CN114940638A - Ionic calcium liquid fertilizer and preparation method thereof - Google Patents
Ionic calcium liquid fertilizer and preparation method thereof Download PDFInfo
- Publication number
- CN114940638A CN114940638A CN202210797644.2A CN202210797644A CN114940638A CN 114940638 A CN114940638 A CN 114940638A CN 202210797644 A CN202210797644 A CN 202210797644A CN 114940638 A CN114940638 A CN 114940638A
- Authority
- CN
- China
- Prior art keywords
- liquid fertilizer
- calcium
- chelating agent
- ionic calcium
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011575 calcium Substances 0.000 title claims abstract description 79
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 75
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 75
- 239000003337 fertilizer Substances 0.000 title claims abstract description 55
- 239000007788 liquid Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000002738 chelating agent Substances 0.000 claims abstract description 47
- 239000000843 powder Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000004094 surface-active agent Substances 0.000 claims abstract description 24
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 19
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004202 carbamide Substances 0.000 claims abstract description 19
- 239000004021 humic acid Substances 0.000 claims abstract description 19
- 239000002131 composite material Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 12
- 235000001014 amino acid Nutrition 0.000 claims description 12
- 150000001413 amino acids Chemical class 0.000 claims description 12
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 238000005303 weighing Methods 0.000 claims description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 6
- 239000004471 Glycine Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 5
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 5
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 4
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 4
- 235000003704 aspartic acid Nutrition 0.000 claims description 4
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims description 4
- 235000013922 glutamic acid Nutrition 0.000 claims description 4
- 239000004220 glutamic acid Substances 0.000 claims description 4
- -1 sodium alkyl aryl sulfonate Chemical class 0.000 claims description 4
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 241000196324 Embryophyta Species 0.000 abstract description 27
- 235000013399 edible fruits Nutrition 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 8
- 230000012010 growth Effects 0.000 abstract description 8
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- 235000015097 nutrients Nutrition 0.000 abstract description 5
- 230000009471 action Effects 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- 239000000126 substance Substances 0.000 description 10
- 241000220223 Fragaria Species 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229960000583 acetic acid Drugs 0.000 description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 description 6
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 6
- 239000012362 glacial acetic acid Substances 0.000 description 6
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 5
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 5
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 5
- 229920002101 Chitin Polymers 0.000 description 5
- 235000016623 Fragaria vesca Nutrition 0.000 description 5
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 5
- 229910001424 calcium ion Inorganic materials 0.000 description 5
- 230000004720 fertilization Effects 0.000 description 5
- 150000004676 glycans Chemical class 0.000 description 5
- 229920001282 polysaccharide Polymers 0.000 description 5
- 239000005017 polysaccharide Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 235000021012 strawberries Nutrition 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000002028 Biomass Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 210000000170 cell membrane Anatomy 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000004060 metabolic process Effects 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 238000003321 atomic absorption spectrophotometry Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 210000002421 cell wall Anatomy 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- TVBSSDNEJWXWFP-UHFFFAOYSA-N nitric acid perchloric acid Chemical compound O[N+]([O-])=O.OCl(=O)(=O)=O TVBSSDNEJWXWFP-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000005648 plant growth regulator Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 206010006956 Calcium deficiency Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- RJGDLRCDCYRQOQ-UHFFFAOYSA-N anthrone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3CC2=C1 RJGDLRCDCYRQOQ-UHFFFAOYSA-N 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000020774 essential nutrients Nutrition 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 230000003859 lipid peroxidation Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000002881 soil fertilizer Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 230000005068 transpiration Effects 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/40—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting fertiliser dosage or release rate; for affecting solubility
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/50—Surfactants; Emulsifiers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses an ionic calcium liquid fertilizer and a preparation method thereof, belonging to the technical field of fertilizer preparation. The ionic calcium liquid fertilizer comprises the following raw materials in percentage by weight: 15-20 wt% of shell powder, 22-35 wt% of composite chelating agent, 4-6 wt% of urea, 5-10 wt% of surfactant, 8-12 wt% of humic acid and the balance of water. The source of calcium is shell powder, which is easier to be absorbed by plant leaves, the chelated calcium has higher solubility in plants by adopting the compound chelating agent, obvious movement advantage is obtained, the calcium can be slowly released, and the action aging of the liquid fertilizer is increased. The preparation method is simple, the preparation conditions are mild, the prepared ionic calcium liquid fertilizer can promote the absorption of plants on the calcium and other growth nutrients, has the effects of protecting flowers and fruits, increasing the yield and improving the quality, and is suitable for large-scale popularization and application.
