CN114456021A - Composite reducing agent for firework unpacking powder - Google Patents
Composite reducing agent for firework unpacking powder Download PDFInfo
- Publication number
- CN114456021A CN114456021A CN202111524117.6A CN202111524117A CN114456021A CN 114456021 A CN114456021 A CN 114456021A CN 202111524117 A CN202111524117 A CN 202111524117A CN 114456021 A CN114456021 A CN 114456021A
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- CN
- China
- Prior art keywords
- reducing agent
- parts
- powder
- unpacking
- composite reducing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003638 chemical reducing agent Substances 0.000 title claims abstract description 40
- 239000000843 powder Substances 0.000 title claims abstract description 26
- 239000002131 composite material Substances 0.000 title claims abstract description 24
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 claims abstract description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003610 charcoal Substances 0.000 claims abstract description 8
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 8
- 239000011593 sulfur Substances 0.000 claims abstract description 8
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical group [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims 1
- 230000035945 sensitivity Effects 0.000 abstract description 12
- 239000000203 mixture Substances 0.000 abstract description 6
- 230000003068 static effect Effects 0.000 abstract description 2
- 239000007769 metal material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000001514 detection method Methods 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229940007424 antimony trisulfide Drugs 0.000 description 3
- NVWBARWTDVQPJD-UHFFFAOYSA-N antimony(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Sb+3].[Sb+3] NVWBARWTDVQPJD-UHFFFAOYSA-N 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- DQYBDCGIPTYXML-UHFFFAOYSA-N ethoxyethane;hydrate Chemical compound O.CCOCC DQYBDCGIPTYXML-UHFFFAOYSA-N 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000002783 friction material Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003721 gunpowder Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 229910052959 stibnite Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B29/00—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
- C06B29/02—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal
- C06B29/12—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal with carbon or sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Air Bags (AREA)
Abstract
The invention discloses a composite reducing agent for fireworks unpacking powder, which comprises, by weight, 15-25 parts of charcoal powder, 10-18 parts of sulfur, 8-12 parts of antimony sulfide and 2-18 parts of phthalic acid, and the components are uniformly mixed. As a substitute of the existing pyrotechnic composition reducing agent, the composite reducing agent provided by the invention has lower friction sensitivity, impact sensitivity, flame sensitivity and static sensitivity, better heat stability at 75 ℃, large heat productivity and high safety performance.
Description
Technical Field
The invention relates to a reducing agent for fireworks unpacking powder.
Background
In the prior art, the firework powder-unpacking powder of firework production enterprises all comprise metal materials: silver powder, aluminum-magnesium alloy powder, copper oxide, and the like, and these metal materials are used as a reducing agent for pyrotechnic charge. The metal material is sensitive, and accidents are easily caused in the production of fireworks, particularly in the process of mixing the medicines. Therefore, for safety reasons, the use of unpacking powder of metal-containing materials is now prohibited by fireworks products exported in the united states.
The invention content is as follows:
in order to solve the disadvantages, the invention aims to provide a safer reducing agent for fireworks unpacking powder. In order to solve the technical problems, the invention adopts the technical scheme that:
the composite reducing agent for fireworks unpacking powder is characterized by comprising, by weight, 15-25 parts of charcoal powder, 10-18 parts of sulfur, 8-12 parts of antimony sulfide and 2-18 parts of phthalic acid, and the components are uniformly mixed.
Preferably, the composite reducing agent comprises 20 parts of charcoal powder, 15 parts of sulfur, 10 parts of antimony sulfide and 10 parts of phthalic acid by weight.
The components are as follows: the sulfur is a reducing agent, is quickly oxidized in the chemical reaction of the combustion of the pyrotechnic composition and quickly combusted with the charcoal to generate a large amount of heat and gas;
antimony sulfide is also known as antimony trisulfide, and is a combustible material that can be burned in oxygen or air. Antimony trisulfide is very easily oxidized, and the ignition point in air, i.e. the temperature from thermal oxidation, depends on its particle size. Antimony trisulfide is widely used as an additive or a catalytic, moisture-proof agent and a heat stabilizer in the aspects of military gunpowder, glass rubber, match, fireworks, friction materials and the like, and replaces antimony oxide to be used as a flame-retardant synergist. Antimony sulfide used in the firework and cracker industry is processed from stibnite ore powder, is black or gray black powder, has metallic luster, is insoluble in water and has strong reducibility. In contrast, 290 ℃ for a particle size of 0.1mm and 340 ℃ for a particle size of 0.2 mm. Antimony sulfide and chlorate are prohibited.
