CN114635146B - Electrolytic tank structure for generating acidic electrolyzed oxidizing water - Google Patents

Electrolytic tank structure for generating acidic electrolyzed oxidizing water Download PDF

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Publication number
CN114635146B
CN114635146B CN202210248311.4A CN202210248311A CN114635146B CN 114635146 B CN114635146 B CN 114635146B CN 202210248311 A CN202210248311 A CN 202210248311A CN 114635146 B CN114635146 B CN 114635146B
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heat exchange
clay block
exchange sleeve
electrolyzed oxidizing
oxidizing water
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CN202210248311.4A
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CN114635146A (en
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张奇
皮明远
任占冬
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Wuhan Lihui New Technology Co ltd
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Wuhan Lihui New Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses an electrolytic tank structure for generating acidic oxidation potential water, which comprises a metal tank body and a clay block lining, wherein the inner wall of the metal tank body is in fit connection with the clay block lining, a T-shaped seat is fixedly arranged at the bottom of an inner cavity of the clay block lining, an insulating partition plate and the T-shaped seat divide the inner cavity of the clay block lining into a left half electrolytic area and a right half electrolytic area, ion membrane plates are arranged in the left half electrolytic area and the right half electrolytic area, the two ion membrane plates are connected with the T-shaped seat, and cathode electrode plates are fixedly arranged on two sides of the insulating partition plate.