Description
Technical Field
The invention relates to an ionic calcium liquid fertilizer and a preparation method thereof, belonging to the technical field of fertilizer preparation.
Background
Calcium is one of essential nutrient elements for promoting plant growth, can effectively promote the growth, development and in-vivo metabolism of plants, can also enhance the stability of plant cell membranes, keeps the integrity of cells and plays an important role in the growth process of the plants. However, calcium is transported along with plant transpiration, and in the process, the calcium cannot reach terminal buds or fruit parts of plants due to long-distance transportation, so that the plants are poor in growth and development, and the yield and the quality are reduced.
Timely supplement of calcium fertilizer in the planting process is a main method for solving the problem of calcium deficiency. At present, two common modes of supplementing calcium fertilizer include foliar fertilization and soil fertilization, and the foliar fertilization is not limited by soil conditions, so that the process that plants absorb nutrient substances from roots and then transport the nutrient substances is reduced, and the method is greatly popularized. The calcium source in the foliar fertilization is calcium chloride or calcium nitrate, the calcium is difficult to be absorbed and utilized by plants when the foliar fertilization is directly applied, and the chelating agent can improve the effectiveness of the calcium fertilizer and promote the absorption of calcium by plant leaves.
The commonly used chelating agents comprise phosphates, hydroxycarboxylic acids, amides and small molecular substances, but the chelating ability of the phosphates and calcium is weak, phosphate precipitation is easy to generate, the amides are not easy to degrade, the water solubility of the hydroxycarboxylic acids is poor, a sprayer is easy to block, and the small molecular substances can be directly absorbed and utilized, but the combination with the calcium is unstable, the absorption process is too fast, and the continuous action effect cannot be achieved. Therefore, it is necessary to find an ionic calcium liquid fertilizer which can quickly and durably supplement calcium and can promote the growth and development of plants.
Disclosure of Invention
In order to solve the technical problems, the invention provides the ionic calcium liquid fertilizer and the preparation method thereof, the preparation method is simple, the preparation conditions are mild, and the prepared ionic calcium liquid fertilizer can promote the absorption of plants on calcium and other growth nutrients and has the effects of protecting flowers and fruits, increasing the yield and improving the quality.
In order to achieve the purpose, the invention provides the following scheme:
the invention provides an ionic calcium liquid fertilizer which comprises the following raw materials in percentage by weight: 15-20 wt% of shell powder, 22-35 wt% of composite chelating agent, 4-6 wt% of urea, 5-10 wt% of surfactant, 8-12 wt% of humic acid and the balance of water.
Further, by weight percentage, 16 wt% of shell powder, 30 wt% of a compound chelating agent, 4 wt% of urea, 5 wt% of a surfactant, 10 wt% of humic acid and the balance of water.
Furthermore, the content of calcium element in the shell powder is more than or equal to 95%, and the mesh number is 500-800 meshes.
Further, the preparation method of the shell powder specifically comprises the following steps: washing shells with clear water for 5 times, soaking in 0.5mol/L NaOH solution for 15h, washing with clear water to neutrality, drying at 120 deg.C for 80min, and pulverizing to 800-1200 mesh.
