CN114586776A - Dispersible oil suspending agent containing metamifop and bispyribac-sodium and preparation method thereof - Google Patents
Dispersible oil suspending agent containing metamifop and bispyribac-sodium and preparation method thereof Download PDFInfo
- Publication number
- CN114586776A CN114586776A CN202210288536.2A CN202210288536A CN114586776A CN 114586776 A CN114586776 A CN 114586776A CN 202210288536 A CN202210288536 A CN 202210288536A CN 114586776 A CN114586776 A CN 114586776A
- Authority
- CN
- China
- Prior art keywords
- sodium
- bispyribac
- metamifop
- dispersible oil
- polyoxyethylene ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- FUHMZYWBSHTEDZ-UHFFFAOYSA-M bispyribac-sodium Chemical compound [Na+].COC1=CC(OC)=NC(OC=2C(=C(OC=3N=C(OC)C=C(OC)N=3)C=CC=2)C([O-])=O)=N1 FUHMZYWBSHTEDZ-UHFFFAOYSA-M 0.000 title claims abstract description 56
- ADDQHLREJDZPMT-AWEZNQCLSA-N (S)-metamifop Chemical compound O=C([C@@H](OC=1C=CC(OC=2OC3=CC(Cl)=CC=C3N=2)=CC=1)C)N(C)C1=CC=CC=C1F ADDQHLREJDZPMT-AWEZNQCLSA-N 0.000 title claims abstract description 48
- 239000000375 suspending agent Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 18
- 239000002612 dispersion medium Substances 0.000 claims abstract description 10
- 239000004480 active ingredient Substances 0.000 claims abstract description 9
- 239000003921 oil Substances 0.000 claims description 38
- 235000019198 oils Nutrition 0.000 claims description 38
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 28
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 28
- 239000012053 oil suspension Substances 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 13
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 12
- 239000002270 dispersing agent Substances 0.000 claims description 12
- 239000003381 stabilizer Substances 0.000 claims description 12
- 238000000227 grinding Methods 0.000 claims description 11
- -1 styryl phenol Chemical compound 0.000 claims description 11
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 10
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims description 10
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- YZYASTRURKBPPS-UHFFFAOYSA-N C(CCC(=O)OCCCCCC(C)C)(=O)OCCCCCC(C)C.[Na] Chemical compound C(CCC(=O)OCCCCCC(C)C)(=O)OCCCCCC(C)C.[Na] YZYASTRURKBPPS-UHFFFAOYSA-N 0.000 claims description 6
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 6
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 6
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 6
- 229920000053 polysorbate 80 Polymers 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- 229910021485 fumed silica Inorganic materials 0.000 claims description 5
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 4
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 4
- 239000001593 sorbitan monooleate Substances 0.000 claims description 4
- 235000011069 sorbitan monooleate Nutrition 0.000 claims description 4
- 229940035049 sorbitan monooleate Drugs 0.000 claims description 4
- 239000000600 sorbitol Substances 0.000 claims description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 4
- 239000008158 vegetable oil Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 229930182478 glucoside Natural products 0.000 claims description 3
- 150000004702 methyl esters Chemical class 0.000 claims description 3
- 238000000518 rheometry Methods 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 229920002261 Corn starch Polymers 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 239000004147 Sorbitan trioleate Substances 0.000 claims description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 239000003849 aromatic solvent Substances 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 239000002285 corn oil Substances 0.000 claims description 2
- 235000005687 corn oil Nutrition 0.000 claims description 2
- 239000008120 corn starch Substances 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 2
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 2
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 2
- 239000002609 medium Substances 0.000 claims description 2
- 229940073769 methyl oleate Drugs 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229960003975 potassium Drugs 0.000 claims description 2
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 2
- 235000019337 sorbitan trioleate Nutrition 0.000 claims description 2
- 229960000391 sorbitan trioleate Drugs 0.000 claims description 2
- 239000012141 concentrate Substances 0.000 claims 5
- 235000019797 dipotassium phosphate Nutrition 0.000 claims 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 claims 1
- BPNQAJFJFNDPPP-UHFFFAOYSA-N furan-2,5-dione;prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 BPNQAJFJFNDPPP-UHFFFAOYSA-N 0.000 claims 1
- 229920005646 polycarboxylate Polymers 0.000 claims 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 abstract description 29
- 230000000694 effects Effects 0.000 abstract description 13
- 238000009333 weeding Methods 0.000 abstract description 13
- 239000004009 herbicide Substances 0.000 abstract description 9
- 230000002363 herbicidal effect Effects 0.000 abstract description 8
- 239000000725 suspension Substances 0.000 abstract description 8
- 240000007594 Oryza sativa Species 0.000 abstract description 5
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 5
- 235000009566 rice Nutrition 0.000 abstract description 5
- 230000007547 defect Effects 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 abstract description 4
