CN114354446A - Selection and evaluation method of window sealant for rail vehicle - Google Patents

Selection and evaluation method of window sealant for rail vehicle Download PDF

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CN114354446A
CN114354446A CN202210018369.XA CN202210018369A CN114354446A CN 114354446 A CN114354446 A CN 114354446A CN 202210018369 A CN202210018369 A CN 202210018369A CN 114354446 A CN114354446 A CN 114354446A
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adhesive
test
glass
samples
rail vehicle
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张静
孙禹
李丽
何晓龙
王浩
姜代旬
倪强
赵民
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CRRC Qingdao Sifang Co Ltd
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Abstract

本发明提供了一种轨道车辆车窗密封胶选型评价方法,包括:初选胶粘剂类型,胶粘剂选择符合性能指标的低模量胶;对初选的各胶粘剂进行粘接性能测试,将胶粘剂在不同类型的样板上各涂打多条胶条,并依次经过常温固化、泡水、高温、高温高湿、低温的试验环境;对初选的各胶粘剂进行人工加速老化性能测试,人工加速老化性能测试包括紫外老化试验、高温疲劳振动试验、模拟酸雨浸泡试验、高低温湿热交变老化试验中的至少一项;对比各胶粘剂的性能差异,选择评价性能最优良、最稳定的胶粘剂类型作为轨道车辆车窗密封胶。本发明解决了现有技术中的胶粘剂选型方法无法选择出适合轨道车辆车窗使用的可靠性好的密封胶的问题。

Figure 202210018369

The invention provides a type selection evaluation method for a window sealant of a rail vehicle, which comprises the following steps: initially selecting the type of the adhesive, selecting the low-modulus adhesive that meets the performance index; Different types of samples were coated with multiple strips of adhesive strips, and then passed through the test environment of room temperature curing, soaking in water, high temperature, high temperature and high humidity, and low temperature; artificially accelerated aging performance tests were carried out on the initially selected adhesives, and artificially accelerated aging performance The test includes at least one of ultraviolet aging test, high temperature fatigue vibration test, simulated acid rain soaking test, high and low temperature humidity and heat alternating aging test; compare the performance differences of each adhesive, and select the type of adhesive with the best and most stable evaluation performance as the rail vehicle Window sealant. The invention solves the problem that the adhesive type selection method in the prior art cannot select a reliable sealant suitable for rail vehicle windows.

Figure 202210018369

Description

轨道车辆车窗密封胶选型评价方法Selection and evaluation method of window sealant for rail vehicle

技术领域technical field

本发明涉及轨道车辆技术领域,具体而言,涉及一种轨道车辆车窗密封胶选型评价方法。The invention relates to the technical field of rail vehicles, in particular to a method for evaluating the selection and evaluation of sealants for windows of rail vehicles.

背景技术Background technique

轨道交通车辆用车窗密封胶在服役过程中受到温度、湿度、日光照射和各类应力等诸多外界因素的综合作用,会出现变色、龟裂、边缘开裂等老化现象,力学性能下降,使用寿命缩短,不但影响车辆外观,给车辆运行带来了一定安全隐患,更给车辆检修和售后服务提出了难题。Window sealants for rail transit vehicles are subject to the combined effects of many external factors such as temperature, humidity, sunlight, and various stresses during service, and aging phenomena such as discoloration, cracking, and edge cracking will occur, mechanical properties will decline, and service life will be reduced. The shortening not only affects the appearance of the vehicle, but also brings certain hidden dangers to the operation of the vehicle, and also poses a problem for the maintenance and after-sales service of the vehicle.

常规的胶粘剂选型过程仅参照了胶粘剂产品说明书中的性能参数,仅依据标准的测试方法判定胶粘剂的性能。依此选择的胶粘剂应用于车辆后,在实际车辆运营过程中仍会出现密封胶开裂、漏水等故障。胶粘剂的老化和破坏受到多种因素的影响。比如,在高低温循环交变试验中,由于胶粘剂与被粘材料热膨胀系数不同,在经过多次冷热交变循环后,粘接界面易出现开裂,进而导致粘接失效;在耐酸雨浸泡试验中,酸性溶液易腐蚀胶粘剂表面,并易渗入粘接界面使粘接失效;在振动疲劳试验中,周期性的应力会导致胶粘剂的微小缺陷逐渐发展,一定时间之后,便可出现界面破坏;在紫外老化试验中,持续高强度的紫外光照射会使胶粘剂表面的大分子链出现断裂,进而导致表面出现开裂,且裂纹会不断加深,逐渐造成粘接失效。The conventional adhesive selection process only refers to the performance parameters in the adhesive product specification, and only judges the performance of the adhesive according to the standard test method. After the adhesive selected in this way is applied to the vehicle, faults such as sealant cracking and water leakage will still occur during the actual vehicle operation. The aging and destruction of adhesives is affected by a variety of factors. For example, in the high and low temperature cyclic alternating test, due to the different thermal expansion coefficients of the adhesive and the material to be adhered, after many alternating cycles of cold and heat, the bonding interface is prone to cracking, which leads to bonding failure; in the acid rain immersion test In the vibration fatigue test, the periodic stress will lead to the gradual development of small defects in the adhesive, and after a certain period of time, interface damage will occur; In the UV aging test, continuous high-intensity UV irradiation will break the macromolecular chains on the surface of the adhesive, which will lead to cracks on the surface, and the cracks will continue to deepen, gradually causing bonding failure.

由此可见,现有的仅按照标准测试方法判定胶粘剂的性能的方法并不能选择出适合轨道车辆车窗使用的可靠性好的密封胶。It can be seen that the existing method of judging the performance of the adhesive only according to the standard test method cannot select a reliable sealant suitable for the use of rail vehicle windows.

发明内容SUMMARY OF THE INVENTION

本发明的主要目的在于提供一种轨道车辆车窗密封胶选型评价方法,以解决现有技术中的胶粘剂选型方法无法选择出适合轨道车辆车窗使用的可靠性好的密封胶的问题。The main purpose of the present invention is to provide a type selection evaluation method for rail vehicle window sealant, so as to solve the problem that the adhesive type selection method in the prior art cannot select a reliable sealant suitable for rail vehicle windows.

