CN114668011B - Deodorant spray for footgear and application thereof - Google Patents
Deodorant spray for footgear and application thereof Download PDFInfo
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- CN114668011B CN114668011B CN202210336024.9A CN202210336024A CN114668011B CN 114668011 B CN114668011 B CN 114668011B CN 202210336024 A CN202210336024 A CN 202210336024A CN 114668011 B CN114668011 B CN 114668011B
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- CN
- China
- Prior art keywords
- essence
- triethanolamine
- spray
- sodium dichloroisocyanurate
- footgear
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Links
- 239000002781 deodorant agent Substances 0.000 title claims description 8
- 239000007921 spray Substances 0.000 claims abstract description 62
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 claims abstract description 46
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 42
- 230000001877 deodorizing effect Effects 0.000 claims abstract description 37
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000004332 deodorization Methods 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 28
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 28
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 28
- 239000001294 propane Substances 0.000 claims abstract description 17
- 230000001954 sterilising effect Effects 0.000 claims abstract description 16
- 239000004088 foaming agent Substances 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 72
- 239000011259 mixed solution Substances 0.000 claims description 40
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 24
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 24
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 24
- HOWJQLVNDUGZBI-UHFFFAOYSA-N butane;propane Chemical compound CCC.CCCC HOWJQLVNDUGZBI-UHFFFAOYSA-N 0.000 claims description 11
- 239000001273 butane Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 10
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000004659 sterilization and disinfection Methods 0.000 claims description 9
- 239000000686 essence Substances 0.000 claims description 2
- 240000001972 Gardenia jasminoides Species 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 18
- 230000001580 bacterial effect Effects 0.000 abstract description 14
- 239000002994 raw material Substances 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 8
- 241000233866 Fungi Species 0.000 abstract description 7
- 210000004027 cell Anatomy 0.000 abstract description 6
- 102000004190 Enzymes Human genes 0.000 abstract description 5
- 108090000790 Enzymes Proteins 0.000 abstract description 5
- 239000003242 anti bacterial agent Substances 0.000 abstract description 5
- 210000000170 cell membrane Anatomy 0.000 abstract description 5
- 210000002421 cell wall Anatomy 0.000 abstract description 5
- 230000002147 killing effect Effects 0.000 abstract description 4
- 239000003206 sterilizing agent Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 description 14
- 239000001963 growth medium Substances 0.000 description 11
- 239000008367 deionised water Substances 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 239000000725 suspension Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 7
- 238000009395 breeding Methods 0.000 description 5
- 230000001488 breeding effect Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 244000063299 Bacillus subtilis Species 0.000 description 4
- 235000014469 Bacillus subtilis Nutrition 0.000 description 4
- 241000588724 Escherichia coli Species 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000249 desinfective effect Effects 0.000 description 4
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 4
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 4
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 210000000106 sweat gland Anatomy 0.000 description 3
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 2
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 2
- OLQJQHSAWMFDJE-UHFFFAOYSA-N 2-(hydroxymethyl)-2-nitropropane-1,3-diol Chemical compound OCC(CO)(CO)[N+]([O-])=O OLQJQHSAWMFDJE-UHFFFAOYSA-N 0.000 description 2
- UIERETOOQGIECD-ARJAWSKDSA-M 2-Methyl-2-butenoic acid Natural products C\C=C(\C)C([O-])=O UIERETOOQGIECD-ARJAWSKDSA-M 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 2
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 2
- 244000111489 Gardenia augusta Species 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 210000004666 bacterial spore Anatomy 0.000 description 2
- 238000012258 culturing Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229930007744 linalool Natural products 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229940095102 methyl benzoate Drugs 0.000 description 2
- 244000000010 microbial pathogen Species 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000007823 ocimene derivatives Chemical class 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 230000035900 sweating Effects 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 description 2
- UAXOELSVPTZZQG-UHFFFAOYSA-N tiglic acid Natural products CC(C)=C(C)C(O)=O UAXOELSVPTZZQG-UHFFFAOYSA-N 0.000 description 2
- XJPBRODHZKDRCB-UHFFFAOYSA-N trans-alpha-ocimene Natural products CC(=C)CCC=C(C)C=C XJPBRODHZKDRCB-UHFFFAOYSA-N 0.000 description 2