Further, the shell powder mainly contains calcium carbonate (about 95 wt.%), and also contains part of chitin, small amount of amino acids and polysaccharide substances. After the shell powder is dissolved in water, calcium ions in the calcium carbonate can be chelated with a chelating agent to form chelated calcium, and the chitin is matched with the chelated calcium to effectively regulate the physiological metabolism of fruits, improve the quality of the fruits and reduce the peroxidation degree of cell membrane lipid, so that the integrity of cell walls is improved, and the resistance of the fruits is increased. Meanwhile, a small amount of amino acid and polysaccharide substances as small molecular substances can chelate a small part of calcium element, and the absorption of plant leaves to calcium is promoted.
Further, the compound chelating agent is composed of an amino acid chelating agent and an organic chelating agent in a mass ratio of (1-2): 1.
Further, the amino acid chelating agent comprises one or more of glycine, aspartic acid and glutamic acid, and the organic chelating agent comprises one or more of diethyltriaminepentaacetic acid (DTPA), ethylenediaminetetraacetic acid (EDTA) or ethylenediaminediphophylacetic acid (EDDHA).
Further, the surfactant comprises one or more of sodium dodecylbenzene sulfonate, sodium alkyl aryl sulfonate and sodium hydroxy alkyl sulfonate. The surfactant can improve the surface activity of the sprayed liquid fertilizer, and is favorable for wetting, adhering and permeating the foliar fertilizer on the leaf surfaces of plants.
The invention also provides a preparation method of the ionic calcium liquid fertilizer, which comprises the following steps:
1) weighing the raw materials according to the weight percentage, dissolving the composite chelating agent in water, adding shell powder, stirring, and reacting at constant temperature;
2) adding urea, a surfactant and humic acid into the solution obtained in the step 1), and continuously stirring;
3) and then adjusting the pH value to be acidic to obtain the ionic calcium liquid fertilizer.
Further, in the step 1), the temperature of the constant-temperature reaction is 55-65 ℃ and the time is 50-100 min. After the constant temperature reaction, the solution turns clear, which shows that calcium ions in the shell powder are all chelated.
Further, in the step 3), the pH is adjusted to be 5.0-6.0, so that when the pH is high and the pH is low, H is added + Will react with Ca 2+ Compete for electron donating groups resulting in Ca 2+ The obtained electrons are reduced, and the generation of chelated calcium is not facilitated; when the pH is too high, OH in the solution - The chance of binding calcium hydroxide increases and the formation or stabilization of chelated calcium is also not favored.
Further, in step 3), the pH is adjusted with glacial acetic acid and ammonia water.
The invention discloses the following technical effects:
the source of calcium in the ionic calcium liquid fertilizer is the shell powder, and the ionic calcium liquid fertilizer is easier to be absorbed by plant leaves compared with calcium sources such as calcium chloride and calcium nitrate, and partial chitin, amino acid and polysaccharide contained in the ionic calcium liquid fertilizer can also promote the plant to absorb calcium. Meanwhile, the compound chelating agent is adopted, on one hand, the amino acid chelating agent can enable the chelated calcium to have higher solubility in plants, obtain obvious movement advantages, overcome the defect that calcium ions are difficult to transport in phloem, and have high speed of penetrating through the cuticle of the leaves when being sprayed on the leaves and high utilization rate, and on the other hand, the organic chelating agent can slowly release calcium and increase the action timeliness of the liquid fertilizer. In addition, the liquid fertilizer disclosed by the invention is further added with urea, a surfactant and humic acid, so that the growth and development of plants are further promoted from the aspects of nutrition conveying and nutrition balance.
The ionic calcium liquid fertilizer disclosed by the invention is simple in preparation method and mild in preparation conditions, can promote plants to absorb calcium and other growth nutrients, has the effects of protecting flowers and fruits, increasing yield and improving quality, and is suitable for large-scale popularization and application.
Detailed Description
Reference will now be made in detail to various exemplary embodiments of the invention, the detailed description should not be construed as limiting the invention but rather as a more detailed description of certain aspects, features and embodiments of the invention.
