CN106472515A - Herbicidal combinations containing bispyribac-sodium - Google Patents
Herbicidal combinations containing bispyribac-sodium Download PDFInfo
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- CN106472515A CN106472515A CN201610894852.9A CN201610894852A CN106472515A CN 106472515 A CN106472515 A CN 106472515A CN 201610894852 A CN201610894852 A CN 201610894852A CN 106472515 A CN106472515 A CN 106472515A
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- Prior art keywords
- sodium
- bispyribac
- benzobicylon
- herbicidal combinations
- pretilachlor
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Herbicidal combinations containing bispyribac-sodium, containing active component a) bispyribac-sodium, b) benzobicylon, c) acetamide-group herbicides, the wherein one kind of acetamide-group herbicides in pretilachlor, mefenacet, fluorine ketone sulphur grass amine；Bispyribac-sodium in composition, benzobicylon, the part by weight between acetamide-group herbicides three are 0.1～30:0.1～30：0.1～30, remaining is insecticides adjuvant；The formulation of Herbicidal combinations of the present invention can be suspending agent, dispersible oil-suspending agent, the one kind in water dispersible granules, wettable powder, be applied to prevent and kill off rice terrace annual grassy weeds.
Description
Technical field
The invention belongs to technical field of pesticide, and in particular to one kind with bispyribac-sodium, benzobicylon, acetamide-group herbicides is
The Synergistic response Herbicidal combinations of active ingredient, wherein acetamide-group herbicides are selected from pretilachlor, mefenacet, fluorine ketone sulphur
One kind in careless amine.
Background technology
Bispyribac-sodium (bispyribac-sodium) is pyrimidinylthiobenzoate herbicides, absorbs suppression vinegar milk acid by root leaf
Synthesis and hindered aminoacid biosynthesis side chain. for selective herbicide, used in rice direct seeding field, herbicidal spectrum is wide, to 1～
7 leaf phase barnyard grasses are all effective, 3～6 leaf phase preventive effects it is further preferred that.To Chinese herbaceous peony Brachiaria Griseb, junglerice, johnson grass, purple water amaranth, dayflower,
Sagittaria pygmaea, difformed galingale herb, cyperus iria, big barnyard grass, firefly Lin, bacopa monnieri, carpet weed also have good preventive effect.
Benzobicylon (benzobicylon) is researched and developed for SDS bioscience Co., Ltd. of Japan, is mainly used in anti-harnessing the river
The weeds that sulfonylurea produces resistance are had good preventive effect, pass through by barnyard grass in paddy field, annual broadleaf weed and sedge weed
Soil treatment can effectively prevent and kill off the paddy field weeds such as barnyard grass, firefly Lin, Monochoria vaginalis, bog pondweed, fake rice, to short arrowhead high dose ability
Preferable preventive effect is reached, the lasting period was up to 6 weeks.
Acetamide-group herbicides mainly have pretilachlor, mefenacet, fluorine ketone sulphur grass amine, alachlor, Acetochlor, butachlor,
Isopropyl methoxalamine, propisochlor etc..
Pretilachlor (pretilachlor), acetamide-group herbicides, selectively pretreating reagent is sprouted, plant hypocotyl can be passed through,
Mesocotyl and plumule absorb, and root slightly absorbs, and direct interference weeds vivo protein synthesizes, and to photosynthetic and respiration
There are remote-effects.Aggrieved weeds seedling distortion, acrospire difficulty are stretched out, and leaf color turns dark green, and growth stops, until dead.Paddy rice pair
Pretilachlor has stronger capacity of decomposition, so as to certain selectivity.
Mefenacet (mefenacet) medicine is a kind of selective inner-adsorption conduction-type herbicide.Mainly by bud scale and
Root absorption, conducts through xylem and bast to young shoot and the tender leaf of weeds, prevents weed growth point cell division elongation, finally
Cause plant dead.Selective to transplanting rice strong, as in water, solubility is low, so under the conditions of water conservation, pesticide-applying weeding
Active highest, soil are very strong to this product absorption affinity, and after dispenser, dose major part is adsorbed on upper soll layer, and in upper soll layer
Process layer is formed within 1cm, be so avoided that contact of the paddy growth point with the medicament so as to higher security is produced, and
Being in the weeds such as the barnyard grass of upper soll layer to growing point has stronger prevention fertility and kill ability, and the seminal propagation to top layer
Perennial weeds also have inhibitory action, low to deep layer weeds effect.
Fluorine ketone sulphur grass amine (triafamone)：Belong to sulfonamides herbicide, can lead to via plant root and Foliage Absorption
Cross suppression acetolactate synthase to work (ALS inhibitor), to rice terrace grassy weed barnyard grass, broad leaved weed Eclipta prostrata, Scirpus tabernaemontani,
And sedge weed difformed galingale herb etc. all has good preventive effect.
Farmland weed grass is mutually complicated, and species is various, and it is to prevent and kill off the maximally effective chemical means of agricultural weed to apply chemical agent
One of；It is a good solution to prevent and kill off agricultural weed with the novel pesticide without cross resistance；But, develop one at present
Individual novel pesticide needs to screen up to ten thousand compounds, and hundred million dollars of cost 1.2-1.5, construction cycle are 5-10, it is difficult to that caught up with is upper miscellaneous
The speed that grass develops immunity to drugs；Other methods such as crop structure adjustment, different agricultural chemicals rotations etc., in actual mechanical process,
It is difficult to play obvious effect.
The rational compounding or mixture of chemical herbicide has expansion weed control spectrum, improves prevention effect, extends dispenser period, subtracts
Few dosage, the poisoning risk that reduces, minimizing are remained, delay the advantages of weeds drug resistance and drug-fast generation and development, so
It is one of maximally efficient and economic method for solving the above problems to select suitable mixture of herbicides or mixture.