- 240000002234 Allium sativum Species 0.000 description 1
- 208000035985 Body Odor Diseases 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 239000012880 LB liquid culture medium Substances 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 206010040904 Skin odour abnormal Diseases 0.000 description 1
- 239000005844 Thymol Substances 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 244000273928 Zingiber officinale Species 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- QZHPTGXQGDFGEN-UHFFFAOYSA-N chromene Chemical compound C1=CC=C2C=C[CH]OC2=C1 QZHPTGXQGDFGEN-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 235000004611 garlic Nutrition 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 208000006454 hepatitis Diseases 0.000 description 1
- 231100000283 hepatitis Toxicity 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000001338 necrotic effect Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 239000012137 tryptone Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/08—Amines; Quaternary ammonium compounds containing oxygen or sulfur
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention belongs to the technical field of deodorizing sprays, and particularly relates to a deodorizing spray for shoes and socks and application thereof. The invention provides a footgear deodorization spray which is prepared by combining substances such as sodium dichloroisocyanurate, triethanolamine, propane, fatty alcohol polyoxyethylene ether, essence and the like, wherein the footgear deodorization spray comprises the following raw materials in percentage by weight: 0.5-1% of sodium dichloroisocyanurate, 2-5% of triethanolamine, 1.5-13.5% of surfactant, 2-5% of foaming agent, 0.5-1% of essence and the balance of water. The invention mainly uses sodium dichloroisocyanurate and triethanolamine as sterilizing and antibacterial agents to act on cell membranes, cell walls, enzymes and the like of bacteria and fungi to destroy the growth and reproduction of the cells, thereby killing the bacteria and fundamentally solving the problems of peculiar smell and bacterial reproduction.
Description
Technical Field
The invention belongs to the technical field of deodorizing sprays, and particularly relates to a deodorizing spray for shoes and socks and application thereof.
Background
Foot odor is a common phenomenon, and more than 85% of people worldwide are plagued by foot odor according to statistics, and the generation of foot odor is always necessarily related to human body structure. The number of sweat glands in the arch of the foot is about 620 sweat glands/cm 2, and the same area of other parts of the body is only 143-339, and because the arch of the foot is more than sweat glands in other parts, when people have increased activities and are stuffy in weather, sweat can be secreted in a large quantity. The humidity and acid-base environment in the shoes after sweating provide a suitable environment for bacteria to grow and reproduce, and the necrotic horny layer of the skin provides enough nutrition for the bacteria, so that the bacteria can reproduce and decompose the horny protein in a large amount to form various metabolites and mix urea and lactic acid in sweat to generate bad odor.
Microorganisms growing in shoes after sweating mainly comprise escherichia coli, mould, fungi, candida albicans and the like, and the microorganisms not only cause the shoes and socks to continuously generate peculiar smell, but also damage foot health. Although the peculiar smell can be weakened by paying attention to foot cleaning and changing footwear, the problem is not solved from the origin, and only the sterilization and the inhibition of bacterial reproduction are realized, the deodorization can be thoroughly performed.
The deodorizing technology in the market at present is divided into physical, sensory, chemical and biological ones, and the biological deodorizing technology mainly uses the antibacterial agent to act on cell membranes, cell walls and enzymes of bacteria and fungi to destroy cell division and inhibit cell respiration and growth and reproduction, so as to kill bacteria.
Chinese patent publication No. CN106106439a discloses a spray agent for sterilization and deodorization of footwear, which is a spray agent capable of sterilization and deodorization formed by compounding triclosan, hydrogenated castor oil, a deodorant and essence, but the specific use effect of the composition is not described. The Chinese patent with publication number of CN106106439A discloses an odor removing agent, which has the functions of resisting bacteria and deodorizing by adding components such as chitosan, ginger, castor leaf, thymol and the like, but the action mechanism and the action effect of the odor removing agent are not described in detail.
Based on the technical problems, the application is urgently needed to develop a deodorizing product which has good sterilizing effect, can effectively remove peculiar smell, is safe and environment-friendly, and therefore, the aim of removing the peculiar smell and the stink of shoes and socks is fulfilled by combining substances such as sodium dichloroisocyanurate, triethanolamine, propane, fatty alcohol polyoxyethylene ether, essence and the like and designing the compound proportion.
