CN114635146A - Electrolytic tank structure for generating acidic oxidation potential water - Google Patents

Electrolytic tank structure for generating acidic oxidation potential water Download PDF

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Publication number
CN114635146A
CN114635146A CN202210248311.4A CN202210248311A CN114635146A CN 114635146 A CN114635146 A CN 114635146A CN 202210248311 A CN202210248311 A CN 202210248311A CN 114635146 A CN114635146 A CN 114635146A
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heat exchange
electrolytic
cover
insulating
clay block
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CN202210248311.4A
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CN114635146B (en
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张奇
皮明远
任占冬
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Wuhan Lihui New Technology Co ltd
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Wuhan Lihui New Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses an electrolytic cell structure for generating acidic electrolyzed oxidizing water, which comprises a metal cell body and a clay block lining, wherein the inner wall of the metal cell body is attached and connected with the clay block lining, the bottom of the inner cavity of the clay block lining is fixedly provided with a T-shaped seat, an insulating partition plate and the T-shaped seat divide the inner cavity of the clay block lining into a left half electrolytic area and a right half electrolytic area, the insides of the left half electrolytic area and the right half electrolytic area are respectively provided with an ionic membrane plate, the two ionic membrane plates are both connected with the T-shaped seat, and both sides of the insulating partition plate are respectively fixedly provided with a cathode electrode plate. The generation amount of the acidic oxidation potential water in unit time is improved, and the practicability is strong.

Description

Electrolytic tank structure for generating acidic oxidation potential water
Technical Field
The invention relates to an electrolytic cell structure, in particular to an electrolytic cell structure for generating acid oxidation potential water, and belongs to the technical field of electrolytic cells.
Background
The electrolytic cell consists of a cell body, an anode and a cathode, and most of the cells are separated from the anode chamber and the cathode chamber by a diaphragm. The electrolytic bath is divided into three types, namely an aqueous solution electrolytic bath, a molten salt electrolytic bath and a non-aqueous solution electrolytic bath according to the difference of the electrolyte. When direct current passes through the electrolytic cell, an oxidation reaction occurs at the interface between the anode and the solution, and a reduction reaction occurs at the interface between the cathode and the solution, so as to prepare the desired product. The optimized design of the electrolytic cell structure and the reasonable selection of the electrode and diaphragm materials are the keys of improving the current efficiency, reducing the cell voltage and saving the energy consumption.
The electrolytic bath is a key component and a core component of equipment for generating acidic electrolyzed oxidizing water, and the working principle of the electrolytic bath is mainly that softened tap water is mixed with a certain proportion of analytically pure NaCL solution by utilizing electrolytic reaction, and then electrolysis is carried out in the electrolytic bath containing an ion exchange membrane through a special platinum-titanium alloy electrode. The water coming out of the anode side is called acid oxidation potential water, and the acid oxidation potential water can destroy the living environment of microorganisms through the combined action of low pH value, high oxidation-reduction potential and available chlorine, enhance the permeability of cell membranes, cause cell swelling, destroy internal metabolic enzymes and enable the microorganisms to die rapidly, so the acid oxidation potential water has the effects of disinfection and sterilization, and has the advantages of high disinfection speed, broad spectrum, safety, reliability, no residual toxicity, environmental protection and the like.
However, when the existing electrolytic cell is used, the anode and the cathode are mostly matched, current flows into the anode, the current flows back through the cathode, the electrolytic efficiency of the electrolytic cell is greatly reduced, the generation amount of the electrolyzed oxidizing water is reduced, the generated heat cannot be recovered, and the heat in the exhaust gas and the acidic oxidizing water level cannot be utilized and is not convenient to store.
Disclosure of Invention
The invention aims to provide an electrolytic cell structure for generating electrolyzed oxidizing water, which solves the problems in the prior art.
