CN114685135A - Light gypsum mortar with high coating rate - Google Patents

Light gypsum mortar with high coating rate Download PDF

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Publication number
CN114685135A
CN114685135A CN202210507484.3A CN202210507484A CN114685135A CN 114685135 A CN114685135 A CN 114685135A CN 202210507484 A CN202210507484 A CN 202210507484A CN 114685135 A CN114685135 A CN 114685135A
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China
Prior art keywords
gypsum mortar
gypsum
mortar
lightweight
coating rate
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CN202210507484.3A
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Chinese (zh)
Inventor
张召舟
蔡欣
赵焕起
许欣
万银萍
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Zhenjiang Jibang Material Technology Co ltd
Jiangsu Jill Mstar Technology Ltd
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Zhenjiang Jibang Material Technology Co ltd
Jiangsu Jill Mstar Technology Ltd
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Priority to CN202210507484.3A priority Critical patent/CN114685135A/en
Publication of CN114685135A publication Critical patent/CN114685135A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/145Calcium sulfate hemi-hydrate with a specific crystal form
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38Fibrous materials; Whiskers
    • C04B14/40Asbestos
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38Fibrous materials; Whiskers
    • C04B14/46Rock wool ; Ceramic or silicate fibres
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention belongs to the technical field of building materials, and particularly discloses light gypsum mortar with high coating rate. The light gypsum mortar provided by the invention has the excellent performance characteristics of high coating rate and high strength by adding mineral wool or asbestos on the basis of the components of the existing gypsum mortar. The composite addition of mineral wool or asbestos and lightweight aggregate ensures that the product strength meets the national standard while greatly improving the coating rate, and solves the technical problem that the product strength is greatly reduced under the condition that the coating rate of the lightweight gypsum mortar is obviously increased. In addition, the mineral wool or the asbestos is also used as an anti-sagging agent, so that the anti-sagging performance of the light gypsum mortar is greatly improved, and the excellent performance characteristics of the mineral wool or the asbestos provide wider application prospects for the light gypsum mortar.