- 230000000857 drug effect Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000005923 long-lasting effect Effects 0.000 abstract description 3
- 238000012216 screening Methods 0.000 abstract description 3
- 230000001934 delay Effects 0.000 abstract description 2
- 231100000053 low toxicity Toxicity 0.000 abstract description 2
- 238000011282 treatment Methods 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 10
- 238000003860 storage Methods 0.000 description 7
- YWWNNLPSZSEZNZ-UHFFFAOYSA-N n,n-dimethyldecan-1-amine Chemical compound CCCCCCCCCCN(C)C YWWNNLPSZSEZNZ-UHFFFAOYSA-N 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 239000000575 pesticide Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000007774 longterm Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 244000058871 Echinochloa crus-galli Species 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000000361 pesticidal effect Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 108010000700 Acetolactate synthase Proteins 0.000 description 1
- 102000000452 Acetyl-CoA carboxylase Human genes 0.000 description 1
- 108010016219 Acetyl-CoA carboxylase Proteins 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241000234646 Cyperaceae Species 0.000 description 1
- 244000075634 Cyperus rotundus Species 0.000 description 1
- 244000152970 Digitaria sanguinalis Species 0.000 description 1
- 235000010823 Digitaria sanguinalis Nutrition 0.000 description 1
- 244000025670 Eleusine indica Species 0.000 description 1
- 235000014716 Eleusine indica Nutrition 0.000 description 1
- 241001553700 Euphorbia lathyris Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000004548 suspo-emulsion Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a dispersible oil suspending agent containing metamifop and bispyribac-sodium, which comprises: active ingredients, emulsifiers, rheological agents, solvents and dispersion media; the active ingredients comprise metamifop and bispyribac-sodium. According to the invention, the metamifop and the bispyribac-sodium are compounded to prepare the dispersible oil suspending agent, and the defect of poor stability of the traditional dispersible oil suspending agent is overcome through fine screening of the formula, so that the dispersible oil suspending agent has the advantages of obvious drug effect, long lasting period, high suspension rate and the like. Meanwhile, the preparation method adopts safe and environment-friendly solvent matching, and the product has stable quality, safety, low toxicity and environmental protection. The mixed herbicide is a post-emergence herbicide for rice, has good control effect on annual weeds, especially resistant weeds, and obviously improves the weeding effect and greatly delays the improvement of the resistance of the weeds compared with the metamifop and the bispyribac-sodium single agent.
Description
Technical Field
The invention relates to the technical field of pesticides, and particularly relates to a dispersible oil suspending agent containing metamifop and bispyribac-sodium and a preparation method thereof.
Background
Metamifop is aryloxy phenoxy propionate herbicide, the action mechanism of which is to inhibit acetyl coenzyme A carboxylase, and the effective ingredients need to reach the target in the plant body to play the role of weeding. The solvent and the surfactant respectively play roles in softening the waxy layer of the leaf surface and opening the stomata of the plant, so that the effective ingredients enter the plant body to play a role. The weeding composition mainly prevents and removes most annual gramineous weeds such as barnyard grass, moleplant seed, large crabgrass and eleusine indica in transplanting and direct seeding fields, and the prevention and removal effect reaches over 95 percent.
The bispyribac-sodium is a benzoic acid herbicide, is a high-activity Acetolactate Synthase (ASL) inhibitor, can be quickly absorbed by stems and leaves of weeds after being sprayed on the weeds, and is conducted to the whole plants to inhibit the growth of plant meristems, so that the weeds are killed, and the bispyribac-sodium is high-efficiency, broad-spectrum and low in dosage. The bispyribac-sodium can effectively prevent and kill barnyard grass and other gramineous weeds in the rice field, and can also control most broadleaf weeds, some cyperaceae weeds and barnyard grass which generates resistance to other herbicides.
The metamifop and the bispyribac-sodium are mixed according to a proper proportion, so that the pesticide effect can be improved, the dosage can be reduced, the economic cost can be saved, and the residue of the pesticide in the environment can be reduced. Meanwhile, the weed resistance can be delayed, the service life of the herbicide is prolonged, the pesticide effect time can be prolonged by adding the auxiliary agent, and the weeding effect in a high-temperature or low-temperature environment is improved.
The dispersible oil suspending agent (OD) has the advantages of environmental friendliness, high drug effect, no need of barrel mixing auxiliary agent and convenient use, but the prior OD product related to metamifop and bispyribac-sodium generally has the defects of high long-term storage decomposition rate, poor stability and high cost, and can cause the problems of layering, bottom formation and the like in the long-term storage or transportation process.
