CN115007425A - Production process of TDX10 color coated board - Google Patents

Production process of TDX10 color coated board Download PDF

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Publication number
CN115007425A
CN115007425A CN202210670249.8A CN202210670249A CN115007425A CN 115007425 A CN115007425 A CN 115007425A CN 202210670249 A CN202210670249 A CN 202210670249A CN 115007425 A CN115007425 A CN 115007425A
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China
Prior art keywords
coating
speed
temperature
zinc
unit
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Pending
Application number
CN202210670249.8A
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Chinese (zh)
Inventor
胡洪林
马孝娟
卢鹏程
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xinjiang Bayi Iron and Steel Co Ltd
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Xinjiang Bayi Iron and Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by Xinjiang Bayi Iron and Steel Co Ltd filed Critical Xinjiang Bayi Iron and Steel Co Ltd
Priority to CN202210670249.8A priority Critical patent/CN115007425A/en
Publication of CN115007425A publication Critical patent/CN115007425A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/10Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
    • B05D3/102Pretreatment of metallic substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/53Base coat plus clear coat type
    • B05D7/532Base coat plus clear coat type the two layers being cured or baked together, i.e. wet on wet
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/54No clear coat specified
    • B05D7/542No clear coat specified the two layers being cured or baked together
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00Metallic substrate
    • B05D2202/30Metallic substrate based on refractory metals (Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2350/00Pretreatment of the substrate
    • B05D2350/30Change of the surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2508/00Polyesters

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a production process of a TDX10 colored coating plate, which adopts a DX51D + Z aluminized zinc substrate and polyester finish paint to produce an ultrathin plating thin-coating colored coating plate with the total film thickness of 9 mu m; coating 10/10g/m of galvanized substrate 2 The coating adopts an aluminum-zinc coating, the zinc content is not less than 85%, the zinc layer is smooth and uniform in surface, and the defects of zinc particles and zinc scars are avoided; the production comprises the following steps of pretreatment, primer coating, finish coating and curing in sequence: the speed of the unit is 50-70 m/min, the working temperature of the primer furnace is divided into 4 sections, and the outlet temperature of the 4 th section is 290-360 ℃; finish paint oven operationThe temperature is divided into 4 sections, the outlet temperature of the 4 th section is 310-370 ℃, the temperature of a finish paint furnace plate is 225-232 ℃, the belt temperature of a water quenching tank after cooling is not more than 45 ℃, and the stable performance of the paint film after being heated is ensured through short-time high-speed low temperature.

