CN114656994A - New energy biofuel oil formula - Google Patents
New energy biofuel oil formula Download PDFInfo
- Publication number
- CN114656994A CN114656994A CN202210381352.0A CN202210381352A CN114656994A CN 114656994 A CN114656994 A CN 114656994A CN 202210381352 A CN202210381352 A CN 202210381352A CN 114656994 A CN114656994 A CN 114656994A
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- Prior art keywords
- catalyst
- methanol
- gasoline
- oil
- new energy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002551 biofuel Substances 0.000 title claims abstract description 37
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 111
- 239000003054 catalyst Substances 0.000 claims abstract description 37
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000003502 gasoline Substances 0.000 claims abstract description 30
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 24
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims abstract description 20
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 9
- 238000009472 formulation Methods 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 230000007797 corrosion Effects 0.000 abstract description 14
- 238000005260 corrosion Methods 0.000 abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- 238000002485 combustion reaction Methods 0.000 abstract description 10
- 239000002184 metal Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 239000003921 oil Substances 0.000 abstract description 7
- 230000006872 improvement Effects 0.000 abstract description 6
- 230000009471 action Effects 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 5
- 230000007547 defect Effects 0.000 abstract description 3
- 230000003381 solubilizing effect Effects 0.000 abstract description 3
- 239000003112 inhibitor Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 3
- 239000003086 colorant Substances 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
- C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention provides a new energy biofuel oil formula, which is prepared from the following raw materials in percentage by weight: 80-83% of methanol, 2-5% of catalyst and 15% of gasoline. According to the bio-fuel oil, methanol and gasoline are mixed under the action of the catalyst prepared from n-butyl alcohol, isopropanol, isoamylol and triethanolamine, so that on one hand, the stability of the mixed methanol and gasoline is enhanced by using the unique solubilizing technology of the catalyst, the layering phenomenon is avoided, the blending quality of the bio-fuel oil is greatly improved, on the other hand, the defects of poor combustion effect and easiness in causing corrosion to a metal container in the using process of the bio-fuel oil can be effectively avoided by means of the super-water resistance, corrosion resistance, environment adaptability and special heat value improvement performance of the catalyst, and the transportation quality and the using performance of the bio-fuel oil are greatly improved.
Description
Technical Field
The invention belongs to the technical field of biofuel preparation, and particularly relates to a new energy biofuel formula.
Background
At present, fossil energy such as coal, oil and natural gas is the main energy used in production and life, and the fossil energy generates pollutants such as CO2, SO2 and NOx easily after being combusted.
However, the existing biofuel oil is mainly prepared by blending methanol with international gasoline product through a catalyst, the blended biofuel oil is easy to generate layering phenomenon in use due to poor solubilizing capability of the catalyst in the biofuel oil, and meanwhile, the blended biofuel oil is poor in combustion effect in use due to poor water resistance, corrosion resistance and heat value improvement performance of the catalyst in the biofuel oil, and is easy to corrode the surface of a metal container, so that the use effect of the biofuel oil is greatly reduced.
Disclosure of Invention
In view of the above, the invention aims to provide a new energy biofuel oil formula, methanol and gasoline are mixed under the action of a catalyst prepared from n-butyl alcohol, isopropanol, isoamyl alcohol and triethanolamine, on one hand, the stability of the methanol and gasoline after mixing is enhanced by using a unique solubilizing technology of the catalyst, the layering phenomenon is avoided, the blending quality of the biofuel oil is greatly improved, on the other hand, the defects of poor combustion effect and easy corrosion to a metal container in the use process of the biofuel oil can be effectively avoided by means of the super-strong water resistance, the corrosion resistance, the environmental adaptability and the special heat value of the catalyst, and the transportation quality and the use performance of the biofuel oil are greatly improved.
In order to achieve the purpose, the technical scheme of the invention is realized as follows:
the new energy biofuel oil formula is prepared from the following raw materials in percentage by weight: 80-83% of methanol, 2-5% of catalyst and 15% of gasoline.
Further, the catalyst is prepared from n-butanol, isopropanol, isoamylol and triethanolamine according to the ratio of 53:25:12: 10.