It is to be understood that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. Further, for numerical ranges in this disclosure, it is understood that each intervening value, between the upper and lower limit of that range, is also specifically disclosed. Every intervening value, to the extent any stated value or intervening value in a stated range, and any other stated or intervening value in a stated range, is encompassed within the invention. The upper and lower limits of these smaller ranges may independently be included or excluded in the range.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Although only preferred methods and materials are described herein, any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present invention. All documents mentioned in this specification are incorporated by reference herein for the purpose of disclosing and describing the methods and/or materials associated with the documents. In case of conflict with any incorporated document, the present specification will control.
It will be apparent to those skilled in the art that various modifications and variations can be made in the specific embodiments of the present disclosure without departing from the scope or spirit of the disclosure. Other embodiments will be apparent to those skilled in the art from consideration of the specification. The description and examples are intended to be illustrative only.
As used herein, the terms "comprising," "including," "having," "containing," and the like are open-ended terms that mean including, but not limited to.
The invention provides an ionic calcium liquid fertilizer which comprises the following raw materials in percentage by weight: 15-20 wt% of shell powder, 22-35 wt% of composite chelating agent, 4-6 wt% of urea, 5-10 wt% of surfactant, 8-12 wt% of humic acid and the balance of water.
Further, by weight percentage, 16 wt% of shell powder, 30 wt% of compound chelating agent, 4 wt% of urea, 5 wt% of surfactant, 10 wt% of humic acid and the balance of water.
Furthermore, the content of calcium element in the shell powder is more than or equal to 95%, and the mesh number is 500-800 meshes.
Further, the preparation method of the shell powder specifically comprises the following steps: washing shells with clear water for 5 times, soaking in 0.5mol/L NaOH solution for 15h, washing with clear water to neutrality, drying at 120 deg.C for 80min, and pulverizing to 800-1200 mesh.
Furthermore, the shell powder contains 95 percent of calcium carbonate as a main component, and also contains part of chitin, a small amount of amino acid and polysaccharide substances. After the shell powder is dissolved in water, calcium ions in calcium carbonate can be chelated with a chelating agent to form chelated calcium, and the chitin is matched with the chelated calcium to effectively regulate fruit physiological metabolism, reduce fruit quality and reduce the degree of cell membrane lipid peroxidation, so that the integrity of cell walls is improved, and the resistance of fruits is increased. Meanwhile, a small amount of amino acid and polysaccharide substances as small molecular substances can chelate a small part of calcium element, and the absorption of plant leaves to calcium is promoted.
Further, the compound chelating agent is composed of an amino acid chelating agent and an organic chelating agent in a mass ratio of (1-2): 1.
Further, the amino acid chelating agent comprises one or more of glycine, aspartic acid and glutamic acid, and the organic chelating agent comprises one or more of diethyltriaminepentaacetic acid (DTPA), ethylenediaminetetraacetic acid (EDTA) or ethylenediaminediphophylacetic acid (EDDHA).
Further, the surfactant comprises one or more of sodium dodecylbenzene sulfonate, sodium alkyl aryl sulfonate and sodium hydroxy alkyl sulfonate. The surfactant can improve the surface activity of the sprayed liquid fertilizer, and is favorable for wetting, adhering and permeating the foliar fertilizer on the leaf surfaces of plants.
The invention also provides a preparation method of the ionic calcium liquid fertilizer, which comprises the following steps:
1) weighing the raw materials according to the weight percentage, dissolving the composite chelating agent in water, adding shell powder, stirring, and reacting at constant temperature;
2) adding urea, a plant growth regulator, a surfactant and humic acid into the solution obtained in the step 1), and continuously stirring;
3) and then adjusting the pH value to be acidic to obtain the ionic calcium liquid fertilizer.
Further, in the step 1), the temperature of the constant-temperature reaction is 55-65 ℃ and the time is 50-100 min. After the constant temperature reaction, the solution turns clear, which shows that the calcium ions in the shell powder are all chelated.