Description

Production process of TDX10 color coated board
Technical Field
The invention relates to a production process of a color coated plate, in particular to a production process of a TDX10 color coated plate.
Background
At present, the domestic times of surplus color coating productivity and high profit of color coated plates are declared to be over, the competition is more and more intense, and the color coated plates can gain the market competitiveness only by improving the product quality, expanding the market share of the products and adopting market segmentation and differentiated operation strategies. The technological development of color coated sheets has mainly surrounded the variation of the combination of coatings and coatings to meet different market demands.
The invention discloses a color-coated sheet and a preparation method thereof in the patent of CN201210092782.7, and provides the color-coated sheet and the preparation method thereof, the color-coated sheet comprises a substrate, the substrate is a steel plate with stamping deformation performance, the surface layer of the substrate is provided with a primer coating and a finish coating in sequence, a chemical conversion layer is arranged between the primer coating and the substrate, and the preparation method of the color-coated sheet comprises the following steps: 1) when the color-coated plate is prepared, firstly, the surface of a substrate is passivated to form a chemical conversion layer; 2) forming a primer coating on the surface of the chemical conversion layer by using coil coating; 3) and respectively forming a front coating and a back coating on two sides of the substrate with the primer coating by using coil coating. The color-coated sheet and the preparation method thereof enable the color-coated sheet to have good stamping performance in the color-coated production line, and can solve the problem that the coating is easy to crack or the substrate is easy to crack when the color-coated sheet is stamped.
The CN201510086879.0 patent is a production method of a color coated sheet with ultrahigh film thickness, and the method comprises the steps of degreasing by pretreatment, surface conditioning and hot water rinsing; the weight of the passive film is controlled to be 30-40 mg/m 2; the designed film thickness of the primer is 15 +/-5 mu m, and upper limit control is adopted; the designed film thickness of the finish paint is 25 +/-3 mu m, and lower limit control is adopted; the stirring speed and time of the premixing room are controlled, the set values of the wind speed and the temperature of the first section and the second section of the curing process are reduced by 20-30% compared with those of a common color-coated plate, the cooling water adopts desalted water, the conductivity is 70 mu m/s, and the cooling treatment time is 12-15 s; the thickness of the plate is less than or equal to 0.6mm, the initial weight of the coiling machine is 1900-2100 kg, the final weight is 2900-3200 kg, and the step tension is 140%; the thickness was > 0.6mm and the step tension ratio of the coiler was set to 40000/base tension. The invention can stably produce the color coated sheet with the ultra-high film thickness of 40 mu m and excellent corrosion resistance, wear resistance and better cost performance in a large scale, the yield reaches more than 95 percent, and the invention is a color coated sheet production process with high added value.
The coating weight of the color-coated substrate is mainly selected according to factors such as application, environmental corrosivity, service life and durability. The corrosion resistance is one of the main functions of the color-coated plate, and the coating weight is a main factor influencing the corrosion resistance of the color-coated plate. Since the color-coated sheet for construction is usually exposed to the atmospheric environment, a substrate such as a hot-dip galvanized sheet or a hot-dip aluminum-zinc sheet having high corrosion resistance and a thick coating layer is usually selected. The corrosion resistance is generally improved along with the increase of the coating weight, and the corrosion resistance of various coated steel plates is basically in direct proportion to the coating thickness, so the corrosion resistance of the color coated plate can be improved by increasing the coating weight. For example, in severe industrial pollution and coastal humid areas, 75/75-140/140 g/m2 hot-galvanized plates are generally used, and 30/30-50/50 g/m2 hot-galvanized plates or hot-dip aluminum-zinc plates are generally used as color-coated substrates required for corrosion prevention. The coating of the color coated steel plate generally has a thickness of about 20 to 25 μm on the upper surface, and the corrosion resistance is generally improved with the increase of the coating weight, and the coating film has protection effects such as scrub resistance, solvent resistance, pollution resistance, sunlight resistance, corrosion resistance and the like, so the color coated steel plate is widely used. The functions of the coatings are from the coating material itself and the good color coating production process. The properties of the coating are an important part of the impact on the coating performance. The paint is composed of four raw materials of resin, pigment, additive and solvent. The resin is the most important part of the coating, and forms a smooth and uniform film on the surface of a coated object. The excellent resin must have the following properties, can form a thin film and has good binding force to a substrate; has good dispersibility on the pigment and uniform color. The appearance is transparent and the chroma is low; resistance to the environment such as sunlight, air and moisture, acid rain, grease and smoke; has the performances of scrubbing resistance, abrasion resistance, collision resistance and the like.
The development of the color-coated sheet suitable for local climate characteristics is a development direction by combining the current demand situation of the local market in Xinjiang; the method is characterized in that the method is carried out on the vernix in Xinjiang, is far away from the sea, is dried all the year round in climate and has low requirement on corrosion resistance of the color-coated sheet, but the color-coated sheet on the market at present generally has thicker coating (about 20-25 microns) and thicker plating (30/30-50/50 g/m 2), and has resource waste when being used in Xinjiang, so that the method is urgently needed to develop a production process of an ultrathin plating thin-coating color coated sheet, and produce an economical color coated sheet suitable for the Xinjiang climate to improve the existing production technology.