Disclosure of Invention
In view of the above, the technical problem to be solved by the invention is to provide a dispersible oil suspension containing metamifop and bispyribac-sodium and a preparation method thereof, and the prepared dispersible oil suspension has high stability.
In order to achieve the purpose, the invention provides a dispersible oil suspending agent containing metamifop and bispyribac-sodium, which comprises:
active ingredients, emulsifiers, rheology agents, solvents and dispersion media;
the active ingredients comprise metamifop and bispyribac-sodium.
Preferably, the dispersible oil suspension containing the metamifop and the bispyribac-sodium comprises the following components in percentage by mass:
furthermore, the content of the metamifop in the dispersible oil suspending agent is preferably 50 g/L-200 g/L; the content of the bispyribac-sodium is preferably 10g/L to 100 g/L.
In some embodiments of the invention, the content of the metamifop is 100g/L, and the content of the bispyribac-sodium is 50 g/L.
The mass ratio of the metamifop to the bispyribac-sodium is preferably 1: 2-20: 1.
The content of metamifop is preferably 5% to 20% by mass, more preferably 10% to 18% by mass, and in some embodiments of the invention, the content of metamifop is 5%, 6%, 8%, 10%, 12%, 15%, 18%, 20% by mass, or any of the above values is an upper limit or a lower limit; the content of bispyribac-sodium is preferably 1% to 10%, more preferably 2% to 5%, and in some embodiments of the invention, the content of bispyribac-sodium is 1%, 2%, 3%, 4%, 5%, 6%, 8%, 10%, or a range value with any of the above values as an upper limit or a lower limit.
In the present invention, the mass content of the emulsifier is preferably 10% to 27.5%, more preferably 20% to 27.5%, and still more preferably 27% to 27.5%.
Preferably, the emulsifier is selected from one or more of styrylphenol polyoxyethylene ether, ethoxylated vegetable oil, calcium dodecylbenzene sulfonate, sorbitan trioleate, potassium sorbitan monooleate polyoxyethylene ether, castor oil polyoxyethylene ether, sodium diisooctyl succinate sulfonate and polyoxyethylene sorbitan monooleate. More preferably, the emulsifier is selected from styrylphenol polyoxyethylene ether and ethoxylated vegetable oil; or castor oil polyoxyethylene ether and calcium dodecylbenzene sulfonate; or styrylphenol polyoxyethylene ether and calcium dodecylbenzene sulfonate; or styrylphenol polyoxyethylene ether and sorbitol glucoside trioleate; or sodium diisooctyl succinate sulfonate and polyoxyethylene sorbitan monooleate; or potassium sorbitan monooleate polyoxyethylene ether and calcium dodecyl benzene sulfonate. Further preferably, the emulsifier is selected from castor oil polyoxyethylene ether and calcium dodecylbenzene sulfonate; the weight ratio of the two is preferably (15-15.5): 12; specifically, the ratio can be 15:12 or 15.5: 12; or styrylphenol polyoxyethylene ether and sorbitol glucoside trioleate; the weight ratio of the two is preferably (15-15.5): 12; specifically, the ratio can be 15:12 or 15.5: 12; or sodium diisooctyl succinate sulfonate and polyoxyethylene sorbitan monooleate; the weight ratio of the two is preferably 12: (15-15.5); specifically, the ratio may be 12:15 or 12: 15.5.
In some embodiments of the invention, the emulsifier comprises: 15.5 percent of castor oil polyoxyethylene ether and 12 percent of calcium dodecyl benzene sulfonate.
In some embodiments of the invention, the emulsifier comprises: 15% of styryl phenol polyoxyethylene ether and 12% of sorbitol glycoside trioleate.
In some embodiments of the invention, the emulsifier comprises: 12% of sodium diisooctyl succinate sulfonate and 15% of polyoxyethylene sorbitan monooleate.
The mass content of the rheological agent is preferably 1-5%, and more preferably 1-3%; further preferably 2%.
Preferably, the rheological agent is selected from one or more of corn starch, magnesium aluminum silicate, precipitated silica, fumed silica and organic bentonite. More preferably, the rheological agent is selected from the group consisting of organobentonite and fumed silica. The weight ratio of the organic bentonite to the fumed silica is preferably 1: 1.
In some embodiments of the invention, the rheological agent is 2% organobentonite.
In some embodiments of the present invention, the rheological agent is 1% of organobentonite and 1% of fumed silica.
The mass content of the solvent is preferably 8-25%; more preferably 15% to 24%. Specifically, the content may be 9%, 15%, 17%, 20%, 24%, or any of the above-mentioned values may be set as an upper limit or a lower limit.
