CN1142994C - Disinfecting detergent and its production process - Google Patents
Disinfecting detergent and its production process Download PDFInfo
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- CN1142994C CN1142994C CNB021348022A CN02134802A CN1142994C CN 1142994 C CN1142994 C CN 1142994C CN B021348022 A CNB021348022 A CN B021348022A CN 02134802 A CN02134802 A CN 02134802A CN 1142994 C CN1142994 C CN 1142994C
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- disinfecting detergent
- dioxide peroxide
- sodium
- disinfecting
- detergent
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Abstract
The present invention relates to a disinfecting detergent and a production method thereof. The disinfecting detergent is prepared from chlorine dioxide, polyoxyethylene fatty alcohol sodium, fat acyl diethanolamine, sodium dodecyl benzene sulfonate, ethylenediamine tetraacetic acid, sodium tetraborate and deionized water according to a certain proportion. The disinfecting detergent has strong detergency, and is capable of effectively killing hepatitis b viruses and most infection germs. The sterilization effect of the disinfecting detergent is good after the disinfecting detergent is stored for a long time.
Description
Technical field
The present invention relates to washing composition and production technology thereof, more particularly, relate to a kind of disinfecting detergent and production method thereof.
Background technology
The high speed development of science and technology makes people's standard of living have increased significantly, and people are also more and more higher to the requirement of Personal hygiene, and daily article for washing also just becomes requisite thing in the daily life.In recent years, people just especially note dietetic hygiene, tableware totally whether directly influenced health of people.Big tableware to the restaurant, little bowl dish in family, the scavenger of these tablewares has made pendulum problem in face of people.The method of " one wash, two brushes, three dash, four sterilizations, five guarantees are clean " in past obviously can not adapt to current society.How just can find and a kind ofly can efficiently remove dirt, the disinfecting type dish washing detergent that can effectively kill various disease carrying germs has again become the problem that present urgent need solves.Recent years, existing many developed countries developed some disinfecting type washing composition, and as the U.S., Japan, Canada etc., and processing method and prescription update, and Japan has also developed some dishwashing detergent sterilant in this respect.China also develops some sterilizing tableware washing composition in succession, and is releasing some products on the market.Recently have many scholars also to deliver the article of relevant disinfecting type washing composition, but mainly study in washing composition add a kind of sterilant and utilization tensio-active agent in conjunction with the method for new element to reach the purpose of killing disease carrying germ.For example: contain iodine dish washing detergent, dish washing detergent, triclosan dish washing detergent etc.Yet the bacterium that these desinfactant detergents can kill is very limited, and is subjected to the influence of the factor of stability, shelf time and temperature etc.; Iodine and triclosan are invalid to hepatitis B virus, make the disinfecting type washing composition can not reach good effect.
Summary of the invention
The object of the present invention is to provide a kind of clean effect good, can effectively kill hepatitis B virus and most of infect bacterium, and can preserve the long period and kill virus effect disinfecting detergent preferably.
Dioxide peroxide is a kind of new and effective multi-functional sterilizing agent, and the sterilizing ability of wide spectrum is arranged, and sterilization effect is higher 2～3 times than other chlorine-containing agents, does not have the pungency of general chlorine-containing agent, LD
50＞9500mg/kg belongs to nontoxic level material, and skin is had no stimulation.The dioxide peroxide use cost is low, and sterilization is wide, but can kill the great majority disease carrying germ; Generally believe that at present its mechanism of killing to microorganism is that dioxide peroxide pair cell wall has stronger absorption and penetrativity, the oxidation cell includes the enzyme of sulfydryl effectively, arrestin matter is synthetic with killing microorganisms fast, but its poor stability, shelf time is shorter, promptly use stable ClO 2 solution (effective content of dioxide peroxide is more than 2%), after placing for some time at normal temperatures, the composition of the dioxide peroxide in the solution significantly reduces: the liquid detergent normal temperature lucifuge that will contain stabilizing chlorine dioxide was placed after 18 months, kill the hepatitis B virus test again, can not play killing action to hepatitis B virus.
Therefore, add the sodium tetraborate used as stabilizers that dioxide peroxide is had obvious stabilising effect in the prescription of the present invention.The result shows, when sodium tetraborate plays stabilization to dioxide peroxide, the sterilizing ability of dioxide peroxide do not produced inhibition.
Disinfecting detergent of the present invention comprises following components in weight percentage content:
Polyoxyethylenated alcohol sodium sulfate: 5～10% sodium tetraborates: 0.1～0.3%
Diethanolamine of fat acyl: 2～8% butyl glycol ethers: 0.5～2%
Sodium dodecylbenzene sulfonate: 10～15% dioxide peroxide: 0.01～0.05%
Ethylenediamine tetraacetic acid (EDTA): 0.05～0.2% deionized water: surplus
PH value: 7.5～8.5
Wherein said dioxide peroxide is a stable ClO 2 solution, and the weight percentage of dioxide peroxide refers to the net content of dioxide peroxide.
The screening formulation of disinfecting detergent of the present invention comprises following components in weight percentage content:
Polyoxyethylenated alcohol sodium sulfate: 7.5% sodium tetraborate: 0.13%
Diethanolamine of fat acyl: 5% butyl glycol ether: 1%
Sodium dodecylbenzene sulfonate: 12.5% dioxide peroxide: 0.03%
Ethylenediamine tetraacetic acid (EDTA): 0.1% deionized water: surplus
PH value: 7.5～8.5
The production method of disinfecting detergent of the present invention is characterized in that comprising:
(1) presses formula ratio and add Sodium dodecylbenzene sulfonate, polyoxyethylenated alcohol sodium sulfate, diethanolamine of fat acyl, ethylenediamine tetraacetic acid (EDTA), sodium tetraborate, deionized water, heating for dissolving;
(2) be cooled to room temperature, slowly add ClO 2 solution while stirring;
(3) add butyl glycol ether;
(4) regulate between pH value to 7.5～8.5.