Description

Electrolytic tank structure for generating acidic electrolyzed oxidizing water
Technical Field
The invention relates to an electrolytic tank structure, in particular to an electrolytic tank structure for generating acidic electrolyzed oxidizing water, and belongs to the technical field of electrolytic tanks.
Background
The electrolytic tank consists of a tank body, an anode and a cathode, and the anode chamber and the cathode chamber are separated by a diaphragm. The electrolyte is divided into three types, namely an aqueous solution electrolytic tank, a molten salt electrolytic tank and a nonaqueous solution electrolytic tank. When the direct current passes through the electrolytic cell, oxidation reaction occurs at the interface between the anode and the solution, and reduction reaction occurs at the interface between the cathode and the solution, so as to prepare the required product. The optimized design of the structure of the electrolytic tank and the reasonable selection of electrode and diaphragm materials are the keys for improving the current efficiency, reducing the tank voltage and saving the energy consumption.
The electrolytic bath is a key component and a core component of equipment for generating acidic oxidation potential water, and the working principle of the electrolytic bath is that softened tap water and a certain proportion of analytical pure NaCL solution are mixed by utilizing electrolytic reaction, and then are electrolyzed in the electrolytic bath containing an ion exchange membrane through a special platinum-titanium alloy electrode. The water coming out from one side of the anode is called acidic oxidation potential water, and the acidic oxidation potential water has the advantages of high sterilization speed, broad spectrum, safety, reliability, no residual toxicity, environmental protection and the like, and can damage the living environment of microorganisms, enhance the permeability of cell membranes, cause cell swelling, damage internal metabolic enzymes and enable the microorganisms to die rapidly due to the combined action of low pH value, high oxidation reduction potential and available chlorine.
However, when the conventional electrolytic tank is used, the conventional electrolytic tank is mostly matched with an anode and a cathode, the anode is supplied with current, the current flows back through the cathode, the electrolytic efficiency of the electrolytic tank is greatly reduced, the generation amount of acidic oxidation potential water is reduced, the generated heat cannot be recovered, and the heat in the exhaust gas and the acidic oxidation water level cannot be utilized, so that the storage is inconvenient.
Disclosure of Invention
The invention aims to provide an electrolytic cell structure for generating acidic electrolyzed oxidizing water, which solves the problems in the prior art.
In order to achieve the above purpose, the present invention provides the following technical solutions: the utility model provides a generate electrolysis trough structure of acid oxidation potential water, includes metal cell body and clay block inside lining, the inner wall and the laminating of clay block inside lining of metal cell body are connected, the bottom fixed mounting of clay block inside lining inner chamber has T type seat, the fixed insulating partition that is equipped with in middle part on T type seat top, insulating partition and T type seat divide into left half electrolysis district and right half electrolysis district with the inner chamber of clay block inside lining, the ion membrane board is all installed to the inside in left half electrolysis district and right half electrolysis district, two the ion membrane board all is connected with T type seat, the equal fixed mounting in both sides of insulating partition has the cathode electrode piece, the equal laminating in both sides of clay block inside lining inner chamber is connected with the anode electrode piece, the equal grafting in middle part of metal cell body both sides is connected with conductive terminal, two conductive terminal's one end all is connected with sealed insulating joint, two sealed insulating joint's one end all is connected with first pure copper wire, two the one end of first pure copper wire all is connected with the output end fixed connection of the integrated wiring end that is equipped with, the inside connection of two pure copper wire is equipped with hollow conductor, two hollow conductor and hollow conductor, two hollow conductor connected with two hollow conductor, two hollow conductor connected with hollow conductor, two hollow conductor connected with hollow conductor.
As a preferable technical scheme of the invention, the heat recovery structure comprises a heat shield body, wherein a first heat exchange sleeve and a second heat exchange sleeve are arranged in the heat shield body and are connected with corresponding hollow guide pipes in a sleeved mode, a first inlet pipe and a second inlet pipe are respectively arranged at one end of the first heat exchange sleeve and one end of the second heat exchange sleeve, and a converging pipeline is fixedly connected between the first heat exchange sleeve and the second heat exchange sleeve.
As a preferable technical scheme of the invention, the inner wall of the clay block lining is coated with a perfluoroethylene propylene coating, the perfluoroethylene propylene coating consists of tetrafluoroethylene and hexafluoropropylene, and the content of hexafluoropropylene is 10-15%.
As a preferable technical scheme of the invention, the anode electrode plate and the cathode electrode plate are platinum-titanium alloy electrodes.
As a preferred technical scheme of the invention, the wire current-carrying capacity of the second pure copper wire is twice that of the first pure copper wire.
As a preferred embodiment of the present invention, the heat exchange coefficient of the first heat exchange jacket is different from the heat exchange coefficient of the second heat exchange jacket.
As a preferable technical scheme of the invention, the top end of the metal groove body is buckled and connected with an insulating groove cover, and the middle part of the insulating groove cover is in sliding connection with the cathode electrode plate.
Compared with the prior art, the invention has the beneficial effects that:
1. according to the electrolytic tank structure for generating the acidic electrolyzed water, the metal tank body is divided into the left half electrolytic area and the right half electrolytic area through the T-shaped seat, the ion diaphragm plate and the insulating partition plate, the first pure copper wire and the second pure copper wire are used for respectively introducing current into the left half electrolytic area and the right half electrolytic area, and then the cathode electrode plate is used for forming a passage, so that the electrolytic efficiency of the electrolytic tank in unit time is greatly improved, the generation amount of the acidic electrolyzed water in unit time is improved, and the electrolytic tank structure is high in practicability.