In order to achieve the purpose, the invention provides the following technical scheme: an electrolytic cell structure for generating acidic oxidation potential water comprises a metal cell body and a clay block lining, wherein the inner wall of the metal cell body is connected with the clay block lining in a fitting manner, a T-shaped seat is fixedly arranged at the bottom of an inner cavity of the clay block lining, an insulating partition plate is fixedly arranged in the middle of the top end of the T-shaped seat, the inner cavity of the clay block lining is divided into a left half electrolytic area and a right half electrolytic area by the insulating partition plate and the T-shaped seat, ion membrane plates are respectively arranged in the left half electrolytic area and the right half electrolytic area, the two ion membrane plates are both connected with the T-shaped seat, cathode electrode plates are respectively and fixedly arranged on two sides of the insulating partition plate, anode electrode plates are respectively and fixedly connected with two sides of the inner cavity of the clay block lining in a fitting manner, conductive connectors are respectively and spliced in the middle of two sides of the metal cell body, one ends of the two conductive connectors are respectively connected with a sealed insulating connector, one end of the two sealed insulating connectors is respectively connected with a first pure copper wire, two the one end of first pure copper wire all with the output fixed connection of the integrated terminal that is equipped with, the input of integrated terminal is connected with the pure copper wire of second, the one end fixedly connected with power plug of the pure copper wire of second, two the one end of negative pole electrode slice all with the integrated plug fixed connection who is equipped with, the inside in half electrolysis district on the left side and the inside in half electrolysis district on the right side all communicate there is hollow pipe, two hollow pipe all is connected with the heat recovery structure that is equipped with.
As a preferred technical scheme of the present invention, the heat recovery structure includes a heat insulation cover body, a first heat exchange jacket and a second heat exchange jacket are installed inside the heat insulation cover body, the first heat exchange jacket and the second heat exchange jacket are connected to corresponding hollow conduits in a sleeved manner, a first inlet pipe and a second inlet pipe are respectively installed at one end of the first heat exchange jacket and one end of the second heat exchange jacket, and a confluence pipeline is fixedly connected between the first heat exchange jacket and the second heat exchange jacket.
According to a preferable technical scheme of the invention, the inner walls of the clay block linings are coated with perfluorinated ethylene propylene coatings, each perfluorinated ethylene propylene coating is composed of tetrafluoroethylene and hexafluoropropylene, and the content of the hexafluoropropylene is 10-15%.
As a preferred technical scheme of the invention, the anode electrode plate and the cathode electrode plate are both platinum-titanium alloy electrodes.
As a preferred embodiment of the present invention, the wire current-carrying capacity of the second pure copper wire is twice the wire current-carrying capacity of the first pure copper wire.
As a preferable technical solution of the present invention, the heat exchange coefficient of the first heat exchange jacket is different from the heat exchange coefficient of the second heat exchange jacket.
As a preferred technical scheme of the invention, the top end of the metal groove body is connected with an insulating groove cover in a buckling mode, and the middle of the insulating groove cover is connected with the cathode electrode plate in a sliding mode.
Compared with the prior art, the invention has the beneficial effects that:
1. according to the electrolytic cell structure for generating the acidic electrolyzed oxidizing water, the metal cell body is divided into the left half electrolytic area and the right half electrolytic area through the T-shaped seat, the ionic membrane plate and the insulating partition plate, current is respectively introduced into the left half electrolytic area and the right half electrolytic area through the first pure copper conducting wire and the second pure copper conducting wire, and then a passage is formed through the cathode electrode plate, so that the electrolytic efficiency of the electrolytic cell in unit time is greatly improved, the generation amount of the acidic electrolyzed oxidizing water in unit time is improved, and the electrolytic cell structure is high in practicability.
2. According to the electrolytic cell structure for generating the electrolyzed oxidizing water, the hollow guide pipe is used for conveniently collecting the discharged gas and recovering the electrolyzed oxidizing water, and the heat contained in the electrolyzed oxidizing water is utilized through the first heat exchange sleeve and the second heat exchange sleeve, so that the heat recovery is facilitated, the heat recovery efficiency is improved, and the use is convenient.