Further, in the step 3), the pH is adjusted to be 5.0-6.0, so that when the pH is higher and lower, H is added + Will react with Ca 2+ Compete for electron donating groups resulting in Ca 2+ The obtained electrons are reduced, and the generation of chelated calcium is not facilitated; when the pH is too high, OH in the solution - The chance of binding calcium hydroxide increases and the formation or stabilization of chelated calcium is also not favored.
Further, in step 3), the pH was adjusted with glacial acetic acid and ammonia water.
The raw materials used in the examples of the present invention are commercially available.
The technical solution of the present invention is further illustrated by the following examples.
Example 1
1) Weighing the following raw materials in percentage by weight: 16 wt% of shell powder, 30 wt% of a composite chelating agent (the mass ratio of glycine to DTPA is 1:1), 4 wt% of urea, 5 wt% of a surfactant (sodium dodecyl benzene sulfonate), 10 wt% of humic acid and the balance of water;
2) dissolving the composite chelating agent in water, adding shell powder, stirring for 5min at 300r/min, and reacting at 60 ℃ for 60 min;
3) adding urea, a surfactant and humic acid into the solution obtained in the step 1), and continuously stirring at 300r/min for 10 min;
4) and then adjusting the pH value to 5.4 by using glacial acetic acid and ammonia water to obtain the ionic calcium liquid fertilizer.
Example 2
1) Weighing the following raw materials in percentage by weight: 18 wt% of shell powder, 26 wt% of compound chelating agent (the mass ratio of aspartic acid to EDDHA is 2:1), 5 wt% of urea, 5 wt% of surfactant (sodium alkyl aryl sulfonate), 9 wt% of humic acid and the balance of water;
2) dissolving the composite chelating agent in water, adding shell powder, stirring for 5min at 300r/min, and reacting at 65 ℃ for 50 min;
3) adding urea, a surfactant and humic acid into the solution obtained in the step 1), and continuously stirring at 300r/min for 10 min;
4) and then regulating the pH value to 6.0 by using glacial acetic acid and ammonia water to obtain the ionic calcium liquid fertilizer.
Example 3
1) Weighing the following raw materials in percentage by weight: 20 wt% of shell powder, 22 wt% of compound chelating agent (the mass ratio of glutamic acid to EDTA is 1:1), 4 wt% of urea, 5 wt% of surfactant (sodium hydroxyalkyl sulfonate), 12 wt% of humic acid and the balance of water;
2) dissolving the composite chelating agent in water, adding shell powder, stirring for 5min at 300r/min, and reacting at the constant temperature of 55 ℃ for 100 min;
3) adding urea, a surfactant and humic acid into the solution obtained in the step 1), and continuously stirring at 300r/min for 10 min;
4) and then adjusting the pH value to 5.8 by using glacial acetic acid and ammonia water to obtain the ionic calcium liquid fertilizer.
Example 4
1) Weighing the following raw materials in percentage by weight: 15 wt% of shell powder, 35 wt% of compound chelating agent (the mass ratio of glycine to EDDHA is 2:1), 6 wt% of urea, 10 wt% of surfactant (sodium dodecyl benzene sulfonate), 8 wt% of humic acid and the balance of water;
2) dissolving the composite chelating agent in water, adding shell powder, stirring for 5min at 300r/min, and reacting at 65 ℃ for 80 min;
3) adding urea, a plant growth regulator, a surfactant and humic acid into the solution obtained in the step 1), and continuously stirring at 300r/min for 10 min;
4) and then adjusting the pH value to 5.5 by using glacial acetic acid and ammonia water to obtain the ionic calcium liquid fertilizer.
Comparative example 1
The only difference from example 1 is that the complex chelator is replaced equally by the single chelator glycine.
Comparative example 2
The only difference from example 1 is that the complex chelator is replaced equally with the single chelator DTPA.
Comparative example 3
The only difference from example 1 is that the isothermal reaction time was 40 ℃ and 110 min.
Comparative example 4
The only difference from example 1 is that the pH is adjusted to 7.4.
