, the spray particles do not remain excessively in the air, and a sufficient amount of the control component adheres uniformly to the ceiling and the wall surface, thereby exhibiting an excellent control effect on a specific pest including a harmful microorganism and/or a harmful fine substance.
In the quantitative injection aerosol product for controlling specific harmful substances according to the present invention,
Preferably, the propellant is liquefied petroleum gas and/or hydrofluoroolefin.
According to the quantitative spray aerosol product for controlling specific pests of the present constitution, by using liquefied petroleum gas and/or hydrofluoroolefin as the spray agent, the spray particles do not remain excessively in the air, and a sufficient amount of the control component adheres uniformly to the ceiling and the wall surface, and an excellent control effect can be exerted on specific pests including harmful microorganisms and/or harmful fine substances.
In the quantitative injection aerosol product for controlling specific harmful substances according to the present invention,
Preferably, the space is a small space having a volume of 2.0 to 18.8m 3.
According to the quantitative spray aerosol product for controlling a specific pest of the present constitution, when the space is a small space having a volume of 2.0 to 18.8m 3, and the quantitative spray aerosol product for controlling a specific pest is sprayed into a small space having a volume of 2.0 to 18.8m 3, the sprayed particles do not remain excessively in the air, and a sufficient amount of the control component uniformly adheres to the ceiling and the wall surface. Harmful microorganisms such as mold and bacteria tend to be generated and propagated in large amounts on ceilings and walls where cleaning is difficult, and even in the case of harmful fine substances such as house dust, the harmful fine substances tend to adhere to ceilings and walls, and thus, a sufficient amount of the control component uniformly adheres to ceilings and walls can exert an excellent control effect on specific harmful substances including harmful microorganisms and/or harmful fine substances in a small space.
In the quantitative injection aerosol product for controlling specific harmful substances according to the present invention,
The release amount of the specific pest control ingredient is preferably set to 0.01 to 250mg/m 3.
According to the quantitative spray aerosol product for controlling a specific pest of the present constitution, by setting the release amount of the specific pest control ingredient contained in the quantitative spray aerosol product for controlling a specific pest to the above-described range, when the quantitative spray aerosol product for controlling a specific pest is sprayed toward the space, the sprayed particles do not remain excessively in the air, and a sufficient amount of the control ingredient uniformly adheres to the ceiling and the wall surface, thereby exhibiting an excellent control effect on a specific pest containing a pest microorganism and/or a pest fine substance.
The specific pest control method according to the present invention for solving the above-mentioned problems is characterized in that,
Which is a specific pest control method of performing a spray treatment using the quantitative spray aerosol product for specific pest control described above,
The quantitative spray aerosol product for preventing and removing the specific harmful substances is sprayed in a room toward a space.
According to the specific pest control method of the present configuration, by a simple operation of spraying only the quantitative spray aerosol product for specific pest control in the indoor space, the sprayed particles do not remain excessively in the air, and a sufficient amount of the control component uniformly adheres to the ceiling and the wall surface. Harmful microorganisms such as mold and bacteria tend to be generated and propagated in large amounts on ceilings and walls where cleaning is difficult, and even in the case of harmful fine substances such as house dust, the harmful fine substances tend to adhere to ceilings and walls, and thus, by means of a sufficient amount of the control component adhering uniformly to ceilings and walls, an excellent control effect can be exerted on specific harmful substances including harmful microorganisms and/or harmful fine substances in a space.
In the specific pest control method according to the present invention,
Preferably, the space is a small space having a volume of 2.0 to 18.8m 3.
According to the specific pest control method of the present constitution, particularly in a small space having a space volume of 2.0 to 18.8m 3, when spraying a specific pest control quantitative spray aerosol product, the spray particles do not remain excessively in the air, and a sufficient amount of the control component uniformly adheres to the ceiling and the wall surface, thereby exhibiting an excellent control effect on specific pests including harmful microorganisms and/or harmful fine substances.
In the specific pest control method according to the present invention,
The quantitative injection aerosol product for controlling specific pests is preferably injected so that the release amount of the specific pest control ingredient is 0.01 to 250mg/m 3.
According to the specific pest control method of the present configuration, by setting the amount of release of the specific pest control ingredient contained in the specific pest control quantitative injection aerosol product to the above-described range, the injection particles do not remain excessively in the air when the specific pest control quantitative injection aerosol product is injected into the space, and a sufficient amount of the control ingredient uniformly adheres to the ceiling and the wall surface, thereby exhibiting an excellent control effect on the specific pest including the harmful microorganism and/or the harmful fine substance.
Detailed Description
Hereinafter, the quantitative injection aerosol product for controlling specific pests and the specific pest control method according to the present invention will be described. However, the present invention is not intended to be limited to the configurations described below.
[ Quantitative spray aerosol product for controlling specific pests ]
The quantitative spray aerosol product for preventing and controlling specific harmful substances of the present invention is a quantitative spray aerosol for preventing and controlling specific harmful substances including harmful microorganisms and/or harmful fine substances in a space (particularly a small space), which is formed by filling an aerosol container provided with a quantitative spray valve with an aerosol collagen liquid containing a specific harmful substance preventing and controlling component and a solvent and a spray agent. The term "harmful microorganism" as used herein refers to a biological or biologically derived substance such as bacteria, mold, virus, mites, and pollen, and the term "harmful fine substance" refers to an abiotic or abiotic-derived substance such as house dust, PM2.5, yellow sand, and the like. In this specification, the term "harmful microorganism" and "harmful fine substance" are collectively referred to as "specific harmful substance". The "space" of the present invention includes, but is not particularly limited to, a gap space of less than 2.0m 3, a narrow space of the order of 2.0 to 18.8m 3, an indoor space of the order of 18.8 to 33.3m 3 (area 7.5 to 13.3m 2, height 2.2 to 3.0 m) corresponding to a room of 4.5 to 8 tatami, and a wide indoor space of the order of 33.3 to 66.6m 3 (area 13.3 to 26.6m 2, height 2.2 to 3.0 m) corresponding to a room of 8 to 16 tatami. The "small space" in which the quantitative spray aerosol product for controlling a specific pest of the present invention exhibits particularly excellent effects is assumed to be a space having a volume of about 2.0 to 18.8m 3, and examples thereof include closed or semi-closed spaces such as bathrooms, dressing rooms, toilets, closets, cupboards, automobiles, tents, warehouses, storehouses, garages, and hallways. More specifically, for example, a toilet or the like is used as a small space having a volume of 2.0 to 3.0m 3, and a bathroom or the like is used as a small space having a volume of 3.0 to 18.8m 3. The quantitative spray aerosol product for controlling specific pests of the present invention is a quantitative spray aerosol, and therefore the spray amount of the chemical is small, and further, by properly setting the specific gravity of the aerosol stock solution at 20 ℃ and the internal pressure of the aerosol container at 25 ℃, an excellent control effect on specific pests including harmful microorganisms and/or harmful fine substances in a space (particularly, a narrow space) is achieved. In the present specification, the harmful microorganisms are killed in addition to the effect of preventing the growth of harmful microorganisms by forming an environment where the growth of harmful microorganisms is difficult or existing, and thus the effect of preventing the growth is called a control effect together with the effect of preventing the growth. For example, when a mold is a control object, the mold-preventing effect and the mold-killing effect are included in the control effect. In addition, the harmful fine material is called a control effect together with the effect of preventing pollution because it is difficult for the harmful fine material to adhere to the environment such as a wall and the harmful fine material that has adhered to the wall is removed. For example, when the indoor dust is a control object, the dust-proof effect and the dust-removing effect are included in the control effect.
