CN114983833A - Wet and smooth cream paper and preparation method thereof - Google Patents

Wet and smooth cream paper and preparation method thereof Download PDF

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Publication number
CN114983833A
CN114983833A CN202110877289.5A CN202110877289A CN114983833A CN 114983833 A CN114983833 A CN 114983833A CN 202110877289 A CN202110877289 A CN 202110877289A CN 114983833 A CN114983833 A CN 114983833A
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Prior art keywords
wet
paper
cream
slippery
softener
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CN202110877289.5A
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CN114983833B (en
Inventor
张玉霞
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Tongling Tiantian Biotechnology Co ltd
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Tongling Tiantian Paper Technology Co ltd
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208—Tissues; Wipes; Patches
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K10/00—Body-drying implements; Toilet paper; Holders therefor
    • A47K10/16—Paper towels; Toilet paper; Holders therefor
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005—Antimicrobial preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/005—Preparations for sensitive skin
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/50—Spraying or projecting
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002—Tissue paper; Absorbent paper

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Biomedical Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Emergency Medicine (AREA)
  • Pest Control & Pesticides (AREA)
  • Paper (AREA)

Abstract

The invention belongs to the technical field of paper for daily use, and particularly relates to wet and smooth cream paper and a preparation method thereof. The invention provides a wet and slippery cream paper, which is prepared from the following raw materials of a wet and slippery cream composition and a base material; the base material is paper base. The prepared wet and smooth cream paper can achieve the effects of moisturizing and softening, and the obtained wet and smooth cream paper can be used for tender skin of infants without any stimulation to the skin; the slippery cream paper prepared by the invention is compounded and cooperated by the compound containing the benzyl ammonium salt and the softener, so that the slippery cream paper is ensured to have excellent smoothness and moisture retention, meanwhile, the antibacterial performance in the using process can be ensured, the moisture retention factor can be locked, the slippery cream paper is suitable for hands and mouths, the invasion of hand-foot-and-mouth viruses can be effectively blocked, and the application value is extremely high.

Description

Wet and smooth cream paper and preparation method thereof
Technical Field
The invention belongs to the technical field of paper for daily use, and particularly relates to wet and smooth cream paper and a preparation method thereof.
Background
With the improvement of the consumption level of people in China and the change of consumption habits, the status and the function of the daily paper in the life of people are more and more prominent, people are already used to replace the conventional handkerchief with the conventional paper as a main wiping object in daily life, and therefore, the development of the daily paper also presents a rapid trend.
With the rapid growth of the population, particularly after the release of the second birth policy, the demand for paper for daily use, particularly for mothers and babies, has increased year by year, and since mothers and babies require extremely high safety, the demand for paper products has become more stringent. At the present stage, there are also many products which are mainly used for making special paper for babies, the antibacterial cream for the baby soft tissue and the preparation method of the baby soft tissue provided by the Chinese invention patent CN111821203A disclose that the antibacterial effect of the antibacterial cream and the stability in the preparation process are relatively poor, and in order to further meet the requirements of paper for mothers and infants, the production and preparation of living paper which does not stimulate the tender skin of babies, is safe in preparation raw materials and has proper cost has greater significance.
Disclosure of Invention
In order to solve the above technical problems, a first aspect of the present invention provides a wet cream paper, which is prepared from raw materials including a wet cream composition and a base material;
the base material is a paper base.
As a preferred technical scheme, the preparation raw materials of the wet and slippery cream composition comprise: moisturizing factor, compound containing benzyl ammonium salt, softener, auxiliary agent and solvent.
Preferably, the moisturizing factor is at least one selected from hyaluronic acid, collagen, amino acids and phosphate esters.
As a preferred technical scheme, the compound containing benzyl ammonium salt is selected from at least one of methacryloyloxyethylbenzyldimethylammonium chloride, methacryloyloxymethylbenzyldimethylammonium chloride and dodecyl dimethylbenzylammonium chloride.
As a preferred technical solution, the weight ratio of the methacryloyloxyethylbenzyldimethylammonium chloride to the dodecyldimethylbenzylammonium chloride is 1: (0.3-1.2).
