CN114801354A - Active carbon composite material with fireproof performance - Google Patents

Active carbon composite material with fireproof performance Download PDF

Info

Publication number
CN114801354A
CN114801354A CN202210369160.8A CN202210369160A CN114801354A CN 114801354 A CN114801354 A CN 114801354A CN 202210369160 A CN202210369160 A CN 202210369160A CN 114801354 A CN114801354 A CN 114801354A
Authority
CN
China
Prior art keywords
adsorption layer
activated carbon
weight
flame
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210369160.8A
Other languages
Chinese (zh)
Inventor
徐晓正
陈乐奇
孙道明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN202210369160.8A priority Critical patent/CN114801354A/en
Publication of CN114801354A publication Critical patent/CN114801354A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/16Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/16Layered products comprising a layer of metal next to a particulate layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/28Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/025Particulate layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10Inorganic particles
    • B32B2264/107Ceramic
    • B32B2264/108Carbon, e.g. graphite particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses an active carbon composite material with fireproof performance, which comprises a metal layer and two adsorption layers; the metal layer is made of aluminum sheets, the adsorption layer is made of activated carbon particles, flame-retardant powder and an adhesive, wherein the activated carbon particles account for 50-60% of the weight of the adsorption layer, the adhesive accounts for 35-45% of the weight of the adsorption layer, the flame-retardant powder accounts for 5-10% of the weight of the adsorption layer, and all the components are in dry weight proportion; the adsorption layer is fully covered on both sides of the metal layer. The composite structure adopted by the invention is characterized in that the adsorption layer is bonded on the aluminum sheet, so that the composite structure has good structural strength, and the problem that the active carbon particles are sealed in a large proportion due to excessive proportion of the adhesive and the auxiliary materials in the traditional honeycomb active carbon is effectively solved. The structural aluminum sheet and the inorganic adhesive are non-combustible materials, and the flame-retardant powder is added into the adsorption layer, so that the risk of ignition of the activated carbon under the high-temperature condition can be effectively prevented, and the method can be applied to hot air desorption at higher temperature.

