CN114907512A - 一种多功能助剂及其制备方法和在制备含氯聚合物材料中的应用 - Google Patents
一种多功能助剂及其制备方法和在制备含氯聚合物材料中的应用 Download PDFInfo
- Publication number
- CN114907512A CN114907512A CN202210741631.3A CN202210741631A CN114907512A CN 114907512 A CN114907512 A CN 114907512A CN 202210741631 A CN202210741631 A CN 202210741631A CN 114907512 A CN114907512 A CN 114907512A
- Authority
- CN
- China
- Prior art keywords
- multifunctional
- preparation
- chlorine
- reaction
- containing polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 239000000460 chlorine Substances 0.000 title claims abstract description 13
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 13
- 239000000654 additive Substances 0.000 title claims description 12
- 230000000996 additive effect Effects 0.000 title claims description 11
- 239000002861 polymer material Substances 0.000 title claims description 8
- 238000002360 preparation method Methods 0.000 title abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 19
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 17
- BMFMTNROJASFBW-UHFFFAOYSA-N 2-(furan-2-ylmethylsulfinyl)acetic acid Chemical compound OC(=O)CS(=O)CC1=CC=CO1 BMFMTNROJASFBW-UHFFFAOYSA-N 0.000 claims abstract description 11
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000012986 chain transfer agent Substances 0.000 claims abstract description 10
- 239000003999 initiator Substances 0.000 claims abstract description 10
- 229920000642 polymer Polymers 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000003638 chemical reducing agent Substances 0.000 claims description 10
- 239000003607 modifier Substances 0.000 claims description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 239000008096 xylene Substances 0.000 claims description 4
- 239000005662 Paraffin oil Substances 0.000 claims description 3
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 3
- 239000012760 heat stabilizer Substances 0.000 claims description 3
- -1 terpene compounds Chemical class 0.000 claims description 3
- FRQQKWGDKVGLFI-UHFFFAOYSA-N 2-methylundecane-2-thiol Chemical compound CCCCCCCCCC(C)(C)S FRQQKWGDKVGLFI-UHFFFAOYSA-N 0.000 claims description 2
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 235000007586 terpenes Nutrition 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims 2
- 239000002904 solvent Substances 0.000 abstract 3
- 239000002131 composite material Substances 0.000 abstract 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004801 Chlorinated PVC Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/286—Chlorinated polyethylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
本发明提供了一种多功能助剂及其制备方法及在制备含氯聚合物复合材料中的应用，该多功能助剂，由以下质量分数的原料制成：甲基丙烯酸甲酯35％～90％、甲基丙烯酸锌29.9％～60％、引发剂0.05％～3％、链转移剂0.005％～1％、溶剂0～40％；所述多功能助剂的制备方法包括以下步骤：将甲基丙烯酸甲酯、甲基丙烯酸锌、引发剂、链转移剂、溶剂混合均匀，反应完成后脱除溶剂，即得到多功能助剂。
Description
技术领域
