CN114958109A

CN114958109A - Makeup art paint and preparation method thereof

Info

Publication number: CN114958109A
Application number: CN202210621309.7A
Authority: CN
Inventors: 李勇; 李昊洋; 黄夕珈; 李俊聪
Original assignee: Chengdu Fubaile Decoration Materials Industry Co ltd
Current assignee: Chengdu Fubaile Decoration Materials Industry Co ltd
Priority date: 2022-06-02
Filing date: 2022-06-02
Publication date: 2022-08-30

Abstract

The application relates to the field of art paint, and particularly discloses makeup art paint and a preparation method thereof, wherein the art paint comprises the following raw materials in parts by weight: 30-50 parts of elastic acrylic emulsion, 6-12 parts of pearl powder, 35-48 parts of water, 10-19 parts of calcium carbonate, 0.2-0.45 part of coupling agent, 0.1-0.3 part of defoaming agent, 0.1-0.25 part of oxidized polyethylene wax, 2-7 parts of conditioner and 3-9 parts of dirt-resistant material; the antifouling material comprises acrylic powder, silica sol, pure acrylic emulsion and silica dimethyl silylate. The preparation method of the art paint comprises the following preparation steps: according to the formula, the elastic acrylic emulsion, the pearl powder, the calcium carbonate, the dirt-resistant material and the conditioner are uniformly mixed, then the coupling agent, the defoaming agent, the oxidized polyethylene wax and the water are added, and the mixture is uniformly stirred. The artistic paint prepared by the method has the advantages of high elasticity and good elongation at break, and has excellent stain resistance and strong stain resistance.

Description

Makeup art paint and preparation method thereof

Technical Field

The application relates to the field of art paint, in particular to makeup art paint and a preparation method thereof.

Background

In the interior decoration, almost all adopt emulsion paint before, and decorative effect is ordinary, and the colour is all white basically, but along with the development of socioeconomic, people's requirement to interior decoration is more and more high, and the makeup paint can show different individualized decorative effect because of its rich look and artistic sense, receives consumer's favor more.

For example, patent application with publication number CN113563780A discloses a bluestone art paint and a preparation method thereof, wherein the bluestone art paint comprises the following raw materials in parts by weight: 8-12 parts of natural blue stone, 10-12 parts of silicon micropowder, 0.2-0.3 part of film-forming additive, 1-3 parts of thickening agent, 0.8-1.2 parts of pH regulator, 4-7 parts of talcum powder, 4-7 parts of pure acrylic emulsion, 0.5-1.5 parts of bactericide, 25-36 parts of water and 4-6 parts of powdered ink. The silicon micropowder and the ink powder are introduced into the art paint, so that the fineness and the using amount of the silicon micropowder and the ink powder are adjusted through research, and the silicon micropowder and the ink powder are combined with the existing raw materials through research and selection of proper auxiliary components and using amounts, so that the silicon micropowder and the ink powder have better stereoscopic impression. The makeup art paint is non-toxic, green and environment-friendly, does not contain harmful substances such as formaldehyde and the like, and has various colors and bright composite color.

In the process of decoration and use by adopting the art paint, the inventor finds that the extensibility of the art paint is poor and the art paint is easy to break in the brushing process, and the paint film is always exposed in the environment and has various external pollutants such as dust, oil smoke, dust and the like in the environment, so that the art paint begins to change color and have poor glossiness after being used for a period of time, and the stain resistance of the art paint is poor.

Disclosure of Invention

The application provides a color cosmetic art paint and a preparation method thereof, which can effectively improve the elongation at break and stain resistance of a paint film.

In a first aspect, the application provides a color art paint which adopts the following technical scheme:

the makeup art paint comprises the following raw materials in parts by weight: 30-50 parts of elastic acrylic emulsion, 6-12 parts of pearl powder, 35-48 parts of water, 10-19 parts of calcium carbonate, 0.2-0.45 part of coupling agent, 0.1-0.3 part of defoaming agent, 0.1-0.25 part of oxidized polyethylene wax, 2-7 parts of conditioner and 3-9 parts of dirt-resistant material; the antifouling material comprises acrylic powder, silica sol, pure acrylic emulsion and silica dimethyl silylate;

the conditioner is prepared by the following steps: adding hydrophilic colloid into water to form a glue solution, adding titanium dioxide and rubber micro powder into an acetic acid solution, stirring to form a slurry, stirring the glue solution, then adding the slurry while dropwise adding a cross-linking agent, wherein the addition amount of the cross-linking agent is 1-2% of the mass of the hydrophilic colloid, and uniformly stirring to obtain the conditioner.