为了实现上述目的,本发明提供了一种轨道车辆车窗密封胶选型评价方法,包括:初选胶粘剂类型,胶粘剂选择符合性能指标的低模量胶;对初选的各胶粘剂进行粘接性能测试,将胶粘剂在不同类型的样板上各涂打多条胶条,并依次经过常温固化、泡水、60-100℃的高温、50-90℃、高于90%相对湿度的高温高湿、-60到-20℃的低温的试验环境,每个试验环境结束后剥离胶条测试,每个试验环境中的各胶条的总内聚破坏比例大于95%为合格;对初选的各胶粘剂进行人工加速老化性能测试,人工加速老化性能测试包括紫外老化试验、高温疲劳振动试验、模拟酸雨浸泡试验、高低温湿热交变老化试验中的至少一项,每个试验后测试并计算胶粘剂的拉伸剪切强度保持率;对比各胶粘剂的性能差异,选择评价性能最优良、最稳定的胶粘剂类型作为轨道车辆车窗密封胶。In order to achieve the above purpose, the present invention provides a method for selecting and evaluating types of sealants for rail vehicle windows, which includes: preselecting the type of adhesives, selecting low-modulus adhesives that meet performance indicators for the adhesives; In the test, the adhesive is coated with multiple strips on different types of samples, and then cured at room temperature, soaked in water, high temperature of 60-100 °C, 50-90 °C, high temperature and high humidity higher than 90% relative humidity, In the low temperature test environment of -60 to -20°C, after each test environment, the adhesive strip is peeled off, and the total cohesive failure ratio of each adhesive strip in each test environment is more than 95%, which is qualified; Carry out artificial accelerated aging performance test. The artificial accelerated aging performance test includes at least one of ultraviolet aging test, high temperature fatigue vibration test, simulated acid rain immersion test, high and low temperature humidity and heat alternating aging test, and test and calculate the tensile strength of the adhesive after each test. Tensile shear strength retention rate; compare the performance differences of each adhesive, and select the type of adhesive with the best and most stable performance as the rail vehicle window sealant.

进一步地,在初选胶粘剂类型时,根据胶粘剂的性能检测报告,选择拉伸剪切强度1.5~4.5Mpa,拉断伸长率200%~450%,23℃、50%相对湿度时的单面固化深度≥12mm/7d,表干时间≥10min,玻璃化转变温度≤-60℃的胶粘剂。Further, in the primary selection of the adhesive type, according to the performance test report of the adhesive, select the tensile shear strength of 1.5~4.5Mpa, the elongation at break of 200%~450%, and the single side at 23℃ and 50% relative humidity. Adhesive with curing depth ≥12mm/7d, surface dry time ≥10min, glass transition temperature ≤-60℃.

进一步地,胶粘剂包括聚氨酯胶、改性硅烷胶、有机硅胶中的至少一项。Further, the adhesive includes at least one of polyurethane glue, modified silane glue, and organic silica gel.

进一步地,在对初选的各胶粘剂进行粘接性能测试时,将初选出的每种胶粘剂在玻璃、铝合金、不锈钢、玻璃钢四种样板上各涂打三条宽度9-11mm,高度大于5mm,长度大于300mm的胶条,然后依次经过常温固化7天、泡水7天、60-100℃的高温1天、50-90℃且高于90%相对湿度的高温高湿7天、-60到-20℃的低温1天的试验环境。Further, when testing the adhesive properties of the initially selected adhesives, apply three strips of each of the initially selected adhesives on the four sample plates of glass, aluminum alloy, stainless steel and glass fiber reinforced plastic with a width of 9-11mm and a height of more than 5mm. , the length of the strip is greater than 300mm, and then cured at room temperature for 7 days, soaked in water for 7 days, high temperature of 60-100 ℃ for 1 day, 50-90 ℃ and higher than 90% relative humidity for 7 days at high temperature and high humidity, -60 To a low temperature of -20°C for 1 day in the test environment.

进一步地,试验环境依次为在23℃、50%相对湿度的环境固化7天;在23℃环境温度下放置水中浸泡7天后拿出室温调节2h;在80℃环境下放置1天立即检测,高温拿出后调节2h;在70℃、95%相对湿度的环境放置7天后拿出室温调节2h;-40℃低温放置1天五步连续试验环境,每个试验环境结束后进行胶条剥离。Further, the test environment was cured in an environment of 23°C and 50% relative humidity for 7 days; soaked in water for 7 days at 23°C, and then taken out to adjust at room temperature for 2h; placed at 80°C for 1 day and immediately detected, high temperature After taking it out, adjust for 2 hours; place it in an environment of 70 °C and 95% relative humidity for 7 days and then take it out for 2 hours at room temperature; place it at -40 °C for 1 day in a five-step continuous test environment, and peel off the adhesive strip after each test environment.

进一步地,在对初选的各胶粘剂进行人工加速老化性能测试时,将由胶粘剂连接的铝合金-玻璃、不锈钢-玻璃、玻璃钢-玻璃三种试样制备拉伸剪切试样,然后进行紫外老化试验、高温疲劳振动试验、模拟酸雨浸泡试验、高低温湿热交变老化试验。Further, in the artificial accelerated aging performance test of each of the primary adhesives, three samples of aluminum alloy-glass, stainless steel-glass, and glass fiber reinforced plastics connected by the adhesive were prepared for tensile shearing samples, and then subjected to ultraviolet aging. Test, high temperature fatigue vibration test, simulated acid rain immersion test, high and low temperature humidity and heat alternating aging test.

进一步地,在进行紫外老化试验时,将由胶粘剂连接的铝合金-玻璃、不锈钢-玻璃、玻璃钢-玻璃三种试样制备拉伸剪切试样,使用工装对试样施加20%的应变,并分别进行8h干燥,紫外波长340nm,辐照度0.76±0.02W/m2×nm,黑板温度60±3℃,4h冷凝,黑板温度50±3℃的循环,每种试样均进行试验周期为1000h、1500h、2000h的三次试验,每个试验周期后测试并计算拉伸剪切强度保持率。Further, in the ultraviolet aging test, three kinds of samples of aluminum alloy-glass, stainless steel-glass, and glass fiber reinforced plastics connected by adhesive were used to prepare tensile shear samples, and a 20% strain was applied to the samples using tooling, and 8h drying, UV wavelength 340nm, irradiance 0.76±0.02W/m 2 ×nm, blackboard temperature 60±3℃, 4h condensation, blackboard temperature 50±3℃ cycle, each sample was tested for a cycle of Three tests of 1000h, 1500h, and 2000h, test and calculate the retention rate of tensile shear strength after each test cycle.

