CN114672196A - Uv胶印温变油墨 - Google Patents

Uv胶印温变油墨 Download PDF

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CN114672196A
CN114672196A CN202011553208.8A CN202011553208A CN114672196A CN 114672196 A CN114672196 A CN 114672196A CN 202011553208 A CN202011553208 A CN 202011553208A CN 114672196 A CN114672196 A CN 114672196A
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陈鹏
秦浩文
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Hunan Jinguli Ink Coating Co ltd
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/50—Sympathetic, colour changing or similar inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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Abstract

本发明涉及新材料技术领域，具体为一种UV胶印温变油墨，包括如下重量占比的原料：温变颜料5～8％、预聚物A10～20％、预聚物B10～30％、预聚物C5～10％、丙烯酸单体10～30％、光引发剂3～8％、助剂0～5％、填料0～5％；所述预聚物A为聚酯类聚丙烯酸酯，预聚物B为环氧类聚丙烯酸酯，预聚物C为自交联聚酯类聚丙烯酸酯。本发明极大丰富了UV胶印油墨的种类，油墨胶印后能随着环境温度的变化而显示不同的颜色，从而使被着色物体具有动态变化的色彩效果。

Description

UV胶印温变油墨
技术领域
本发明涉及新材料技术领域，具体涉及一种UV胶印温变油墨。
背景技术
由于胶印机的印刷速度越来越快，印刷操作人员和印刷品用户对产品环保性能的要求也越来越高，因此要求油墨生产厂必须不段改进胶印油墨质量。要求油墨的转移性能好，着色力高、印后干燥速度快、机上不结皮时间长、油墨产品中的重金属含量低等。要达到这些要求，就必须在原料选择、配方技术、生产工艺、生产环境等方面进行改进，并对生产过程进行严格控制。
UV胶印油墨的固含量较高，而且其在固化之前颜料与连结料的比率与普通胶印油墨相仿，因此最先在胶印中得到应用。UV胶印油墨固化无渗透问题，不仅可以在纸张印刷，还可以在非吸收性承印材料上印刷。现有UV胶印油墨中常用的夜光油墨能在漆黑的条件下发亮，而光变油墨可随着光线的变化变色，然而现有技术中尚没有能随着环境的温度进行变色的UV胶印油墨，因此，亟待改进。
发明内容
本发明所解决的技术问题在于提供一种UV胶印温变油墨，以解决上述背景技术中的问题。
本发明所解决的技术问题采用以下技术方案来实现：
UV胶印温变油墨，包括如下重量占比的原料：温变颜料5～8％、预聚物A10～20％、预聚物B10～30％、预聚物C5～10％、丙烯酸单体10～30％、光引发剂3～8％、助剂0～5％、填料0～5％；所述预聚物A为聚酯类聚丙烯酸酯，预聚物B为环氧类聚丙烯酸酯，预聚物C为自交联聚酯类聚丙烯酸酯。
优选地，由如下重量占比的原料组成：温变颜料8％、预聚物A20％、预聚物B30％、预聚物C10％、丙烯酸单体20％、光引发剂8％、助剂2％、填料2％。
优选地，由如下重量占比的原料组成：温变颜料5％、预聚物A10％、预聚物B30％、预聚物C10％、丙烯酸单体30％、光引发剂5％、助剂5％、填料5％。
