CN114957830A - Panel substrate - Google Patents
Panel substrate Download PDFInfo
- Publication number
- CN114957830A CN114957830A CN202210408948.5A CN202210408948A CN114957830A CN 114957830 A CN114957830 A CN 114957830A CN 202210408948 A CN202210408948 A CN 202210408948A CN 114957830 A CN114957830 A CN 114957830A
- Authority
- CN
- China
- Prior art keywords
- numbness
- natural material
- substrate
- calcium carbonate
- board substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 54
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 63
- 239000005445 natural material Substances 0.000 claims abstract description 34
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 31
- 239000012815 thermoplastic material Substances 0.000 claims abstract description 9
- 208000004044 Hypesthesia Diseases 0.000 claims description 24
- 208000034783 hypoesthesia Diseases 0.000 claims description 24
- 231100000862 numbness Toxicity 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000000835 fiber Substances 0.000 claims description 7
- 239000004800 polyvinyl chloride Substances 0.000 claims description 7
- 240000000111 Saccharum officinarum Species 0.000 claims description 6
- 235000007201 Saccharum officinarum Nutrition 0.000 claims description 6
- 239000007799 cork Substances 0.000 claims description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 6
- -1 polyethylene Polymers 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 2
- 239000000463 material Substances 0.000 abstract description 13
- 229920003023 plastic Polymers 0.000 description 16
- 239000004033 plastic Substances 0.000 description 16
- 239000002131 composite material Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
A board substrate mainly comprises at least one thermoplastic material, a natural material and calcium carbonate. Wherein the density of the board can be reduced to 1700g/cm by adding the natural material 3 And the elastic modulus of the material is not reduced by the addition of the natural material, and the flexural modulus of the material is higher than 22.
Description
Technical Field
The invention relates to the technical field of composite floors, in particular to a plate substrate.
Background
Existing composite flooring is typically made primarily from polyvinyl chloride (PVC) as the starting material. Specifically, the composite floor is formed by adding a color film layer and a wear-resistant layer on one side of a substrate made of polyvinyl chloride. The main materials of the board substrate produced by this extrusion process include polyvinyl chloride and calcium carbonate. The main reason for adding calcium carbonate into the substrate is that 1, the size stability of the plastic product is improved, and the calcium carbonate plays a skeleton role in the plastic product due to the addition of the calcium carbonate and has a great effect on the size stability of the plastic product. 2. The hardness and rigidity of the plastic product are improved, namely in plastics, particularly soft polyvinyl chloride, the hardness is gradually increased along with the addition of calcium carbonate, and the elongation is reduced along with the increase of the hardness. Fine particles, large oil absorption value and high hardness increment rate. On the contrary, the calcium carbonate with coarse particles and small oil absorption value has small hardness growth rate of the plastic. In soft polyvinyl chloride, the hardness increase rate of heavy calcium carbonate is the smallest, and precipitated calcium carbonate (light) is the second. 3. The processing property of the plastic is improved, namely the rheological property of the plastic can be changed by adding calcium carbonate. The calcium carbonate powder is added in a large amount, so that the calcium carbonate powder is beneficial to mixing with other components and processing and shaping of plastics. Due to the addition of the calcium carbonate, particularly after the calcium carbonate is subjected to surface treatment, the hardness of the product can be improved, and the surface gloss and the surface smoothness of the product can also be improved. In addition, due to the addition of calcium carbonate, the shrinkage rate, the linear expansion coefficient and the creep property of the plastic product can be reduced, and conditions are created for processing and forming. 4. The heat resistance of plastic products is improved, that is, the heat resistance is improved by adding calcium carbonate to general plastic products, for example, about 40% of calcium carbonate is added to polypropylene to improve the heat resistance by about 200 ℃. When the filling ratio of the calcium carbonate is less than or equal to 20 percent, the heat-resistant temperature is increased by 8-130 ℃. 5. The cost of the plastic product is reduced, namely the prices of the common light calcium carbonate and the heavy calcium carbonate are far lower than the price of the plastic, and the cost of the plastic product is reduced by adding the calcium carbonate.