As a preferred technical solution, the weight ratio of methacryloyloxyethylbenzyldimethylammonium chloride to dodecyldimethylbenzylammonium chloride is 1: (0.5-1).
As a preferable technical scheme, the softener is at least one selected from silicone softeners, fatty acid salt softeners and ester-based quaternary ammonium salt softeners.
As a preferable technical scheme, the weight ratio of the compound containing benzyl ammonium salt to the softener is 1: (0.8-1.2).
As a preferable technical scheme, the preparation raw materials of the wet and slippery cream composition comprise the following components in percentage by weight: 0.001-0.01% of moisture retention factor, 0.1-1% of benzylammonium salt compound, 0.05-1.2% of softener, 2-10% of auxiliary agent and the balance of solvent supplement to 100%.
The second aspect of the invention provides a preparation method of wet and smooth cream paper, which comprises the following steps:
1) mixing raw materials for preparing the wet and slippery cream composition in a reaction kettle, stirring and homogenizing to obtain the wet and slippery cream composition;
2) adding the wet and slippery cream composition obtained in the step 1) into a spray type compound machine, and compounding the wet and slippery cream composition on the surface of paper through spraying and atomizing under pressure to obtain the wet and slippery cream composition.
Has the advantages that: the wet and smooth cream paper prepared by the invention has the following advantages:
1. the prepared wet and smooth cream paper can achieve the effects of moisturizing and softening, and the obtained wet and smooth cream paper can be used for tender skin of infants without any stimulation to the skin;
2. the preparation method of the wet and smooth cream paper provided by the invention is simple and suitable for large-scale popularization;
3. the wet and smooth cream paper prepared by the invention meets the national skin irritation test index and has extremely high application value;
4. the wet and smooth cream paper prepared by the invention has excellent smoothness and moisture retention, and simultaneously can ensure the antibacterial performance in the use process and lock moisture retention factors through the compounding synergistic effect of the benzyl ammonium salt compound and the softener, is suitable for hands and mouths, effectively prevents the invasion of hand-foot-and-mouth viruses, and has extremely high application value.
Detailed Description
The invention will be further understood by reference to the following detailed description of preferred embodiments of the invention and the examples included therein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. To the extent that a definition of a particular term disclosed in the prior art is inconsistent with any definitions provided herein, the definition of the term provided herein controls.
As used herein, a feature that does not define a singular or plural form is also intended to include a plural form of the feature unless the context clearly indicates otherwise. It will be further understood that the term "prepared from …," as used herein, is synonymous with "comprising," including, "comprising," "having," "including," and/or "containing," when used in this specification means that the recited composition, step, method, article, or device is present, but does not preclude the presence or addition of one or more other compositions, steps, methods, articles, or devices. Furthermore, the use of "preferred," "preferably," "more preferred," etc., when describing embodiments of the present application, is meant to refer to embodiments of the invention that may provide certain benefits, under certain circumstances. However, other embodiments may be preferred, under the same or other circumstances. In addition, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, nor is it intended to exclude other embodiments from the scope of the invention.
In order to solve the above technical problems, a first aspect of the present invention provides a wet cream paper, which is prepared from raw materials including a wet cream composition and a base material;
the base material is a paper base.
It is noted that in the present application the paper substrate is a common commercially available paper, such as roll toilet paper, facial tissue, paper towel, etc.
In some preferred embodiments, the wet cream composition is prepared from the following raw materials: moisturizing factor, compound containing benzyl ammonium salt, softener, auxiliary agent and solvent.
In some preferred embodiments, the moisturizing factor is at least one selected from hyaluronic acid, collagen, amino acid, and phosphate.
In some preferred embodiments, the moisturizing factor is hyaluronic acid and an amino acid.
In some preferred embodiments, the molecular weight of the hyaluronic acid is 1000000-1800000 Da.
Hyaluronic acid, purchased from chemical products, ltd, huayue, hannan.
In some preferred embodiments, the weight ratio of hyaluronic acid to amino acid is 0.6: (1-1.2).
