CN114591661A - Microcrystalline color 5D skin-feel art paint and preparation method thereof - Google Patents
Microcrystalline color 5D skin-feel art paint and preparation method thereof Download PDFInfo
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- CN114591661A CN114591661A CN202210070774.6A CN202210070774A CN114591661A CN 114591661 A CN114591661 A CN 114591661A CN 202210070774 A CN202210070774 A CN 202210070774A CN 114591661 A CN114591661 A CN 114591661A
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- 239000003973 paint Substances 0.000 title claims abstract description 78
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 129
- 229920001971 elastomer Polymers 0.000 claims abstract description 52
- 239000000806 elastomer Substances 0.000 claims abstract description 52
- 239000000839 emulsion Substances 0.000 claims abstract description 36
- 239000004327 boric acid Substances 0.000 claims abstract description 34
- 239000011347 resin Substances 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000919 ceramic Substances 0.000 claims abstract description 14
- 239000011521 glass Substances 0.000 claims abstract description 14
- 229920000642 polymer Polymers 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000004814 polyurethane Substances 0.000 claims abstract description 13
- 229920002635 polyurethane Polymers 0.000 claims abstract description 12
- 229920001661 Chitosan Polymers 0.000 claims abstract description 9
- 210000000988 bone and bone Anatomy 0.000 claims abstract description 9
- 239000012188 paraffin wax Substances 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 238000001723 curing Methods 0.000 claims description 14
- 239000006185 dispersion Substances 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000002518 antifoaming agent Substances 0.000 claims description 10
- -1 boric acid modified carbonate Chemical class 0.000 claims description 10
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 229920001684 low density polyethylene Polymers 0.000 claims description 10
- 239000004702 low-density polyethylene Substances 0.000 claims description 10
- 239000000741 silica gel Substances 0.000 claims description 10
- 229910002027 silica gel Inorganic materials 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 238000004806 packaging method and process Methods 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 238000009461 vacuum packaging Methods 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 4
- 238000007580 dry-mixing Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000009210 therapy by ultrasound Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 19
- 239000000654 additive Substances 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract 3
- 230000036548 skin texture Effects 0.000 abstract 1
- 238000003848 UV Light-Curing Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000006221 furniture coating Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 235000014594 pastries Nutrition 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention provides a microcrystalline color 5D skin-feel art paint and a preparation method thereof. The 5D skin-feel art paint comprises the following components: 15-45% of boric acid modified polymer emulsion, 15-35% of nano transparent polyurethane elastic resin, 10-25% of modified transparent skin-feel elastic resin, 5-15% of microcrystalline color powder, 5-10% of chitosan micro powder, 5-10% of elastic powder, 3-10% of degummed defatted animal bone powder, 3-8% of chlorinated paraffin, 3-5% of other additives, 3-8% of animal flake powder and 10-40% of water. Glass, ceramic and animal flake powder with the microcrystalline color effect are added into the water-based transparent art paint to be dispersed, the microcrystalline color effect is endowed to the art paint, the microcrystalline colors with different colors are combined to obtain varieties with different colors or mixed color varieties, the ornamental effect of the art paint is greatly improved, the resin emulsion is modified to obtain the fireproof and waterproof effect, the efficacy of the art paint is improved, and the elastomer material is added to enable the art paint to be elastic, fine and soft, further endow the art paint with 5D skin feeling, and fully embody the skin texture and the artistic aesthetic feeling.
Description
Technical Field
The invention relates to the technical field of production and preparation of building materials, in particular to a microcrystalline color 5D skin-feel art paint and a preparation method thereof.
Background
With the improvement of living standard and social development of people, consumers pay more and more attention to the artistic aesthetic feeling of architectural decoration. The art paint originates from Europe, the advanced process is spread from Europe, and after entering the domestic market, the art paint is popular and advocated by people with novel decorative style and unusual decorative effect. The art paint is a novel wall decoration art paint, and is added with modern high-tech treatment process, so that the product is nontoxic and environment-friendly, and simultaneously has the functions of water resistance, dust prevention, flame retardance and the like, and the high-quality art paint can be brushed in batches, has strong adsorbability and is updated in color.
The 5D artistic paint is one kind of artistic paint, and can make wall surface fully show the artistic aesthetic feeling of nature. Skin-feel furniture originated in italy and is named after paint films like baby skin feel and is called "blue blood noble in luxury goods". In recent years, skin feel effects have rapidly prevailed in China, and the skin feel effects have become a new trend of furniture coating. Especially in the high-end customization field, the skin-feel effect is rather regarded as a gold partner for light luxury customization of furniture, and the skin-feel paint naturally becomes a fresh air opening of furniture paint. At present, good skin feel paint products can be said to be pastry, but the supply is limited.