By adopting the technical scheme, the elastic acrylic emulsion has good elasticity and workability, good film forming property and good compounding compatibility with other raw material components, the pearl powder can endow the art paint with good color sense and stereoscopic impression, the oxidized polyethylene wax has good lubricating and dispersing effects, the wetting dispersion and suspension properties of the pearl powder, the dirt-resistant material and the conditioner in a system can be improved, the precipitation of particles in the system is reduced, the elongation at break of a paint film is assisted to be improved, and meanwhile, the art paint has good anti-fouling effect.

The acrylic powder generally has the grain diameter of 15-30 mu m, can be used as filler for filling, has good transparency, can improve the color presentation effect of the art paint, and has fine sol particles and stronger permeability and dispersibility; the acrylic powder is modified by adopting the silica sol under a certain condition, when the water in the silica sol solution is evaporated, the colloidal particles are firmly attached to the surface of the acrylic powder, silica bonding is formed among the particles, the binding power of the whole system is enhanced, and the colloidal particles are compounded with the pure acrylic emulsion and the silica dimethyl silylate under a certain condition to form a coating film with good antifouling, dustproof and elastic properties, so that the antifouling property of the coating film is improved, and the formed coating film has excellent antifouling property.

Uniformly dispersing titanium dioxide and rubber micro powder in an acetic acid solution, curing and crosslinking by adopting a hydrophilic colloid under the action of a crosslinking agent, carrying the added titanium dioxide and rubber micro powder in a crosslinking reaction to form a microcapsule with good elasticity, and compounding with an elastic acrylic emulsion, so that the elongation at break of the art paint can be effectively improved, and the art paint has good elasticity; under the action of the coupling agent, the compatibility between the conditioning agent and each raw material component can be improved, the effect of the conditioning agent is promoted to be exerted, a paint film with uniform elasticity is formed by coating, and the stain resistance of the paint film is optimized to a certain extent. Wherein, the acetic acid solution generally adopts 5 percent acetic acid solution by mass concentration to promote the progress of the crosslinking reaction and the crosslinking effect.

Preferably, the hydrophilic colloid is selected from at least two of gelatin, gum arabic, carrageenan, and xanthan gum.

By adopting the technical scheme, the selection of the components of the hydrophilic colloid is optimized, so that the hydrophilic colloid is favorable for better curing and crosslinking with a crosslinking agent, the elasticity of a paint film is improved, the elongation at break of the art paint is improved, the hydrophilic colloid is usually compounded by gelatin, Arabic gum and xanthan gum, the crosslinking effect is improved, the elongation at break of the paint film is favorably improved, and the elasticity of the art paint is improved.

Preferably, the cross-linking agent is formaldehyde or glutaraldehyde.

By adopting the technical scheme, the selection of the cross-linking agent is optimized, the cross-linking curing effect is improved, the formaldehyde has certain toxicity, the glutaraldehyde can be selected for carrying out the cross-linking reaction, and the glutaraldehyde has certain volatility, but has certain sterilization and anticorrosion effects, and can assist in improving the corrosion resistance of the art paint.

Preferably, the mass ratio of the hydrophilic colloid, the titanium dioxide and the rubber micro powder is (1.7-3): 4-6.5): 0.7-1.5.

By adopting the technical scheme, the dosage relationship of the hydrophilic colloid, the titanium dioxide and the rubber micro powder is optimized, so that the art paint has good elongation at break and good elasticity, and a paint film formed by coating has good color and luster, good stereoscopic impression and good comprehensive performance.

Preferably, the stain-resistant material is prepared by the following steps:

step 1, placing acrylic powder in an alkali liquor, heating to 40-55 ℃, filtering and cleaning the alkali liquor, adding silica sol, and maintaining to obtain solid slurry;

and 2, mixing the pure acrylic emulsion and the silica dimethyl silylate, performing ultrasonic uniform dispersion to obtain a mixture, and performing spray granulation on the mixture and the solid slurry to obtain the stain-resistant material.

By adopting the technical scheme, the acrylic powder is placed in warm alkali liquor, a certain etching effect is realized on the surface of the acrylic powder, the apparent performance of the acrylic powder is improved, certain pores are generated on the surface of the acrylic powder, the surface area of the acrylic powder is increased, the adhesion of silica sol is facilitated, in the maintenance process, water in the silica sol solution is evaporated, colloid particles are firmly adhered to the surface of the acrylic powder, silica bonding is formed among the particles, and then the colloidal particles are sprayed and granulated with the mixture of the acrylic emulsion and the silica dimethyl silylate to form the stain-resistant material, so that a stain-resistant, dust-proof and good-elasticity coating film can be formed after the art paint is coated, and the stain resistance and the elasticity of the coating film are improved.

