CN114774831A - Textured babbit metal coating antifriction surface and preparation method thereof - Google Patents

Textured babbit metal coating antifriction surface and preparation method thereof Download PDF

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Publication number
CN114774831A
CN114774831A CN202210448016.3A CN202210448016A CN114774831A CN 114774831 A CN114774831 A CN 114774831A CN 202210448016 A CN202210448016 A CN 202210448016A CN 114774831 A CN114774831 A CN 114774831A
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metal coating
babbitt metal
laser
micro
texture
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CN114774831B (en
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郭前建
王文华
袁伟
丛建臣
张磊安
于洁
池宝涛
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Shandong University of Technology
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Shandong University of Technology
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/129Flame spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P15/00Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/08Metallic material containing only metal elements

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Laser Beam Processing (AREA)

Abstract

The patent discloses a textured babbit metal coating antifriction surface and a preparation method thereof, and belongs to the technical field of mechanical motion friction pair surfaces. The circular micro-pit array is a regularly distributed surface pit texture formed by laser processing; the Babbitt metal coating is a mask which is thermally sprayed on the surface of the substrate to reduce the thermal influence of laser processing; the multilayer texture consists of an array of laser-machined pits and babbitt surface interstices. According to the invention, by arranging the Babbitt metal coating and the composite modified surface formed by laser surface texturing, the adverse effect of laser processing on the surface performance can be obviously reduced, the burrs formed by accumulation of hard molten metal and oxides thereof generated in the processing process are reduced, and the formed multilayer texture is beneficial to the storage of abrasive particles and the formation of hydrodynamic lubrication, so that the occurrence of micro-cutting abrasion is reduced, and the frictional abrasion performance of a friction pair is improved.