Develop new product herbicide is expensive, the cycle is long, and by contrast, exploitation is efficient, low toxicity, low-residual with research
Compound short with the investment little, lead time with mixture and attention both domestic and external is subject to, numerous and confused increasing development dynamics.
Bispyribac-sodium, benzobicylon, acetamide-group herbicides (in pretilachlor, mefenacet, fluorine ketone sulphur grass amine
Kind), three's mechanism of action is different, and weed control spectrum is not quite similar, and, using easily developing immunity to drugs, consumption is increasing, herbicide for single dose
Spectrum is narrower, it is impossible to meet reality need, benzobicylon is with bispyribac-sodium, benzobicylon and acetamide-group herbicides (selected from the third grass
One kind in amine, mefenacet, fluorine ketone sulphur grass amine), bispyribac-sodium and acetamide-group herbicides (selected from pretilachlor, mefenacet,
One kind in fluorine ketone sulphur grass amine) Binary mixture there is also the problem similar with single dose exclusive use, although making moderate progress, therefore exists
To a certain extent in the urgent need to the appearance of novel built herbicide.
The present inventor is to bispyribac-sodium, benzobicylon, acetamide-group herbicides (selected from pretilachlor, mefenacet, fluorine ketone sulphur
One kind in careless amine) mixture has made intensive studies, and finds bispyribac-sodium, benzobicylon, acetamide-group herbicides (selected from the third grass
One kind in amine, mefenacet, fluorine ketone sulphur grass amine) Ternary is more than theoretical prediction to the observed value of target weeds preventive effect
Value, the beat all Synergistic that shows as are responded.
The present invention possesses the prospect of industrial applications, by certain technological means, can with excipient as suspending agent, dispersible
Oil-suspending agent, water dispersible granules, wettable powder etc. are easy to the formulation for agriculturally using.
Content of the invention
The object of the invention provides a kind of collaboration with bispyribac-sodium, benzobicylon, acetamide-group herbicides as active ingredient and increases
Effect response Herbicidal combinations.Have and expand weed control spectrum, improve prevention effect.
The technical scheme is that：A kind of Herbicidal combinations containing bispyribac-sodium, containing active component a) bispyribac-sodium, b)
Benzobicylon, c) acetamide-group herbicides (one kind in pretilachlor, mefenacet, fluorine ketone sulphur grass amine), bispyribac-sodium, double
Weight between ring sulphur humulone, acetamide-group herbicides (one kind in pretilachlor, mefenacet, fluorine ketone sulphur grass amine) three
Ratio is 0.1～30:0.1～30：0.1～10, remaining is insecticides adjuvant.
The Synergistic mixture of the present invention can be co-administered with other herbicides one or more of to prevent and treat more extensive farming class
Undesirable vegetation.When being used in combination with other herbicides, the composition can be joined with other one or more herbicides
System, is carried out tank with other one or more herbicides and mixes or successively applied with other one or more herbicides.Can be with this
Some herbicides that bright synergistic combination thing is used in combination include：2,4- drop (2,4-D), mowing amine (acetochlor), three
Acifluorfen (acifluorfen), aclonifen (aclonifen), AE0172747, alachlor (alachlor), sulphur ammonia sulphur are grand
(amidosulfuron), aminotriazole(ATA) (aminotriazole), ammonium thiocyanate (ammonium thiocyanate), anilofos
(anilofos), atrazine (atrazine), AVH301, tetrazolium sulphur grand (azimsulfuron), benfuresate
(benfuresate), Bentazon (bentazone), benthiocarb (benthiocarb), the bicyclic ketone of benzo
(benzobicyclon), bifenox (bifenox), bromacil (bromacil), Brominal (bromoxynil), butachlor
(butachlor), butafenacil (butafenacil), Amex820 (butralin), cafenstrole (cafenstrole), length are killed
Careless (carbetamide), azoles humulone (carfentrazone-ethyl), polybenzobisoxazole humulone, chloroflurenol (chlorflurenol), chlorine
Chem hoe (chlorpropham), clethodim (clethodim), different humulone (clomazone), cloransulammethyl
(cloransulam-methyl), cycloxydim (cycloxydim), Mediben (dicamba), dichlobenil (dichlobenil),
Smart 2,4- drop propionic acid (dichlorprop-P), the phonetic sulfanilamide (SN) of azoles (diclosulam), diflufenican (diflufenican), two
Fluorine pyrrole grand (diflufenzopyr), dimethenamid (dimethenamid), smart dimethenamid (dimethenamid-p),
Diquat dibromide (diquat), dithiopyr (dithiopyr), diuron (diuron), EK2612, EPTC (EPTC), esprocarb
(esprocarb), ET-751, ethoxysulfuron (ethoxysulfuron), ethbenzanid, F7967, azoles diclofop-methyl
(fenoxaprop), azoles diclofop-methyl (fenoxaprop-ethyl), azoles diclofop-methyl (fenoxaprop-ethyl)+bis- benzene
Azoles acetoacetic ester (isoxadifen-ethyl), fentrazamide (fentrazamide), fluorine ketone sulphur grass amine, flazasulfuron
(flazasulfuron), florasulam (florasulam), pyrrole fluorine first standing grain spirit (fluazifop), efficient fluazifop
(fluazifop-P-butyl), flufenacet (flufenacet), flufenpyrethyl (flufenpyr-ethyl), fluorine ethofumesate
(flumetsulam), Flumiclorac pentyl (flumiclorac-pentyl), flumioxazin (flumioxazin), fluometuron
(fluometuron), fluorine pyridine sulphur grand (flupyrsulfuron), fomesafen (fomesafen), foramsulfuron
(foramsulfuron), fumiclorac, glufosinate-ammonium (glufosinate), glufosinate-ammonium (glufosinate-ammonium),
