CN114652625A - Hair dye agent, and preparation method and application thereof - Google Patents
Hair dye agent, and preparation method and application thereof Download PDFInfo
- Publication number
- CN114652625A CN114652625A CN202210262352.9A CN202210262352A CN114652625A CN 114652625 A CN114652625 A CN 114652625A CN 202210262352 A CN202210262352 A CN 202210262352A CN 114652625 A CN114652625 A CN 114652625A
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- China
- Prior art keywords
- hair dye
- agent
- fatty alcohol
- hair
- polyether
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- Granted
Links
- 239000000118 hair dye Substances 0.000 title claims abstract description 158
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 73
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 68
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 29
- 229920000570 polyether Polymers 0.000 claims abstract description 29
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 21
- 229940049292 n-(3-(dimethylamino)propyl)octadecanamide Drugs 0.000 claims description 17
- WWVIUVHFPSALDO-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C WWVIUVHFPSALDO-UHFFFAOYSA-N 0.000 claims description 17
- 239000002738 chelating agent Substances 0.000 claims description 10
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- MNAZHGAWPCLLGX-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C MNAZHGAWPCLLGX-UHFFFAOYSA-N 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 230000001502 supplementing effect Effects 0.000 claims description 3
- 239000010499 rapseed oil Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims 1
- 239000006260 foam Substances 0.000 abstract description 37
- 238000004043 dyeing Methods 0.000 abstract description 19
- 230000008569 process Effects 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 6
- 230000009286 beneficial effect Effects 0.000 abstract description 5
- 239000000975 dye Substances 0.000 abstract description 5
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 37
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 34
- 230000000052 comparative effect Effects 0.000 description 30
- 239000000047 product Substances 0.000 description 29
- 229960000541 cetyl alcohol Drugs 0.000 description 18
- XOHQAXXZXMHLPT-UHFFFAOYSA-N ethyl(phosphonooxy)phosphinic acid Chemical compound CCP(O)(=O)OP(O)(O)=O XOHQAXXZXMHLPT-UHFFFAOYSA-N 0.000 description 17
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 17
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 14
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 229940056318 ceteth-20 Drugs 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 229940043348 myristyl alcohol Drugs 0.000 description 7
- 230000008859 change Effects 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000013065 commercial product Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 2
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 229940012831 stearyl alcohol Drugs 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- DMOXNIKYXJYCFQ-UHFFFAOYSA-N (2-hydroxy-1-phosphonooxyethyl) dihydrogen phosphate Chemical compound OP(=O)(O)OC(CO)OP(O)(O)=O DMOXNIKYXJYCFQ-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 229940113490 2,4-diaminophenoxyethanol hydrochloride Drugs 0.000 description 1
- PBVFDMZFBPZIMC-UHFFFAOYSA-N 2-(2,4-diaminophenoxy)ethanol;hydrochloride Chemical compound Cl.NC1=CC=C(OCCO)C(N)=C1 PBVFDMZFBPZIMC-UHFFFAOYSA-N 0.000 description 1
- MMKZAICYSVWBPW-UHFFFAOYSA-N 2-[[2-(difluoromethoxy)phenyl]methylamino]-1-[3-(trifluoromethyl)phenyl]ethanol Chemical compound C=1C=CC(C(F)(F)F)=CC=1C(O)CNCC1=CC=CC=C1OC(F)F MMKZAICYSVWBPW-UHFFFAOYSA-N 0.000 description 1
- TWMBOHVOMWFMJI-UHFFFAOYSA-N 2-hydroxyethyl phosphono hydrogen phosphate Chemical compound OCCOP(O)(=O)OP(O)(O)=O TWMBOHVOMWFMJI-UHFFFAOYSA-N 0.000 description 1
- 229940018563 3-aminophenol Drugs 0.000 description 1
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
- 239000005725 8-Hydroxyquinoline Substances 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 1
- 241001135917 Vitellaria paradoxa Species 0.000 description 1
- DDAQLPYLBPPPRV-UHFFFAOYSA-N [4-(hydroxymethyl)-2-oxo-1,3,2lambda5-dioxaphosphetan-2-yl] dihydrogen phosphate Chemical compound OCC1OP(=O)(OP(O)(O)=O)O1 DDAQLPYLBPPPRV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229940073499 decyl glucoside Drugs 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 1
- TVQLLNFANZSCGY-UHFFFAOYSA-N disodium;dioxido(oxo)tin Chemical compound [Na+].[Na+].[O-][Sn]([O-])=O TVQLLNFANZSCGY-UHFFFAOYSA-N 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229960003540 oxyquinoline Drugs 0.000 description 1