< Aerosol collagen liquid >)
Specific pest control components which are one of the main components of the aerosol-generating liquid include a bacterial control component, a mold control component, a virus control component, an allergen control component, and the like. The specific pest control ingredient may be used singly or in combination of plural kinds. In the specific pest control ingredient, when an asymmetric carbon-based optical isomer or a double bond-based geometric isomer is present, any one or any mixture thereof is also included in the present invention.
The bacterial control component is not particularly limited, but examples thereof include: phenol-based bacterial control components such as isopropyl methylphenol (IPMP), carvacrol, thymol, triclosan (Triclosan), methylparaben (Paraben), ethylparaben, propylparaben, butylparaben, 4-chloro-3, 5-dimethylphenol, o-phenylphenol, o-cresol, m-cresol, and p-cresol, benzalkonium chloride (Benzalkonium chloride), benzalkonium chloride (japanese: benzyl ammonium salts such as methyl sulfate, benzyl organic acid salts such as benzyl ammonium salt, benzyl ammonium chloride (Benzethonium chloride), benzyl ethonium (Japanese: benzyl ethonium salts such as benzyl ethonium salts, cetyl pyridinium chloride (Cetylpyridinium chloride), cetyl pyridinium (Japanese: benzyl methyl sulfate, cetyl pyridinium salts such as cetyl pyridinium salts, didecyl dimethyl ammonium chloride, didecyl dimethyl ammonium salts such as didecyl dimethyl ammonium methyl sulfate, didecyl dimethyl ammonium salts such as dilauryl dimethyl ammonium chloride, distearyl dimethyl ammonium chloride such as distearyl dimethyl ammonium methyl sulfate, distearyl dimethyl ammonium salts such as distearyl dimethyl ammonium methyl sulfate, 1, 4-bis [3,3'- (1-decylpyridinium) methoxy ] dibromobutane, 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] butane Cationic surfactant-based bacterial control components such as 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] butanedimethylsulfate and the like, and cationic surfactant-based bacterial control components such as chlorhexidine digluconate and the like, biguanide (Biguanide) -based bacterial control components, tebuconazole (Tebuconazole), azole-based bacterial control components such as Enconazole (Enilconazole) and the like, grapefruit seed extract, persimmon seed extract, fruit seed extract-based bacterial control components such as grape seed extract and the like, glycerol monolaurate (Monolaurin), glycerol monolaurate (Monocaprin), glycerol monolaurate (Monocaprylin) and the like, chlorhexidine-based bacterial control components such as chlorhexidine digluconate, chlorhexidine hydrochloride and the like, chlorhexidine-based bacterial control components such as chlorhexidine, octadecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, dodecyl diisopropyl (3-triethoxysilylpropyl) ammonium chloride, tetradecyldimethyl (3-triethoxysilylpropyl) ammonium chloride, diethoxysilylpropyl (3-diethoxypropyl) ammonium chloride, tetradecylpropyl (3-diethoxypropyl) ammonium chloride, and diethoxypropyl (3-diethoxypropyl) ammonium chloride, A silicon-based bacterial control component such as pentadecyl di-N-propyl (3-triethoxysilylpropyl) ammonium chloride, cetyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, cetyl diethyl (3-triethoxysilylpropyl) ammonium chloride, cetyl di-N-propyl (3-triethoxysilylpropyl) ammonium chloride, octadecyl diethyl (3-triethoxysilylpropyl) ammonium chloride, octadecyl di-N-propyl (3-triethoxysilylpropyl) ammonium chloride, a carboxylic acid-based bacterial control component such as benzoic acid, salicylic acid, sorbic acid, ethylenediamine tetraacetic acid (EDTA), glycine, alkyl diethylaminoglycine, and polylysine, or a salt thereof, dehydroacetic acid, chloramine (Chloramine), 3-iodo-2-propyl-N-butylcarbamate (IPBC), phenoxyethanol, silver-based bacterial control components such as silver zeolite, zinc pyrithione (Zinc), thiamine dilauryl sulfate (solar sulfate), refined proteins, and hydroxy alkyl chitosan, or a salt thereof. Among these bacterial control components, preferred are isopropyl methylphenol (IPMP), carvacrol, thymol, benzalkonium chloride, 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] dibromobutane, glyceryl monocaprylate and tebuconazole.
