CN114657769A - Processing method of oil-stain-resistant shirt fabric - Google Patents
Processing method of oil-stain-resistant shirt fabric Download PDFInfo
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- CN114657769A CN114657769A CN202210257858.0A CN202210257858A CN114657769A CN 114657769 A CN114657769 A CN 114657769A CN 202210257858 A CN202210257858 A CN 202210257858A CN 114657769 A CN114657769 A CN 114657769A
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- 239000004744 fabric Substances 0.000 title claims abstract description 222
- 238000003672 processing method Methods 0.000 title claims abstract description 15
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 83
- 238000000034 method Methods 0.000 claims abstract description 59
- 229920000742 Cotton Polymers 0.000 claims abstract description 56
- 238000009990 desizing Methods 0.000 claims abstract description 52
- 230000008569 process Effects 0.000 claims abstract description 40
- 238000005406 washing Methods 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000007788 liquid Substances 0.000 claims abstract description 17
- 239000002689 soil Substances 0.000 claims abstract description 15
- 238000009999 singeing Methods 0.000 claims abstract description 11
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 7
- 238000012545 processing Methods 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims description 24
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 21
- 229910021529 ammonia Inorganic materials 0.000 claims description 20
- 239000000835 fiber Substances 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 230000009471 action Effects 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 10
- 238000005096 rolling process Methods 0.000 claims description 10
- 102000004190 Enzymes Human genes 0.000 claims description 8
- 108090000790 Enzymes Proteins 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 239000002932 luster Substances 0.000 claims description 8
- 238000010025 steaming Methods 0.000 claims description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 238000004061 bleaching Methods 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 238000002347 injection Methods 0.000 claims description 5
- 239000007924 injection Substances 0.000 claims description 5
- 239000003607 modifier Substances 0.000 claims description 5
- 239000007800 oxidant agent Substances 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 239000003223 protective agent Substances 0.000 claims description 5
- 230000001007 puffing effect Effects 0.000 claims description 5
- 239000008234 soft water Substances 0.000 claims description 5
- 239000002516 radical scavenger Substances 0.000 claims description 4
- 238000005517 mercerization Methods 0.000 abstract description 2
- 230000002035 prolonged effect Effects 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000012466 permeate Substances 0.000 description 3
- 230000004224 protection Effects 0.000 description 3
- 239000002964 rayon Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- 230000002522 swelling effect Effects 0.000 description 3
- 238000009954 braiding Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000007730 finishing process Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
- D06M11/61—Liquid ammonia
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C17/00—Fulling
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C9/00—Singeing
- D06C9/02—Singeing by flame
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/14—De-sizing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/01—Stain or soil resistance
Abstract
The invention discloses a processing method of an oil-stain-resistant shirt fabric, which comprises the following specific processes of taking a pure cotton fabric as a grey fabric, carrying out different procedures on the grey fabric, and finishing to obtain a finished fabric, wherein the different procedures comprise S1 desizing treatment, S2 high-temperature water washing, S3 mercerizing singeing, S4 liquid ammonia finishing, S5 tentering, S6 baking, and S7 preshrinking. Compared with the method of directly performing soil release finishing after mercerization, the method for processing the oil stain resistant shirt fabric has the advantages that the soil release finishing after the liquid ammonia is performed is more favorable for improving the soil release performance of the fabric, so that the oil stain resistance of the fabric is effectively improved, and the water washing resistance of the soil release performance of the fabric can be improved after a certain amount of resin cross-linking agent is added into the finishing liquid, so that the service life of the fabric is effectively prolonged.
Description
Technical Field
The invention relates to the related technical field of textile fabrics, in particular to a processing method of an oil-stain-resistant shirt fabric.
Background
Along with the increasing improvement of living standard of people, the requirements of people on clothes eating and living are qualitatively changed, especially, the pursuit of people on dressing is not limited to the requirement on the comfort level of products, the functionality of the fabric is more and more emphasized by people, the functional finishing and processing mode not only can improve the quality of the products and improve the wearing comfort experience of people, but also can improve the grade and the added value of the products, the functional finishing of the fabric comprises three-proofing finishing, ultraviolet resistance, antibacterial and deodorant finishing, mosquito-proof finishing, easy-decontamination finishing and the like, wherein the easy-decontamination finishing is more and more concerned by people in the fields of garment fabrics, kitchen cloth, dining table cloth, decorative cloth, military cloth, labor protection cloth and the like.