Description

Light gypsum mortar with high coating rate
Technical Field
The invention belongs to the technical field of building materials, and particularly relates to light gypsum mortar with high coating rate.
Background
The lightweight gypsum mortar is a novel environment-friendly plastering material, takes semi-hydrated gypsum as a main cementing material, is prepared by adding lightweight aggregate and functional additives, has the advantages of good working performance, small shrinkage, difficult cracking and hollowing, good cohesiveness, environmental protection and the like compared with the traditional cement plastering material, and has the effect of adjusting indoor humidity. With the rapid development of the building material industry, lightweight gypsum mortar is developing toward higher quality products. The coating rate of the lightweight gypsum mortar is an important performance index with higher market attention, and the coating rate of the gypsum mortar is generally increased by adding lightweight aggregate. However, the incorporation of excessive or poorly graded lightweight aggregates leads to a decrease in the strength of the gypsum mortar and a serious influence on the workability of the product. Therefore, how to balance and match the relationship between the coating rate and the strength of the light gypsum mortar is a technical point of the light gypsum mortar in the prior stage for intensive research.
In addition, the light gypsum mortar has the problems of sagging, slipping and the like in the construction process, so that the product has poor construction performance and low construction efficiency. The prior method for improving the sag resistance of the lightweight gypsum mortar is generally to add a thixotropic agent or a thickening agent, but the additive can increase the slurry consistency, so that the problems of difficult scraping of the product, labor-consuming construction and the like are caused. In addition, the water consumption of products is not accurately controlled on a construction site, and the water adding amount completely depends on the visual feeling of constructors; when the amount of water used is excessive, the problem of sagging of the gypsum mortar is more likely to occur. Therefore, how to improve the sag resistance of the gypsum mortar is also an important research topic of the lightweight gypsum mortar.
Disclosure of Invention
The inventor of the invention provides a brand-new method for improving the coating rate of the light gypsum mortar based on long-term research on the performance of the light gypsum mortar, and simultaneously has the characteristic of high strength; in addition, the light gypsum mortar also has excellent anti-sagging performance, and provides wider application prospects for the light gypsum mortar.
The invention adopts the following technical scheme:
the light gypsum mortar with high coating rate comprises the following components in parts by mass, which are uniformly mixed:
Figure BDA0003636640520000021
in individual embodiments, no more than 200 parts of fine sand is also included.
In a particular embodiment, no more than 3 parts of dispersible latex powder is included.
According to the light gypsum mortar provided by the invention, the mineral wool or the asbestos is added, and the content of the mineral wool or the asbestos is preferably controlled to be 0.1-3% of the total weight of the light gypsum mortar, so that the light gypsum mortar has the performance characteristics of high coating rate and high strength, and has better sag resistance, and the improvement of the performance of the light gypsum mortar in the two aspects provides great advantages for the practical application of the light gypsum mortar.
The mineral wool is inorganic fiber cotton prepared by using rock such as slag, fly ash or basalt as main raw materials and melting the rock into cotton at high temperature, and the bulk density of the mineral wool is 50kg/m3~250kg/m3
The asbestos, a natural silicate material with industrial application, contains iron, magnesium, calcium or sodium, exists in a crystalline form, is in a fibrous form, and has a bulk density of 50kg/m3~250kg/m3
The semi-hydrated gypsum can be prepared by calcining a byproduct in a flue gas desulfurization process of a thermal power plant, wherein the purity of the desulfurized gypsum is not lower than 85%.
The particle size of the closed-cell vitrified micro-bead or the open-cell perlite is 0.3 mm-1.0 mm, and the bulk density is more than 80kg/m3The cylinder pressure strength is not lower than 200kPa, the heat conductivity coefficient is not higher than 0.070W/(m.K), the volume water absorption rate is not higher than 45%, and the volume floating rate is not lower than 80%.
The retarder adopts bone glue protein retarder and/or sugar calcium gypsum retarder material.
The water retention agent adopts hydroxyethyl methyl cellulose or hydroxypropyl methyl cellulose, and the viscosity of the water retention agent is 30000mPa & s-100000 mPa & s.
The fine sand is selected from any one of natural river sand, lake sand, sea sand and machine-made sand, and the preferred mesh number is 50-120 meshes.
The dispersible latex powder adopts at least one of ethylene-vinyl acetate copolymer, acrylic acid copolymer and polyvinyl alcohol.
On the basis of the components of the existing gypsum mortar, the light gypsum mortar obtained by adding mineral wool or asbestos has the excellent performance characteristics of high coating rate and high strength. The composite addition of mineral wool or asbestos and lightweight aggregate ensures that the product strength meets the national standard while greatly improving the coating rate, and solves the technical problem that the product strength is greatly reduced under the condition that the coating rate of the lightweight gypsum mortar is obviously increased. In addition, the mineral wool or the asbestos is also used as an anti-sagging agent, so that the anti-sagging performance of the light gypsum mortar is greatly improved, and the excellent performance characteristics of the mineral wool or the asbestos provide wider application prospects for the light gypsum mortar.
Detailed Description
The following describes embodiments of the present invention in detail. As the present invention may be embodied in many different forms, the invention should not be construed as limited to the specific embodiments set forth herein. Rather, these embodiments are provided to explain the principles of the invention and its practical application so as to enable others skilled in the art to understand the invention for various embodiments and its practical application.
