CN114990287A - Preparation method and application method of aluminum briquetting deoxidizer - Google Patents

Preparation method and application method of aluminum briquetting deoxidizer Download PDF

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Publication number
CN114990287A
CN114990287A CN202210620148.XA CN202210620148A CN114990287A CN 114990287 A CN114990287 A CN 114990287A CN 202210620148 A CN202210620148 A CN 202210620148A CN 114990287 A CN114990287 A CN 114990287A
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China
Prior art keywords
aluminum
deoxidizer
material distribution
rod
briquetting
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CN202210620148.XA
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CN114990287B (en
Inventor
鲍剑铭
杨富强
张文用
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Inner Mongolia Qinyuan Alloy Technology Co ltd
Baotou Suihai Furnace Charge Co ltd
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Inner Mongolia Qinyuan Alloy Technology Co ltd
Baotou Suihai Furnace Charge Co ltd
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Publication of CN114990287A publication Critical patent/CN114990287A/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/06Deoxidising, e.g. killing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0006Adding metallic additives
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention discloses a preparation method of an aluminum briquetting deoxidizer, which comprises the following steps: crushing the collected aluminum recycling waste to enable the aluminum recycling waste to be crushed to form aluminum particles, and dehydrating by utilizing heat generated in the crushing process; the aluminum particles are sent into a compression molding device, and the compression molding device presses the aluminum particles into blocky aluminum briquetting deoxidizer. The invention also discloses an application method of the aluminum briquetting deoxidizer. The whole preparation process of the invention has no fuel consumption and no burning loss of materials, and the energy consumed in the crushing process is utilized to heat the materials and dehydrate in the dehydration process, thereby realizing the recycling of crushing energy.

Description

Preparation method and application method of aluminum briquetting deoxidizer
Technical Field
The invention belongs to a waste metal aluminum recycling technology, and particularly relates to a preparation method and an application method of an aluminum briquetting deoxidizer.
Background
In the metal smelting industry such as steel making, a large amount of various charging additives (for example, the using amount of aluminum and calcium is about 0.2-8 kg/ton steel) are used for deoxidizing and denitriding the smelting metal and improving the performance of the smelting metal. The main products of the aluminium-based deoxidizer for steel making at present comprise aluminium blocks, aluminium iron and other materials, and the main raw materials of the deoxidizer are metal aluminium ingots generated by aluminium oxide electrolysis or aluminium ingots obtained by melting and casting secondary aluminium in a reverberatory furnace, and then the deoxidizer is melted and cast in an intermediate frequency furnace according to a certain proportion with waste steel. Both the electrolytic process of metal aluminum ingot, the melting process of secondary aluminum in a reverberatory furnace and the smelting and casting process of an intermediate frequency furnace need to consume a large amount of electric energy and fuel, so that the energy consumption cost is high.
The recovered waste metal materials are used for preparing the furnace charge additive, a process method of heating and melting metals and then cutting into blocks for molding is generally adopted, the energy consumption of molten metal casting molding in the manufacturing process is large, a large amount of carbon dioxide is discharged due to fuel consumption in the heating and melting process, the environmental pollution is large, and the production cost is high.
CN201210432365.2 discloses a method for recycling waste aluminum and waste zip-top cans in a green circulating and guaranteed level, which comprises the following steps: the aluminum alloy for producing the waste pop-top can is obtained through the working procedures of crushing, magnetic separation iron removal, paint removal, smelting, component adjustment, filtration and casting. Wherein, pretreatment paint removal: the method comprises the steps of enabling waste pop-top can fragments to enter a paint removing kiln for paint removal, enabling a paint layer to be carbonized, enabling carbon particles to fall off completely through special vibration equipment, enabling gas and the carbon particles discharged from a rotary paint removing kiln to be introduced into a high-temperature furnace for secondary combustion, enabling one-stage combustion to be in an anoxic reduction region, controlling the temperature to be about 850 ℃, enabling smoke to continue to be sent into a secondary combustion chamber for thorough oxidative decomposition, and enabling the temperature in the secondary combustion chamber to be higher, wherein the temperature is usually higher than 1000 ℃. Smelting: a heat accumulating type double-chamber reverberatory furnace is adopted, after an aluminum sheet after depainting is packed, molten aluminum liquid is pressed into an outer chamber for melting, the molten aluminum liquid is heated by the flame of the reverberatory furnace in an inner chamber, and the molten aluminum liquid in the inner chamber and the outer chamber circulates by virtue of a ceramic pump; the temperature of the aluminum liquid in the outer chamber is 700-850 ℃, and the temperature of the aluminum liquid in the inner chamber is 850-950 ℃.
CN202011449896.3 discloses an aluminum-iron deoxidizer for smelting and a preparation method thereof, wherein the aluminum-iron deoxidizer for smelting comprises the following components: 35 to 75 percent of aluminum, 23 to 63 percent of iron and 1.0 to 3.5 percent of binding agent. The preparation method of the aluminum-iron deoxidizer for smelting comprises the following steps: carrying out impurity removal, preselection and crushing treatment on the waste aluminum foil light thin material; roasting the crushed waste aluminum foil light and thin material to remove surface attachments, and then granulating to obtain aluminum particles; weighing aluminum particles, iron and a binding agent, uniformly mixing to obtain a mixture, carrying out cold press molding on the mixture, and curing to obtain the high-strength aluminum-iron deoxidizer. Wherein cold press forming the blend comprises: feeding the mixture into a briquetting machine for primary extrusion forming to obtain a primary cold-pressed block, crushing the primary cold-pressed block, returning the crushed primary cold-pressed block to the briquetting machine for secondary extrusion forming to obtain the high-strength cold-pressed block.
In the existing method for recycling the waste easy open can, paint removal is realized by carbonizing organic matters in a fuel heating roasting and smelting mode; in the molding and smelting process, fuel is used for heating to melt and mold the aluminum sheet. Because the aluminum sheet formed after the waste aluminum and waste pop-top cans are crushed belongs to a solid with large sheet surface area, the aluminum is an active metal, and is subjected to paint removal and forming in a roasting and smelting mode under the aerobic condition, the aluminum sheet can be inevitably oxidized into Al 2 O 3 The burning loss is serious, the recovery rate of the waste aluminum and the waste pop-top can is greatly reduced, and the recovery cost is improved. Meanwhile, in the paint removing and smelting processes, a large amount of fuel is inevitably consumed additionally, so that the energy consumption cost is high, the carbon dioxide emission is increased, the solid hazardous waste emission such as aluminum ash is increased, and the environmental pollution is caused.