Glyphosate (glyphosate), haloxyfop-P-methyl (haloxyfop-methyl), smart fluazifop-butyl (haloxyfop-R), miaow grass
Ester (imazamethabenz), imazamox (imazamox), AC 263222 (imazapic), AC 263222
(imazapyr), Scepter (imazaquin), Imazethapyr (imazethapyr), pyridine miaow sulphur grand (imazosulfuron), indenes grass
Ketone (indanofan), indaziflam grass amine (indaziflam), iodine sulphur grand (iodosulfuron), ioxynil (ioxynil),
Ipfencarbazone (HOK-201), IR5790, isoproturon (isoproturon), different acyl grass amine (isoxaben), different
Fluorine humulone (isoxaflutole), KUH-071, lactofen (lactofen), linuron (linuron), 2 first, 4 chlorine
(MCPA), MCPA ester ＆ amine, mecopropP (mecoprop-P), mesosulfuron (mesosulfuron), mesotrione
(mesotrione), bispyribac-sodium (metamifop), bis ether halosulfuronmethyl (metazosulfuron, NC-620), isopropyl first grass
Amine (metolachlor), azoles grass sulfanilamide (SN) (metosulam), metribuzin (oxaziclomefone), metribuzin
(metribuzin), metsulfuron-methyl (metsulfuron), Hydram (molinate), monsodium acid methanearsonate (MSMA) (MSMA), napropamide
(napropamide), nicosulfuron (nicosulfuron), monometflurazone (norflurazon), OK-9701, oryzalin
(oryzalin), Oxadiargyl (oxadiargyl), humulone (oxadiazon), oxazichlomefone, ethoxy fluorine grass
Ether (oxyfluorfen), fluoroglycofen-ethyl (Fluoroglycofen), paraquat (paraquat), pendimethalin
(pendimethalin), penoxsuam (penoxsulam), penta azoles grass (pentoxazone), pethoxamid
(pethoxamid), piperophos (piperophos), primisulfuronmethyl (primisulfuron), clefoxidim (profoxydim),
Propachlor (propachlor), propanil (propanil), propyrisulfuron (TH-547), propyzamide
(propyzamide), prosulfocarb (prosulfocarb), the third sulphur of fluorine grand (prosulfuron), pyraclonil
(pyraclonil), pyrazogyl, phonetic benzene grass oxime (pyribenzoxim, LGC-40863), pyriftalid (pyriftalid),
KIH 6127 (pyriminobac-methyl), fluoropyrimidine grass ether, pyrimisulfan (KUH-021), pyroxsulam
(pyroxsulam), pyroxasulfone (KIH-485), quizalofop-ethyl-D, S-3252, sethoxydim
(sethoxydim), SL-0401, SL-0402, S-metolachlor (S-metolachlor), sulphur humulone (sulcotrione),
Ring sulphur ketone (Tembotrione), triazole sulphur humulone, sulfentrazone (sulfentrazone), sulphosate (sulfosate), fourth azoles
Grand (tebuthiuron), tefuryltrione (AVH-301), terbacil (terbacil), thiazopyr (thiazopyr), standing grain
Grass pellet (thiobencarb), Triclopyr (triclopyr), trefanocide (trifluralin) and tritosulfuron
(tritosulfuron), dichloro quinolinic acid (quinclorac), benzene pyrazoles humulone (Topramezone), fluorine benzofenap
(bicyclopyrone), fluroxypyr, trichlopyr, the acid of chlorine Fampridine, polybenzobisoxazole humulone, ring pyrrole fluorine humulone, triazole
Sulphur humulone, benzene azoles fluorine humulone, promazine Sulfometuron Methyl, piperazine pyrazosulfuron, Florpyrauxifen.
The synergistic combination thing of the present invention can also be with glyphosate, glufosinate-ammonium, Mediben, imidazolone type
(imidazolinones), sulfonylurea (sulfonylureas) or 2,4- drop are combined used in glyphosate tolerant (glyphosate-
Tolerant), resistance to glufosinate-ammonium (glufosinate-tolerant), resistance to Mediben (dicamba-tolerant), resistance to imidazoline
Ketone (imidazolinone-tolerant), resistance to sulfonylurea (sulfonylurea-tolerant) and resistance to 2,4- drop (2,4-
D-tolerant on crop).Generally preferably the synergistic combination thing of the present invention is used with combinations of herbicides, the herbicide with
Rate of application used using when treat the crop of disposal and have selective, and the spectrum of the weeds of these compounds preventing and treatings is carried out
Supplement.Synergistic combination thing and other complementary herbicides of the present invention are generally further preferably applied simultaneously, or conduct
Combination preparation, or or apply as tank mixture.
The synergistic combination thing of the present invention generally can be combined with known herbicide-safener (herbicide safener)
Use, to strengthen its selectivity, the herbicide-safener such as benoxacor (benoxacor), benthiocarb (benthiocarb),
Study on brassinolide (brassinolide), cloquitocet_mexyl (cloquintocet (mexyl)), cyometrinil (cyometrinil), kill
Careless grand (daimuron), dichlormide (dichlormid), dicyclonon, dimepiperate (dimepiperate), disulfoton
(disulfoton), fenchlorazole (fenchlorazole-ethyl), fenclorim (fenclorim), solution careless amine (flurazole),
The careless furan (furilazole) of fluxofenim (fluxofenim), solution, harpin albumen, double benzene azoles acetoacetic ester (isoxadifen-
Ethyl), mefenpyrdiethyl (mefenpyr-diethyl), MG191 (MG191), MON4660, naphthalene dimethyl anhydride (naphthalic
Anhydride, NA), oxabetrinil (oxabetrinil), R29148 and N- phenyl-sulfonyl benzoic amide.Cloquitocet_mexyl is this
The particularly preferred safener of the synergistic combination thing of invention, is especially resisting the synergistic combination thing to rice and cereal
During any ill-effect.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention are more short and sweet, present invention specific examples below
Illustrate, but the present invention is only limitted to absolutely not these examples.Described below is only the preferable embodiment of the present invention, is used only for retouching
State the present invention, it is impossible to be interpreted as limiting the scope of the present invention.It should be pointed out that all the spirit and principles in the present invention it
Interior done any modification, equivalent and improvement etc., should be included within the scope of the present invention.