优选地，由如下重量占比的原料组成：温变颜料6％、预聚物A18％、预聚物B30％、预聚物C10％、丙烯酸单体30％、光引发剂3％、助剂1％、填料2％。
优选地，由如下重量占比的原料组成：温变颜料7％、预聚物A16％、预聚物B27％、预聚物C10％、丙烯酸单体28％、光引发剂8％、助剂2％、填料3％。
优选地，由如下重量占比的原料组成：温变颜料5％、预聚物A20％、预聚物B25％、预聚物C10％、丙烯酸单体28％、光引发剂8％、助剂2％、填料2％。
优选地，由如下重量占比的原料组成：温变颜料8％、预聚物A16％、预聚物B28％、预聚物C8％、丙烯酸单体22％、光引发剂8％、助剂5％、填料5％。
优选地，由如下重量占比的原料组成：温变颜料5％、预聚物A20％、预聚物B30％、预聚物C10％、丙烯酸单体22％、光引发剂8％、助剂3％、填料2％。
有益效果：本发明所述的UV胶印温变油墨，其能随着环境温度的变化而显示不同的颜色，从而使被着色物体具有动态变化的色彩效果，丰富了UV胶印油墨的种类，拓宽了市场，使应用更为广泛。
具体实施方式
为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体实施例进一步阐述本发明。
实施例1
本实施例所述的UV胶印温变油墨由如下重量占比的原料组成：温变颜料8％、预聚物A20％、预聚物B30％、预聚物C10％、丙烯酸单体20％、光引发剂8％、助剂2％、填料2％。其中预聚物A为聚酯类聚丙烯酸酯，预聚物B为环氧类聚丙烯酸酯，预聚物C为自交联聚酯类聚丙烯酸酯。
实施例2
本实施例所述的UV胶印温变油墨由如下重量占比的原料组成：温变颜料5％、预聚物A10％、预聚物B30％、预聚物C10％、丙烯酸单体30％、光引发剂5％、助剂5％、填料5％。其中预聚物A为聚酯类聚丙烯酸酯，预聚物B为环氧类聚丙烯酸酯，预聚物C为自交联聚酯类聚丙烯酸酯。
实施例3
本实施例所述的UV胶印温变油墨由如下重量占比的原料组成：由如下重量占比的原料组成：温变颜料6％、预聚物A18％、预聚物B30％、预聚物C10％、丙烯酸单体30％、光引发剂3％、助剂1％、填料2％。其中预聚物A为聚酯类聚丙烯酸酯，预聚物B为环氧类聚丙烯酸酯，预聚物C为自交联聚酯类聚丙烯酸酯。
实施例4
本实施例所述的UV胶印温变油墨由如下重量占比的原料组成：由如下重量占比的原料组成：温变颜料7％、预聚物A16％、预聚物B27％、预聚物C10％、丙烯酸单体28％、光引发剂8％、助剂2％、填料3％。其中预聚物A为聚酯类聚丙烯酸酯，预聚物B为环氧类聚丙烯酸酯，预聚物C为自交联聚酯类聚丙烯酸酯。
实施例5
本实施例所述的UV胶印温变油墨由如下重量占比的原料组成：由如下重量占比的原料组成：温变颜料5％、预聚物A20％、预聚物B25％、预聚物C10％、丙烯酸单体28％、光引发剂8％、助剂2％、填料2％。其中预聚物A为聚酯类聚丙烯酸酯，预聚物B为环氧类聚丙烯酸酯，预聚物C为自交联聚酯类聚丙烯酸酯。
实施例6
本实施例所述的UV胶印温变油墨由如下重量占比的原料组成：由如下重量占比的原料组成：温变颜料8％、预聚物A16％、预聚物B28％、预聚物C8％、丙烯酸单体22％、光引发剂8％、助剂5％、填料5％。其中预聚物A为聚酯类聚丙烯酸酯，预聚物B为环氧类聚丙烯酸酯，预聚物C为自交联聚酯类聚丙烯酸酯。
实施例7
本实施例所述的UV胶印温变油墨由如下重量占比的原料组成：由如下重量占比的原料组成：温变颜料5％、预聚物A20％、预聚物B30％、预聚物C10％、丙烯酸单体22％、光引发剂8％、助剂3％、填料2％。其中预聚物A为聚酯类聚丙烯酸酯，预聚物B为环氧类聚丙烯酸酯，预聚物C为自交联聚酯类聚丙烯酸酯。
以上显示和描述了本发明的基本原理、主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。