In the cold press molding process, aluminum particles and iron are bonded together by a bonding agent, wherein the bonding agent is a mixture of a high molecular bonding agent and a liquid metal bonding agent. Because the time is required for the bonding agent to perform the bonding action, the cold-pressed block needs to be shaped through maintenance. Because the binding agent is a polymer binding agent, which is equivalent to re-injecting the carbonaceous material into the aluminum material, the roasting decarburization effect at the beginning of the process is greatly reduced, even the decarburization effect is completely counteracted, and the use effect of the aluminum-iron deoxidizer is seriously influenced.
Among the above-mentioned equipment, no matter roasting kiln, depainting kiln all are firing equipment, and firing equipment need keep away from material former, and the decarbonization material needs frequently carry former, causes firing equipment, former can not use same production line, and it is big not only to occupy the place, is unfavorable for realizing the butt joint from top to bottom of production node moreover, is unfavorable for realizing automated production.
Disclosure of Invention
Aiming at the defects of high energy consumption and large burning loss in the production of aluminum briquettes or aluminum frits in the prior art, the invention aims to provide a preparation method and an application method of an aluminum briquette forming deoxidizer.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
the preparation method of the aluminum briquetting deoxidizer comprises the following steps:
crushing the collected aluminum recycling waste to enable the aluminum recycling waste to be crushed to form aluminum particles, and dehydrating by utilizing heat generated in the crushing process;
the aluminum particles are sent into a compression molding device, and the compression molding device presses the aluminum particles into blocky aluminum briquetting deoxidizer.
Further, the aluminum recycling waste products are waste pop cans, automobile waste water tanks, aluminum waste heat radiating fins or waste aluminum shavings.
Further, in the crushing process, the mechanical removing mode is utilized to remove paint from the aluminum recovered waste with paint surfaces; the heat generated in the crushing process is utilized for dehydration, the temperature of the space where the aluminum recovery waste is located is higher than 120 ℃, and the energy consumed in the crushing process is recovered.
Further, the press-forming apparatus includes: the aluminum particle forming deoxidizer comprises a hydraulic press, a material distribution mechanism and a die, wherein the material distribution mechanism is used for conveying aluminum particles into the die arranged in the hydraulic press, and the hydraulic press presses the aluminum particles in the die into a blocky aluminum pressing block forming deoxidizer.
Further, the mold includes: the mould comprises a mould hole assembly, a pressing rod assembly and a jacking rod assembly; the fixed base beam of the hydraulic press is provided with a fixed support, the material distribution mechanism, the die hole assembly and the separated discharge port are respectively connected to the fixed support, the material distribution mechanism and the separated discharge port are respectively positioned on two sides of the die, the material distribution mechanism, the die and the separated discharge port are positioned between the fixed base beam and the movable beam, and the pressing rod assembly is arranged on the lower part of the movable beam of the hydraulic press; the orifice assembly includes: the hole sleeve mounting lower plate is provided with a plurality of lower plate through holes, the hole sleeve mounting upper plate is provided with a plurality of upper plate through holes, and the die hole sleeve is connected between the lower plate through holes and the upper plate through holes; the two ends of the die hole sleeve are provided with rabbets which are inserted into the lower plate through hole and the upper plate through hole; the hold-down bar assembly includes: the device comprises a pressure rod mounting plate, a pressure rod and a pressure head, wherein the pressure rod mounting plate is provided with a plurality of pressure rod mounting through holes, the top ends of the pressure rods are inserted into the pressure rod mounting through holes, and the bottom ends of the pressure rods are connected with the pressure head; the jacking-rod assembly includes: the jacking rod mounting plate is provided with a plurality of jacking rod mounting through holes, the bottom ends of the jacking rods are inserted into the jacking rod mounting through holes, and the jacking head is connected to the top ends of the jacking rods; the bottom of the jacking rod mounting plate is connected to the top of the jacking rod of the jacking cylinder.
Further, the cloth mechanism includes: the cloth mechanism includes: the device comprises a raw material bin, a baffle plate, a material distribution box, an upper sealing plate, a rack, a material box guide strip, a telescopic mechanism and a lower sealing plate; the bottom of the baffle is connected with the side edge of the upper sealing plate, the baffle encloses a feeding channel, and the front end of the feeding channel is provided with a guide opening; a feed opening is formed in the bottom of the raw material bin, the feed opening is located in the feeding channel, and the bottom end of the feed opening is lower than the upper edge of the baffle; the front part of the upper sealing plate is provided with a feeding opening, the top of the material distribution box is connected to the lower part of the feeding opening, the upper part and the lower part of the material distribution box are respectively provided with an opening, and a plurality of material stirring devices are arranged in the material distribution box; the bottoms of the rear sections of the two bin guide strips are connected to the lower sealing plate, the front sections of the two bin guide strips extend out of two sides of the die hole assembly, and the racks are connected to the upper parts of the bin guide strips; the material stirring device comprises: a deflector rod mounting shaft, a material poking rod, a material poking power gear and a bearing seat; the two bearing blocks are respectively connected to the outer side wall of the material distribution box, two ends of a deflector rod mounting shaft are respectively sleeved in the two bearing blocks, and the two material shifting power gears are respectively connected to the outer sides of the two bearing blocks; the end parts of the plurality of material stirring rods are connected to the outer wall of the material stirring rod mounting shaft, and the telescopic mechanism is connected between the lower sealing plate and the side wall of the rear end of the material distributing box.