In the experimental process, the applicant finds that the moisturizing factor added into the system can improve the moisturizing effect of the wet and smooth cream paper, and particularly has the mild moisturizing effect when the moisturizing factor is used on the skin of a baby, but in the experimental process, the applicant finds that the interaction between hyaluronic acid with the molecular weight of 1000000-1800000 Da and amino acid is selected, and the weight ratio of the hyaluronic acid to the amino acid is 0.6: (1-1.2), the stability of hyaluronic acid in the system can be ensured, and the damage of harmful substances in the environment to the skin is avoided. The applicant speculates that the reason for this phenomenon is: when the hyaluronic acid with the molecular weight of 1000000-1800000 Da is compounded with amino acid, the action effect of the hyaluronic acid in dermal cells is improved through the interaction force among molecules, the amino acid components are locked in the skin, the hydration of the skin is maintained, meanwhile, sufficient nutrients are provided for the cells, skin lipid is protected, and the resistance activity to oxidation substances such as sunlight is excited, meanwhile, due to the synergistic effect of the amino acid and the hyaluronic acid with the molecular weight of 1000000-1800000 Da, a protective barrier can be formed on the surface layer of the skin, the skin is prevented from being eroded by harmful substances in the environment such as dust and sunlight, the moisture retention performance of the skin is improved, and meanwhile, the damage of the external harmful substances is reduced.
In some preferred embodiments, the benzyl ammonium salt-containing compound is at least one selected from the group consisting of methacryloyloxyethylbenzyldimethylammonium chloride, methacryloyloxymethylbenzyldimethylammonium chloride, and dodecyldimethylbenzylammonium chloride.
In some preferred embodiments, the weight ratio of methacryloyloxyethylbenzyldimethylammonium chloride to dodecyldimethylbenzylammonium chloride is 1: (0.3-1.2).
In some preferred embodiments, the weight ratio of methacryloyloxyethylbenzyldimethylammonium chloride to dodecyldimethylbenzylammonium chloride is 1: (0.5-1).
In the experimental process, the applicant finds that the benzyl ammonium salt compound selected in the system provides certain antibacterial performance for the wet-skid cream paper, and particularly when the benzyl ammonium salt compound is methacryloyloxyethylbenzyldimethylammonium chloride and dodecyldimethylbenzylammonium chloride, the damage to infants caused by hand-foot-and-mouth viruses and the like can be resisted, and the reason for the phenomenon is presumed that: in the system, through the synergistic effect of methacryloyloxyethylbenzyldimethylammonium chloride and dodecyldimethylbenzylammonium chloride, strong interaction force or hydrophobic association can be generated with protein molecules in the hand-foot-and-mouth virus through electrostatic interaction, intermolecular strong hydrogen bond action and the like, so that the protein helical structure of the virus is damaged, the protein loses physiological activity, the normal growth of the virus is inhibited, and the capacities of infection, pathogenesis and reproduction are lost. The compound is compounded with methacryloyloxyethylbenzyldimethylammonium chloride and dodecyl-dimethylbenzylammonium chloride in a weight ratio of 1: (0.5-1), the charge density in the system is improved, the high efficiency of the action with the virus is improved, and the capability of quickly removing the virus is achieved.
In some preferred embodiments, the softener is selected from at least one of silicone softeners, fatty acid salt softeners, and esterquat softeners.
In some preferred embodiments, the softener is an esterquat softener.
In some preferred embodiments, the esterquat softener is selected from distearyldimethylammonium chloride, alkyl ester quaternaries, imidazoline quaternaries, and bis fatty acid ethylhydroxyethyl methyl ammonium methyl sulfate.
Bis fatty acid ethyl ester hydroxyethyl methyl ammonium methyl sulfate, available from bosch Huarun oleochemical Co., Ltd.
In the experimental process, the applicant finds that the softening performance of the prepared wet and smooth cream paper can be greatly improved by adding the esterquat softener into the system, and when the added esterquat is the difatty ethyl hydroxyethyl methyl ammonium methyl sulfate, the flexibility can be ensured, and meanwhile, the better dispersing performance of the esterquat in the system can be ensured. The applicant speculates that this phenomenon occurs because: the hyaluronic acid in the system can provide more attachment sites for the ester quaternary ammonium salt, and when the hyaluronic acid is immersed in the paper base, the friction coefficient between short fibers in the paper base can be improved, the water absorption performance of the paper base is improved, and the effect of protecting tender skin of a baby when the hyaluronic acid is used as wet and smooth cream paper is ensured.