The mold control component is not particularly limited, but examples thereof include: isopropyl methylphenol (IPMP), carvacrol, thymol, triclosan, methyl parahydroxybenzoate, ethyl parahydroxybenzoate, propyl parahydroxybenzoate, butyl parahydroxybenzoate, 4-chloro-3, 5-dimethylphenol, phenol-o-phenylphenol, o-cresol, m-cresol and p-cresol phenol-based mold-control components, benzalkonium chloride, benzalkonium methosulfate, benzalkonium salts such as benzalkonium organic acid salts, benzethonium chloride, benzethonium methosulfate, benzethonium salts such as benzethonium organic acid salts, cetylpyridinium chloride, cetylpyridinium methyl sulfate, cetylpyridinium salts such as cetylpyridinium organic acid salts, didecyl dimethyl ammonium chloride, didecyl dimethyl ammonium methyl sulfate, didecyl dimethyl ammonium salt such as didecyl dimethyl ammonium methyl sulfate cationic surfactant-based mold control component such as dilauryldimethylammonium salt such as dilauryldimethylammonium chloride and dilauryldimethylammonium methylsulfate, distearyldimethylammonium salt such as distearyldimethylammonium chloride and distearyldimethylammonium methylsulfate, distearyldimethylammonium salt such as 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] dibromobutane, 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] dichlorobutane and 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] butane dimethyl sulfate, 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] butane salt such as 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] butane, biguanide-based mold control component, azole-based mold control component such as tebuconazole and Enconazole, grapefruit seed extract, persimmon seed extract, fruit seed extract such as grape seed extract, and other fruit seed extract, such as mold control component, glycerol monolaurate, glycerol monocaprylate, and other glycerol monofatty acid ester, chlorhexidine digluconate, chlorhexidine salts such as chlorhexidine hydrochloride, chlorhexidine based mold control component such as chlorhexidine, octadecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, dodecyl diisopropyl (3-triethoxysilylpropyl) ammonium chloride, tetradecyldimethyl (3-triethoxysilylpropyl) ammonium chloride, tetradecyldiethyl (3-triethoxysilylpropyl) ammonium chloride, tetradecyldi-n-propyl (3-triethoxysilylpropyl) ammonium chloride, pentadecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, pentadecyl diethyl (3-triethoxysilylpropyl) ammonium chloride, hexadecyldimethyl (3-triethoxysilylpropyl) ammonium chloride, hexadecyldiethyl (3-triethoxysilylpropyl) ammonium chloride, and octadecyl diethyl (3-triethoxysilylpropyl) ammonium chloride, silicon-based mold control components such as octadecyl di-N-propyl (3-triethoxysilylpropyl) ammonium chloride, benzoic acid, salicylic acid, sorbic acid, ethylenediamine tetraacetic acid (EDTA), glycine, alkyl diethylaminoglycine, and carboxylic acid-based mold control components such as polylysine, salts thereof, dehydroacetic acid, chloramine, 3-iodo-2-propyl-N-butylcarbamate (IPBC), silver-based mold control components such as phenoxyethanol and silver zeolite, zinc pyrithione, dilauryl thiamine sulfate, protamine, hydroxyalkyl chitosan, salts thereof, and mold-proofing fragrances. Among these mold control components, preferred are isopropyl methylphenol (IPMP), carvacrol, thymol, benzalkonium chloride, 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] dibromobutane, glyceryl monocaprylate, and tebuconazole.
The virus-controlling component is not particularly limited, but examples thereof include: isopropyl methylphenol (IPMP), carvacrol, thymol, triclosan, methyl parahydroxybenzoate, ethyl parahydroxybenzoate, propyl parahydroxybenzoate, butyl parahydroxybenzoate, 4-chloro-3, 5-dimethylphenol, o-phenylphenol, o-cresol, m-cresol and p-cresol and other phenol-based virus control components, benzalkonium chloride, benzalkonium methosulfate, benzalkonium salts such as benzalkonium organic acid salts, benzethonium chloride, benzethonium methosulfate, benzethonium organic acid salts such as benzethonium organic acid salts, cetylpyridinium chloride, cetylpyridinium methyl sulfate, cetylpyridinium salts such as cetylpyridinium organic acid salts, didecyl dimethyl ammonium chloride, didecyl dimethyl ammonium methyl sulfate, didecyl dimethyl ammonium salt such as didecyl dimethyl ammonium methyl sulfate cationic surfactant-based virus control component such as dilauryldimethylammonium salt such as dilauryldimethylammonium chloride and dilauryldimethylammonium methylsulfate, distearyldimethylammonium salt such as distearyldimethylammonium chloride and distearyldimethylammonium methylsulfate, distearyldimethylammonium salt such as 1, 4-bis [3,3'- (1-decylpyridinium) methoxy ] dibromobutane, 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] dichlorobutane, 1, 4-bis [3,3'- (1-decylpyridinium) methoxy ] butane dimethyl sulfate, 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] butane, biguanide-based virus control component, azole-based virus control component such as tebuconazole and Enconazole, grapefruit seed extract, persimmon seed extract, fruit seed extract-based virus control component such as grape seed extract, glycerol monofatty acid ester-based virus control component such as glycerol monolaurate, glycerol monocaprylate, chlorhexidine salts such as chlorhexidine digluconate and chlorhexidine hydrochloride, chlorhexidine-based virus control component such as chlorhexidine, octadecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, dodecyl diisopropyl (3-triethoxysilylpropyl) ammonium chloride, tetradecyldimethyl (3-triethoxysilylpropyl) ammonium chloride, tetradecyldiethyl (3-triethoxysilylpropyl) ammonium chloride, tetradecyldi-n-propyl (3-triethoxysilylpropyl) ammonium chloride, pentadecyl dimethyl (3-triethoxysilylpropyl) ammonium chloride, pentadecyl diethyl (3-triethoxysilylpropyl) ammonium chloride, hexadecyldimethyl (3-triethoxysilylpropyl) ammonium chloride, hexadecyldiethyl (3-triethoxysilylpropyl) ammonium chloride, hexadecylpropyl (3-triethoxysilylpropyl) ammonium chloride, and octadecyl diethyl (3-triethoxysilylpropyl) ammonium chloride, silicon virus control components such as octadecyl di-N-propyl (3-triethoxysilylpropyl) ammonium chloride, carboxylic acid virus control components such as benzoic acid, salicylic acid, sorbic acid, ethylenediamine tetraacetic acid (EDTA), glycine, alkyl diethylaminoglycine, and polylysine, or salts thereof, silver virus control components such as dehydroacetic acid, chloramine, 3-iodo-2-propyl-N-butylcarbamate (IPBC), phenoxyethanol, and silver zeolite, zinc pyrithione, dilauryl thiamine sulfate, protamine, and hydroxyalkyl chitosan, or salts thereof. Among these virus control components, preferred are isopropyl methylphenol (IPMP), carvacrol, thymol, benzalkonium chloride, 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] dibromobutane, glyceryl monocaprylate and tebuconazole.