Disclosure of Invention
The invention aims to develop a production process of a TDX10 color coated plate to produce an economical color coated plate suitable for Xinjiang climate.
The technical scheme of the invention is as follows: a production process of a TDX10 colored coated plate adopts a DX51D + Z aluminized zinc substrate and polyester finish paint to produce an ultrathin coating thin-coating colored coated plate with the total film thickness of 9 mu m; plating layer 10/10g/m of galvanized substrate 2 The coating is an aluminum-zinc coating, the zinc content is not less than 85%, the zinc layer is smooth and uniform in surface, and the defects of zinc particles and zinc scars are avoided;
the pretreatment process comprises the following steps: 7-10 parts of degreasing solution alkali point; the temperature is 65-75 ℃; the chromium point of the passivation solution is 24 +/-2, the temperature is 27 +/-5 ℃, the temperature of a chemical coating PMT plate is 50-70 ℃, and the weight of a passivation film is 15-25mg/m 2
Primer coating process: the thickness of a primer film is 3 +/-1 mu m, the on-machine viscosity of the polyester back surface paint is 30-33 seconds, and the speed of a coating roller is as follows: the numerical ratio of the speed of the unit to the speed of the unit is 1.1-1.3: 1, speed of the draw roll: the numerical ratio of the speed of the unit to the speed of the unit is 0.3-0.5: 1, the pressure between the coating roller and the swabbing roller is less than or equal to 1250 kg;
and a finish paint coating process: the thickness of a finish paint film is 6 +/-1 mu m, the machine viscosity of the polyester back finish paint is 30-35 seconds, and the speed of a coating roller is as follows: the numerical ratio of the speed of the unit to the speed of the unit is 1.2-1.4: 1, speed of the draw roll: the numerical ratio of the speed of the unit to the speed of the unit is 0.4-0.7: 1, the pressure between a coating roller and a drawing roller is less than or equal to 1350kg, the thickness of a paint film is reduced by improving the roller speed ratio and the pressure between the rollers, and the paint film is uniformly distributed;
and (3) a curing process: the speed of the unit is 50-70 m/min, the working temperature of the primer furnace is divided into 4 sections, and the outlet temperature of the 4 th section is 290-360 ℃; the working temperature of the finish paint furnace is divided into 4 sections, the outlet temperature of the 4 th section is 310-370 ℃, the temperature of a finish paint furnace plate is 225-232 ℃, the belt temperature of the water quenching tank after cooling is not more than 45 ℃, and the stable heating uniformity of a paint film is ensured through short-time high-speed low temperature.
The production process of the ultrathin plating thin-coating color coating plate of the TDX10 can better realize the production of the ultrathin plating thin-coating color coating plate and meet the requirements of the economic color coating plate in arid climate in Xinjiang local and northwest regions. By adopting the process, the low-cost color-coated steel coil meeting the protection requirement of downstream users can be produced under limited equipment precision on the premise of the traditional cold-rolled aluminum-zinc-plated color coating production line, and a new way for producing the color-coated plate is developed. The invention is suitable for steel mills and comprises the following components: iron and steel production enterprises of tool equipment of continuous hot-dip aluminum-zinc machine sets-continuous color coating machine sets.
Detailed Description
In order to achieve the purpose, the technical scheme of the invention is that the production process of the ultrathin plating thin-coating color coating plate TDX10 comprises the following steps:
1) preparing raw materials: the finished aluminum-zinc-plated substrate adopts an aluminum-zinc plating layer, the zinc content is not less than 85 percent, and the plating layer is 10/10g/m 2 The surface of the zinc layer is uniform;
2) the pretreatment process comprises the following steps: 7-10 parts of degreasing solution alkali point; the temperature is 65-75 ℃; the chromium point of the passivation solution is 24 +/-2, the temperature is 27 +/-5 ℃, the temperature of a chemical coating PMT plate is 50-70 ℃, and the weight of a passivation film is 15-25mg/m 2
3) Primer coating process: the thickness of a primer film is 3 +/-1 mu m, the on-machine viscosity of the polyester back surface paint is 30-33 seconds, and the speed of a coating roller is as follows: unit speed (1.1-1.3): 1, speed of the draw roll: unit speed (0.3-0.5): 1, the pressure between the coating roller and the drawing roller is less than or equal to 1250 kg.
4) And a finish coating process: the thickness of a finish paint film is 6 +/-1 mu m, the machine viscosity of the polyester back finish paint is 30-35 seconds, and the speed of a coating roller is as follows: unit speed (1.2-1.4): 1, speed of the draw roll: unit speed (0.4-0.7): 1, the pressure between the coating roller and the drawing roller is less than or equal to 1350kg, and the thickness of a paint film is reduced and the paint film is uniformly distributed by improving the roller speed ratio and the pressure between the rollers.
5) And a finish coating process: the thickness of a finish paint film is 6-8 mu m, the on-machine viscosity of the polyester back finish paint is 30-40 seconds, and the speed of a coating roller is as follows: unit speed (1.2-1.8): 1, speed of the draw roll: unit speed (0.3-0.7): 1, the pressure between the coating roller and the suction roller is less than or equal to 1500kg, and the paint film has thin thickness and uniform distribution.
6) And (3) a curing process: the speed of the unit is 50-70 m/min, the working temperature of the primer furnace is divided into 4 sections, and the outlet temperature of the 4 th section is 290-360 ℃; the working temperature of the finish paint furnace is divided into 4 sections, the outlet temperature of the 4 th section is 310-370 ℃, the temperature of a finish paint furnace plate is 225-232 ℃, the belt temperature of the water quenching tank after cooling is not more than 45 ℃, and the stable heating uniformity of a paint film is ensured through short-time high-speed low temperature.