Comparative example 5
The only difference from example 1 is that the shell powder is replaced by calcium nitrate in equal amounts.
Fertilizer efficiency test
Yield increasing test for Chinese cabbage
From 10 months to 1 month of 2021 in 2020, the method is carried out at the sun and at room temperature in a plant soil and fertilizer research institute of agricultural academy of sciences in Hubei province, the planted Chinese cabbages are named as Qingza III, potted plants are adopted, each pot is filled with 5kg of soil (pH is 7.62, nitrogen content is 0.25mg/g, potassium content is 78mg/g, phosphorus content is 3.85mg/g, and calcium content is 20mg/g), seedlings are fixed in the three-leaf period of the seedlings, 3 seedlings are planted in each pot, 45 pots are planted in total, the fertilizers prepared in examples 1-4 and comparative examples 1-5 are diluted with water, a blank control group is set to be equal amount of clear water, the spraying is carried out in the four-leaf period of the seedlings, each treatment is repeated for 5 times, and the specific treatment is shown in Table 1.
TABLE 1 modes of treatment
Harvesting at No. 15/1/2021, removing roots of each Chinese cabbage after harvesting, weighing to obtain biomass (fresh weight), and determining total calcium content according to concentrated nitric acid-perchloric acid digestion-atomic absorption spectrophotometry in GBT 23375-.
TABLE 2 measurement results
| Group of | Biomass (kg/basin) | Calcium content (mg/basin) |
| Example 1 | 10.58 | 202.3 |
| Example 2 | 9.89 | 189.4 |
| Example 3 | 10.31 | 198.9 |
| Example 4 | 9.74 | 194.6 |
| Comparative example 1 | 5.36 | 89.3 |
| Comparative example 2 | 4.85 | 74.2 |
| Comparative example 3 | 4.93 | 65.6 |
| Comparative example 4 | 4.52 | 68.4 |
| Control group | 2.88 | 4.6 |
As can be seen from the data in Table 2, the fertilizer prepared by the embodiment of the invention can improve the calcium absorption of the Chinese cabbage by foliage spraying, so that the yield of the Chinese cabbage is increased, and the comparative example shows that the ionic calcium liquid fertilizer prepared by the embodiment of the invention can achieve the purpose of increasing the yield by changing the types of the chelating agents, the chelation reaction time and the pH condition of the fertilizer, although the calcium content and the biomass are improved compared with those of a control group, the ionic calcium liquid fertilizer is far lower than that of the embodiment of the invention.
Second, strawberry yield increase test
From 8 months to 2021 months in 2020, the method is carried out at a sunlight room temperature in a plant soil fertilizer research institute of agricultural academy of sciences in Hubei province, the planted strawberries are No. 1 star, potted plants are adopted, 5kg of soil (pH 7.62, nitrogen content 0.25mg/g, potassium content 78mg/g, phosphorus content 3.85mg/g and calcium content 20mg/g) is filled in each pot, 4 strawberries are planted in each pot, 45 pots are planted in total, the fertilizers prepared in examples 1 to 4 and comparative examples 1 to 5 are diluted with water, a blank control group is set to be equal amount of clear water, the spraying is carried out at the early flowering phase of the strawberries, each treatment is repeated for 5 times, and the specific treatment is shown in Table 3.
TABLE 3 modes of treatment
The strawberry is harvested in No. 20 at No. 4/2021, the strawberry in each pot is collected, weighed after pedicle removal, averaged, and calculated to obtain the yield (g/pot) of the strawberry, the content of soluble sugar is determined according to an anthrone colorimetric method, and the content of calcium in the strawberry fruit is determined according to a concentrated nitric acid-perchloric acid digestion-atomic absorption spectrophotometry method in GBT 23375-one 2009, and the results are shown in Table 4.