The allergen-controlling component is not particularly limited, but may be a mite-controlling component, a pollen-controlling component, a house dust-controlling component, or the like, and the mite-controlling component may be: sulfamethoate (Amidoflumet), benzyl benzoate, phenyl salicylate, benzyl salicylate, cyclohexyl salicylate, dibutyl sebacate, dipropyl sebacate, dibutyl adipate, diethyl phthalate, dipropyl phthalate, dibutyl phthalate, p-menthane-3, 8-diol (PMD), 3-iodo-2-propynylbutylcarbamate (IPBC), phenothrin (Phenothrin), elcatrietin (Icaridin), ethyl butylacetylaminopropionate (IR 3535), and mosquito repellent amine (DEET), and the like. Examples of the pollen control ingredient or the house dust control ingredient include: poly (2- (meth) acryloyloxyalkylphosphocholine (Phosphocholine), 2- (meth) acryloyloxyalkylphosphocholine- (meth) acrylic acid copolymer, 2- (meth) acryloyloxyalkylphosphocholine- (meth) acrylic acid-alkyl ester copolymer, 2- (meth) acryloyloxyalkylphosphocholine-1- (meth) acryloyloxy 2-hydroxyalkyl 3-trialkylammonium copolymer, N- (meth) acryloyloxyalkyl N, N-dialkylammonium- α -N- (alkyl) carboxybetaine-N- (meth) acrylic acid-alkyl ester copolymer, N-phosphorylcholine-N' -alkylenedioxy-bis-alkylacrylamide-N-isoalkylacrylamide copolymer, poly (N, N-di (alkyl) ammonium- α -N-alkylsulfonbetaine (meth) acrylic acid, hydroxyalkylchitosan or salts thereof, titanium oxide, and the like.
The content of the specific pest control ingredient in the aerosol-type collagen liquid is preferably 0.01 to 70w/v%, more preferably 0.05 to 50w/v%, still more preferably 0.1 to 40w/v%. When the content of the specific pest control ingredient in the aerosol stock solution is in the range of 0.01 to 70w/v%, a sufficient amount of the pest control ingredient is uniformly adhered to the ceiling and the wall surface when the aerosol is sprayed in a space (particularly, a small space), and therefore, an appropriate pest control effect on the specific pest including the pest microorganism and/or the pest fine substance can be obtained.
Examples of the organic solvent that is one of the main components of the aerosol collagen liquid include: lower alcohols having 2 to 3 carbon atoms such as ethanol and isopropyl alcohol (IPA), hydrocarbon solvents such as normal paraffins and isoparaffins, higher fatty acid esters having 16 to 20 carbon atoms such as isopropyl myristate (IPM), glycol ether solvents having 3 to 10 carbon atoms, ketone solvents, and the like. Among these, in order to obtain an excellent control effect on specific pests including harmful microorganisms and/or harmful fine substances by uniformly adhering a sufficient amount of a control component to the ceiling and wall surfaces without excessively leaving the particles in the air, a lower alcohol having 2 to 3 carbon atoms, a hydrocarbon solvent, and a higher fatty acid ester having 16 to 20 carbon atoms are preferable, and a lower alcohol having 2 to 3 carbon atoms, which also has a bacterial control effect, a virus control effect, and the like, is more preferable. The organic solvent may be used alone or in a mixture of a plurality of types, but from the viewpoint of simplifying the production process, it is preferable to use only one type of component. In addition, an aqueous solvent such as water may be mixed in addition to the organic solvent.
The specific gravity of the aerosol stock solution at 20 ℃ is set to 0.76 to 0.95, preferably 0.76 to 0.90, more preferably 0.76 to 0.88. The specific gravity of the aerosol stock solution at 20 ℃ is an important factor related to sedimentation of the sprayed particles, and if the specific gravity of the aerosol stock solution at 20 ℃ is 0.76 to 0.95, a sufficient amount of the control component after spraying can be uniformly adhered to the ceiling and wall surface in a space (particularly, a narrow space). Harmful microorganisms such as mold and bacteria tend to be generated and propagated in large amounts in ceilings, walls, and the like where cleaning is difficult, and even in the case of harmful fine substances such as house dust, the harmful fine substances tend to adhere to ceilings and walls, and thus, by means of a sufficient amount of the control component adhering uniformly to ceilings and walls, excellent control effects can be exerted on specific harmful substances including harmful microorganisms and/or harmful fine substances in a space (particularly, a narrow space).
In addition to the above components, the aerosol collagen liquid may be appropriately blended with an insecticidal component, a repellent, a fragrance, a deodorant, a stabilizer, an antistatic agent, an antifoaming agent, an excipient, and the like, as long as the gist of the present invention is not impaired. Examples of the insecticidal component include: transfluthrin, bifenthrin, profluthrin, cycloprothrin, furethrin, enemthrin (Empenthrin), momfluorothrin (CAS: -29-4, japanese: mevalonate (), tetrafluoromethyverhrin (), halothrin (), tefluthrin (), phenothrin (), fenpropathrin (), permethrin (), cypermethrin (), flucythrin (), bifenthrin (), fenpropathrin (), tetrabromothrin (), ethofenthrin (), prallethrin () pyrethroid compounds such as bifenthrin () and natural pyrethrin (), silicone compounds such as silafluofen (), organophosphorus compounds such as dichlorvos (), fenitrothion (), carbamate compounds such as propoxur (), anabasine compounds such as dinotefuran (), imidacloprid (), clothianidin (), fenpropi (Fipronil), indoxacarb (), brofenbendiamide (), and oxadiazon (), and the like, there may be mentioned: mosquito repellent amine (DEET), ethyl butyl acetamido propionate (IR 3535), p-menthane-3, 8-diol, and ecaritol (Icaridin), and the like. Examples of the fragrance include: aromatic components such as orange oil, lemon oil, lavender oil, peppermint oil, eucalyptus oil, citronella oil, lyme oil, grapefruit oil, jasmine oil, juniper oil, green tea essential oil, peppermint oil, menthol, menthyl acetate, limonene, α -pinene, linalool, geraniol, phenylethyl alcohol, amyl cinnamaldehyde, cumyl aldehyde, terpineol, and benzyl acetate, and perfume components containing green leaf alcohol or green leaf aldehyde called "green fragrance" are blended. In the case where an asymmetric carbon-based optical isomer or a double bond-based geometric isomer of each component exists, each of them may be used or any mixture thereof may be used.