Disclosure of Invention
Aiming at the defects in the prior art, the invention combines substances such as sodium dichloroisocyanurate, triethanolamine, propane, fatty alcohol polyoxyethylene ether, essence and the like, and aims to provide the footgear deodorizing spray, which mainly uses the sodium dichloroisocyanurate and the triethanolamine as sterilizing and antibacterial agents to act on multiple aspects such as cell membranes, cell walls, enzymes and the like of bacteria and fungi, and damages the growth and propagation of cells, thereby killing bacteria and fundamentally solving the problem of peculiar smell and bacterial propagation.
The invention also provides a method for deodorizing footwear by using the footwear deodorizing spray.
Based on the above purpose, the invention adopts the following technical scheme:
A deodorizing spray for shoes and socks is prepared from sodium dichloroisocyanurate, triethanolamine, a surfactant, a foaming agent, essence and water, wherein the mass percentages of the components are as follows: 0.5-1% of sodium dichloroisocyanurate, 2-5% of triethanolamine, 1.5-13.5% of surfactant, 2-5% of foaming agent, 0.5-1% of essence and the balance of water.
Specifically, the surfactant is two or more than two of glycerol, fatty alcohol polyoxyethylene ether and tween-20.
Specifically, the foaming agent is propane.
Specifically, the footgear deodorization spray consists of the following raw materials in percentage by weight: 0.5-1% of sodium dichloroisocyanurate, 2-5% of triethanolamine, 5-10% of glycerol, 2-5% of propane, 1-2% of fatty alcohol polyoxyethylene ether, 0.5-1.5% of tween-20, 0.5-1% of essence and the balance of water.
Preferably, the footgear deodorization spray comprises the following raw materials, by weight, 0.7-1% of sodium dichloroisocyanurate, 4-5% of triethanolamine, 8-10% of glycerol, 4-5% of propane butane, 1.6-2% of fatty alcohol polyoxyethylene ether, 1.2-1.5% of tween-20, 0.5-1% of essence, and the balance of water.
Specifically, the essence adopts gardenia essence of Jinan Yuxin chemical industry Co Ltd, the model is HX5551A, and the essence comprises 64.86% of alloy glacene, 29.33% of ocimene, 2.74% of linalool, 2.48% of trimethylol nitromethane, 0.34% of tiglic acid cis-alcohol ester and 0.25% of methyl benzoate by mass.
Further, the invention also provides a preparation method of the footgear deodorization spray, which comprises the following steps:
1) Uniformly mixing glycerol, fatty alcohol polyoxyethylene ether and sodium dichloroisocyanurate according to a proportion to obtain a mixed solution A;
2) Adding triethanolamine, tween-20, propane butane and essence into deionized water according to a certain proportion to obtain a mixed solution B;
3) Adding the mixed solution B in the step 2) into the mixed solution A in the step 1), and uniformly stirring to obtain transparent liquid, namely the footgear deodorizing spray.
Furthermore, the invention also provides application of the footgear deodorizing spray in removing footgear peculiar smell.
Furthermore, the invention also provides application of the footgear deodorization spray in bacteriostasis and sterilization of footgear.
The principle and the using effect of each component in the footgear deodorization spray are as follows:
the present invention belongs to biological deodorizing technology, and is especially one kind of sterilizing and antibacterial agent comprising sodium dichloroisocyanurate and triethanolamine and acting on cell membrane, cell wall, enzyme, etc. to destroy the growth and propagation of cell and kill bacteria. After the bacteria die, no odor is generated, so that the problems of odor and bacteria breeding are fundamentally solved.
The main active ingredients of the invention are sodium dichloroisocyanurate and triethanolamine, wherein the sodium dichloroisocyanurate is the disinfectant with the widest sterilizing spectrum, high efficiency and safety in the oxidative bactericide, can strongly kill various pathogenic microorganisms such as bacterial spores, bacterial propagules, fungi and the like, and has special effect of killing hepatitis viruses. Triethanolamine is often used as a high-quality additive and applied to various fields and high-end cosmetics to play roles of emulsification, moisture preservation, thickening and balancing. In the invention, the triethanolamine can promote the sterilization effect of the sodium dichloroisocyanurate besides the effects, and the triethanolamine can promote the release of oxygen atoms and increase the sterilization effect.