- 239000001024 permanent hair color Substances 0.000 description 1
- 229960003893 phenacetin Drugs 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 229940057910 shea butter Drugs 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229940065859 sodium cocoyl glycinate Drugs 0.000 description 1
- 229940079864 sodium stannate Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- IKGKWKGYFJBGQJ-UHFFFAOYSA-M sodium;2-(dodecanoylamino)acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCC([O-])=O IKGKWKGYFJBGQJ-UHFFFAOYSA-M 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229940071182 stannate Drugs 0.000 description 1
- 125000005402 stannate group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- KWXLCDNSEHTOCB-UHFFFAOYSA-J tetrasodium;1,1-diphosphonatoethanol Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P(=O)([O-])C(O)(C)P([O-])([O-])=O KWXLCDNSEHTOCB-UHFFFAOYSA-J 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a hair dye agent II and a preparation method and application thereof, belonging to the technical field of daily chemicals. The invention relates to a hair dye agent II, which comprises the following components in percentage by mass: 0.5-2.0% of alkyl amidopropyl dimethylamine, 0.5-2.0% of fatty alcohol polyether, 0.5-1.5% of higher fatty alcohol, 1-12% of hydrogen peroxide and the balance of water; the alkyl amidopropyl dimethylamine, the fatty alcohol polyether and the higher fatty alcohol added into the hair dye agent provided by the invention have good cooperation and synergistic effects, so that the foamability of the product can be effectively increased, the texture of foam can be improved, firmer foam can be formed, and the stability of foam generated in the using process of the product can be improved; in addition, the product provided by the invention has excellent high and low temperature stability; meanwhile, the preparation method of the second hair dye agent provided by the invention is simple and is beneficial to actual production; the hair dye can be used as a compounding agent of a conventional hair dyeing agent to form a hair dye, and the obtained hair dye has good foamability and stability and excellent hair dyeing capability.
Description
Technical Field
The invention belongs to the technical field of daily chemicals, and particularly relates to a hair dye agent, a preparation method and application thereof.
Background
The two-part hair dye is the mainstream of the existing permanent hair dye, and generally comprises a basic agent containing hair dye or a colorant raw material and a two-part agent containing peroxide such as hydrogen peroxide; wherein the two-agent hair-dyeing cream requires a certain hair-dyeing skill, which is time-consuming and not easy to be uniformly applied on the hair for unskilled persons. Therefore, a double-agent type hair dyeing foam has appeared in the market, and a hair dyeing foam obtained by pumping a mixed solution of a primary hair dyeing agent and a secondary hair dyeing agent from a non-aerosol type foaming container can be lightly and uniformly coated on hair to achieve a uniform hair dyeing effect, but the phenomenon that the foam disappears to form a mixed solution in the hair dyeing process, drops and the like is avoided, so that the hair dyeing experience is poor, and the risk of contacting with the scalp is increased.
At present, there are many researches on two-part type foam hair dyes, such as patents CN103079532A, CN108245435B, CN103957877B, etc., which all propose a formula or composition of foam hair dyes with good foamability and foam stability, but all are applied in a formula of hair dye; patent JP2020180084A provides a composition containing stannate, anionic surfactant and zwitterionic surfactant, which according to the patent content can be used either as a one-part hair dye or as a two-part hair dye, but with anionic surfactant, further irritation may be induced or the dyeing ability may be reduced; KR20190051793A also provides a foam type hair dye composition which can be used in one or two-part hair dyeing, and can form softer hair dyeing foam and better dyeing quality by containing polyquaternium-55, shea butter and glyceryl stearate, but there is no mention about the stability of the two-part hair dye added with the composition.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a hair dye agent which does not drip foam in the hair dyeing process and is stable at high and low temperatures, a preparation method and application thereof.