Preferably, the solvent is selected from one or more of heavy aromatic solvent oil (preferably 200# solvent oil), 150# solvent oil (preferably S-200150 # solvent oil), 100# solvent oil (preferably S-200100 # solvent oil), N-methylpyrrolidone, cyclohexanone, N-dimethyldecylamine and isophorone; more preferably N-methylpyrrolidone and No. 150 solvent oil, or N-methylpyrrolidone and cyclohexanone, or 1-methyl-2-pyrrolidone, or No. 150 solvent oil and N, N-dimethyldecylamine, or N, N-dimethyldecylamine and isophorone, or cyclohexanone, or N-methylpyrrolidone and heavy aromatic hydrocarbon solvent oil S-200 #. More preferably, the solvent is selected from N-methylpyrrolidone and cyclohexanone, preferably in a mass ratio of 4: 1; or 150# solvent oil and N, N-dimethyl decylamine, the mass ratio is preferably 1: 1; or N, N-dimethyldecylamine and isophorone, preferably in a 4:1 mass ratio.
In some embodiments of the invention, the solvent is N-methylpyrrolidone 12% and cyclohexanone 3%.
In some embodiments of the invention, the solvent is 150# mineral spirit 12% and N, N-dimethyldecylamine 12%.
In some embodiments of the invention, the solvent is N, N-dimethyldecylamine 12% and isophorone 3%.
By adopting the solvent combination, the metamifop and the bispyribac-sodium have better solubility and are not easy to separate out, so that the prepared dispersible oil suspending agent has optimal stability.
The dispersion medium is preferably one or more of soybean oil methyl ester, corn oil, 200# solvent oil, cis-9-octadecenoic acid methyl ester and methyl oleate. More preferably cis-9-octadecenoic acid methyl ester, soybean oil methyl ester or cis-9-octadecenoic acid methyl ester.
Preferably, the dispersible oil suspending agent containing metamifop and bispyribac-sodium also comprises a dispersant and/or a stabilizer.
Preferably, the mass content of the dispersing agent is 2-5%; more preferably 2.5% to 5%. Specifically, the content may be 2.5%, 3%, 5%, or a range value in which any of the above values is an upper limit or a lower limit.
Preferably, the dispersing agent is selected from one or more of styryl phenol polyoxyethylene ether sulfonate, styryl maleic anhydride acrylate polymer ammonium salt, fatty alcohol derivative, sodium lignosulfonate, styryl phenol polyoxyethylene ether phosphate, alkylphenol polyoxyethylene ether phosphate, styryl phenol polyoxyethylene ether sulfonate, polyoxyethylene-polyoxypropylene copolymer and polycarboxylic acid ester; more preferably a polyoxyethylene-polyoxypropylene copolymer, a fatty alcohol polyether or a polycarboxylic acid ester.
The mass content of the stabilizer is preferably 0.5% to 1.5%, more preferably 0.5% to 1%, and specifically may be 0.5% or 1%.
Preferably, the stabilizer is selected from one or more of dipotassium hydrogen phosphate, urea, triethanolamine, diethanolamine, isopropylamine, sodium carbonate and sodium tripolyphosphate; more preferably sodium carbonate, triethanolamine or sodium tripolyphosphate.
The stabilizer has the functions of adjusting pH and fixing water, achieves the effect of preventing the bispyribac-sodium from decomposing by adjusting the pH upwards and absorbing free water in a product, and further improves the stability of the dispersible oil suspending agent.
Unless otherwise specified, the percentages in the present invention are all by weight.
The invention provides a preparation method of the dispersible oil suspending agent containing metamifop and bispyribac-sodium, which comprises the following steps:
s1) dissolving metamifop with a solvent to be used as a dissolved phase;
s2) mixing the bispyribac-sodium, the dispersing agent, the emulsifier, the rheological agent and the dispersing medium, and then grinding by sanding to obtain a grinding phase;
s3) mixing the dissolved phase and the sand grinding phase to obtain the dispersible oil suspending agent of metamifop and bispyribac-sodium.
Preferably, in the present invention, the step S2) is specifically: mixing the dispersion medium and the rheological agent, fully activating, then mixing the bispyribac-sodium, the dispersing agent and the emulsifying agent, and grinding by sanding to obtain a sanding phase.
When a stabilizer is added into the system, the step S2) is specifically as follows: mixing the dispersion medium and the rheological agent, fully activating, then mixing the bispyribac-sodium, the dispersing agent, the emulsifying agent and the stabilizing agent, and grinding by sanding to obtain a sanding phase.
Furthermore, the provided dispersible oil suspension containing metamifop and bispyribac-sodium is mainly applied to preventing and killing various weeds in paddy fields and can be used in 2-6 leaf periods of the weeds. The common dosage is 80-120 mL/mu, and the application mode is stem leaf spraying.