The quantitative injection aerosol product for controlling specific harmful substances of the present invention may be formulated as an aqueous formulation. In this case, the amount of water contained in the aerosol stock solution is not particularly limited, but is preferably 5 to 80v/v%, and a small amount of nonionic surfactant may be added as a solubilizing aid within a range that does not affect the spray pattern of the spray particles. Examples of the nonionic surfactant include: polyoxyethylene alkyl ethers, polyoxyethylene alkylphenyl ethers, polyoxyethylene polyoxypropylene alkyl ethers, and ethers such as polyoxyethylene alkyl amino ethers, polyethylene glycol fatty acid esters, polyoxyethylene sorbitan fatty acid esters, and fatty acid esters such as polyoxyethylene glycerin fatty acid esters, polyoxyethylene styrenated phenols, and polyalkylene alkanolamides of fatty acids.
< Propellant >)
The propellant used in the quantitative spray aerosol product for controlling a specific pest of the present invention is not particularly limited, but examples thereof include: liquefied Petroleum Gas (LPG) such as propane and butane, liquefied gas such as hydrofluoroolefins such as n-pentane, isopentane, dimethyl ether (DME) and HFO1234ze, and other gases such as nitrogen, carbonic acid gas, nitrous oxide and compressed air. The propellant may be used alone or in a mixed state, but is preferably composed of LPG or hydrofluoroolefins because a sufficient amount of a control component is uniformly adhered to the ceiling and wall surface so that the particles are not excessively left in the air, and a more excellent control effect can be exerted on specific pests including harmful microorganisms and/or harmful fine substances in a space (particularly a narrow space). The propellant is preferably used by adjusting the gauge pressure (20 ℃) to 0.10 to 0.70 MPa.
In the quantitative spray aerosol product for controlling a specific pest of the present invention, the volume ratio (a/b) of the aerosol-forming liquid (a) to the propellant (b) in the aerosol container is preferably set to 1/99 to 70/30 by volume, more preferably 10/90 to 60/40, still more preferably 20/80 to 55/45 from the viewpoint of adhesion of the chemical to the ceiling and wall surfaces. When the volume ratio (a/b) is within the above range, the particles to be sprayed are not excessively left in the air and adhere to the ceiling and wall surface when the aerosol is sprayed in the space (particularly, a small space), and therefore a sufficient amount of the specific pest control ingredient can be uniformly adhered to the ceiling and wall surface. Thus, the effect of preventing and removing specific harmful substances including harmful microorganisms and/or harmful fine substances can be obtained properly, and the feeling of irritation to the human can be reduced.
The internal pressure of the aerosol container of the quantitative injection aerosol product for controlling specific pests according to the present invention is set to 0.60MPa or less, preferably 0.10 to 0.60MPa, more preferably 0.20 to 0.60MPa, and even more preferably 0.30 to 0.50MPa at 25 ℃. When the internal pressure is 0.60MPa or less at 25 ℃, a sufficient amount of the specific pest control ingredient can be adhered to the ceiling or wall surface when the aerosol is sprayed in a space (particularly, a narrow space). If the internal pressure exceeds 0.60MPa, the force of the jet is too strong, so that when the jet reaches the wall surface, a part of the jet particles rebound, and there is a possibility that the uniformity of diffusion of adhesion to the ceiling or the wall surface becomes insufficient. The internal pressure of such an aerosol product can be appropriately adjusted by the type of propellant, the vapor pressure of the propellant, and the like. The aerosol container may be a pressure-resistant container capable of withstanding an internal pressure of 0.60MPa, and examples of the material thereof include metals such as aluminum and tin plating, synthetic resins such as polyethylene terephthalate, pressure-resistant glass, and the like. In addition, when the aerosol container is made of synthetic resin, it may be translucent or transparent. In the present embodiment, the internal pressure of the aerosol container of the quantitative injection aerosol product for controlling a specific pest is measured by the following procedure.
(1) A quantitative spray aerosol product for controlling specific harmful substances was immersed in a constant temperature water tank at 25.+ -. 0.5 ℃ for 30 minutes.
(2) Next, the quantitative spray aerosol product for specific pest control was set in an upright state, and a stem of an aerosol container was air-tightly inserted into an insertion port of a pressure gauge, and the measured pressure was read to the 2 nd decimal place.
(3) The above measurement was performed 1 time, and the read value was set as the internal pressure value, instead of rounding the measured value.
In the quantitative spray aerosol product for controlling a specific pest of the present invention, the spray force is preferably 2.0 to 40.0gf, more preferably 2.0 to 35.0gf, even more preferably 3.0 to 30.0gf, and particularly preferably 5.0 to 20.0gf at a distance of 15cm from the spray opening. When the spraying force is in the above range, a sufficient amount of the specific pest control ingredient uniformly adheres to the ceiling and the wall surface when spraying the aerosol in the space (particularly, a small space), and a practically sufficient control effect on the specific pest including the harmful microorganism and/or the harmful fine substance is obtained. If the spraying force is less than 2.0gf, the spraying force may be insufficient, and the adhesion amount of the specific pest control ingredient to the ceiling or wall surface may be insufficient, whereas if the spraying force exceeds 40.0gf, the spraying force is too strong, and therefore when the wall surface is reached, a part of the sprayed particles rebound, and there is a possibility that the uniformity of diffusion at the ceiling or wall surface becomes insufficient. Such ejection force can be appropriately adjusted by the composition of the aerosol liquid, the type of the ejection agent, the internal pressure of the aerosol product, the size and shape of the ejection orifice, and the like. In the present embodiment, the injection force of the quantitative injection aerosol product for controlling specific pests was measured by a digital dynamometer (FGC-0.5, manufactured by japan electric power generation and new co).