本发明涉及聚合物改性技术领域，尤其是涉及一种多功能助剂及其制备方法和在制备含氯聚合物材料中的应用。
背景技术
对于含氯聚合物，例如：聚氯乙烯(PVC)、氯化聚乙烯(CPE)、氯丁橡胶、氯磺化聚乙烯、氯化聚丙烯等等，大多不能单独使用，需混炼和改性。由于氯化物的特殊分子结构，需要添加稳定剂、耐热剂等，由于多种助剂及填料的加入，使体系熔体粘度增加，不利于加工，需要加入流动改性剂。而流动改性剂的加入，又大大降低了，材料的耐热性。市场急需一种同时满足耐热、稳定和改善加工性的助剂，以替代目前使用的多组份、难以兼顾性能、含有重金属的普通助剂。
发明内容
为了克服现有技术存在的缺陷，本发明提供了一种多种功能、性价比高、易于操作和实施，易于工业化大规模生产的多功能助剂及其制备方法和在制备含氯聚合物材料中的应用，
本发明解决其技术问题所采用的技术方案是：
一种多功能助剂，包括如下质量分数的原料：甲基丙烯酸甲酯35％～90％、甲基丙烯酸锌29.9％～60％、引发剂0.05％～3％、链转移剂0.005％～1％、减粘剂0～40％。
多功能助剂的制备方法，包括以下步骤：将甲基丙烯酸甲酯、甲基丙烯酸锌、引发剂、链转移剂、减粘剂混合均匀，反应温度为130～180℃，反应压力为0.01～0.8MPa，反应时间为45～80min，反应完成后脱除减粘剂，即得到多功能助剂。
多功能助剂，可作为含氯聚合物改性配方中的流动改性剂、外观改性剂或热稳定剂，在制备含氯聚合物材料中的应用。
本发明的有益效果主要表现在：对于含氯聚合物料如：聚氯乙烯、氯化聚乙烯、氯化聚氯乙烯等，该助剂实现了含氯聚合物材料改性过程一种助剂多种功能的目的，降低了多种助剂加入导致的材料性能降低和成本增加问题，易于操作和实施，易于工业化大规模生产，具备广阔的应用前景。
具体实施方式
下面对本发明作进一步描述。
一种多功能助剂，包括如下质量分数的原料：甲基丙烯酸甲酯35％～90％、甲基丙烯酸锌29.9％～60％、引发剂0.05％～3％、链转移剂0.005％～1％、减粘剂0～40％。
多功能助剂的制备方法，包括以下步骤：将甲基丙烯酸甲酯、甲基丙烯酸锌、引发剂、链转移剂、减粘剂混合均匀，反应温度为130～180℃，反应压力为0.01～0.8MPa，反应时间为45～80min，反应完成后脱除减粘剂，即得到多功能助剂。其中，引发剂可以是过氧化二异丙苯、过氧化苯甲酰、过氧化二叔丁基中的一种或多种的组合；链转移剂可以是叔十二碳硫醇、正十二碳硫醇、萜烯类化合物中的一种或多种；减粘剂可以是甲苯、二甲苯、乙苯、石蜡油中的一种或多种。
实例1
在一装有行星搅拌器、温度计、压力表和回流冷凝管的反应釜中，加入甲基丙烯酸甲酯350g、甲基丙烯酸锌650g、过氧化二叔丁基45g、叔十二碳硫醇7g、石蜡油50g。开动搅拌器，反应体系用油浴加热。通入氮气，待缓慢升温至反应温度140℃时，保持压力0.3MPa。反应时间70min，当反应结束后，撤去油浴降温，将产物用己烷洗涤数次，在60℃真空烘箱中干燥10小时，即得到多功能助剂。
将10Kg氯化聚乙烯(CPE)、多功能助剂800g、抗氧剂10g，置于高速混合机中，混合3min。将混合后的物料加入到双螺杆挤出机中，螺杆的各段温度为155～185℃，螺杆转速为150rpm。物料经挤出、切粒得氯化聚乙烯(CPE)粒料。
实例2
在一装有行星搅拌器、温度计、压力表和回流冷凝管的反应釜中，加入甲基丙烯酸甲酯650g、甲基丙烯酸锌350g、过氧化二异丙苯25g、叔十二碳硫醇4g、二甲苯250g。开动搅拌器，反应体系用油浴加热。通入氮气，待缓慢升温至反应温度140℃时，保持压力0.3-0.4MPa。反应时间65min，当反应结束后，撤去油浴降温，将产物用乙醇沉析，并洗涤数次，在60℃真空烘箱中干燥10小时，即得到多功能助剂。
将10Kg氯化聚乙烯(CPE)、多功能助剂剂1000g、碳酸钙100g,置于低速混合机中，混合3min。将混合后的物料加入到单螺杆挤出机中，螺杆的各段温度为155～175℃，螺杆转速为100rpm。物料经挤出、切粒得氯化聚乙烯(CPE)粒料。
实例3
在一装有行星搅拌器、温度计、压力表和回流冷凝管的反应釜中，加入甲基丙烯酸甲酯550g、甲基丙烯酸锌450g、过氧化二异丙苯35g、叔十二碳硫醇8g、二甲苯450g。开动搅拌器，反应体系用油浴加热。通入氮气，待缓慢升温至反应温度140℃时，保持压力0.3-0.4MPa。反应时间70min，当反应结束后，撤去油浴降温，将产物用乙醇沉析，并洗涤数次，在60℃真空烘箱中干燥10小时，即得到多功能助剂。
将8Kg聚氯乙烯(PVC)、2Kg氯化聚乙烯(CPE)、多功能助剂1000g、碳酸钙100g，置于低速混合机中，混合3min。将混合后的物料加入到单螺杆挤出机中，螺杆的各段温度为155～175℃，螺杆转速为100rpm。物料经挤出、切粒得共混粒料。
本发明可作为流动改性剂、外观改性剂或热稳定剂，用于含氯聚合物材料中，如：聚氯乙烯、氯化聚乙烯、氯化聚氯乙烯等。本助剂具有环保、不引起材料性能劣化、性价比优异等特点。
Claims (4)
1.一种多功能助剂，其特征在于，包括如下质量分数的原料：甲基丙烯酸甲酯35％～90％、甲基丙烯酸锌29.9％～60％、引发剂0.05％～3％、链转移剂0.005％～1％、减粘剂0～40％。
2.如权利要求1所述的多功能助剂，其特征在于，所述引发剂是过氧化二异丙苯、过氧化苯甲酰、过氧化二叔丁基中的一种或多种的组合；所述链转移剂是叔十二碳硫醇、正十二碳硫醇、萜烯类化合物中的一种或多种；减粘剂是甲苯、二甲苯、乙苯、石蜡油中的一种或多种。
3.如权利要求1所述的多功能助剂的制备方法，其特征在于，包括以下步骤：将甲基丙烯酸甲酯、甲基丙烯酸锌、引发剂、链转移剂、减粘剂混合均匀，反应温度为130～180℃，反应压力为0.01～0.8MPa，反应时间为45～80min，反应完成后脱除减粘剂，即得到多功能助剂。
4.如权利要求1或2所述的多功能助剂，可作为含氯聚合物改性配方中的流动改性剂、外观改性剂或热稳定剂，在制备含氯聚合物材料中的应用。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210741631.3A CN114907512A (zh) | 2022-06-27 | 2022-06-27 | 一种多功能助剂及其制备方法和在制备含氯聚合物材料中的应用 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210741631.3A CN114907512A (zh) | 2022-06-27 | 2022-06-27 | 一种多功能助剂及其制备方法和在制备含氯聚合物材料中的应用 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114907512A true CN114907512A (zh) | 2022-08-16 |