In some preferred embodiments, the weight ratio of the benzylammonium salt-containing compound to the softener is 1: (0.1-0.8).
In some preferred embodiments, the weight ratio of the benzyl ammonium salt-containing compound to the softener is 1: 0.7.
through a large amount of creative experimental researches, the applicant discovers that the weight ratio of the compound containing benzylammonium salt to the softener added into the system is 1: (0.1-0.8), the synergistic effect between the benzyl ammonium salt compound and the softener can be improved, the antibacterial and softening effects of the wet-slip cream paper are improved, and the yellowing resistance of the wet-slip cream paper is improved, and the applicant speculates that the reason for the phenomenon is that: because more cationic groups exist on the surfaces of the compounds containing benzyl ammonium salt, such as methacryloyloxyethylbenzyldimethylammonium chloride, dodecyl dimethyl benzyl ammonium chloride and di-fatty acid ethyl ester hydroxyethyl methyl ammonium methosulfate, the compounds can be further bonded with active groups with negative charges in the system, the stability of the network structure of the compounds is improved, and when the compounds face light, heat and other stimuli, the generation of active centers among molecular chains is reduced due to strong interaction among molecules, the breakage of carbon-carbon bonds and the like is avoided, and the occurrence of paper yellowing is avoided.
Meanwhile, the applicant finds that when the content of the softener is too much, the heat resistance is reduced, and the wet skid effect of the fabric can be influenced due to the change of temperature during the storage process.
In some preferred embodiments, the wet cream composition is prepared from raw materials by weight percentage, including: 0.001-0.01% of moisture retention factor, 0.1-1% of benzylammonium salt compound, 0.05-0.8% of softener, 2-10% of auxiliary agent and the balance of solvent supplement to 100%.
In some preferred embodiments, the adjuvant comprises at least one of glycerol, tetramethylolmethane, and propylene glycol.
The second aspect of the invention provides a preparation method of wet and smooth cream paper, which comprises the following steps:
1) mixing raw materials for preparing the wet and slippery cream composition in a reaction kettle, stirring and homogenizing to obtain the wet and slippery cream composition;
2) adding the wet and slippery cream composition obtained in the step 1) into a spray type compound machine, and compounding the wet and slippery cream composition on the surface of paper through spraying and atomizing under pressure to obtain the wet and slippery cream composition.
In addition, the starting materials used are all commercially available, unless otherwise specified.
Examples
The present invention will be specifically described below by way of examples. It should be noted that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention, and that the insubstantial modifications and adaptations of the present invention by those skilled in the art based on the above disclosure are still within the scope of the present invention.
Example 1
A wet and slippery cream paper is prepared from wet and slippery cream composition and paper base;
the wet and slippery cream composition comprises the following raw materials in percentage by weight: 0.001% of moisturizing factor, 0.1% of benzylammonium salt compound, 0.05% of softener, 2% of auxiliary agent and the balance of solvent to 100%.
The moisturizing factor is hyaluronic acid and amino acid, the molecular weight of the hyaluronic acid is 1000000-1800000 Da, and the hyaluronic acid is purchased from Henan Huayue chemical products Co.
The weight ratio of hyaluronic acid to amino acid is 0.6: 1.
the benzyl ammonium salt-containing compounds are methacryloyloxyethyl benzyl dimethyl ammonium chloride and dodecyl dimethyl benzyl ammonium chloride, and the weight ratio of the compounds is 1: 0.7.
the softener is difatty ethyl hydroxyethyl methyl sulfate, and is purchased from Boxing Huarun oil chemical Co.
The auxiliary agent is glycerol, tetramethylolmethane and propylene glycol, and the weight percentages of the auxiliary agent are respectively 1.5%, 1% and 0.5%.
The solvent is water.