In order to achieve the purpose, the invention adopts the technical scheme that: a hair dye agent comprises the following components in percentage by mass: 0.5-2.0% of alkyl amidopropyl dimethylamine, 0.5-2.0% of fatty alcohol polyether, 0.5-1.5% of higher fatty alcohol, 1-12% of hydrogen peroxide and the balance of water.
The hair dye agent two agent is added with the alkyl amidopropyl dimethylamine, the fatty alcohol polyether and the higher fatty alcohol in proper mass percentage, so that the hair dye agent two agent has good cooperation and synergistic effect, and the three agents can be used simultaneously, so that the foamability of the product can be effectively improved, the texture of generated foam can be improved, firmer foam can be formed, and the stability of the generated foam of the product in the using process can be improved; in addition, the formula provided by the invention can improve the stability of the product at high and low temperatures, and is beneficial to storage and transportation.
As a preferred embodiment of the second hair dye agent, the second hair dye agent comprises the following components in percentage by mass: 0.8-1.2% of alkyl amidopropyl dimethylamine, 0.6-1.2% of fatty alcohol polyether, 0.5-1.2% of higher fatty alcohol, 1-12% of hydrogen peroxide and the balance of water.
When the added mass percentages of the alkylamidopropyldimethylamine, the fatty alcohol polyether and the higher fatty alcohol are within the above ranges, the prepared foam has better stability and the product has better high and low temperature stability.
In a preferred embodiment of the hair dye preparation of the present invention, the alkylamidopropyldimethylamine comprises one of behenamidopropyldimethylamine, cocamidopropyldimethylamine, stearamidopropyldimethylamine, and rape-oil amidopropyldimethylamine.
In a preferred embodiment of the hair dye dimer of the present invention, the alkylamidopropyldimethylamine comprises one of behenamidopropyldimethylamine, brassinoylamidopropyldimethylamine and stearamidopropyldimethylamine.
Behenamidopropyl dimethylamine, brassinoamidopropyl dimethylamine and stearamidopropyl dimethylamine are linear chain saturated amidopropyl dimethylamine substances, and compared with other amidopropyl dimethylamine substances, such as linear chain unsaturated substances, aromatic substances and the like, the stability of the product can be improved better.
As a preferable embodiment of the second hair dye agent, the fatty alcohol in the fatty alcohol polyether is a straight-chain fatty alcohol, and the degree of polymerization of the polyether in the fatty alcohol polyether is 20-150.
The fatty alcohol in the fatty alcohol polyether is preferably straight-chain fatty alcohol, and because the fatty alcohol polyether with a branched chain and the fatty alcohol have steric hindrance when being compounded, a compact structure cannot be formed better, the stability of the product can be influenced, and the stability of the product is reduced; when the polymerization degree of polyether in the fatty alcohol polyether is preferably within the range of 20-150, the hydrophilic and lipophilic property and the better water locking performance can be moderate, and the liquid flow in foam gaps is reduced, so that the stability of the foam is improved, and the use feeling of the product is improved.
As a preferable embodiment of the hair dye two-component of the present invention, the fatty alcohol polyether includes at least one of laureth, myristyl polyether, ceteth, ceteareth, steareth, and beheneth.
As a preferable embodiment of the hair dye two-component, the fatty alcohol polyether comprises at least one of ceteth and ceteareth.
In a preferred embodiment of the two-component hair dye of the present invention, the higher aliphatic alcohol is a straight chain higher aliphatic alcohol, and the number of carbon atoms of the higher aliphatic alcohol is 10 to 24.
As a preferable embodiment of the hair dye two-component of the present invention, the higher fatty alcohol includes at least one of myristyl alcohol, cetyl alcohol, stearyl alcohol, lauryl alcohol, and behenyl alcohol.
In a preferred embodiment of the two-component hair dye of the present invention, the higher aliphatic alcohol has 14 to 18 carbon atoms.
As a preferable embodiment of the hair dye agent of the present invention, the higher fatty alcohol includes at least one of myristyl alcohol, cetyl alcohol, and stearyl alcohol.