2. The invention relates to an electrolytic tank structure for generating acidic oxidation potential water, which is provided with a heat shield body, a first heat exchange sleeve, a first inlet pipe, a second heat exchange sleeve, a converging pipe and a second inlet pipe, and is convenient for collecting discharged gas and recycling acidic oxidation water through a hollow pipe, wherein heat contained in the electrolytic tank structure is utilized through the first heat exchange sleeve and the second heat exchange sleeve, so that the heat is convenient to recycle, the heat recycling efficiency is improved, and the use is convenient.
Drawings
FIG. 1 is a schematic diagram of the structure of the present invention;
FIG. 2 is a schematic view of the internal structure of the heat shield body of the present invention.
In the figure: 1. a metal tank body; 2. a clay block liner; 3. a power plug; 4. a second pure copper wire; 5. an integrated terminal block; 6. a first pure copper wire; 7. sealing the insulating joint; 8. a conductive contact; 9. an anode electrode sheet; 10. a T-shaped seat; 11. an ion membrane plate; 12. an insulating separator; 13. a cathode electrode sheet; 14. an integrated plug; 15. an insulating slot cover; 16. a hollow conduit; 17. a heat shield body; 18. a first heat exchange jacket; 19. a first inlet pipe; 20. a second heat exchange jacket; 21. a confluence pipe; 22. and a second inlet pipe.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Referring to fig. 1-2, the invention provides a technical scheme of an electrolytic cell structure for generating acidic electrolyzed oxidizing water, which comprises the following steps:
according to the illustration of fig. 1-2, including metal cell body 1 and clay block inside lining 2, the inner wall of metal cell body 1 is connected with the laminating of clay block inside lining 2, the bottom fixed mounting of clay block inside lining 2 inner chamber has T type seat 10, the middle part on T type seat 10 top is fixed to be equipped with insulating partition 12, insulating partition 12 and T type seat 10 divide into left half electrolysis district and right half electrolysis district with the inner chamber of clay block inside lining 2, ion membrane plate 11 is all installed to the inside in left half electrolysis district and right half electrolysis district, two ion membrane plates 11 all are connected with T type seat 10, the equal fixed mounting in both sides of insulating partition 12 has cathode electrode piece 13, the equal laminating in both sides of clay block inside lining 2 inner chamber is connected with anode electrode piece 9, the middle part of metal cell body 1 both sides is all pegged graft and is connected with conductive connection, the one end of two conductive connection 8 all is connected with sealed insulating connection 7, the one end of two sealed insulating connection 7 all is connected with first pure copper wire 6, the one end of two first pure copper wire 6 all is connected with the output fixed connection of integrated terminal 5 that is equipped with, the inside connection terminal 5, the two hollow conductor 16 is equipped with two hollow conductor 16 and is connected with two hollow conductor 16, two hollow conductor 16 inside hollow conductor 16 are connected with two hollow conductor 16, two hollow conductor 16 are connected with the inside hollow conductor 16 and two hollow conductor 16 are connected with the inside hollow conductor 16.
According to the embodiment shown in fig. 1 and 2, the heat recovery structure comprises a heat-insulating cover body 17, a first heat exchange sleeve 18 and a second heat exchange sleeve 20 are installed in the heat-insulating cover body 17, the first heat exchange sleeve 18 and the second heat exchange sleeve 20 are sleeved and connected with corresponding hollow guide pipes 16, a first inlet pipe 19 and a second inlet pipe 22 are installed at one end of the first heat exchange sleeve 18 and one end of the second heat exchange sleeve 20 respectively, a confluence pipeline 21 is fixedly connected between the first heat exchange sleeve 18 and the second heat exchange sleeve 20, heat recovery is facilitated, heat recovery is improved, a polytetrafluoroethylene coating is coated on the inner wall of a clay liner 2, the polytetrafluoroethylene coating consists of tetrafluoroethylene and hexafluoropropylene, the hexafluoropropylene content is 10-15%, an anode electrode plate 9 and a cathode electrode plate 13 are platinum-titanium alloy electrodes, good conductive performance and good service life are achieved, the wire flow of a second pure copper wire 4 is twice that of a first pure copper wire 6, the heat exchange coefficient of the first heat exchange sleeve 18 and the second heat exchange sleeve 20 are not good, the heat recovery effect is improved, the heat recovery is achieved by a metal groove cover 1 is connected with a heat recovery groove cover, the heat recovery effect is improved, and a metal groove cover 1 is connected with the heat recovery groove cover is provided.
When the invention is used, the anode electrode plate 9 is supplied with current, the first pure copper lead 6 and the second pure copper lead 4 are respectively used for supplying current to the insides of the left half electrolysis area and the right half electrolysis area, and then the cathode electrode plate 13 is used for forming a passage, so that the electrolysis efficiency of the electrolytic cell in unit time is greatly improved, the generation amount of acidic oxidation potential water in unit time is improved, the practicability is high, the discharged gas is conveniently collected and the acidic oxidation water is conveniently recycled through the two hollow guide pipes 16, and the contained heat is conveniently recycled through the first heat exchange sleeve 18 and the second heat exchange sleeve 20, thereby improving the heat recycling efficiency and being convenient to use.
In the description of the present invention, it should be understood that the orientation or positional relationship indicated is based on the orientation or positional relationship shown in the drawings, and is merely for convenience in describing the present invention and simplifying the description, and does not indicate or imply that the apparatus or element referred to must have a specific orientation, be configured and operated in a specific orientation, and thus should not be construed as limiting the present invention.
In the present invention, unless explicitly specified and defined otherwise, for example, it may be fixedly connected, detachably connected, or integrally formed; can be mechanically or electrically connected; either directly or indirectly through intermediaries, or in communication with each other or in interaction with each other, unless explicitly defined otherwise, the meaning of the terms described above in this application will be understood by those of ordinary skill in the art in view of the specific circumstances.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (7)