Preferably, the mass ratio of the solid slurry, the pure acrylic emulsion and the silica dimethyl silylate is (3-7): (1.4-2.5): (0.7-1.5).

By adopting the technical scheme, the dosage relationship among the solid slurry, the pure acrylic emulsion and the silica dimethyl silylate is optimized, and the stain resistance of the art paint is further improved.

Preferably, in the step 1, curing is performed at a temperature of 50-65 ℃ to obtain a solid slurry with a solid content of 60-75%.

By adopting the technical scheme, the curing condition is optimized, the modification effect of the silica sol on the acrylic powder is improved, and the binding power of the acrylic powder is improved, so that an excellent anti-fouling dustproof coating film is formed after the art paint is coated to form a film.

Preferably, the raw materials also comprise 0.2-0.5 part of color paste.

By adopting the technical scheme, the color of the color paste can be selected according to actual needs, and the color paste is selected instead of pigment particles, so that the color effect of the art paint can be improved, a paint film with uniform color is formed, and the color of the art paint can be effectively improved by matching with the pearl powder.

In a second aspect, the application provides a preparation method of a makeup art paint, which adopts the following technical scheme:

a preparation method of a color cosmetic art paint comprises the following preparation steps: according to the formula, the elastic acrylic emulsion, the pearl powder, the calcium carbonate, the dirt-resistant material and the conditioner are uniformly mixed, then the coupling agent, the defoaming agent, the oxidized polyethylene wax and the water are added, and the mixture is uniformly stirred.

By adopting the technical scheme, the main components are uniformly mixed, and then the auxiliary agent is added, so that the comprehensive quality of the art paint is improved.

In summary, the present application has the following beneficial effects:

1. the elastic acrylic emulsion has good elasticity and workability, good film forming property and good compounding compatibility with other raw material components, the pearl powder can endow the art paint with good color sense and stereoscopic impression, the oxidized polyethylene wax has good lubricating and dispersing effects, the wetting dispersion and suspension of the pearl powder, the dirt-resistant material and the conditioner in a system can be improved, the precipitation of particles in the system is reduced, the elongation at break of a paint film is improved in an assisting manner, and meanwhile, the art paint has a good anti-fouling effect.

2. The titanium dioxide and the rubber micro powder are uniformly dispersed in the acetic acid solution, the hydrophilic colloid is adopted for curing and crosslinking under the action of the crosslinking agent, the added titanium dioxide and the rubber micro powder are carried in the crosslinking reaction to form a microcapsule with good elasticity, and after the microcapsule is compounded with the elastic acrylic emulsion, the elongation at break of the art paint can be effectively improved, so that the art paint has good elasticity. Under the action of the coupling agent, the compatibility between the conditioning agent and each raw material component can be improved, the effect of the conditioning agent is promoted to be exerted, a paint film with uniform elasticity is formed by coating, and the stain resistance of the paint film is optimized to a certain extent.

3. The acrylic powder is placed in warm alkali liquor, a certain etching effect is achieved on the surface of the acrylic powder, the apparent performance of the acrylic powder is improved, certain pores are formed on the surface of the acrylic powder, the surface area of the acrylic powder is increased, the adhesion of silica sol is facilitated, in the maintenance process, water in the silica sol solution is evaporated, colloid particles are firmly attached to the surface of the acrylic powder, silica bonding is formed among the particles, then the colloid particles are sprayed and granulated with the mixture of the pure acrylic emulsion and the dimethyl silylated silica, and the formed stain-resistant material enables a stain-resistant, dustproof and good-elasticity coating film to be formed after the art paint is coated, and the stain resistance and the elasticity of the paint film are improved.

Detailed Description

The present application will be described in further detail with reference to examples.

The raw materials used in the application are all common commercially available raw materials, the defoaming agent is an organic silicon defoaming agent, and the rubber micro powder is white silicon rubber micro powder with the particle size of 20-35 mu m; the acrylic powder is purchased from Virginia plastic raw material Co., Ltd, the particle size is 15-30 μm, and the coupling agent is aminosilane coupling agent.