The quantitative injection aerosol product for preventing and eliminating specific harmful matters is provided with a quantitative injection valve for performing quantitative injection treatment in a space. The injection capacity of the quantitative injection valve is set to 0.08 to 3.0mL, preferably 0.08 to 2.0mL, more preferably 0.1 to 1.0mL, and even more preferably 0.2 to 0.9mL. When the spraying capacity per time is within the above range, a sufficient amount of the specific pest control ingredient can be uniformly adhered to the ceiling and wall surface, and an excellent pest control effect on the specific pest including the harmful microorganism and/or the harmful fine substance can be obtained.
The ejection member (ejection button) is a member attached to the aerosol container via a metering jet valve. An injection port that injects aerosol stock solution and an injection agent obtained from an aerosol container through a stem hole of a metering injection valve is formed on the injection member. The ejection orifice diameter of the ejection member is preferably 0.2 to 1.0mm. If the injection port diameter is in the above range, the injection force can be adjusted to an appropriate range. The shape (cross-sectional shape) of the ejection opening is not particularly limited, but a polygon such as a circle or a quadrangle, an ellipse, or the like is exemplified, and a circle is preferable. Here, the jet port diameter refers to the major diameter of an ellipse when the jet port is elliptical in shape, and refers to the diameter of a circumscribed circle of a polygon when the jet port is polygonal in shape.
In the quantitative injection aerosol product for controlling specific pests according to the present invention, the release amount of the specific pest control ingredient to the air is preferably set to 0.01 to 250mg/m 3, more preferably set to 0.025 to 125mg/m 3. When the amount of the specific pest control ingredient released into the air is within the above range, the effect of controlling the specific pest including the harmful microorganism and/or the harmful fine substance is properly exhibited in the space, and the specific pest including the harmful microorganism and/or the harmful fine substance can be reliably controlled. The quantitative injection aerosol product for controlling a specific pest of the present invention may be configured such that the amount of the specific pest control ingredient released into the air is 0.01 to 250mg/m 3 by 1 injection, or the amount of the specific pest control ingredient released into the air may be set such that the amount of the specific pest control ingredient released into the air is 0.01 to 250mg/m 3 by 2 or more injections. In view of obtaining an excellent control effect on a specific pest including a pest microorganism and/or a pest fine substance by uniformly adhering a sufficient amount of the specific pest control ingredient to a ceiling or a wall surface, the amount of the specific pest control ingredient released into the air is preferably set to 0.01 to 250mg/m 3 by 2 or more injections. The amount of the specific pest control ingredient released can be appropriately adjusted in the above-described ranges by adjusting the composition of the aerosol stock solution, the volume ratio (a/b) of the aerosol stock solution (a) to the propellant (b), the injection volume of each of the quantitative injection valves, and the like.
The quantitative spray aerosol product for controlling a specific pest according to the present invention can make a space an environment capable of controlling a specific pest including a harmful microorganism and/or a harmful fine substance in about 7 to 14 days, usually by 1 application. The period in which a specific pest including a harmful microorganism and/or a harmful fine substance can be controlled may be set to be less than 7 days or more than 14 days by adjusting the composition of the aerosol collagen liquid, the type of the propellant, the specific gravity of the aerosol stock solution at 20 ℃, the internal pressure of the aerosol container, and the like.
< Specific pests >)
The specific harmful substances to be controlled in the present invention include organisms such as bacteria, mold, viruses, mites, and pollen, or substances derived from organisms, and the harmful fine substances include non-organisms such as house dust, PM2.5, and yellow sand, or substances derived from non-organisms. The harmful microorganisms and the harmful fine substances include allergens. The quantitative spray aerosol product for preventing and removing specific harmful substances of the present invention can more effectively prevent and remove bacteria and mold, which are liable to be generated and propagated in a large amount on ceilings and walls which are difficult to clean, among the specific harmful substances.
[ Method for controlling specific pests ]
The specific pest control method of the present invention is carried out by spraying the quantitative spray aerosol product for specific pest control described above in a room facing space (preferably a small space having a volume of 2.0 to 18.8m 3). When the specific pest control method of the present invention is carried out, a sufficient amount of the control component uniformly adheres to the ceiling and the wall in a space (particularly, a small space), and an excellent control effect is exhibited on specific pests containing harmful microorganisms and/or harmful fine substances. The amount of the specific pest control quantitative injection aerosol product to be injected is preferably adjusted so that the amount of the specific pest control ingredient released into the air is 0.01 to 250mg/m 3, more preferably 0.025 to 125mg/m 3. When the amount of the specific pest control ingredient released is within the above range, a more excellent control effect can be exerted on the specific pest including the pest microorganism and/or the pest fine substance.
Examples
In order to verify the effect of the quantitative spray aerosol product for controlling a specific pest of the present invention, quantitative spray aerosol products for controlling a specific pest of the present invention (examples 1 to 16) having the characteristic constitution of the present invention were prepared, and (1) tests for evaluating the adhesion and diffusion uniformity of the ceiling/wall surface of the specific pest controlling component were performed.
For comparison, quantitative injection aerosol products (comparative examples 1 to 3) having no characteristic constitution of the present invention were prepared, and the same test was performed. Further, using the quantitative spray aerosol products for controlling specific pests of examples 1, 4, 8, 14, and 15, (2) tests for evaluating use in bathrooms were performed.
Example 1
An aerosol stock solution was prepared by dissolving isopropyl methylphenol (IPMP) (15 w/v%) as a specific pest control ingredient in ethanol as an organic solvent. The specific gravity of the aerosol stock solution at 20 ℃ is 0.82. 12mL of the aerosol stock solution (a) and 18mL of liquefied petroleum gas (b) as a propellant were pressurized and filled into an aerosol container (pressure-resistant container) having a quantitative injection valve with an injection capacity of 0.4mL so that the volume ratio (a/b) became 40/60, thereby obtaining a quantitative injection aerosol product for specific pest control in example 1. The internal pressure of the quantitative spray aerosol product for controlling specific harmful substances at 25 ℃ was 0.45MPa, and the spray amount of the specific harmful substance controlling component per spray was 24mg. The ejection force at the ejection distance of 15cm was 6.5gf.