In the actual production process of the shirt fabric in the prior art, the easy-decontamination finishing process is inconvenient for the gray fabric, so that the dirt resistance of the fiber surface of the gray fabric is reduced, oil stain adhesion is easy to cause, and the pollutants are inconvenient to be quickly removed by a user during washing;
therefore, a processing method of the oil-stain-resistant shirt fabric is provided.
Disclosure of Invention
The invention aims to provide a processing method of an oil-stain-resistant shirt fabric, aiming at solving the problems in the background technology.
In order to achieve the purpose, the invention is realized by the following technical scheme: a processing method of an oil stain resistant shirt fabric comprises the steps of taking a pure cotton fabric as a grey fabric, carrying out different procedures on the grey fabric, and finishing to obtain a finished fabric;
the specific processes of different procedures comprise:
s1, desizing treatment: and desizing the grey cloth by a desizing process to obtain a grey cloth I, wherein the desizing process comprises enzyme desizing, alkali desizing, oxidant desizing and acid desizing.
S2, high-temperature water washing: after desizing, the first grey cloth is cleaned by hot water in time to obtain a second grey cloth, the washing speed is 50-60m/min, the water temperature of the initial washing tanks is 60-70 ℃, the water temperature of the middle washing tanks is 90 ℃, and the water temperature of the tail washing tank is 40-50 ℃.
S3, mercerizing and singeing: burning fine fluff on the surface of a second cotton fabric of the second grey fabric through an annular flame nozzle of a singeing machine, puffing molecular bond gaps and expanding cells of the second cotton fiber of the second grey fabric through a concentrated alkali process of a mercerizing machine, and enabling the surface of the second cotton fabric of the second grey fabric to become smooth and round under the action of soft water injection to obtain a third grey fabric; thereby increasing the three-fiber luster of the grey cloth and improving the brightness of the cotton fabric;
s4, liquid ammonia finishing:
the third grey cloth is firstly pre-dried by a drying cylinder and then enters a sealed box for liquid ammonia treatment, during pre-drying, the steam pressure is adjusted according to the thickness and the humidity of the fabric to ensure that most of moisture on the fabric is removed, the moisture content is controlled within a certain range, thus the liquid ammonia can be ensured to instantly enter the third grey cloth and be uniformly permeated, the three cotton fibers of the grey cloth are fully expanded in a short time, then the cooling is carried out to prevent the liquid ammonia in a rolling groove from being greatly volatilized due to overhigh temperature of the cloth surface, the liquid ammonia is padded in a sealed treatment chamber, the pressure of a padder is adjusted to control the ammonia amount of the fabric, the ammonia and the cotton fibers are fully reacted, and then the ammonia enters a steaming box to further remove residual ammonia to obtain a fourth grey cloth,
s5 tentering: padding the four pieces of grey cloth in the prepared finishing liquid on a stenter, fully penetrating the finishing liquid, wherein the rolling residual rate is 40-65%, and the process formula of the finishing liquid is as follows: the soil release finishing agent is SRF-6000, 60g/L, the resin cross-linking agent CR-E, 60g/L, the catalyst LRMC, 60g/L, 15g/L, the formaldehyde trapping agent CFF, 60g/L, 10g/L, the fiber protecting agent SF-P, 60g/L, 20g/L, the chlorine bleaching modifier RA-202, and 10 g/L.
S6, baking: preheating the dryer at the preheating temperature of 110 ℃ for 100s, and then placing the grey cloth IV on a drying rack of the dryer for baking at the baking temperature of 155 ℃ for 3 min.
And S7, preshrinking, namely preshrinking under the action of mechanical pressure through the rubber blanket to control, and preshrinking in the weft direction is realized by controlling the width of the cropping cloth.
The preshrinking process comprises the steps of (m.min-1) vehicle speed/(m.min-1) 60-70, cropping width/cm 144/147,
the density of weft in the cloth fall/(root/10 cm) 464-.