Preparation of Conditioning agent

Preparation example 1

The conditioner is prepared by the following steps: adding hydrophilic colloid into water of 45 ℃ to form a glue solution, adding titanium dioxide and rubber micro powder into an acetic acid solution with the mass concentration of 5%, stirring to form a slurry, stirring the glue solution, then adding the slurry while dropwise adding formaldehyde, wherein the adding amount of the formaldehyde is 1% of the mass of the hydrophilic colloid, and uniformly stirring to obtain a conditioner;

the hydrophilic colloid is xanthan gum and gelatin with the mass ratio of 1: 2;

the mass ratio of the hydrophilic colloid, the titanium dioxide and the rubber micro powder is 1.7:4: 0.7.

Preparation example 2

The conditioner is prepared by the following steps: adding hydrophilic colloid into water of 45 ℃ to form a glue solution, adding titanium dioxide and rubber micro powder into an acetic acid solution with the mass concentration of 5%, stirring to form a slurry, stirring the glue solution, then adding glutaraldehyde dropwise while adding the slurry, wherein the addition amount of the glutaraldehyde is 2% of the mass of the hydrophilic colloid, and uniformly stirring to obtain a conditioner;

the hydrophilic colloid is acacia and carrageenan with the mass ratio of 2: 1.5;

the mass ratio of the hydrophilic colloid, the titanium dioxide and the rubber micro powder is 3:6.5: 1.5.

Preparation example 3

The difference from preparation example 2 is that the hydrophilic colloid is gelatin, gum arabic, carrageenan and xanthan gum in a mass ratio of 1:1:1:1, and the rest is the same as preparation example 2.

Preparation example 4

The difference from preparation example 2 is that the hydrophilic colloid is gelatin, gum arabic and xanthan gum in a mass ratio of 3:2:1, and the rest is the same as preparation example 2.

Preparation example 5

The difference from the preparation example 4 is that the mass ratio of the hydrophilic colloid, the titanium dioxide and the rubber micro powder is 2.6:6:1.3, and the rest is the same as the preparation example 4.

Preparation example 6

The difference from the preparation example 4 is that the mass ratio of the hydrophilic colloid, the titanium dioxide and the rubber micro powder is 1:6.9:2, and the rest is the same as the preparation example 4.

Preparation of soil resist

Preparation example 1

The stain-resistant material is prepared by the following steps:

step 1, placing acrylic powder in a sodium hydroxide solution with the mass concentration of 8%, heating to 40 ℃, stirring for 15min, filtering, cleaning, adding silica sol, and maintaining at the temperature of 50 ℃ for 20min to obtain solid slurry with the solid content of 75%;

step 2, mixing the pure acrylic emulsion and the silica dimethyl silylate, performing ultrasonic uniform dispersion to obtain a mixture, and performing spray granulation on the mixture and the solid slurry to obtain the dirt-resistant material with the particle size of less than 30 microns;

wherein the mass ratio of the solid slurry, the pure acrylic emulsion and the silica dimethyl silylate is 3:1.4: 0.7.

Preparation example two

The stain-resistant material is prepared by the following steps:

step 1, placing acrylic powder in a sodium hydroxide solution with the mass concentration of 10%, heating to 55 ℃, stirring for 15min, filtering, cleaning, adding silica sol, and maintaining for 20min at the temperature of 65 ℃ to obtain solid slurry with the solid content of 60%;

wherein the mass ratio of the solid slurry, the pure acrylic emulsion and the silica dimethyl silylate is 7:2.5: 1.5.

Preparation example three

The stain-resistant material is prepared by the following steps:

step 1, placing acrylic powder in a sodium hydroxide solution with the mass concentration of 8%, heating to 50 ℃, stirring for 15min, filtering, cleaning, adding silica sol, and maintaining at the temperature of 58 ℃ for 18min to obtain solid slurry with the solid content of 66%;

wherein the mass ratio of the solid slurry, the pure acrylic emulsion and the silica dimethyl silylate is 6.3:2.2: 1.2.

Preparation example four

The difference from the third preparation example is that the mass ratio of the solid slurry, the acrylic emulsion and the silica dimethyl silylate is 6:3.2:0.5, and the rest is the same as the third preparation example.

Examples

Example 1

The makeup art paint comprises the following raw materials in parts by weight: 30 parts of elastic acrylic emulsion, 6 parts of pearl powder, 35 parts of water, 19 parts of calcium carbonate, 0.2 part of aminosilane coupling agent, 0.1 part of organic silicon defoaming agent, 0.1 part of oxidized polyethylene wax, 2 parts of conditioner prepared in preparation example 1 and 3 parts of stain-resistant material prepared in preparation example I.