Drawings
FIG. 1 is a schematic structural view of the present invention;
FIG. 2 is a schematic view of the internal structure of the heat-insulating cover body of the present invention.
In the figure: 1. a metal tank body; 2. clay block lining; 3. a power plug; 4. a second pure copper wire; 5. integrating a terminal; 6. a first pure copper wire; 7. sealing the insulated joint; 8. a conductive joint; 9. an anode electrode sheet; 10. a T-shaped seat; 11. an ionic membrane plate; 12. an insulating spacer; 13. a cathode electrode sheet; 14. an integrated plug; 15. an insulating slot cover; 16. a hollow conduit; 17. a heat insulating cover body; 18. a first heat exchange jacket; 19. a first inlet pipe; 20. a second heat exchange jacket; 21. a converging duct; 22. a second inlet pipe.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1-2, the present invention provides a technical solution of an electrolytic cell structure for generating electrolyzed oxidizing water:
according to the figure 1-2, comprises a metal tank body 1 and a clay block lining 2, wherein the inner wall of the metal tank body 1 is connected with the clay block lining 2 in a fitting manner, a T-shaped seat 10 is fixedly arranged at the bottom of the inner cavity of the clay block lining 2, an insulating partition plate 12 is fixedly arranged in the middle of the top end of the T-shaped seat 10, the inner cavity of the clay block lining 2 is divided into a left half electrolytic area and a right half electrolytic area by the insulating partition plate 12 and the T-shaped seat 10, ion membrane plates 11 are respectively arranged in the left half electrolytic area and the right half electrolytic area, the two ion membrane plates 11 are respectively connected with the T-shaped seat 10, cathode electrode plates 13 are respectively and fixedly arranged on the two sides of the insulating partition plate 12, anode electrode plates 9 are respectively connected on the two sides of the inner cavity of the clay block lining 2 in a fitting manner, conductive connectors 8 are respectively connected in the middle parts of the two sides of the metal tank body 1 in an inserting manner, sealed insulating connectors 7 are respectively connected with one end of each conductive connector 8, a first pure copper conductor 6 is respectively connected with one end of each sealed insulating connector 7, the one end of two first pure copper conductor 6 all with the output fixed connection of the integrated terminal 5 that is equipped with, the input of integrated terminal 5 is connected with second pure copper conductor 4, the one end fixedly connected with power plug 3 of second pure copper conductor 4, the one end of two negative pole electrode slices 13 all with the integrated plug 14 fixed connection who is equipped with, the inside in half electrolysis district on the left side and the inside in half electrolysis district on the right side all communicate there is hollow pipe 16, two hollow pipe 16 all with the heat recovery structure connection that is equipped with.
As shown in fig. 1 and 2, the heat recovery structure includes a heat insulation cover body 17, a first heat exchange jacket 18 and a second heat exchange jacket 20 are installed inside the heat insulation cover body 17, the first heat exchange jacket 18 and the second heat exchange jacket 20 are connected with corresponding hollow conduits 16, a first inlet pipe 19 and a second inlet pipe 22 are respectively installed at one end of the first heat exchange jacket 18 and one end of the second heat exchange jacket 20, a confluence pipe 21 is fixedly connected between the first heat exchange jacket 18 and the second heat exchange jacket 20, so as to facilitate heat recovery and improve heat recovery, a polyfluorinated ethylene propylene coating is coated on the inner wall of the clay block lining 2, the polyfluorinated ethylene propylene coating is composed of tetrafluoroethylene and hexafluoropropylene, the content of hexafluoropropylene is 10-15%, the anode electrode sheet 9 and the cathode electrode sheet 13 are both platinum-titanium alloy electrodes, and has good conductivity and good service life, the wire current-carrying capacity of the pure copper wire 4 of second is the wire current-carrying capacity twice of the pure copper wire 6 of first, and the heat exchange coefficient of first heat exchange sleeve 18 is inequality with the heat exchange coefficient of second heat exchange sleeve 20, can carry out good heat exchange, improves the heat recovery effect, and the top lock of metal cell body 1 is connected with insulating capping 15, and insulating capping 15's middle part and cathode electrode piece 13 sliding connection improve the safeguard effect.