As a preferable embodiment of the second hair dye agent, the second hair dye agent further comprises the following components in percentage by mass: 0.1-0.3% of chelating agent.
In a preferred embodiment of the second hair dye preparation of the present invention, the chelating agent is a heavy metal chelating agent, and includes any one of disodium EDTA, tetrasodium EDTA, etidronic acid, tetrasodium etidronate, pentasodium pentatetanic acid, and 2, 6-dicarboxylpyridine.
As a preferable embodiment of the second hair dye agent, the second hair dye agent further comprises the following components in percentage by mass: 0.1-0.3% of hydrogen peroxide stabilizer.
In a preferred embodiment of the second hair dye agent of the present invention, the hydrogen peroxide stabilizer comprises any one of sodium stannate, phenacetin and 8-hydroxyquinoline; the hydrogen peroxide stabilizer can play a role in stabilizing hydrogen peroxide in a system, and the degradation of the hydrogen peroxide to avoid the reduction of the hair dyeing performance of one dose of the subsequent mixed hair dye.
In a preferred embodiment of the second hair dye preparation of the present invention, the pH of the system of the second hair dye preparation is 2 to 4.
When the pH value of the system is between 2 and 4, the hydrogen peroxide stabilizer can be matched to stabilize the active component hydrogen peroxide in the system.
In a preferred embodiment of the second hair dye preparation of the present invention, the pH of the system of the second hair dye preparation is adjusted to 2 to 4 by using a pH adjuster, wherein the pH adjuster comprises any one of phosphoric acid/phosphate, sodium citrate/citric acid, sodium hydroxide and potassium hydroxide.
In addition, the invention also provides a preparation method of the hair dye agent II, which comprises the following steps:
(1) heating and uniformly mixing alkyl amidopropyl dimethylamine, fatty alcohol polyether and higher fatty alcohol, dripping water into the mixture, and stirring the mixture until the temperature is reduced to room temperature to obtain a mixture;
(2) dissolving a chelating agent in water to obtain a chelating agent aqueous solution;
(3) and (2) adding a chelating agent aqueous solution and hydrogen peroxide into the mixture obtained in the step (1), supplementing water to 100 parts by weight, adjusting the pH value of the system to 2-4, and uniformly mixing to obtain the second hair dye.
In a preferred embodiment of the preparation method of the present invention, in the step (1), the temperature for heating and uniformly mixing is 70 to 90 ℃.
In addition, the invention also provides a hair dye, which comprises a first hair dye agent and a second hair dye agent.
In a preferred embodiment of the hair dye of the present invention, the mass ratio of the first hair dye to the second hair dye is (1:2) - (2: 1).
As a preferred embodiment of the hair dye of the present invention, the hair dye is prepared by mixing one part of the hair dye with two parts of the hair dye in a foam bottle.
Compared with the prior art, the invention has the following beneficial effects:
firstly, the method comprises the following steps: the hair dye agent two agent is added with the alkyl amidopropyl dimethylamine, the fatty alcohol polyether and the higher fatty alcohol in proper mass percentage, so that the hair dye agent two agent has good cooperation and synergistic effect, and the three agents can be used simultaneously, so that the foamability of the product can be effectively improved, the texture of generated foam can be improved, firmer foam can be formed, and the stability of the generated foam of the product in the using process can be improved; in addition, the formula of the invention can also improve the stability of the product at high and low temperatures, and is beneficial to storage and transportation;
secondly, the method comprises the following steps: the preparation method of the second hair dye agent provided by the invention is simple and is beneficial to actual production;
thirdly, the steps of: the hair dye agent II provided by the technical scheme of the invention can be used as a formulation of a conventional hair dye agent I to form a hair dye, and the obtained hair dye has good foamability and stability and excellent hair dyeing capability.
Detailed Description
To better illustrate the objects, aspects and advantages of the present invention, the present invention will be further described with reference to specific examples.