The color cosmetic art paint comprises the following preparation steps: and uniformly mixing the elastic acrylic emulsion, the pearl powder, the calcium carbonate, the stain-resistant material and the conditioner, then adding the aminosilane coupling agent, the organic silicon defoamer, the oxidized polyethylene wax and water, and uniformly stirring to obtain the color makeup art paint.

Example 2

The makeup art paint comprises the following raw materials in parts by weight: 50 parts of elastic acrylic emulsion, 12 parts of pearl powder, 48 parts of water, 10 parts of calcium carbonate, 0.45 part of aminosilane coupling agent, 0.3 part of organic silicon defoamer, 0.25 part of oxidized polyethylene wax, 7 parts of conditioner prepared in preparation example 1 and 9 parts of stain resistant material prepared in preparation example I;

the preparation method of the makeup art paint is the same as that of example 1.

Example 3

The makeup art paint comprises the following raw materials in parts by weight: 45 parts of elastic acrylic emulsion, 10 parts of pearl powder, 40 parts of water, 16 parts of calcium carbonate, 0.3 part of aminosilane coupling agent, 0.2 part of organic silicon defoamer, 0.2 part of oxidized polyethylene wax, 6 parts of conditioner prepared in preparation example 1 and 8 parts of stain resistant material prepared in preparation example I;

Example 4

The difference from example 3 is that the conditioner obtained in preparation example 2 was used, and the rest was the same as example 3.

Example 5

The difference from example 3 is that the conditioner obtained in preparation example 3 was selected and the rest was the same as example 3.

Example 6

The difference from example 3 is that the conditioner obtained in preparation example 4 was used, and the rest was the same as example 3.

Example 7

The difference from example 3 is that the conditioner obtained in preparation example 5 was used, and the rest was the same as example 3.

Example 8

The difference from example 3 is that the conditioner obtained in preparation example 6 was used, and the rest was the same as example 3.

Example 9

The difference from example 7 is that the stain-resistant material prepared in preparation example two was selected and the rest was the same as example 7.

Example 10

The difference from example 7 is that the stain-resistant material obtained in preparation example three was selected and the rest was the same as example 7.

Example 11

The difference from example 7 is that the stain-resistant material obtained in preparation example four was selected and the rest was the same as example 7.

Comparative example

Comparative example 1

The difference from example 10 is that the conditioner is prepared by the following steps: the gelatin, gum arabic, xanthan gum, titanium dioxide and rubber micropowder were mixed uniformly to prepare a conditioner, and the rest was the same as in example 10.

Comparative example 2

The difference from the example 10 is that the conditioner is replaced by titanium dioxide in equal amount, and the rest is the same as the example 10.

Comparative example 3

The difference from example 10 is that the stain resistant material was made by the following steps:

step 1, uniformly mixing acrylic powder and silica sol to obtain solid slurry with the solid content of 66%;

step 2, uniformly mixing the solid slurry, the pure acrylic emulsion and the silica dimethyl silylate to prepare a dirt-resistant material; the rest is the same as in example 10.

Comparative example 4

The difference from example 10 is that the stain-resistant material was replaced with acrylic powder in equal amount, and the rest is the same as example 10.

Comparative example 5

The difference from example 10 is that the same as example 10 was not used except that no aminosilane coupling agent and oxidized polyethylene wax were added.

Performance test

The art paints obtained in examples 1 to 11 and comparative examples 1 to 5 were subjected to elongation at break and stain resistance tests in accordance with JG/T172-2014 elastic building coating, while the appearance of the formed paint films was evaluated, and the results are shown in Table 1.

TABLE 1

	Elongation at break (Standard State)/%	Stain resistance/percent
			Example 1	332	9.9
Example 2	337	9.6
			Example 3	348	9
Example 4	342	9.4
			Example 5	355	8.5
Example 6	361	8
			Example 7	369	7.3
Example 8	358	7.8
			Example 9	363	7.5
Example 10	373	6.7
			Example 11	360	7.9
Comparative example 1	302	13.7
			Comparative example 2	266	15.1
Comparative example 3	311	19.8
			Comparative example 4	288	21.4
Comparative example 5	324	12.2

By combining examples 1-11 and table 1, the art paint prepared by the method has the advantages of high elasticity, good elongation at break, excellent stain resistance and strong stain resistance.