When the electrolytic cell is used, current is introduced into the anode electrode plate 9, the first pure copper wire 6 and the second pure copper wire 4 are respectively introduced into the left half electrolysis region and the right half electrolysis region, and then the cathode electrode plate 13 is utilized to form a passage, so that the electrolysis efficiency of the electrolytic cell in unit time is greatly improved, the generation amount of acidic oxidation potential water in unit time is improved, the practicability is high, discharged gas can be conveniently collected and the acidic oxidation water can be conveniently recycled through the two hollow guide pipes 16, and the heat contained in the electrolytic cell can be conveniently recycled through the first heat exchange sleeve 18 and the second heat exchange sleeve 20, so that the heat recycling efficiency is improved, and the use is convenient.
In the description of the present invention, it is to be understood that the indicated orientations or positional relationships are based on the orientations or positional relationships shown in the drawings and are only for convenience in describing the present invention and simplifying the description, but are not intended to indicate or imply that the indicated devices or elements must have a particular orientation, be constructed and operated in a particular orientation, and are not to be construed as limiting the present invention.
In the present invention, unless otherwise explicitly specified or limited, for example, it may be fixedly attached, detachably attached, or integrated; can be mechanically or electrically connected; the terms may be directly connected or indirectly connected through an intermediate, and may be communication between two elements or interaction relationship between two elements, unless otherwise specifically limited, and the specific meaning of the terms in the present invention will be understood by those skilled in the art according to specific situations.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (7)

1. An electrolytic tank structure for generating acidic electrolyzed oxidizing water comprises a metal tank body (1) and a clay block lining (2), and is characterized in that the inner wall of the metal tank body (1) is attached and connected with the clay block lining (2), a T-shaped seat (10) is fixedly installed at the bottom of an inner cavity of the clay block lining (2), an insulating partition plate (12) is fixedly arranged in the middle of the top end of the T-shaped seat (10), the inner cavity of the clay block lining (2) is divided into a left half electrolytic area and a right half electrolytic area by the insulating partition plate (12) and the T-shaped seat (10), ion membrane plates (11) are respectively installed inside the left half electrolytic area and the right half electrolytic area, the two ion membrane plates (11) are respectively connected with the T-shaped seat (10), cathode electrode plates (13) are respectively fixedly installed on two sides of the insulating partition plate (12), and anodes (9) are respectively attached and connected with two sides of the inner cavity of the clay block lining (2), the middle parts of two sides of the metal tank body (1) are respectively connected with a conductive joint (8) in an inserting way, one end of each of the two conductive joints (8) is connected with a sealing insulating joint (7), one end of each of the two sealing insulating joints (7) is connected with a first pure copper wire (6), one end of each of the two first pure copper wires (6) is fixedly connected with the output end of the integrated terminal (5), the input end of the integrated wiring terminal (5) is connected with a second pure copper wire (4), one end of the second pure copper wire (4) is fixedly connected with an electric power plug (3), one ends of the two cathode electrode plates (13) are fixedly connected with an integrated plug (14), the inside of the left half electrolysis area and the inside of the right half electrolysis area are both communicated with hollow conduits (16), and the two hollow conduits (16) are both connected with a heat recovery structure arranged on the heat recovery structure.
2. An electrolytic cell structure for generating electrolyzed oxidizing water according to claim 1, characterized in that: the heat recovery structure includes the heat insulating cover body (17), the internally mounted of the heat insulating cover body (17) has first heat exchange cover (18) and second heat exchange cover (20), first heat exchange cover (18) and second heat exchange cover (20) are established with the hollow pipe (16) cover that corresponds and are connected, first pipe (19) and second pipe (22) are advanced to the one end of first heat exchange cover (18) and the one end of second heat exchange cover (20) are installed respectively, fixedly connected with conflux pipeline (21) between first heat exchange cover (18) and the second heat exchange cover (20).