Description

Active carbon composite material with fireproof performance
Technical Field
The invention relates to an active carbon composite material with fireproof performance, in particular to an active carbon composite sheet material which is applied to organic waste gas treatment and has safety performance, and belongs to the technical field of new materials and environmental protection.
Background
The activated carbon with good adsorption performance is widely applied to the adsorption of harmful gases in air purification, and the most widely applied to the treatment of organic waste gases including VOCs is a honeycomb activated carbon product.
The porous structure of the activated carbon has extremely high specific surface area and better adsorption capacity to organic gas, the structure of the honeycomb activated carbon also has larger overfire air contact area under smaller overall dimension, but a certain proportion of bonding materials and other auxiliary materials need to be added into the activated carbon powder in the manufacturing process of the honeycomb activated carbon to meet the requirement of extrusion molding, if the addition proportion of the bonding materials and the auxiliary materials is too large, the adsorption efficiency of the honeycomb activated carbon is reduced, but the strength of a finished product is reduced if the addition amount is too small, the damage in transportation and use is easily caused, and particularly when the honeycomb activated carbon is regenerated in an off-line desorption mode, the breakage rate is greatly increased by repeated assembly, disassembly and transportation, so the contradiction between the adsorption efficiency of the honeycomb activated carbon and the structural strength exists all the time.
Furthermore, the honeycomb activated carbon is easy to cause fire accidents during desorption and regeneration, and the reason is that exothermic reaction is generated in the process of activated carbon reabsorption, and particularly when organic waste gas with low burning point (such as ketone and aldehyde gas) is treated, spontaneous combustion is easily generated to cause fire if the heat dissipation is poor, so that only hot air temperature below 120 ℃ can be used for ensuring safe desorption, and the low desorption temperature is difficult to completely desorb organic solvent with high boiling point, so that the adsorption capacity after honeycomb activated carbon regeneration is gradually reduced, and the service life of the honeycomb activated carbon is reduced.
The zeolite rotating wheel used in the current market can be desorbed by high-temperature hot air, but the price is very high, and the zeolite molecular sieve has a narrow application range to organic waste gas types compared with activated carbon, so the zeolite rotating wheel cannot be generally applied in the market.
Disclosure of Invention
The technical problem to be solved by the invention is to provide the active carbon composite material with the fireproof performance, and the composite material has the advantages of high adsorption efficiency, difficult damage, long service life, wide application range to organic waste gas, low price and safety.
The invention can adopt the following technical scheme:
an active carbon composite material with fireproof performance comprises a metal layer and two adsorption layers; the metal layer is made of aluminum sheets, the adsorption layer is made of activated carbon particles, flame-retardant powder and an adhesive, wherein the activated carbon particles account for 50-60% of the weight of the adsorption layer, the adhesive accounts for 35-45% of the weight of the adsorption layer, the flame-retardant powder accounts for 5-10% of the weight of the adsorption layer, and all the components are in dry weight proportion; the adsorption layer is fully covered on both sides of the metal layer.
The invention can further adopt the following improvement measures to solve the problems:
the further improvement is that: the flame-retardant powder is distributed on the outer surface of the adsorption layer.
The further improvement is that: the activated carbon particles account for 55 percent of the weight of the adsorption layer, the flame-retardant powder accounts for 5 percent of the weight of the adsorption layer, and the adhesive accounts for 40 percent of the weight of the adsorption layer.
The further improvement is that: the activated carbon particles account for 60% of the weight of the adsorption layer, the flame-retardant powder accounts for 5% of the weight of the adsorption layer, and the adhesive accounts for 35% of the weight of the adsorption layer.
The further improvement is that: the activated carbon particles account for 57% of the weight of the adsorption layer, the flame-retardant powder accounts for 8% of the weight of the adsorption layer, and the adhesive accounts for 35% of the weight of the adsorption layer.
The further improvement is that: the thickness of the aluminum sheet is between 50 and 200 um.
The further improvement is that: the aluminum sheet is a planar aluminum sheet or a corrugated aluminum sheet.
The further improvement is that: the particle size of the active carbon particles is between 50 and 500 um.
The further improvement is that: the adhesive is a high-temperature resistant inorganic adhesive.
The further improvement is that: the flame-retardant powder is aluminum hydroxide or magnesium hydroxide.
The technical scheme has the following technical effects:
1. the composite structure adopted by the invention is characterized in that the adsorption layer is bonded on the aluminum sheet to form good structural strength, so that the adsorption layer is not easy to generate structural damage when being subjected to external force, and the composite structure is suitable for off-line desorption regeneration application occasions with frequent assembly, disassembly and replacement.
2. Based on the fact that an aluminum sheet is used as a structural foundation, only a small amount of adhesive needs to be added into the adsorption layer to guarantee the structural strength of the adsorption layer, and due to the fact that the inorganic adhesive attached to the active carbon particles is thin, the inorganic adhesive can shrink after drying and dehydration to crack, countless micro cracks form gaps for communicating the active carbon with the outside, and the problem that micropores of the active carbon are sealed in a large proportion due to the fact that the adding proportion of the adhesive and auxiliary materials is too large in the traditional honeycomb active carbon is effectively solved.