Example 1
The hair dye comprises a first hair dye and a second hair dye, wherein the mass ratio of the first hair dye to the second hair dye is 1: 1;
the hair dye comprises the following components in percentage by mass: 12% cocamidopropyl betaine, 8% sodium cocoyl glycinate, 2.8% decyl glucoside, 2% ceteareth-25, 0.2% myristyl alcohol, 0.3% disodium EDTA, 0.8% cocamide MEA, 0.35% toluene-2, 5-diammonium sulfate, 0.1% 4-amino-2-hydroxytoluene, 0.15% 2, 4-diaminophenoxyethanol hydrochloride, 0.1% m-aminophenol, 0.4% sodium sulfite, 0.4% sodium ascorbate, 1% ammonium bicarbonate, 6% ethanolamine, 10% ethanol, the balance water;
the second hair dye agent comprises the following components in percentage by mass: 1.0% behenamidopropyl dimethylamine, 0.5% ceteth-150, 0.16% ceteth-20, 0.36% stearyl alcohol, 0.16% cetyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, balance water;
the preparation method of the hair dye agent comprises the following steps:
(1) weighing 1 part by weight of behenamidopropyl dimethylamine, 0.5 part by weight of cetyl polyether-150, 0.16 part by weight of cetyl polyether-20, 0.36 part by weight of stearyl alcohol and 0.16 part by weight of cetyl alcohol, adding into a beaker, heating to 80 ℃, stirring and mixing uniformly, then, dropwise adding water while stirring until the temperature is reduced to room temperature, wherein the weight part of the dropwise added water is 20 parts by weight, and obtaining a mixture;
(2) dissolving 0.3 weight part of hydroxyethyldiphosphonic acid in 10 weight parts of water to obtain a hydroxyethyldiphosphonic acid aqueous solution;
(3) adding an aqueous solution of hydroxyethylidene diphosphoric acid and hydrogen peroxide into the mixture obtained in the step (1), supplementing water to 100 parts by weight, adjusting the pH value of a system to be 3.85-3.95 by adopting a pH regulator, and uniformly mixing to obtain a second hair dye agent;
the preparation method of the hair dye comprises the following steps: uniformly mixing the first hair dye agent and the second hair dye agent in a mass ratio of 1:1 in a foam bottle to obtain the hair dye.
Example 2
The hair dye of the embodiment is only different from the hair dye of the embodiment 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 0.5% ceteth-150, 0.16% ceteth-20, 0.36% stearyl alcohol, 0.16% cetyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, the balance being water.
Example 3
The hair dye of the embodiment is only different from the hair dye of the embodiment 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% behenamidopropyl dimethylamine, 1.12% ceteareth-25, 0.6% cetyl alcohol, 0.36% myristyl alcohol, 0.3% hydroxyethyl diphosphate, 2.6% hydrogen peroxide, the balance being water.
Example 4
The hair dye of the embodiment is only different from the hair dye of the embodiment 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 1.12% ceteareth-25, 0.6% cetyl alcohol, 0.36% myristyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, balance water.
Example 5
The hair dye of the embodiment is only different from the hair dye of the embodiment 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 0.42% ceteth-150, 0.14% ceteth-25, 0.3% stearyl alcohol, 0.14% cetyl alcohol, 0.20% myristyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, the balance water.
Example 6
The hair dye of the embodiment is only different from the hair dye of the embodiment 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 0.5% ceteth-150, 0.16% ceteth-20, 0.36% stearyl alcohol, 0.16% cetyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, the balance being water.
Example 7
The hair dye of the embodiment is only different from the hair dye of the embodiment 1 in that the hair dye agent II comprises the following components in percentage by mass: 2.0% stearamidopropyl dimethylamine, 0.5% ceteth-150, 0.16% ceteth-20, 0.36% stearyl alcohol, 0.16% cetyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, the balance being water.
Example 8
The hair dye of the embodiment is only different from the hair dye of the embodiment 1 in that the hair dye agent comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 1.5% ceteth-150, 0.48% ceteth-20, 0.36% stearyl alcohol, 0.16% cetyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, the balance water.
Example 9
The hair dye of the embodiment is only different from the hair dye of the embodiment 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 0.5% ceteth-150, 0.16% ceteth-20, 0.9% stearyl alcohol, 0.4% cetyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, the balance being water.
Example 10
The hair dye of the embodiment is only different from the hair dye of the embodiment 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% cocamidopropyl dimethylamine, 0.5% ceteth-150, 0.16% ceteth-20, 0.36% stearyl alcohol, 0.16% cetyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, the balance water.