The skin-feel paint has the following characteristics: the skin-care product is smooth, has slight elasticity, and feels as smooth, elastic and comfortable as the skin of a newborn; the gloss of the surface of the paint film is mainly matte, and the matte effect below 15 degrees can be realized; the surface is fine and smooth and has texture; the paint can be self-repaired, and the surface of the paint film is slightly scratched, thereby having the self-repairing function.
Skin-feel panels have become a hot spot for applications in the furniture and upholstery industry due to their good tactile and visual effects. Currently, skin feel effects are generally obtained by three processing techniques:
membrane pressure technology
And (3) rolling UV finish on a workpiece with the primer, pressing and flattening the skin-feel finish by using a skin-feel film, and removing the film after the UV light source is cured to obtain a skin-feel product with film pressure. The film pressing technique is only suitable for processing plane products. And due to the microstructure limitation of the skin-feel film, the aging property of the skin feel can be limited under certain conditions. At present, skin feel films are disposable, so that the operation cost is high.
Second, coating technology
At present, the self-drying paint (PU, water-based) can realize the skin feeling effect through the paint formula.
Curing technology of three-quasi-molecule lamp
1. Principle of operation
IOT from Germany created a 172nm UV curing apparatus (EXCIMER) and has unique properties which can be referred to as "black technology" for UV curing technology.
Acrylate double bonds in the UV coating formulation, upon absorption of 172nm UV light, can generate free radicals without the need for photoinitiators. Meanwhile, the penetration depth of UV at 172nm is only 100 to 500nm, so that only one layer of the paint having a very thin surface is cured. Polymerization and crosslinking of this thin layer shrinks to form a matte surface and floats on the uncured underlying liquid, providing a matte finish. However, the curing is carried out in a nitrogen environment, so that the oxygen concentration of the operation environment is lower than 100 ppm; and then the whole curing is carried out by adopting the conventional UV or electron beam.
This method of matting is called "physical matting" because it does not require the use of a matting agent. While polymerization and crosslinking of the surface at 172nm provides high surface hardness and high coating density.
2. Process and apparatus
Excimer lamp curing technology is currently only available for flat products. And (3) rolling UV skin-feel finishing paint on a workpiece with the UV primer, and obtaining a skin-feel product through ultra-matte UV equipment and conventional UV curing equipment.
Disclosure of Invention
In order to solve the technical problems, the invention provides the microcrystalline color 5D skin-feel art paint and the preparation method thereof, the glass, the ceramic and the animal flake powder with the microcrystalline color effect are added into the water-based transparent art paint, the resin emulsion is used for modification, so that the waterproof and fireproof effects are obtained, and the elastomer material is added to endow the art paint with the 5D skin-feel.
In order to achieve the technical purpose, the technical scheme of the invention is realized as follows:
the microcrystalline color 5D skin-feel art paint comprises the following components:
15-45% of boric acid modified polymer emulsion
15-35% of nano transparent polyurethane elastic resin
10 to 25 percent of modified transparent skin-feel elastic resin
5 to 15 percent of microcrystalline color powder
5 to 10 percent of chitosan micro powder
5 to 10 percent of elastic powder
3-10% of degummed and degreased animal bone powder
3 to 8 percent of chlorinated paraffin
3 to 5 percent of other auxiliary agents
10-40% of water.
Preferably, the boric acid modified polymer emulsion comprises boric acid modified acrylic emulsion and boric acid modified carbonate emulsion, wherein the proportion of the boric acid modified acrylic emulsion to the boric acid modified carbonate emulsion is 40-60% to 40-50%.
Preferably, the microcrystalline color powder comprises microcrystalline glass color powder and microcrystalline ceramic color powder, wherein the ratio of the microcrystalline glass color powder to the microcrystalline ceramic color powder is 40-80% to 20-50%.
Preferably, the other auxiliary agents comprise a curing agent, a defoaming agent, a film forming agent and a dispersing agent, and the proportion ratio of the curing agent to the defoaming agent to the film forming agent to the dispersing agent is 1-2:1-3:2-3: 1-2.
Preferably, the elastic powder comprises POE elastomer powder, PVC elastomer powder, LDPE elastomer powder, EVA elastomer powder and silica gel elastomer powder, wherein the proportion of the POE elastomer powder, the PVC elastomer powder, the LDPE elastomer powder, the EVA elastomer powder and the silica gel elastomer powder is 1-2:1-3:2-3:1-2: 2-5.