Further, the catalyst has the following characteristics: 1. the unique dissolving assisting technology enhances the stability, enables the methanol to be organically dissolved with the gasoline, does not delaminate or emulsify, and is infinitely compatible with the international gasoline; 2. the water-resistant performance is super strong, and the water absorbed into the air in the processes of transportation, storage, filling and the like can be resisted; 3. the corrosion inhibitor has good corrosion resistance, and can generate chemical and physical actions through the strong action of alkaline genes in the molecules of the corrosion inhibitor on the metal surface to form a good protective film, so that the contact between methanol and a metal device is isolated to a certain extent to achieve the purpose of reducing or inhibiting corrosion; 4. the high-temperature environment adaptability is realized, the high-temperature environment-friendly oil-water separator can be normally produced and used in an environment of (-40 ℃ -40 ℃), oil and water separation is resisted, the low temperature is easy to start, and the high temperature does not cause air resistance; 5. the special heat value improving technology improves the heat value by changing the characteristics of the methanol, and simultaneously promotes the integral improvement of the combustion rate and the heat efficiency according to the characteristic of high latent heat of gasification of the methanol, so that the fuel also generates the combustion effect of national standard gasoline in the combustion process, improves the power and reduces the oil consumption; 6. the colors can be blended with pigments according to the needs of the user.
Further, the gasoline is international finished gasoline.
The preparation method of the biofuel oil comprises the following steps:
step (1): preparing a 2kg plastic container, adding 1000kg methanol into the 2kg plastic container;
step (2): preparing a 10kg plastic container, adding a catalyst into the 10kg plastic container according to the proportion of 53% of n-butyl alcohol, 25% of isopropanol, 12% of isoamyl alcohol and 10% of triethanolamine, and uniformly stirring the n-butyl alcohol, the isopropanol, the isoamyl alcohol and the triethanolamine to prepare the catalyst for later use;
and (3): taking 2-5kg of the catalyst prepared in the step (2), adding the taken catalyst into the methanol in the step (1), and uniformly stirring to prepare methanol oil for later use;
and (4): blending the methanol oil prepared in the step (3) with gasoline according to the ratio of 85:15 to obtain the biofuel oil.
Further, the stirring time in the step (3) is 30 minutes, so that the sufficient mixing of the catalyst and the methanol can be ensured, the wireless compatibility of the methanol gasoline can be ensured through the catalyst, and the transportation of the methanol gasoline is facilitated.
Compared with the prior art, the biofuel oil provided by the invention has the following advantages:
according to the biofuel oil, methanol and gasoline are mixed under the action of the catalyst prepared from n-butyl alcohol, isopropanol, isoamylol and triethanolamine, so that the stability of the mixed methanol and gasoline is enhanced by using the unique dissolving assisting technology of the catalyst, the layering phenomenon is avoided, the blending quality of the biofuel oil is greatly improved, and the defects of poor combustion effect and easiness in corroding a metal container in the use process of the biofuel oil can be effectively avoided by means of the super-strong water resistance, corrosion resistance, environment adaptability and special heat value improvement performance of the catalyst, so that the transportation quality and the use performance of the biofuel oil are greatly improved.
Detailed Description
Unless defined otherwise, technical terms used in the following examples have the same meanings as commonly understood by one of ordinary skill in the art to which the present invention belongs.
The present invention will be described in detail below.
The new energy biofuel oil formula is prepared from the following raw materials in percentage by weight: 80-83% of methanol, 2-5% of catalyst and 15% of gasoline.
In this example, the catalyst is prepared from n-butanol, isopropanol, isoamyl alcohol, and triethanolamine in a ratio of 53:25:12: 10.
In this example, the catalyst has the following characteristics: 1. the unique dissolving assisting technology enhances the stability, enables the methanol to be organically dissolved with the gasoline, does not delaminate or emulsify, and is infinitely compatible with the international gasoline; 2. the water-resistant performance is super strong, and the water absorbed into the air in the processes of transportation, storage, filling and the like can be resisted; 3. the corrosion inhibitor has good corrosion resistance, and can generate chemical and physical actions through the strong action of alkaline genes in the molecules of the corrosion inhibitor on the metal surface to form a good protective film, so that the contact between methanol and a metal device is isolated to a certain extent to achieve the purpose of reducing or inhibiting corrosion; 4. the high-temperature environment adaptability is realized, the high-temperature environment-friendly oil-water separator can be normally produced and used in an environment of (-40 ℃ -40 ℃), oil and water separation is resisted, the low temperature is easy to start, and the high temperature does not cause air resistance; 5. the special heat value improving technology improves the heat value by changing the characteristics of the methanol, and simultaneously promotes the integral improvement of the combustion rate and the heat efficiency according to the characteristic of high latent heat of gasification of the methanol, so that the fuel also generates the combustion effect of national standard gasoline in the combustion process, improves the power and reduces the oil consumption; 6. the colors can be blended with pigments according to the needs of the user.
In this embodiment, the gasoline is international finished gasoline.
The preparation method of the biofuel oil comprises the following steps:
step (1): preparing a 2kg plastic container, adding 1000kg methanol into the 2kg plastic container;
step (2): preparing a 10kg plastic container, adding a catalyst into the 10kg plastic container according to the proportion of 53% of n-butyl alcohol, 25% of isopropanol, 12% of isoamyl alcohol and 10% of triethanolamine, and uniformly stirring the n-butyl alcohol, the isopropanol, the isoamyl alcohol and the triethanolamine to prepare the catalyst for later use;
and (3): taking 2-5kg of the catalyst prepared in the step (2), adding the taken catalyst into the methanol in the step (1), and uniformly stirring to prepare methanol oil for later use;
and (4): blending the methanol oil prepared in the step (3) with gasoline according to the ratio of 85:15 to obtain the biofuel oil.
In this embodiment, the stirring time in step (3) is 30 minutes, which can ensure sufficient mixing of the catalyst and the methanol, so as to ensure wireless compatibility of the methanol gasoline by the catalyst, and facilitate transportation of the methanol gasoline.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.
Claims (5)
1. The new energy biofuel formula is characterized in that: the biofuel oil is prepared from the following raw materials in percentage by weight: 80-83% of methanol, 2-5% of catalyst and 15% of gasoline.
2. The new energy biofuel oil formulation according to claim 1, characterized in that: the catalyst is prepared from n-butanol, isopropanol, isoamylol and triethanolamine according to the ratio of 53:25:12: 10.
3. The new energy biofuel oil formulation according to claim 1, characterized in that: the gasoline is international finished gasoline.
4. The new energy biofuel formulation of any one of claims 1-3, characterized in that: the method comprises the following steps:
step (1): preparing a 2kg plastic container, adding 1000kg methanol into the 2kg plastic container;
step (2): preparing a 10kg plastic container, adding a catalyst into the 10kg plastic container according to the proportion of 53% of n-butyl alcohol, 25% of isopropanol, 12% of isoamyl alcohol and 10% of triethanolamine, and uniformly stirring the n-butyl alcohol, the isopropanol, the isoamyl alcohol and the triethanolamine to prepare the catalyst for later use;
and (3): taking 2-5kg of the catalyst prepared in the step (2), adding the taken catalyst into the methanol in the step (1), and uniformly stirring to prepare methanol oil for later use;
and (4): blending the methanol oil prepared in the step (3) with gasoline according to the ratio of 85:15 to obtain the biofuel oil.
5. The new energy biofuel oil formulation according to claim 4, characterized in that: the stirring time in the step (3) is 30 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210381352.0A CN114656994A (en) | 2022-04-13 | 2022-04-13 | New energy biofuel oil formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210381352.0A CN114656994A (en) | 2022-04-13 | 2022-04-13 | New energy biofuel oil formula |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114656994A true CN114656994A (en) | 2022-06-24 |
Family
ID=82034440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210381352.0A Pending CN114656994A (en) | 2022-04-13 | 2022-04-13 | New energy biofuel oil formula |
Country Status (1)
| Country | Link |
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| CN (1) | CN114656994A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101818084A (en) * | 2010-04-09 | 2010-09-01 | 陈广宇 | Clean gasoline and clean diesel oil |
| CN102295962A (en) * | 2011-08-01 | 2011-12-28 | 长安大学 | High-proportion methanol gasoline additive |
| CN102786993A (en) * | 2011-05-20 | 2012-11-21 | 北京化工大学 | Low-ratio methanol gasoline for automobiles |
| CN103160344A (en) * | 2011-12-12 | 2013-06-19 | 杨军 | Large-proportion methanol gasoline catalyst and preparation method |
| CN107384490A (en) * | 2017-09-01 | 2017-11-24 | 于仰坤 | A kind of biogasoline containing additive and its preparation method and application |
-
2022
- 2022-04-13 CN CN202210381352.0A patent/CN114656994A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101818084A (en) * | 2010-04-09 | 2010-09-01 | 陈广宇 | Clean gasoline and clean diesel oil |
| CN102786993A (en) * | 2011-05-20 | 2012-11-21 | 北京化工大学 | Low-ratio methanol gasoline for automobiles |
| CN102295962A (en) * | 2011-08-01 | 2011-12-28 | 长安大学 | High-proportion methanol gasoline additive |
| CN103160344A (en) * | 2011-12-12 | 2013-06-19 | 杨军 | Large-proportion methanol gasoline catalyst and preparation method |
| CN107384490A (en) * | 2017-09-01 | 2017-11-24 | 于仰坤 | A kind of biogasoline containing additive and its preparation method and application |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220624 |
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| RJ01 | Rejection of invention patent application after publication |