3. The structure of the invention adopts the aluminum sheet with high heat conductivity coefficient, has good heat dispersion performance, and avoids the risk of fire caused by local heat accumulation in the use process of the traditional honeycomb activated carbon.
4. The structural aluminum sheet and the inorganic adhesive are non-combustible materials, and the flame-retardant powder is added into the adsorption layer, so that the risk of ignition of the activated carbon under the high-temperature condition can be effectively prevented, and the method can be applied to hot air desorption at higher temperature.
5. The aluminum sheet in the structure of the invention has good flexibility and ductility, is easy to be processed into a corrugated shape, can be made into a planar sheet and a corrugated sheet, can form a honeycomb-like structure by the crossed lamination of the aluminum sheet and the corrugated sheet, forms a larger over-wind contact area, and can replace the traditional honeycomb activated carbon structure.
6. The product manufactured by the invention has wide application range, low manufacturing cost, good safety performance and convenient installation and maintenance.
Drawings
Fig. 1 is an enlarged schematic view of the structure of the present invention.
Fig. 2 is a schematic diagram of an embodiment of the present invention.
Fig. 3 is another schematic structure of the present invention.
Fig. 4 is a schematic cross-sectional view of an application structure of the present invention.
Fig. 5 is an enlarged schematic view of the structure of embodiment 2 of the present invention.
Detailed Description
The present invention will be described in detail with reference to specific examples.
Example 1: as shown in fig. 1, fig. 2, fig. 3, an activated carbon composite material with fire-proof performance comprises a metal layer 1 and two adsorption layers 2; the metal layer 1 is made of aluminum sheets, the adsorption layer 2 is made of activated carbon particles 3, flame-retardant powder 4 and adhesive 5, wherein the activated carbon particles 3 account for 50-60% of the weight of the adsorption layer 2, the adhesive 5 accounts for 35-45% of the weight of the adsorption layer, the flame-retardant powder 4 accounts for 5-10% of the weight of the adsorption layer, and all the components are in dry weight proportion; the adsorption layer 2 is fully covered on two sides of the metal layer 1. In this example, the activated carbon particles 3 account for 55% by weight of the adsorption layer 2, the flame-retardant powder 4 accounts for 5% by weight of the adsorption layer 2, and the binder 5 accounts for 40% by weight of the adsorption layer 2. The adhesive 5 is a high-temperature-resistant silica sol inorganic adhesive.
The thickness of the aluminum sheet 1 is between 50 and 200 um. The flame-retardant powder 4 is aluminum hydroxide or magnesium hydroxide. The particle size of the activated carbon particles 3 is between 50 and 500 um.
The aluminum sheet is a planar aluminum sheet, and is made into a planar sheet-shaped composite material (as shown in figure 2).
The working principle is as follows:
the product manufactured by the invention is mainly applied to the adsorption and desorption of harmful gases, including the adsorption and desorption of VOCs organic waste gases, and in the structure of the invention, the functions of all structural layers are as follows:
the adsorption layer is used as a working layer and is formed by the way that activated carbon particles have adsorption effect on organic gas molecules.
The aluminum sheet is as bearing structure layer, can let thin crisp adsorbed layer again realize having the sheet structure of certain intensity and toughness through the combination with the adsorbed layer, and the aluminum sheet has compliance and ductility, can make required shape through punching press or roll-in, including the flute form, and the aluminum sheet is heated and can not produce the burning in addition, possesses the safe effect, and the good heat conductivity of aluminum sheet plays the radiating action and prevents local heat accumulation, and the aluminum sheet also is a general material and acquires easily.
The adhesive is used for bonding the mixture of the activated carbon particles and the flame-retardant powder with the aluminum sheet, the hardness of the inorganic adhesive is increased after the inorganic adhesive is dried, namely, the hardened layers are coated on the two surfaces of the aluminum sheet, so that the hardness of the whole structure is increased, the defect that the aluminum sheet is soft is overcome, and the sheet is prevented from shaking under the action of wind force in the using process. The inorganic adhesive has the advantages of high temperature resistance, non-flammability and safety.
The flame-retardant powder added into the adsorption layer in a certain proportion can effectively prevent the fire risk that the activated carbon and other organic components are ignited due to unexpected high temperature.
Example 2: as shown in fig. 5. The present embodiment is characterized in that the flame retardant powder 4 is distributed on the outer surface of the adsorption layer 2.
Example 3: the present embodiment is characterized in that the aluminum sheet 1 can also be a corrugated aluminum sheet, and made into a corrugated composite material (as shown in fig. 3). The rest is the same as example 1 or example 2.
Example 4: the characteristics of the example are that the activated carbon particles account for 60% of the weight of the adsorption layer, the flame retardant powder accounts for 5% of the weight of the adsorption layer, and the adhesive accounts for 35% of the weight of the adsorption layer. The rest is the same as example 1 or example 2 or example 3.
Example 5: the characteristics of this example are that the activated carbon particles account for 57% by weight of the adsorption layer, the flame retardant powder accounts for 8% by weight of the adsorption layer, and the binder accounts for 35% by weight of the adsorption layer. The rest is the same as example 1 or example 2 or example 3.
The flat (as shown in fig. 2) and corrugated (as shown in fig. 3) fire-retardant activated carbon composite sheets manufactured by the above embodiments respectively can be stacked to form a honeycomb-like assembly (as shown in fig. 4) by crossing each other in the metal frame, and in the implementation, the flat and corrugated aluminum sheets can be stacked after the manufacture of the adsorption layer is finished respectively, or the flat and corrugated aluminum sheets are stacked and then the adsorption layer is manufactured by soaking or pouring adhesion, so that the composite sheet can be applied to the adsorption and desorption projects of organic waste gas.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.