Further, the microcrystalline color 5D skin-feel art paint also comprises 3-8% of animal scale powder.
The preparation method of the microcrystalline color 5D skin-feel art paint comprises the following steps:
(1) dry mixing: accurately weighing the required parts by weight of microcrystalline color powder, chitosan micro powder, elastic powder, degummed defatted animal bone powder and animal scale powder according to a formula, uniformly stirring and mixing the materials, sieving the materials by a 100-plus-400-mesh sieve, and uniformly mixing the materials again for later use;
(2) and dispersing: adding all boric acid modified polymer emulsion, 1/3-1/2 nanometer transparent polyurethane elastic resin and 1/3-1/2 modified transparent skin-feel elastic resin into a premixing dispersion cylinder, starting a dispersion machine, adding 1/2-2/3 solvent water at the rotation speed of 500-;
(3) adjusting viscosity: adding the residual nano transparent polyurethane elastic resin, the modified transparent skin-feel elastic resin, solvent water and chlorinated paraffin into the paint, starting a dispersion machine to stir and disperse, controlling the rotating speed to be 500-1000r/min, dispersing for 10-25min, adjusting the viscosity of the paint, filtering the dispersed paint through a 100-400-mesh sieve to remove large particles or carrying out ultrasonic treatment on the dispersed paint at 10-20 ℃ for 20-30min to prepare the finished 5D skin-feel artistic paint;
(4) and packaging: and (3) carrying out low-temperature secondary filtration on the obtained finished product 5D skin-feel artistic paint by using a 80-200-mesh sieve for returning to a cage for 5-10min, carrying out low-temperature vacuum packaging, and then packaging and warehousing.
Wherein the temperature of the low-temperature secondary filtration and cage returning in the step 4 of the preparation method is 5-15 ℃, and the temperature of the low-temperature vacuum packaging is 5-10 ℃.
The invention has the beneficial effects that: the microcrystalline-color 5D skin-feel art paint prepared by the invention is characterized in that glass, ceramics and animal flake powder with microcrystalline-color effect are added into the water-based transparent art paint to be dispersed, and then the microcrystalline-color effect is given to the art paint; the paint can be made into different artistic shapes according to actual needs, achieves different artistic effects, has wide application range, is a general artistic paint for inner and outer walls, and can be used for buildings such as high-rise villas, living quarters and the like.
Detailed Description
The technical solutions claimed in the present invention will be described clearly and completely with reference to specific embodiments of the present invention, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The microcrystalline color 5D skin-feel art paint comprises the following components:
boric acid modified polymer emulsion 35%
15 percent of nano transparent polyurethane elastic resin
10 percent of modified transparent skin-feel elastic resin
Microcrystalline color powder 5%
5 percent of chitosan micro powder
5 percent of elastic powder
6 percent of degummed and degreased animal bone powder
Chlorinated paraffin 3%
3 percent of animal scale powder
3 percent of other auxiliary agents
10 percent of water.
Further, the boric acid modified polymer emulsion comprises boric acid modified acrylic emulsion and boric acid modified carbonate emulsion, wherein the proportion of the boric acid modified acrylic emulsion to the boric acid modified carbonate emulsion is 60% to 40%.
Furthermore, the microcrystalline color powder comprises microcrystalline glass color powder and microcrystalline ceramic color powder, wherein the ratio of the microcrystalline glass color powder to the microcrystalline ceramic color powder is 50% to 50%.
Further, the other auxiliary agents comprise a curing agent, a defoaming agent, a film forming agent and a dispersing agent, wherein the ratio of the curing agent to the defoaming agent to the film forming agent to the dispersing agent is 1:1:2: 1.
Further, the elastic powder comprises POE elastomer powder, PVC elastomer powder, LDPE elastomer powder, EVA elastomer powder and silica gel elastomer powder, wherein the proportion of the POE elastomer powder, the PVC elastomer powder, the LDPE elastomer powder, the EVA elastomer powder and the silica gel elastomer powder is 1:1:2:1: 2.
Example 2
The microcrystalline color 5D skin-feel art paint comprises the following components:
boric acid modified polymer emulsion 15%
15 percent of nano transparent polyurethane elastic resin
10 percent of modified transparent skin-feel elastic resin
15 percent of microcrystalline color powder
5 percent of chitosan micro powder
5 percent of elastic powder
5 percent of degummed and degreased animal bone powder
Chlorinated paraffin 5%
5 percent of animal scale powder
3 percent of other auxiliary agents
And 17% of water.