3. An electrolytic cell structure for generating electrolyzed oxidizing water according to claim 1, characterized in that: the inner wall of the clay block lining (2) is coated with a polyfluorinated ethylene propylene coating, the polyfluorinated ethylene propylene coating is composed of tetrafluoroethylene and hexafluoropropylene, and the content of the hexafluoropropylene is 10-15%.
4. An electrolytic cell structure for generating electrolyzed oxidizing water according to claim 1, characterized in that: the anode electrode plate (9) and the cathode electrode plate (13) are both platinum-titanium alloy electrodes.
5. An electrolytic cell structure for generating electrolyzed oxidizing water according to claim 1, characterized in that: the wire current-carrying capacity of the second pure copper wire (4) is twice that of the first pure copper wire (6).
6. An electrolytic cell structure for generating electrolyzed oxidizing water according to claim 2, characterized in that: the heat exchange coefficient of the first heat exchange sleeve (18) is different from that of the second heat exchange sleeve (20).
7. An electrolytic cell structure for generating electrolyzed oxidizing water according to claim 1, characterized in that: the top end of the metal tank body (1) is connected with an insulating tank cover (15) in a buckling mode, and the middle of the insulating tank cover (15) is connected with the cathode electrode plate (13) in a sliding mode.
CN202210248311.4A 2022-03-14 2022-03-14 Electrolytic tank structure for generating acidic electrolyzed oxidizing water Active CN114635146B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07236888A (en) * 1994-02-28 1995-09-12 Nippon Intec Kk Electrolytic water and oxidation potential water making apparatus
JPH07328639A (en) * 1994-06-02 1995-12-19 Nippon Intec Kk Oxidation potential water forming device
CN104562092A (en) * 2015-02-03 2015-04-29 奉新赣锋锂业有限公司 Multi-anode lithium metal electrolytic bath
CN206680226U (en) * 2017-03-27 2017-11-28 长春云卫科技有限公司 Acidic oxidized electric potential water produces electrolytic cell
CN211734057U (en) * 2019-12-21 2020-10-23 武汉丽辉新技术有限公司 Acidic oxidation potential water generator
CN212246339U (en) * 2020-05-08 2020-12-29 河北宏泰丰业医疗器械有限公司 Electrolytic tank of acidic oxidation potential water generator
CN213803049U (en) * 2020-11-06 2021-07-27 江西坤灿环保科技股份有限公司 Acidic electrolytic tank
CN214936277U (en) * 2021-06-25 2021-11-30 石首市金祥米业有限公司 Acidic oxidation potential water generating device

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07236888A (en) * 1994-02-28 1995-09-12 Nippon Intec Kk Electrolytic water and oxidation potential water making apparatus
JPH07328639A (en) * 1994-06-02 1995-12-19 Nippon Intec Kk Oxidation potential water forming device
CN104562092A (en) * 2015-02-03 2015-04-29 奉新赣锋锂业有限公司 Multi-anode lithium metal electrolytic bath
CN206680226U (en) * 2017-03-27 2017-11-28 长春云卫科技有限公司 Acidic oxidized electric potential water produces electrolytic cell
CN211734057U (en) * 2019-12-21 2020-10-23 武汉丽辉新技术有限公司 Acidic oxidation potential water generator
CN212246339U (en) * 2020-05-08 2020-12-29 河北宏泰丰业医疗器械有限公司 Electrolytic tank of acidic oxidation potential water generator
CN213803049U (en) * 2020-11-06 2021-07-27 江西坤灿环保科技股份有限公司 Acidic electrolytic tank
CN214936277U (en) * 2021-06-25 2021-11-30 石首市金祥米业有限公司 Acidic oxidation potential water generating device

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
余浩 等: ""酸性氧化电位水制备技术研究进展"", 《中国消毒学杂志》, pages 155 - 158 *

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