The reaction mechanism of the invention is shown as follows:
DCCNa (sodium dichloroisocyanurate) +H 2 O→HClO; hclo→hcl+o (atom);
N (CH 2CH2OH)3 (triethanolamine) +HCl→HN (CH 2CH2OH)3 Cl).
Compared with the prior art, the invention has the beneficial effects that:
The main components of the deodorant spray are sodium dichloroisocyanurate and triethanolamine, and the sodium dichloroisocyanurate is a common disinfectant, has strong oxidizing property and strong killing effect on various pathogenic microorganisms such as viruses, bacterial spores, fungi and the like, is a wide-application-range and high-efficiency disinfectant, and is mainly used for disinfecting swimming pool water, drinking water, preventive disinfection, disinfecting various public places, disinfecting breeding and the like, and also can be used for wool shrink-proof finishing, textile industry bleaching, disinfecting industrial circulating water and the like.
According to the invention, substances such as sodium dichloroisocyanurate, triethanolamine, propane, fatty alcohol polyoxyethylene ether, essence and the like are combined, and sodium dichloroisocyanurate and triethanolamine are used as sterilizing and antibacterial agents to act on cell membranes, cell walls, enzymes and the like of bacteria and fungi, so that the growth and propagation of the cells are destroyed, and bacteria are killed, and the problems of peculiar smell and bacterial propagation are fundamentally solved.
When the footgear deodorizing spray provided by the invention is used, the footgear deodorizing spray has the characteristics of quick response and remarkable deodorizing effect.
Detailed Description
In order to make the technical objects, technical solutions and advantageous effects of the present invention more apparent, the technical solutions of the present invention will be further described with reference to specific examples, which are intended to illustrate the present invention but are not to be construed as limiting the present invention, and specific techniques or conditions are not specified in the examples, and are performed according to techniques or conditions described in the literature in the art or according to the product specifications.
The essence used in the following examples was gardenia essence from Jinan Yuxin chemical Co., ltd, model HX5551A, which contains 64.86% of alloy chromene, 29.33% of ocimene, 2.74% of linalool, 2.48% of trimethylol nitromethane, 0.34% of tiglic acid cis-alcohol ester, and 0.25% of methyl benzoate by mass.
Example 1
A footgear deodorization spray comprises the following raw materials in percentage by weight: 0.5% of sodium dichloroisocyanurate, 2% of triethanolamine, 5% of glycerol, 2% of propane and butane, 1% of fatty alcohol polyoxyethylene ether, 0.5% of tween-20, 0.5% of essence and the balance of water.
The preparation method of the footgear deodorization spray comprises the following specific steps:
1) Uniformly mixing glycerol, fatty alcohol polyoxyethylene ether and sodium dichloroisocyanurate according to a proportion to obtain a mixed solution A;
2) Adding triethanolamine, tween-20, propane butane and essence into deionized water according to a certain proportion to obtain a mixed solution B;
3) Slowly adding the mixed solution B in the step 2) into the mixed solution A in the step 1), and uniformly stirring to form transparent liquid, namely the footgear deodorizing spray.
Example 2
A footgear deodorization spray comprises the following raw materials in percentage by weight: 1% of sodium dichloroisocyanurate, 5% of triethanolamine, 10% of glycerol, 5% of propane and butane, 2% of fatty alcohol polyoxyethylene ether, 1% of tween-20, 1% of essence and the balance of water.
The preparation method of the footgear deodorization spray comprises the following specific steps:
1) Uniformly mixing glycerol, fatty alcohol polyoxyethylene ether and sodium dichloroisocyanurate according to a proportion to obtain a mixed solution A;
2) Adding triethanolamine, tween-20, propane butane and essence into deionized water according to a certain proportion to obtain a mixed solution B;
3) Slowly adding the mixed solution B in the step 2) into the mixed solution A in the step 1), and uniformly stirring to form transparent liquid, namely the footgear deodorizing spray.
Example 3
A footgear deodorization spray comprises the following raw materials in percentage by weight: 0.5% of sodium dichloroisocyanurate, 5% of triethanolamine, 5% of glycerol, 2% of propane and butane, 1% of fatty alcohol polyoxyethylene ether, 0.5% of tween-20, 0.5% of essence and the balance of water.