A preparation method of wet and smooth cream paper comprises the following steps:
1) mixing raw materials for preparing the wet and slippery cream composition in a reaction kettle, stirring and homogenizing to obtain the wet and slippery cream composition;
2) adding the wet and slippery cream composition obtained in the step 1) into a spray type compound machine, and compounding the wet and slippery cream composition on the surface of paper through spraying and atomizing under pressure to obtain the wet and slippery cream composition.
Example 2
A wet and slippery cream paper is prepared from wet and slippery cream composition and paper base;
the wet and slippery cream composition comprises the following raw materials in percentage by weight: 0.01% of moisturizing factor, 1% of benzylammonium salt compound, 0.8% of softener, 10% of auxiliary agent and the balance of solvent supplement to 100%.
The moisturizing factor is hyaluronic acid and amino acid, the molecular weight of the hyaluronic acid is 1000000-1800000 Da, and the hyaluronic acid is purchased from Henan Huayue chemical products Co.
The weight ratio of hyaluronic acid to amino acid is 0.6: 1.2.
the benzyl ammonium salt-containing compounds are methacryloyloxyethyl benzyl dimethyl ammonium chloride and dodecyl dimethyl benzyl ammonium chloride, and the weight ratio of the compounds is 1: 0.7.
the softener is difatty ethyl hydroxyethyl methyl sulfate, and is purchased from Boxing Huarun oil chemical Co.
The auxiliary agent is glycerol, tetramethylolmethane and propylene glycol, and the weight percentages of the auxiliary agent are respectively 6%, 3% and 1%.
The solvent is water.
A method of making a wet-slip paper cream reference example 1.
Example 3
A wet and slippery cream paper is prepared from wet and slippery cream composition and paper base;
the wet and slippery cream composition comprises the following raw materials in percentage by weight: 0.008% of moisturizing factor, 0.8% of benzylammonium salt compound, 0.4% of softener, 8% of auxiliary agent and the balance of solvent supplement to 100%.
The moisturizing factor is hyaluronic acid and amino acid, the molecular weight of the hyaluronic acid is 1000000-1800000 Da, and the hyaluronic acid is purchased from Henan Huayue chemical products Co.
The weight ratio of hyaluronic acid to amino acid is 0.6: 1.1.
the benzyl ammonium salt-containing compounds are methacryloyloxyethyl benzyl dimethyl ammonium chloride and dodecyl dimethyl benzyl ammonium chloride, and the weight ratio of the compounds is 1: 0.7.
the softener is difatty ethyl hydroxyethyl methyl sulfate, and is purchased from Boxing Huarun oil chemical Co.
The auxiliary agent is glycerol, tetramethylolmethane and propylene glycol, and the weight percentages of the auxiliary agent are respectively 5%, 2% and 1%.
The solvent is water.
A method of making a wet-slip cream paper is according to example 1.
Example 4
A wet and slippery cream paper is prepared from wet and slippery cream composition and paper base;
the wet and slippery cream composition comprises the following raw materials in percentage by weight: 0.008% of moisturizing factor, 0.8% of benzylammonium salt compound, 0.4% of softener, 8% of auxiliary agent and the balance of solvent to 100%.
The moisturizing factor is hyaluronic acid and amino acid, the molecular weight of the hyaluronic acid is 1800000-2200000 Da, and the hyaluronic acid is purchased from Henan Huayue chemical products Co.
The weight ratio of hyaluronic acid to amino acid is 0.6: 1.1.
the benzyl ammonium salt-containing compounds are methacryloyloxyethyl benzyl dimethyl ammonium chloride and dodecyl dimethyl benzyl ammonium chloride, and the weight ratio of the compounds is 1: 0.7.
the softener is difatty ethyl hydroxyethyl methyl sulfate, and is purchased from Boxing Huarun oil chemical Co.
The auxiliary agent is glycerol, tetramethylolmethane and propylene glycol, and the weight percentages of the auxiliary agent are respectively 5%, 2% and 1%.
The solvent is water.
A method of making a wet-slip cream paper is according to example 1.