The dispersible oil suspension containing metamifop and bispyribac-sodium provided by the invention can be used for preventing and treating gramineous weeds, broadleaf weeds and nutgrass flatsedge.
Compared with the prior art, the invention provides a dispersible oil suspending agent containing metamifop and bispyribac-sodium, which comprises the following components: active ingredients, emulsifiers, rheology agents, solvents and dispersion media; the active ingredients comprise metamifop and bispyribac-sodium.
According to the invention, the metamifop and the bispyribac-sodium are compounded to prepare the dispersible oil suspending agent, and the defect of poor stability of the traditional dispersible oil suspending agent is overcome through fine screening of the formula, so that the dispersible oil suspending agent has the advantages of obvious drug effect, long lasting period, high suspension rate and the like. Meanwhile, the preparation method adopts safe and environment-friendly solvent matching, and the product has stable quality, safety, low toxicity and environmental protection. The mixed herbicide is a post-emergence herbicide for rice, has good control effect on annual weeds, especially resistant weeds, and obviously improves the weeding effect and greatly delays the improvement of the resistance of the weeds compared with the metamifop and the bispyribac-sodium single agent.
Furthermore, the invention solves the defect that bispyribac-sodium in the traditional dispersible oil suspending agent is easy to decompose by screening the stabilizing agent, greatly increases the physical and chemical stability of the product and has great advantages for long-term storage of customers.
Test results show that the dispersible oil suspending agent prepared by the invention has the characteristics of quick response, long lasting period and safety to soybean when being applied to a paddy field, particularly when being used for preventing and killing resistant weeds, and has the effects of increasing yield and enhancing effect to a certain extent.
Detailed Description
In order to further illustrate the invention, the dispersible oil suspension containing metamifop and bispyribac-sodium and the preparation method thereof provided by the invention are described in detail by combining the examples.
Examples 1 to 8
Preparing a dispersible oil suspending agent:
s1) dissolving metamifop with a solvent to be used as a dissolved phase;
s2) mixing the dispersion medium and the rheological agent, fully activating, then mixing the bispyribac-sodium, the dispersing agent, the emulsifying agent and the stabilizing agent, and then grinding by sanding to obtain a grinding phase;
s3) mixing the dissolved phase and the sand grinding phase to obtain the dispersible oil suspending agent of metamifop and bispyribac-sodium.
The raw material ratios of the examples are shown in tables 1 to 2.
Comparative examples 1 to 2
The preparation method is the same as that of the examples 1 to 8, and the raw material formulation of each example is shown in Table 3.
TABLE 1 examples 1 to 4 raw material ratios
TABLE 2 blending ratio of each raw material in examples 5 to 8
TABLE 3 raw material ratios of comparative examples 1 to 2
Performance detection
The properties of the dispersible oil suspending agents prepared in the above examples and comparative examples were measured, and the results are shown in table 5. Wherein, the suspension percentage is detected according to a method for measuring the suspension percentage of the pesticide GB/T14825-2006, the pourability is detected according to a method for measuring the pourability of the pesticide GB/T31737-2015, and the dispersion stability is detected according to CIPAC MT 180 measuring the dispersion stability of the suspoemulsion by the International Committee for pesticide analysis and collaboration.
According to the FAO about the dispersion stability detection standard, the dispersion stability detection standard was set as in the following table 4:
TABLE 4
TABLE 5 dispersible oil suspension product prepared by compounding metamifop and bispyribac-sodium
As can be seen from table 5, the dispersible oil suspension agents prepared in examples 1 to 6 have good stability and high suspension before and after thermal storage, and examples 2, 4 and 5 have significantly better stability than other examples; has obvious advantages in the heat storage stability, the suspension of solid active ingredients and the dispersion stability of the product of the bispyribac-sodium. The suspension rate after the thermal storage is obviously reduced in examples 7 to 8, the suspension property and stability before and after the thermal storage are not qualified in comparative examples 1 to 2, and the decomposition rate of the bispyribac-sodium after the thermal storage is high.
Field test
1. Test material
The rice varieties tested were "NSIC 238 and NSIC RC 216".
The test medicament is the obtained metamifop-bispyribac-sodium dispersible oil suspending agent.
2. Experimental methods
2.1 design of the experiment
6-9 months in 2018, in UPLB CES rice paddy field, university of Philippine Lagenarian. The total number of 4 treatments are respectively as follows: treatment 1-3: the metamifop-bispyribac-sodium dispersible oil suspending agent obtained in example 2, example 4 and example 5 is used for spray treatment; and (4) treatment 4-5: carrying out spray treatment by using the metamifop-bispyribac-sodium dispersible oil suspending agent obtained in comparative example 1 and comparative example 2; and (6) treatment: no medicine is used, and the grass is artificially pulled out for 3 times; and (7) treatment: no treatment was performed as a blank control.