Example 11
The hair dye of the embodiment is only different from the hair dye of the embodiment 1 in that the hair dye agent comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 1.12% laureth-25, 0.6% cetyl alcohol, 0.36% myristyl alcohol, 0.3% hydroxyethylidene diphosphate, 2.6% hydrogen peroxide, the balance being water.
Example 12
The hair dye of the embodiment is only different from the hair dye of the embodiment 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 0.5% ceteth-150, 0.16% ceteth-20, 0.36% stearyl alcohol, 0.16% lauryl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, the balance being water.
Comparative example 1
The hair dye of the comparative example is only different from that of example 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 0.28% stearyl alcohol, 0.68% cetyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, and the balance water.
Comparative example 2
The hair dye of the comparative example is only different from that of example 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 1.12% ceteareth-25, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, balance water.
Comparative example 3
The hair dye of the comparative example is only different from that of example 1 in that the hair dye agent II comprises the following components in percentage by mass: 0.5% ceteth-150, 0.16% ceteth-20, 0.36% stearyl alcohol, 0.16% cetyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, and the balance water.
Comparative example 4
The hair dye of the comparative example is only different from that of example 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.12% ceteareth-25, 0.28% stearyl alcohol, 0.68% cetyl alcohol, 0.3% oxydehydrogen peroxide, 2.6% hydrogen peroxide, and the balance water.
Comparative example 5
The hair dye of the comparative example is only different from that of example 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 1.12% ceteth-10, 0.28% stearyl alcohol, 0.68% cetyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, and the balance water.
Comparative example 6
The hair dye of the comparative example is only different from that of example 1 in that the hair dye agent II comprises the following components in percentage by mass: 1.0% stearamidopropyl dimethylamine, 1.12% ceteareth-25, 0.28% stearyl alcohol, 0.68% isocetyl alcohol, 0.3% hydroxyethyldiphosphonic acid, 2.6% hydrogen peroxide, balance water.
Effect example 1
This effect example investigated the stability of the two-agent hair dye prepared in examples 1 to 12 and comparative examples 1 to 6 under high and low temperature conditions, in which the product was placed in an oven at 45 ℃ and the product was placed in an oven at-18 ℃ for one week and then evaluated by visual observation to confirm whether or not delamination occurred; wherein, 5 points represent no change, 4 points represent layering after 5 days, 3 points represent layering after 3 days, 2 points represent layering after 1 day, and 1 point represents layering after 1 day without placing in an oven at normal temperature; specific results are shown in table 1; the commercial product is a certain S-brand bubble hair dye color developing application milk, the commercial product in effect examples 2-3 adopts the same commercial product as the product in effect example 1, namely the certain S-brand bubble hair dye color developing application milk as a second hair dye agent, and then the first hair dye agent and the second hair dye agent are mixed according to the mass ratio of 1:1 to obtain the hair dye for testing, wherein the first hair dye agent is the first hair dye agent used in the embodiment and the comparative example of the invention;
table 1: high and Low temperature stability rating Table of Hair dye formulas of examples 1 to 12 and comparative examples 1 to 6 and commercial products
As can be seen from the table 1, the hair dye agent II obtained by adopting the technical scheme of the invention has excellent stability at high and low temperatures; when any one or two of alkyl amidopropyl dimethylamine, fatty alcohol polyether and higher fatty alcohol are not added, the stability of the obtained product is greatly reduced, the obtained product can be layered after being placed at room temperature for one day, and the stability of the obtained product also shows a trend of reduction when the polymerization degree of the fatty alcohol polyether is reduced or branched fatty alcohol is used; meanwhile, comparing the high and low temperature stability of examples 1 to 12 of the present invention with those of commercially available products, the commercially available products were equally good in low temperature stability, but delamination occurred already at 1 day of the high temperature test.