Family
ID=82772575
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210741631.3A Pending CN114907512A (zh) | 2022-06-27 | 2022-06-27 | 一种多功能助剂及其制备方法和在制备含氯聚合物材料中的应用 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114907512A (zh) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4820748A (en) * | 1986-09-16 | 1989-04-11 | Nippon Paint Co., Ltd. | Antifouling coating composition |
| JPH06145255A (ja) * | 1992-11-09 | 1994-05-24 | Nippon Shokubai Co Ltd | 耐熱性に優れたメタクリル系樹脂の製造方法 |
| CN101440174A (zh) * | 2008-12-23 | 2009-05-27 | 南京工业大学 | 一种新型钙/锌复合热稳定剂组合物及其应用 |
| CN103992447A (zh) * | 2014-06-05 | 2014-08-20 | 上海众取化工有限公司 | 一种丙烯酸锌树脂的合成方法 |
| CN107501461A (zh) * | 2017-08-18 | 2017-12-22 | 天津科技大学 | 一种具有热稳定剂和增塑双功能的共聚型pvc 专用助剂 |
-
2022
- 2022-06-27 CN CN202210741631.3A patent/CN114907512A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4820748A (en) * | 1986-09-16 | 1989-04-11 | Nippon Paint Co., Ltd. | Antifouling coating composition |
| JPH06145255A (ja) * | 1992-11-09 | 1994-05-24 | Nippon Shokubai Co Ltd | 耐熱性に優れたメタクリル系樹脂の製造方法 |
| CN101440174A (zh) * | 2008-12-23 | 2009-05-27 | 南京工业大学 | 一种新型钙/锌复合热稳定剂组合物及其应用 |
| CN103992447A (zh) * | 2014-06-05 | 2014-08-20 | 上海众取化工有限公司 | 一种丙烯酸锌树脂的合成方法 |
| CN107501461A (zh) * | 2017-08-18 | 2017-12-22 | 天津科技大学 | 一种具有热稳定剂和增塑双功能的共聚型pvc 专用助剂 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3693017B2 (ja) | 熱可塑性エラストマー組成物 | |
| CN105504172B (zh) | 一种用于橡塑材料的改性氯化聚乙烯的制备工艺 | |
| CN104672613A (zh) | 一种耐高温的热塑性弹性体材料及其制备方法 | |
| EP0796286A1 (en) | Preparation of polyolefin based thermoplastic elastomers | |
| CN109422969B (zh) | 一种基于evoh的高气体阻隔性热塑性硫化胶及其制备方法 | |
| CN111718587A (zh) | 一种低压缩永久变形热塑性弹性体材料及其制备方法 | |
| CN114193881B (zh) | 一种高分子预铺防水卷材及其制备方法 | |
| US3997487A (en) | Thermoplastic elastomer | |
| CN107250246B (zh) | 热塑性弹性体组合物及其制造方法 | |
| CN114907512A (zh) | 一种多功能助剂及其制备方法和在制备含氯聚合物材料中的应用 | |
| CN112143125A (zh) | 一种聚氯乙烯材料及其制备方法 | |
| CN104292391A (zh) | 一种不饱和酸酐接枝氯化聚乙烯熔融生产法 | |
| CN103435920A (zh) | 一种三元乙丙再生橡胶密封条的生产方法 | |
| CN114051506B (zh) | 保存稳定性、耐水性优异的丙烯酸橡胶胶包 | |
| CN103951874A (zh) | 一种超强超韧聚丙烯改性树脂及其制备工艺 | |
| CN115058086B (zh) | 一种挤出级热塑性硫化橡胶及其制备方法 | |
| CN114573955B (zh) | 一种动态硫化tpee组合物其制备方法和应用 | |
| CN112321982A (zh) | 一种耐老化hips发泡塑料 | |
| CN110256632B (zh) | 一种不含铬的高支化度聚烯烃树脂的制备方法 | |
| KR20230027027A (ko) | 밴버리 가공성이 우수한 아크릴 고무 베일 | |
| CN112940435A (zh) | 一种低压缩永久形变热塑性弹性体密封材料及其制备方法 | |
| US5104940A (en) | Thermoplastic elastomer based on ethylene/acrylate copolymer and polynorbornene | |
| CN115043992B (zh) | 一种提高了硬度的热塑性弹性体及其制备方法 | |
| CN115322489B (zh) | 一种耐高温发泡聚丙烯母粒及其制备方法 | |
| JP2637844B2 (ja) | エチレン／α―オレフィンコポリマー及びポリノルボルネンをベースとする熱可塑性エラストマー |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220816 |
|
| RJ01 | Rejection of invention patent application after publication |