Further, the boric acid modified polymer emulsion comprises boric acid modified acrylic emulsion and boric acid modified carbonate emulsion, wherein the proportion of the boric acid modified acrylic emulsion to the boric acid modified carbonate emulsion is 60% to 40%.
Furthermore, the microcrystalline color powder comprises microcrystalline glass color powder and microcrystalline ceramic color powder, wherein the ratio of the microcrystalline glass color powder to the microcrystalline ceramic color powder is 80% to 20%.
Further, the other auxiliary agents comprise a curing agent, a defoaming agent, a film forming agent and a dispersing agent, wherein the ratio of the curing agent to the defoaming agent to the film forming agent to the dispersing agent is 2:3:3: 2.
Further, the elastic powder comprises POE elastomer powder, PVC elastomer powder, LDPE elastomer powder, EVA elastomer powder and silica gel elastomer powder, wherein the proportion of the POE elastomer powder, the PVC elastomer powder, the LDPE elastomer powder, the EVA elastomer powder and the silica gel elastomer powder is 2:3:3:2: 5.
Example 3
The microcrystalline color 5D skin-feel art paint comprises the following components:
boric acid modified polymer emulsion 15%
15 percent of nano transparent polyurethane elastic resin
10 percent of modified transparent skin-feel elastic resin
5 percent of microcrystalline color powder
5 percent of chitosan micro powder
5 percent of elastic powder
5 percent of degummed and degreased animal bone powder
Chlorinated paraffin 6%
8 percent of animal scale powder
Other additives are 6 percent
And 20% of water.
Further, the boric acid modified polymer emulsion comprises boric acid modified acrylic emulsion and boric acid modified carbonate emulsion, wherein the proportion of the boric acid modified acrylic emulsion to the boric acid modified carbonate emulsion is 50% to 50%.
Furthermore, the microcrystalline color powder comprises microcrystalline glass color powder and microcrystalline ceramic color powder, wherein the ratio of the microcrystalline glass color powder to the microcrystalline ceramic color powder is 50% to 50%.
Further, the other auxiliary agents comprise a curing agent, a defoaming agent, a film forming agent and a dispersing agent, wherein the ratio of the curing agent to the defoaming agent to the film forming agent to the dispersing agent is 2:1:3: 1.
Further, the elastic powder comprises POE elastomer powder, PVC elastomer powder, LDPE elastomer powder, EVA elastomer powder and silica gel elastomer powder, wherein the proportion of the POE elastomer powder, the PVC elastomer powder, the LDPE elastomer powder, the EVA elastomer powder and the silica gel elastomer powder is 1:3:2:2: 5.
The preparation method of the microcrystalline color 5D skin-feel art paint based on the embodiment comprises the following steps:
(1) and dry mixing: accurately weighing the required parts by weight of microcrystalline color powder, chitosan micro powder, elastic powder, degummed and defatted animal bone powder and animal scale powder according to the formula, stirring and mixing the materials uniformly, sieving the materials by a 200-mesh sieve, and mixing the materials uniformly for later use;
(2) and dispersing: adding all boric acid modified polymer emulsion, 1/2 nano transparent polyurethane elastic resin and 1/2 modified transparent skin-feel elastic resin into a premixing dispersion cylinder, starting a dispersion machine, adding 2/3 solvent water at the rotating speed of 800min, fully and uniformly stirring, adding all the mixed materials obtained in the step 1, adding all other auxiliary agents, standing for 45min, and fully stirring at the rotating speed of 800r/min of the dispersion machine to form a pre-dispersion paint;
(3) adjusting viscosity: adding the rest nano transparent polyurethane elastic resin, the modified transparent skin-feel elastic resin, solvent water and chlorinated paraffin into the paint vehicle, starting a dispersion machine to stir and disperse, controlling the rotating speed to be 800r/min, dispersing for 25min, adjusting the viscosity of the paint vehicle, sieving the dispersed paint vehicle with a 200-mesh sieve to filter out large particles or performing ultrasonic treatment on the dispersed paint vehicle at 20 ℃ for 30min to prepare the finished 5D skin-feel artistic paint;
(4) and packaging: and (3) carrying out low-temperature secondary filtration on the obtained finished product 5D skin-feel artistic paint by using a 200-mesh sieve for 10min, carrying out low-temperature vacuum packaging, and then packaging and warehousing.
Furthermore, the temperature of the low-temperature secondary filtration and cage returning in the step 4 of the preparation method is 10 ℃, and the temperature of the low-temperature vacuum packaging is 5 ℃.