Table 1 below shows the characteristic analysis of the current board substrate in different ratios of pvc and calcium carbonate.
TABLE 1PVCvsCaCO3
| Ratio of | Density (g/cm3) | MOR | MOE |
| 2.2:1 | 2000 | 18 | 3000 |
| 3:1 | 2100 | 18 | 7000 |
| 3.3:1 | 2200 | 14 | 9000 |
As is clear from table 1, the greater the amount of pvc added, the greater the elastic modulus of the substrate, i.e., the greater the expansion and contraction rate of the substrate. However, by changing the angle, it appears that the flex modulus does not change as the pvc increases. From this, it is inferred that the flexural modulus of the plate substrate changes basically with the increase and decrease of calcium carbonate.
The board substrate can achieve the predetermined effect after being manufactured. However, because the global environmental protection requirements are becoming more and more strict and more important, people are gradually developing various products in a direction of being durable and degradable without losing the original designed efficacy. However, the above-described material combinations for the conventional plate substrates cannot achieve the purpose of degradation and weight reduction at all.
Disclosure of Invention
In view of the above, the present invention provides a board substrate, which is lower in manufacturing cost than the existing similar products, and has a higher flexural modulus than the original composition.
In order to achieve the above objectives, the main technical means of the present invention is to provide a board substrate, which is mainly made of at least one thermoplastic material, at least one calcium carbonate, and at least one natural material, so that the flexural modulus of the board substrate is between 20 and 24.
Further, the thermoplastic material is polyethylene.
Further, the at least one natural material includes numbness.
Further, the at least one natural material includes cork.
Further, the at least one natural material includes sugar cane fiber.
Further, the at least one natural material includes numbness, which results in an elastic modulus of the sheet substrate of 6000.
Further, the at least one natural material includes numbness, such that the sheet substrate has an elastic modulus of 6000 and a flexural modulus of not less than 20.
Further, the at least one natural material includes numbness such that the sheet substrate has an elastic modulus of 6000 and a flexural modulus of 22.
Further, the at least one natural material includes at least one of numbness, cork, and sugar cane fiber, or a mixture thereof.
Further, the at least one natural material includes numbness such that the density of the panel substrate is only 1700g/cm 3 。
Further, the at least one natural material includes numbness, and the numbness is treated with maleic anhydride.
Further, the at least one natural material includes numbness, and the numbness is treated with an alkali, preferably sodium hydroxide.
Compared with the prior art, the natural material is added into the plate substrate, so that the durability of the plate substrate can achieve the expected purpose and can achieve the degradable purpose on the basis of not losing the basic flexural modulus of the plate substrate.
Detailed Description
Specific examples of the present invention will be described in further detail below. It should be understood that the description herein of embodiments of the invention is not intended to limit the scope of the invention.
The invention provides a board substrate which is mainly made of at least one thermoplastic material, at least one calcium carbonate and at least one natural material. The thermoplastic material is plastic which has plasticity at a certain temperature, is solidified after cooling and can repeat the process, and the molecular structure of the thermoplastic material is characterized by linear macromolecular compounds, generally has no active groups and does not generate linear intermolecular crosslinking when being heated. In this embodiment, the thermoplastic material is polyethylene. The calcium carbonate itselfCalcium carbonate is classified into heavy calcium carbonate, light calcium carbonate, colloidal calcium carbonate and crystalline calcium carbonate according to the production method, which is prior art. In the present invention, the calcium carbonate may be one or more of the above-mentioned classes. In order to reduce the overall weight of the plate substrate and enhance the Modulus of flexure (MOR), a naturally degradable material is selected from the material of the plate substrate, and the material can be one or more of numbness, sugarcane fiber and cork, wherein the numbness is at least 5-10 mm long, so that the elasticity and toughness of the plate can be increased after the numbness is added. After the natural materials are added, experiments prove that the elastic modulus of the plate substrate is about 6000, and the flexural Modulus (MOR) of the plate substrate is not less than 20, namely between 20 and 24, and is preferably 22. In addition, in addition to the single natural material described above, a mixture of one or more materials including numbness, cork, and sugar cane fiber may be added to the board substrate. Through experiments, when the natural material is numb, the natural material only enables the density of the board substrate to be 1700g/cm 3 Thus, the weight of the plate substrate can be greatly reduced. Also, in another embodiment, it can be seen that the numbing surface added may be preceded by maleic anhydride. Also, numbing fibers may be treated with alkali, preferably sodium hydroxide. Therefore, the surface energy can be increased for the subsequent processing and jointing of the plate in the future.