进一步地,在进行高温疲劳振动试验时,将由胶粘剂连接的铝合金-玻璃、不锈钢-玻璃、玻璃钢-玻璃三种试样制备拉伸剪切试样,且胶层厚度为4-6mm,在70℃下进行胶粘剂材料疲劳老化试验,试样振幅为1.0mm,频率30Hz,循环至少100万次,测试并计算老化前后拉伸剪切强度保持率。Further, in the high-temperature fatigue vibration test, three kinds of samples of aluminum alloy-glass, stainless steel-glass, and glass fiber reinforced plastics connected by adhesive were used to prepare tensile shear samples, and the thickness of the adhesive layer was 4-6mm. The fatigue aging test of the adhesive material is carried out at ℃. The sample amplitude is 1.0mm, the frequency is 30Hz, and the cycle is at least 1 million times. The tensile shear strength retention rate before and after aging is tested and calculated.

进一步地,在进行模拟酸雨浸泡试验时,将由胶粘剂连接的铝合金-玻璃、不锈钢-玻璃、玻璃钢-玻璃三种试样制备拉伸剪切试样,使用工装对试样施加20%的应变,将每种试样均在40℃的pH=2.0的模拟酸雨溶液中进行480h、960h、1440h的浸泡,在各个时间点依次取出试样进行拉伸剪切强度,测试并计算拉伸剪切强度保持率。Further, in the simulated acid rain soaking test, three kinds of samples of aluminum alloy-glass, stainless steel-glass, and glass fiber reinforced plastics connected by adhesives were prepared for tensile shearing samples, and 20% strain was applied to the samples using tooling, Each sample was soaked in a simulated acid rain solution with pH=2.0 at 40°C for 480h, 960h, and 1440h, and the samples were taken out at each time point for tensile shear strength, and the tensile shear strength was tested and calculated. retention rate.

进一步地,在进行高低温湿热交变老化试验时,将由胶粘剂连接的铝合金-玻璃、不锈钢-玻璃、玻璃钢-玻璃三种试样制备拉伸剪切试样,并进行80℃、95%相对湿度下放置4h,2h内冷却到-40℃,在-40℃下放置4h,2h内升温到80℃、95%相对湿度的循环,每种试样均进行试验周期为480h、720h、960h、1440h的四次试验,每个试验周期后测试并计算拉伸剪切强度保持率。Further, in the high and low temperature humidity and heat alternating aging test, three kinds of samples of aluminum alloy-glass, stainless steel-glass, and glass fiber reinforced plastics connected by adhesive were used to prepare tensile shear samples, and were subjected to 80°C, 95% relative Placed under humidity for 4h, cooled to -40°C within 2h, placed at -40°C for 4h, heated to 80°C within 2h, 95% relative humidity cycle, each sample was tested for 480h, 720h, 960h, Four tests of 1440h were tested and the retention of tensile shear strength was measured and calculated after each test cycle.

进一步地,在选择评价性能最优良、最稳定的胶粘剂类型作为轨道车辆车窗密封胶时,选择拉伸剪切强度保持率大于55%的胶粘剂作为最优良、最稳定的胶粘剂。Further, when selecting the type of adhesive with the best evaluation performance and the most stable as the rail vehicle window sealant, the adhesive with the retention rate of tensile shear strength greater than 55% is selected as the best and most stable adhesive.

应用本发明的技术方案,通过三个阶段对应用在轨道车辆车窗密封的胶粘剂进行严格筛选,具体而言,分为初选胶粘剂、粘接性能测试和人工加速老化性能测试三个阶段,并在人工加速老化性能测试时进行紫外老化试验、高温疲劳振动试验、模拟酸雨浸泡试验、高低温湿热交变老化试验,从而能够充分验证和评价胶粘剂的性能,选用真实基材进行人工加速老化性能测试且对试样施加了一定的应变,模拟车辆实际运行过程中受载荷变形的情况,更接近真实车辆运行中的载荷工况。经过上述评价方法确认合格的胶粘剂应用于轨道车辆的车窗密封可防止车辆运营过程中出现密封胶开裂、漏雨现象,保障了轨道车辆车窗密封性,提高乘客乘坐舒适度,减少了车辆运营故障,保证了车窗密封环境需求和正常运营检修周期。同时弥补了现有的粘接接头在复杂服役环境中老化方法及相关性能评价的空白,具有性能考核较完善和节省老化试验时间等优点。By applying the technical scheme of the present invention, the adhesives used in the window sealing of rail vehicles are strictly screened through three stages. In the artificial accelerated aging performance test, ultraviolet aging test, high temperature fatigue vibration test, simulated acid rain immersion test, high and low temperature humidity and heat alternating aging test can be carried out, so that the performance of the adhesive can be fully verified and evaluated, and real substrates are selected for artificial accelerated aging performance test. And a certain strain is applied to the sample to simulate the deformation of the vehicle under load during the actual operation of the vehicle, which is closer to the load condition in the real vehicle operation. The application of the qualified adhesive to the window sealing of rail vehicles through the above evaluation methods can prevent the cracking of the sealant and the phenomenon of rain leakage during the operation of the vehicle, ensure the sealing of the windows of the rail vehicle, improve the passenger comfort, and reduce the operation of the vehicle. Failure to ensure the environmental requirements of the window seal and the normal operation and maintenance cycle. At the same time, it makes up for the existing gaps in the aging method and related performance evaluation of bonded joints in complex service environments, and has the advantages of more complete performance evaluation and saving aging test time.