Example 5
A wet and slippery cream paper is prepared from wet and slippery cream composition and paper base;
the wet and slippery cream composition comprises the following raw materials in percentage by weight: 0.008% of moisturizing factor, 0.8% of benzylammonium salt compound, 1% of softener, 8% of auxiliary agent and the balance of solvent supplement to 100%.
The moisturizing factor is hyaluronic acid and amino acid, the molecular weight of the hyaluronic acid is 1000000-1800000 Da, and the hyaluronic acid is purchased from Henan Huayue chemical products Co.
The weight ratio of hyaluronic acid to amino acid is 0.6: 1.1.
the benzyl ammonium salt-containing compounds are methacryloyloxyethyl benzyl dimethyl ammonium chloride and dodecyl dimethyl benzyl ammonium chloride, and the weight ratio of the compounds is 1: 0.7.
the softener is difatty ethyl hydroxyethyl methyl sulfate, and is purchased from Boxing Huarun oil chemical Co.
The auxiliary agent is glycerol, tetramethylolmethane and propylene glycol, and the weight percentages of the auxiliary agent are respectively 5%, 2% and 1%.
The solvent is water.
A method of making a wet-slip cream paper is according to example 1.
Example 6
A wet and slippery cream paper is prepared from wet and slippery cream composition and paper base;
the wet and slippery cream composition comprises the following raw materials in percentage by weight: 0.008% of moisturizing factor, 0.8% of benzylammonium salt compound, 0.08% of softener, 8% of auxiliary agent and the balance of solvent supplement to 100%.
The moisturizing factor is hyaluronic acid and amino acid, the molecular weight of the hyaluronic acid is 1000000-1800000 Da, and the hyaluronic acid is purchased from Henan Huayue chemical products Co.
The weight ratio of hyaluronic acid to amino acid is 0.6: 1.1.
the benzyl ammonium salt-containing compounds are methacryloyloxyethyl benzyl dimethyl ammonium chloride and dodecyl dimethyl benzyl ammonium chloride, and the weight ratio of the compounds is 1: 0.7.
the softener is difatty ethyl hydroxyethyl methyl sulfate, and is purchased from Boxing Huarun oil chemical Co.
The auxiliary agent is glycerol, tetramethylolmethane and propylene glycol, and the weight percentages of the auxiliary agent are respectively 5%, 2% and 1%.
The solvent is water.
A method of making a wet-slip paper cream reference example 1.
Example 7
A wet and slippery cream paper is prepared from wet and slippery cream composition and paper base;
the wet and slippery cream composition comprises the following raw materials in percentage by weight: 0.008% of moisturizing factor, 0.8% of benzylammonium salt compound, 0.4% of softener, 8% of auxiliary agent and the balance of solvent supplement to 100%.
The moisturizing factor is hyaluronic acid and amino acid, the molecular weight of the hyaluronic acid is 1000000-1800000 Da, and the moisturizing factor is purchased from Henan Huayue chemical products Limited company.
The weight ratio of hyaluronic acid to amino acid is 0.6: 1.1.
the benzyl ammonium salt-containing compound is dodecyl dimethyl benzyl ammonium chloride.
The softener is difatty ethyl hydroxyethyl methyl sulfate, and is purchased from Boxing Huarun oil chemical Co.
The auxiliary agent is glycerol, tetramethylolmethane and propylene glycol, and the weight percentages of the auxiliary agent are respectively 5%, 2% and 1%.
The solvent is water.
A method of making a wet-slip paper cream reference example 1.
And (3) performance testing:
1. the wet and slippery cream paper prepared in example 3 was used for antiviral performance test, and the test virus was coxsackie virus, and the test results were recorded in table 1 below.
Table 1:
experiment of Viral clearance rate%
Example 3 95.4％
2. Skin irritation test: the test method is referred to "Disinfection Specification" (2002 edition), and the test animal is a New Zealand rabbit.
The results of the tests for examples 1-3 are reported in table 2 below.