After the addition of the above natural materials, the physical characteristics of each item were compared with those of the original materials, and the data are shown in Table 2.
TABLE 2 PVC vs CaCO 3
Compared with the prior art, the natural material is added into the plate substrate, so that the durability of the plate substrate can achieve the expected purpose on the basis of not losing the basic flexural modulus of the plate substrate, and meanwhile, the plate substrate can achieve the degradable purpose.
As can be seen from the above description, the board substrate provided by the present invention, after being added with natural materials, has a flexural Modulus (MOR) that is not comparable to that of the existing product, and also has an elastic Modulus (MOE) that is not inferior to that of the existing product; therefore, the natural material is added, the characteristics of the natural material are not lost, and the natural material is more outstanding than the existing product in some aspects; furthermore, due to the addition of natural materials, the overall density is only 1700g/cm3 after the production is finished, which is far lower than that of the existing products. Weight reduction means that more finished products can be worn in transit with conventional shipping wear, thereby reducing the cost of more transportation.
The above description is only a preferred embodiment of the present invention and should not be taken as limiting the scope of the present invention, and any modifications, equivalents or 145-improvements within the spirit of the present invention are intended to be covered by the claims of the present invention.
Claims (12)
1. A panel substrate, comprising: the plate substrate is mainly made of at least one thermoplastic material and at least one natural material, so that the flexural Modulus (MOR) of the plate substrate is 20-24.
2. The board substrate according to claim 1, wherein: the thermoplastic material is polyethylene, poly terephthalic acid, polypropylene or polyvinyl chloride.
3. The board substrate according to claim 1, wherein: the at least one natural material includes numbness, and at least one calcium carbonate.
4. The board substrate according to claim 1, wherein: the at least one natural material comprises cork.
5. The board substrate according to claim 1, wherein: the at least one natural material comprises sugar cane fiber.
6. The sheet substrate of claim 1, wherein: the at least one natural material includes numbness such that the sheet substrate has an elastic modulus of 6000.
7. The board substrate according to claim 3, wherein: the at least one natural material comprises numbness, so that the elastic modulus of the plate substrate is 6000, and the flexural modulus is not less than 20, wherein the length of the numbness is at least 5-10 mm.
8. The sheet substrate of claim 1, wherein: the at least one natural material is at least one of numb, cork and sugar cane fiber or a mixture thereof.
9. The board substrate according to claim 3, wherein: the at least one natural material includes numbness such that the sheet substrate has an elastic modulus of 6000 and a flexural modulus of 22.
10. The board substrate according to claim 3, wherein: the at least one natural material includes numbness such that the density of the sheet substrate is only 1700g/cm 3 。
11. The board substrate according to claim 3, wherein: the at least one natural material comprises numbness, and the numbness is treated with maleic anhydride.