Effect example 2
This effect example explores the properties of the foams produced by the hair dyes prepared in examples 1 to 12 and comparative examples 1 to 6, wherein the density of the foam is calculated by measuring the weight of 50mL of the foam; after 30min, the accumulated liquid is obtained by taking 10g of foam, standing in a beaker for 30min, sucking out the foam by using a suction pipe for 30min, accumulating liquid at the bottom and measuring the mass of the liquid;
the resulting test data are shown in table 2;
table 2: tables for testing foam properties of hairdye prepared in examples 1 to 12 and comparative examples 1 to 6 and commercial products
As can be seen from the table 2, the hair dye obtained by the invention has less effusion in the test process, less than 5.92g, high foam density, more than 0.0613g/mL and good stability, which indicates that the foam is not easy to reduce, i.e. not easy to drip, and has good use experience in the actual use process; when no fatty alcohol polyether or higher fatty alcohol is added in any of comparative examples 1-2, compared with example 1, the foam density obtained in comparative examples 1-2 is obviously reduced, the liquid loading is obviously increased, and even when no alkylamidopropyldimethylamine is added in comparative examples 3-4, the obtained hair dye can be separated out and float upwards, and cannot be shaken up for testing; from the data of example 2 and examples 7-9, it can be seen that when the content of the added alkylamidopropyldimethylamine, fatty alcohol polyether or higher fatty alcohol is outside the preferred range of the present invention, the foam density of the resulting hair dye formulation is significantly reduced, with a reduction of between 9.32 and 19.55%; as can be seen from example 6 and comparative example 5, when the degree of polymerization in fatty alcohol polyether was changed to 10, the liquid loading of the resulting product increased significantly, the liquid loading obtained in comparative example 5 was 1.34 times the weight of the liquid loading of example 6, and the foam density in comparative example 5 also tended to decrease compared to example 6; as can be seen from example 6 and comparative example 6, when the higher aliphatic alcohol used was the branched aliphatic alcohol, the amount of accumulated liquid of the resulting hair dye formulation was significantly increased, the amount of accumulated liquid obtained in comparative example 6 was 1.49 times the weight of the accumulated liquid of example 6, and the foam density in comparative example 6 also tended to decrease compared to example 6; meanwhile, the liquid loading of the product obtained by the invention is smaller than that of the product sold on the market, which shows that the overall quality of the foam formed by the product of the invention is better than that of the product sold on the market.
Effect example 3
Effect example the evaluation of the hair dyeing ability of the hair dyes prepared in examples 1 to 6 and comparative examples 1 to 2 was investigated, and the resulting foam mixed and pumped out from the hair dye was left on the bundle of white hair for 30 minutes to dye, and then the change in the Lab value of the bundle was measured by a color difference meter and the change in the shade (Δ L value) and the change in the total color difference (Δ E value) were calculated; the results of the tests are shown in table 3;
table 3: hair dyeing agents prepared in examples 1 to 6 and comparative examples 1 to 2 and hair dyeing property test charts of commercially available products
| Delta L value | Delta E value | Delta L value | Delta E value | ||
| Example 1 | -40.912 | 44.704 | Example 6 | -40.082 | 45.56 |
| Example 2 | -41.522 | 45.202 | Comparative example 1 | -38.426 | 45.032 |
| Example 3 | -41.174 | 45.852 | Comparative example 2 | -40.232 | 44.698 |
| Example 4 | -39.504 | 44.044 | Commercially available product | -40.862 | 44.502 |
| Example 5 | -40.665 | 45.632 |
As can be seen from Table 3, the measured DeltaL and DeltaE values of the hair tresses after dyeing in the examples are very significantly changed, which shows that the hair dye obtained by the invention has certain dyeing capability, and is comparable to or slightly improved from the commercial products.
Finally, it should be noted that the above embodiments are intended to illustrate the technical solutions of the present invention and not to limit the scope of the present invention, and although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications and equivalent substitutions can be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention.
Claims (10)
1. The hair dye agent is characterized by comprising the following components in percentage by mass: 0.5-2.0% of alkyl amidopropyl dimethylamine, 0.5-2.0% of fatty alcohol polyether, 0.5-1.5% of higher fatty alcohol, 1-12% of hydrogen peroxide and the balance of water.