Compared with the prior art, the invention has the beneficial effects that: the processing method of the oil stain resistant shirt fabric has the characteristics of reasonable design and simplicity in operation
(1) Compared with the method that the soil release finishing is directly carried out after mercerization, the soil release finishing is carried out after the liquid ammonia, so that the soil release performance of the fabric is improved, and the oil stain resistance of the fabric is further effectively improved;
(2) after a certain amount of resin cross-linking agent is added into the finishing liquid, the washing resistance of the easy-to-decontaminate fabric can be improved, so that the service life of the fabric is effectively prolonged.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings that are required to be used in the embodiments will be briefly described below, it should be understood that the following drawings only illustrate some embodiments of the present invention and therefore should not be considered as limiting the scope, and for those skilled in the art, other related drawings can be obtained according to the drawings without inventive efforts.
Fig. 1 is a flow chart of the processing method of the oil-stain-resistant shirt fabric.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention more apparent, the technical solutions of the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings of the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all embodiments of the present invention. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, are within the scope of the present invention. Thus, the following detailed description of the embodiments of the present invention, presented in the figures, is not intended to limit the scope of the invention, as claimed, but is merely representative of selected embodiments of the invention. All other embodiments, which can be obtained by a person skilled in the art without inventive efforts based on the embodiments of the present invention, are within the scope of protection of the present invention.
Referring to fig. 1, the present invention provides a technical solution: processing method of anti-oil shirt fabric, embodiment I
Taking the pure cotton fabric as grey cloth, and finishing the grey cloth through different procedures to obtain a finished fabric;
it should be noted here that the pure cotton fabric is selected as the grey cloth of the shirt fabric to facilitate the washing of the shirt by the user, because the hydrophilic segment of the fluorine-containing soil release finishing agent cooperates with the hydrophilic group of the pure cotton fabric in an aqueous solution to minimize the interfacial energy of the fabric, and thus the dirt on the pure cotton fabric is easily separated from the fabric.
The specific process of different procedures comprises the following steps:
s1, desizing treatment: and (3) desizing the grey cloth through a desizing process to obtain the grey cloth I, wherein the desizing process comprises enzyme desizing, alkali desizing, oxidant desizing and acid desizing.
S2, high-temperature water washing: after desizing, the grey cloth I is cleaned by hot water in time to obtain a grey cloth II, impurities such as decomposition products of starch of the desized grey cloth I can be condensed on the fabric again, so that the subsequent processing process is seriously hindered, and as the conditions of the enzyme desizing process are mild, good desizing effect is obtained by intensive washing, the washing speed is 50m/min, the water temperature of the initial washing tanks is 60 ℃, the water temperature of the middle washing tanks is 90 ℃, and the water temperature of the tail washing tank is 40 ℃.
S3, mercerizing and singeing: burning fine fluff on the surface of a second cotton fabric of the second grey cloth through an annular flame jet of a singeing machine, puffing molecular bond gaps and expanding cells of the second cotton fiber of the second grey cloth through a thick alkali process of a mercerizing machine, and enabling the surface of the second cotton fabric of the second grey cloth to be smooth and round under the action of soft water injection to obtain a third grey cloth; thereby increasing the three-fiber luster of the grey cloth and improving the brightness of the cotton fabric;
s4, liquid ammonia finishing: liquid ammonia is a small-molecular, low-viscosity and high-polarity fiber swelling agent, can quickly permeate into the inner part of the rayon fiber, has uniform swelling effect, and is easy to remove. After the cotton fibers are treated by the liquid ammonia, the cross sections of the cotton fibers are round, the cavity diameters of the cotton fibers are reduced, the surfaces of the cotton fibers are smooth, the crystalline structures are changed, the internal stress is eliminated, the tensile strength and the tearing strength are improved, and the cotton fibers can still keep good hand feeling even if being repeatedly washed. For the yarn dyed fabric with higher quality requirement, soft luster, soft hand feeling, better crease resistance and higher dimensional stability can be obtained through liquid ammonia finishing, the elasticity, the wear resistance, the tearing strength and the like of the fabric can be improved, and the grade of the yarn dyed fabric is greatly improved;
the process flow comprises cloth feeding → pre-drying → cooling → liquid ammonia treatment (padding liquid ammonia → drying) → steaming → water washing → drying → cropping.