It should be noted that, since the performance of each light gypsum mortar is measured with respect to a system obtained after mixing with water, and the amount of water used for mixing affects the performance of the system after mixing, in order to distinguish between before and after mixing with water, in each of the following examples, the term "light gypsum mortar dry-mixed material" refers to the light gypsum mortar protected by the present invention, and the term "gypsum mortar" refers to the product obtained after mixing the light gypsum mortar protected by the present invention with water.
The following table 1 shows the components and contents of the light gypsum mortar dry-mixed materials provided in examples 1 to 8 of the present invention.
Table 1 components and amounts of dry-mix for lightweight gypsum mortar provided in examples 1-8
Unit: kg of
Figure BDA0003636640520000031
In the above examples, the retarders in examples 1 to 3, 5, 6 and 8 are all ossein retarders, and the dispersible latex powder is all ethylene-vinyl acetate copolymer; in the other examples, the retarder is a calcium-sugar gypsum retarder material, and the dispersible latex powder is a mixture of acrylic copolymer and polyvinyl alcohol. The water-retaining agents in examples 1 to 6 were each hydroxyethyl methylcellulose having a viscosity of about 50000 mPas, and the water-retaining agents in the remaining examples were each hydroxypropyl methylcellulose having a viscosity of about 80000 mPas.
Meanwhile, the closed cell vitrified microbeads of examples 1 to 3, 5, 6 and 8 and the open cell perlite of examples 4 and 7 were selected to meet the following characteristics: the grain diameter is 0.3 mm-1.0 mm, and the bulk density is more than 80kg/m3The cylinder pressure strength is not lower than 200kPa, the heat conductivity coefficient is not higher than 0.070W/(m.K), the volume water absorption is not higher than 45 percent, and the volume floating rate is not lower than 80 percent.
The above components and the addition of the fine sand are all conventional in the art, and are not described herein, and those skilled in the art can refer to the prior art.
In order to show the influence of the mineral wool or asbestos in the dry-mixed material of the lightweight gypsum mortar provided in each example on the coating rate, strength and sag resistance of the gypsum mortar, the following comparative experiment was performed.
The components and contents of the comparative lightweight gypsum mortar dry mixes provided in comparative examples 1 to 4 are shown in table 2 below.
Table 2 components and content units of comparative light gypsum mortar dry-mixes provided in comparative examples 1 to 4: kg of
Figure BDA0003636640520000041
The following performance tests were carried out on each of the obtained gypsum mortars:
and (3) detecting the coating rate: taking 10kg of light gypsum mortar dry-mixed material or contrast light gypsum mortar dry-mixed material, adding water consumption with standard diffusivity, stirring for 1min to obtain uniformly stirred gypsum mortar, and uniformly coating the gypsum mortar in a pre-manufactured test mold frame, wherein the thickness of the gypsum mortar coated on the test mold frame is 10mm, and the coating area is 1m x 2 m. The actual application area of 10kg of dry mix of gypsum mortar was tested. Wherein, the water consumption data of the standard diffusivity refers to a method for measuring the water consumption of the standard diffusivity in GB/T28627-2012 plastering gypsum, namely the water consumption when the standard diffusivity range is 160-170 mm.
The glide distance of the mortar with the thickness of 10 mm: and (3) scraping gypsum mortar with the thickness of 10mm on the smooth and flat aluminum alloy plate, marking the lower bottom surface, then vertically placing the aluminum alloy plate, and observing the downward sliding distance of the lower bottom surface after the gypsum mortar is solidified and hardened. The aluminum alloy plate belongs to a smooth and flat surface, and the frictional resistance of the surface of the assembled building wall which is even very flat is far higher than that of the aluminum alloy plate on the site generally, so that the gliding distance is observed on the smooth and flat aluminum alloy plate, and the sagging resistance of the product is more intuitive and enlarged.
TABLE 3 Properties of Gypsum mortars corresponding to examples 1 to 8 and comparative gypsum mortars corresponding to comparative examples 1 to 4
Figure BDA0003636640520000051
In examples 1 to 3, the gypsum mortar obtained by adding different amounts of mineral wool, and in examples 4 to 6, the gypsum mortar obtained by adding different amounts of mineral wool was remarkably improved in sag resistance, and the surface of the mortar was smooth and fine without granular feeling. With the increase of the mixing amount of the mineral wool or the asbestos, the coating rate of the gypsum mortar is gradually increased, but the flexural strength/compressive strength is not obviously influenced, and is slightly reduced, such as example 1 and example 3, and under the condition that the coating rate is increased by 19.0%, the compressive strength is only reduced by 7.3%; as in examples 4 and 6, the compressive strength decreased by only 5.5% when the coating rate was increased by 20.3%.
Comparative example 1 in comparison with examples 1 to 8, the mineral wool or asbestos was not added, the coating rate was the lowest, the sag resistance was poor, and the surface had a coarse granular feel.
Comparative example 2 in comparison with example 2, the same application area of 1.75m was achieved210kg, mineral wool is not mixed in the comparative example 2, 45kg of closed-cell vitrified micro-beads are additionally added, the flexural strength and the compressive strength of the comparative example 2 are obviously reduced, and the strength requirement of a light bottom layer in GB/T28627-2012 plastering gypsum can not be met. It can be seen that when mineral wool is not used in the comparative gypsum mortar, even if the coating rate is increased by adding a large amount of closed-cell vitrified micro bubbles, the flexural/compressive strength is still significantly affected, and both cannot be considered. Also, the incorporation of too much lightweight aggregate leads to a decrease in slurry viscosity and poor sag resistance.
In comparative example 3 and comparative example 4, too much mineral wool or asbestos is added, the coating rate is obviously improved, but the flexural strength and the compressive strength are obviously reduced, and the strength requirement of a light bottom layer in GB/T28627-2012 plastering gypsum is not met. Also, the incorporation of too much mineral wool or asbestos results in excessive water usage, increased slurry porosity, reduced viscosity, and poor slip resistance of the slurry.
While the invention has been shown and described with reference to certain embodiments, those skilled in the art will understand that: various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims and their equivalents.