A kind of Herbicidal combinations containing bispyribac-sodium, containing active component a) bispyribac-sodium, b) benzobicylon, c) amide-type
Herbicide (one kind in pretilachlor, mefenacet, fluorine ketone sulphur grass amine), bispyribac-sodium, benzobicylon, amide-type herbiciding
Part by weight between agent (one kind in pretilachlor, mefenacet, fluorine ketone sulphur grass amine) three is 0.1～30:0.1～
30：0.1～10, remaining is insecticides adjuvant.Herbicidal combinations by certain technological means can excipient be suspending agent, dispersible oil
Suspending agent, water dispersible granules, wettable powder etc..
The suspending agent formulation weight percent is consisted of：Bispyribac-sodium 0.1～30%, benzobicylon 0.1～30%,
Acetamide-group herbicides (one kind in pretilachlor, mefenacet, fluorine ketone sulphur grass amine) 0.1～30%, dispersant 0.1～
15%th, wetting agent 0.1-15%, thickener 0.1～2%, deionized water carrier complement to 100%.Specifically production stage is：Will
Active ingredient and the mixing of other auxiliary agents, after sand milling in high speed shear dispersion, sand mill, formed in water-medium high dispersive,
Stable suspension system, is obtained the suspending agent of corresponding weight percentage, and suspending agent Active principals content is not higher than 50%.
The oil-suspending agent formulation weight percent that dispersibles is consisted of：Bispyribac-sodium 0.1～30%, benzobicylon
0.1～30%, acetamide-group herbicides 0.1～30% (one kind in pretilachlor, mefenacet, fluorine ketone sulphur grass amine), point
Powder 0.1～15%, wetting agent 0.1-15%, thickener 0.1～2%, liquid-carrier complements to 100%.Concrete production stage
For：By active ingredient and the mixing of other auxiliary agents, after sand milling in high speed shear dispersion, sand mill, formed in non-water-medium
High dispersive, stable suspension system, corresponding weight percentage is obtained dispersible oil-suspending agent, dispersible oil-suspending agent and always live
Property component content is not higher than 50%.
The dosage form of water dispersible granule weight percent is consisted of：Bispyribac-sodium 0.1～30%, benzobicylon 0.1～
30%, acetamide-group herbicides (one kind in pretilachlor, mefenacet, fluorine ketone sulphur grass amine) 0.1～30%, dispersant
0.1～15%, wetting agent 0.1～10%, disintegrant 0.1～10%, solid carrier complements to 100%.Specifically production stage is：
Active ingredient and other auxiliary agents are mixed, is crushed with micro jet, through mediating, be subsequently adding fluidized bed prilling and do
Carry out granulating in dry machine, dry, sieve, the water dispersible granules of corresponding weight percentage are obtained, water dispersible granules gross activity becomes
Point content is not higher than 90%.
The wettable powder formulation weight percent is consisted of：Bispyribac-sodium 0.1～30%, benzobicylon 0.1～
30%, acetamide-group herbicides (one kind in pretilachlor, mefenacet, fluorine ketone sulphur grass amine) 0.1～30%, dispersant
0.1～15%, wetting agent 0.1～15%, solid carrier complements to 100%.Specifically production stage is：By active ingredient and other
Auxiliary agent mixes, and again through air-flow crushing after mechanical crushing, mixes, and the wettable powder of corresponding weight percentage is obtained, can
WP Active principals content is not higher than 90%.
Described defoamer can be the one kind in silicone compound, epoxidized soybean oil, methyl alcohol, silicone oil, fatty alcohol etc.
Or it is several.
Described antifreezing agent can be glycerine, propane diols, diethylene glycol (DEG), urea, in glycerine-ether diglycol, inorganic salts etc.
One or more.
Described wetting agent can be lauryl sodium sulfate, neopelex, sodium butylnaphthalenesulfonate, alkyl sulphur
One or more in sour sodium, tea seed cake powder, spaonin powder, spaonin powder, condensed phosphate, sulfate, phosphate etc..
Described dispersant can be APES formaldehyde condensation product, naphthalenesulfonate formaldehyde condensation compound, to first
Epoxide fatty acyl anilinesulfonic acid, lignosulfonates, polycarboxylate, APES sulfate, alkyl benzene sulphonate
Calcium salt, fatty acid ester sulfate, APES, AEO, polyoxyethylene polyoxypropylene base ether are embedding
One or more in section copolymer etc..
Described disintegrant can be sodium carboxymethyl starch, low-substituted hydroxypropyl cellulose, Ac-Di-Sol,
PVPP, shitosan, sodium alginate sodium acid carbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite etc.
In one or more.
Described thickener can be polyvinyl acetate, xanthans, gelatin, gum arabic, aluminium-magnesium silicate, phenolic aldehyde tree
One or more in fat, hydroxymethyl cellulose, sodium alginate etc..
Described solid carrier can be precipitated calcium carbonate, potter's clay, kaolin, diatomite, bentonite, white carbon, clay,
One or more in attapulgite, talcum powder, quartz sand etc..
Described liquid-carrier can be exquisite soybean oil, corn oil, rapeseed oil, turpentine oil, methyl oleate, coconut oil,
One or more in palm oil, peanut oil, sunflower oil etc..
Described deionized water is industrialization deionized water.
Described binding agent can be sucrose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, carboxymethylcellulose calcium
One kind in calcium, carboxy-propyl cellulose, dextrin, amylodextrin, polyvinylpyrrolidone, viscosity kaolin, paraffin, rosin etc. or
Several.
