CN102382691B - Highly clean biodiesel - Google Patents
Highly clean biodiesel Download PDFInfo
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- CN102382691B CN102382691B CN2010102666362A CN201010266636A CN102382691B CN 102382691 B CN102382691 B CN 102382691B CN 2010102666362 A CN2010102666362 A CN 2010102666362A CN 201010266636 A CN201010266636 A CN 201010266636A CN 102382691 B CN102382691 B CN 102382691B
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- Prior art keywords
- oil
- abrasive
- biofuel
- additive
- diesel oil
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Abstract
The invention especially relates to highly clean biodiesel, which belongs to the technical field of clean fuels. The biodiesel comprises the following raw materials by weight: 20% to 50% of diesel oil, 5% to 25% of biomass alcohol, 5% to 25% of plant oil, 5% to 15% of kerosene, 5% to 15% of aliphatic acid, 3% to 10% of an additive and water. The highly clean biodiesel provided in the invention has the advantages of complete combustion, no toxicity, slight smoke, high combustion efficiency, no pollution to environment, cleanness, environmental protection, wide and easily available main raw materials, low cost for the raw materials, a cost 4/5 of liquefied petroleum gas or diesel oil and a cheap price, enables a fuel cost to be saved by 10% to 25%, and is economical and practical. The biodiesel provided in the invention can be used to substitute diesel oil, is applicable to power generation, and is used in diesel powered motor vehicles and in boilers in restaurants, hotels and dining rooms. The biodiesel does not blast during combustion and is safe to transport and store.
Description
Technical field
The invention belongs to the clean fuel technical field, particularly a kind of abrasive biofuel.
Background technology
The world today, national governments, for the problem that the reply petroleum resources are short and global climate warms, have taked many measures.Particularly the Chinese government will develop the strategic position that substitute energy is included national energy security in, and formulate " about developing the instruction of substitute energy ".This can Optimization of Energy Structure, accelerates the research and development paces of new forms of energy and the alternative energy, alleviates the fossil energy imbalance between supply and demand, alleviates petroleum import pressure.For alleviating the resource environment constraint, ensure energy security, promote China's sustainable economic development to there is very important large meaning.
At present China's substitute energy development is still in the starting stage, methanol gasoline, alcohol fuel, coal-based alternative fuel and biomass propellant combination all in disperseing, during the research and development of miniaturization, these substitute energy efficiencies of combustion are low, price is high.Distance " the year two thousand twenty realize new and renewable sources of energy account for China's primary energy source total quantity consumed 20% " target is far away.
Summary of the invention
The object of the invention is to provides a kind of abrasive biofuel for the deficiencies in the prior art, and its efficiency of combustion is high, and clean environment firendly, and low price are economical and practical.
The object of the present invention is achieved like this.
A kind of abrasive biofuel, it comprises the raw material of following weight percent:
Diesel oil 20%~50%
Biomass alcohol 5%~25%
Vegetables oil 5%~25%
Kerosene 5%~15%
Lipid acid 5%~15%
Additive 3%~10%.
Preferably, a kind of abrasive biofuel, it comprises the raw material of following weight percent:
Diesel oil 20%~50%
Biomass alcohol 5%~25%
Vegetables oil 5%~25%
Kerosene 5%~15%
Lipid acid 5%~15%
Additive 3%~10%
Water 1%~30%.
Preferably, a kind of abrasive biofuel, it comprises the raw material of following weight percent:
Diesel oil 20%~45%
Biomass alcohol 10%~25%
Vegetables oil 5%~20%
Kerosene 8%~15%
Lipid acid 8%~15%
Additive 5%~10%.
More preferably, a kind of abrasive biofuel, it comprises the raw material of following weight percent:
Diesel oil 30%~40%
Biomass alcohol 10%~25%
Vegetables oil 10%~20%
Kerosene 10%~15%
Lipid acid 5%~10%
Additive 5%~10%
Water 5%~25%.
More preferably, a kind of abrasive biofuel, it comprises the raw material of following weight percent:
Diesel oil 30%
Biomass alcohol 20%
Vegetables oil 15%
Kerosene 12%
Lipid acid 7%
Additive 8%
Water 8%.
Wherein, described biomass alcohol is industrial methanol or industrial alcohol, and methyl alcohol or ethanol are from the byproduct in chemical plant or fertilizer plant or brewery or pharmaceutical factory or sugar refinery.Use above-mentioned byproduct as methyl alcohol or ethanol raw material, raw material sources extensively are easy to get, and cost is low and save national resources; Utilize the oxygen in methanol molecules, C imperfect combustion in diesel oil, H compound are burnt fully, improved efficiency of combustion, and can not explode.
Wherein, described vegetables oil is one or more in rapeseed oil, Oleum Cocois, Viscotrol C, Oleum Gossypii semen, tea-seed oil, soybean oil.
Wherein, described additive comprises the raw material of following weight percent: isopropylcarbinol 10%~20%, nitric acid isooctyl 1%~5%, thanomin 1%~5%, diesel oil stabilizing agent 1%~3%, ammoniacal liquor 20%~40%, hexahydroaniline 10%~20%, carbon 9 10%~42%, cetane number improver 1%~3%, sherwood oil 10%~20%, ferrocene 1%~2%.Cetane number improver is selected amyl nitrate or methylcarbonate.Above-mentioned raw materials is mixed and makes additive.
A kind of preparation method of abrasive biofuel is as follows: at normal temperatures and pressures, by the raw material of above-mentioned weight percent, be sequentially added in reactor, stir 20 minutes~30 minutes by the agitator high speed shear, get product after filtration.
Beneficial effect of the present invention: a kind of abrasive biofuel of the present invention, it comprises the raw material of following weight percent: diesel oil 20%~50%, biomass alcohol 5%~25% vegetables oil 5%~25%, kerosene 5%~15%, lipid acid 5%~15%, additive 3%~10% and water.A kind of abrasive biofuel of the present invention, sufficient combustion and nontoxic, micro-cigarette, efficiency of combustion is high, free from environmental pollution, clean environment firendly, the main raw material wide material sources are easy to get, raw materials cost is low, and its cost is 4/5 of liquefied petroleum gas (LPG) or diesel oil, and fuel economy takes 10%~25%, low price is economical and practical.The present invention can diesel oil substitute, for generating with use at diesel car, also can in the boiler in restaurant, hotel, dining room, use.When burning, the present invention can not explode, and also safer when transportation and storage.
Embodiment
Below with specific embodiment, the present invention is further illustrated, but the present invention is not subject to the restriction of following embodiment.
Embodiment 1.
A kind of abrasive biofuel, its preparation process is as follows.
Step 1: prepare additive.
Isopropylcarbinol 10%, nitric acid isooctyl 5%, thanomin 4%, diesel oil stabilizing agent 1%, ammoniacal liquor 35%, hexahydroaniline 20%, carbon 9 10%, cetane number improver 3%, sherwood oil 10%, ferrocene 2% are mixed and make additive, standby.
Step 2: prepare a kind of abrasive biofuel of the present invention.
Get diesel oil 30 grams, methyl alcohol 13 grams, Viscotrol C 5 grams, Oleum Cocois 5 grams, soybean oil 3 grams, kerosene 12 grams, lipid acid 7 grams, additive 5 grams prepared by step 1, water 20 grams.At normal temperatures and pressures, by the raw material of above-mentioned weight percent, be sequentially added in reactor, stir 20 minutes~30 minutes by the agitator high speed shear, get product after filtration.
Abrasive biofuel prepared by the present embodiment, can be used as the boiler of fuel for restaurant, hotel, dining room.
Embodiment 2.
A kind of abrasive biofuel, its preparation process is as follows.
Step 1: prepare additive.
Isopropylcarbinol 12%, nitric acid isooctyl 4%, thanomin 2%, diesel oil stabilizing agent 1%, ammoniacal liquor 38%, hexahydroaniline 14%, carbon 9 15%, cetane number improver 1%, sherwood oil 12%, ferrocene 1% are mixed and make additive, standby.
Step 2: prepare a kind of abrasive biofuel of the present invention.
Get diesel oil 20 grams, ethanol 20 grams, rapeseed oil 9 grams, Oleum Cocois 16 grams, kerosene 5 grams, lipid acid 7 grams, additive 3 grams prepared by step 1, water 20 grams.At normal temperatures and pressures, by the raw material of above-mentioned weight percent, order adds in reactor, by the agitator high speed shear, stirs 20 minutes~30 minutes, after filtration, gets product.
Abrasive biofuel prepared by the present embodiment, can be used as the boiler of fuel for restaurant, hotel, dining room.
Embodiment 3.
A kind of abrasive biofuel, its preparation process is as follows.
Step 1: prepare additive.
Isopropylcarbinol 15%, nitric acid isooctyl 3%, thanomin 3%, diesel oil stabilizing agent 2%, ammoniacal liquor 20%, hexahydroaniline 15%, carbon 9 30%, cetane number improver 1%, sherwood oil 10%, ferrocene 1% are mixed and make additive, standby.
Step 2: prepare a kind of abrasive biofuel of the present invention.
Get diesel oil 45 grams, methyl alcohol 12 grams, Viscotrol C 20 grams, kerosene 5 grams, lipid acid 5 grams, additive 8 grams prepared by step 1, water 5 grams.At normal temperatures and pressures, by the raw material of above-mentioned weight percent, order adds in reactor, by the agitator high speed shear, stirs 20 minutes~30 minutes, after filtration, gets product.
Abrasive biofuel prepared by the present embodiment is moisture below 20%, can be used as fuel for generating.
Embodiment 4.
A kind of abrasive biofuel, its preparation process is as follows.
Step 1: prepare additive.
Isopropylcarbinol 16%, nitric acid isooctyl 2%, thanomin 1%, diesel oil stabilizing agent 1%, ammoniacal liquor 25%, hexahydroaniline 12%, carbon 9 25%, cetane number improver 2%, sherwood oil 15%, ferrocene 1% are mixed and make additive, standby.
Step 2: prepare a kind of abrasive biofuel of the present invention
Get diesel oil 40 grams, methyl alcohol 15 grams, Viscotrol C 12 grams, kerosene 5 grams, lipid acid 6 grams, additive 14 grams prepared by step 1, water 8 grams.At normal temperatures and pressures, be sequentially added in proportion in reactor, carry out high speed shear with machinery and stir 20 minutes~30 minutes, get product after filtration.
Abrasive biofuel prepared by the present embodiment is moisture below 10%, can be used as fuel for diesel vehicle.
Embodiment 5.
A kind of abrasive biofuel, its preparation process is as follows.
Step 1: prepare additive.
Isopropylcarbinol 20%, nitric acid isooctyl 1%, thanomin 4%, diesel oil stabilizing agent 3%, ammoniacal liquor 20%, hexahydroaniline 10%, carbon 9 20%, cetane number improver 1%, sherwood oil 20%, ferrocene 1% are mixed and make additive, standby.
Step 2: prepare a kind of abrasive biofuel of the present invention.
Get diesel oil 50 grams, ethanol 25 grams, Viscotrol C 10 grams, kerosene 5 grams, lipid acid 5 grams, additive 5 grams prepared by step 1.At normal temperatures and pressures, be sequentially added in proportion in reactor, carry out high speed shear with machinery and stir 20 minutes~30 minutes, get product after filtration.
Abrasive biofuel prepared by the present embodiment can be used as fuel for diesel vehicle.
The above is only preferred embodiment of the present invention, and the equivalence of doing according to the described structure of patent claim of the present invention, feature and principle therefore all changes or modifies, and is included in patent claim of the present invention.
Claims (8)
1. an abrasive biofuel, it is characterized in that: it comprises the raw material of following weight percent:
Diesel oil 20%~50%
Biomass alcohol 5%~25%
Vegetables oil 5%~25%
Kerosene 5%~15%
Lipid acid 5%~15%
Additive 3%~10%;
Described additive comprises the raw material of following weight percent: isopropylcarbinol 10%~20%, nitric acid isooctyl 1%~5%, thanomin 1%~5%, diesel oil stabilizing agent 1%~3%, ammoniacal liquor 20%~40%, hexahydroaniline 10%~20%, carbon 9 10%~42%, cetane number improver 1%~3%, sherwood oil 10%~20%, ferrocene 1%~2%.
2. a kind of abrasive biofuel according to claim 1, it is characterized in that: it comprises the raw material of following weight percent:
Diesel oil 20%~50%
Biomass alcohol 5%~25%
Vegetables oil 5%~25%
Kerosene 5%~15%
Lipid acid 5%~15%
Additive 3%~10%
Water 1%~30%.
3. a kind of abrasive biofuel according to claim 1, it is characterized in that: it comprises the raw material of following weight percent:
Diesel oil 20%~45%
Biomass alcohol 10%~25%
Vegetables oil 5%~20%
Kerosene 8%~15%
Lipid acid 8%~15%
Additive 5%~10%.
4. a kind of abrasive biofuel according to claim 2, it is characterized in that: it comprises the raw material of following weight percent:
Diesel oil 30%~40%
Biomass alcohol 10%~25%
Vegetables oil 10%~20%
Kerosene 10%~15%
Lipid acid 5%~10%
Additive 5%~10%
Water 5%~25%.
5. a kind of abrasive biofuel according to claim 4, it is characterized in that: it comprises the raw material of following weight percent:
Diesel oil 30%
Biomass alcohol 20%
Vegetables oil 15%
Kerosene 12%
Lipid acid 7%
Additive 8%
Water 8%.
6. according to the described a kind of abrasive biofuel of claim 1 ~ 5 any one, it is characterized in that: described biomass alcohol is methyl alcohol or ethanol, and methyl alcohol or ethanol are from the byproduct in chemical plant or fertilizer plant or brewery or pharmaceutical factory or sugar refinery.
7. according to the described a kind of abrasive biofuel of claim 1 ~ 5 any one, it is characterized in that: described vegetables oil is one or more in rapeseed oil, Oleum Cocois, Viscotrol C, Oleum Gossypii semen, tea-seed oil, soybean oil.
8. according to the described a kind of abrasive biofuel of claim 1 ~ 5 any one, it is characterized in that: its preparation method is as follows: at normal temperatures and pressures, raw material by above-mentioned weight percent, be sequentially added in reactor, stir 20 minutes~30 minutes by the agitator high speed shear, get product after filtration.
Priority Applications (1)
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CN2010102666362A CN102382691B (en) | 2010-08-30 | 2010-08-30 | Highly clean biodiesel |
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CN2010102666362A CN102382691B (en) | 2010-08-30 | 2010-08-30 | Highly clean biodiesel |
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CN102382691A CN102382691A (en) | 2012-03-21 |
CN102382691B true CN102382691B (en) | 2013-12-18 |
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Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102732331A (en) * | 2012-04-18 | 2012-10-17 | 吕桂生 | Petrochemical bio-oil methanol-synthesized (low PM2.5) diesel oil and preparation method thereof |
CN104099141B (en) * | 2014-08-01 | 2016-01-20 | 东莞市向阳世纪能源有限公司 | Energy-conserving and environment-protective oil fuel and preparation method thereof |
CN104232182B (en) * | 2014-09-22 | 2015-07-01 | 尹熙哲 | Diesel additive as well as preparation method and use method thereof |
CN105838456A (en) * | 2015-01-13 | 2016-08-10 | 赵惠霖 | High-cleanness diesel and preparation method thereof |
CN104694178B (en) * | 2015-01-30 | 2016-08-24 | 安徽海德石油化工有限公司 | A kind of preparation method of fuel oil |
CN108300522A (en) * | 2017-01-11 | 2018-07-20 | 张�杰 | Biodiesel substitutes the preparation method of petrifaction diesel |
CN108117897A (en) * | 2017-12-25 | 2018-06-05 | 中山市得高行知识产权中心(有限合伙) | A kind of high cleaning biodiesel |
CN111690468A (en) * | 2020-06-24 | 2020-09-22 | 海南绿新新能源有限公司 | Production method of novel biological grease blended clean fuel oil |
CN113088343A (en) * | 2021-03-26 | 2021-07-09 | 叁久国际新能源科技有限公司 | Clean fuel for replacing diesel oil |
Citations (4)
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JP2004359766A (en) * | 2003-06-03 | 2004-12-24 | Malaysian Palm Oil Board | Diesel oil having low pour point |
CN101003756A (en) * | 2007-01-18 | 2007-07-25 | 鲁希诺 | Synthetized diesel oil |
CN101082003A (en) * | 2007-06-04 | 2007-12-05 | 王承东 | Environmental protection biological diesel and preparation method thereof |
CN101302450A (en) * | 2008-07-15 | 2008-11-12 | 周凯亮 | Biosynthetic diesel and preparation thereof |
-
2010
- 2010-08-30 CN CN2010102666362A patent/CN102382691B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004359766A (en) * | 2003-06-03 | 2004-12-24 | Malaysian Palm Oil Board | Diesel oil having low pour point |
CN101003756A (en) * | 2007-01-18 | 2007-07-25 | 鲁希诺 | Synthetized diesel oil |
CN101082003A (en) * | 2007-06-04 | 2007-12-05 | 王承东 | Environmental protection biological diesel and preparation method thereof |
CN101302450A (en) * | 2008-07-15 | 2008-11-12 | 周凯亮 | Biosynthetic diesel and preparation thereof |
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CN102382691A (en) | 2012-03-21 |
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