Claims (1)

1. A production process of a TDX10 color coating plate is characterized in that an ultrathin plating thin-coating color coating plate with the total film thickness of 9 mu m is produced by adopting a DX51D + Z aluminized zinc substrate and polyester finish; coating 10/10g/m of galvanized substrate 2 The coating is an aluminum-zinc coating, the zinc content is not less than 85%, the zinc layer is smooth and uniform in surface, and the defects of zinc particles and zinc scars are avoided; the specific process steps are as follows:
1) and the pretreatment process comprises the following steps: 7-10 parts of degreasing solution alkali point; the temperature is 65-75 ℃; the chromium point of the passivation solution is 24 +/-2, the temperature is 27 +/-5 ℃, the temperature of a chemical coating PMT plate is 50-70 ℃, and the weight of a passivation film is 15-25mg/m 2
2) And a primer coating process: the thickness of a primer film is 3 +/-1 mu m, the on-machine viscosity of the polyester back surface paint is 30-33 seconds, and the speed of a coating roller is as follows: the numerical ratio of the speed of the unit to the speed of the unit is 1.1-1.3: 1, speed of the draw roll: the numerical ratio of the speed of the unit to the speed of the unit is 0.3-0.5: 1, the pressure between the coating roller and the swabbing roller is less than or equal to 1250 kg;
3) and a finish coating process: the thickness of a finish paint film is 6 +/-1 mu m, the on-machine viscosity of polyester back finish paint is 30-35 seconds, and the speed of a coating roller is as follows: the numerical ratio of the speed of the unit to the speed of the unit is 1.2-1.4: 1, speed of the draw roll: the numerical ratio of the speed of the unit to the speed of the unit is 0.4-0.7: 1, the pressure between a coating roller and a drawing roller is less than or equal to 1350kg, the thickness of a paint film is reduced by improving the roller speed ratio and the pressure between the rollers, and the paint film is uniformly distributed;
4) and a curing process: the speed of the unit is 50-70 m/min, the working temperature of the primer furnace is divided into 4 sections, and the outlet temperature of the 4 th section is 290-360 ℃; the working temperature of the finish paint furnace is divided into 4 sections, the outlet temperature of the 4 th section is 310-370 ℃, the temperature of a finish paint furnace plate is 225-232 ℃, the belt temperature of the water quenching tank after cooling is not more than 45 ℃, and the stable heating uniformity of a paint film is ensured through short-time high-speed low temperature.
CN202210670249.8A 2022-06-15 2022-06-15 Production process of TDX10 color coated board Pending CN115007425A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210670249.8A CN115007425A (en) 2022-06-15 2022-06-15 Production process of TDX10 color coated board

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Application Number Priority Date Filing Date Title
CN202210670249.8A CN115007425A (en) 2022-06-15 2022-06-15 Production process of TDX10 color coated board

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116764916A (en) * 2023-06-27 2023-09-19 新疆八一钢铁股份有限公司 Production process of 6-8 mu thin-coating color-coated plate

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113695206A (en) * 2021-09-13 2021-11-26 新疆八一钢铁股份有限公司 Production process of color coated plate

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113695206A (en) * 2021-09-13 2021-11-26 新疆八一钢铁股份有限公司 Production process of color coated plate

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116764916A (en) * 2023-06-27 2023-09-19 新疆八一钢铁股份有限公司 Production process of 6-8 mu thin-coating color-coated plate

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