CN114349544A - Preparation method of all-mineral metal element liquid - Google Patents
Preparation method of all-mineral metal element liquid Download PDFInfo
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- CN114349544A CN114349544A CN202111525508.XA CN202111525508A CN114349544A CN 114349544 A CN114349544 A CN 114349544A CN 202111525508 A CN202111525508 A CN 202111525508A CN 114349544 A CN114349544 A CN 114349544A
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Abstract
The invention provides a preparation method of a full-mineral metal element liquid, belonging to the technical field of utilization of mineral soil resources. The method comprises the steps of carrying out acidolysis on a raw ore soil material to obtain acidolysis solution; adjusting the pH value of the acidolysis solution by using furnace ash, and then reacting to obtain a reaction solution; and standing and layering the reaction solution to obtain supernatant liquid, namely the all-mineral metal element liquid. The all-mineral metal element liquid can be used for supplementing mineral elements lost in soil, recovering soil enzyme activity, obviously improving crop yield, improving taste and flavor and improving disease and pest resistance. The all-mineral metal element liquid can also be used for antibiotic-free breeding of livestock such as pigs, chickens, ducks, geese and the like, so that the survival rate is obviously improved, and the fatality rate is reduced.
Description
Technical Field
The invention relates to the technical field of utilization of mineral soil resources, in particular to a preparation method of a full-mineral metal element liquid.
Background
In recent decades, the non-cyclic agricultural production mode causes the severe loss of farmland mineral elements, and the loss of the mineral metal elements causes the severe shortage of farmland metal ions. Dozens of metal ions are responsible for activating the photosynthesis enzyme protein, and the serious shortage of the metal ions causes the reduction of the activity of the photosynthesis enzyme protein, so that the photosynthesis is weakened in the growth process of plants, the yield and the quality are reduced, the products are not eaten better and better, and the plant diseases and insect pests are serious. On the other hand, the feed for domestic animals such as pigs, chickens, ducks, geese and the like is seriously lack of metal ions, so that the activity of immunocyte enzyme protein is reduced, the synthesis of immunocyte substances is hindered, the immunocyte defects and the immunity are reduced, and the death rate in the culture process is higher and higher. Therefore, mineral elements lost by soil are supplemented, sufficient photosynthetic enzyme protein is activated, substance synthesis in the plant growth process is promoted, the crop yield can be obviously improved, and the application amount of chemical fertilizers is greatly reduced; the sufficient synthesis of the flavor substances can lead the agricultural products to be more delicious, and improve the quality of the agricultural products; the immune cell substance is synthesized in sufficient quantity, so that the immune cell defect can be effectively repaired, the disease and insect resistance can be improved, and the use of pesticides can be greatly reduced. In addition, the feed is added with the all-mineral metal element liquid, and metal ions in the all-mineral metal element liquid can effectively activate immune cell enzyme proteins of livestock such as pigs, chickens, ducks and geese, promote synthesis of immune cell substances, repair immune cell defects, improve immunity, obviously improve survival rate of the livestock such as pigs, chickens, ducks and geese, reduce fatality rate and realize true antibiotic-free breeding.
In general, people can singly supplement calcium, iron, zinc or several mineral elements to the soil to solve a specific problem(s), but the method is difficult to comprehensively supplement the mineral elements and cannot systematically solve the problem. The problem of the lack of dozens of mineral elements is difficult to solve by singly adding calcium, iron, zinc or a plurality of mineral elements into the feed, and the fatality rate of livestock and poultry is difficult to be fundamentally and greatly reduced.
Disclosure of Invention
The invention aims to provide a preparation method of a full-mineral metal element liquid, and the full-mineral metal element liquid obtained by the invention can be used for supplementing mineral elements lost by soil and can also be added into feed to completely supplement mineral elements lost by livestock and animals.
In order to achieve the above object, the present invention provides the following technical solutions:
the invention provides a preparation method of a full-mineral metal element liquid, which comprises the following steps:
carrying out acidolysis on the ore soil raw material to obtain acidolysis solution;
adjusting the pH value of the acidolysis solution by using furnace ash, and then reacting to obtain a reaction solution;
standing and layering the reaction solution to obtain supernatant liquid, namely the all-mineral metal element liquid;
the mass ratio of the ore soil raw material to the furnace straw ash is 3-5: 0 to 3.
Furthermore, the content of Si element in the ore soil raw material is less than or equal to 60 wt%, the content of Fe element is more than or equal to 9 wt%, the content of Ca element is more than or equal to 4 wt%, and the content of Mg element is more than or equal to 2 wt%.
Further, the acid solution for acidolysis is a sulfuric acid solution or a nitric acid solution with the volume concentration of 1-20%.
Further, the mass-volume ratio of the ore soil raw material to the acid solution is 3-8 g: 10 to 20 ml.
Furthermore, the acidolysis temperature is 15-50 ℃, and the acidolysis time is 2-8 h.