Phthalic acid, also known as o-phthalic acid; 1, 2-phthalic acid; the two carboxyl groups of the o-phthalic acid are respectively connected with two adjacent carbon atoms in the benzene ring to form the binary aromatic carboxylic acid. The molecular formula is as follows: c8H6O4. Molecular weight: 166.13. CAS number: 88-99-3.
The properties are as follows: colorless monoclinic crystals. Melting point 191 deg.C (closed tube). Density (20/4 ℃ C.) of 1.593g/cm3. When rapidly heated to 230 ℃, it melts and decomposes into water and phthalic anhydride. Slightly soluble in water and diethyl ether, soluble in methanol and ethanol, and insoluble in chloroform and benzene. It can be used to prepare dye, polyester resin, terylene, medicine and plasticizer.
The reducing agent is a substance that loses electrons or has an electron deviation in a redox reaction. The reducing agent itself has reducing property and is oxidized, and the product is called oxidation product. The reducing agent reduces the oxide in the oxidation-reduction reaction to reduce the valence of the oxide. The reduction and oxidation reactions are carried out simultaneously.
The composite reducing agent is applied to fireworks unpacking powder.
The method comprises the following steps of (1) preparing fireworks unpacking powder: reducing agents according to the weight ratio: mixing oxidant at ratio of 1: 2. The oxidant is preferably potassium perchlorate.
The invention has the beneficial effect that the smoke reducing agent is used as a substitute of the existing pyrotechnic composition reducing agent. The composite reducing agent provided by the invention has lower friction sensitivity, impact sensitivity, flame sensitivity and static sensitivity, better 750C heat stability, large heat productivity and high safety performance.
In the description herein, references to the description of "one embodiment," "an example," "a specific example" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
Detailed Description
Example 1: reflects a specific preparation mode of the invention.
The preparation method of the composite reducing agent for the firework unpacking powder comprises the following steps: weighing 20 parts of charcoal powder, 15 parts of sulfur, 10 parts of antimony sulfide and 10 parts of phthalic acid according to weight. The components are uniformly mixed according to a common method to obtain the composition.
Examples 2 to 9: reflecting other specific modes of preparation of the invention.
The difference from the example 1 lies in the different mixture ratio of the components. The weight part ratios of the examples are shown in the following table 1;
TABLE 1
| Example number | Charcoal powder (parts) | Sulfur (in parts) | Antimony sulfide (in) | Phthalic acid (part) |
| 2 | 15 | 13 | 12 | 15 |
| 3 | 25 | 14 | 8 | 12 |
| 4 | 19 | 15 | 10 | 18 |
| 5 | 17 | 11 | 9 | 5 |
| 6 | 18 | 12 | 11 | 2 |
| 7 | 20 | 16 | 8 | 8 |
| 8 | 16 | 18 | 10 | 16 |
| 9 | 22 | 10 | 10 | 14 |
Security performance detection
The composite reducing agent prepared by the method randomly samples and commissions the national firework and firecracker product quality supervision and inspection center to carry out the following detection and issue a detection report-report number WAY 20211448:
first, a consignment unit: entrusted unit contact Yangbijiang of Liuyang city lucky environmental protection materials development Limited company
Secondly, the number of samples: date of production of 150g sample: appearance of sample at 10 months and 30 days 2021: black powder
Thirdly, checking and judging according to the following steps: AQ 4104 + 2008 safety performance index and determination method for fireworks and crackers pyrotechnic composition
Fourthly, detection purpose: verification of safety of composite reducing agent and application of composite reducing agent to unpacking drug
Fifthly, checking results: according to the requirement of the commission inspection, the inspected items conform to the requirements of AQ 4104-. Specific test items and results are shown in table 2:
sixthly, result analysis: 1. the sensitivity to friction and impact is an index for measuring the anti-friction, anti-impact and anti-static damage capability of the medicament in production, transportation and transportation, and the test results in table 2 show that: the friction and impact sensitivity of the composite reducing agent is 0, which not only meets the national standard requirements, but also is far lower than the indexes of the existing metal material reducing agents.
2. The inspection results in table 2 show that the composite reducing agent of the invention has low electrostatic sensitivity and is more insensitive than the prior metal material reducing agent.