The preparation method of the footgear deodorization spray comprises the following specific steps:
1) Uniformly mixing glycerol, fatty alcohol polyoxyethylene ether and sodium dichloroisocyanurate according to a proportion to obtain a mixed solution A;
2) Adding triethanolamine, tween-20, propane butane and essence into deionized water according to a certain proportion to obtain a mixed solution B;
3) Slowly adding the mixed solution B in the step 2) into the mixed solution A in the step 1), and uniformly stirring to form transparent liquid, namely the footgear deodorizing spray.
Example 4
A footgear deodorization spray comprises the following raw materials in percentage by weight: 0.5% of sodium dichloroisocyanurate, 5% of triethanolamine, 10% of glycerol, 2% of propane and butane, 1% of fatty alcohol polyoxyethylene ether, 0.5% of tween-20, 0.5% of essence and the balance of water.
The preparation method of the footgear deodorization spray comprises the following specific steps:
1) Uniformly mixing glycerol, fatty alcohol polyoxyethylene ether and sodium dichloroisocyanurate according to a proportion to obtain a mixed solution A;
2) Adding triethanolamine, tween-20, propane butane and essence into deionized water according to a certain proportion to obtain a mixed solution B;
3) Slowly adding the mixed solution B in the step 2) into the mixed solution A in the step 1), and uniformly stirring to form transparent liquid, namely the footgear deodorizing spray.
Example 5
A footgear deodorization spray comprises the following raw materials in percentage by weight: 0.5% of sodium dichloroisocyanurate, 5% of triethanolamine, 10% of glycerol, 5% of propane and butane, 1% of fatty alcohol polyoxyethylene ether, 0.5% of tween-20, 0.5% of essence and the balance of water.
The preparation method of the footgear deodorization spray comprises the following specific steps:
1) Uniformly mixing glycerol, fatty alcohol polyoxyethylene ether and sodium dichloroisocyanurate according to a proportion to obtain a mixed solution A;
2) Adding triethanolamine, tween-20, propane butane and essence into deionized water according to a certain proportion to obtain a mixed solution B;
3) Slowly adding the mixed solution B in the step 2) into the mixed solution A in the step 1), and uniformly stirring to form transparent liquid, namely the footgear deodorizing spray.
Example 6
A footgear deodorization spray comprises the following raw materials in percentage by weight: 0.5% of sodium dichloroisocyanurate, 5% of triethanolamine, 10% of glycerol, 5% of propane and butane, 2% of fatty alcohol polyoxyethylene ether, 0.5% of tween-20, 0.5% of essence and the balance of water.
The preparation method of the footgear deodorization spray comprises the following specific steps:
1) Uniformly mixing glycerol, fatty alcohol polyoxyethylene ether and sodium dichloroisocyanurate according to a proportion to obtain a mixed solution A;
2) Adding triethanolamine, tween-20, propane butane and essence into deionized water according to a certain proportion to obtain a mixed solution B;
3) Slowly adding the mixed solution B in the step 2) into the mixed solution A in the step 1), and uniformly stirring to form transparent liquid, namely the footgear deodorizing spray.
Example 7
A footgear deodorization spray comprises the following raw materials in percentage by weight: 0.8% of sodium dichloroisocyanurate, 5% of triethanolamine, 10% of glycerol, 5% of propane and butane, 2% of fatty alcohol polyoxyethylene ether, 0.5% of tween-20, 1.5% of essence and the balance of water.
The preparation method of the footgear deodorization spray comprises the following specific steps:
1) Uniformly mixing glycerol, fatty alcohol polyoxyethylene ether and sodium dichloroisocyanurate according to a proportion to obtain a mixed solution A;
2) Adding triethanolamine, tween-20, propane butane and essence into deionized water according to a certain proportion to obtain a mixed solution B;
3) Slowly adding the mixed solution B in the step 2) into the mixed solution A in the step 1), and uniformly stirring to form transparent liquid, namely the footgear deodorizing spray.
Example 8
A footgear deodorization spray comprises the following raw materials in percentage by weight: 0.7% of sodium dichloroisocyanurate, 5% of triethanolamine, 10% of glycerol, 5% of propane and butane, 2% of fatty alcohol polyoxyethylene ether, 0.5% of tween-20, 0.5% of essence and the balance of water.