附图说明Description of drawings

构成本申请的一部分的说明书附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The accompanying drawings forming a part of the present application are used to provide further understanding of the present invention, and the exemplary embodiments of the present invention and their descriptions are used to explain the present invention and do not constitute an improper limitation of the present invention. In the attached image:

图1示出了本发明的轨道车辆车窗密封胶选型评价方法的流程图;Fig. 1 shows the flow chart of the method for selecting and evaluating type of sealant for rail vehicle window of the present invention;

图2示出了图1中的轨道车辆车窗密封胶选型评价方法的粘接性能测试的流程图;Fig. 2 shows the flow chart of the bonding performance test of the method for selecting and evaluating the sealant for rail vehicle window in Fig. 1;

图3示出了图1中的轨道车辆车窗密封胶选型评价方法的拉伸剪切试样施加20%应变的示意图;Fig. 3 shows a schematic diagram of applying 20% strain to the tensile shear specimen of the method for evaluating the selection and evaluation of sealant for rail vehicle windows in Fig. 1;

图4示出了图1中的轨道车辆车窗密封胶选型评价方法的高低温湿热交变老化试验中一个循环的示意图。FIG. 4 shows a schematic diagram of a cycle in the high and low temperature humidity and heat alternating aging test of the method for evaluating the selection and evaluation of sealant for rail vehicle windows in FIG. 1 .

具体实施方式Detailed ways

需要说明的是,在不冲突的情况下,本申请中的实施例及实施例中的特征可以相互组合。下面将参考附图并结合实施例来详细说明本发明。It should be noted that the embodiments in the present application and the features of the embodiments may be combined with each other in the case of no conflict. The present invention will be described in detail below with reference to the accompanying drawings and in conjunction with the embodiments.

需要指出的是,除非另有指明,本申请使用的所有技术和科学术语具有与本申请所属技术领域的普通技术人员通常理解的相同含义。It should be noted that, unless otherwise specified, all technical and scientific terms used in this application have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs.

在本发明中,在未作相反说明的情况下,使用的方位词如“上、下、顶、底”通常是针对附图所示的方向而言的,或者是针对部件本身在竖直、垂直或重力方向上而言的;同样地,为便于理解和描述,“内、外”是指相对于各部件本身的轮廓的内、外,但上述方位词并不用于限制本发明。In the present invention, unless otherwise stated, the directional words used such as "upper, lower, top, bottom" are usually for the directions shown in the drawings, or for the components themselves in vertical, In terms of vertical or gravitational direction; similarly, for the convenience of understanding and description, "inner and outer" refers to the inner and outer relative to the contour of each component itself, but the above-mentioned orientation words are not used to limit the present invention.

为了解决现有技术中的胶粘剂选型方法无法选择出适合轨道车辆车窗使用的可靠性好的密封胶的问题,本发明提供了一种轨道车辆车窗密封胶选型评价方法。In order to solve the problem that the adhesive type selection method in the prior art cannot select a reliable sealant suitable for rail vehicle windows, the present invention provides a type selection evaluation method for rail vehicle window sealants.

如图1所示的一种轨道车辆车窗密封胶选型评价方法,包括:初选胶粘剂类型,胶粘剂选择符合性能指标的低模量胶;对初选的各胶粘剂进行粘接性能测试,将胶粘剂在不同类型的样板上各涂打多条胶条,并依次经过常温固化、泡水、60-100℃的高温、50-90℃、高于90%相对湿度的高温高湿、-60到-20℃的低温的试验环境,每个试验环境结束后剥离胶条测试,每个试验环境中的各胶条的总内聚破坏比例大于95%为合格;对初选的各胶粘剂进行人工加速老化性能测试,人工加速老化性能测试包括紫外老化试验、高温疲劳振动试验、模拟酸雨浸泡试验、高低温湿热交变老化试验中的至少一项,每个试验后测试并计算胶粘剂的拉伸剪切强度保持率;对比各胶粘剂的性能差异,选择评价性能最优良、最稳定的胶粘剂类型作为轨道车辆车窗密封胶。As shown in Figure 1, a method for evaluating the selection and evaluation of sealants for rail vehicle windows includes: primary selection of adhesive types, and selection of low-modulus adhesives that meet performance indicators; The adhesive is coated with multiple strips on different types of samples, and then cured at room temperature, soaked in water, high temperature of 60-100 ° C, 50-90 ° C, high temperature and high humidity higher than 90% relative humidity, -60 to In the low temperature test environment of -20°C, after the end of each test environment, the adhesive strip is peeled off, and the total cohesive failure ratio of each adhesive strip in each test environment is more than 95%, which is qualified; artificial acceleration is performed on the primary adhesives. Aging performance test, artificial accelerated aging performance test includes at least one of ultraviolet aging test, high temperature fatigue vibration test, simulated acid rain immersion test, high and low temperature humidity and heat alternating aging test, test and calculate the tensile shear of the adhesive after each test Strength retention rate; compare the performance differences of various adhesives, and select the type of adhesive with the best and most stable evaluation performance as the rail vehicle window sealant.

本实施例通过三个阶段对应用在轨道车辆车窗密封的胶粘剂进行严格筛选,具体而言,分为初选胶粘剂、粘接性能测试和人工加速老化性能测试三个阶段,并在人工加速老化性能测试时进行紫外老化试验、高温疲劳振动试验、模拟酸雨浸泡试验、高低温湿热交变老化试验,从而能够充分验证和评价胶粘剂的性能,选用真实基材进行人工加速老化性能测试且对试样施加了一定的应变,模拟车辆实际运行过程中受载荷变形的情况,更接近真实车辆运行中的载荷工况。经过上述评价方法确认合格的胶粘剂应用于轨道车辆的车窗密封可防止车辆运营过程中出现密封胶开裂、漏雨现象,保障了轨道车辆车窗密封性,提高乘客乘坐舒适度,减少了车辆运营故障,保证了车窗密封环境需求和正常运营检修周期。同时弥补了现有的粘接接头在复杂服役环境中老化方法及相关性能评价的空白,具有性能考核较完善和节省老化试验时间等优点。In this embodiment, the adhesives used in the window sealing of rail vehicles are strictly screened in three stages. Specifically, it is divided into three stages: primary selection of adhesives, adhesion performance test and artificial accelerated aging performance test. In the performance test, ultraviolet aging test, high temperature fatigue vibration test, simulated acid rain immersion test, high and low temperature humidity and heat alternating aging test are carried out, so that the performance of the adhesive can be fully verified and evaluated. A certain strain is applied to simulate the deformation of the vehicle under load during the actual operation of the vehicle, which is closer to the load condition in the actual vehicle operation. The application of the qualified adhesive to the window sealing of rail vehicles through the above evaluation methods can prevent the cracking of the sealant and the phenomenon of rain leakage during the operation of the vehicle, ensure the sealing of the windows of the rail vehicle, improve the passenger comfort, and reduce the operation of the vehicle. Failure to ensure the environmental requirements of the window seal and the normal operation and maintenance cycle. At the same time, it makes up for the existing gaps in the aging method and related performance evaluation of bonded joints in complex service environments, and has the advantages of more complete performance evaluation and saving aging test time.