The third grey cloth is firstly pre-dried by a drying cylinder and then enters a sealed box for liquid ammonia treatment, during pre-drying, the steam pressure is adjusted according to the thickness and the humidity of the fabric to ensure that most of moisture on the fabric is removed, the moisture content is controlled within a certain range, thus the liquid ammonia can be ensured to instantly enter the third grey cloth and be uniformly permeated, the three cotton fibers of the grey cloth are fully expanded in a short time, then the cooling is carried out to prevent the liquid ammonia in a rolling groove from being greatly volatilized due to overhigh temperature of the cloth surface, the liquid ammonia is padded in a sealed treatment chamber, the pressure of a padder is adjusted to control the ammonia amount of the fabric, the ammonia and the cotton fibers are fully reacted, and then the ammonia enters a steaming box to further remove residual ammonia to obtain a fourth grey cloth,
s5 tentering: padding the fourth grey cloth in the prepared finishing liquid on a tenter, wherein the finishing liquid is fully permeated, the rolling residual rate is 40-65%, and the process formula of the finishing liquid is as follows: the soil release finishing agent SRF-6000 is used in an amount of 60g/L, the resin cross-linking agent CR-E is used in an amount of 60g/L60g/L, the catalyst LRMC is used in an amount of 60g/L15g/L, the formaldehyde scavenger CFF is used in an amount of 60g/L10g/L, the fiber protective agent SF-P is used in an amount of 60g/L20g/L, and the chlorine bleaching modifier RA-202 is used in an amount of 10 g/L.
S6, baking: preheating the dryer at the preheating temperature of 110 ℃ for 100s, and then placing the grey cloth IV on a drying rack of the dryer for baking at the baking temperature of 155 ℃ for 3 min.
And S7, preshrinking, namely preshrinking under the action of mechanical pressure through the rubber blanket to control, and preshrinking in the weft direction is realized by controlling the width of the cropping cloth.
The preshrinking process comprises the steps of vehicle speed/(m.min-1) 60, cropping width/cm 144/147,
the density of the cloth falling weft/(root/10 cm)464 and the shrinkage of the warp and weft directions is less than 3.
Example two
Taking the pure cotton fabric as grey cloth, and finishing the grey cloth through different procedures to obtain a finished fabric;
it should be noted here that the pure cotton fabric is selected as the grey cloth of the shirt fabric to facilitate the washing of the shirt by the user, because the hydrophilic segment of the fluorine-containing soil release finishing agent cooperates with the hydrophilic group of the pure cotton fabric in an aqueous solution to minimize the interfacial energy of the fabric, and thus the dirt on the pure cotton fabric is easily separated from the fabric.
The specific processes of different procedures comprise:
s1, desizing treatment: and (3) desizing the grey cloth through a desizing process to obtain the grey cloth I, wherein the desizing process comprises enzyme desizing, alkali desizing, oxidant desizing and acid desizing.
S2, high-temperature water washing: after desizing, the first grey cloth is cleaned by hot water in time to obtain a second grey cloth, the washing time is 30 minutes, impurities such as decomposition products of starch of the desized first grey cloth can be condensed on the fabric again, the subsequent processing process is seriously hindered, and the enzyme desizing process conditions are mild, so that good desizing effect is obtained, the washing is strengthened, the washing speed is 55m/min, the water temperature of the initial washing tanks is 65 ℃, the water temperature of the middle washing tanks is 90 ℃, and the water temperature of the tail washing tank is 45 ℃.