The preparation method of the footgear deodorization spray comprises the following specific steps:
1) Uniformly mixing glycerol, fatty alcohol polyoxyethylene ether and sodium dichloroisocyanurate according to a proportion to obtain a mixed solution A;
2) Adding triethanolamine, tween-20, propane butane and essence into deionized water according to a certain proportion to obtain a mixed solution B;
3) Slowly adding the mixed solution B in the step 2) into the mixed solution A in the step 1), and uniformly stirring to form transparent liquid, namely the footgear deodorizing spray.
Application test 1 bacteriostasis test
(1) Preparing a bacterial suspension: respectively inoculating strains of escherichia coli, bacillus subtilis and staphylococcus aureus into an LB liquid culture medium, culturing in a constant-temperature shake incubator at 37 ℃ and 200r/min for 12 hours for activation, and then performing secondary inoculation activation on the strains by the same method to obtain a bacterial suspension serving as a bacteriostasis experiment; preparing an LB solid culture medium for later use, wherein the LB solid culture medium comprises the following components: tryptone: 10g/L, yeast powder: 5g/L, sodium chloride: 10g/L, agar: 1.5% -2%, ph=about 7.4;
(2) Three groups of 100mL of the above LB solid agar medium at 70℃were taken, 10mL of E.coli suspension (the initial number of bacteria in E.coli suspension was about 1X 10 3, which were purchased from Shanghai Biotech Co., ltd., cell number ATCC 8099) was added to one group of the medium, and then 1g of the sprays of examples 1 to 8 were added to the first group of the medium, respectively;
10mL of a Bacillus subtilis suspension (the initial bacterial count in the Bacillus subtilis suspension is about 1×10 3, the Bacillus subtilis is purchased from Beijing Wanja first Biotech Co., ltd., bacterial number is CMCC (B) 693501) is added into the second group of culture media, and then 1g of the spray of examples 1-8 is added into the second group of culture media respectively;
10mL of a suspension of Staphylococcus aureus (the initial number of bacteria in the suspension of Staphylococcus aureus is about 1X 10 3, which is purchased from Shanghai, biotech Co., ltd., with the bacterial number ATCC 6538) was added to the third group of culture media, and then 1g of the spray of examples 1-8 was added to the third group of culture media, respectively; after culturing for 24 hours, the number of strains in the culture medium is measured, and the sterilization effect is evaluated according to the change condition of the number of microorganisms;
And simultaneously, a blank group (without any treatment) is arranged for the culture mediums of the three groups of added bacterial suspensions, and a comparison experiment is carried out on a comparison group, wherein 1g of sodium dichloroisocyanurate solution with the mass fraction of 0.5% is only added into the culture medium of the comparison group 1, 1g of sodium dichloroisocyanurate solution with the mass fraction of 0.7% is only added into the culture medium of the comparison group 2, 1g of sodium dichloroisocyanurate solution with the mass fraction of 0.8% is only added into the culture medium of the comparison group 3, and 1g of 1% sodium dichloroisocyanurate solution is only added into the culture medium of the comparison group 4. The results are shown in Table 1 below, with the units in Table 1 being one.
TABLE 1
As can be seen from Table 1, the deodorizing sprays for footwear in examples 1 to 8 have a strong broad-spectrum sterilizing effect, and by comparing the comparative examples 1 to 4 with examples 1 to 8, it can be seen that triethanolamine has a synergistic effect on the sterilizing effect of sodium dichloroisocyanurate.
Application test 2 footwear deodorant spray deodorant test
The deodorizing sprays of the shoes and socks of examples 1-8 are used for removing the odor substances of the products in the shoes and socks, when the deodorizing sprays of the shoes and socks are used for the test, the deodorizing sprays of the shoes and socks of examples 1-8 are used for respectively spraying the deodorizing and deodorizing effects of the shoes and socks in a spray pot, and the shoes and socks with similar new and old degrees, dirt degrees and materials are selected.
The specific method comprises the following steps: the distance between the shoes and socks is 10-20cm, the spray nozzle is pressed to spray for 3-5 times, and the single spraying amount is 0.10g-0.12g. After spraying, the results are recorded respectively, and after 30 minutes, the removal effect of the product peculiar smell substances in the footwear is detected. The test was repeated 5 times, each time evaluated by 5 different laboratory workers, and 6 grades were set, and the 6 grades were specifically: 1 = no off-flavor; 2 = slightly odorous; 3 = tasty, but not irritating; 4 = having a pungent odor; 5 = strong pungent odor; 6 = intolerable taste, with blank control, test results are shown in table 2.