Further, the step of pressing the aluminum particles into the massive aluminum briquetting deoxidizer by the press forming equipment comprises the following steps:
aluminum particles in the raw material bin fall into the material distribution box, the telescopic mechanism pushes the material distribution box to move forwards to the upper part of the die hole assembly, the upper sealing plate seals a feed opening of the raw material bin in the forward moving process of the material distribution box, after the material distribution box reaches the upper part of the die hole sleeve, an opening in the lower part of the material distribution box is opened, the rack drives the material stirring power gear to rotate, and the material stirring rod loads the aluminum particles into a hole cavity of the die hole sleeve in the rotating process;
after the aluminum particles are filled, the telescopic mechanism drives the material distribution box to move backwards, the material distribution box scrapes the aluminum particles of the die hole sleeve, the material distribution box moves backwards to the lower part of the raw material bin, the upper sealing plate opens the feed opening of the raw material bin, the lower sealing plate closes the lower opening of the material distribution box, and the aluminum particles fall into the material distribution box;
the telescopic rod is pressed downwards by the hydraulic cylinder to move downwards, the movable beam is pushed to move downwards, the movable beam drives the pressing rod assembly to move downwards, the pressing head at the lower part of the pressing rod extends into the hole cavity of the die hole sleeve, and the pressing head presses and forms aluminum particles to form a block-shaped aluminum pressing block forming deoxidizer;
the telescopic rod is pressed downwards to rise, the movable beam drives the pressing rod assembly to rise, and the pressing rod and the pressing head leave from the hole cavity of the die hole sleeve; a jacking rod of the jacking cylinder pushes the jacking rod assembly to rise, a jacking rod and a jacking head extend into the hole cavity of the die hole sleeve, and the aluminum briquetting deoxidizer is ejected out of the hole cavity;
the telescopic mechanism pushes the material distribution box to move forwards, the material distribution box pushes the aluminum briquetting forming deoxidizer to a separate discharge port, and meanwhile, aluminum particles are filled into the hole cavity of the die hole sleeve again, and the aluminum briquetting forming deoxidizer falls into a collection box at the lower part; the material distributing box moves backwards, and the pressing forming equipment presses the aluminum particles into the aluminum pressing block forming deoxidizer again.
Further, a pressure head connecting end is arranged at the top end of the pressure head, external threads are arranged on the outer wall of the pressure head connecting end, a pressure head connecting threaded hole is formed in the bottom end of the pressure rod, and the pressure head connecting end is connected in the pressure head connecting threaded hole through threads; the bottom of top is provided with top connection end, and top connection end outer wall is provided with the external screw thread, and the top of top is provided with top connection screw hole, and top connection end utilizes threaded connection in top connection screw hole.
An application method of an aluminum briquetting deoxidizer, which is used as an aluminum-based deoxidizer for steelmaking.
Preferably, the shape of the aluminum briquetting deoxidizer is a cylinder, and the outer diameter of the cylinder is less than 50mm, or the outer diameter of the cylinder is between 50mm and 400 mm.
The invention has the technical effects that:
1. the whole preparation process of the invention does not consume combustion fuel, so the preparation process does not discharge carbon dioxide, and because the smelting process is not adopted, the energy consumption in the production process is low (the production energy consumption is more than 80% lower than that of similar products produced by the traditional smelting process), the invention is environment-friendly, has no hazardous waste discharge, does not discharge industrial three wastes in the production process, has the advantages of low energy consumption, green and low carbon, and the like, meets the requirements of energy conservation and emission reduction, simultaneously reduces the manufacturing cost, is beneficial to popularization and use, and helps to realize carbon peak reaching and carbon neutralization.
2. The invention does not consume fuel in the crushing, paint removing, dehydrating and forming processes of the aluminum recycling waste products, heats materials by using energy consumed in the crushing process in the paint removing and dehydrating processes, realizes the recycling of crushing energy, and has no burning loss.
In the crushing process, the modes of friction, shearing, kneading, beating and the like are adopted for depainting (non-heating physical mode depainting), and the friction heating mode is adopted for dehydration, so that the situation that the light and thin aluminum material with small volume is oxidized into Al in the depainting, purifying and forming processes is avoided 2 O 3 And the material recovery rate is improved due to burning loss, the traditional aluminum recovery waste is more prone to burning loss in the smelting process, the recovery efficiency is only 80-85%, the recovery rate of aluminum is more than 98%, the processing loss is less than 2%, and the recovery efficiency is different by more than 10%.
The compression molding process adopts a large compression ratio for compression molding, and the temperature of the crushed hot aluminum particles can be continuously raised in the die in the compression process with a high compression ratio, so that the material molding and bonding are facilitated, and the molding can be greatly improvedThe density and molding strength of the material are such that the press-molding material (bulk aluminum briquette-molding deoxidizer, p 2.0-2.4 g/cm) 3 ) The density of the deoxidizer is close to that of the aluminum block formed by melting, so that the use performance of the deoxidizer for forming the aluminum block is not lower than that of the deoxidizer formed by melting or bonding.
The recovered waste aluminum products are dehydrated by heat generated in the processes of rubbing, shearing, kneading and beating the waste aluminum products in the process of crushing and kneading the waste aluminum products into granular aluminum particles. The dehydration and depainting processes have no carbon dioxide emission and no raw material burning loss.
3. The invention adopts a compression molding process, and gets rid of the defect that the devices such as crushing, burdening and molding cannot be arranged on the same production line in the process of processing materials by heating equipment, and each device is easy to butt up and down as a production node, is automatically and short-range connected by a belt, does not need long-distance conveying, avoids heat loss during crushing and pressing, is convenient to realize electric automatic production, and can obviously improve the production efficiency; the formed material has good size and component consistency and high strength, and is convenient for accurately feeding materials into a smelting furnace.
5. Compared with the traditional process, the invention systematically solves the problems of high energy consumption, high carbon dioxide emission, high cost, difficult control of product quality and the like of the traditional process in the aspects of raw material treatment, production equipment, process flow, product performance, environmental protection energy consumption and the like.