12. The board substrate according to claim 3, wherein: the at least one natural material includes numbness, and the numbness is treated with an alkali, preferably sodium hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210408948.5A CN114957830A (en) | 2022-04-19 | 2022-04-19 | Panel substrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210408948.5A CN114957830A (en) | 2022-04-19 | 2022-04-19 | Panel substrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114957830A true CN114957830A (en) | 2022-08-30 |
Family
ID=82976889
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210408948.5A Pending CN114957830A (en) | 2022-04-19 | 2022-04-19 | Panel substrate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114957830A (en) |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4851458A (en) * | 1986-09-11 | 1989-07-25 | Rehau Ag & Co. | Use of cellulose fibers for structurally modifying polyvinyl chloride articles |
| CN1063694A (en) * | 1992-03-03 | 1992-08-19 | 贾玉良 | Recycled plastic and preparation method thereof |
| EP1070782A1 (en) * | 1999-07-20 | 2001-01-24 | Wwj, L.L.C. | Lignocellulose fiber filler for thermoplastic composite compositions |
| US20060270762A1 (en) * | 2005-03-17 | 2006-11-30 | Luzenac America, Inc. | Cellulosic inorganic-filled plastic composite |
| US20080269377A1 (en) * | 2007-04-26 | 2008-10-30 | Board Of Trustees Of Michigan State University | Hybrid PVC/wood-reinforcement nanocomposites and method of manufacture |
| US20090012213A1 (en) * | 2006-02-15 | 2009-01-08 | Elkem As | Composite Plastics Material |
| CN101708617A (en) * | 2009-11-25 | 2010-05-19 | 宜兴森诺塑胶复合制品有限公司 | Anti-ageing wood-plastic composite board and preparation method thereof |
| WO2012128790A1 (en) * | 2010-10-29 | 2012-09-27 | Interfacial Solutions Ip, Llc | High strength polymeric composites |
| CN106479046A (en) * | 2016-09-28 | 2017-03-08 | 广东碧盛环球环保材料有限公司 | A kind of PPM environment-friendly materials and preparation method thereof |
| CN107662268A (en) * | 2016-12-31 | 2018-02-06 | 北京林业大学 | A kind of flaxen fiber enhancing orientation wood-plastic composite particleboard and its manufacture method |
| CN107778634A (en) * | 2017-11-14 | 2018-03-09 | 南京维思创新材料科技有限公司 | A kind of fiber reinforcement biological material and preparation method thereof |
| WO2019038260A1 (en) * | 2017-08-21 | 2019-02-28 | Swisspearl Group Ag | Drop impact-resistant and adaptive flooring |
| CN110894329A (en) * | 2019-12-09 | 2020-03-20 | 十倍好智能家居(广州)有限公司 | Sheet material, preparation method and use method |
-
2022
- 2022-04-19 CN CN202210408948.5A patent/CN114957830A/en active Pending
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4851458A (en) * | 1986-09-11 | 1989-07-25 | Rehau Ag & Co. | Use of cellulose fibers for structurally modifying polyvinyl chloride articles |
| CN1063694A (en) * | 1992-03-03 | 1992-08-19 | 贾玉良 | Recycled plastic and preparation method thereof |
| EP1070782A1 (en) * | 1999-07-20 | 2001-01-24 | Wwj, L.L.C. | Lignocellulose fiber filler for thermoplastic composite compositions |
| US20060270762A1 (en) * | 2005-03-17 | 2006-11-30 | Luzenac America, Inc. | Cellulosic inorganic-filled plastic composite |
| US20090012213A1 (en) * | 2006-02-15 | 2009-01-08 | Elkem As | Composite Plastics Material |
| US20080269377A1 (en) * | 2007-04-26 | 2008-10-30 | Board Of Trustees Of Michigan State University | Hybrid PVC/wood-reinforcement nanocomposites and method of manufacture |
| CN101708617A (en) * | 2009-11-25 | 2010-05-19 | 宜兴森诺塑胶复合制品有限公司 | Anti-ageing wood-plastic composite board and preparation method thereof |
| WO2012128790A1 (en) * | 2010-10-29 | 2012-09-27 | Interfacial Solutions Ip, Llc | High strength polymeric composites |
| CN106479046A (en) * | 2016-09-28 | 2017-03-08 | 广东碧盛环球环保材料有限公司 | A kind of PPM environment-friendly materials and preparation method thereof |
| CN107662268A (en) * | 2016-12-31 | 2018-02-06 | 北京林业大学 | A kind of flaxen fiber enhancing orientation wood-plastic composite particleboard and its manufacture method |
| WO2019038260A1 (en) * | 2017-08-21 | 2019-02-28 | Swisspearl Group Ag | Drop impact-resistant and adaptive flooring |
| CN107778634A (en) * | 2017-11-14 | 2018-03-09 | 南京维思创新材料科技有限公司 | A kind of fiber reinforcement biological material and preparation method thereof |
| CN110894329A (en) * | 2019-12-09 | 2020-03-20 | 十倍好智能家居(广州)有限公司 | Sheet material, preparation method and use method |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20220830 |