Description

Textured babbit metal coating antifriction surface and preparation method thereof
Technical Field
The invention belongs to the technical field of mechanical motion friction pair surfaces, and particularly relates to a textured babbitt metal coating antifriction surface and a preparation method thereof.
Background
The main cause of the mechanical component failure due to frictional wear, about 80% of the mechanical component failure is caused by various forms of wear, and the economic loss due to the mechanical component failure is as high as billions of yuan.
At present, methods for improving the surface tribological performance include surface texturing and surface coating technologies, wherein the laser surface processing technology is an important way for processing micro-textures on the surface due to high efficiency, strong controllability and high precision. However, the laser surface processing technology is not very favorable for improving the surface tribological performance because the material is melted, splashed and accumulated to generate burrs due to high temperature while the micro texture is processed on the surface.
Researches show that the laser surface processing under the protection of underwater or a mask can well inhibit burrs, so that the coating-texture composite modified antifriction surface for reducing the laser surface processing heat influence is provided, and the formation of a multi-layer texture is more beneficial to the improvement of the surface tribological performance while the adverse effect caused by the laser surface processing is reduced.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a textured babbitt metal coating antifriction surface which simultaneously has a babbitt metal coating and a surface texture, the babbitt metal coating serving as a solid mask during laser surface processing can reduce the adverse effects of burrs and the like formed by accumulation of hard metals and oxides thereof during processing, and meanwhile, the multilayer texture formed by micro gaps on the surface of the babbitt metal coating and a circular micro-pit array generated by laser processing is more favorable for formation of fluid dynamic pressure lubrication, so that the three-body friction wear on the surface of a friction pair is reduced, and the purpose of improving the overall friction performance of the surface is achieved.
The invention is realized in this way, the invention discloses a textured babbitt metal coating antifriction surface, the surface comprises a round micro-pit array, a babbitt metal coating mask and a multi-layer texture, the round micro-pit array is regularly distributed surface micro-texture processed by laser surface; the Babbitt metal coating is a mask which is sprayed on the surface of a substrate by flame to reduce the thermal influence of laser surface processing; the multilayer texture is composed of a pit array generated by laser surface processing and a surface gap formed by the characteristic that a soft matrix and hard particles are embedded in the surface of the Babbitt metal.
Further, the circular micro-pit array is a micro-texture formed by processing a picosecond laser under the Babbitt metal coating serving as a solid mask, and the specific geometric parameters are as follows: the diameter is ∈ [130,160] μm, the depth is ∈ [50,80] μm, and the area density is 20%.
Furthermore, the thickness of the Babbitt metal coating mask is within the range of 20,40 μm, and a secondary texture is formed by surface gaps formed by the characteristic that a soft matrix and hard particles are embedded in the surface of the Babbitt metal.
Furthermore, the gaps on the surface of the babbitt metal and the circular micro-pit array generated by laser surface processing form a multi-layer texture, wherein the gaps on the surface of the babbitt metal coating are randomly distributed, and the texture of the circular micro-pit array micro-pits is uniform and regularly distributed.
The other purpose of the invention is realized by the following technical scheme: a preparation method of a composite modified antifriction surface for reducing the thermal influence of laser surface processing is characterized by comprising the following steps: selecting babbit alloy as a coating, spraying the babbit alloy on a base material in a thermal spraying mode, and carrying out grinding and polishing and ethanol and acetone bath ultrasonic cleaning treatment before spraying; the Barbie alloy coating is used as a solid mask, adverse thermal influence is reduced during laser surface processing, and the following laser processing parameters are adopted to manufacture a circular micro-pit array on the surface of the material under the Barbie alloy solid mask: the average power is 20W, the repetition frequency is 2 MHz, the pulse width is 300 ps, the scanning speed is 2000 mm/s, and the scanning times are 30-50; after laser surface machining, the machined surface is lightly polished with an automatic polisher to reduce the effect of some residual adhering debris on the quality of the surface finish.
The invention has the following beneficial effects in the prior art: according to the invention, the textured babbit alloy coating antifriction surface is processed on the surface of the friction pair, the composite surface is beneficial to improving the friction and wear performance of the surface of the friction pair, compared with burrs generated by traditional laser surface processing, the babbit alloy coating has an obvious inhibition effect on the generation of hard burrs, and the multilayer texture can better store oil and abrasive particles, and is more beneficial to forming fluid dynamic pressure lubrication.
Drawings
FIG. 1 is a top view of a schematic representation of the structure of a composite modified antifriction surface of the present invention.
FIG. 2 is an axial view of a schematic representation of the structure of the composite modified antifriction surface of the present invention.
FIG. 3 is a structural diagram of a composite modified antifriction surface multilayer texture of the present invention.
In the figure: 1-base material, 2-round micro-pit array, 3-single micro-pit forming the micro-pit array, 4-babbitt metal coating, 5-multilayer texture.
Detailed Description
The invention provides a textured babbitt metal coating antifriction surface and a preparation method thereof, and in order to make the purpose, technical scheme and effect of the invention clearer and clearer, the invention is further described in detail by referring to the attached drawings and by taking examples. The specific embodiments described herein are merely illustrative of the invention and are not intended to be limiting.
The processing method of the babbitt metal coating is thermal spraying but is not limited to the thermal spraying, and the processing parameters of the circular pit array can be determined according to the requirements and equipment requirements in actual processing.
The GCr15 bearing steel substrate and the picosecond fiber laser are selected as the laser processing method, and the composite modified antifriction surface for reducing the heat influence of laser surface processing and the preparation method thereof are further described in the following by combining the attached drawings 1, 2 and 3 in the specification: FIG. 1 is a schematic diagram of a GCr15 bearing steel material sprayed with Babbitt metal coating after laser surface processing, which comprises a base material GCr15 bearing steel 1, a circular micro-pit array 2, a single micro-pit 3 forming the micro-pit array, and a Babbitt metal coating 4.
In the attached figure 1, a circular micro-pit array 2 is a micro-texture formed by processing a picosecond laser under a babbitt metal coating serving as a solid mask, and the specific geometric parameters are as follows: the diameter is ∈ [130,160] μm, the depth is ∈ [50,80] μm, and the area density is 20%.
In the attached figure 2, the thickness of a mask of the Babyite coating 4 belongs to [20,40] mu m, and a secondary texture is formed by surface gaps formed by the characteristic that a soft matrix and hard particles are embedded in the surface of the Babyite.
In the attached figure 1, the Babbitt metal surface gaps and the circular micro-pit array generated by laser surface processing form a multilayer texture, wherein the surface gaps of the Babbitt metal coating 4 are randomly distributed, and the texture of the circular micro-pit array micro-pits 3 is uniform and regularly distributed.
FIG. 2 is a view showing that a Babbitt metal coating 4 is a mask which is sprayed on the surface of a substrate by flame to reduce the thermal influence of laser surface processing; the multilayer texture 5 in fig. 3 is composed of an array of pits formed by laser surface processing and surface gaps formed by the characteristic that a soft matrix and hard particles are embedded in the surface of babbitt metal.
A preparation method of a composite modified antifriction surface for reducing the thermal influence of laser surface processing comprises the following steps:
firstly, Babbitt metal is selected as a coating, the coating is sprayed on a GCr15 bearing steel matrix material 1 in a thermal spraying mode, the spraying thickness is within 20 and 40 mu m, the surface roughness Ra is about 0.4 mu m, and grinding and polishing and ethanol and acetone bath ultrasonic cleaning treatment are carried out before spraying.
Step two, taking the Barbie alloy coating 4 as a solid mask, reducing adverse thermal influence during laser surface processing, and adopting the following laser processing parameters to manufacture a circular micro-pit array on the surface of a material under the Barbie alloy solid mask, wherein the average power is 20W, the repetition frequency is 2 MHz, the pulse width is 300 ps, the scanning speed is 2000 mm/s, and the scanning times are 30-50 times; a circular array of micro-pits with a diameter ∈ [130,160] μm, a depth ∈ [50,80] μm, and an area density of 20% was obtained.
And step three, after the laser surface processing, slightly polishing the surface on the processed surface by using an automatic polishing machine to reduce the influence of part of residual adhesive debris on the surface processing quality.