S3, mercerizing and singeing: burning fine fluff on the surface of a second cotton fabric of the second grey cloth through an annular flame jet of a singeing machine, puffing molecular bond gaps and expanding cells of the second cotton fiber of the second grey cloth through a thick alkali process of a mercerizing machine, and enabling the surface of the second cotton fabric of the second grey cloth to be smooth and round under the action of soft water injection to obtain a third grey cloth; thereby increasing the three-fiber luster of the grey cloth and improving the brightness of the cotton fabric;
s4, liquid ammonia finishing: liquid ammonia is a small-molecular, low-viscosity and high-polarity fiber swelling agent, can quickly permeate into the inner part of the rayon fiber, has uniform swelling effect, and is easy to remove. After the cotton fibers are treated by the liquid ammonia, the cross section of the cotton fibers is round, the cavity diameter is reduced, the surface is smooth, the crystalline structure is changed, the internal stress is eliminated, the tensile strength and the tearing strength are improved, and the good hand feeling can be still kept even if the cotton fibers are repeatedly washed. For yarn-dyed fabrics with higher quality requirements, soft luster, soft hand feeling, better crease resistance and higher dimensional stability can be obtained through liquid ammonia finishing, the elasticity, wear resistance, tearing strength and the like of the fabrics can be improved, and the grade of the yarn-dyed fabrics is greatly improved;
the process flow comprises cloth feeding → pre-drying → cooling → liquid ammonia treatment (padding liquid ammonia → drying) → steaming → water washing → drying → cropping.
The third grey cloth is firstly pre-dried by a drying cylinder and then enters a sealed box for liquid ammonia treatment, during pre-drying, the steam pressure is adjusted according to the thickness and the humidity of the fabric to ensure that most of moisture on the fabric is removed, the moisture content is controlled within a certain range, thus the liquid ammonia can be ensured to instantly enter the third grey cloth and be uniformly permeated, the three cotton fibers of the grey cloth are fully expanded in a short time, then the cooling is carried out to prevent the liquid ammonia in a rolling groove from being greatly volatilized due to overhigh temperature of the cloth surface, the liquid ammonia is padded in a sealed treatment chamber, the pressure of a padder is adjusted to control the ammonia amount of the fabric, the ammonia and the cotton fibers are fully reacted, and then the ammonia enters a steaming box to further remove residual ammonia to obtain a fourth grey cloth,
s5 tentering: padding the fourth grey cloth in the prepared finishing liquid on a tenter, wherein the finishing liquid is fully permeated, the rolling residual rate is 40-65%, and the process formula of the finishing liquid is as follows: the soil release finishing agent SRF-6000 is used in an amount of 60g/L, the resin cross-linking agent CR-E is used in an amount of 60g/L60g/L, the catalyst LRMC is used in an amount of 60g/L15g/L, the formaldehyde scavenger CFF is used in an amount of 60g/L10g/L, the fiber protective agent SF-P is used in an amount of 60g/L20g/L, and the chlorine bleaching modifier RA-202 is used in an amount of 10 g/L.
S6, baking: preheating the dryer at the preheating temperature of 110 ℃ for 100s, and then baking the fourth grey cloth on a drying frame of a baking machine at the baking temperature of 155 ℃ for 3 min.
And S7, preshrinking, namely preshrinking under the action of mechanical pressure through the rubber blanket to control, and preshrinking in the weft direction is realized by controlling the width of the cropping cloth.
The preshrinking process comprises the steps of vehicle speed/(m.min-1) 65, cropping width/cm 144/147,
the density of the plaiting weft/(root/10 cm)468 and the shrinkage of the warp and weft direction/% < 3.
EXAMPLE III
Taking the pure cotton fabric as grey cloth, and finishing the grey cloth through different procedures to obtain a finished fabric;
it should be noted here that the pure cotton fabric is selected as the grey cloth of the shirt fabric, which is convenient for the user to clean the shirt, because the hydrophilic segment of the fluorine-containing soil release finish cooperates with the hydrophilic group of the pure cotton fabric in an aqueous solution to minimize the interfacial energy of the fabric, and thus the dirt on the pure cotton fabric can be easily separated from the fabric.
The specific process of different procedures comprises the following steps:
s1, desizing treatment: and (3) desizing the grey cloth through a desizing process to obtain the grey cloth I, wherein the desizing process comprises enzyme desizing, alkali desizing, oxidant desizing and acid desizing.
S2, high-temperature water washing: after desizing, the grey cloth I is cleaned by hot water in time to obtain a grey cloth II, impurities such as decomposition products of starch of the desized grey cloth I can be condensed on the fabric again, so that the subsequent processing process is seriously hindered, and because the conditions of the enzyme desizing process are mild, the water washing speed is 60m/min, the water temperature of the initial washing tanks is 70 ℃, the water temperature of the middle washing tanks is 90 ℃, and the water temperature of the tail washing tank is 50 ℃ to obtain a good desizing effect.