在本实施例中,在初选胶粘剂类型时,根据胶粘剂的性能检测报告,选择拉伸剪切强度1.5~4.5Mpa,拉断伸长率200%~450%,单面固化深度(23℃、50%相对湿度的环境下)≥12mm/7d(毫米/天),表干时间≥10min,玻璃化转变温度(中值)≤-60℃的胶粘剂。并且胶粘剂成分包括聚氨酯胶、改性硅烷胶、有机硅胶中的至少一项,类型优选为聚硫胶、聚氨酯胶、改性硅烷胶等低模量胶。符合上述性能指标的胶粘剂型号可作为初选出的胶粘剂进行后续试验。In this embodiment, when the type of adhesive is initially selected, according to the performance test report of the adhesive, the tensile shear strength is 1.5-4.5Mpa, the elongation at break is 200%-450%, and the single-sided curing depth (23°C, 50% relative humidity environment) ≥ 12mm/7d (mm/day), surface dry time ≥ 10min, glass transition temperature (median) ≤ -60 ℃ adhesive. And the adhesive component includes at least one of polyurethane glue, modified silane glue, and organic silica gel, and the type is preferably low-modulus glue such as polysulfide glue, polyurethane glue, and modified silane glue. Adhesive models that meet the above performance indicators can be used as the initially selected adhesives for follow-up tests.

在本实施例中,为了验证胶粘剂与实际粘接基材的黏附效果,并模拟轨道车辆运营的极端环境条件,对初选的各胶粘剂进行粘接性能测试。在测试时,将初选出的每种胶粘剂在玻璃、铝合金、不锈钢、玻璃钢四种样板上各涂打三条宽度9-11mm,优选为10mm,高度大于5mm,长度大于300mm的胶条,然后依次经过常温固化7天、泡水7天、60-100℃的高温1天、50-90℃且高于90%相对湿度的高温高湿7天、-60到-20℃的低温1天的试验环境。上述宽度、高度等参数是为了便于后续操作中使用尖嘴钳进行剪卷剥离,胶条不易断裂。每个试验条件需要剥离50mm长度,6个试验阶段共需要300mm长度。上述的温度湿度的具体参数均可以根据需要进行相应选择。In this embodiment, in order to verify the adhesion effect between the adhesive and the actual bonding substrate, and to simulate the extreme environmental conditions of rail vehicle operation, the adhesive performance test is carried out on each of the initially selected adhesives. During the test, each of the initially selected adhesives was coated with three strips of 9-11mm in width, preferably 10mm in width, 5mm in height and 300mm in length on each of the four samples of glass, aluminum alloy, stainless steel and glass fiber reinforced plastic, and then After curing at room temperature for 7 days, soaking in water for 7 days, high temperature of 60-100°C for 1 day, high temperature and humidity of 50-90°C and higher than 90% relative humidity for 7 days, and low temperature of -60 to -20°C for 1 day test environment. The above parameters such as width and height are used to facilitate the use of needle-nose pliers to cut and roll off in subsequent operations, and the rubber strip is not easy to break. Each test condition required a stripping length of 50mm, for a total of 300mm lengths for the 6 test stages. The specific parameters of the above temperature and humidity can be selected according to needs.

具体而言,如图2所示,本实施例的试验环境依次为在23℃、50%相对湿度的环境固化7天;在23℃环境温度下放置水中浸泡7天后拿出室温调节2h;在80℃环境下放置1天立即检测,80℃高温拿出后调节2h;在70℃、95%相对湿度的环境放置7天后拿出室温调节2h;-40℃低温放置1天五步连续试验环境,每个试验环境结束后进行胶条剥离,其中,在80℃环境下放置1天立即检测和80℃高温拿出后调节2h均需要进行胶条剥离,总共剥离6次。上述五个阶段中的五个分别对应常温固化、高湿度(泡水)、高温、高温高湿、低温条件五种环境下,胶粘剂与粘接基材的黏附性。每个试验环境结束后剥离胶条测试,每步试验环境后的三个平行样的总粘附破坏比例均大于95%为粘接力合格的胶粘剂,这样进一步筛选出与基材粘接力好的胶粘剂。上述过程使用高低温湿热试验箱进行。Specifically, as shown in FIG. 2 , the test environment of this embodiment is followed by curing in an environment of 23°C and 50% relative humidity for 7 days; soaking in water for 7 days at an ambient temperature of 23°C and then taking out room temperature for 2h adjustment; Put it in the environment of 80℃ for 1 day and test immediately, take out the high temperature of 80℃ and adjust for 2h; put it in the environment of 70℃ and 95% relative humidity for 7 days and then take out the room temperature and adjust it for 2h; put it at the low temperature of -40℃ for 1 day in five-step continuous test environment , the strips are peeled off after each test environment. Among them, the strips need to be stripped for 1 day at 80 °C for immediate detection and 2 hours after taking out at 80 °C for a total of 6 strippings. Five of the above five stages correspond to the adhesion between the adhesive and the bonding substrate under the five environments of room temperature curing, high humidity (water soaking), high temperature, high temperature and high humidity, and low temperature conditions. After each test environment is finished, the adhesive strip is peeled off, and the total adhesion failure ratio of the three parallel samples after each test environment is greater than 95%, which is an adhesive with qualified adhesion, which is further screened out. adhesive. The above process is carried out using a high and low temperature damp heat test chamber.