Table 2:
experiment of Skin irritation
Example 1 Is free of
Example 2 Is composed of
Example 3 Is composed of
3. Yellowing resistance test: the wet slip cream papers prepared in examples 1 to 3 and 5 to 7 were used for yellowing resistance test, and the test method was according to astm d1148-1995, wherein the yellowing resistance rating was recorded in the following table, which was classified into 1 to 5, 5 represents no discoloration, 3 or below represents the occurrence of significant discoloration, and the test results were recorded in the following table.
Experiment of Yellowing resistance per grade
Example 1 5
Example 2 5
Example 3 5
Example 5 4
Example 6 3
Example 7 3
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is specific and detailed, but not to be understood as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.

Claims (10)

1. The wet and slippery cream paper is characterized in that the preparation raw materials comprise a wet and slippery cream composition and a base material;
the base material is a paper base.
2. The slip cream paper as claimed in claim 1, wherein the slip cream composition is prepared from the following raw materials: moisturizing factor, compound containing benzyl ammonium salt, softener, auxiliary agent and solvent.
3. The wet and slippery cream paper as claimed in claim 2, wherein the moisturizing factor is at least one selected from hyaluronic acid, collagen, amino acids, and phosphates.
4. The wet and slippery cream paper as claimed in claim 2, wherein the benzyl ammonium salt compound is at least one selected from the group consisting of methacryloyloxyethylbenzyldimethylammonium chloride, methacryloyloxymethylbenzyldimethylammonium chloride, and dodecyldimethylbenzylammonium chloride.
5. The wet slip cream paper as claimed in claim 4, wherein the weight ratio of methacryloyloxyethylbenzyldimethylammonium chloride to dodecyldimethylbenzylammonium chloride is 1: (0.3-1.2).
6. The wet slip cream paper as claimed in claim 5, wherein the weight ratio of methacryloyloxyethylbenzyldimethylammonium chloride to dodecyldimethylbenzylammonium chloride is 1: (0.5-1).
7. The wet and slippery cream paper as claimed in claim 2, wherein the softener is at least one selected from the group consisting of silicone softener, fatty acid salt softener, and esterquat softener.
8. The wet wiping cream paper as claimed in claim 2 or 7, characterized in that the weight ratio of the compound containing benzyl ammonium salt to the softener is 1: (0.8-1.2).
9. The wet cream paper as claimed in claim 2, wherein the wet cream composition is prepared from raw materials in percentage by weight comprising: 0.001-0.01% of moisture retention factor, 0.1-1% of benzylammonium salt compound, 0.05-1.2% of softener, 2-10% of auxiliary agent and the balance of solvent supplement to 100%.
10. A method of making a wet skim paper according to any one of claims 1 to 2, comprising the steps of:
1) mixing raw materials for preparing the wet and slippery cream composition in a reaction kettle, stirring and homogenizing to obtain the wet and slippery cream composition;
2) adding the wet and slippery cream composition obtained in the step 1) into a spray type compound machine, and compounding the wet and slippery cream composition on the surface of paper through spraying and atomizing under pressure to obtain the wet and slippery cream composition.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102871867A (en) * 2012-10-24 2013-01-16 金红叶纸业集团有限公司 Cream composition and paper comprising same
WO2016126059A1 (en) * 2015-02-04 2016-08-11 임호 Antibacterial composition and wet tissue comprising antibacterial composition
CN109431837A (en) * 2018-11-27 2019-03-08 旌德县万方日用品有限公司 A kind of moisturizing beauty paper handkerchief and preparation method thereof
CN111821203A (en) * 2020-06-22 2020-10-27 浙江新远实业有限公司 Antibacterial cream for baby soft tissue and preparation method of baby soft tissue

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102871867A (en) * 2012-10-24 2013-01-16 金红叶纸业集团有限公司 Cream composition and paper comprising same
WO2016126059A1 (en) * 2015-02-04 2016-08-11 임호 Antibacterial composition and wet tissue comprising antibacterial composition
CN109431837A (en) * 2018-11-27 2019-03-08 旌德县万方日用品有限公司 A kind of moisturizing beauty paper handkerchief and preparation method thereof
CN111821203A (en) * 2020-06-22 2020-10-27 浙江新远实业有限公司 Antibacterial cream for baby soft tissue and preparation method of baby soft tissue

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