Drawings
FIG. 1 is a flow chart of a cold-working forming method for producing a deoxidizer for briquetting of aluminum in the present invention;
FIG. 2 is a schematic view of the construction of the crushing and kneading machine of the present invention;
FIG. 3 is a schematic diagram of the arrangement of hammers and blades on a rotor disc in the invention;
FIG. 4 is a schematic perspective view of a press molding apparatus according to the present invention;
FIG. 5 is a schematic sectional view of the press-molding apparatus of the present invention;
FIG. 6 is a schematic view of the construction of the hydraulic press of the present invention;
FIG. 7 is a schematic view of the orifice assembly of the present invention;
FIG. 8 is a cross-sectional view of a die orifice assembly of the present invention;
FIG. 9 is a cross-sectional view of a die sleeve of the present invention;
FIG. 10 is a schematic view of the construction of a hold-down bar assembly of the present invention;
FIG. 11 is a cross-sectional view of a hold-down bar assembly of the present invention;
FIG. 12 is a block diagram of the indenter of the present invention;
FIG. 13 is a schematic view of the construction of a lift pin assembly according to the present invention;
FIG. 14 is a schematic view of the structure of the plug in the present invention;
FIG. 15 is a schematic view of the structure of the distributing mechanism in the present invention;
FIG. 16 is a schematic view of the construction of the setting device of the present invention;
FIG. 17 is a schematic view showing the combination of the hydraulic press, the distributing mechanism and the mold according to the present invention.
Detailed Description
The following description sufficiently illustrates specific embodiments of the invention to enable those skilled in the art to practice and reproduce it.
As shown in FIG. 1, it is a flow chart of a cold working forming method of a deoxidizer for briquetting of aluminum in the present invention.
The invention adopts the pressing process to prepare the aluminum briquetting deoxidizer, the recycled aluminum is utilized to recycle waste products, and the crushed aluminum particles are used for preparing the aluminum briquetting deoxidizer through the pressing forming process route, so that the aluminum briquetting deoxidizer can be used for replacing the traditional production process for preparing furnace burden by pouring molten metal.
The preparation method of the aluminum briquetting deoxidizer comprises the following specific steps:
step 1: crushing the collected aluminum recycling waste, dehydrating by using heat generated in the crushing process, and crushing the aluminum recycling waste into aluminum particles by using friction depainting in the crushing process;
the aluminum recovery waste products are selected from waste pop cans, automobile waste water tanks, aluminum waste heat radiating fins, waste shavings and the like. The different aluminum recycling waste products are selected according to different steel grades, so that molten steel is prevented from being polluted, and the deoxidation effect can be improved.
For the aluminum recycled waste with paint surface, such as a waste pop can, the paint surface attached to the aluminum recycled waste is removed by using a non-heating mechanical removing mode such as shearing, kneading, beating, friction and the like, so that paint removal is realized.
The energy consumed in the crushing process can be effectively recovered and utilized by utilizing the heat generated by shearing, kneading, beating, friction and the like to dehydrate, wherein the heating temperature is higher than 120 ℃. The raw materials can be effectively prevented from being burnt by adopting non-roasting dehydration and decarburization.
As shown in fig. 2, is a schematic view of the structure of the crushing and kneading machine of the present invention. Fig. 3 is a schematic view showing the arrangement of the hammer 46 and the blades 47 on the rotor disk 44 according to the present invention.
Step 1.1: collecting the recycled aluminum recycling waste products and forming waste metal material compression packages, and sending the waste metal material compression packages (through a conveyor or a forklift) to an unpacking and scattering machine; the unpacking and evacuating machine unpacks the waste metal material compression packs, and sends the aluminum recovery waste products into a conveyor, and the conveyor sends the aluminum recovery waste products into a crushing and kneading machine;
the structure of the crushing and kneading machine comprises: the device comprises a shell 41, a base stock bin 42, a lining plate 43, a rotor disc 44, a main shaft 45, a hammer 46, a blade 47 and a material sieve 48; the bottom of the shell 41 is fixed on the upper part of the base stock bin 42, the bottom of the shell 41 is provided with a crushing discharge port 411, the upper part is provided with a crushing feed port 412, and the side part is provided with a motor through hole; the material sieve 48 is connected below the inner cavity of the shell 41 by a spring, the end part of the material sieve 48 is connected with a material sieve motor through a material sieve connecting rod, and the material sieve 48 is driven to vibrate by the material sieve motor; the lining plate 43 is fixed on the inner wall of the side part of the shell 41, two ends of the main shaft 45 are respectively installed on the main shaft installation seat on the side wall of the shell 41, the end part of the main shaft 45 is connected with the main shaft motor through the speed reducer, and the main shaft 45 is driven to rotate through the speed reducer.
The rotor disk 44 includes: the rotor disc single body 441 is provided with a plurality of connecting shaft through holes, the center of the rotor disc single body 441 is provided with a main shaft through hole, and the plurality of connecting shaft through holes which are circumferentially arranged are positioned at the outer side of the main shaft through hole; both ends of the plurality of hammer connecting shafts 442 are respectively connected in the plurality of connecting shaft through holes of the two rotor disc units 441, and the plurality of hammer connecting shafts 442 are parallel to each other; the hammer 46 and the blade 47 are provided with shaft holes at the end portions, the plurality of hammers 46 and the plurality of blades 47 are sleeved on the hammer connecting shaft 442 through the shaft holes, snap rings are respectively arranged on two sides of each of the hammers 46 and the blades 47 and are mounted in the annular grooves of the hammer connecting shaft 442, the hammers 46 and the blades 47 are positioned through the snap rings, and the hammers 46 and the blades 47 on each hammer connecting shaft 442 are arranged at intervals.
Rotor disk 44 is fitted to spindle 45 through a spindle through hole, key grooves are provided in the spindle through hole of rotor disk 44 and the outer wall of spindle 45, respectively, fixing key 443 is fitted in the key grooves, and rotor disk 44 is fixed to spindle 45 by fixing key 443.
Step 1.2: crushing, depainting and dehydrating the aluminum recycled waste by using a crushing and kneading machine, and crushing the aluminum recycled waste into aluminum particles; in the crushing process, the blades 47 and the hammer heads 46 continuously shear, rub and knead the aluminum recycling waste, and the generated heat evaporates water carried by the aluminum recycling waste.
Sending the recycled aluminum recycled waste into a crushing and kneading machine, driving a hammer head 46 to beat, rub and knead the surface of the aluminum recycled waste by a rotor disc 44 of the crushing and kneading machine, evaporating water brought by the aluminum recycled waste by frictional heat generation, and controlling the space temperature of the aluminum recycled waste to be 120-200 ℃; residual moisture in the aluminum recycling waste products is completely evaporated, and the moisture content of the materials is zero, so that energy in the crushing process is recycled and utilized.