Claims (10)

1. An activated carbon composite material with fireproof performance is characterized in that: comprises a metal layer and two adsorption layers; the metal layer is made of aluminum sheets, the adsorption layer is made of activated carbon particles, flame-retardant powder and an adhesive, wherein the activated carbon particles account for 50-60% of the weight of the adsorption layer, the flame-retardant powder accounts for 5-10% of the weight of the adsorption layer, the adhesive accounts for 35-45% of the weight of the adsorption layer, and all the components are in dry weight proportion; the adsorption layer is fully covered on both sides of the metal layer.
2. The activated carbon composite material with fire-retardant property according to claim 1, wherein: the flame-retardant powder is distributed on the outer surface of the adsorption layer.
3. The activated carbon composite material with fire-retardant property according to claim 1 or 2, characterized in that: the activated carbon particles account for 50% of the weight of the adsorption layer, the flame-retardant powder accounts for 5% of the weight of the adsorption layer, and the adhesive accounts for 45% of the weight of the adsorption layer.
4. The activated carbon composite material with fire-retardant property according to claim 1 or 2, characterized in that: the activated carbon particles account for 60% of the weight of the adsorption layer, the flame-retardant powder accounts for 5% of the weight of the adsorption layer, and the adhesive accounts for 35% of the weight of the adsorption layer.
5. The activated carbon composite material with fire-retardant property according to claim 1 or 2, characterized in that: the weight of the activated carbon particles accounts for 57%, the weight of the flame-retardant powder accounts for 8%, and the weight of the adhesive accounts for 35%.
6. The activated carbon composite material with fire-retardant property according to claim 1, wherein: the thickness of the aluminum sheet is between 50 and 200 um.
7. The activated carbon composite material with fire-retardant property according to claim 1, wherein: the aluminum sheet is a planar aluminum sheet or a corrugated aluminum sheet.
8. The activated carbon composite material with fire-retardant property according to claim 1, wherein: the particle size of the active carbon particles is between 50 and 500 um.
9. The activated carbon composite material with fire-retardant property according to claim 1, wherein: the adhesive is a high-temperature-resistant silica sol inorganic adhesive.
10. The activated carbon composite material with fire-retardant property according to claim 1, wherein: the flame-retardant powder is aluminum hydroxide or magnesium hydroxide.
CN202210369160.8A 2022-04-08 2022-04-08 Active carbon composite material with fireproof performance Pending CN114801354A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210369160.8A CN114801354A (en) 2022-04-08 2022-04-08 Active carbon composite material with fireproof performance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210369160.8A CN114801354A (en) 2022-04-08 2022-04-08 Active carbon composite material with fireproof performance

Publications (1)

Publication Number Publication Date
CN114801354A true CN114801354A (en) 2022-07-29

Family

ID=82535501

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210369160.8A Pending CN114801354A (en) 2022-04-08 2022-04-08 Active carbon composite material with fireproof performance

Country Status (1)

Country Link
CN (1) CN114801354A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060141256A1 (en) * 2003-06-13 2006-06-29 Kuraray Chemical Co., Ltd. Activated carbon product in sheet form and element of device for preventing transpiration of fuel vapor
CN114148049A (en) * 2021-12-24 2022-03-08 徐晓正 Flame-retardant active carbon composite sheet

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060141256A1 (en) * 2003-06-13 2006-06-29 Kuraray Chemical Co., Ltd. Activated carbon product in sheet form and element of device for preventing transpiration of fuel vapor
CN114148049A (en) * 2021-12-24 2022-03-08 徐晓正 Flame-retardant active carbon composite sheet

Similar Documents

Publication Publication Date Title
JP6339291B2 (en) SOUND ABSORPTION REFRESHING INSULATION PANELS USING EXPANDED GRAPHITE AND SWELLING CRAY AND METHOD FOR PRODUCING THE SAME
CN109650841B (en) Fireproof sound-insulation heat-preservation aerogel composite material and preparation method thereof
KR101336964B1 (en) An aerogel binder for forming insulating materials of glass long fibers and forming process of insulating materials thereby
KR101177383B1 (en) A production method of fire resistance composite
KR101287805B1 (en) An aerogel binder for forming insulating materials of glass long fibers and forming process of insulating materials thereby
CN103192582A (en) Production method of no-powder-falling interlayer structure super heat insulation gas gel composite material
CN113510978B (en) Aerogel anticorrosion heat-insulation flexible plate and manufacturing method thereof
KR102145611B1 (en) Aerogel insulation composition for thin film and aerogel thin film sheet comprising the same
CN114197219A (en) Composite lithium battery fireproof material and preparation method and application thereof
JP2006239917A (en) Honeycomb structure and its manufacturing method
CN216832612U (en) Flame-retardant active carbon composite sheet
CN114801354A (en) Active carbon composite material with fireproof performance
CN114148049A (en) Flame-retardant active carbon composite sheet
KR101519864B1 (en) Sound absorbing and adiabatic material having lightweight fireproof using expandable graphite and manufacturing method of the same
CN101786815B (en) Inorganic intercalated vermiculite insulation refractory material and preparation method thereof
CN114032045A (en) Fireproof heat-insulating material and preparation method and application thereof
CN106313763A (en) Aerogel-based composite aluminum fiber acoustic panel absorber and preparation method thereof
CN2893603Y (en) Industrial furnace body structure
CN204850102U (en) High -efficient heat preservation heat insulating board
CN211875441U (en) Light high-temperature-resistant heat-insulating plate
CN201059405Y (en) Insulating material composite bed structure
CN212266878U (en) A-level fireproof far infrared thermal radiation plate
CN221022650U (en) Multi-layer high-temperature-resistant composite needled felt
CN203846626U (en) Novel heat preservation board
CN212737359U (en) Shaving board capable of efficiently adsorbing formaldehyde

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20220729