In which treatments 1 to 3 were spray-treated with the metamifop-bispyribac-sodium dispersible oil suspension obtained in example at application rate of 1L (FP/Ha), and treatments 4 to 5 were spray-treated with the metamifop-bispyribac-sodium dispersible oil suspension obtained in comparative example at application rate of 1L (FP/Ha).
Cell area 4X 5m (20 m)2) 3 treatment groups, each with 3 replicates.
Herbicide application: the experimental apparatus is a knapsack sprayer (6 fan nozzles 8002), and the spraying amount is 160L/Ha.
TABLE 6 treatment of experimental groups
TABLE 7 grassy weed control Rate (%)
TABLE 8 broad leaf weed control Rate (%)
TABLE 9 Shacao control (%)
TABLE 10 comprehensive weed control Rate (%)
The results in tables 7-10 show that the artificial weeding has the best effect on controlling weeds in crop fields, can achieve the average prevention and control rate of 95%, and is most stable in controlling weeds. The treatments 1-3 corresponding to the examples 2, 4 and 5 have obviously better weeding effects and long persistent periods compared with the comparative example treatments 4 and 5, and the recurrence rate of weeds is obviously lower; from 15 days of data of application, the results of example 2, example 4 and example 5 show that the effect is equivalent to artificial weeding, the overall weeding ratio is over 95%, and the treatment scheme of the comparative example is obviously lower in weeding efficiency; from the data of 30 days and 45 days of application, the weeding effect of the embodiment is better than that of the comparative example on the whole, but the control aspect of long-term weeds is deficient compared with artificial weeding.
The test results show that the provided dispersible oil suspension of metamifop and bispyribac-sodium has high stability and excellent weeding performance.
The above description of the embodiments is only intended to facilitate the understanding of the method of the invention and its core idea. It should be noted that, for those skilled in the art, it is possible to make various improvements and modifications to the present invention without departing from the principle of the present invention, and those improvements and modifications also fall within the scope of the claims of the present invention.
Claims (10)
1. A dispersible oil suspending agent containing metamifop and bispyribac-sodium is characterized by comprising:
active ingredients, emulsifiers, rheology agents, solvents and dispersion media;
the active ingredients comprise metamifop and bispyribac-sodium.
2. The dispersible oil suspension containing metamifop and bispyribac-sodium of claim 1, which comprises the following components in percentage by mass:
the dispersion medium makes up 100%.
3. The dispersible oil suspension concentrate containing metamifop and bispyribac-sodium of claim 1 or 2, wherein the emulsifier is selected from one or more of styrylphenol polyoxyethylene ether, ethoxylated vegetable oil, calcium dodecylbenzene sulfonate, sorbitan trioleate, potassium sorbitan monooleate polyoxyethylene ether, castor oil polyoxyethylene ether, sodium diisooctyl succinate sulfonate, polyoxyethylene sorbitan monooleate.
4. The dispersible oil suspension concentrate containing metamifop and bispyribac-sodium of claim 3, wherein the emulsifier is selected from styrylphenol polyoxyethylene ether and ethoxylated vegetable oil; or castor oil polyoxyethylene ether and calcium dodecylbenzene sulfonate; or styryl phenol polyoxyethylene ether and calcium dodecyl benzene sulfonate; or styrylphenol polyoxyethylene ether and sorbitol glucoside trioleate; or sodium diisooctyl succinate sulfonate and polyoxyethylene sorbitan monooleate; or potassium sorbitan monooleate polyoxyethylene ether and calcium dodecyl benzene sulfonate.
5. The dispersible oil suspending agent containing metamifop and bispyribac-sodium as claimed in claim 1 or 2, wherein the rheological agent is selected from one or more of corn starch, magnesium aluminum silicate, precipitated silica, fumed silica and organic bentonite;
the solvent is selected from one or more of heavy aromatic solvent naphtha, No. 150 solvent naphtha, No. 100 solvent naphtha, N-methyl pyrrolidone, cyclohexanone, N-dimethyl decylamine and isophorone;
the dispersion medium is selected from one or more of soybean oil methyl ester, corn oil, 200# solvent oil, cis-9-octadecenoic acid methyl ester, and methyl oleate.
6. The dispersible oil suspension concentrate containing metamifop and bispyribac-sodium of claim 1 or 2, further comprising a dispersant and/or a stabilizer.
7. The dispersible oil suspending agent containing metamifop and bispyribac-sodium of claim 6, wherein the mass content of the dispersing agent is 2-5%;
the mass content of the stabilizer is 0.5-1.5%.