本实施例的人工加速老化性能测试包括紫外老化试验、高温疲劳振动试验、模拟酸雨浸泡试验、高低温湿热交变老化试验四项试验,即对胶粘剂进行上述四项试验,以保证试验结果全面可靠。当然,实际测试时也可以根据实际需要选择性地进行试验。在对初选的各胶粘剂进行人工加速老化性能测试时,将由胶粘剂连接的铝合金-玻璃、不锈钢-玻璃、玻璃钢-玻璃三种试样制备拉伸剪切试样,然后分别进行紫外老化试验、高温疲劳振动试验、模拟酸雨浸泡试验、高低温湿热交变老化试验。The artificial accelerated aging performance test in this embodiment includes four tests: ultraviolet aging test, high temperature fatigue vibration test, simulated acid rain soaking test, and high and low temperature humidity and heat alternating aging test, that is, the above four tests are performed on the adhesive to ensure that the test results are comprehensive and reliable. . Of course, the actual test can also be selectively carried out according to actual needs. In the artificial accelerated aging performance test of the primary selected adhesives, tensile shear samples were prepared from three kinds of samples of aluminum alloy-glass, stainless steel-glass and glass fiber reinforced plastics connected by adhesives, and then subjected to ultraviolet aging test, High temperature fatigue vibration test, simulated acid rain immersion test, high and low temperature humidity and heat alternating aging test.

具体而言,在进行紫外老化试验时,将由胶粘剂连接的铝合金-玻璃、不锈钢-玻璃、玻璃钢-玻璃三种试样制备拉伸剪切试样,使用工装对试样施加20%的应变,如图3所示,并分别进行8h干燥,紫外波长340nm,辐照度0.76±0.02W/m2×nm,黑板温度60±3℃,4h冷凝,黑板温度50±3℃的循环,每种试样均进行试验周期为1000h、1500h、2000h的三次试验,即三个试样均进行此试验周期的试验过程,每个试验周期后测试并计算拉伸剪切强度保持率。该过程使用紫外灯加速老化试验箱进行。Specifically, during the ultraviolet aging test, three kinds of samples of aluminum alloy-glass, stainless steel-glass, and glass fiber reinforced plastics connected by adhesive were prepared to prepare tensile shear samples, and a 20% strain was applied to the samples using tooling. As shown in Figure 3, and were respectively dried for 8h, UV wavelength 340nm, irradiance 0.76±0.02W/m 2 ×nm, blackboard temperature 60±3℃, 4h condensation, blackboard temperature 50±3℃, each cycle. The samples were tested three times with test cycles of 1000h, 1500h, and 2000h, that is, the three samples were all subjected to the test process of this test cycle, and the tensile shear strength retention rate was measured and calculated after each test cycle. This process is carried out using a UV lamp accelerated aging test chamber.

在进行高温疲劳振动试验时,将由胶粘剂连接的铝合金-玻璃、不锈钢-玻璃、玻璃钢-玻璃三种试样制备拉伸剪切试样,且胶层厚度为4-6mm,优选5mm,在70℃下进行胶粘剂材料疲劳老化试验,试样振幅为1.0mm,频率30Hz,循环至少100万次,测试并计算老化前后拉伸剪切强度保持率。该过程使用疲劳试验机进行。In the high-temperature fatigue vibration test, three kinds of samples of aluminum alloy-glass, stainless steel-glass, and glass fiber reinforced plastics connected by adhesive are used to prepare tensile shear samples, and the thickness of the adhesive layer is 4-6mm, preferably 5mm, at 70 The fatigue aging test of the adhesive material is carried out at ℃. The sample amplitude is 1.0mm, the frequency is 30Hz, and the cycle is at least 1 million times. The tensile shear strength retention rate before and after aging is tested and calculated. This process is carried out using a fatigue testing machine.

在进行模拟酸雨浸泡试验时,将由胶粘剂连接的铝合金-玻璃、不锈钢-玻璃、玻璃钢-玻璃三种试样制备拉伸剪切试样,使用工装对试样施加20%的应变,将每种试样均在40℃的pH=2.0的模拟酸雨溶液中进行480h、960h、1440h的浸泡,在各个时间点依次取出试样进行拉伸剪切强度,测试并计算拉伸剪切强度保持率。该过程使用高低温湿热试验箱进行。In the simulated acid rain immersion test, tensile shear specimens were prepared from three specimens of aluminum alloy-glass, stainless steel-glass, and glass fiber reinforced plastics connected by adhesives, and a 20% strain was applied to the specimens using a tooling. The samples were soaked in simulated acid rain solution with pH=2.0 at 40°C for 480h, 960h, and 1440h. The samples were taken out at each time point for tensile shear strength, and the tensile shear strength retention rate was measured and calculated. This process is carried out using a high and low temperature damp heat test chamber.

在进行高低温湿热交变老化试验时,将由胶粘剂连接的铝合金-玻璃、不锈钢-玻璃、玻璃钢-玻璃三种试样制备拉伸剪切试样,并进行80℃、95%相对湿度下放置4h,2h内冷却到-40℃,在-40℃下放置4h,2h内升温到80℃、95%相对湿度的循环,如图4所示,每种试样均进行试验周期为480h、720h、960h、1440h的四次试验,即三个试样均进行此试验周期的试验过程,每个试验周期后测试并计算拉伸剪切强度保持率。该过程使用高低温湿热试验箱进行。During the high and low temperature humidity and heat alternating aging test, three kinds of samples of aluminum alloy-glass, stainless steel-glass, and glass fiber reinforced plastics connected by adhesive were prepared for tensile shearing samples, and they were placed at 80°C and 95% relative humidity. 4h, cooling to -40°C within 2h, placing at -40°C for 4h, heating to 80°C within 2h, 95% relative humidity cycle, as shown in Figure 4, each sample was tested for 480h, 720h , 960h, 1440h four tests, that is, the three samples are all subjected to the test process of this test cycle, and the tensile shear strength retention rate is measured and calculated after each test cycle. This process is carried out using a high and low temperature damp heat test chamber.

需要说明的是,上述所说的由胶粘剂连接的试样是指试样的两种材料之间通过胶粘剂粘接连接形成一个整体,例如铝合金-玻璃即为通过胶粘剂将铝合金和玻璃粘接在一起等。It should be noted that the above-mentioned sample connected by adhesive means that the two materials of the sample are connected by adhesive to form a whole. For example, aluminum alloy-glass means that aluminum alloy and glass are bonded by adhesive. wait together.