TABLE 4 measurement results
As can be seen from the data in Table 4, the ionic calcium liquid fertilizer prepared in the embodiment of the invention can effectively improve the yield and sweetness of strawberries, and the change of the type of the chelating agent, the chelating reaction time and the pH value of the fertilizer in the preparation process can affect the action and efficacy of the fertilizer, so that the ionic calcium liquid fertilizer prepared in the invention has the effects of flower and fruit protection, yield increase and sweetness improvement.
The above-described embodiments are only intended to illustrate the preferred embodiments of the present invention, and not to limit the scope of the present invention, and various modifications and improvements made to the technical solution of the present invention by those skilled in the art without departing from the spirit of the present invention should fall within the protection scope defined by the claims of the present invention.
Claims (9)
1. The ionic calcium liquid fertilizer is characterized by comprising the following raw materials in percentage by weight: 15-20 wt% of shell powder, 22-35 wt% of a composite chelating agent, 4-6 wt% of urea, 5-10 wt% of a surfactant, 8-12 wt% of humic acid and the balance of water.
2. The ionic calcium liquid fertilizer is characterized by comprising 16 wt% of shell powder, 30 wt% of compound chelating agent, 4 wt% of urea, 5 wt% of surfactant and 10 wt% of humic acid, and the balance being water.
3. The ionic calcium liquid fertilizer as claimed in claim 1, wherein the content of calcium element in the shell powder is not less than 95%, and the mesh number is 800-1200 meshes.
4. The ionic calcium liquid fertilizer is characterized in that the compound chelating agent consists of an amino acid chelating agent and an organic chelating agent in a mass ratio of (1-2): 1.
5. The ionic calcium liquid fertilizer of claim 4, wherein said amino acid based chelating agent comprises one or more of glycine, aspartic acid and glutamic acid and said organic chelating agent comprises one or more of diethyltriaminepentaacetic acid, ethylenediaminetetraacetic acid or ethylenediaminediphthalacetic acid.
6. The ionic calcium liquid fertilizer according to claim 1, wherein the surfactant comprises one or more of sodium dodecylbenzene sulfonate, sodium alkyl aryl sulfonate and sodium hydroxy alkyl sulfonate.
7. A method for preparing the ionic calcium liquid fertilizer as claimed in any one of claims 1 to 6, which is characterized by comprising the following steps:
1) weighing the raw materials according to the weight percentage, dissolving the composite chelating agent in water, adding shell powder, stirring, and reacting at constant temperature;
2) adding urea, a surfactant and humic acid into the solution obtained in the step 1), and continuously stirring;
3) and then adjusting the pH value to be acidic to obtain the ionic calcium liquid fertilizer.
8. The preparation method according to claim 7, wherein in the step 1), the isothermal reaction is carried out at a temperature of 55-65 ℃ for 50-100 min.
9. The method according to claim 7, wherein the pH is adjusted to 5.0 to 6.0 in the step 3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210797644.2A CN114940638A (en) | 2022-07-08 | 2022-07-08 | Ionic calcium liquid fertilizer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210797644.2A CN114940638A (en) | 2022-07-08 | 2022-07-08 | Ionic calcium liquid fertilizer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114940638A true CN114940638A (en) | 2022-08-26 |
Family
ID=82910719
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210797644.2A Pending CN114940638A (en) | 2022-07-08 | 2022-07-08 | Ionic calcium liquid fertilizer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114940638A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102219610A (en) * | 2011-05-19 | 2011-10-19 | 湖南省中科农业有限公司 | Amino acid compound leaf fertilizer and preparation method thereof |
| CN105084944A (en) * | 2015-08-21 | 2015-11-25 | 南宁汉和生物科技有限公司 | Chelated calcium fertilizer prepared by utilizing shells as well as preparation method and application thereof |