2. The hair dye agent II according to claim 1, which is characterized by comprising the following components in percentage by mass: 0.8-1.2% of alkyl amidopropyl dimethylamine, 0.6-1.2% of fatty alcohol polyether, 0.5-1.2% of higher fatty alcohol, 1-12% of hydrogen peroxide and the balance of water.
3. The hair dye agent of claim 1, wherein the alkylamidopropyldimethylamine comprises any one of behenamidopropyldimethylamine, cocamidopropyldimethylamine, stearamidopropyldimethylamine, and rape-oil amidopropyldimethylamine.
4. The hair dye agent of claim 1, wherein the fatty alcohol in the fatty alcohol polyether is a straight-chain fatty alcohol, and the degree of polymerization of the polyether in the fatty alcohol polyether is 20-150.
5. The hair dye agent of claim 1, wherein the higher aliphatic alcohol is a straight chain higher aliphatic alcohol, and the number of carbon atoms of the straight chain higher aliphatic alcohol is 10 to 24.
6. The two-component hair dye preparation as claimed in claim 1, further comprising the following components in percentage by mass: 0.1-0.3% of chelating agent.
7. The hair dye two-component preparation according to claim 1, wherein the system pH of the hair dye two-component preparation is 2 to 4.
8. The method for preparing the hair dye two agent as set forth in any one of claims 1 to 7, comprising the steps of:
(1) heating and uniformly mixing alkyl amidopropyl dimethylamine, fatty alcohol polyether and higher fatty alcohol, dripping part of water into the mixture while stirring the mixture until the mixture is uniform, and then continuously stirring the mixture and cooling the mixture to room temperature to obtain a mixture;
(2) dissolving a chelating agent in water to obtain a chelating agent aqueous solution;
(3) and (2) adding a chelating agent aqueous solution and hydrogen peroxide into the mixture obtained in the step (1), supplementing water to 100 parts by weight, adjusting the pH value of the system to 2-4, and uniformly mixing to obtain the second hair dye.
9. A hair dye, characterized in that it comprises one part of a hair dye and two parts of a hair dye as claimed in any one of claims 1 to 7.
10. The hair dye as set forth in claim 9, wherein the mass ratio of the one-part hair dye to the two-part hair dye is (1:2) - (2: 1).
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| JP2002363047A (en) * | 2001-06-06 | 2002-12-18 | Milbon Co Ltd | Oxidation hair dye |
| EP1714677A1 (en) * | 2005-04-22 | 2006-10-25 | Kao Corporation, S.A. | Long chain fatty acid dimethylaminopropylamide as levelling agent for dyeing kerationous fibres, or as thickening agent |
| CN102755256A (en) * | 2007-10-24 | 2012-10-31 | 花王株式会社 | Double-agent type hair dye combination |
| CN110891546A (en) * | 2017-07-19 | 2020-03-17 | 日商桑妮布雷斯股份有限公司 | Hair cosmetic composition, hair dye composition and hair dyeing method |
| JP2020121937A (en) * | 2019-01-30 | 2020-08-13 | 株式会社 ナチュラル | Hair dying composition |
| CN112955112A (en) * | 2018-10-31 | 2021-06-11 | 汉高股份有限及两合公司 | Two-component system for artificial hair coloring |
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2022
- 2022-03-16 CN CN202210262352.9A patent/CN114652625B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002363047A (en) * | 2001-06-06 | 2002-12-18 | Milbon Co Ltd | Oxidation hair dye |
| EP1714677A1 (en) * | 2005-04-22 | 2006-10-25 | Kao Corporation, S.A. | Long chain fatty acid dimethylaminopropylamide as levelling agent for dyeing kerationous fibres, or as thickening agent |
| CN102755256A (en) * | 2007-10-24 | 2012-10-31 | 花王株式会社 | Double-agent type hair dye combination |
| CN110891546A (en) * | 2017-07-19 | 2020-03-17 | 日商桑妮布雷斯股份有限公司 | Hair cosmetic composition, hair dye composition and hair dyeing method |
| CN112955112A (en) * | 2018-10-31 | 2021-06-11 | 汉高股份有限及两合公司 | Two-component system for artificial hair coloring |
| JP2020121937A (en) * | 2019-01-30 | 2020-08-13 | 株式会社 ナチュラル | Hair dying composition |
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