For the aluminum recycled waste with paint surfaces, the rotor disc 44 of the crushing and kneading machine drives the hammer 46 to strike and rub the surface of the aluminum recycled waste, so that paint removal is realized, and burning loss caused by baking and paint removal is avoided.
The rotor disc 44 drives the blades 47 to shear, the hammer 46 rubs, and the aluminum recovered waste is formed into aluminum particles.
The granularity of the aluminum particles is less than 10mm, the aluminum particles are collected and then sent into a main material bin, and the aluminum particles with the granularity of more than 10mm are continuously crushed in a crushing and kneading machine.
Step 2: the aluminum particles are sent into a compression molding device and pressed into a blocky aluminum briquetting deoxidizer.
The prepared aluminum briquette forming deoxidizer belongs to an aluminum-based deoxidizer and is used as a deoxidizer for molten steel in a steelmaking process. The shape of the aluminum briquetting deoxidizer is a cylinder, and the diameter of the cylinder is less than 50 mm; for the steel-making process of manually delivering the deoxidizer, the diameter of the cylinder is 50mm-400 mm.
Fig. 4 is a schematic perspective view of the press molding apparatus according to the present invention. Fig. 5 is a schematic sectional view of the press-molding apparatus according to the present invention.
The press forming equipment structurally comprises: hydraulic press 1, cloth mechanism 2, mould 3. The material distribution mechanism 2 is used for feeding the mixture into a die 3 arranged in a hydraulic press 1, and the hydraulic press 1 presses the aluminum particles in the die into blocky aluminum briquetting deoxidizer.
Fig. 6 is a schematic view showing the structure of the hydraulic press 1 according to the present invention.
The hydraulic press 1 structurally includes: hydraulic cylinder 101, upper fixed beam 102, movable beam 103, fixed base beam 104, upright 105.
An oil inlet at the top of the hydraulic cylinder 101 is connected with a hydraulic system through a hydraulic pipeline. Go up fixed beam 102 and be provided with pneumatic cylinder fixing through hole, connect fixed through hole on four, pneumatic cylinder fixing through hole is located fixed beam 102 middle part on, connects fixed through hole on four and is located the pneumatic cylinder fixing through hole outside. The bottom of pneumatic cylinder 101 is fixed in the pneumatic cylinder fixed through-hole, and the telescopic link one end that pushes down of pneumatic cylinder 101 is located pneumatic cylinder 101, and the other end stretches out pneumatic cylinder fixed through-hole and is connected with walking beam 103.
The fixed base beam 104 is provided with a jacking cylinder fixing through hole 107 and four lower connecting fixing through holes, the jacking cylinder fixing through hole is positioned in the middle of the fixed base beam 104, and the four lower connecting fixing through holes are positioned outside the jacking through hole. A jacking cylinder 106 is arranged in the jacking through hole, and a jacking rod is arranged in the jacking cylinder 106. An oil inlet at the lower part of the jacking cylinder 106 is connected with a hydraulic system through a hydraulic pipeline.
The movable beam 103 is provided with four positioning through holes, four upright posts 105 are respectively sleeved in the four positioning through holes, the upper parts of the upright posts 105 are connected in the upper connecting and fixing through holes, and the lower parts of the upright posts 105 are connected in the lower connecting and fixing through holes and are fixed by bolts.
The fixed base beam 104 is provided with a fixed support 109, the material distribution mechanism 2, the die hole assembly 31 and the separated material outlet 108 are respectively connected to the fixed support 109, the material distribution mechanism 2 and the separated material outlet 108 are respectively positioned at two sides of the die 3, and the material distribution mechanism 2, the die 3 and the separated material outlet 108 are positioned between the fixed base beam 104 and the movable beam 103.
Fig. 7 is a schematic view showing the structure of the orifice assembly 31 according to the present invention. Referring now to fig. 8, there is shown a cross-sectional view of a die orifice assembly 31 in accordance with the present invention. Fig. 9 is a cross-sectional view of a die sleeve 312 according to the present invention.
The structure of the mold 3 includes: a die hole assembly 31, a pressing rod assembly 32 and a jacking rod assembly 33.
The structure of the orifice assembly 31 includes: the hole sleeve mounting lower plate 311, the die hole sleeve 312 and the hole sleeve mounting upper plate 313 are arranged, the hole sleeve mounting lower plate 311 is provided with a plurality of lower plate through holes, the hole sleeve mounting upper plate 313 is provided with a plurality of upper plate through holes, and the die hole sleeve 312 is connected between the lower plate through holes and the upper plate through holes. The two ends of the die hole sleeve 312 are provided with rabbets, and the rabbets are inserted into the lower plate through hole and the upper plate through hole (through fastening connection). The spigot can ensure the accurate positioning of the two ends of the die hole sleeve 312, and is arranged in the through hole of the lower plate and the through hole of the upper plate to prevent the movement. When the die hole sleeve 312 is seriously worn and needs to be replaced, other parts are not affected, and the waste part can be replaced quickly and inexpensively by the structural mode.
Fig. 10 is a schematic view of the construction of the hold-down bar assembly 32 of the present invention. As shown in fig. 11, a cross-sectional view of a hold-down bar assembly 32 of the present invention is shown. As shown in fig. 12, a structure of the indenter 323 in the present invention is shown.
The pressing rod assembly 32 is connected to the lower part of the movable beam 103, and the structure comprises: the pressing rod mounting plate 321 is provided with a plurality of pressing rod mounting through holes 324, the top end of the pressing rod 322 is inserted into the pressing rod mounting through holes 324 (through fastening connection), and the bottom end of the pressing rod 322 is connected with the pressing head 323.
The top of pressure head 323 is provided with pressure head connection end 325, and pressure head connection end 325 outer wall is provided with the external screw thread, and the bottom of depression bar 322 is provided with pressure head connection screw hole, and pressure head connection end 324 utilizes threaded connection in pressure head connection screw hole.
The pressing rod 322 and the pressing head 323 are connected through threads, when the pressing head 323 is worn or damaged, the pressing rod 322 does not need to be replaced, the pressing head 323 can be directly replaced, and the maintenance cost is reduced. The bottom surface of the pressure head 323 can be provided with a strip-shaped groove or an annular groove, so that the sheet-shaped raw materials can be better combined under the action of the non-planar bottom of the pressure head 323. The outer wall of the upper part of the pressure lever 322 is provided with a pressing limiting ring 326 for limiting the descending distance of the pressure lever 322.