Comparative example 1
Isopropyl methylphenol (IPMP) (15 w/v%) as a control component was dissolved in ethanol as an organic solvent to prepare 30mL of an aerosol stock solution. The specific gravity of the aerosol stock solution at 20 ℃ is 0.82. The aerosol collagen liquid was placed in a container having a pump type spray head with a spray capacity of 0.2mL for 1 time, to obtain a pump type spray product of comparative example 1. The amount of the control component sprayed per one spray of the pump spray product was 30mg. The ejection force at the ejection distance of 15cm was 2.0gf.
Examples 2 to 16 and comparative examples 2 to 3
By following the procedure of example 1, various aerosol articles shown in table 1 were prepared. The specific quantitative spray aerosol product for pest control of example 8 was an aerosol container with a 1-time spray valve having a spray capacity of 0.2mL, and the specific quantitative spray aerosol products for pest control of examples 1,3, 4, 6, 9, 11 to 13 and 16 and the comparative examples 2 to 3 were aerosol containers with a 1-time spray valve having a spray capacity of 0.4mL, and the specific quantitative spray aerosol products for pest control of examples 2,5, 7, 10, 14 and 15 were aerosol containers with a 1-time spray valve having a spray capacity of 1.0 mL.
TABLE 1
In Table 1 above, IPMP represents isopropyl methylphenol, compound A represents 1, 4-bis [3,3' - (1-decylpyridinium) methoxy ] dibromobutane, IPBC represents 3-iodo-2-propyl-N-butylcarbamate, IPA represents isopropyl alcohol, IPM represents isopropyl myristate, LPG represents liquefied petroleum gas, HFO1234ze represents trans-1, 3-tetrafluoropropane. The specific gravity (20 ℃) of each component was IPMP:0.97, thymol: 0.97, benzalkonium chloride 10% aqueous solution: 0.98, tebuconazole: 1.25, glycerol monocaprylate: 0.99, glyceryl monocaprylate: 0.99, IPBC:1.61, ethanol: 0.79, IPA:0.79, neo-chiozol:0.76, IPM:0.86, hexyl laurate: 0.86.
Tests for evaluating the adhesion to the ceiling and wall surfaces and the uniformity of diffusion of specific pest control ingredients were conducted in examples 1 to 16 and comparative examples 1 to 3 (1). The test results are shown in Table 2.
(1) Ceiling/wall adhesion and diffusion uniformity of specific pest control ingredient
Glass plates of 20cm×20cm were placed on the floor 6, ceiling 2 and wall 4 of a closed small room (width 1.8m, depth 1.3m and height 1.8 m) having a volume of 4.2m 3. Standing at one of the 4 corners of the cubicle, the aerosol product to be tested was sprayed 2 times in a slightly obliquely upward direction from a height of 1m from the floor toward the center of the space. After 20 minutes from the spraying, the glass plate provided on the floor, the glass plate provided on the ceiling, and the glass plate provided on the wall were taken out, and the specific harmful substance-removing component attached thereto was washed out with acetone, and analyzed by gas chromatography. Based on the analysis values obtained, the proportion of the amount of the control component adhering to the ceiling and the wall surface relative to the amount of the control component adhering to the floor surface was determined from the spray treatment for 20 minutes, and the ceiling/wall surface adhesion was evaluated. The evaluation results were shown in the order of A, B, C stages from the ceiling and wall adhesion to the good. The diffusion uniformity was evaluated based on the amounts of the control components attached to the ceiling and the wall, respectively. For the evaluation results, the 3-stage representation of A, B, C was performed in order from the one with good diffusion uniformity.
TABLE 2
As a result of the test, the ceiling and wall adhesion of the specific pest control ingredient was good, as compared with the quantitative injection aerosol products for pest control of examples 1 to 16. Among them, examples 1,3 to 10 and 12 to 15 having a specific gravity of 0.76 to 0.88 at 20℃are excellent in that not only the ceiling/wall adhesion of the specific pest control ingredient is good, but also the diffusion uniformity is good. From these results, it was found that the quantitative injection aerosol product for controlling specific pests according to the present invention has a confirmed effect of controlling specific pests including harmful microorganisms and/or harmful fine substances in a space.
In contrast, the pump-type spray product of comparative example 1 and the quantitative spray aerosol product of comparative example 3 in which the specific gravity of the aerosol stock solution exceeds 0.95 at 20 ℃ had low ceiling/wall adhesion as the control component. This is considered as follows: the pump-type spray product of comparative example 1 and the quantitative spray aerosol product of comparative example 3 were insufficient in the effect of controlling specific harmful substances including harmful microorganisms and/or harmful fine substances in the space.
The quantitative injection aerosol product of comparative example 2 having an internal pressure exceeding 0.60MPa at 25 ℃ is insufficient in terms of uniformity of diffusion to the ceiling and wall surfaces.
(2) Use in bathroom
Test example 1
The quantitative spray aerosol product for pest control of example 1 was sprayed 4 times from the inlet into a bath having a volume of 4m 3 (area 2m 2, height 2 m). After 14 days, it was confirmed that pink mucus (bacteria) or black mold (mold) was not generated in the bath room. That is, pink mucus (bacteria) or black mold (mold) can be prevented and removed in 14 days or more. In addition, during the spraying operation in the bathroom, no stimulus such as choking is felt.
Test example 2
The quantitative spray aerosol product for pest control of example 4 was sprayed 2 times from the inlet into a bath having a volume of 4m 3 (area 2m 2, height 2 m). After 14 days, it was confirmed that no pink mucus (bacteria) or black mold (mold) was produced in the bath. That is, pink mucus (bacteria) or black mold (mold) can be prevented and removed in 14 days or more. In addition, during the spraying operation in the bathroom, no stimulus such as choking is felt.
Test example 3
The quantitative spray aerosol product for pest control of example 8 was sprayed 2 times from the inlet in a bathroom having a volume of 4m 3 (area 2m 2, height 2 m). After 7 days, it was confirmed that no pink mucus (bacteria) or black mold (mold) was produced in the bath. That is, pink mucus (bacteria) or black mold (mold) can be prevented and removed in 7 days or more. In addition, during the spraying operation in the bathroom, no stimulus such as choking is felt.