Disinfecting detergent of the present invention and production method thereof are all used trisodium citrate adjust pH to 7.5～8.5.
The liquid detergent that adopts prescription of the present invention and method to produce, clean effect is good, can effectively kill hepatitis B virus and multiple unwanted bacterias such as intestinal bacteria and staphylococcus aureus, and the energy long period preserves and the kill virus effect is better, solved the problem that some disinfection liquid detergents are difficult for prolonged preservation greatly, the cost of liquid detergent is not high, helps actual production.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1
According to screening formulation configuration 100 gram liquid detergents of the present invention, each amounts of components is as follows:
Polyoxyethylenated alcohol sodium sulfate: 7.5 grams
Diethanolamine of fat acyl: 5 grams
Sodium dodecylbenzene sulfonate: 12.5 grams
Ethylenediamine tetraacetic acid (EDTA): 0.1 gram
Sodium tetraborate: 0.13 gram
Butyl glycol ether: 1 gram
2.18% ClO 2 solution: 15 grams (being that the dioxide peroxide net content is 0.03 gram)
Water surplus is also transferred pH to 8.0 with trisodium citrate
By compound method preparation of the present invention.
Use enzyme immunoassay to measure hepatitis B surface antigen (HBV) test kit, use double antibody sandwich method, detect through the hepatitis B serum after the liquid detergent processing of the present invention whether contain HBV; 1～10 day detection time, survey once every other day.
The result shows: liquid detergent of the present invention has good killing effect to hepatitis B virus.Liquid detergent has very strong stability, preserves through longer-term, and sterilizing power does not still descend.
Claims (5)
1, a kind of disinfecting detergent is characterized in that comprising following components in weight percentage content:
Polyoxyethylenated alcohol sodium sulfate: 5～10% sodium tetraborates: 0.1～0.3%
Diethanolamine of fat acyl: 2～8% butyl glycol ethers: 0.5～2%
Sodium dodecylbenzene sulfonate: 10～15% dioxide peroxide: 0.01～0.05%
Ethylenediamine tetraacetic acid (EDTA): 0.05～0.2% deionized water: surplus
The pH value: 7.5～8.5 wherein said dioxide peroxide are stable ClO 2 solution, and the weight percentage of above-mentioned dioxide peroxide refers to the net content of dioxide peroxide.
2, disinfecting detergent as claimed in claim 1 is characterized in that comprising following components in weight percentage content:
Polyoxyethylenated alcohol sodium sulfate: 7.5% sodium tetraborate: 0.13%
Diethanolamine of fat acyl: 5% butyl glycol ether: 1%
Sodium dodecylbenzene sulfonate: 12.5% dioxide peroxide: 0.03%
Ethylenediamine tetraacetic acid (EDTA): 0.1% deionized water: surplus
PH value: 7.5～8.5
3, disinfecting detergent as claimed in claim 1 or 2 is characterized in that with trisodium citrate adjust pH to 7.5～8.5.
4, the production method of claim 1 or 2 described disinfecting detergents is characterized in that comprising:
(1) presses formula ratio and add Sodium dodecylbenzene sulfonate, polyoxyethylenated alcohol sodium sulfate, diethanolamine of fat acyl, ethylenediamine tetraacetic acid (EDTA), sodium tetraborate, deionized water, heating for dissolving;
(2) be cooled to room temperature, slowly add ClO 2 solution while stirring;
(3) add butyl glycol ether;
(4) regulate between pH value to 7.5～8.5.
5, the production method of disinfecting detergent as claimed in claim 4 is characterized in that with trisodium citrate adjust pH to 7.5～8.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021348022A CN1142994C (en) | 2002-09-24 | 2002-09-24 | Disinfecting detergent and its production process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB021348022A CN1142994C (en) | 2002-09-24 | 2002-09-24 | Disinfecting detergent and its production process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1403558A CN1403558A (en) | 2003-03-19 |
| CN1142994C true CN1142994C (en) | 2004-03-24 |
Family
ID=4747896
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021348022A Expired - Fee Related CN1142994C (en) | 2002-09-24 | 2002-09-24 | Disinfecting detergent and its production process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1142994C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787334B (en) * | 2010-03-09 | 2012-02-01 | 北京欧凯纳斯科技有限公司 | Pesticide residue removing and sterilizing detergent |
| CN102876484A (en) * | 2012-10-12 | 2013-01-16 | 苏州谷力生物科技有限公司 | Environment-friendly tableware detergent |
| CN103264609A (en) * | 2013-05-09 | 2013-08-28 | 广州大学 | Chemical composition and drawing method |
| CN104450335A (en) * | 2014-11-26 | 2015-03-25 | 成都顺发消洗科技有限公司 | Compound detergent |
| CN105400605A (en) * | 2015-12-16 | 2016-03-16 | 无锡吉进环保科技有限公司 | Industrial heavy-oil-stain cleaning agent |
| CN109423374A (en) * | 2017-08-26 | 2019-03-05 | 陈璇 | A kind of antibacterial dish washing liquid of sodium bicarbonate and preparation method thereof |
-
2002
- 2002-09-24 CN CNB021348022A patent/CN1142994C/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN1403558A (en) | 2003-03-19 |
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