The outer diameter of the compression bar 322 is smaller than the inner diameter of the die hole sleeve 312, so that the compression bar 322 extends into the die hole sleeve 312 to press aluminum particles, and when the lower pressing limiting ring 326 moves downwards and abuts against the upper plate 313 arranged on the die hole sleeve, the pressing bar assembly 32 stops moving downwards.
Fig. 13 is a schematic view of the construction of the lift pin assembly 33 according to the present invention. Fig. 14 is a schematic view showing the structure of the plug 333 according to the present invention.
The structure of the lift pin assembly 33 includes: the lifting rod mounting plate 331 is provided with a plurality of lifting rod mounting through holes 334, the bottom end of the lifting rod 332 is inserted into the lifting rod mounting through holes 334 (through fastening connection), and the top head 333 is connected to the top end of the lifting rod 332. The bottom of the lift pin mounting plate 331 is attached to the top of the lift pin of the lift cylinder 106.
The bottom of top 333 is provided with top connection end 335, and top connection end 335 outer wall is provided with the external screw thread, and the top of top 333 is provided with top connection screw hole, and top connection end 335 utilizes threaded connection in top connection screw hole.
The ejector rod 332 and the ejector head 333 are connected through threads, when the ejector head 333 is worn or damaged, the ejector rod 332 does not need to be replaced, the ejector head 333 is directly replaced, and maintenance cost is reduced. The top surface of the plug 333 may be provided with a stripe-shaped groove or a ring-shaped groove.
The outer diameter of the ejector rod 332 is smaller than the inner diameter of the die hole sleeve 312, and the ejector rod 332 extends into the die hole sleeve 312 to eject the compression-molded material from the die hole sleeve 312.
Fig. 15 is a schematic view showing the structure of the material distributing mechanism 2 according to the present invention. Fig. 16 is a schematic structural view of the setting device 231 according to the present invention. Fig. 17 is a schematic view showing the combination of the hydraulic press 1, the distributing mechanism 2, and the die 3 according to the present invention.
The distributing mechanism 2 includes: raw material bin 21, baffle 22, cloth workbin 23, upper seal plate 24, rack 25, workbin guide strip 26, telescopic machanism 27, lower seal plate 28.
The bottom of the baffle plate 22 is connected with the side edge of the upper closing plate 24, the baffle plate 22 encloses a feeding channel 221, and the front end of the feeding channel 221 is provided with a guide opening 222; a feed opening is formed in the bottom of the raw material bin 21, the feed opening is located in the feeding channel 221, and the bottom end of the feed opening is lower than the upper edge of the baffle 22; the front part of the upper sealing plate 24 is provided with a feeding opening 241, the top of the material distribution box 23 is connected with the lower part of the feeding opening 241, the upper part and the lower part of the material distribution box 23 are respectively provided with an opening, and a plurality of material stirring devices 231 are arranged in the material distribution box 23; the lower sealing plate 28 and the upper sealing plate 24 are parallel to each other, the bottoms of the rear sections of the two box guide bars 26 are connected to the lower sealing plate 28, and the front sections of the two box guide bars extend out of two sides of the die hole assembly 31; the rack 25 is connected to the upper part of the feed box guide strip 26, the lower part of the telescopic mechanism 27 is fixed on the lower sealing plate 28, and the telescopic part of the telescopic mechanism 27 is connected to the outer wall of the distribution feed box 23.
The lower plate 28 is attached to the mounting bracket 109 and the lower plate 28 acts to support the upper plate 24 and its components mounted on the upper plate 24. The lower sealing plate 28 is used for sealing or opening the opening at the lower part of the distribution box 23 along with the position change of the distribution box 23 relative to the lower sealing plate 28. Along with the position change of the feed opening of the raw material bin 21 and the upper sealing plate 24, the upper sealing plate 24 is used for plugging or opening the feed opening.
The material setting device 231 includes: a shifting rod mounting shaft 232, a shifting rod 233, a shifting power gear 234 and a bearing seat 235; the two bearing blocks 235 are respectively connected to the outer side wall of the material distribution box 23, two ends of the deflector rod mounting shaft 232 are respectively sleeved in the two bearing blocks 235, and the two material shifting power gears 234 are respectively connected to the outer sides of the two bearing blocks 235; the ends of the plurality of shift levers 233 are connected to the outer wall of the shift lever mounting shaft 232.
The plurality of radially arranged material shifting rods 233 form a material shifting rod group, and the plurality of material shifting rod groups are axially distributed on the material shifting rod mounting shaft 232.
The telescopic mechanism 27 includes: the material shifting hydraulic cylinder 271, the telescopic rod 272, the hydraulic support seat 273 and the hinge seat 274; the hydraulic support 273 is connected with the outer wall of the material stirring hydraulic cylinder 271, and the bottom of the hydraulic support 273 is connected with the lower sealing plate 28; one end of the telescopic rod 272 is located in the material stirring hydraulic cylinder 271, the other end of the telescopic rod is connected with the front end of the hinged seat 274, and the bottom of the hinged seat 274 is connected to the side wall of the material distribution box 23.
Of course, the telescopic mechanism 27 may also be an electric telescopic rod or a stepping motor. The mold 3 is intermittently filled with aluminum particles by the telescopic mechanism 27.
In order to make the material distribution box 23 advance along a straight line, the edges of two sides of the upper sealing plate 24 are provided with guide blocks, and the material distribution box 23 always keeps advancing straight line in the process that the telescopic mechanism 27 pushes the material distribution box 23 and the upper sealing plate 24 to move.