8. The dispersible oil suspension concentrate containing metamifop and bispyribac-sodium of claim 6, wherein the dispersant is selected from one or more of styrylphenol polyoxyethylene ether sulfonate, styrene maleic anhydride acrylate polymer ammonium salt, fatty alcohol derivatives, sodium lignosulfonate, styrylphenol polyoxyethylene ether phosphate, alkylphenol polyoxyethylene ether phosphate, styrylphenol polyoxyethylene ether sulfonate, polyoxyethylene-polyoxypropylene copolymer, and polycarboxylic acid ester;
the stabilizer is selected from one or more of dipotassium phosphate, urea, triethanolamine, diethanolamine, isopropylamine, sodium carbonate and sodium tripolyphosphate.
9. The dispersible oil suspension concentrate containing metamifop and bispyribac-sodium of claim 8, wherein the dispersant is selected from polyoxyethylene-polyoxypropylene copolymer, fatty alcohol polyether or polycarboxylate;
the stabilizer is selected from sodium carbonate, triethanolamine or sodium tripolyphosphate.
10. A preparation method of a dispersible oil suspending agent containing metamifop and bispyribac-sodium comprises the following steps:
s1) dissolving metamifop with a solvent to obtain a dissolved phase;
s2) mixing bispyribac-sodium, a dispersing agent, an emulsifying agent, a rheological agent and a dispersing medium, and then grinding and crushing to obtain a grinding phase;
s3) mixing the dissolved phase and the sand grinding phase to obtain the dispersible oil suspending agent of metamifop and bispyribac-sodium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210288536.2A CN114586776B (en) | 2022-03-23 | 2022-03-23 | Dispersible oil suspending agent containing metamifop and bispyribac-sodium and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210288536.2A CN114586776B (en) | 2022-03-23 | 2022-03-23 | Dispersible oil suspending agent containing metamifop and bispyribac-sodium and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114586776A true CN114586776A (en) | 2022-06-07 |
| CN114586776B CN114586776B (en) | 2024-01-26 |
Family
ID=81811346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210288536.2A Active CN114586776B (en) | 2022-03-23 | 2022-03-23 | Dispersible oil suspending agent containing metamifop and bispyribac-sodium and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114586776B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117481113A (en) * | 2023-12-21 | 2024-02-02 | 山东科赛基农生物工程有限公司 | Topramezone and clodinafop-propargyl dispersible oil suspending agent and application thereof |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101743957A (en) * | 2010-01-27 | 2010-06-23 | 江苏省农用激素工程技术研究中心有限公司 | Bispyribac-sodium salt suspending agent and preparation method thereof |
| CN101828562A (en) * | 2010-06-12 | 2010-09-15 | 济南科赛基农化工有限公司 | Herbicide composition with bentazon and bispyribac-sodium as active ingredients |
| CN102113503A (en) * | 2010-12-30 | 2011-07-06 | 苏州富美实植物保护剂有限公司 | Herbicide composite used in paddy field |
| CN102165956A (en) * | 2011-03-24 | 2011-08-31 | 广东中迅农科股份有限公司 | Pesticide composite containing bispyribac-sodium and penoxsulam and application thereof |
| CN102326560A (en) * | 2011-05-30 | 2012-01-25 | 陕西韦尔奇作物保护有限公司 | Weeding composition containing carfentrazone-ethyl and metamifop |
| CN102342280A (en) * | 2011-10-26 | 2012-02-08 | 中化蓝天集团有限公司 | Active composition for preventing and eliminating resistant weeds in paddy field and weedicide thereof |
| CN103621508A (en) * | 2013-11-08 | 2014-03-12 | 美丰农化有限公司 | Bispyribac-sodium dispersible oil suspended agent and preparation method thereof |
| CN104521981A (en) * | 2014-12-23 | 2015-04-22 | 江西中迅农化有限公司 | Weed control composition containing pyriftalid, fenoxaprop-p-ethyl and metamifop |
| CN106472515A (en) * | 2016-10-13 | 2017-03-08 | 广东中迅农科股份有限公司 | Herbicidal combinations containing bispyribac-sodium |
| CN108432774A (en) * | 2018-03-26 | 2018-08-24 | 孟州传奇生物科技有限公司 | A kind of herbicidal composition of rice terrace |
| CN114208833A (en) * | 2021-12-30 | 2022-03-22 | 青岛润农化工有限公司 | Pesticide composition containing fluroxypyr-meptyl and diclosulam, and preparation method and application thereof |
-
2022