The microcrystalline color 5D skin-feel paint produced in each example was characterized and tested and applied, and the results are shown in the following table:
the microcrystalline-color 5D skin-feel art paint prepared by the invention is characterized in that glass, ceramics and animal flake powder with microcrystalline-color effect are added into the water-based transparent art paint to be dispersed, and then the microcrystalline-color effect is given to the art paint; the paint can be made into different artistic shapes according to actual needs, achieves different artistic effects, has wide application range, can effectively resist water, alkali, dirt, washing, aging and the like, is an artistic paint material commonly used for inner and outer walls, and can be used for buildings such as high-rise villas, living quarters and the like.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (8)
1. The microcrystalline color 5D skin-feel art paint is characterized by comprising the following components:
15-45% of boric acid modified polymer emulsion
15-35% of nano transparent polyurethane elastic resin
10 to 25 percent of modified transparent skin-feel elastic resin
5 to 15 percent of microcrystalline color powder
5 to 10 percent of chitosan micro powder
5 to 10 percent of elastic powder
3-10% of degummed defatted animal bone powder
3 to 8 percent of chlorinated paraffin
3 to 5 percent of other auxiliary agents
10-40% of water.
2. The microcrystalline color 5D skin-feel paint according to claim 1, wherein the boric acid modified polymer emulsion comprises boric acid modified acrylic emulsion and boric acid modified carbonate emulsion, wherein the ratio of the boric acid modified acrylic emulsion to the boric acid modified carbonate emulsion is 40-60% to 40-50%.
3. The microcrystalline color 5D skin-feel paint as claimed in claim 1, wherein the microcrystalline color powder comprises microcrystalline glass color powder and microcrystalline ceramic color powder, and the ratio of the microcrystalline glass color powder to the microcrystalline ceramic color powder is 40-80% to 20-50%.
4. The microcrystalline color 5D skin-feel art paint as claimed in claim 1, wherein the other auxiliaries comprise a curing agent, a defoaming agent, a film-forming agent and a dispersing agent, and the proportion of the curing agent, the defoaming agent, the film-forming agent and the dispersing agent is 1-2:1-3:2-3: 1-2.
5. The microcrystalline color 5D skin-feel artistic paint according to claim 1, wherein the elastic powder comprises POE elastomer powder, PVC elastomer powder, LDPE elastomer powder, EVA elastomer powder and silica gel elastomer powder, and the proportion ratio of the POE elastomer powder to the PVC elastomer powder to the LDPE elastomer powder to the EVA elastomer powder to the silica gel elastomer powder is 1-2:1-3:2-3:1-2: 2-5.
6. The microcrystalline color 5D skin paint of claim 1 further comprising 3-8% animal flake powder.
7. A method of preparing the microcrystalline color 5D skin-feel paint according to any one of claims 1 to 6, comprising the steps of:
(1) and dry mixing: accurately weighing the required parts by weight of microcrystalline color powder, chitosan micro powder, elastic powder, degummed defatted animal bone powder and animal scale powder according to a formula, uniformly stirring and mixing the materials, sieving the materials by a 100-plus-400-mesh sieve, and uniformly mixing the materials again for later use;
(2) and dispersing: adding all boric acid modified polymer emulsion, 1/3-1/2 nanometer transparent polyurethane elastic resin and 1/3-1/2 modified transparent skin-feel elastic resin into a premixing dispersion cylinder, starting a dispersion machine, adding 1/2-2/3 solvent water at the rotation speed of 500-;
(3) adjusting viscosity: adding the residual nano transparent polyurethane elastic resin, the modified transparent skin-feel elastic resin, solvent water and chlorinated paraffin into the paint, starting a dispersion machine to stir and disperse, controlling the rotating speed to be 500-1000r/min, dispersing for 10-25min, adjusting the viscosity of the paint, filtering the dispersed paint through a 100-400-mesh sieve to remove large particles or carrying out ultrasonic treatment on the dispersed paint at 10-20 ℃ for 20-30min to prepare the finished 5D skin-feel artistic paint;
(4) and packaging: and (3) carrying out low-temperature secondary filtration on the obtained finished product 5D skin-feel artistic paint by using a 80-200-mesh sieve for returning to a cage for 5-10min, carrying out low-temperature vacuum packaging, and then packaging and warehousing.
8. The preparation method of the microcrystalline color 5D skin feel art paint as claimed in claim 7, wherein the temperature of the low-temperature secondary filtration in step 4 of the preparation method is 5-15 ℃ and the temperature of the low-temperature vacuum packaging is 5-10 ℃.
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