It can be seen by combining example 10 and comparative examples 1-2 with table 1 that, in comparative example 1, the components of the conditioner are directly mixed without corresponding crosslinking, in comparative example 2, titanium dioxide with equal weight is directly used for replacement, the artistic paints prepared in comparative examples 1 and 2 have poor elasticity, obviously reduced elongation at break, and reduced stain resistance to a certain degree. The hydrophilic colloid is cured and crosslinked under the action of the crosslinking agent, the added titanium dioxide and the rubber micro powder are carried and wrapped in the crosslinking reaction to form a microcapsule with good elasticity, and after the microcapsule is compounded with the elastic acrylic emulsion, the elongation at break of the art paint can be effectively improved, so that the art paint has good elasticity, the elongation at break of the art paint is obviously improved, meanwhile, under the action of the aminosilane coupling agent, the compatibility between the conditioner and each raw material component can be improved, the effectiveness of the conditioner is promoted to be exerted, a paint film with uniform elasticity is formed by coating, and the stain resistance of the paint film is optimized to a certain degree.

By combining the example 10 and the comparative examples 3-4 and combining the table 1, it can be seen that the raw material components of the stain-resistant material are directly mixed in the comparative example 3, the acrylic powder with the same weight is adopted for replacing the comparative example 4, the stain resistance of the art paint prepared in the comparative examples 3 and 4 is poor, the elongation at break is reduced to a certain degree, and the elasticity of the art paint is poor; the acrylic powder is modified by the silica sol and then is subjected to spray granulation with the mixture of the pure acrylic emulsion and the dimethyl silylated silica, so that the formed stain-resistant material can form a coating film with stain resistance, dust resistance and good elasticity after the art paint is coated, and the stain resistance and the elasticity of the coating film are improved.

Combining example 10 and comparative example 5 and table 1, it can be seen that, in comparative example 5, the two assistants, namely the aminosilane coupling agent and the oxidized polyethylene wax, are absent, and the elongation at break and the stain resistance of the art paint prepared in comparative example 5 are reduced, because the aminosilane coupling agent and the oxidized polyethylene wax in the system can synergistically improve the compatibility, uniform dispersibility and cohesiveness among the raw material components, can contribute to the exertion of the effects of the raw material components, and can improve the comprehensive performance of a paint film.

The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.

Claims

1. The color makeup art paint is characterized by comprising the following raw materials in parts by weight: 30-50 parts of elastic acrylic emulsion, 6-12 parts of pearl powder, 35-48 parts of water, 10-19 parts of calcium carbonate, 0.2-0.45 part of coupling agent, 0.1-0.3 part of defoaming agent, 0.1-0.25 part of oxidized polyethylene wax, 2-7 parts of conditioner and 3-9 parts of dirt-resistant material; the antifouling material comprises acrylic powder, silica sol, pure acrylic emulsion and silica dimethyl silylate;

2. The make-up art paint according to claim 1, wherein: the hydrophilic colloid is selected from at least two of gelatin, arabic gum, carrageenan and xanthan gum.

3. The make-up art paint according to claim 1, wherein: the cross-linking agent is formaldehyde or glutaraldehyde.

4. The make-up art paint according to any one of claims 1 to 3, characterized in that: the mass ratio of the hydrophilic colloid, the titanium dioxide and the rubber micro powder is (1.7-3) to (4-6.5) to (0.7-1.5).

5. The make-up art paint according to claim 1, wherein: the stain-resistant material is prepared by the following steps:

and 2, mixing the pure acrylic emulsion and the silica dimethyl silylate, uniformly dispersing by using ultrasonic waves to obtain a mixture, and performing spray granulation on the mixture and the solid slurry to obtain the dirt-resistant material.

6. The make-up art paint according to claim 5, wherein: the mass ratio of the solid slurry, the pure acrylic emulsion and the dimethyl silica is (3-7): (1.4-2.5): (0.7-1.5).

7. The make-up art paint according to claim 5 or 6, characterized in that: in the step 1, curing is carried out at a temperature of 50-65 ℃ to obtain solid slurry with a solid content of 60-75%.

8. The make-up art paint according to claim 1, wherein: the raw materials also comprise 0.2 to 0.5 portion of color paste.

9. The method for preparing the makeup art paint according to any one of claims 1 to 8, characterized in that: the preparation method comprises the following preparation steps: according to the formula, the elastic acrylic emulsion, the pearl powder, the calcium carbonate, the dirt-resistant material and the conditioner are uniformly mixed, then the coupling agent, the defoaming agent, the oxidized polyethylene wax and the water are added, and the mixture is uniformly stirred.