Step 2.1: the aluminum particles in the main bin are conveyed to the raw material bin 21, the aluminum particles in the raw material bin 21 fall into the material distribution bin 23, the material stirring hydraulic cylinder 271 is filled with pressure oil, the telescopic rod 272 pushes the material distribution bin 23 to move forwards to the upper part of the die hole assembly 31, the upper sealing plate 24 seals a feed opening of the raw material bin 21 in the process of forward movement of the material distribution bin 23, after the material distribution bin 23 reaches the upper part of the die hole sleeve 312, an opening in the lower part of the material distribution bin 23 is opened, the rack 25 drives the material stirring power gear 234 to rotate, and the material stirring rod 233 charges the aluminum particles into the hole cavity of the die hole sleeve 312 in the rotating process;
step 2.2: after the aluminum particles are filled, the telescopic rod 272 retracts to drive the material distribution box 23 to move backwards, the material distribution box 23 scrapes the aluminum particles of the die hole sleeve 312 flat, the material distribution box 23 moves backwards to the lower part of the raw material bin 21, the upper sealing plate 24 opens the feed opening of the raw material bin 21, the lower sealing plate 28 closes the lower opening of the material distribution box 23, and the aluminum particles fall into the material distribution box 23;
step 2.3: the hydraulic cylinder 101 of the press forming equipment injects pressure oil, the telescopic rod is pressed downwards to move downwards, the movable beam 103 is pushed to move downwards, the movable beam 103 drives the press rod assembly 32 to move downwards, the pressure head 323 at the lower part of the pressure rod 322 extends into the hole cavity of the die hole sleeve 312, and the pressure head 323 presses and forms aluminum particles to form a blocky aluminum briquetting forming deoxidizer;
step 2.4: oil is drained by the hydraulic cylinder 101, the telescopic rod is pressed downwards to rise, the movable beam 103 drives the pressing rod assembly 32 to rise, and the pressing rod 322 and the pressing head 323 leave from the hole cavity of the die hole sleeve 312; lifting the lifting rod of the lifting cylinder 106 to push the lifting rod assembly 33 to lift, wherein the ejector rod 332 and the ejector head 333 extend into the hole cavity of the die hole sleeve 312 to eject the aluminum briquetting deoxidizer out of the hole cavity;
step 2.5: the telescopic rod 272 pushes the material distribution box 23 to move forward, and the front scraper of the material distribution box 23 pushes the aluminum briquetting deoxidizer to the separated discharge port 108 and falls into a collection box at the lower part; the material distributing box 23 moves forward to push the aluminum briquetting deoxidizer, and meanwhile, the aluminum particles are filled into the hole cavity of the die hole sleeve 312 again, and the aluminum particles are pressed into the aluminum briquetting deoxidizer by the pressing forming equipment again.
The aluminum particles scattered in the filling process enter the raw material bin 21 again, and after the aluminum briquette forming deoxidizer in the collecting box is filled, the aluminum briquette forming deoxidizer is conveyed to a warehouse for storage through a conveying belt or a forklift.
The terminology used herein is for the purpose of description and illustration, rather than of limitation. As the present invention may be embodied in several forms without departing from the spirit or essential characteristics thereof, it should also be understood that the above-described embodiments are not limited by any of the details of the foregoing description, but rather should be construed broadly within its spirit and scope as defined in the appended claims, and therefore all changes and modifications that fall within the meets and bounds of the claims, or equivalences of such meets and bounds are therefore intended to be embraced by the appended claims.

Claims (10)

1. A preparation method of an aluminum briquetting deoxidizing agent is characterized by comprising the following steps:
crushing the collected aluminum recycling waste to enable the aluminum recycling waste to be crushed to form aluminum particles, and dehydrating by utilizing heat generated in the crushing process;
the aluminum particles are sent into a compression molding device, and the compression molding device presses the aluminum particles into blocky aluminum briquetting deoxidizer.
2. The method for producing a deoxidizer for aluminum briquetting of claim 1 wherein the aluminum recovered waste is a waste pop can, an automobile waste water tank, an aluminum waste heat sink, or a waste aluminum shavings.
3. The method for preparing a deoxidizer for aluminum briquetting according to claim 1, characterized in that, in the crushing process, the aluminum recovered waste with paint is depainted by mechanical removal; the heat generated in the crushing process is utilized for dehydration, the temperature of the space where the aluminum recovery waste is located is higher than 120 ℃, and the energy consumed in the crushing process is recovered.
4. The method for producing a deoxidizer for aluminum briquetting of claim 1 wherein the briquetting apparatus includes: the aluminum particle forming deoxidizer comprises a hydraulic press, a material distribution mechanism and a die, wherein the material distribution mechanism is used for conveying aluminum particles into the die arranged in the hydraulic press, and the hydraulic press presses the aluminum particles in the die into a blocky aluminum pressing block forming deoxidizer.
5. The method for producing a deoxidizer for aluminum briquetting according to claim 4, characterized in that the die comprises: the device comprises a die hole assembly, a pressing rod assembly and a jacking rod assembly; the fixed base beam of the hydraulic press is provided with a fixed support, the material distribution mechanism, the die hole assembly and the separated discharge port are respectively connected to the fixed support, the material distribution mechanism and the separated discharge port are respectively positioned on two sides of the die, the material distribution mechanism, the die and the separated discharge port are positioned between the fixed base beam and the movable beam, and the pressing rod assembly is arranged on the lower part of the movable beam of the hydraulic press; the orifice assembly includes: the hole sleeve mounting lower plate is provided with a plurality of lower plate through holes, the hole sleeve mounting upper plate is provided with a plurality of upper plate through holes, and the die hole sleeve is connected between the lower plate through holes and the upper plate through holes; two ends of the die hole sleeve are provided with rabbets which are inserted into the through hole of the lower plate and the through hole of the upper plate; the hold-down bar assembly includes: the device comprises a pressure rod mounting plate, a pressure rod and a pressure head, wherein the pressure rod mounting plate is provided with a plurality of pressure rod mounting through holes, the top ends of the pressure rods are inserted into the pressure rod mounting through holes, and the bottom ends of the pressure rods are connected with the pressure head; the jacking-rod assembly includes: the jacking rod mounting plate is provided with a plurality of jacking rod mounting through holes, the bottom ends of the jacking rods are inserted into the jacking rod mounting through holes, and the jacking head is connected to the top ends of the jacking rods; the bottom of the jacking rod mounting plate is connected to the top of the jacking rod of the jacking cylinder.