Claims (8)

1.UV胶印温变油墨，其特征在于，包括如下重量占比的原料：温变颜料5～8％、预聚物A10～20％、预聚物B10～30％、预聚物C5～10％、丙烯酸单体10～30％、光引发剂3～8％、助剂0～5％、填料0～5％；所述预聚物A为聚酯类聚丙烯酸酯，预聚物B为环氧类聚丙烯酸酯，预聚物C为自交联聚酯类聚丙烯酸酯。
2.根据权利要求1所述的UV胶印温变油墨，其特征在于，由如下重量占比的原料组成：温变颜料8％、预聚物A20％、预聚物B30％、预聚物C10％、丙烯酸单体20％、光引发剂8％、助剂2％、填料2％。
3.根据权利要求1所述的UV胶印温变油墨，其特征在于，由如下重量占比的原料组成：温变颜料5％、预聚物A10％、预聚物B30％、预聚物C10％、丙烯酸单体30％、光引发剂5％、助剂5％、填料5％。
4.根据权利要求1所述的UV胶印温变油墨，其特征在于，由如下重量占比的原料组成：温变颜料6％、预聚物A18％、预聚物B30％、预聚物C10％、丙烯酸单体30％、光引发剂3％、助剂1％、填料2％。
5.根据权利要求1所述的UV胶印温变油墨，其特征在于，由如下重量占比的原料组成：温变颜料7％、预聚物A16％、预聚物B27％、预聚物C10％、丙烯酸单体28％、光引发剂8％、助剂2％、填料3％。
6.根据权利要求1所述的UV胶印温变油墨，其特征在于，由如下重量占比的原料组成：温变颜料5％、预聚物A20％、预聚物B25％、预聚物C10％、丙烯酸单体28％、光引发剂8％、助剂2％、填料2％。
7.根据权利要求1所述的UV胶印温变油墨，其特征在于，由如下重量占比的原料组成：温变颜料8％、预聚物A16％、预聚物B28％、预聚物C8％、丙烯酸单体22％、光引发剂8％、助剂5％、填料5％。
8.根据权利要求1所述的UV胶印温变油墨，其特征在于，由如下重量占比的原料组成：温变颜料5％、预聚物A20％、预聚物B30％、预聚物C10％、丙烯酸单体22％、光引发剂8％、助剂3％、填料2％。
CN202011553208.8A 2020-12-24 2020-12-24 Uv胶印温变油墨 Withdrawn CN114672196A (zh)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101338096A (zh) * 2008-08-11 2009-01-07 深圳市美丽华油墨涂料有限公司 Uv固化胶印油墨及用途
CN102367339A (zh) * 2011-07-01 2012-03-07 深圳市美丽华油墨涂料有限公司 一种印刷用uv胶印油墨
CN105419461A (zh) * 2015-12-08 2016-03-23 上海杰易森股份有限公司 一种uv胶印金属油墨及其制备方法
CN109694615A (zh) * 2017-10-20 2019-04-30 吕丽霞 一种温变油墨
CN110564216A (zh) * 2019-09-30 2019-12-13 湖北中烟工业有限责任公司 一种烟用包装储能延时温变油墨及其应用

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101338096A (zh) * 2008-08-11 2009-01-07 深圳市美丽华油墨涂料有限公司 Uv固化胶印油墨及用途
CN102367339A (zh) * 2011-07-01 2012-03-07 深圳市美丽华油墨涂料有限公司 一种印刷用uv胶印油墨
CN105419461A (zh) * 2015-12-08 2016-03-23 上海杰易森股份有限公司 一种uv胶印金属油墨及其制备方法
CN109694615A (zh) * 2017-10-20 2019-04-30 吕丽霞 一种温变油墨
CN110564216A (zh) * 2019-09-30 2019-12-13 湖北中烟工业有限责任公司 一种烟用包装储能延时温变油墨及其应用

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