Described solid acid can be citric acid, butanedioic acid, maleic acid, fumaric acid, tartaric acid, oxalic acid, malonic acid, apple
Acid, succinic acid, hexanedioic acid, boric acid, phosphoric acid, benzoic acid, sulfamic acid, salicylic acid, glutamic acid, phenylacetic acid, nicotinic acid or sorbic acid
Deng in one or more.
Described carbonate can be sodium carbonate, potassium carbonate, ammonium carbonate, calcium carbonate, lithium carbonate, sodium acid carbonate, bicarbonate
One or more in potassium, lithium bicarbonate, sodium sesquicarbonate, bicarbonate tripotassium or three ammonium of bicarbonate etc..
Described flowing regulator can be calcium stearate, magnesium stearate, barium stearate, titanium dioxide, talcum powder, 12
In alkylsurfuric acid magnesium, polysorbate, wheat starch or Sodium Benzoate etc. one or more.
The frequency of administration of the present composition and amount of application change and have small variations with crops, weeds, weather condition,
The purpose of effective preventing and treating can be reached by using appropriate dosage.
(i.e. bispyribac-sodium benzobicylon acetamide-group herbicides are (selected from pretilachlor, benzene thiophene acyl grass for triple combination of the present invention
One kind in amine, fluorine ketone sulphur grass amine)) deficiency that can solve when herbicide is single or two-spot is used, expand weed control spectrum, and composition
Respond with Synergistic, such as to barnyard grass (Echinochloa crusgalli), moleplant seed (Leptochloa
Chinensis), Scirpus tabernaemontani (Scirpus validus) is responded with obvious Synergistic, can be rice terrace annual grassy weeds
Offer excellent fix is provided.
Embodiment one：Toxicity Determination
Colby equation is used for determining desired herbicide effect (Colby, the S.R.Weeds1967,15,20- of mixture
22.Calculation of the synergistic and antagonistic response of herbicide
combinations)：
Following equatioies are used for calculating the activity of the expectation containing two kinds of active components A and the mixture of B：
In formula：
Effect of the active components A of the same concentrations used by mixture observed by A=；
Effect of the active component B of the same concentrations used by mixture observed by B=.
When used by mixture, concentration activity actual observation value is more than desired value, mixture shows as to be had to target weeds
Unexpected synergy.
Bispyribac-sodium, benzobicylon, acetamide-group herbicides and its compounding to barnyard grass (Echinochloa crusgalli),
Moleplant seed (Leptochloa chinensis), the Toxicity Determination of Scirpus tabernaemontani (Scirpus validus).
The preventing and treating percentage of Obs- observation.
Preventing and treating percentage desired by Exp-Colby equation.
G a.i./ha- gram active component/hectare.
The collaboration to weeds in 15 days is prevented and treated after application for table 1, A1 and B1, and A1 is the bicyclic sulphur grass of bispyribac-sodium 5g a.i./ha+
Ketone 300g a.i./ha, B1 are pretilachlor.
The collaboration to weeds in 15 days is prevented and treated after application for table 2, A2 and B1, and A2 is the bicyclic sulphur of bispyribac-sodium 7.5g a.i./ha+
Humulone 225g a.i./ha, B1 are pretilachlor.
The collaboration to weeds in 15 days is prevented and treated after application for table 3, A3 and B1, and A3 is the bicyclic sulphur grass of bispyribac-sodium 10g a.i./ha+
Ketone 150g a.i./ha, B1 are pretilachlor.
The collaboration to weeds in 15 days is prevented and treated after application for table 4, A4 and B1, and A4 is the bicyclic sulphur grass of bispyribac-sodium 15g a.i./ha+
Ketone 15g a.i./ha, B1 are pretilachlor.
The collaboration to weeds in 15 days is prevented and treated after application for table 5, A5 and B1, and A5 is the bicyclic sulphur grass of bispyribac-sodium 30g a.i./ha+
Ketone 1.5g a.i./ha, B1 are pretilachlor.
The collaboration to weeds in 15 days is prevented and treated after application for table 6, A6 and B1, and A5 is the bicyclic sulphur of bispyribac-sodium 7.5g a.i./ha+
Humulone 15g a.i./ha, B1 are pretilachlor.
The collaboration to weeds in 15 days is prevented and treated after application for table 7, A1 and B2, and A1 is the bicyclic sulphur grass of bispyribac-sodium 5g a.i./ha+
Ketone 300g a.i./ha, B2 are mefenacet.
The collaboration to weeds in 15 days is prevented and treated after application for table 8, A2 and B2, and A2 is the bicyclic sulphur of bispyribac-sodium 7.5g a.i./ha+
Humulone 225g a.i./ha, B2 are mefenacet.
The collaboration to weeds in 15 days is prevented and treated after application for table 9, A3 and B2, and A3 is the bicyclic sulphur grass of bispyribac-sodium 10g a.i./ha+
Ketone 150g a.i./ha, B2 are mefenacet.
The collaboration to weeds in 15 days is prevented and treated after application for table 10, A4 and B2, and A4 is the bicyclic sulphur of bispyribac-sodium 15g a.i./ha+
Humulone 15g a.i./ha, B2 are mefenacet.
The collaboration to weeds in 15 days is prevented and treated after application for table 11, A5 and B2, and A5 is the bicyclic sulphur of bispyribac-sodium 30g a.i./ha+
Humulone 1.5g a.i./ha, B2 are mefenacet.
The collaboration to weeds in 15 days is prevented and treated after application for table 12, A1 and B3, and A1 is the bicyclic sulphur grass of bispyribac-sodium 5g a.i./ha+
Ketone 300g a.i./ha, B3 are fluorine ketone sulphur grass amine.
The collaboration to weeds in 15 days is prevented and treated after application for table 13, A2 and B3, and A2 is the bicyclic sulphur of bispyribac-sodium 7.5g a.i./ha+
Humulone 225g a.i./ha, B3 are fluorine ketone sulphur grass amine.