6. The method for preparing a deoxidizer for aluminum briquetting according to claim 5, characterized in that the material distribution mechanism includes: the cloth mechanism includes: the device comprises a raw material bin, a baffle plate, a material distribution box, an upper sealing plate, a rack, a material box guide strip, a telescopic mechanism and a lower sealing plate; the bottom of the baffle is connected with the side edge of the upper sealing plate, the baffle encloses a feeding channel, and the front end of the feeding channel is provided with a guide opening; a feed opening is formed in the bottom of the raw material bin, the feed opening is located in the feeding channel, and the bottom end of the feed opening is lower than the upper edge of the baffle; the front part of the upper sealing plate is provided with a feeding opening, the top of the material distribution box is connected to the lower part of the feeding opening, the upper part and the lower part of the material distribution box are respectively provided with an opening, and a plurality of material stirring devices are arranged in the material distribution box; the bottoms of the rear sections of the two bin guide strips are connected to the lower sealing plate, the front sections of the two bin guide strips extend out of two sides of the die hole assembly, and the racks are connected to the upper parts of the bin guide strips; the material poking device comprises: a deflector rod mounting shaft, a material poking rod, a material poking power gear and a bearing seat; the two bearing blocks are respectively connected to the outer side wall of the material distribution box, two ends of a deflector rod mounting shaft are respectively sleeved in the two bearing blocks, and the two material shifting power gears are respectively connected to the outer sides of the two bearing blocks; the end parts of the plurality of material stirring rods are connected to the outer wall of the material stirring rod mounting shaft, and the telescopic mechanism is connected between the lower sealing plate and the side wall of the rear end of the material distributing box.
7. The method for producing a deoxidizer of aluminum compact molding according to claim 6, wherein the step of pressing aluminum particles into the deoxidizer of aluminum compact molding in a lump shape by a press molding apparatus includes:
aluminum particles in the raw material bin fall into the material distribution box, the telescopic mechanism pushes the material distribution box to move forwards to the upper part of the die hole assembly, the upper sealing plate seals a feed opening of the raw material bin in the forward moving process of the material distribution box, after the material distribution box reaches the upper part of the die hole sleeve, an opening in the lower part of the material distribution box is opened, the rack drives the material stirring power gear to rotate, and the material stirring rod loads the aluminum particles into a hole cavity of the die hole sleeve in the rotating process;
after the aluminum particles are filled, the telescopic mechanism drives the material distribution box to move backwards, the material distribution box scrapes the aluminum particles of the die hole sleeve, the material distribution box moves backwards to the lower part of the raw material bin, the upper sealing plate opens the feed opening of the raw material bin, the lower sealing plate closes the lower opening of the material distribution box, and the aluminum particles fall into the material distribution box;
the telescopic rod is pressed downwards by the hydraulic cylinder to move downwards, the movable beam is pushed to move downwards, the movable beam drives the pressing rod assembly to move downwards, the pressing head at the lower part of the pressing rod extends into the hole cavity of the die hole sleeve, and the pressing head presses and forms aluminum particles to form a block-shaped aluminum pressing block forming deoxidizer;
the telescopic rod is pressed downwards to rise, the movable beam drives the pressing rod assembly to rise, and the pressing rod and the pressing head leave from the hole cavity of the die hole sleeve; a jacking rod of the jacking cylinder pushes the jacking rod assembly to rise, an ejector rod and an ejector head extend into the hole cavity of the die hole sleeve, and the aluminum briquetting deoxidizer is ejected out of the hole cavity;
the telescopic mechanism pushes the material distribution box to move forwards, the material distribution box pushes the aluminum briquetting deoxidizing agent to a separated discharge port, meanwhile, aluminum particles are filled into the hole cavity of the die hole sleeve again, and the aluminum briquetting deoxidizing agent falls into a collecting box at the lower part; and moving the material distributing box backwards, and pressing the aluminum particles into an aluminum briquetting and forming deoxidizer by the pressing and forming equipment.
8. The method for preparing a deoxidizer for aluminum briquetting as claimed in claim 5, wherein the top end of the pressure head is provided with a pressure head connecting end, the outer wall of the pressure head connecting end is provided with external threads, the bottom end of the pressure rod is provided with a pressure head connecting threaded hole, and the pressure head connecting end is connected in the pressure head connecting threaded hole by threads; the bottom of top is provided with top connection end, and top connection end outer wall is provided with the external screw thread, and the top of top is provided with top connection screw hole, and top connection end utilizes threaded connection in top connection screw hole.
9. The application method of the aluminum briquetting deoxidizer obtained by the preparation method of any one of claims 1 to 8 is characterized in that the aluminum briquetting deoxidizer is used as an aluminum-based deoxidizer for steelmaking.
10. The method for using the deoxidizer of aluminum compact forming of claim 9, wherein the deoxidizer of aluminum compact forming has an outer shape of a cylinder, an outer diameter of the cylinder is less than 50mm, or an outer diameter of the cylinder is between 50mm and 400 mm.
CN202210620148.XA 2022-06-02 2022-06-02 Preparation method and application method of aluminum briquetting deoxidizer Active CN114990287B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09263852A (en) * 1996-03-27 1997-10-07 Aikoo Kk Aluminum pressure molding and deoxidizing agent for iron and steel or raw material for remolten aluminum
CN102172964A (en) * 2011-01-21 2011-09-07 郑州华隆机械制造有限公司 Full-automatic hydraulic press
CN102304619A (en) * 2011-08-26 2012-01-04 刘济华 Method for producing directly-molten aluminum by using aluminum scraps
CN109097597A (en) * 2018-11-01 2018-12-28 长沙汇聚环境技术有限公司 A kind of recovery method of useless aluminium ring pull end
CN112626310A (en) * 2020-12-09 2021-04-09 攀枝花钢城集团有限公司 Aluminum-iron deoxidizer for smelting and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09263852A (en) * 1996-03-27 1997-10-07 Aikoo Kk Aluminum pressure molding and deoxidizing agent for iron and steel or raw material for remolten aluminum
CN102172964A (en) * 2011-01-21 2011-09-07 郑州华隆机械制造有限公司 Full-automatic hydraulic press
CN102304619A (en) * 2011-08-26 2012-01-04 刘济华 Method for producing directly-molten aluminum by using aluminum scraps
CN109097597A (en) * 2018-11-01 2018-12-28 长沙汇聚环境技术有限公司 A kind of recovery method of useless aluminium ring pull end
CN112626310A (en) * 2020-12-09 2021-04-09 攀枝花钢城集团有限公司 Aluminum-iron deoxidizer for smelting and preparation method thereof

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