TABLE 2
As can be seen from Table 2, the deodorizing spray for footwear provided by the invention can effectively remove strong pungent odor such as footgear, body odor, amine smell and garbage smell generated by bacterial breeding, has stable product performance, has the characteristics of quick response and remarkable deodorizing effect, and can fundamentally solve the problem of breeding of odor and bacteria. However, the effect is not obvious, but has a certain effect on the peculiar smell (such as oil smoke smell, tobacco smell, garlic smell and the like) generated by common non-bacterial decomposed proteins and the like. The deodorizing spray for footgear provided by the invention can specifically treat peculiar smell generated by bacterial breeding, and has obvious effect of removing the peculiar smell.
Finally, what should be said is: the above embodiments are only for illustrating the technical solution of the present invention, and any equivalent replacement of the present invention and modification or partial replacement without departing from the spirit and scope of the present invention should be covered in the scope of the claims of the present invention.
Claims (6)
1. The footgear deodorization spray is characterized by being prepared from sodium dichloroisocyanurate, triethanolamine, a surfactant, a foaming agent, essence and water, wherein the weight percentages of the components are as follows: 0.5-1% of sodium dichloroisocyanurate, 2-5% of triethanolamine, 1.5-13.5% of surfactant, 2-5% of foaming agent, 0.5-1% of essence and the balance of water;
The surfactant is two or more than two of glycerol, fatty alcohol polyoxyethylene ether and tween-20;
the foaming agent is propane and butane;
the footgear deodorization spray is prepared by the following steps:
1) Uniformly mixing glycerol, fatty alcohol polyoxyethylene ether and sodium dichloroisocyanurate according to a proportion to obtain a mixed solution A;
2) Adding triethanolamine, tween-20, propane butane and essence into water according to a certain proportion to obtain a mixed solution B;
3) Adding the mixed solution B in the step 2) into the mixed solution A in the step 1), and uniformly stirring to obtain transparent liquid, namely the footgear deodorizing spray.
2. The footwear deodorization spray according to claim 1, wherein the mass percentages of the components are: 0.5-1% of sodium dichloroisocyanurate, 2-5% of triethanolamine, 5-10% of glycerol, 2-5% of propane, 1-2% of fatty alcohol polyoxyethylene ether, 0.5-1.5% of tween-20, 0.5-1% of essence and the balance of water.
3. The footwear deodorization spray according to claim 2, wherein the mass percentages of the components are: 0.7-1% of sodium dichloroisocyanurate, 4-5% of triethanolamine, 8-10% of glycerol, 4-5% of propane and butane, 1.6-2% of fatty alcohol polyoxyethylene ether, 1.2-1.5% of tween-20, 0.5-1% of essence and the balance of water.
4. A footgear deodorizing spray as claimed in any one of claims 1-3, wherein said essence is gardenia essence, model HX5551A.
5. Use of a footwear deodorant spray according to any one of claims 1 to 3 for removing footwear malodour.
6. Use of a footwear deodorant spray according to any one of claims 1 to 3 for the bacteriostasis and sterilization of footwear.
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| CN109771684A (en) * | 2017-11-14 | 2019-05-21 | 青岛凯玉盈商贸有限公司 | A kind of long-acting mould-proof deodorant |
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|---|---|---|---|---|
| CN1470171A (en) * | 2003-06-09 | 2004-01-28 | 谷增林 | Slow-release sterilizing deodourizing agent of sodium dichloroisocyanurate |
| CN102041198A (en) * | 2010-12-23 | 2011-05-04 | 成都飞机工业（集团）有限责任公司 | Instant cleaning powder |
| CN104629918A (en) * | 2013-11-14 | 2015-05-20 | 青岛锦涟鑫商贸有限公司 | Improved powerful cloth detergent |
| CN106635486A (en) * | 2016-12-24 | 2017-05-10 | 严志海 | Kitchen oil cleaning agent |
| CN109771684A (en) * | 2017-11-14 | 2019-05-21 | 青岛凯玉盈商贸有限公司 | A kind of long-acting mould-proof deodorant |
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