The collaboration to weeds in 15 days is prevented and treated after application for table 14, A3 and B3, and A3 is the bicyclic sulphur of bispyribac-sodium 10g a.i./ha+
Humulone 150g a.i./ha, B3 are fluorine ketone sulphur grass amine.
The collaboration to weeds in 15 days is prevented and treated after application for table 15, A4 and B3, and A4 is the bicyclic sulphur of bispyribac-sodium 15g a.i./ha+
Humulone 15g a.i./ha, B3 are fluorine ketone sulphur grass amine.
The collaboration to weeds in 15 days is prevented and treated after application for table 16, A5 and B3, and A5 is the bicyclic sulphur of bispyribac-sodium 30g a.i./ha+
Humulone 1.5g a.i./ha, B3 are fluorine ketone sulphur grass amine.
Embodiment two：71% bispyribac-sodium benzobicylon pretilachlor water dispersible granules
Following material is weight ratio：Bispyribac-sodium 1%, benzobicylon 30%, pretilachlor 40%, fatty acid ester sulfate
6%th, polycarboxylic acid salt 4%, corn flour 8%, sodium lignin sulfonate 7%, diatomite to 100%；Above-mentioned material is added together
Mix in cone-type mixer, crush by airslide disintegrating mill, the material after crushing mixes through cone-type mixer again, after mixing
Fineness of materials 98% pass through 600 mesh standard sieves, add kneader in be kneaded into plasticity material, finally this material is put into crowded
Extruder grain in pressure comminutor, is obtained 71% bispyribac-sodium benzobicylon pretilachlor water after drying, screening after granulation
Dispersible granule.
Embodiment three：56% bispyribac-sodium benzobicylon pretilachlor water dispersible granules
Following material is weight ratio：Bispyribac-sodium 1%, benzobicylon 15%, pretilachlor 40%, fatty acid ester sulfate
6%th, polycarboxylic acid salt 4%, corn flour 8%, sodium lignin sulfonate 9%, diatomite to 100%；Above-mentioned material is added together
Mix in cone-type mixer, crush by airslide disintegrating mill, the material after crushing mixes through cone-type mixer again, after mixing
Fineness of materials 98% pass through 600 mesh standard sieves, add kneader in be kneaded into plasticity material, finally this material is put into crowded
Extruder grain in pressure comminutor, is obtained 56% bispyribac-sodium benzobicylon pretilachlor water after drying, screening after granulation
Dispersible granule.
Example IV：44% bispyribac-sodium benzobicylon fluorine ketone sulphur grass aqueous amine dispersible granule
Following material is weight ratio：Bispyribac-sodium 1%, benzobicylon 39%, fluorine ketone sulphur grass amine 4%, fatty acid ester sulphur
Hydrochlorate 6%, polycarboxylic acid salt 4%, corn flour 8%, sodium lignin sulfonate 9%, diatomite to 100%；By above-mentioned material together
Add and mix in cone-type mixer, crush by airslide disintegrating mill, the material after crushing mixes through cone-type mixer again, mix
Fineness of materials 98% after conjunction passes through 600 mesh standard sieves, adds in kneader and is kneaded into plasticity material, finally puts this material
Enter extruder grain in Squeezinggranulator, after drying, screening, 44% bispyribac-sodium benzobicylon fluorine ketone after granulation, is obtained
Sulphur grass aqueous amine dispersible granule.
Embodiment five：40% bispyribac-sodium benzobicylon mefenacet water dispersible granules
Following material is weight ratio：Bispyribac-sodium 0.5%, benzobicylon 19.5%, mefenacet 20%%, fat
Acid esters sulfate 6%, polycarboxylic acid salt 4%, corn flour 8%, sodium lignin sulfonate 9%, diatomite to 100%；By above-mentioned thing
Material is added together and is mixed in cone-type mixer, is crushed by airslide disintegrating mill, and the material after crushing is again through cone-type mixer
Mixing, mixed fineness of materials 98% pass through 600 mesh standard sieves, add in kneader and are kneaded into plasticity material, finally will
This material is put into extruder grain in Squeezinggranulator, and the bicyclic sulphur grass of 40% bispyribac-sodium is obtained after granulation after drying, screening
Ketone mefenacet water dispersible granules.
Embodiment six：40% bispyribac-sodium benzobicylon pretilachlor wettable powder
Following material is weight ratio：Bispyribac-sodium 0.5%, benzobicylon 19.5%, pretilachlor 20%, dodecyl sulphur
Sour sodium 6%, sodium lignin sulfonate 4%, diatomite 2%, kaolin to 100%；Above-mentioned material is added cone-type mixer together
In mix, by airslide disintegrating mill crush, the material after crushing again through cone-type mixer mix, mixed fineness of materials
98% passes through 600 mesh standard sieves, that is, 40% bispyribac-sodium benzobicylon pretilachlor wettable powder is obtained.
Embodiment seven：40% bispyribac-sodium benzobicylon mefenacet wettable powder
Following material is weight ratio：Bispyribac-sodium 0.5%, benzobicylon 19.5%, mefenacet 20%, dodecane
Base sodium sulphate 6%, sodium lignin sulfonate 4%, diatomite 2%, kaolin to 100%；Above-mentioned material is added taper to mix together
Mix in conjunction machine, crush by airslide disintegrating mill, the material after crushing mixes through cone-type mixer again, mixed material
Fineness 98% passes through 600 mesh standard sieves, that is, 40% bispyribac-sodium benzobicylon mefenacet wettable powder is obtained.
Embodiment eight：44% bispyribac-sodium benzobicylon fluorine ketone sulphur grass amine wettable powder
Following material is weight ratio：Bispyribac-sodium 1%, benzobicylon 39%, fluorine ketone sulphur grass amine 4%, dodecyl sulphur
Sour sodium 6%, sodium lignin sulfonate 4%, diatomite 2%, kaolin to 100%；Above-mentioned material is added cone-type mixer together
In mix, by airslide disintegrating mill crush, the material after crushing again through cone-type mixer mix, mixed fineness of materials
98% passes through 600 mesh standard sieves, that is, 44% bispyribac-sodium benzobicylon fluorine ketone sulphur grass amine sylvite wettable powder is obtained.
Embodiment nine：40% bispyribac-sodium benzobicylon pretilachlor suspending agent
Following material is weight ratio：Bispyribac-sodium 0.5%, benzobicylon 19.5%, pretilachlor 20%, lignin sulfonic acid
Salt calcium 3%, urea 0.5%, polyoxyethylene poly-oxygen propylene aether block copolymer 7%, deionized water complement to 100%；Will be above-mentioned
Formula is crushed in proportion in advance, is added in sand mill and is ground, and allocates that 40% bispyribac-sodium is obtained after high shear mixing
Benzobicylon pretilachlor suspending agent.
Embodiment ten：40% benzobicylon bispyribac-sodium mefenacet suspending agent
Following material is weight ratio：Bispyribac-sodium 0.5%, benzobicylon 19.5%, mefenacet 20%, lignin
Sulfonate calcium 5%, urea 1%, polyoxyethylene poly-oxygen propylene aether block copolymer 9%, deionized water complement to 100%；Will be upper
State formula to be crushed in advance in proportion, add in sand mill and grind, allocate that 40% pair of grass is obtained after high shear mixing
Ether benzobicylon mefenacet suspending agent.
Embodiment 11：18% benzobicylon bispyribac-sodium fluorine ketone sulphur grass amine suspending agent
Following material is weight ratio：Bispyribac-sodium 1.5%, benzobicylon 7.5%, fluorine ketone sulphur grass amine 9%, sulfomethylated lignin
Hydrochlorate calcium 5%, urea 1%, polyoxyethylene poly-oxygen propylene aether block copolymer 9%, deionized water complement to 100%；Will be above-mentioned
Formula is crushed in proportion in advance, is added in sand mill and is ground, and allocates that 18% bispyribac-sodium is obtained after high shear mixing
Benzobicylon fluorine ketone sulphur grass amine suspending agent.
Embodiment 12：40% bispyribac-sodium benzobicylon pretilachlor dispersibles oil-suspending agent
Following material is weight ratio：Bispyribac-sodium 0.5%, benzobicylon 19.5%, pretilachlor 20%, benzene ethylphenol gather
Oxygen vinethene 5%, methyl oleate 20%, polyoxyethylene poly-oxygen propylene aether block copolymer 8%, bentonite 4%, corn oil extremely
100%；Above-mentioned material (except organobentonite) is added in reactor mixer together, is stirred 2 hours, is opened bottom and enter
Material valve, material is injected in multistage sand mill and is ground, the fineness of materials 98% after grinding by discharging after 1-5um, material again with
The organobentonite for dissolve in advance is put in high-shear emulsifying kettle together, can be made into stream to good 40% pair of property after emulsification
Careless ether benzobicylon pretilachlor dispersibles oil-suspending agent.
Embodiment 13：23% bispyribac-sodium benzobicylon pretilachlor dispersibles oil-suspending agent
Following material is weight ratio：Bispyribac-sodium 0.5%, benzobicylon 2.5%, pretilachlor 20%, benzene ethylphenol gather
Oxygen vinethene 5%, methyl oleate 20%, polyoxyethylene poly-oxygen propylene aether block copolymer 8%, bentonite 4%, corn oil are extremely
100%；Above-mentioned material (except organobentonite) is added in reactor mixer together, is stirred 2 hours, is opened bottom and enter
Material valve, material is injected in multistage sand mill and is ground, the fineness of materials 98% after grinding by discharging after 1-5um, material again with
The organobentonite for dissolve in advance is put in high-shear emulsifying kettle together, can be made into stream to good 23% pair of property after emulsification
Careless ether benzobicylon pretilachlor dispersibles oil-suspending agent.
Embodiment 14：40% bispyribac-sodium benzobicylon mefenacet dispersibles oil-suspending agent
Following material is weight ratio：Bispyribac-sodium 0.5%, benzobicylon 19.5%, mefenacet 20%, benzene ethylbenzene
Phenol polyethenoxy ether 5%, methyl oleate 20%, polyoxyethylene poly-oxygen propylene aether block copolymer 8%, bentonite 4%, corn oil
To 100%；Above-mentioned material (except organobentonite) is added in reactor mixer together, is stirred 2 hours, opens bottom
Pan feeding valve, material is injected in multistage sand mill and is ground, and the fineness of materials 98% after grinding is discharged after 1-5um, and material is again
Be put in high-shear emulsifying kettle together with the organobentonite for dissolve in advance, can be made into after emulsification stream to property good 40%
Bispyribac-sodium benzobicylon mefenacet dispersibles oil-suspending agent.
Embodiment 15：24% bispyribac-sodium benzobicylon fluorine ketone sulphur grass amine dispersibles oil-suspending agent
Following material is weight ratio：Bispyribac-sodium 1.5%, benzobicylon 15%, fluorine ketone sulphur grass amine 7.5%, benzene ethylbenzene
Phenol polyethenoxy ether 5%, methyl oleate 20%, polyoxyethylene poly-oxygen propylene aether block copolymer 8%, bentonite 4%, corn
Oil is to 100%；Above-mentioned material (except organobentonite) is added in reactor mixer together, is stirred 2 hours, opens kettle
Bottom pan feeding valve, material is injected in multistage sand mill and is ground, and the fineness of materials 98% after grinding is discharged after 1-5um, material
Be put in high-shear emulsifying kettle together with the organobentonite for having dissolved in advance again, stream is can be made into after emulsification good to property
24% bispyribac-sodium benzobicylon fluorine ketone sulphur grass amine dispersibles oil-suspending agent.