Claims (10)

1. The light gypsum mortar with high coating rate is characterized by comprising the following components in parts by mass which are uniformly mixed:
Figure FDA0003636640510000011
2. the lightweight gypsum mortar of claim 1, further comprising no more than 200 parts of fine sand.
3. The lightweight gypsum mortar of claim 1, further comprising not more than 3 parts of a dispersible latex powder.
4. The lightweight gypsum mortar of any one of claims 1 to 3, wherein the mineral wool and the asbestos each have a bulk density of 50kg/m3~250kg/m3
5. The light gypsum mortar of claim 4, wherein the hemihydrate gypsum is gypsum calcined as a byproduct in a flue gas desulfurization process of a thermal power plant, and the purity of the desulfurized gypsum in the hemihydrate gypsum is not less than 85%.
6. The lightweight gypsum mortar of claim 4, wherein the closed cell vitrified microbeads and the open cell perlite have a particle size of 0.3mm to 1.0mm and a bulk density of more than 80kg/m3The cylinder pressure strength is not lower than 200kPa, the heat conductivity coefficient is not higher than 0.070W/(m.K), the volume water absorption is not higher than 45 percent, and the volume floating rate is not lower than 80 percent.
7. The lightweight gypsum mortar of claim 4, wherein the set retarder is selected from the group consisting of bone glue protein set retarders and/or calcium sugar gypsum set retarders.
8. The light gypsum mortar of claim 4, wherein the water retaining agent is selected from hydroxyethyl methylcellulose and/or hydroxypropyl methylcellulose, and the viscosity of the water retaining agent is 30000mPa s to 100000mPa s.
9. The lightweight gypsum mortar of claim 2, wherein the fine sand is selected from any one of natural river sand, lake sand, sea sand and machine-made sand, and the mesh number of the fine sand is 50 to 120 mesh.
10. The lightweight gypsum mortar of claim 3, wherein the dispersible latex powder is selected from at least one of ethylene-vinyl acetate copolymer, acrylic acid copolymer, polyvinyl alcohol.
CN202210507484.3A 2022-05-10 2022-05-10 Light gypsum mortar with high coating rate Pending CN114685135A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643071A (en) * 2012-05-17 2012-08-22 浙江方远建材科技有限公司 Calcination-free desulfurized gypsum walling plastering dry-mixed mortar
CN103819166A (en) * 2013-12-31 2014-05-28 安徽省美域节能环保技术应用有限公司 Quick-drying enhanced fireproof thermal mortar
BR102014002644A2 (en) * 2013-02-05 2015-12-08 Promat Res And Technology Ct Nv fire protection mortar
CN105367030A (en) * 2015-11-06 2016-03-02 江苏尼高科技有限公司 Desulfurized-gypsum-base lightweight spraying gypsum mortar
CN108275959A (en) * 2018-03-12 2018-07-13 太原理工大学 A kind of cracking resistance plastering gupsum of high tenacity enhanced water resistance
CN111268983A (en) * 2019-12-02 2020-06-12 江苏吉邦材料科技有限公司 Application of closed-cell vitrified micro bubbles and light gypsum mortar using same and easy to detect bubble hollowing
CN112723907A (en) * 2021-02-01 2021-04-30 贵州中亚高科涂料有限公司 Formula and production method of high-tensile-strength plastering gypsum
CN114349453A (en) * 2021-12-31 2022-04-15 江苏吉邦材料科技有限公司 High-coating-rate light gypsum mortar

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643071A (en) * 2012-05-17 2012-08-22 浙江方远建材科技有限公司 Calcination-free desulfurized gypsum walling plastering dry-mixed mortar
BR102014002644A2 (en) * 2013-02-05 2015-12-08 Promat Res And Technology Ct Nv fire protection mortar
CN103819166A (en) * 2013-12-31 2014-05-28 安徽省美域节能环保技术应用有限公司 Quick-drying enhanced fireproof thermal mortar
CN105367030A (en) * 2015-11-06 2016-03-02 江苏尼高科技有限公司 Desulfurized-gypsum-base lightweight spraying gypsum mortar
CN108275959A (en) * 2018-03-12 2018-07-13 太原理工大学 A kind of cracking resistance plastering gupsum of high tenacity enhanced water resistance
CN111268983A (en) * 2019-12-02 2020-06-12 江苏吉邦材料科技有限公司 Application of closed-cell vitrified micro bubbles and light gypsum mortar using same and easy to detect bubble hollowing
CN112723907A (en) * 2021-02-01 2021-04-30 贵州中亚高科涂料有限公司 Formula and production method of high-tensile-strength plastering gypsum
CN114349453A (en) * 2021-12-31 2022-04-15 江苏吉邦材料科技有限公司 High-coating-rate light gypsum mortar

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Application publication date: 20220701