3. The test results in table 2 show that the composite reducing agent of the invention has more insensitive sensitivity to flame than the prior reducing agent of metal materials.
4. The test results in table 2 show that the moisture absorption rate of the composite reducing agent meets the requirements of national standards.
5. The thermal stability test is an index for measuring the ability of the product to resist extreme high temperature conditions in production, transportation and storage, and the test results in Table 2 show that the composite reducing agent of the invention does not have combustion and explosion phenomena after the test, and meets the requirements of national standards.
6. The inspection results in table 2 show that the composite reducing agent of the invention can not be ignited by a firing line, and the safety is guaranteed.
The application mode of the composite reducing agent. Preparing fireworks unpacking powder: reducing agents according to the weight ratio: and weighing the composite reducing agent and the potassium perchlorate according to the ratio of 1:2, and uniformly mixing according to a known conventional process to prepare the potassium perchlorate.
The embodiments of the invention disclosed above are intended merely to aid in the explanation of the invention. The examples are not intended to be exhaustive or to limit the invention to the precise forms disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best understand the invention for and utilize the invention. This invention can be practiced otherwise than as specifically described herein and similar modifications can be made by those skilled in the art without departing from the spirit and scope of the invention and it is intended that the invention be limited only by the claims and their full scope and equivalents, rather than by the specific embodiments disclosed.
Claims (5)
1. The composite reducing agent for fireworks unpacking powder is characterized by comprising, by weight, 15-25 parts of charcoal powder, 10-18 parts of sulfur, 8-12 parts of antimony sulfide and 2-18 parts of phthalic acid, and the components are uniformly mixed.
2. The composite reducing agent according to claim 1, wherein the composite reducing agent comprises, by weight, 20 parts of charcoal powder, 15 parts of sulfur, 10 parts of antimony sulfide, and 10 parts of phthalic acid.
3. The composite reducing agent is applied to fireworks unpacking powder.
4. The use according to claim 3, wherein the fireworks unpacking powder is manufactured by: reducing agents according to the weight ratio: and (3) uniformly mixing the oxidant 1:2 to obtain the catalyst.
5. Use according to claim 4, wherein the oxidant is preferably potassium perchlorate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111524117.6A CN114456021A (en) | 2021-12-14 | 2021-12-14 | Composite reducing agent for firework unpacking powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111524117.6A CN114456021A (en) | 2021-12-14 | 2021-12-14 | Composite reducing agent for firework unpacking powder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114456021A true CN114456021A (en) | 2022-05-10 |
Family
ID=81406644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111524117.6A Pending CN114456021A (en) | 2021-12-14 | 2021-12-14 | Composite reducing agent for firework unpacking powder |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114456021A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1376657A (en) * | 2002-04-24 | 2002-10-30 | 深圳市华之泰投资有限公司 | Fireworks-firecrackers assembly and its preparing process |
| CN1640856A (en) * | 2004-01-12 | 2005-07-20 | 刘青春 | Fireworks detonating agent without chlorate and perchlorate |
| CN101270014A (en) * | 2008-05-06 | 2008-09-24 | 湖南省浏阳金生花炮有限公司 | Blast black powder for fireworks |
| CN106397075A (en) * | 2016-08-31 | 2017-02-15 | 万载县建坤化工有限公司 | Safe blasting-fuse composition for firecracker |
| CN106673929A (en) * | 2016-12-13 | 2017-05-17 | 杨厚煌 | Organic carbon powder explosive reducing agent |
-
2021
- 2021-12-14 CN CN202111524117.6A patent/CN114456021A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1376657A (en) * | 2002-04-24 | 2002-10-30 | 深圳市华之泰投资有限公司 | Fireworks-firecrackers assembly and its preparing process |
| CN1640856A (en) * | 2004-01-12 | 2005-07-20 | 刘青春 | Fireworks detonating agent without chlorate and perchlorate |
| CN101270014A (en) * | 2008-05-06 | 2008-09-24 | 湖南省浏阳金生花炮有限公司 | Blast black powder for fireworks |
| CN106397075A (en) * | 2016-08-31 | 2017-02-15 | 万载县建坤化工有限公司 | Safe blasting-fuse composition for firecracker |
| CN106673929A (en) * | 2016-12-13 | 2017-05-17 | 杨厚煌 | Organic carbon powder explosive reducing agent |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220510 |
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