在上述紫外老化试验、模拟酸雨浸泡试验、高低温湿热交变老化试验时,每种试验分别进行多次试验周期不同的试验,若将三种试样分别单独试验,则试验次数较多,以紫外老化试验为例,三种试样总计需要进行九次试验。为了减少试验次数,基于三种试样进行试验的环境是相同的基础,在实际试验时,可以将三种试样同时进行同一个周期的试验,例如在紫外老化试验时将三种试样同时在特定环境中进行试验周期为1000h试验,这样,三种试样只需要针对三个周期总共进行三次试验即可,极大降低了试验次数,提高了试验效率。In the above-mentioned ultraviolet aging test, simulated acid rain soaking test, and alternating high and low temperature humidity and heat aging test, each test is carried out for several times with different test cycles. Taking the UV aging test as an example, a total of nine tests are required for the three samples. In order to reduce the number of tests, the test environment based on the three samples is the same. In the actual test, the three samples can be tested in the same cycle at the same time. For example, in the ultraviolet aging test, the three samples can be tested at the same time. The test cycle is 1000h in a specific environment, so the three samples only need to be tested three times in total for three cycles, which greatly reduces the number of tests and improves the test efficiency.

本实施例为了使得试样的材质与胶粘剂在车辆车窗密封胶实际接触的材料一致,因而采用胶粘剂粘接形成的铝合金-玻璃、不锈钢-玻璃、玻璃钢-玻璃三种试样。当然,上述三种试样的具体材质也可以根据实际需要进行相应改变。In this embodiment, in order to make the material of the sample consistent with the material that the adhesive actually contacts in the vehicle window sealant, three samples of aluminum alloy-glass, stainless steel-glass, and glass fiber reinforced plastics formed by adhesive bonding are used. Of course, the specific materials of the above three samples can also be changed according to actual needs.

在进行完上述试验后,对比各胶粘剂的性能差异,选择轨道车辆车窗密封胶。选择时最终选择评价性能最优良、最稳定的胶粘剂类型作为轨道车辆车窗密封胶,更具体地说选择拉伸剪切强度保持率大于55%的胶粘剂作为最优良、最稳定的胶粘剂。After the above test is completed, the performance difference of each adhesive is compared, and the window sealant for rail vehicles is selected. When selecting, the type of adhesive with the best evaluation performance and the most stable is selected as the rail vehicle window sealant, and more specifically, the adhesive with the retention rate of tensile shear strength greater than 55% is selected as the best and most stable adhesive.

需要说明的是,上述实施例中的具体参数均可以根据需要进行相应调整,上述实施例中的多条指的是至少两条。It should be noted that, the specific parameters in the above embodiments can be adjusted correspondingly as required, and the plurality of parameters in the above embodiments refers to at least two.

从以上的描述中,可以看出,本发明上述的实施例实现了如下技术效果:From the above description, it can be seen that the above-mentioned embodiments of the present invention achieve the following technical effects:

1、解决了现有技术中的胶粘剂选型方法无法选择出适合轨道车辆车窗使用的可靠性好的密封胶的问题;1. Solve the problem that the adhesive type selection method in the prior art cannot select a reliable sealant suitable for the use of rail vehicle windows;

2、充分验证和评价胶粘剂的性能,选用真实基材进行人工加速老化性能测试且对试样施加了一定的应变,模拟车辆实际运行过程中受载荷变形的情况,更接近真实车辆运行中的载荷工况;2. Fully verify and evaluate the performance of the adhesive, select the real substrate for artificial accelerated aging performance test and apply a certain strain to the sample to simulate the deformation of the vehicle under load during the actual operation of the vehicle, which is closer to the load in the real vehicle operation working condition;

3、经过评价方法确认合格的胶粘剂应用于轨道车辆的车窗密封可防止车辆运营过程中出现密封胶开裂、漏雨现象,保障了轨道车辆车窗密封性,提高乘客乘坐舒适度,减少了车辆运营故障,保证了车窗密封环境需求和正常运营检修周期;3. The application of the qualified adhesive to the window seal of the rail vehicle through the evaluation method can prevent the cracking of the sealant and the rain leakage during the operation of the vehicle, ensure the sealing of the window of the rail vehicle, improve the passenger comfort, and reduce the number of vehicles. Operation failure ensures the window sealing environment requirements and the normal operation and maintenance cycle;

4、弥补了现有的粘接接头在复杂服役环境中老化方法及相关性能评价的空白,具有性能考核较完善和节省老化试验时间等优点。4. It makes up for the existing gaps in the aging method and related performance evaluation of adhesive joints in complex service environments, and has the advantages of more complete performance evaluation and saving aging test time.

显然,上述所描述的实施例仅仅是本发明一部分的实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本发明保护的范围。Obviously, the above-described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

需要注意的是,这里所使用的术语仅是为了描述具体实施方式,而非意图限制根据本申请的示例性实施方式。如在这里所使用的,除非上下文另外明确指出,否则单数形式也意图包括复数形式,此外,还应当理解的是,当在本说明书中使用术语“包含”和/或“包括”时,其指明存在特征、步骤、工作、器件、组件和/或它们的组合。It should be noted that the terminology used herein is for the purpose of describing specific embodiments only, and is not intended to limit the exemplary embodiments according to the present application. As used herein, unless the context clearly dictates otherwise, the singular is intended to include the plural as well, furthermore, it is to be understood that when the terms "comprising" and/or "including" are used in this specification, it indicates that There are features, steps, acts, devices, components, and/or combinations thereof.

需要说明的是,本申请的说明书和权利要求书及上述附图中的术语“第一”、“第二”等是用于区别类似的对象,而不必用于描述特定的顺序或先后次序。应该理解这样使用的数据在适当情况下可以互换,以便这里描述的本申请的实施方式能够以除了在这里图示或描述的那些以外的顺序实施。It should be noted that the terms "first", "second", etc. in the description and claims of the present application and the above drawings are used to distinguish similar objects, and are not necessarily used to describe a specific sequence or sequence. It is to be understood that data so used may be interchanged under appropriate circumstances so that the embodiments of the application described herein can be practiced in sequences other than those illustrated or described herein.

以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.