Further, the furnace ash comprises one or more of plant ash, coal ash and furnace ash.
Further, adjusting the pH value of the acidolysis solution to 1-7.5.
Further, the reaction temperature of the mixed solution after acidolysis and the furnace ash is 10-50 ℃, and the reaction time is 1-3 h.
The invention has the beneficial effects that:
the invention utilizes the mixture of the furnace ash and the mineral soil according to different proportions as the raw materials, produces the full mineral metal element liquid by the acidolysis method, has the obvious advantages of wide raw material sources, simple production flow and low production cost, and also has the outstanding advantage of recycling waste.
Detailed Description
The invention provides a preparation method of a full-mineral metal element liquid, which comprises the following steps:
carrying out acidolysis on the ore soil raw material to obtain acidolysis solution;
adjusting the pH value of the acidolysis solution by using furnace ash, and then reacting to obtain a reaction solution;
standing and layering the reaction solution to obtain supernatant liquid, namely the all-mineral metal element liquid;
the mass ratio of the ore soil raw material to the furnace straw ash is 3-5: 0 to 3.
In the invention, the mass ratio of the ore soil raw material to the straw ash is preferably 3.5-4.5: 0 to 2, more preferably 4: 1.
in the invention, the content of Si element in the ore soil raw material is less than or equal to 60 wt%, the content of Fe element is more than or equal to 9 wt%, the content of Ca element is more than or equal to 4 wt%, and the content of Mg element is more than or equal to 2 wt%; preferably, the content of Si element in the ore soil raw material is less than or equal to 58 wt%, the content of Fe element is more than or equal to 10 wt%, the content of Ca element is more than or equal to 6 wt%, and the content of Mg element is more than or equal to 3 wt%; further preferably, the content of Si element in the ore soil raw material is less than or equal to 50 wt%, the content of Fe element is more than or equal to 12 wt%, the content of Ca element is more than or equal to 8 wt%, and the content of Mg element is more than or equal to 4 wt%.
In the present invention, the raw ore material is more preferably the raw ore materials in the following tables 1 and 2:
TABLE 1
TABLE 2
In the present invention, the acid solution for acidolysis is a sulfuric acid solution or a nitric acid solution having a volume concentration of 1 to 20%, preferably 2 to 18%, and more preferably 5 to 15%.
In the invention, the mass-volume ratio of the ore soil raw material to the acid solution is 3-8 g: 10-20 ml, preferably 4-7 g: 12 to 18ml, more preferably 5 to 6 g: 15 ml.
In the invention, the acidolysis temperature is 15-50 ℃, and the acidolysis time is 2-8 h; preferably, the acidolysis temperature is 20-45 ℃, and the acidolysis time is 3-6 h.
In the present invention, the plant ash comprises one or more of plant ash, coal ash and furnace ash, preferably the plant ash and/or coal ash in table 2 above.
In the present invention, the pH of the acidolysis solution is adjusted to 1 to 7.5, preferably 2 to 5, and more preferably 4.
In the invention, the temperature of the reaction between the mixed solution after acidolysis and the furnace ash is 10-50 ℃, and the reaction time is 1-3 h; preferably, the reaction temperature is 15-45 ℃, and the reaction time is 2 h.
The technical solutions provided by the present invention are described in detail below with reference to examples, but they should not be construed as limiting the scope of the present invention.
Example 1
And (3) mixing the following components in percentage by mass: 3, taking the ore soil raw material and the furnace ash as preparation raw materials; 2750ml of 10% sulfuric acid solution is taken, 750g of mineral soil raw material is gradually added into the sulfuric acid solution at room temperature and stirred for 5 hours for full reaction, then 1000 ml of water is added, the furnace ash is gradually added into the solution, the furnace ash is stopped adding when the pH value of the solution is 3, and stirring is carried out for 2 hours for full reaction. Standing for layering, and taking the upper layer liquid to obtain the prepared all-mineral metal element liquid product, wherein the element composition is shown in the following table 3. (wherein, the raw materials of the mineral soil comprise 1 part of mineral soil, 4 parts of mineral soil and 9 parts of mineral soil in a mass ratio of 1: 1: 1; and the furnace ash comprises 2: 1 parts of furnace ash and plant ash in a mass ratio of 2: 1).
Table 3 example 1 elemental composition table for all-mineral metallic liquid
Example 2
Mixing the components in a mass ratio of 1: 1: 1: 1, taking a mixed ore soil raw material of ore soil 1, ore soil 5, ore soil 6 and ore soil 10 as a preparation raw material; 3520ml of 10 volume percent nitric acid solution is taken, 1200g of mixed ore soil raw material is gradually added into the nitric acid solution at 40 ℃ until the pH value of the solution reaches 6, the mixed ore soil raw material is stopped to be added, and the mixture is stirred for 2 hours to fully react. Standing for layering, and taking the upper layer liquid to obtain the prepared all-mineral metal element liquid product, wherein the element composition is shown in the following table 4. The full-mineral metal element liquid is typically characterized by very high calcium content.