Claims (6)

1. A textured babbitt metal coating antifriction surface and a preparation method thereof are provided, wherein the surface comprises a circular micro-pit array, a babbitt metal coating mask and a multi-layer texture.
2. The circular micro-pit array is regularly distributed surface micro-texture formed by laser surface processing; the Babbitt metal coating is a mask which is thermally sprayed on the surface of a substrate to reduce the processing heat influence of the laser surface; the multilayer texture is composed of a pit array generated by laser surface processing and a surface gap formed by the characteristic that a soft matrix on the surface of Babbitt metal is embedded with hard particles.
3. The textured babbitt metal coating antifriction surface of claim 1, wherein the circular array of micro-pits is micro-texture formed by picosecond laser machining under the babbitt metal coating as a solid mask, and the specific geometric parameters are as follows: the diameter is ∈ [130,160] μm, the depth is ∈ [50,80] μm, and the area density is 20%.
4. The textured babbitt metal coating antifriction surface of claim 2, wherein the babbitt metal coating mask has a thickness e [20,40] μm, and surface microgaps formed by the characteristic that a soft matrix and hard particles are embedded in the babbitt metal surface form a secondary texture.
5. The textured babbitt metal coating antifriction surface of claim 1, wherein babbitt metal surface gaps and a circular array of micro-pits produced by laser surface machining form a multi-layer texture, wherein babbitt metal coating surface gaps are randomly distributed and the circular array of micro-pits are uniformly and regularly distributed.
6. A preparation method of a composite modified antifriction surface for reducing the thermal influence of laser surface processing is characterized by comprising the following steps:
1) selecting babbit alloy as a coating, spraying the babbit alloy on a base material in a thermal spraying mode, and carrying out grinding and polishing and ethanol and acetone bath ultrasonic cleaning treatment before spraying;
2) taking the Babbitt metal coating as a solid mask, reducing adverse thermal influence during laser surface processing, and manufacturing a circular micro-pit array on the surface of a material under the Babbitt metal solid mask by adopting the following laser processing parameters: the average power is 20W, the repetition frequency is 2 MHz, the pulse width is 300 ps, the scanning speed is 2000 mm/s, and the scanning times are 30-50 times;
3) after laser surface machining, the machined surface is lightly polished with an automatic polisher to reduce the effect of some residual adhering debris on the quality of the surface finish.
CN202210448016.3A 2022-04-26 2022-04-26 Textured Babbitt metal coating antifriction surface and preparation method thereof Active CN114774831B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3310423A (en) * 1963-08-27 1967-03-21 Metco Inc Flame spraying employing laser heating
CN103014589A (en) * 2011-09-26 2013-04-03 上海大豪纳米材料喷涂有限公司 Method for thermally spraying Babbitt-metal coating on surface of crosshead
CN111020448A (en) * 2019-12-12 2020-04-17 北京工商大学 Wear-resistant anti-corrosion sucker rod coupling with oil storage and oil supplement channel on surface and preparation process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3310423A (en) * 1963-08-27 1967-03-21 Metco Inc Flame spraying employing laser heating
CN103014589A (en) * 2011-09-26 2013-04-03 上海大豪纳米材料喷涂有限公司 Method for thermally spraying Babbitt-metal coating on surface of crosshead
CN111020448A (en) * 2019-12-12 2020-04-17 北京工商大学 Wear-resistant anti-corrosion sucker rod coupling with oil storage and oil supplement channel on surface and preparation process

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