| CN106431692A (en) * | 2016-10-18 | 2017-02-22 | 徐宜强 | Amino acid calcium water-soluble fertilizer and preparation method thereof |
-
2022
- 2022-07-08 CN CN202210797644.2A patent/CN114940638A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102219610A (en) * | 2011-05-19 | 2011-10-19 | 湖南省中科农业有限公司 | Amino acid compound leaf fertilizer and preparation method thereof |
| CN105084944A (en) * | 2015-08-21 | 2015-11-25 | 南宁汉和生物科技有限公司 | Chelated calcium fertilizer prepared by utilizing shells as well as preparation method and application thereof |
| CN106431692A (en) * | 2016-10-18 | 2017-02-22 | 徐宜强 | Amino acid calcium water-soluble fertilizer and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 任帅等: "海湾贝壳制备甘氨酸及其他氨基酸螯合钙的研究进展" * |
| 叶剑等: "海洋生物钙的开发利用研究进展" * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101792348B (en) | Humic acid liquid fertilizer and preparation method thereof | |
| CN104609972A (en) | Dual-chelated foliar special fertilizer | |
| CN108849984B (en) | Wheat drought-tolerance stress-tolerance compound regulator and application thereof | |
| KR101732080B1 (en) | A Manufacturing Method Of Composition Of Fluid Fertilizer | |
| CN111592413A (en) | Efficient fruit and vegetable blended compound fertilizer and preparation method thereof | |
| CN102260117B (en) | High-efficiency compound foliar fertilizer | |
| CN106883056A (en) | One kind is enlarged afforested area anti-early ageing liquid fertilizer | |
| CN110590464A (en) | Four-in-one total-nutrient composite microbial fertilizer | |
| CN108503469B (en) | Organic chelated selenium fertilizer synergist and preparation method and application thereof | |
| CN101223848B (en) | Use of poly-gamma-glutamate in burley tobacco field production | |
| CN108689780A (en) | The method that the sustained release organic composite base manure for being suitble to salt-soda soil to use is produced using ardealite | |
| CN106673922A (en) | Special water-soluble fertilizer for tomatoes and application method of special water-soluble fertilizer | |
| CN114940638A (en) | Ionic calcium liquid fertilizer and preparation method thereof | |
| WO1998027028A1 (en) | Plant treatment compositions and process | |
| CN107500851B (en) | Vegetable leaf surface composite regulating agent for reducing cadmium and improving zinc biological availability | |
| CN112759469A (en) | Special macroelement water-soluble fertilizer for clear liquid type vegetables and preparation method thereof | |
| CN113603530A (en) | Multifunctional organic water liquid fertilizer | |
| CN113277904A (en) | Pricklyash peel leaf fertilizer and preparation method and use method thereof | |
| CN102372514A (en) | Compound fertilizer for greenhouse crops and preparation method thereof | |
| CN105237277B (en) | A kind of multi-functional boron magnesium zinc humic acid chelating Eco-fertilizer | |
| CN115322027B (en) | Special water-soluble compound fertilizer for kiwi fruits and fertilizing method thereof | |
| KR100512986B1 (en) | Complex fertilizer of trace elements comprising humic acid and illite | |
| US5563116A (en) | Method and composition for supplying sulphur to a plant | |
| CN113800990A (en) | AB water-soluble formula fertilizer special for gerbera jamesonii and preparation method thereof | |
| CN116854528A (en) | Preparation method and application of silicon-carbon chelating agent for increasing yield |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20220909 Address after: Suoxidu Village Committee, Erjie Town, Jinning District, Kunming City, Yunnan Province 650608 Applicant after: Yunnan Mengniu Biotechnology Co.,Ltd. Applicant after: INSTITUTE FOR PLANT PROTECTION AND SOIL SCIENCE, HUBEI ACADEMY OF AGRICULTURAL SCIENCES Applicant after: Shijiazhuang Mingyang Chemical Factory Address before: Suoxidu Village Committee, Erjie Town, Jinning District, Kunming City, Yunnan Province 650608 Applicant before: Yunnan Mengniu Biotechnology Co.,Ltd. Applicant before: INSTITUTE FOR PLANT PROTECTION AND SOIL SCIENCE, HUBEI ACADEMY OF AGRICULTURAL SCIENCES |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220826 |