Claims (11)

1. A rail vehicle window sealant selection evaluation method is characterized by comprising the following steps:
primarily selecting the type of an adhesive, wherein the adhesive selects a low-modulus adhesive meeting performance indexes;
testing the bonding performance of each initially selected adhesive, coating a plurality of adhesive strips on different types of sample plates respectively by the adhesive, sequentially carrying out normal-temperature curing, water soaking, high temperature of 60-100 ℃, high temperature and high humidity of 50-90 ℃ and relative humidity higher than 90%, and low-temperature testing environments of-60 ℃ to-20 ℃, stripping the adhesive strips after each testing environment is finished, and determining that the total cohesive failure proportion of each adhesive strip in each testing environment is greater than 95% to be qualified;
carrying out artificial accelerated aging performance test on each preliminarily selected adhesive, wherein the artificial accelerated aging performance test comprises at least one of an ultraviolet aging test, a high-temperature fatigue vibration test, a simulated acid rain soaking test and a high-low temperature damp-heat alternating aging test, and the tensile shear strength retention rate of the adhesive is tested and calculated after each test;
and comparing the performance difference of the adhesives, and selecting the adhesive type with the best and most stable evaluation performance as the rail vehicle window sealant.
2. The rail vehicle window sealant type selection evaluation method as claimed in claim 1, wherein when the type of the adhesive is initially selected, according to the performance detection report of the adhesive, the adhesive with the tensile shear strength of 1.5-4.5 Mpa, the elongation at break of 200% -450%, the single-side curing depth of more than or equal to 12mm/7d at 23 ℃ and 50% relative humidity, the surface drying time of more than or equal to 10min and the glass transition temperature of less than or equal to-60 ℃ is selected.
3. The rail vehicle window sealant selection evaluation method as claimed in claim 1, wherein the adhesive comprises at least one of a polyurethane adhesive, a modified silane adhesive, and a silicone adhesive.
4. The rail vehicle window sealant type selection evaluation method as claimed in claim 1, wherein when the bonding performance of each of the preliminarily selected adhesives is tested, each of the preliminarily selected adhesives is coated with three adhesive tapes with the width of 9-11mm, the height of more than 5mm and the length of more than 300mm on four sample plates of glass, aluminum alloy, stainless steel and glass fiber reinforced plastic, and then the adhesive tapes are sequentially subjected to the test environments of normal temperature curing for 7 days, water soaking for 7 days, high temperature of 60-100 ℃ for 1 day, high temperature and high humidity of 50-90 ℃ and higher than 90% relative humidity for 7 days, and low temperature of-60 to-20 ℃ for 1 day.
5. The rail vehicle window sealant type selection evaluation method as claimed in claim 4, wherein the test environment is sequentially cured for 7 days at 23 ℃ and 50% relative humidity; soaking in water at 23 deg.C for 7 days, and adjusting for 2 hr; standing at 80 deg.C for 1 day, immediately detecting, taking out at high temperature, and adjusting for 2 hr; standing at 70 deg.C and 95% relative humidity for 7 days, and adjusting room temperature for 2 h; and (3) placing the test piece at the low temperature of minus 40 ℃ for 1 day in five continuous test environments, and stripping the adhesive tape after each test environment is finished.
6. The rail vehicle window sealant type selection evaluation method as claimed in claim 1, wherein when each preliminarily selected adhesive is subjected to an artificial accelerated aging performance test, three samples of aluminum alloy-glass, stainless steel-glass and glass fiber reinforced plastic-glass connected by the adhesive are prepared into tensile shear samples, and then the ultraviolet aging test, the high temperature fatigue vibration test, the simulated acid rain soaking test and the high and low temperature damp and hot alternation aging test are performed.
7. The rail vehicle window seal of claim 1The glue type selection evaluation method is characterized in that when the ultraviolet aging test is carried out, three samples of aluminum alloy-glass, stainless steel-glass and glass fiber reinforced plastic-glass connected by the adhesive are prepared into tensile shearing samples, a tool is used for applying 20% strain to the samples, and the samples are respectively dried for 8 hours, wherein the ultraviolet wavelength is 340nm, and the irradiance is 0.76 +/-0.02W/m2And (3) multiplying the test sample by nm, wherein the blackboard temperature is 60 +/-3 ℃, the blackboard is condensed for 4 hours, the blackboard temperature is 50 +/-3 ℃, three tests with the test periods of 1000 hours, 1500 hours and 2000 hours are carried out on each sample, and the tensile shear strength retention rate is tested and calculated after each test period.
8. The rail vehicle window sealant type selection evaluation method as claimed in claim 1, wherein in the high temperature fatigue vibration test, three samples of aluminum alloy-glass, stainless steel-glass and glass fiber reinforced plastic-glass connected by the adhesive are prepared into tensile shear samples, the thickness of the adhesive layer is 4-6mm, the fatigue aging test of the adhesive material is carried out at 70 ℃, the amplitude of the sample is 1.0mm, the frequency is 30Hz, the cycle is carried out for at least 100 ten thousand times, and the retention rate of the tensile shear strength before and after aging is tested and calculated.
9. The rail vehicle window sealant type selection evaluation method according to claim 1, wherein in the simulated acid rain soaking test, three samples of aluminum alloy-glass, stainless steel-glass and glass fiber reinforced plastic-glass connected by the adhesive are prepared into tensile shear samples, a tool is used for applying a strain of 20% to the samples, each sample is soaked in a simulated acid rain solution with a pH value of 2.0 at 40 ℃ for 480h, 960h and 1440h, the samples are taken out in sequence at each time point for tensile shear strength, and the tensile shear strength retention rate is tested and calculated.
10. The method for selectively evaluating the rail vehicle window sealant according to claim 1, wherein in the high and low temperature humid heat alternating aging test, three samples of aluminum alloy-glass, stainless steel-glass and glass fiber reinforced plastic-glass connected by the adhesive are prepared into tensile shear samples, and are placed for 4h at 80 ℃ and 95% relative humidity, cooled to-40 ℃ within 2h, placed for 4h at-40 ℃ and heated to 80 ℃ and 95% relative humidity within 2h, each sample is subjected to four tests with test periods of 480h, 720h, 960h and 1440h, and the tensile shear strength retention rate is tested and calculated after each test period.
11. The rail vehicle window sealant type selection evaluation method as claimed in claim 1, wherein when an adhesive type with the best and most stable evaluation performance is selected as the rail vehicle window sealant, the adhesive with the tensile shear strength retention rate of more than 55% is selected as the best and most stable adhesive.
CN202210018369.XA 2022-01-07 2022-01-07 Selection and evaluation method of window sealant for rail vehicle Pending CN114354446A (en)

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