Embodiment 16：Composition prevents and kill off rice terrace annual grassy weeds field control effectiveness test
Field dominant weed is barnyard grass, moleplant seed, Scirpus tabernaemontani, difformed galingale herb, accounts for more than the 99% of weeds total amount, prevention and controls
For spray-on process, about 30 kilograms of every mu of water consumption.
Drug effect computing formula is as follows：
Table 17, prevent and kill off rice terrace annual grassy weeds field control effectiveness test result
Claims (9)
1. a kind of Herbicidal combinations containing bispyribac-sodium, it is characterised in that：Containing active component a) bispyribac-sodium, b) bicyclic sulphur is careless
Ketone, c) acetamide-group herbicides；The one kind of the acetamide-group herbicides in pretilachlor, mefenacet, fluorine ketone sulphur grass amine.
2. a kind of Herbicidal combinations containing bispyribac-sodium according to claim 1, it is characterised in that：Double grass in composition
Ether, benzobicylon, the part by weight between acetamide-group herbicides three are 0.1～30:0.1～30：0.1～30, remaining is
Insecticides adjuvant.
3. a kind of Herbicidal combinations containing bispyribac-sodium according to claim 1, it is characterised in that：Double grass in composition
Ether, benzobicylon, the part by weight between acetamide-group herbicides three are 0.1～10:0.1～10：0.1～10, remaining is
Insecticides adjuvant.
4. a kind of Herbicidal combinations containing bispyribac-sodium according to claim 1, it is characterised in that：Double grass in composition
Ether, benzobicylon, the part by weight between pretilachlor three are 1～10:1～50：1～50, remaining is insecticides adjuvant.
5. a kind of Herbicidal combinations containing bispyribac-sodium according to claim 1, it is characterised in that：Double grass in composition
Ether, benzobicylon, the part by weight between mefenacet three are 1～10:1～50：1～50, remaining is insecticides adjuvant.
6. a kind of Herbicidal combinations containing bispyribac-sodium according to claim 1, it is characterised in that：Double grass in composition
Part by weight between the careless amine three of ether, benzobicylon, fluorine ketone sulphur is 1～10:1～50：1～20, remaining is insecticides adjuvant.
7. a kind of Herbicidal combinations containing bispyribac-sodium according to claim 1, it is characterised in that：Double grass in composition
Ether, benzobicylon, the part by weight between pretilachlor three are 1:30:40, remaining is insecticides adjuvant.
8. a kind of Herbicidal combinations containing bispyribac-sodium according to claim 1, it is characterised in that：The Herbicidal combinations
Formulation be suspending agent, dispersible oil-suspending agent, the one kind in water dispersible granules, wettable powder.
9. a kind of Herbicidal combinations containing bispyribac-sodium described in claim 1 on rice terrace annual grassy weeds is prevented and kill off should
With.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107027788A (en) * | 2017-05-27 | 2017-08-11 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing benzobicylon |
| CN110024788A (en) * | 2019-04-28 | 2019-07-19 | 江苏省激素研究所股份有限公司 | The herbicide for paddy field of benzobicylon compounding |
| CN110402924A (en) * | 2019-07-31 | 2019-11-05 | 淮安市植保植检站 | Transplanted rice field super large age barnyard grass control method |
| CN114586776A (en) * | 2022-03-23 | 2022-06-07 | 山东潍坊润丰化工股份有限公司 | Dispersible oil suspending agent containing metamifop and bispyribac-sodium and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101677540A (en) * | 2007-06-12 | 2010-03-24 | 巴斯夫欧洲公司 | Herbicidally effective composition |
| CN104115835A (en) * | 2014-06-24 | 2014-10-29 | 江苏省激素研究所股份有限公司 | Herbicide composition |
| CN105104375A (en) * | 2015-08-14 | 2015-12-02 | 京博农化科技股份有限公司 | Glycerine-containing herbicidal composition |
| CN105142402A (en) * | 2013-02-25 | 2015-12-09 | 美国陶氏益农公司 | Synergistic weed control with penoxsulam and acetochlor |
| CN105284836A (en) * | 2015-11-30 | 2016-02-03 | 佛山市盈辉作物科学有限公司 | Gibberellic acid-containing herbicide composition and preparation method as well as application thereof |
-
2016
- 2016-10-13 CN CN201610894852.9A patent/CN106472515A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101677540A (en) * | 2007-06-12 | 2010-03-24 | 巴斯夫欧洲公司 | Herbicidally effective composition |
| CN105142402A (en) * | 2013-02-25 | 2015-12-09 | 美国陶氏益农公司 | Synergistic weed control with penoxsulam and acetochlor |
| CN104115835A (en) * | 2014-06-24 | 2014-10-29 | 江苏省激素研究所股份有限公司 | Herbicide composition |
| CN105104375A (en) * | 2015-08-14 | 2015-12-02 | 京博农化科技股份有限公司 | Glycerine-containing herbicidal composition |
| CN105284836A (en) * | 2015-11-30 | 2016-02-03 | 佛山市盈辉作物科学有限公司 | Gibberellic acid-containing herbicide composition and preparation method as well as application thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107027788A (en) * | 2017-05-27 | 2017-08-11 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing benzobicylon |
| CN110024788A (en) * | 2019-04-28 | 2019-07-19 | 江苏省激素研究所股份有限公司 | The herbicide for paddy field of benzobicylon compounding |
| CN110402924A (en) * | 2019-07-31 | 2019-11-05 | 淮安市植保植检站 | Transplanted rice field super large age barnyard grass control method |
| CN114586776A (en) * | 2022-03-23 | 2022-06-07 | 山东潍坊润丰化工股份有限公司 | Dispersible oil suspending agent containing metamifop and bispyribac-sodium and preparation method thereof |
| CN114586776B (en) * | 2022-03-23 | 2024-01-26 | 山东潍坊润丰化工股份有限公司 | Dispersible oil suspending agent containing metamifop and bispyribac-sodium and preparation method thereof |
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