S3, mercerizing and singeing: burning fine fluff on the surface of a second cotton fabric of the second grey cloth through an annular flame jet of a singeing machine, puffing molecular bond gaps and expanding cells of the second cotton fiber of the second grey cloth through a thick alkali process of a mercerizing machine, and enabling the surface of the second cotton fabric of the second grey cloth to be smooth and round under the action of soft water injection to obtain a third grey cloth; thereby increasing the three-fiber luster of the grey cloth and improving the brightness of the cotton fabric;
s4, liquid ammonia finishing: liquid ammonia is a small-molecule, low-viscosity and high-polarity fiber swelling agent, can quickly permeate into the inner part of the rayon fiber, has uniform swelling effect, and is easy to remove. After the cotton fibers are treated by the liquid ammonia, the cross section of the cotton fibers is round, the cavity diameter is reduced, the surface is smooth, the crystalline structure is changed, the internal stress is eliminated, the tensile strength and the tearing strength are improved, and the good hand feeling can be still kept even if the cotton fibers are repeatedly washed. For yarn-dyed fabrics with higher quality requirements, soft luster, soft hand feeling, better crease resistance and higher dimensional stability can be obtained through liquid ammonia finishing, the elasticity, wear resistance, tearing strength and the like of the fabrics can be improved, and the grade of the yarn-dyed fabrics is greatly improved;
the process flow comprises cloth feeding → pre-drying → cooling → liquid ammonia treatment (padding liquid ammonia → drying) → steaming → water washing → drying → cropping.
The third grey cloth is firstly pre-dried by a drying cylinder and then enters a sealed box for liquid ammonia treatment, during pre-drying, the steam pressure is adjusted according to the thickness and the humidity of the fabric to ensure that most of moisture on the fabric is removed, the moisture content is controlled within a certain range, thus the liquid ammonia can be ensured to instantly enter the third grey cloth and be uniformly permeated, the three cotton fibers of the grey cloth are fully expanded in a short time, then the cooling is carried out to prevent the liquid ammonia in a rolling groove from being greatly volatilized due to overhigh temperature of the cloth surface, the liquid ammonia is padded in a sealed treatment chamber, the pressure of a padder is adjusted to control the ammonia amount of the fabric, the ammonia and the cotton fibers are fully reacted, and then the ammonia enters a steaming box to further remove residual ammonia to obtain a fourth grey cloth,
s5 tentering: padding the fourth grey cloth in the prepared finishing liquid on a tenter, wherein the finishing liquid is fully permeated, the rolling residual rate is 40-65%, and the process formula of the finishing liquid is as follows: the soil release finishing agent SRF-6000 is used in an amount of 60g/L, the resin cross-linking agent CR-E is used in an amount of 60g/L60g/L, the catalyst LRMC is used in an amount of 60g/L15g/L, the formaldehyde scavenger CFF is used in an amount of 60g/L10g/L, the fiber protective agent SF-P is used in an amount of 60g/L20g/L, and the chlorine bleaching modifier RA-202 is used in an amount of 10 g/L.
S6, baking: preheating the dryer at the preheating temperature of 110 ℃ for 100s, and then placing the grey cloth IV on a drying rack of the dryer for baking at the baking temperature of 155 ℃ for 3 min.
And S7, preshrinking, namely preshrinking under the action of mechanical pressure through the rubber blanket to control, and preshrinking in the weft direction is realized by controlling the width of the cropping cloth.
The preshrinking process comprises the steps of vehicle speed/(m.min-1) 70, cropping width/cm 144/147,
the density of the plaiting weft/(root/10 cm)472 and the shrinkage of the warp and weft directions are less than 3.
In the above examples, the reference standards employed in the steps are as follows:
easy detergency: with AATCC 130: 2000 "detergency: oil stain removal method and JIS L1919 "method for testing fiber product for stain repellency" C-2 method.
Breaking strength: using a JISL 1096: 20108.14.1B test method for breaking strength and elongation of fabric.
Tearing strength: using a JISL 1096: 20108.17.4D test method for tear Strength of Fabric.
Content of formaldehyde: JISL 1041 is adopted; 2011/8.1.4B & lt testing method for free formaldehyde & gt.
Finishing durability and appearance after washing: JIS L0217: 1995103.