Test example 4
The quantitative spray aerosol product for pest control of example 14 was sprayed 4 times from the inlet into a bath having a volume of 4m 3 (area 2m 2, height 2 m). After 7 days, it was confirmed that no pink mucus (bacteria) or black mold (mold) was produced in the bath. That is, pink mucus (bacteria) or black mold (mold) can be prevented and removed in 7 days or more. In addition, during the spraying operation in the bathroom, no stimulus such as choking is felt.
Test example 5
The quantitative spray aerosol product for pest control of example 15 was sprayed 4 times from the inlet into a bath having a volume of 4m 3 (area 2m 2, height 2 m). After 14 days, it was confirmed that no pink mucus (bacteria) or black mold (mold) was produced in the bath. That is, pink mucus (bacteria) or black mold (mold) can be prevented and removed in 14 days or more. In addition, during the spraying operation in the bathroom, no stimulus such as choking is felt.
Industrial applicability
The quantitative spray aerosol product for controlling specific pests and the method for controlling specific pests according to the present invention can be used for the purpose of controlling specific pests containing harmful microorganisms and/or harmful fine substances in a space, particularly in a small space such as a bathroom or a toilet.
Claims (3)
1. A method for controlling a specific pest, which comprises spraying a specific pest control aerosol product for controlling a specific pest comprising a harmful microorganism and/or a harmful fine substance in a space,
The quantitative spray aerosol product for preventing and controlling specific harmful substances is formed by filling aerosol containers with a quantitative spray valve with aerosol collagen liquid containing specific harmful substance preventing and controlling components and organic solvent and a spray agent,
The specific gravity of the aerosol stock solution is 0.76-0.95 at 20 ℃,
The injection capacity of each quantitative injection valve is set to be 0.2 mL-0.9 mL,
In the aerosol container, the volume ratio a/b of the aerosol collagen liquid a and the propellant b is set to 20/80-70/30 by volume ratio,
In the aerosol container, the internal pressure is set to be below 0.60MPa at 25 ℃,
The quantitative injection aerosol product for specific pest control is injected by injecting 2 or more times toward a narrow space in a house having a volume of 2.0m 3～18.8m3 so that the release amount of the specific pest control component is 0.01mg/m 3～250mg/m3.
2. The method for controlling a specific pest according to claim 1, wherein the organic solvent is at least one selected from the group consisting of a lower alcohol having 2 to 3 carbon atoms, a higher fatty acid ester having 16 to 20 carbon atoms, and a hydrocarbon solvent.
3. The specific pest control method according to claim 1 or 2, wherein the propellant is liquefied petroleum gas and/or hydrofluoroolefin.
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| PCT/JP2021/009146 WO2021182433A1 (en) | 2020-03-13 | 2021-03-09 | Fixed-amount spray aerosol product for controlling specific hazardous things, and method for controlling specific hazardous things using same |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104203773A (en) * | 2012-03-30 | 2014-12-10 | 株式会社大造 | Aerosol product and method for manufacturing same |
| CN106163274A (en) * | 2014-04-18 | 2016-11-23 | 大日本除虫菊株式会社 | Mosquito class is prevented and kill off with aerosol and mosquito class the method for control |
| CN107427419A (en) * | 2015-03-20 | 2017-12-01 | 东洋喷雾工业株式会社 | Biliquid mixed type aerosol denfifrice |
| CN109414522A (en) * | 2016-07-06 | 2019-03-01 | 雷克特本克斯尔(品牌)有限公司 | Preparation with fresh air |
| WO2019117164A1 (en) * | 2017-12-12 | 2019-06-20 | アース製薬株式会社 | Metered-spray aerosol, method for spraying metered-spray aerosol, and method for improving effect of chemical agent |
| JP2019202949A (en) * | 2018-05-22 | 2019-11-28 | アース製薬株式会社 | All-quantity ejection aerosol product for mold prevention and mold prevention method |
| CN110709109A (en) * | 2017-06-22 | 2020-01-17 | 大日本除虫菊株式会社 | Deodorant aerosol |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5517122B2 (en) * | 2009-08-20 | 2014-06-11 | 大日本除蟲菊株式会社 | How to control pests and ticks |
| JP5695344B2 (en) * | 2010-05-24 | 2015-04-01 | フマキラー株式会社 | Anti-mold aerosol device |
| JP6034658B2 (en) * | 2012-10-29 | 2016-11-30 | 大日本除蟲菊株式会社 | Clothing pest control method |
| JP2015017083A (en) * | 2013-06-11 | 2015-01-29 | 大日本除蟲菊株式会社 | Aerosol for mosquito control and mosquito control method using the same |
| JP7268965B2 (en) * | 2018-06-05 | 2023-05-08 | アース製薬株式会社 | Quantitative injection type aerosol product and deodorizing method |
| CN115568465A (en) * | 2018-12-14 | 2023-01-06 | 大日本除虫菊株式会社 | Method for controlling pests and mites, and aerosol for controlling pests and mites |
-
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Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104203773A (en) * | 2012-03-30 | 2014-12-10 | 株式会社大造 | Aerosol product and method for manufacturing same |
| CN106163274A (en) * | 2014-04-18 | 2016-11-23 | 大日本除虫菊株式会社 | Mosquito class is prevented and kill off with aerosol and mosquito class the method for control |
| CN107427419A (en) * | 2015-03-20 | 2017-12-01 | 东洋喷雾工业株式会社 | Biliquid mixed type aerosol denfifrice |
| CN109414522A (en) * | 2016-07-06 | 2019-03-01 | 雷克特本克斯尔(品牌)有限公司 | Preparation with fresh air |
| CN110709109A (en) * | 2017-06-22 | 2020-01-17 | 大日本除虫菊株式会社 | Deodorant aerosol |
| WO2019117164A1 (en) * | 2017-12-12 | 2019-06-20 | アース製薬株式会社 | Metered-spray aerosol, method for spraying metered-spray aerosol, and method for improving effect of chemical agent |
| JP2019202949A (en) * | 2018-05-22 | 2019-11-28 | アース製薬株式会社 | All-quantity ejection aerosol product for mold prevention and mold prevention method |
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| TWI796648B (en) | 2023-03-21 |
| TW202142113A (en) | 2021-11-16 |
| JP7016991B1 (en) | 2022-02-07 |
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