- 2022-03-23 CN CN202210288536.2A patent/CN114586776B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101743957A (en) * | 2010-01-27 | 2010-06-23 | 江苏省农用激素工程技术研究中心有限公司 | Bispyribac-sodium salt suspending agent and preparation method thereof |
| CN101828562A (en) * | 2010-06-12 | 2010-09-15 | 济南科赛基农化工有限公司 | Herbicide composition with bentazon and bispyribac-sodium as active ingredients |
| CN102113503A (en) * | 2010-12-30 | 2011-07-06 | 苏州富美实植物保护剂有限公司 | Herbicide composite used in paddy field |
| CN102165956A (en) * | 2011-03-24 | 2011-08-31 | 广东中迅农科股份有限公司 | Pesticide composite containing bispyribac-sodium and penoxsulam and application thereof |
| CN102326560A (en) * | 2011-05-30 | 2012-01-25 | 陕西韦尔奇作物保护有限公司 | Weeding composition containing carfentrazone-ethyl and metamifop |
| CN102342280A (en) * | 2011-10-26 | 2012-02-08 | 中化蓝天集团有限公司 | Active composition for preventing and eliminating resistant weeds in paddy field and weedicide thereof |
| CN103621508A (en) * | 2013-11-08 | 2014-03-12 | 美丰农化有限公司 | Bispyribac-sodium dispersible oil suspended agent and preparation method thereof |
| CN104521981A (en) * | 2014-12-23 | 2015-04-22 | 江西中迅农化有限公司 | Weed control composition containing pyriftalid, fenoxaprop-p-ethyl and metamifop |
| CN106472515A (en) * | 2016-10-13 | 2017-03-08 | 广东中迅农科股份有限公司 | Herbicidal combinations containing bispyribac-sodium |
| CN108432774A (en) * | 2018-03-26 | 2018-08-24 | 孟州传奇生物科技有限公司 | A kind of herbicidal composition of rice terrace |
| CN114208833A (en) * | 2021-12-30 | 2022-03-22 | 青岛润农化工有限公司 | Pesticide composition containing fluroxypyr-meptyl and diclosulam, and preparation method and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117481113A (en) * | 2023-12-21 | 2024-02-02 | 山东科赛基农生物工程有限公司 | Topramezone and clodinafop-propargyl dispersible oil suspending agent and application thereof |
| CN117481113B (en) * | 2023-12-21 | 2024-03-29 | 山东科赛基农生物工程有限公司 | Topramezone and clodinafop-propargyl dispersible oil suspending agent and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114586776B (en) | 2024-01-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP3378314B1 (en) | Synergistic herbicidal composition | |
| EA021070B1 (en) | Herbicidal compositions comprising naptalam | |
| EA018968B1 (en) | Herbicidal compositions comprising pyroxasulfone vii | |
| CN114586776A (en) | Dispersible oil suspending agent containing metamifop and bispyribac-sodium and preparation method thereof | |
| WO2020147277A1 (en) | Plant growth regulator composition | |
| CN104488914A (en) | Complex herbicide for rice field | |
| WO2017166564A1 (en) | Plant growth regulator composition | |
| CA2374150A1 (en) | Strobilurin-based fungicide composition causing reduced chemical damage | |
| WO2018036294A1 (en) | Pesticide composition | |
| CN114208833B (en) | Pesticide composition containing fluroxypyr and diclosulam as well as preparation method and application thereof | |
| CN108432774A (en) | A kind of herbicidal composition of rice terrace | |
| CN106879618A (en) | Containing benzobicylon, pyrazosulfuron, pretilachlor Herbicidal combinations | |
| CN111066811A (en) | Herbicide composition containing penoxsulam and application thereof | |
| WO2018036288A1 (en) | Pesticide composition | |
| CN112042650B (en) | Weeding composition, application thereof and pesticide herbicide | |
| CN110881465A (en) | Herbicidal composition containing pyribenzoxim | |
| CN110876385A (en) | Herbicidal composition and use thereof | |
| EP3915370A1 (en) | Stable phytoene desaturase inhibitor herbicide formulation | |
| CA1204298A (en) | Synergistic herbicidal composition | |
| CN115843799B (en) | Composition for preventing and killing weeds in cotton fields | |
| CN108935506A (en) | Synergistic herbicide compositions containing glufosinate-ammonium | |
| CN117481113B (en) | Topramezone and clodinafop-propargyl dispersible oil suspending agent and application thereof | |
| CN108419803B (en) | Herbicidal composition containing imazapic and prometryn and application thereof | |
| CN115669667A (en) | Composition containing 2-methyl-4-chloroisooctyl, fluroxypyr-meptyl and clopyralid as well as preparation method and application thereof | |
| CN117814220A (en) | Pesticide dispersible oil suspending agent and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |