CN114479236A - Plastic particle flame-retardant research formula and main raw material storage monitoring system - Google Patents
Plastic particle flame-retardant research formula and main raw material storage monitoring system Download PDFInfo
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- CN114479236A CN114479236A CN202111590627.3A CN202111590627A CN114479236A CN 114479236 A CN114479236 A CN 114479236A CN 202111590627 A CN202111590627 A CN 202111590627A CN 114479236 A CN114479236 A CN 114479236A
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- 238000012544 monitoring process Methods 0.000 title claims abstract description 61
- 229920003023 plastic Polymers 0.000 title claims abstract description 46
- 239000004033 plastic Substances 0.000 title claims abstract description 46
- 239000002245 particle Substances 0.000 title claims abstract description 43
- 239000002994 raw material Substances 0.000 title claims abstract description 36
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 239000003063 flame retardant Substances 0.000 title claims abstract description 17
- 238000011160 research Methods 0.000 title claims abstract description 9
- -1 polyethylene Polymers 0.000 claims abstract description 17
- 239000004698 Polyethylene Substances 0.000 claims abstract description 14
- 229920000573 polyethylene Polymers 0.000 claims abstract description 14
- 238000001514 detection method Methods 0.000 claims abstract description 9
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 8
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 8
- 239000006084 composite stabilizer Substances 0.000 claims abstract description 7
- 239000004014 plasticizer Substances 0.000 claims abstract description 6
- 239000003365 glass fiber Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 8
- FIAXCDIQXHJNIX-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-ethylbenzene Chemical compound CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br FIAXCDIQXHJNIX-UHFFFAOYSA-N 0.000 claims description 3
- MGFRKBRDZIMZGO-UHFFFAOYSA-N barium cadmium Chemical group [Cd].[Ba] MGFRKBRDZIMZGO-UHFFFAOYSA-N 0.000 claims description 3
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 3
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims 7
- 239000006096 absorbing agent Substances 0.000 claims 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 claims 1
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims 1
- 125000005498 phthalate group Chemical group 0.000 claims 1
- 229920000426 Microplastic Polymers 0.000 abstract description 2
- 230000032683 aging Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract 3
- 238000000151 deposition Methods 0.000 abstract 1
- 239000002075 main ingredient Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000000126 substance Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000010292 electrical insulation Methods 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- PGRNEGLBSNLPNP-UHFFFAOYSA-N 1,6-dichloro-3-methylhex-1-ene Chemical compound ClC=CC(C)CCCCl PGRNEGLBSNLPNP-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01D—MEASURING NOT SPECIALLY ADAPTED FOR A SPECIFIC VARIABLE; ARRANGEMENTS FOR MEASURING TWO OR MORE VARIABLES NOT COVERED IN A SINGLE OTHER SUBCLASS; TARIFF METERING APPARATUS; MEASURING OR TESTING NOT OTHERWISE PROVIDED FOR
- G01D21/00—Measuring or testing not otherwise provided for
- G01D21/02—Measuring two or more variables by means not covered by a single other subclass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the technical field of plastic particles, in particular to a plastic particle flame retardant research formula and a main raw material storage monitoring system. The technical scheme comprises the following steps: a plastic particle flame retardant research formula comprises 30-50 parts of polyethylene, 10-20 parts of polyvinyl chloride, 2-4 parts of plasticizer, 15-25 parts of composite stabilizer, 5-10 parts of glass fiber and 30-50 parts of flame retardant; the utility model provides a plastic pellet main ingredient storage monitoring system, monitoring module is used for monitoring the environment of storage container unit, and big environmental monitoring unit is used for the monitoring to depositing the whole environment in storage container workshop, and little environmental monitoring unit is used for the environmental monitoring to single storage container. The invention improves the high temperature resistance and ageing resistance of the plastic particles and improves the basic performance of the plastic particles, and the plastic particles are matched with a main raw material storage monitoring system, so that the quality of the raw materials before being put into a warehouse is ensured through warehouse detection, then the raw materials enter each storage container, and the safety of the storage environment is ensured through the environment monitoring unit.
Description
Technical Field
The invention relates to the technical field of plastic particles, in particular to a plastic particle flame retardant research formula and a main raw material storage monitoring system.
Background
Plastic particles are the common name for plastic granules, and are the raw material for storing, transporting and processing plastic in the form of semi-finished products. Plastics are a kind of high molecular material, and can be used to prepare ethylene, propylene, vinyl chloride, styrene, etc. by using petroleum as raw material, and the molecules of these substances can react with each other under a certain condition to produce compounds with very large molecular weight, i.e. high molecules.
The existing plastic particles are applied to various industries, but with the improvement of science and technology and the non-continuous increase of application fields, the requirements on plastics are further improved.
In addition, in the processing and production process of the existing plastic particles, the main raw materials of the existing plastic particles mostly need special storage environments, and a whole set of method for storing and monitoring the raw materials of the plastic particles does not exist.
Disclosure of Invention
The invention aims to provide a plastic particle flame retardant research formula and a main raw material storage monitoring system aiming at the problems in the background art.
The technical scheme of the invention is as follows: a plastic particle flame-retardant research formula and a main raw material storage monitoring system.
One embodiment of the invention provides a plastic particle flame retardant research formula, which comprises the following components: 30-50 parts of polyethylene, wherein the polyethylene has excellent low-temperature resistance, good chemical stability, small water absorption and excellent electrical insulation, can resist most of acid and alkali erosion, and can effectively improve the basic performance of plastic particles; 10-20 parts of polyvinyl chloride, which has high flame retardance and chemical resistance, stable physicochemical properties and low gas and water vapor leakage, and is insoluble in water, alcohol and gasoline, so that the application range of plastic particles can be enlarged and the basic performance can be improved by matching with polyethylene; 2-4 parts of a plasticizer; 15-25 parts of a composite stabilizer; 5-10 parts of glass fiber; 30-50 parts of a flame retardant.
Preferably, the flame retardant is prepared from tributyl phosphate, triphenyl phosphate and pentabromoethyl benzene according to the ratio of 2:1: 1.
Preferably, the plasticizer is a mixture of phthalic acid ester, fatty acid ester, benzene polyacid ester according to a ratio of 1.5: 0.5: 1 proportion.
Preferably, the composite stabilizer is a barium cadmium stabilizer.
Preferably, the ultraviolet absorbent is prepared from benzotriazole and phenyl o-hydroxybenzoate according to the ratio of 1: 1.
An embodiment of the present invention provides a system for storing and monitoring plastic particles, including: the formula is provided with a storage monitoring system for creating main raw materials suitable for the formula, and is characterized by comprising a monitoring master control end, wherein the monitoring master control end comprises a storage module and a monitoring module, the storage module comprises a warehousing detection unit and a storage container unit, and the monitoring module comprises a large environment monitoring unit and a small environment monitoring unit.
Preferably, the monitoring module is used for monitoring the environment of the storage container unit, the large environment monitoring unit is used for monitoring the overall environment of a workshop for storing the storage containers, and the small environment monitoring unit is used for monitoring the environment of a single storage container.
Preferably, the warehousing detection unit is used for detecting the raw materials before warehousing, and the quality and the color of the raw materials are detected by workers, so that the problem of the warehoused raw materials is solved.
Compared with the prior art, the invention has the beneficial effects that:
1. in the invention, the plastic particles contain polyethylene, the polyethylene has excellent low temperature resistance, good chemical stability, can resist most of acid and alkali erosion, has small water absorption and excellent electrical insulation, thereby effectively improving the basic performance of the plastic particles, the polyvinyl chloride is contained, has high flame retardance and chemical resistance, has stable physicochemical properties, is insoluble in water, alcohol and gasoline, has low gas and water vapor leakage, can improve the application range of the plastic particles and improve the basic performance by matching with the polyethylene, and is added with a plurality of auxiliary materials and auxiliary agents, so that the plastic particles are resistant to high temperature and ageing, and the basic performance of the plastic particles is improved.
2. In the invention, the main raw material storage monitoring system is matched to ensure the quality of the raw materials before being stored in the storage container by the storage detection of the raw materials, then the raw materials enter each storage container, and the safety of the storage environment is ensured by the large environment monitoring unit and the small environment monitoring unit.
Drawings
FIG. 1 is a block diagram of a storage monitoring system for plastic particles as a main raw material according to the present invention;
Detailed Description
The technical solution of the present invention is further explained with reference to the accompanying drawings and specific embodiments.
Example one
30-50 parts of polyethylene, wherein the polyethylene has excellent low-temperature resistance, good chemical stability, resistance to corrosion of most of acid and alkali, small water absorption and excellent electrical insulation, so that the basic performance of the plastic particles can be effectively improved; 10-20 parts of polyvinyl chloride, which has high flame retardance and chemical resistance, stable physicochemical properties and low gas and water vapor leakage, and is insoluble in water, alcohol and gasoline, so that the application range of plastic particles can be enlarged and the basic performance can be improved by matching with polyethylene; 2-4 parts of a plasticizer; 15-25 parts of composite stabilizer, wherein the composite stabilizer is a barium-cadmium stabilizer and has the effect of stabilizing polyvinyl chloride; 5-10 parts of glass fiber, wherein the glass fiber improves the insulativity, the heat resistance strength, the corrosion resistance strength and the mechanical strength of the plastic particles; 30-50 parts of flame retardant, tributyl phosphate, triphenyl phosphate and pentabromoethyl benzene are prepared according to the proportion of 2:1:1, so that the flame retardant property of the plastic particles can be improved;
the plastic particles contain polyethylene, the polyethylene has excellent low-temperature resistance, the chemical stability is good, most of acid and alkali erosion resistance can be achieved, the water absorption is small, the electric insulation is excellent, the basic performance of the plastic particles can be effectively improved, the polyvinyl chloride is contained, the polyvinyl chloride has high flame retardance and chemical resistance, the plastic particles have stable physicochemical properties, the water-insoluble, alcohol and gasoline are low in leakage of gas and water vapor, the application range of the plastic particles can be enlarged and the basic performance can be improved by matching with the polyethylene, and in addition, some auxiliary materials are used for assisting, so that the plastic particles are high-temperature resistant and anti-aging, and the basic performance of the plastic particles is improved.
Example two
Referring to fig. 1, a structural block diagram of a storage and monitoring system for plastic particle main raw materials is shown, based on the first embodiment, a formula has a storage and monitoring system for creating main raw materials suitable for the formula, and the storage and monitoring system comprises a monitoring master control end, the monitoring master control end comprises a storage module and a monitoring module, the storage module comprises a warehousing detection unit and a storage container unit, and the monitoring module comprises a large environment monitoring unit and a small environment monitoring unit;
the storage detection unit is used for detecting the quality and the color of raw materials before storage, and ensures that the raw materials stored in the storage container unit have no problem by detecting the quality and the color of the raw materials through workers;
the main raw material storage monitoring system is arranged in a matched manner, so that the quality of raw materials before being put in a warehouse is ensured through warehouse-in detection, then the raw materials enter each storage container, and the safety of the storage environment is ensured through the large environment monitoring unit and the small environment monitoring unit.
The above embodiments are merely some preferred embodiments of the present invention, and those skilled in the art can make various alternative modifications and combinations of the above embodiments based on the technical solution of the present invention and the related teaching of the above embodiments.
It is to be noted that the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (8)
1. A plastic particle flame retardant research formula comprises the following components: the flame-retardant plastic particle comprises the following components:
30-50 parts of polyethylene;
10-20 parts of polyvinyl chloride;
2-4 parts of a plasticizer;
15-25 parts of a composite stabilizer;
5-10 parts of glass fiber;
30-50 parts of a flame retardant;
2. the formulation according to claim 1, wherein the flame retardant is selected from the group consisting of tributyl phosphate, triphenyl phosphate, and pentabromoethyl benzene at a ratio of 2:1: 1.
3. The formulation according to claim 1, wherein the plasticizer is selected from the group consisting of phthalates, fatty acid esters, and benzoates in a ratio of 1.5: 0.5: 1 proportion.
4. The formulation according to claim 1, wherein the composite stabilizer is a barium cadmium stabilizer.
5. The formulation according to claim 1, wherein the UV absorber is selected from the group consisting of benzotriazole and phenyl ortho-hydroxybenzoate in a ratio of 1: 1.
6. The formulation for researching fire retardation of plastic particles according to any one of claims 1 to 5, wherein the formulation has a storage monitoring system for creating a suitable main raw material for the formulation, and is characterized by comprising a monitoring master terminal, the monitoring master terminal comprises a storage module and a monitoring module, the storage module comprises a warehousing detection unit and a storage container unit, and the monitoring module comprises a large environment monitoring unit and a small environment monitoring unit.
7. The plastic particle primary raw material storage monitoring system as claimed in claim 6, wherein the monitoring module is used for monitoring the environment of the storage container unit, the large environment monitoring unit is used for monitoring the overall environment of a plant for storing the storage containers, and the small environment monitoring unit is used for monitoring the environment of a single storage container.
8. The system for storing and monitoring the main raw materials of the plastic particles according to claim 6, wherein the warehousing detection unit is used for detecting the raw materials before warehousing, and the quality and the color of the raw materials are detected by workers, so that the raw materials warehoused are ensured to have no problem.
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CN202111590627.3A CN114479236A (en) | 2021-12-23 | 2021-12-23 | Plastic particle flame-retardant research formula and main raw material storage monitoring system |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103862651A (en) * | 2014-03-30 | 2014-06-18 | 湖州凯博电子线缆有限公司 | Plastic particle feeding device of cable processing device |
CN112266525A (en) * | 2020-11-14 | 2021-01-26 | 吴春明 | Anti-cracking polyethylene photovoltaic cable material and preparation method thereof |
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2021
- 2021-12-23 CN CN202111590627.3A patent/CN114479236A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103862651A (en) * | 2014-03-30 | 2014-06-18 | 湖州凯博电子线缆有限公司 | Plastic particle feeding device of cable processing device |
CN112266525A (en) * | 2020-11-14 | 2021-01-26 | 吴春明 | Anti-cracking polyethylene photovoltaic cable material and preparation method thereof |
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