1. The utility model provides a generate electrolytic tank structure of acid oxidation potential water, includes metal cell body (1) and clay block inside lining (2), its characterized in that, the inner wall and the clay block inside lining (2) laminating of metal cell body (1) are connected, the bottom fixed mounting of clay block inside lining (2) inner chamber has T type seat (10), the middle part at T type seat (10) top is fixed to be equipped with insulating barrier (12), insulating barrier (12) and T type seat (10) divide into left half electrolysis district and right half electrolysis district with the inner chamber of clay block inside lining (2), ion membrane board (11) are all installed to the inside of left half electrolysis district and right half electrolysis district, two ion membrane board (11) all are connected with T type seat (10), the both sides of insulating barrier (12) all fixed mounting have negative pole electrode piece (13), the both sides of clay block inside lining (2) inner chamber all are laminated and are connected with positive pole electrode piece (9), the middle part all in both sides of metal cell body (1) is connected with conducting connection (8), two conducting connection has conducting wire (6) in the middle part of both sides, two conducting connection (7) are all connected with one end (6) of a sealed connection wire (6) and one end (6) are all connected with one end (6) of pure copper wire (6) respectively, the integrated terminal head (5) is connected with a second pure copper wire (4), one end fixedly connected with power plug (3) of second pure copper wire (4), two the one end of negative pole electrode piece (13) all with integrated plug (14) fixed connection that are equipped with, the inside in half electrolysis district in left side and the inside in half electrolysis district in right side all communicate there is hollow pipe (16), two hollow pipe (16) all are connected with the heat recovery structure that is equipped with.
2. An electrolyzer structure for generating electrolyzed oxidizing water according to claim 1, characterized in that: the heat recovery structure comprises a heat shield body (17), a first heat exchange sleeve (18) and a second heat exchange sleeve (20) are mounted in the heat shield body (17), the first heat exchange sleeve (18) and the second heat exchange sleeve (20) are sleeved with corresponding hollow pipes (16) to be connected, a first inlet pipe (19) and a second inlet pipe (22) are mounted at one end of the first heat exchange sleeve (18) and one end of the second heat exchange sleeve (20) respectively, and a converging pipeline (21) is fixedly connected between the first heat exchange sleeve (18) and the second heat exchange sleeve (20).
3. An electrolyzer structure for generating electrolyzed oxidizing water according to claim 1, characterized in that: the inner wall of the clay block lining (2) is coated with a perfluoroethylene propylene coating, the perfluoroethylene propylene coating consists of tetrafluoroethylene and hexafluoropropylene, and the content of the hexafluoropropylene is 10-15%.
4. An electrolyzer structure for generating electrolyzed oxidizing water according to claim 1, characterized in that: the anode electrode plate (9) and the cathode electrode plate (13) are platinum-titanium alloy electrodes.
5. An electrolyzer structure for generating electrolyzed oxidizing water according to claim 1, characterized in that: the wire current-carrying capacity of the second pure copper wire (4) is twice that of the first pure copper wire (6).
6. An electrolytic cell structure for generating electrolyzed oxidizing water according to claim 2, wherein: the heat exchange coefficient of the first heat exchange jacket (18) is different from the heat exchange coefficient of the second heat exchange jacket (20).
7. An electrolyzer structure for generating electrolyzed oxidizing water according to claim 1, characterized in that: the top of the metal groove body (1) is buckled and connected with an insulating groove cover (15), and the middle part of the insulating groove cover (15) is in sliding connection with the cathode electrode plate (13).
CN202210248311.4A 2022-03-14 2022-03-14 Electrolytic tank structure for generating acidic electrolyzed oxidizing water Active CN114635146B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07236888A (en) * 1994-02-28 1995-09-12 Nippon Intec Kk Electrolytic water and oxidation potential water making apparatus
JPH07328639A (en) * 1994-06-02 1995-12-19 Nippon Intec Kk Oxidation potential water forming device
CN104562092A (en) * 2015-02-03 2015-04-29 奉新赣锋锂业有限公司 Multi-anode lithium metal electrolytic bath
CN206680226U (en) * 2017-03-27 2017-11-28 长春云卫科技有限公司 Acidic oxidized electric potential water produces electrolytic cell
CN211734057U (en) * 2019-12-21 2020-10-23 武汉丽辉新技术有限公司 Acidic oxidation potential water generator
CN212246339U (en) * 2020-05-08 2020-12-29 河北宏泰丰业医疗器械有限公司 Electrolytic tank of acidic oxidation potential water generator
CN213803049U (en) * 2020-11-06 2021-07-27 江西坤灿环保科技股份有限公司 Acidic electrolytic tank
CN214936277U (en) * 2021-06-25 2021-11-30 石首市金祥米业有限公司 Acidic oxidation potential water generating device

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07236888A (en) * 1994-02-28 1995-09-12 Nippon Intec Kk Electrolytic water and oxidation potential water making apparatus
JPH07328639A (en) * 1994-06-02 1995-12-19 Nippon Intec Kk Oxidation potential water forming device
CN104562092A (en) * 2015-02-03 2015-04-29 奉新赣锋锂业有限公司 Multi-anode lithium metal electrolytic bath
CN206680226U (en) * 2017-03-27 2017-11-28 长春云卫科技有限公司 Acidic oxidized electric potential water produces electrolytic cell
CN211734057U (en) * 2019-12-21 2020-10-23 武汉丽辉新技术有限公司 Acidic oxidation potential water generator
CN212246339U (en) * 2020-05-08 2020-12-29 河北宏泰丰业医疗器械有限公司 Electrolytic tank of acidic oxidation potential water generator
CN213803049U (en) * 2020-11-06 2021-07-27 江西坤灿环保科技股份有限公司 Acidic electrolytic tank
CN214936277U (en) * 2021-06-25 2021-11-30 石首市金祥米业有限公司 Acidic oxidation potential water generating device

Non-Patent Citations (1)

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Title
"酸性氧化电位水制备技术研究进展";余浩 等;《中国消毒学杂志》;第155-158页 *

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