Table 4 example 2 liquid elemental composition table for all-mineral metallic elements
From the above examples, the present invention provides a method for preparing a liquid of all-mineral metallic elements. The invention utilizes plant ash, coal ash and mineral soil to be mixed according to different proportions as raw materials, produces the full mineral metal element liquid by a method of dissolving with sulfuric acid or nitric acid, and the mineral elements for supplementing soil loss can promote the synthesis of substances in the process of plant growth, thereby not only obviously improving the crop yield and greatly reducing the application amount of chemical fertilizers, but also obviously improving the quality of agricultural products and the capability of resisting diseases and insect pests and greatly reducing the use of pesticides. In addition, the feed is added with the all-mineral metal element liquid, so that the survival rate of livestock and animals such as pigs, chickens, ducks and geese can be obviously improved, and the fatality rate is reduced.
The invention selects 11 kinds of mineral soil, plant ash and coal ash from Shandong, Henan, Hebei and Liaoning, the compositions of which are shown in tables 1 and 2. It can be seen that mineral elements of mineral soil, plant ash and coal ash from different sources are obviously different, for example, the content of calcium in the mineral soil 1, the mineral soil 3, the mineral soil 10 and the coal ash is relatively high, and the content of potassium in the mineral soil 5, the mineral soil 7, the mineral soil 9 and the plant ash is relatively high, which provides feasibility for pertinently adjusting the composition of the mineral elements according to requirements.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (8)
1. The preparation method of the all-mineral metal element liquid is characterized by comprising the following steps of:
carrying out acidolysis on the ore soil raw material to obtain acidolysis solution;
adjusting the pH value of the acidolysis solution by using furnace ash, and then reacting to obtain a reaction solution;
standing and layering the reaction solution to obtain supernatant liquid, namely the all-mineral metal element liquid;
the mass ratio of the ore soil raw material to the furnace straw ash is 3-5: 0 to 3.
2. The method for preparing the all-mineral metallic element liquid according to claim 1, wherein the content of Si element in the ore soil raw material is not more than 60 wt%, the content of Fe element is not less than 9 wt%, the content of Ca element is not less than 4 wt%, and the content of Mg element is not less than 2 wt%.
3. The method for producing an all-mineral elemental metal solution according to claim 1 or 2, wherein the acid solution for acid hydrolysis is a sulfuric acid solution or a nitric acid solution having a volume concentration of 1 to 20%.
4. The preparation method of the all-mineral elemental metal solution according to claim 3, wherein the mass-to-volume ratio of the raw ore material to the acid solution is 3-8 g: 10 to 20 ml.
5. The method for producing an all-mineral-metal-element liquid according to claim 3, wherein the acid hydrolysis is carried out at a temperature of 15 to 50 ℃ for 2 to 8 hours.
6. The method for preparing the all-mineral metallic element liquid according to claim 1, 4 or 5, wherein the furnace ash comprises one or more of plant ash, coal ash and furnace ash.
7. The method of producing an all-mineral elemental metal solution according to claim 6, wherein the pH of the acid hydrolysis solution is adjusted to 1 to 7.5.
8. The method for producing an all-mineral elemental metal solution according to claim 7, wherein the temperature of the reaction of the mixed solution after the acid hydrolysis with the furnace ash is 10 to 50 ℃ and the reaction time is 1 to 3 hours.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109678624A (en) * | 2019-01-18 | 2019-04-26 | 柳先东 | A kind of mineral water solution and the preparation method and application thereof |
| CN112322909A (en) * | 2020-10-11 | 2021-02-05 | 眉山顺应动力电池材料有限公司 | Method for extracting valuable metal elements from laterite-nickel ore by sulfuric acid leaching method and acid-base regeneration circulation |
| CN112645773A (en) * | 2021-01-08 | 2021-04-13 | 河南炜炎肥业有限责任公司 | Mineral supplement preparation, fertilizer comprising mineral supplement preparation, preparation method and application |
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- 2021-12-14 CN CN202111525508.XA patent/CN114349544A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109678624A (en) * | 2019-01-18 | 2019-04-26 | 柳先东 | A kind of mineral water solution and the preparation method and application thereof |
| CN112322909A (en) * | 2020-10-11 | 2021-02-05 | 眉山顺应动力电池材料有限公司 | Method for extracting valuable metal elements from laterite-nickel ore by sulfuric acid leaching method and acid-base regeneration circulation |
| CN112645773A (en) * | 2021-01-08 | 2021-04-13 | 河南炜炎肥业有限责任公司 | Mineral supplement preparation, fertilizer comprising mineral supplement preparation, preparation method and application |
Non-Patent Citations (1)
| Title |
|---|
| 臧芳芳等: "混合酸热压浸出纯化脉石英及机理", 《中国矿业》 * |
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