Whiteness: measured by a Datacolor-650 computer color measuring and matching instrument.
The device obtained through the design can basically solve the problems that in the actual production process of shirt fabric in the prior art, the gray fabric is inconvenient to carry out a stain-removing finishing process, the stain resistance of the fiber surface of the gray fabric is further reduced, oil stain adhesion is easily caused, and pollutants of a user are inconvenient to use in the rapid removal process during washing.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (6)
1. A processing method of an oil-stain-resistant shirt fabric is characterized by comprising the following steps: the pure cotton fabric is used as grey fabric, and the finished fabric is obtained after the grey fabric is subjected to different procedures and finishing processing.
The specific processes of different procedures comprise:
s1, desizing treatment: desizing the grey cloth through a desizing process to obtain a grey cloth I;
s2, high-temperature water washing: after desizing, the grey cloth I is cleaned by hot water in time to obtain grey cloth II;
s3, mercerizing and singeing: burning fine fluff on the surface of a second cotton fabric of the second grey fabric through an annular flame nozzle of a singeing machine, puffing molecular bond gaps and expanding cells of the second cotton fiber of the second grey fabric through a concentrated alkali process of a mercerizing machine, and enabling the surface of the second cotton fabric of the second grey fabric to become smooth and round under the action of soft water injection to obtain a third grey fabric; thereby increasing the three-fiber luster of the grey cloth and improving the brightness of the cotton fabric;
s4, liquid ammonia finishing: the third gray fabric is pre-dried by a drying cylinder and then enters a sealed box for liquid ammonia treatment, during pre-drying, the steam pressure is adjusted according to the thickness and the humidity of the fabric to ensure that most of moisture on the fabric is removed, the moisture content is controlled within a certain range, so that the liquid ammonia can be instantly entered into the third gray fabric and uniformly permeated, the three cotton fibers of the gray fabric are fully expanded in a short time, then the cooling is carried out to prevent the liquid ammonia in a rolling groove from being greatly volatilized due to overhigh temperature of a fabric surface, the liquid ammonia is padded in a sealed treatment chamber, the ammonia carrying amount of the fabric is controlled by adjusting the pressure of a padder, the ammonia and the cotton fibers are fully reacted, and then the ammonia enters a steaming box to further remove residual ammonia, and a fourth gray fabric is obtained;
s5 tentering: padding the fourth gray fabric in the prepared finishing liquid through a stenter, wherein the finishing liquid is fully permeated, and the rolling allowance rate is 40-65%;
s6, baking: preheating a dryer, and then placing the fourth grey cloth on a drying frame of a baking machine for baking;
and S7, preshrinking, namely preshrinking under the action of mechanical pressure through the rubber blanket to control, and preshrinking in the weft direction is realized by controlling the width of the cropping cloth.
2. The processing method of the oil-stain-resistant shirt fabric according to claim 1, characterized by comprising the following steps: the desizing process described in S1 is enzyme desizing, alkali desizing, oxidant desizing, and acid desizing.
3. The processing method of the oil-stain-resistant shirt fabric according to claim 1, wherein the washing speed in S2 is 50-60m/min, the water temperature in the initial washing tanks is 60-70 ℃, the water temperature in the middle washing tanks is 90 ℃, and the water temperature in the tail washing tank is 40-50 ℃.
4. The processing method of the oil-stain-resistant shirt fabric according to claim 3, wherein the process formula of the finishing liquid in S5 is as follows: the soil release finishing agent SRF-6000 is used in an amount of 60g/L, the resin cross-linking agent CR-E is used in an amount of 60g/L60g/L, the catalyst LRMC is used in an amount of 60g/L15g/L, the formaldehyde scavenger CFF is used in an amount of 60g/L10g/L, the fiber protective agent SF-P is used in an amount of 60g/L20g/L, and the chlorine bleaching modifier RA-202 is used in an amount of 10 g/L.
5. The method for processing the oil-stain-resistant shirt fabric according to claim 4, wherein the preheating temperature in the step S6 is 110 ℃ and the time is 100S.
6. The processing method of the oil-stain-resistant shirt fabric according to claim 5, wherein the baking temperature in S6 is 155 ℃ and the baking time is 3 min.
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